Academic literature on the topic 'Enantiomere'

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Journal articles on the topic "Enantiomere"

1

de Vries, J. X., U. Völker, and E. Weber. "Zur Enantioselektivität von Phenprocoumon beim Menschen*." Hämostaseologie 11, no. 02 (1991): 60–65. http://dx.doi.org/10.1055/s-0038-1660282.

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ZusammenfassungEnantiomere sind Moleküle, die sich wie Bild zu Spiegelbild verhalten; sie weisen fast identische chemische oder physikalische Eigenschaften auf, unterscheiden sich aber in ihren physiologischen Wirkungen. Es wird über das unterschiedliche pharmakokinetische Verhalten und die differierenden pharmakodynamischen Eigenschaften der Enantiomeren der oralen Antikoagulanzien Phenoprocoumon (PH), Warfarin (WA) und Acenocoumarol (AC) beim Menschen und über die daraus resultierenden therapeutischen Konsequenzen berichtet.Für eigene Untersuchungen zur enantioselektiven Elimination von PH b
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Saufi, Ahmad, Cosima B. I. von Heimendahl, A. Wilhelm Alfermann, and Elisabeth Fuss. "Stereochemistry of Lignans in Phaleria macrocarpa (Scheff.) Boerl." Zeitschrift für Naturforschung C 63, no. 1-2 (2008): 13–16. http://dx.doi.org/10.1515/znc-2008-1-203.

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Phaleria macrocarpa (Scheff.) Boerl., a member of the Thymelaeaceae, is traditionally used in Indonesia as medicinal plant against cancer. In this context, we isolated the lignans pinoresinol, lariciresinol and matairesinol from different parts of this plant. The enantiomeric composition of these lignans was determined by chiral column analysis. Pinoresinol and lariciresinol were mixtures of both enantiomers with (79 ± 4)% and (55 ± 6)% enantiomeric excess for the (−)-enantiomers, respectively, whereas matairesinol was found as pure (+)-enantiomer.
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Coles, Simon, David Davies, Michael Hursthouse, Serkan Yeşilot, Bünyemin Çoşut, and Adem Kılıç. "Absolute structure determination as a reference for the enantiomeric resolution of racemic mixtures of cyclophosphazenes via chiral high-performance liquid chromatography." Acta Crystallographica Section B Structural Science 65, no. 3 (2009): 355–62. http://dx.doi.org/10.1107/s0108768109006120.

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Reversed-phase chiral high-performance liquid chromatography (HPLC) is a potentially powerful technique for the enantiomeric resolution of racemic mixtures, although the elution order of enantiomers is only relative and it is necessary to fully characterize reference systems for this method to provide absolute configurational information. The enantiomeric resolution of a series of racemic di-spiro cyclotriphosphazene derivatives, N3P3 X 2[O(CH2)3NH]2 (X = Cl, Ph, SPh, NHPh, OPh) [(1)–(5), respectively] was carried out by reversed-phase chiral HPLC on a commercially available Pirkle-type chiral
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Wagener, H., D. Kalbhen, G. Berner, and U. Vögtle-Junkert. "Ibuprofen - Racemat und Enantiomere*." Aktuelle Rheumatologie 16, no. 02 (1991): 65–69. http://dx.doi.org/10.1055/s-2008-1047384.

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Knabe, Joachim. "Synthetische Enantiomere als Arzneistoffe." Pharmazie in Unserer Zeit 24, no. 6 (1995): 324–30. http://dx.doi.org/10.1002/pauz.19950240608.

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Blaschke, Gottfried, and Wolfgang F. Graute. "Enantiomere des konfigurationsstabilenC-Methylthalidomids." Liebigs Annalen der Chemie 1987, no. 7 (1987): 647–48. http://dx.doi.org/10.1002/jlac.198719870716.

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VS, PRAGADHEESH, ANJU YADAV, and CHANDAN S. CHANOTIYA. "Chiral differentiation of terpenoids in bergamot mint (Mentha citrata) cultivar Kiran: A non-menthol mint essential oil." Journal of Medicinal and Aromatic Plant Sciences 42, no. 2 (2020): 138–44. http://dx.doi.org/10.62029/jmaps.v42i2.vs.

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Mentha citrata, popularly known as bergamot mint,is one of the mint species which does not possess menthol, a terpenoid chemical constituent that gives the name Mentha to the genus. CSIR-CIMAP has developed a cultivar cv. Kiran by induced mutagenesis. Gas chromatographic (GC) analysis of the essential oil of this cultivar shows linalool (44.9 %) and linalyl acetate (28.7%) as the major constituents. Further, the enantioselective GC analysis of the essential oil to determine the enantiomeric ratio of linalool and linalyl acetate indicate that (R)-(-)-linalool is in 78.8% excess over its enantio
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Zhou, Juan, Qiao Chen, Li-lan Wang, Yong-hua Wang, and Ying-zi Fu. "Chiral Discrimination of Tryptophan Enantiomers via (1R, 2R)-2-Amino-1, 2-Diphenyl Ethanol Modified Interface." International Journal of Electrochemistry 2011 (2011): 1–6. http://dx.doi.org/10.4061/2011/502364.

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The paper reported that a simple chiral selective interface constructed by (1R, 2R)-2-amino-1, 2-diphenyl ethanol had been developed to discriminate tryptophan enantiomers. Cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) were used for the characteristic analysis of the electrode. The results indicated that the interface showed stable and sensitive property to determine the tryptophan enantiomers. Moreover, it exhibited the better stereoselectivity for L-tryptophan than that for D-tryptophan. The discrimination characteristics of the chiral selective interface for discr
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Tok, Kenan Can, Mehmet Gumustas, Giorgi Jibuti, Halit Sinan Suzen, Sibel A. Ozkan, and Bezhan Chankvetadze. "The Effect of Enantiomer Elution Order on the Determination of Minor Enantiomeric Impurity in Ketoprofen and Enantiomeric Purity Evaluation of Commercially Available Dexketoprofen Formulations." Molecules 25, no. 24 (2020): 5865. http://dx.doi.org/10.3390/molecules25245865.

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In a recent study, opposite enantiomer elution order was observed for ketoprofen enantiomers on two amylose-phenylcarbamate-based chiral columns with the same chemical composition of the chiral selector but in one case with coated while in the other with an immobilized chiral selector. In the present study, the influence of this uncommon effect on method validation parameters for the determination of minor enantiomeric impurity in dexketoprofen was studied. The validated methods with two alternative elution orders for enantiomers were applied for the evaluation of enantiomeric impurity in six
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Hocking, Martin B., and Aga Z.-Q. Khan. "Chromatographic enantiomer separation and circular dichroism (CD) spectra of three 4-endosubstituted-3,6-diphenyl-3,6-phenylphosphorylcyclohexenes." Canadian Journal of Chemistry 85, no. 9 (2007): 600–602. http://dx.doi.org/10.1139/v07-088.

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Three enantiomeric pairs of Diels–Alder adducts of 2,5-diphenylphosphole-1-oxide have been resolved by elution of each of the enantiomers with 95% ethanol from a swollen microcrystalline triacetylcellulose stationary phase. The degree of separation achieved in each case was confirmed by comparing the absorbance maximum of the UV spectrum of each separated enantiomer with that of a similar concentration of the relevant racemic mixture. The circular dichroism (CD) spectrum of each of the separated enantiomers was recorded, and spectral parameters are listed.Key words: enantiomer separations, thr
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Dissertations / Theses on the topic "Enantiomere"

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Lavé, Thierry. "Pharmacocinetique et methodes d'analyse chromatographique des enantiomeres." Strasbourg 1, 1992. http://www.theses.fr/1992STR15092.

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Würthner, Stefan. "Diskriminierung von Enantiomeren mit chiralen Selektoren." [S.l. : s.n.], 2007.

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Lavé, Thierry. "Etude de la pharmacocinetique et du metabolisme des enantiomeres du tertatolol chez le rat et chez l'homme." Strasbourg 1, 1993. http://www.theses.fr/1993STR15093.

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Frihmat, Rachid. "Stéréoisomérie et biopharmacie : méthodes analytiques par HPLC et étude pharmacocinétique des énantiomères de l'ibuprofène après administration chez le chien." Clermont-Ferrand 1, 1993. http://www.theses.fr/1993CLF1PP08.

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BUI, TUNG HIEP. "Etude de la stereoselectivite de la pharmacocinetique de la chlorpheniramine : influence sur les etudes de bioequivalence (doctorat : pharmacotechnie et biopharmacie)." Paris 11, 1999. http://www.theses.fr/1999PA114819.

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Driehsen, Carina. ""Zur Wirkung von Mirtazapin und seiner Enantiomere auf chronisch neuropathische Schmerzen der Ratte"." Diss., lmu, 2008. http://nbn-resolving.de/urn:nbn:de:bvb:19-90461.

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Leynadier, Daniel. "Interactions de deux enantiomeres 1-deaza-7,8-dihydropteridiques avec le systeme microtubulaire." Aix-Marseille 2, 1993. http://www.theses.fr/1993AIX22954.

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Munkelt, Thomas [Verfasser], and Andreas [Gutachter] Seidel-Morgenstern. "Separation, Speicherung und Gewinnung der Enantiomere chiraler Anästhetika / Thomas Munkelt ; Gutachter: Andreas Seidel-Morgenstern." Magdeburg : Universitätsbibliothek Otto-von-Guericke-Universität, 2019. http://d-nb.info/1219937061/34.

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Chimier, Sylvie. "Etude "in vitro" de la distribution érythrocytaire de la méfloquine et de ses énantiomères." Paris 5, 1996. http://www.theses.fr/1996PA05P143.

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Song, Karine. "Etudes pharmacotoxicologiques du propranolol et de ses enantiomères." Paris 5, 1997. http://www.theses.fr/1997PA05P126.

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Books on the topic "Enantiomere"

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Chromatographic enantioseparation: Methods and applications. 2nd ed. E. Horwood, 1991.

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Allenmark, Stig G. Chromatographic enantioseparation: Methods and applications. E. Horwood, 1988.

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Toda, Fumio, ed. Enantiomer Separation. Springer Netherlands, 2004. http://dx.doi.org/10.1007/978-1-4020-2337-8.

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Todd, Matthew, ed. Separation of Enantiomers. Wiley-VCH Verlag GmbH & Co. KGaA, 2014. http://dx.doi.org/10.1002/9783527650880.

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Schurig, Volker, ed. Differentiation of Enantiomers I. Springer International Publishing, 2013. http://dx.doi.org/10.1007/978-3-319-03239-9.

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Schurig, Volker, ed. Differentiation of Enantiomers II. Springer International Publishing, 2013. http://dx.doi.org/10.1007/978-3-319-03716-5.

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André, Coller, and Wilen Samuel H, eds. Enantiomers, racemates, and resolutions. Krieger Pub. Co., 1991.

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Fumio, Toda, ed. Practical methods of enantiomer separation. Kluwer Academic Publishers, 2004.

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Červinka, Otakar. Enantioselective reactions in organic chemistry. E. Horwood, 1995.

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Fumio, Toda, ed. Enantiomer separation: Fundamentals and practical methods. Kluwer Academic, 2004.

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Book chapters on the topic "Enantiomere"

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Vidal, C., and W. R. Külpmann. "Enantiomere." In Springer Reference Medizin. Springer Berlin Heidelberg, 2019. http://dx.doi.org/10.1007/978-3-662-48986-4_998.

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Vidal, C., and W. R. Külpmann. "Enantiomere." In Lexikon der Medizinischen Laboratoriumsdiagnostik. Springer Berlin Heidelberg, 2018. http://dx.doi.org/10.1007/978-3-662-49054-9_998-1.

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Diwo, S., and G. Petroianu. "Die Pharmakologie von Ketamin: Enantiomere, Distomere, Eutomere und Razemat." In (S)-Ketamin. Springer Berlin Heidelberg, 2002. http://dx.doi.org/10.1007/978-3-662-09790-8_1.

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Ellenbroek, Bart, Alfonso Abizaid, Shimon Amir, et al. "Enantiomers." In Encyclopedia of Psychopharmacology. Springer Berlin Heidelberg, 2010. http://dx.doi.org/10.1007/978-3-540-68706-1_4233.

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Bada, Jeffrey. "Enantiomers." In Encyclopedia of Astrobiology. Springer Berlin Heidelberg, 2015. http://dx.doi.org/10.1007/978-3-662-44185-5_508.

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Uzir, Mohamad Hekarl. "Enantiomers." In Encyclopedia of Membranes. Springer Berlin Heidelberg, 2016. http://dx.doi.org/10.1007/978-3-662-44324-8_2160.

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Bada, Jeffrey. "Enantiomers." In Encyclopedia of Astrobiology. Springer Berlin Heidelberg, 2011. http://dx.doi.org/10.1007/978-3-642-11274-4_508.

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Uzir, Mohamad Hekarl. "Enantiomers." In Encyclopedia of Membranes. Springer Berlin Heidelberg, 2015. http://dx.doi.org/10.1007/978-3-642-40872-4_2160-1.

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Gooch, Jan W. "Enantiomers." In Encyclopedic Dictionary of Polymers. Springer New York, 2011. http://dx.doi.org/10.1007/978-1-4419-6247-8_13634.

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Oonk, H. A. J., and I. B. Rietveld. "Enantiomers." In Physical Chemistry in Action. Springer International Publishing, 2021. http://dx.doi.org/10.1007/978-3-030-68727-4_9.

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Conference papers on the topic "Enantiomere"

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Rincón, D. A., M. C. Daza, and M. Doerr. "Application of the quantum theory of atoms in molecules (QTAIM) to the study of the enzymatic kinetic resolution of propranolol, an amino alcohol with pharmaceutical applications." In VIII Simpósio de Estrutura Eletrônica e Dinâmica Molecular. Universidade de Brasília, 2020. http://dx.doi.org/10.21826/viiiseedmol2020135.

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Propranolol, ((R,S)-1-iso-propylamino-3-(1-naphthoxy)-2-propanol), is a β-adrenergic antagonist and is commercially available as a racemic mixture. Only the S-enantiomer has the desired therapeutic effect. Therefore, many researchers have been working on strategies to obtain S-propranolol with high enantiomeric purity. One approach to carry out the acetylation of (R,S)-Propranolol using Candida antarctica lipase B, CalB. This reaction leads to an enantiomeric purity of 96% at a relatively low conversion rate of 30 %. In our research group, we have been studying this reaction. The CalB active s
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Golder, Francis J., Santhosh M. Baby, Ryan B. Gruber, et al. "Enantiomeric Separation Of Doxapram Reveals The (+)-Enantiomer (GAL-054) To Be A Superior Respiratory Stimulant With An Improved Therapeutic Index." In American Thoracic Society 2012 International Conference, May 18-23, 2012 • San Francisco, California. American Thoracic Society, 2012. http://dx.doi.org/10.1164/ajrccm-conference.2012.185.1_meetingabstracts.a3616.

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Farukh, Arjmand. "Abstract B87:In vitroDNA binding studies of S‐ and R‐enantiomers of organotin complexes: Antitumor activity of S‐enantiomer against human tumor cell lines." In Abstracts: AACR International Conference on Frontiers in Cancer Prevention Research‐‐ Dec 6–9, 2009; Houston, TX. American Association for Cancer Research, 2010. http://dx.doi.org/10.1158/1940-6207.prev-09-b87.

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Krejčová, Romana, Květoslava Horská, Ivan Votruba, and Antonín Holý. "Phosphorylation of enantiomers of HPMPG." In XIth Symposium on Chemistry of Nucleic Acid Components. Institute of Organic Chemistry and Biochemistry, Academy of Sciences of the Czech Republic, 1999. http://dx.doi.org/10.1135/css199902286.

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Kim, Tae Hyun, Jae-Hyeon Ko, Haruki Takayama, Tomohiko Shibata, and Seiji Kojima. "Glass transition dynamics of enantiomer (+)-ibuprofen." In 4TH INTERNATIONAL SYMPOSIUM ON SLOW DYNAMICS IN COMPLEX SYSTEMS: Keep Going Tohoku. American Institute of Physics, 2013. http://dx.doi.org/10.1063/1.4794590.

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Mohammadi, Ershad, T. V. Raziman, and Alberto G. Curto. "Nanophotonic chirality transfer to dielectric Mie resonators." In CLEO: Applications and Technology. Optica Publishing Group, 2022. http://dx.doi.org/10.1364/cleo_at.2022.jtu3b.41.

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We propose that chirality transfer from chiral molecules to dielectric nanoresonators enhances enantiomer detection. Our approach offers circular dichroism enhancements orders of magnitude stronger than optical chirality-based methods.
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Mayer, N., D. Ayuso, M. Ivanov, and O. Smirnova. "Synthetic chiral vortices for highly-sensitive chiral discrimination." In Frontiers in Optics. Optica Publishing Group, 2022. http://dx.doi.org/10.1364/fio.2022.fm4e.5.

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We combine bicircular vortex beams, creating light that displays chirality in the dipole approximation with azimuthally varying handedness. The chiral vortex leads to a robust and highly-sensitive response in molecular enantiomers with topological properties.
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Fujimura, Y., L. González, K. Hoki, J. Manz, Y. Ohtsuki, and H. Umeda. "QUANTUM CONTROL OF ISOMERIZATION AND ENANTIOMER PREPARATION." In Proceedings of the US-Japan Workshop. WORLD SCIENTIFIC, 2000. http://dx.doi.org/10.1142/9789812791948_0003.

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Xiao, Ting-Hui, Zhengyi Luo, Kotaro Hiramatsu, et al. "On-chip chiral-field-enhanced Raman optical activity for biosensing." In Conference on Lasers and Electro-Optics/Pacific Rim. Optica Publishing Group, 2022. http://dx.doi.org/10.1364/cleopr.2022.cpdp_06.

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We demonstrate on-chip chiral-field-enhanced Raman optical activity (ROA) by tailoring a dark mode excited in a silicon nanodisk array. We show >100x enhanced chiral light-molecule interaction with negligible artifacts for ROA measurement of biological enantiomers.
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Pikuta, Elena V., and Richard B. Hoover. "Utilization of alternate chirality enantiomers in microbial communities." In SPIE Optical Engineering + Applications, edited by Richard B. Hoover, Gilbert V. Levin, Alexei Y. Rozanov, and Paul C. W. Davies. SPIE, 2010. http://dx.doi.org/10.1117/12.862232.

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Reports on the topic "Enantiomere"

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Liu, Ying. Chromatographic Separations of Enantiomers and Underivatized Oligosaccharides. Office of Scientific and Technical Information (OSTI), 2004. http://dx.doi.org/10.2172/837283.

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Bradshaw, Jerald S., and Reed M. Izatt. Principles Guiding Enantiomeric Recognition in Macrocycle-Amine Systems. Defense Technical Information Center, 1991. http://dx.doi.org/10.21236/ada234915.

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Bae, Sue Y., and Mark D. Winemiller. Separation of VX, RVX and GB Enantiomers Using Liquid ChromatographyTime-of-Flight Mass Spectrometry. Defense Technical Information Center, 2016. http://dx.doi.org/10.21236/ad1002738.

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Ding, Wei Liang. Capillary electrophoresis separation of neutral organic compounds, pharmaceutical drugs, proteins and peptides, enantiomers, and anions. Office of Scientific and Technical Information (OSTI), 1999. http://dx.doi.org/10.2172/350830.

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Nazyrov, Marat, and Yulia Yarkaeva. Enantioselective voltammetric sensor system based on mesoporous carbon black Carbopack X and cyclopentadiene derivatives for determination of clopidogrel enantiomers. Peeref, 2023. http://dx.doi.org/10.54985/peeref.2307p5734071.

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Bradshaw, J. S., F. Huszthy, C. W. McDaniel, M. Oue, and C. Y. Zhu. Enantiomeric Recognition of Organic Ammonium Salts by Chiral Pyridino- 18-Crown-6 Ligands: A Short Review. Defense Technical Information Center, 1990. http://dx.doi.org/10.21236/ada228546.

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Huszthy, P., J. S. Bradshaw, C. Y. Zhu, T. Wang, and R. M. Izatt. Recognition of the Enantiomers of Chiral Organic Ammonium Salts by Chiral Dibenzyl- and Diphenyl-Substituted Diamido-or Dithionoamidopyridino-18- crown-6 Ligands. Defense Technical Information Center, 1992. http://dx.doi.org/10.21236/ada248026.

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Desai, Meera Jay. Development of Chiral LC-MS Methods for small Molecules and Their Applications in the Analysis of Enantiomeric Composition and Pharmacokinetic Studies. Office of Scientific and Technical Information (OSTI), 2004. http://dx.doi.org/10.2172/837266.

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Joshi, Navalkishore N., Chongsuh Pyun, Verinder K. Mahindroo, Bakthan Singaram, and Herbert C. Brown. Chiral Synthesis via Organoboranes. 33. The Controlled Reaction of B- Alkydiisopinocampheylboranes with Aldehydes Providing a Convenient Procedure for the Enantiomeric Enrichment of the Boronic Ester Products Through Kinetic Resolution. Defense Technical Information Center, 1991. http://dx.doi.org/10.21236/ada238257.

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