Academic literature on the topic 'Enoate'

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Journal articles on the topic "Enoate"

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Rohdich, Felix, Anja Wiese, Richard Feicht, Helmut Simon, and Adelbert Bacher. "Enoate Reductases ofClostridia." Journal of Biological Chemistry 276, no. 8 (2000): 5779–87. http://dx.doi.org/10.1074/jbc.m008656200.

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Rauf, Abdul, and Shabana Ahmad. "Aziridination of Methyl Long-chain Alkenoates Using Chloramine-T." Journal of Chemical Research 2005, no. 6 (2005): 407–9. http://dx.doi.org/10.3184/0308234054506802.

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Methyl long-chain alkenoates on treatment with chloramine-T [N-chloro-N-sodio-p-toluenesulfonamide] resulted in the formation of the corresponding aziridines in moderate yields. The N-substituted aziridine derivatives based on methyl undec-10-enoate (1), methyl (Z)-octadec-9-enoate (3) and methyl (9Z,12R)-12-hydroxyoctadec-9-enoate (5) have been synthesised under mild reaction conditions. The products were characterised using micro-analytical and spectral data.
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Wang, Xiao, and Li-Zhu Zhang. "Methyl 3-aminobut-2-enoate." Acta Crystallographica Section E Structure Reports Online 68, no. 6 (2012): o1930. http://dx.doi.org/10.1107/s160053681202288x.

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The title compound, C5H9NO2, is almost planar (r.m.s. deviation for the non-H atoms = 0.036 Å) and an intramolecular N—H...O hydrogen bond generates an S(6) ring. In the crystal, N—H...O interactions link the molecules into C(6) chains propagating along [010].
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Andrade, L. C. R., J. A. Paixão, M. J. M. de Almeida, E. J. Tavares da Silva, and F. M. Fernandes Roleira. "Pentafluorophenyl 3-phenylprop-2-enoate." Acta Crystallographica Section E Structure Reports Online 62, no. 1 (2005): o193—o194. http://dx.doi.org/10.1107/s1600536805040389.

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Anitha, R., S. Athimoolam, S. Asath Bahadur, and M. Gunasekaran. "4-Chloroanilinium 3-carboxyprop-2-enoate." Acta Crystallographica Section E Structure Reports Online 68, no. 4 (2012): o959—o960. http://dx.doi.org/10.1107/s1600536812008458.

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In the title compound, C6H7ClN+·C4H3O4−, the cations and anions lie on mirror planes and hence only half of the molecules are present in the asymmeric unit. The 4-chloroanilinium cation and hydrogen maleate anion in the asymmetric unit are each planar and are oriented at an angle of 15.6 (1)° to one another and perpendicular to thebaxis. A characterestic intramolecular O—H...O hydrogen bond, forming an S(7) motif, is observed in the maleate anion. In the crystal, the cations and anions are linked by N—H...O hydrogen bonds, forming layers in theabplane. The aromatic rings of the cations are san
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Tsaconas, Michael, Rolf H. Prager, and David S. Millan. "Intramolecular Rearrangements of But-3-enoic Esters." Australian Journal of Chemistry 53, no. 5 (2000): 435. http://dx.doi.org/10.1071/ch00075.

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Support for the proposal by Khalafy and Prager1 of a cheletropic rearrangement of a 6-methylidenecyclohexa-2,4-diene-1-carboxylate under flash vacuum pyrolysis (f.v.p.) conditions has been obtained by a study of the f.v.p. products obtained from methyl 1-methyl-6-methylidenecyclohexa-2,4-diene-1-carboxylate and methyl 2,2-dimethylbut-3-enoate. A significant product in each case arises from a reaction involving decarbonylation and transfer of a methoxy group to C 4 (but-3-enoate numbering).
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Wang, Jian, Wen Zhou, and Wen-Gui Xu. "Ethyl 3-benzoyl-2-hydroxyprop-2-enoate." Acta Crystallographica Section E Structure Reports Online 64, no. 1 (2007): o15. http://dx.doi.org/10.1107/s1600536807061223.

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Xia, Chun-Nian, Wei-Xiao Hu, and Wei Zhou. "Octyl 3-(3,4-dihydroxyphenyl)prop-2-enoate." Acta Crystallographica Section E Structure Reports Online 62, no. 9 (2006): o3900—o3901. http://dx.doi.org/10.1107/s1600536806031588.

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Bujak, Maciej, Jacek Zaleski, Victor Prezhdo, and Boris Uspenskiy. "Methyl 3-(4-methoxyphenyl)prop-2-enoate." Acta Crystallographica Section C Crystal Structure Communications 58, no. 2 (2002): o76—o77. http://dx.doi.org/10.1107/s0108270101019539.

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Xia, Chun-Nian, Wei-Xiao Hu, and Wei Zhou. "Propyl 3-(3,4-dihydroxyphenyl)prop-2-enoate." Acta Crystallographica Section E Structure Reports Online 63, no. 5 (2007): o2482. http://dx.doi.org/10.1107/s1600536807017849.

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Dissertations / Theses on the topic "Enoate"

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Yanto, Yanto. "Evaluation of novel enoate reductases as potential biocatalyst for enantiomerically pure compound synthesis." Diss., Georgia Institute of Technology, 2011. http://hdl.handle.net/1853/39576.

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Asymmetric synthesis with biocatalyst has become an increasingly interesting and cost effective manufacturing process in fine chemicals, pharmaceuticals, and agrochemical intermediates. Enoate reductases from the Old Yellow Enzyme family offer high substrate efficiency, region, stereo-, and enantioselectivity in the catalyzed biotransformations. Asymmetric reduction of activated C=C bond is one of the most widely applied synthetic tools for the potential to generate up to two stereogenic centers in one step reaction. The thesis contributed to the development and characterization of the Old Yel
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Yu, Elsie. "Catalytic Stereoselective Olefin Metathesis for Natural Product Synthesis." Thesis, Boston College, 2018. http://hdl.handle.net/2345/bc-ir:107714.

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Thesis advisor: Amir H. Hoveyda<br>Chapter 1. Efficient Z-Selective Synthesis of Allylic- and Alkenyl Boronates by Catalytic Cross-Metathesis Efficient Z-selective cross-metathesis reactions to furnish Z-(pinacolato)-allylboron and Z-(pinacolato)alkenylboron compounds through catalytic cross-metathesis are disclosed. Z-allylic boron compounds are generated by the use of catalytic amounts of a W-based monoaryloxide monopyrrolide (MAP) complex in up to 91% yield and 96:4 dr after allylation to benzaldehyde. Alkenylboron compounds are prepared in high yields and high Z selectivity in up to 93% yi
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Chaker, Leila. "Réactivité du 4-N,N,-diméthylhydrazonobut-2-enoate de méthyle vis-à-vis des bromonaphtoquinones : synthèses régiospécifiques de dérivés de la benzo(g)quinoléinequinone." Lyon 1, 1995. http://www.theses.fr/1995LYO1T176.

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Toth, Christopher A. "Synthesis of Coupling Substrates for Use in a Highly Enantioselective Conjugated Triene Cyclization Enabled by a Chiral N-Heterocyclic Carbene." Digital Archive @ GSU, 2012. http://digitalarchive.gsu.edu/chemistry_theses/48.

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The ability to generate chiral building blocks is of paramount importance to organic chemists. This problem presents itself most notably at the interface of chemistry and biology, where molecules of only a single enantiomer can induce function to many biological systems. In this context, recent developments in the field of organocatalysis, most notably the employment of chiral N-heterocyclic carbenes (NHCs) have shown much promise. Our group has recently shown that one possible chiral NHC catalyzed Stetter cyclization product of a conjugated triene, a highly functionalized cyclopentenone, cont
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Guo, Junhong. "Part I: Biological Activities and Cellular Metabolism of 4-Hydroxy-7-oxohept-5-enoate and 5-Hydroxy-8-oxo-6-octenoate LactonesPart II: Carboxyalkylpyrrole, Pentylpyrrole and 4-Oxo-heptanedioic Amide Derivatives of Ethanolamine Phospholipids and Proteins." Case Western Reserve University School of Graduate Studies / OhioLINK, 2016. http://rave.ohiolink.edu/etdc/view?acc_num=case1467829630.

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Polo, Ellen Christine 1985. "Controle da estereoquímica remota 1,5 em adições de enolatos de boro de metilcetonas a aldeídos." [s.n.], 2011. http://repositorio.unicamp.br/jspui/handle/REPOSIP/248454.

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Orientador: Luiz Carlos Dias<br>Dissertação (mestrado) - Universidade Estadual de Campinas, Instituto de Química<br>Made available in DSpace on 2018-08-18T09:04:21Z (GMT). No. of bitstreams: 1 Polo_EllenChristine_M.pdf: 6602828 bytes, checksum: d42e742a7de09597441836d6ade5c8bf (MD5) Previous issue date: 2011<br>Resumo: As reações aldólicas com o enolato de boro da metilcetona 44, com protetor cíclico de acetonídeo e relação trans entre os centros quirais, levaram à obtenção de adutos de aldol com níveis de seletividade variando de moderados a bons, em favor do isômero 1,5-anti. Reações aldól
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Lucca, Júnior Emilio Carlos de 1986. "Estudo do efeito do substituinte em ß nas reações aldólicas envolvendo enolatos de boro de metilcetonas." [s.n.], 2011. http://repositorio.unicamp.br/jspui/handle/REPOSIP/248453.

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Orientador: Luiz Carlos Dias<br>Dissertação (mestrado) - Universidade Estadual de Campinas, Instituto de Química<br>Made available in DSpace on 2018-08-18T09:00:14Z (GMT). No. of bitstreams: 1 LuccaJunior_EmilioCarlosde_M.pdf: 5948258 bytes, checksum: 406eb38fa953e871cd9581138b7bc85d (MD5) Previous issue date: 2011<br>Resumo: As reações aldólicas envolvendo os enolatos de boro 71 (P = TBS, R = t-Bu), 72 (P = PMB, R = t-Bu) e 96 (P = TPS, R = t-Bu) levaram à formação de adutos de aldol com seletividades de moderadas a boas em favor do isômero 1,5-syn. As reações aldólicas envolvendo os enolat
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Prasad, R. Shyam. "Chiral aldehyde enolate equivalents." Thesis, University of Oxford, 2001. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.249580.

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Zine, Khalid. "Synthèse régio- et stéréosélective du 4,4,4-trifluorobut-2-énoate d'éthyle porteur d'un groupement tributylstannyl en position alpha ou bêta : réactivité cupro-catalysée des vinylétains en l'absence de complexes du palladium." Thesis, Tours, 2011. http://www.theses.fr/2011TOUR4044/document.

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Vu l’importance des molécules fluorées dans différents domaines et vu la réactivité engendrée par le 4,4,4-trifluorobut-2-ynoate d’éthyle 1 lors des travaux antérieurs réalisés au laboratoire, nous avons décidé d’étudier le comportement de dérivé fluoré 1 vis-à-vis d’hydrure tributylétain sans l’emploi de catalyseurs ou d’additifs. Le but est d’accéder à de nouveaux synthons fluorés par voies originales.Après une étude préliminaire pour effectuer cette réaction d’hydrostannation dans les meilleures conditions, nous avons réalisé pour la première fois la synthèse totalement régio- et stéréoséle
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Penny, M. R. "Studies on enolate directed carbometallation reactions." Thesis, University College London (University of London), 2011. http://discovery.ucl.ac.uk/1324553/.

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The present thesis is concerned with the concept of an enolate directed carbometallation reaction. The first chapter provides a review of the area of heteroatom directed carbometallation of isolated alkynes and allenes as a powerful method for the formation of double bonds and attempts to rationalise the regio and stereochemistry of such additions. The second chapter begins with the results of a small study on the copper(I) mediated carbometallation reactions of homoallenols. The research into the aforementioned enolate directed carbometallation reaction is then presented and discussed, and es
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Books on the topic "Enoate"

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Braun, Manfred. Modern Enolate Chemistry. Wiley-VCH Verlag GmbH & Co. KGaA, 2015. http://dx.doi.org/10.1002/9783527671069.

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Enoree. Royal Fireworks Press, 2009.

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Martha Sofía Parra de Pinillos. La lesión enorme. Pontificia Universidad Javeriana, Facultad de Ciencias Jurídicas y Socio Económicas, 1990.

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Ariel, Sigfredo. El enorme verano. Casa Editora Abril, 1996.

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illustrator, Gurrutxaga Maite 1983, ed. La enorme nada. Fondo De Cultura Económica, Fundación para las Letras Mexicanas, 2015.

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Bonaviri, Giuseppe. L' enorme tempo. A. Mondadori, 1999.

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Sheila Ann Mary Coates Holland. Enohe agape. Harlenik Ellas, 1995.

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Carballido, Emilio. Un enorme animal nube. Fondo Cultura Econónica, 1996.

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Balderston, Daniel. El deseo, enorme cicatriz luminosa. Ediciones eXcultura, 1999.

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Stibilj, Matjaž. Bratstvo na delu: Delovne enote cone A Julijske krajine. Založništvo tržaškega tiska ZTT-EST, 2015.

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Book chapters on the topic "Enoate"

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Schomburg, Dietmar, Margit Salzmann, and Dörte Stephan. "2-Enoate reductase." In Enzyme Handbook. Springer Berlin Heidelberg, 1993. http://dx.doi.org/10.1007/978-3-642-58051-2_104.

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Schomburg, Dietmar, and Margit Salzmann. "2-Oxopent-4-enoate hydratase." In Enzyme Handbook 1. Springer Berlin Heidelberg, 1990. http://dx.doi.org/10.1007/978-3-642-86605-0_202.

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Schomburg, Dietmar, and Dörte Stephan. "2,6-Dioxo-6-phenylhexa-3-enoate hydrolase." In Enzyme Handbook 16. Springer Berlin Heidelberg, 1998. http://dx.doi.org/10.1007/978-3-642-58903-4_138.

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Schomburg, Dietmar, and Dörte Stephan. "L-2-Amino-4-chloropent-4-enoate dehydrochlorinase." In Enzyme Handbook 17. Springer Berlin Heidelberg, 1998. http://dx.doi.org/10.1007/978-3-642-58969-0_47.

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Schomburg, Dietmar, and Dörte Stephan. "4-(2-Carboxyphenyl)-2-oxobut-3-enoate aldolase." In Enzyme Handbook 17. Springer Berlin Heidelberg, 1998. http://dx.doi.org/10.1007/978-3-642-58969-0_8.

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Hall, Mélanie, Christoph K. Winkler, Gábor Tasnádi, et al. "Enoate Reductases for Reduction of Electron Deficient Alkenes." In Practical Methods for Biocatalysis and Biotransformations 2. John Wiley & Sons, Ltd, 2012. http://dx.doi.org/10.1002/9781119943426.ch3.

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Moloney, Mark G. "Enolate Chemistry." In How to Solve Organic Reaction Mechanisms. John Wiley & Sons, Ltd, 2015. http://dx.doi.org/10.1002/9781118698532.ch4.

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Qian, Cheng-Ping, and Takeshi Nakai. "Perfluorinated Enolate Chemistry." In ACS Symposium Series. American Chemical Society, 1991. http://dx.doi.org/10.1021/bk-1991-0456.ch006.

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Abiko, Atsushi. "Boron Enolate Chemistry." In Boron Reagents in Synthesis. American Chemical Society, 2016. http://dx.doi.org/10.1021/bk-2016-1236.ch004.

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Schomburg, Dietmar, and Margit Salzmann. "Enolase." In Enzyme Handbook 1. Springer Berlin Heidelberg, 1990. http://dx.doi.org/10.1007/978-3-642-86605-0_139.

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Conference papers on the topic "Enoate"

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Mues, H., and U. Kazmaier. "Via Ester Enolate Claisen Rearrangements To a Variety of Non-Proteinogenic Amino Acids." In The 4th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2000. http://dx.doi.org/10.3390/ecsoc-4-01901.

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Gudmundsson, Karl S., Abdul A. S. Awwal, and Ricardo Gutierrez-Osuna. "Application of POF on eNose data." In Optical Science and Technology, SPIE's 48th Annual Meeting, edited by Khan M. Iftekharuddin and Abdul Ahad S. Awwal. SPIE, 2003. http://dx.doi.org/10.1117/12.510833.

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Ewing, R. L., H. S. Abdel-Aty-Zohdy, and J. R. Morrison. "Polymorphic Architecture for an Electronic Nose (eNose)." In 2006 49th IEEE International Midwest Symposium on Circuits and Systems. IEEE, 2006. http://dx.doi.org/10.1109/mwscas.2006.381789.

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Sharma, Vasundhara, Agni Christodoulidou, Lanzhu Yue, et al. "Abstract LB-249: HDAC11 regulates lysine acetylation of enolase 1." In Proceedings: AACR Annual Meeting 2018; April 14-18, 2018; Chicago, IL. American Association for Cancer Research, 2018. http://dx.doi.org/10.1158/1538-7445.am2018-lb-249.

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Moor, Catharina, Judith Oppenheimer, Gizal Nakshbandi, et al. "Diagnosis of interstitial lung diseases using eNose technology." In ERS International Congress 2020 abstracts. European Respiratory Society, 2020. http://dx.doi.org/10.1183/13993003.congress-2020.5191.

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M, Ferreiro-González, Palma M, and Ayuso J. "Classification of different gasoline type by HS-MS eNose." In Annual International Conference on Forensic Sciences & Criminalistics Research. Global Science & Technology Forum (GSTF), 2013. http://dx.doi.org/10.5176/2382-5642_fscr13.30.

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Cook, Katherine, Ian Daniels, Victoria Brentville та ін. "Abstract A035: Citrullinated α-enolase as a novel target for cancer immunotherapy". У Abstracts: Second CRI-CIMT-EATI-AACR International Cancer Immunotherapy Conference: Translating Science into Survival; September 25-28, 2016; New York, NY. American Association for Cancer Research, 2016. http://dx.doi.org/10.1158/2326-6066.imm2016-a035.

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Principe, Moitza, Michela Capello, Michelle Samuel Chattaragada, et al. "Abstract A65: Effects of alpha-enolase silencing in adenocarcinoma pancreatic cell line." In Abstracts: AACR Special Conference on Pancreatic Cancer: Progress and Challenges; June 18-21, 2012; Lake Tahoe, NV. American Association for Cancer Research, 2012. http://dx.doi.org/10.1158/1538-7445.panca2012-a65.

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Sanchez, Tino Wilson, Guangyu Zhang, Jitian Li, et al. "Abstract 1130: Targeting the tumor-associated autoantigen alpha-enolase in prostate cancer." In Proceedings: AACR Annual Meeting 2017; April 1-5, 2017; Washington, DC. American Association for Cancer Research, 2017. http://dx.doi.org/10.1158/1538-7445.am2017-1130.

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Oliveira, Helder May Nunes da Silva, and Nelson Luis Saldanha da Fonseca. "Uma estratégia de proteção eficiente em EONs-SDM utilizando p-cycle FIPP." In Simpósio Brasileiro de Redes de Computadores e Sistemas Distribuídos. Sociedade Brasileira de Computação, 2020. http://dx.doi.org/10.5753/sbrc.2020.12280.

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O fluxo contínuo de aplicações e serviços digitais emergentes tem impulsionado um enorme crescimento de tráfego no núcleo da Internet e consequentemente o estudo de tecnologias para aumentar a capacidade dessas redes. A multiplexação por divisão espacial é uma solução promissora para lidar com o esgotamento esperado da capacidade dessas redes. Adicionalmente, a enorme quantidade de tráfego nestas redes acarreta na necessidade de proteção contra falhas, uma vez que essas são relativamente frequentes. Neste artigo, propõe-se um algoritmo de roteamento e proteção em redes ópticas elásticas com mu
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Reports on the topic "Enoate"

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Peak, M. J., J. G. Peak, F. J. Stevens, et al. Characterization of the glycolytic enzyme enolase which is abundant in the hyperthermophilic archaeon, Pyrococcus furiosus. Office of Scientific and Technical Information (OSTI), 1993. http://dx.doi.org/10.2172/10124321.

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Cardini, Alejandra, Andrea Bergamaschi, Vanessa D'Alessandre, and Agustina Ollivier. Educar en tiempos de pandemia: Un nuevo impulso para la transformación digital del sistema educativo en la Argentina. Inter-American Development Bank, 2021. http://dx.doi.org/10.18235/0003323.

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La incorporación de tecnologías digitales a los procesos de enseñanza y aprendizaje tiene un enorme potencial para ampliar las oportunidades de que los niños, niñas, adolescentes y jóvenes desplieguen trayectorias escolares completas, extensas y densas en aprendizajes. Desde mediados de 2020, debido a las medidas para la contención de la circulación del COVID-19, el sistema educativo migró masivamente al espacio digital para impulsar respuestas de emergencia para sostener la continuidad pedagógica. Desde entonces, las políticas educativas digitales, en marcha desde hacía más de dos décadas, re
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Godenau, Dirk, Daniel Buraschi, and Vicente M. Zapata Hernández. Evolución reciente de la inmigración marítima irregular en Canarias. Observatorio de la Inmigración de Tenerife. Departamento de Geografía e Historia. Universidad de La Laguna. Tenerife, 2020. http://dx.doi.org/10.25145/r.obitfact.2020.05.

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La reciente intensificación de las migraciones marítimas irregulares que protagonizan la ruta atlántica a través de Canarias, con el fin de acceder al continente europeo desde el africano, coincide en el tiempo con el desarrollo de la pandemia por coronavirus e incorpora algunas novedades en relación con una corriente que viene estando presente en el devenir del archipiélago desde hace casi tres décadas. También ofrece muchas similitudes con la permanente manifestación de esta afluencia, pese a que la escasa planificación y debilidad de la respuesta articulada inicialmente para abordar su gest
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Godenau, Dirk, Daniel Buraschi, and Vicente M. Zapata Hernández. Evolución reciente de la inmigración marítima irregular en Canarias. Observatorio de la Inmigración de Tenerife. Departamento de Geografía e Historia. Universidad de La Laguna. Tenerife, 2020. http://dx.doi.org/10.25145/r.obitfact.2020.05.

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La reciente intensificación de las migraciones marítimas irregulares que protagonizan la ruta atlántica a través de Canarias, con el fin de acceder al continente europeo desde el africano, coincide en el tiempo con el desarrollo de la pandemia por coronavirus e incorpora algunas novedades en relación con una corriente que viene estando presente en el devenir del archipiélago desde hace casi tres décadas. También ofrece muchas similitudes con la permanente manifestación de esta afluencia, pese a que la escasa planificación y debilidad de la respuesta articulada inicialmente para abordar su gest
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Costa, Paulo, Gisele Nunes, Vitória Martins, Renato Oliveira, José Bitencourt, and Guilherme Oliveira. Manual para o monitoramento da ictiofauna por meio de DNA ambiental (eDNA). ITV DS, 2021. http://dx.doi.org/10.29223/prod.tec.itv.ds.2020.24.costa.

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A ictiofauna amazônica é composta por uma enorme diverdidade de peixes sendo muitas espécies de ocorrência local. Programas de conservação e monitoramento são muitas vezes dificultados tanto pela falta de especialistas quanto pela dificuldade da captura dos espécimes. A criação de indicadores biológicos é de suma importância principalmente para mineração, que necessita realizar monitoramento periódico para verificar se suas atividades estão ou podem causar impactos sob a diversidade ao entorno do empreendimento. Na Serra dos Carajás, um dos maiores depósitos mineral do mundo, existem lagoas qu
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Morales, Olga, Benedicte De Waziers, and Adriana Salazar. ¿Cuál es el impacto de las adquisiciones en el sector de infraestructura?: Número especial de Infraestructura para el desarrollo No. 3. Inter-American Development Bank, 2021. http://dx.doi.org/10.18235/0003062.

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La adecuada dotación de servicios de infraestructura en las sociedades ha probado ser un pilar fundamental para el desarrollo sostenible permitiendo aumentar la calidad de vida, reducir los niveles de pobreza, estimular el crecimiento económico y promover la inclusión social. Estos impactos positivos mantienen a la infraestructura en un lugar primordial en las agendas de la inversión pública de los países de América Latina y el Caribe (ALC). Además, su continuo desarrollo se traduce en cantidades gigantescas de inversión en la región canalizadas en su mayoría a través de contrataciones y compr
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Aguerrevere, Gabriela, María Caridad Araujo, Mariano Bosch, et al. La gran oportunidad: De la crisis a la transformación del empleo femenino. Inter-American Development Bank, 2021. http://dx.doi.org/10.18235/0003222.

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Desde una perspectiva macro, el empleo femenino en América Latina y el Caribe ha vivido cambios positivos a lo largo del siglo XXI. Sin embargo, la incorporación de la mujer al mercado laboral se venía dando en un contexto de desigualdad que se manifestaba en mayor desempleo, segregación ocupacional, y brecha salarial, entre otras desventajas. A esto se suma la pandemia del COVID-19, que ha destruido el empleo como ninguna otra crisis y ha impactado especialmente a las mujeres, exponiendo las vulnerabilidades de los mercados de trabajo de la región y amenazando con deshacer los avances logrado
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