Dissertations / Theses on the topic 'Environmental aspects of Gas stoves'

Field studies were conducted at Lincoln University of Missouri (USA) and Hokkaido University (Japan) to: (i) study the relationships between greenhouse gases emissions and soil properties, (ii) assess the influence of agricultural practices on greenhouse gas fluxes and soil properties and (iii) improve the quantification of greenhouse gases from soil in agricultural fields using geospatial technologies. Results showed that besides soil temperature (T), soil thermal properties such as thermal conductivity (K), resistivity (R) and diffusivity (D) and soil pore spaces indices such as the pore tortuosity factor and the relative gas diffusion coefficient (Ds/Do) are controlling factors for greenhouse gases emissions. Soil thermal properties correlated with greenhouse gases emissions when soil temperature could not. The study has found that predicted Ds/Do and correlate with greenhouse gas fluxes even when the air-filled porosity and the total porosity from which they are predicted did not. We have also showed that Ds/Do and can be predicted quickly from routine measurements of soil water and air and existing diffusivity models found in the literature. Agricultural practices do seriously impact greenhouse gases emissions as showed by the effect of mechanized tillage operations on soil physical properties and greenhouse gas fluxes in a corn and soybean fields. In fact, our results showed that tractor compaction increased soil resistance to penetration, water, bulk density and pore tortuosity while reducing air-filled porosity, total pore space and the soil gas diffusion coefficient. Changes in soil properties resulted in increased CO2, NO and N2O emissions. Finally, our results also confirmed that greenhouse gas fluxes vary tremendously in space and time. As estimates of greenhouse gas emissions are influenced by the data processing approach, differences between the different calculation approaches leads to uncertainty. Thus, techniques for developing better estimates are needed. We have showed that Geographic Information Systems (GIS), Global Positioning System (GPS), computer mapping and geo-statistics are technologies that can be used to better understand systems containing large amounts of spatial and temporal variability. Our GIS-based approach for quantifying CO2, CH4 and N2O fluxes from soil in agricultural fields showed that estimating (extrapolating) total greenhouse gas fluxes using the “standard” approach – multiplying the average flux value by the total field area – results in biased predictions of field total greenhouse gases emissions. In contrast, the GIS-based approach we developed produces an interpolated map portraying the spatial distribution of gas fluxes across the field from point measurements and later process the interpolated map produced to determine flux zones. Furthermore, processing, classification and modeling enables the computation of field total fluxes as the sum of fluxes in different zones, therefore taking into account the spatial variability of greenhouse gas fluxes.

Two beliefs drove this dissertation to be centered on the analysis of the UK corporate disclosure (CD) related to global climate change (GCC). Firstly, GCC is the most significant environmental concern of our current age (IPCC, 2001; Stern, 2006; IPCC, 2007). Secondly, CD could illustrate the values of organizations and possibilities for changing organizations’ responsibility regarding to GCC (Gray et al., 1996; Bebbington and Larrinaga-Gonzalez, 2008; Bebbington et al., 2009). This study utilizes content analysis as its principal method and seeks to achieve its goal by way of a two investigations. The first investigation focuses on disclosures made by direct participants’ (DP) in the UK Emissions Trading Scheme (UK ETS). It captures GCC disclosures from both stand alone (SA) and annual reports (AR) during 2000 - 2004. This part of the study explores if joining the UK ETS changed GCC disclosures. This is tested on both a longitudinal and matched pair (MP) basis. An analysis using institutional theory suggests that instruments of environmental policy may influence GCC disclosures. Results showed that DP increased GCC disclosure, especially in the AR where mainstream business rationale is accepted. MP disclosures, in contrast, focus on the SA media and on different topics than DP disclosures. AR and SA both contain CD, but in this study they showed different patterns of disclosure and therefore may constitute different disclosure media. The second investigation suggests a method to compare GCC disclosure for a sample of DP and MP, using three different media: carbon disclosure project (CDP), AR and SA. Analysis shows that GCC disclosure did not provide sufficient information to compare GCC initiatives and disclosures. Despite the fact that organizations have similar characteristics in terms of sector, size and origin country, they showed different views on GCC issues and this may partially explain differences on GCC initiatives and disclosure.

The aim of this study was to explore the spatial variation in household greenhouse emissions from local transportation in Trondheim, the reasons for this variation, and explore scenarios of what bearing these variations might have on greenhouse gas emissions in the future. Data from a national travel survey was used together with modal emissions coefficients to model the average emissions per capita for 46 geographic zones in Trondheim. Linear regression was used to explain the variation in average emissions using a number of explanatory variables identified from the literature. The regression models explained around 75–80 per cent of the spatial variation in average emissions (0.75 ≤ adj r2 ≤ 0.79), with centre distance explaining the majority of variation. Using a regression function containing centre distance and access to public transport as explanatory variables, five scenarios were constructed for emissions in 2030, which suggest that centralisation of new residential building developments and improvement in the public transport network could limit the growth in annual greenhouse gas emissions to approximately 10 per cent in the presence of approximately 30 per cent population growth.

Measurements of radon (²
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Rn) concentration in soil gas are routinely used to locate geological fault zones. This study was undertaken to investigate the systematic effects that influence radon soil-gas measurements, in preparation for the first such fault zone measurements in South Africa.

Thesis (MTech (Chemical Engineering))--Peninsula Technikon, Cape Town, 2003
The monitoring of pesticide contamination in surface and groundwater is an essential aspect of an assessment of the potential environmental and health impacts of widespread pesticide use. Previous research in three Western Cape farming areas found consistent (37% to 69% of samples) pesticide contamination of rural water sources. However, despite the need, monitoring of pesticides in water is not done due to lack of analytical capacity and the cost of analysis in South Africa. The Solid Phase Microextraction (SPME) sampling method has been developed over the last decade as a replacement for solvent-based analyte extraction procedures. The method utilizes a short, thin, solid rod of fused silica coated with an absorbent polymer. The fibre is exposed to the pesticide contaminated water sample under vigorous agitation. The pesticide is absorbed into the polymer coating; the mass absorbed depends on the partition coefficient of the pesticide between the sample phase and the polymeric coating, the exposure time and factors such as agitation rate, the diffusivity of the analyte in water and the polymeric coating, and the volume and thickness of the coating. After absorption, the fibre is directly inserted into the Gas Chromatograph (GC) injection port for analysis. For extraction from a stirred solution a fibre will have a boundary region where the solution moves slowly near the fibre surface and faster further away until the analyte is practically perfectly mixed in the bulk solution by convection. The boundary region may be modelled as a layer of stationary solution surrounded by perfectly mixed solution.

The effect of shale gas activities on ground-level ozone pollution in the Dallas-Fort Worth area is studied in detail here. Ozone is a highly reactive species with harmful effects on human and environment. Shale gas development, or fracking, involves activities such as hydraulic fracturing, drilling, fluid mixing, and trucks idling that are sources of nitrogen oxides (NOX) and volatile organic compounds (VOC), two of the most important precursors of ozone. In this study two independent approaches have been applied in evaluating the influences on ozone concentrations. In the first approach, the influence of meteorology were removed from ozone time series through the application of Kolmogorov-Zurbenko low-pass filter, logarithmic transformation, and subsequent multi-linear regression. Ozone measurement data were acquired from Texas Commission on Environmental Quality (TCEQ) monitoring stations for 14 years. The comparison between ozone trends in non-shale gas region and shale gas region shows increasing ozone trends at the monitoring stations in close proximity to the Barnett Shale activities. In the second approach, the CAMx photochemical model was used to assess the sensitivity of ozone to the NOX and VOC sources associated with shale oil and gas activities. Brute force method was applied on Barnett Shale and Haynesville Shale emission sources to generate four hypothetical scenarios. Ozone sensitivity analysis was performed for a future year of 2018 and it was based on the photochemical simulation that TCEQ had developed for demonstrating ozone attainment under the State Implementation Plan (SIP). Results showed various level of ozone impact at different locations within the DFW region attributed to area and point sources of emissions in the shale region. Maximum ozone impact due to shale gas activities is expected to be in the order of several parts per billion, while lower impacts on design values were predicted. The results from the photochemical modeling can be used for health impact assessment and air quality management purposes. Both studies in this research show that the impact of shale gas development on local and regional level of ozone is significant, and therefore, it should be considered in the implementation of effective air quality strategies.

This study uses life cycle analysis to examine the net greenhouse gas (GHG) emissions from the activities of the peat industry in Canada for the period 1990 to 2000. GHG accounting is undertaken for (1) land use change, (2) peat extraction and processing, (3) the transport of peat to market by truck, train and ship, and (4) the in situ decomposition of extracted peat. The emission estimates were based on results from GHG accounting models using data derived from scientific literature, government and industry statistics, and the responses to a questionnaire sent to Canada's peat establishments. The questionnaire, designed to obtain information on peat extraction methods, land and fuel use, as well as the transportation of peat, had a response rate representing 69% of Canada's total peat production in the year 2000. Results indicate that 540 600 tonnes of greenhouse gases were emitted in 1990 and 893 300 tonnes were emitted in the year 2000 (emission figures are measured in CO2 equivalents using a 100-year time horizon). Peat decomposition was by far the largest source of GHG emissions, averaging 70.6% of total emissions during the eleven-year period from 1990 to 2000. Greenhouse gases from land use change averaged 14.7%. An average of 10.4% of total emissions resulted from the transport of peat to market, while GHGs from extraction and processing averaged 4.3%. Predictions of the annual GHG emissions from the peat industry, assuming a "business as usual" context, were produced for the years 2001 to 2012. These figures were compared with those resulting from various greenhouse gas reduction scenarios.

Thesis (PhD)--Stellenbosch University, 2012.
ENGLISH ABSTRACT: World crude oil demand and production is set to increase in the long term and is projected to increase from 82 barrels per day in 2007 to an estimated 104 million barrels per day in 2030 according to the International Energy Agency. The environmental challenges posed by the current and projected increased future fuel use, with specific reference to air, aquatic and terrestrial impact, are driving producers and legislators to change fuel specifications and consequently fuel properties to be less harmful to the environment. Traditionally transportation fuels are produced through crude oil refining but in South Africa more than one third of the liquid fuels are produced synthetically through catalytic conversion of gassified coal via the Fischer-Tropsch process by Sasol. Diesel from syncrude is referred to as synthetic diesel and the refiner must blend various hydrocarbon streams, effectively tailoring the diesel to its final composition. Biodiesel from renewable sources like vegetable oils is considered environmentally more acceptable than petrodiesel because of its high biodegradability in the environment, lower sulphur and aromatic hydrocarbon content as well as lowered particulate content in the exhaust emissions. The present research was aimed at evaluating whether the composition of diesels derived from different feed stocks, that included coal, natural gas, crude oil and soybean oil, would influence its biodegradability and ecotoxicity. Acute aquatic tests that included freshwater fish, crustaceans, algae and marine bacteria were used to determine the acute toxicity of diesels. In addition, quantitative structure activity relationship models were used to estimate the biodegradation and ecotoxicity properties of the diesels in an attempt to develop a cost effective tool to determine those properties. The results indicated that the 2-D GC technique quantitatively and qualitatively identified the hydrocarbon constituents in the diesels. The relevance of using the 2-D GC technique was in identifying and quantifying the hydrocarbon breakdown products and being used in a mass balance to confirm the potential biological breakdown processes of the materials used in the present study. The differences in theoretical oxygen demand (ThOD) of the different experimental diesel blends using various blending materials and biodiesel, emphasised and confirmed the importance of calculating the ThOD for the respective blending materials when measuring the biodegradation rates. Furthermore, the biodegradation hierarchy of Pitter and Chudoba (1990) in order of decreasing biodegradability: alkanes > branched alkanes > cyclo-alkanes > aromatic hydrocarbons, could be expanded to include FAME: FAME > alkanes > branched alkanes > cyclo-alkanes > aromatic hydrocarbons. The biochemical pathways identified for the biodegradation of all the diesels was enzyme-enhanced β-oxidation. The present research also indicated that biodiesel addition to crude-derived diesels to increase the density to within the current required specifications for diesels cannot be a reality in SA because of the underdeveloped biodiesel industry. To increase the density by using biodiesel to within the specification for GTL diesel, more than 27% biodiesel would be required, which is currently is not achievable from an economic perspective as well as governmental national strategy perspective. The addition of biodiesel as lubricity enhancer seems more plausible, because less than 5% would be required for petrodiesels. The results on the ecotoxicity of the diesels and diesel blends demonstrated a general lack of acute toxic effect, especially for the fish and crustaceans used during the present study. Although algal and bacterial tests showed an effect at most of the WAF loading rates, none were high enough to enable the calculation of a median effect loading rate (EL50). QSAR‟s, like EPI Suite, together with prediction models, like the Fisk Ecotoxicity Estimation Model, can be used to screen for ecotoxicity and biodegradability of hydrocarbons found in Petrodiesels. It was less applicable for the prediction of biodiesel constituents. The use of different cut-off values for the constituents of biodiesel could be developed in future research. The use of this combination enabled the present research into the potential toxicity of hydrocarbon mixtures to be conducted, especially since tests on individual constituents are impractical. QSAR‟s may provide a relatively cost-effective way to screen for potential environmental acceptability of such mixtures. The contributors to the toxicity of mixtures of hydrocarbons found in diesels were evaluated and it appears that paraffins contribute more to the overall toxicity than previously thought and aromatics less. By putting well-defined policies and incentives in place, a robust biodiesel industry could be created that will enable SA to contribute to the mitigation of the threat of climate change, to become less dependent on foreign oil and to develop rural agriculture. The key to energy security is not one solution to South Africa‟s energy needs, but a multifaceted approach to the complex subject of sustainable energy security. The end of the hydrocarbon era of energy is not in sight, at least for the near future, but soon even hydrocarbon energy in the form of coal and crude oil will have to be re-evaluated as SA‟s major energy resource for economic and energy security. In SA the potential of developing natural gas resources through fracking, nuclear, solar, wind, biological and even wastes to energy processes as well as better energy efficiency, in a balanced and diverse energy portfolio, could pave the way toward energy security in the long run.
AFRIKAANSE OPSOMMING: Ru-olie aanvraag en produksie wêreldwyd is besig om toe te neem en die Internasionale Energie Agentskap projekteer dat wêreld ru-olie verbruik sal toeneem van 82 vate per dag in 2007 tot „n beraamde 104 vate per dag in 2030. Die omgewings uitdagings wat huidige en toekomstige toename in brandstof verbruik, spesifiek die impak op lug gehalte, water- en grond, mag hê, is dryfvere vir produseerders en reguleerders om brandstof spesifikasies te verander om minder omgewings impak te veroorsaak. Brandstof vir vervoer doeleindes word oor die algemeen van ru-olie gemaak, maar in Suid Afrika word ongeveer „n derde van die vloeibare brandtof gemaak deur middel van gekatiliseerde omskakeling van vergasde steenkool via die Fischer-Tropsch proses by Sasol. Diesel wat uit sintetiese ru-olie gemaak is, is sinteties en die raffineerder moet verskillende koolwaterstof strome meng om „n finale produk te lewer. Biodiesel wat uit hernubare hulpbronne soos plant-olies en diervet gemaak word, kan oorweeg word vir die vervaardiging van meer omgewings aanvaarbare brandstof met laer swael en aromatiese koolwaterstof inhoud en ook minder partikel inhoud in die uitlaatgas. Die huidige navorsing het beoog om te evalueer of die samestelling van diesels wat vervaardig is uit verskillende hulpbronne, wat steenkool, aardgas, ru-olie en sojaboon olie ingesluit het, die biodegradeerbaarheid en ekotoksisiteit kan beïnvloed. Akute akwatiese toetse wat varswater vis, krustaseë, alge en marine bakterieë ingesluit het, was aangewend om die akute toksisiteit van die diesels te bepaal. Kwantitatiewe struktuur aktiwiteit verwantskaps modelle is ook gebruik om die biodegradeerbaarheid en ekotoksisiteits eienskappe van die diesels te beraam om vas te stel of 'n bekostigbare alternatief beskikbaar is om daardie eienskappe te bepaal. Die resultate het aangedui dat die 2D GC tegniek kwantitatief en kwalitatief gebruik kan word om die koolwaterstowwe in die diesels te identifiseer. Die benutting van die 2D GC tegnieke is egter om die koolwaterstof afbraak produkte te identifiseer en ook om die massa balans gedurende die biodegradering te bevestig. Die verskil in teoretiese suurstof aanvraag van die verskillende diesels het die belangrikheid daarvan blemtoon en bevestig om die teoretiese suurstof aanvraag korrek te bereken en sodoende die biodegradasie korrek te bepaal. Verder kan die biodegradasie hierargie van Pitter en Chudoba (1990) volgens afnemende biodegradasie: alkane > vertakte alkane > siklo-alkane > aromatiese koolwaterstowwe, uitgebrei word om vetsuur-metielesters in te sluit: vetsuur-metielesters > alkane > vertakte alkane > siklo-alkane > aromatiese koolwaterstowwe. Die biochemiese roetes wat geïdentifiseer is vir die biodegradasie van die diesels, was ensiem-verbeterde β-oksidasie. Die huidige navorsing het ook aangedui dat biodiesel toevoeging tot ru-olie vervaardigde diesel om die digtheid te verhoog to binne huidige spesifikasies is nog nie lewensvatbaar in Suid Afrika nie as gevolg van die onderontwikkelde biodiesel industrie. Om die digtheid te verhoog met biodiesel tot binne spesifikasie verg meer as 27% biodiesel en is huidiglik nie haalbaar vanuit 'n ekonomiese persketief en ook nie vanuit 'n regerings nasionale strategie perspektief nie. Die toevoeging van biodiesel as lubrisiteits vervetering blyk meer van toepassing te wees aangesien minder as 5% biodiesel toevoeging benodig sou wees. Die resultate van die ekotoksisiteits toetse het 'n algemene gebrek aan akute toksisiteits effek aangedui, veral vir vis en skaaldiere wat in die huidige studie gebruik is. Howel alge en bakteriële toetse daarop gedui het dat 'n toksiese effek wel aanwesig was, was dit gering en kon die median effektiewe ladings koers (EL50) nie bepaal word nie. QSARs, soos Epi Suite, tesame met voospellings modelle, soos die Fisk Ecotoxicity Estimation Model, kan gebruik word om ekotoksisiteit en biodegradeerbaarheid van koolwaterstowwe in petrodiesels te beraam, alhoewel dit minder van toepassing was op biodiesel. Die gebruik van ander afsny waardes spesifiek vir biodiesel kan oorweeg word in toekomstige navorsing. Die molecules wat bygedra het tot die toksisiteit van die koolwaterstof mengsels was geëvalueeren daar is gevind dat die paraffiniese molekules meer begedra het tot die totale toksisiteit en die aromate minder. Deur goed gedefinieerde beleid en aansporings meganismes inplek te sit, kan 'n biodiesel industrie in SA geskep word wat SA sal help om by te dra tot die bekamping van klimaats vendering en sodoende minder afhanklik te wees van buitelandse olie en ook landbou in SA te bevorder. Die sluetel tot energie sekuriteit is nie een oplossing vir SA se energie aanvraag nie, maar eerder 'n veelsydige benadering tot die komplekse onderwerp van volhoubare energie sekuriteit. Die einde van koolwaterstof energie is nog nie in sig nie, ten miste nie in die nabye toekoms nie, maar binnekort sal selfs koolwaterstof energie in die vorm van steenkool en ru-olie heroorweeg moet word as SA se hoof energie hulpbronne vir ekonomiese en energie sekuriteit. In SA moet die potensiaal van natuurlike gas ontginning deur middel van hidrauliese breking, kernkrag, wind energie, biologiese energie en selfs afval tot energie prosesse bestudeer word, so-ook beter energie doeltreffendheid om sodoende 'n gebalansweerde energie portefuelje te skep wat die weg sal baan na energie sekuriteit op die lang termyn.

Mobile source emissions are a major contributor to global and local air pollution. Governments and regulatory agencies have been increasing the stringency of regulations in the transportation sector for the last ten years to help curb transportation sector air pollution. The need for regulations has been emphasized by scientific research on the impacts from ambient pollution, especially research on the effect of particulate matter on human health. The particulate emissions from diesel vehicles, diesel particulate matter (DPM) is considered a known or probable carcinogen in various countries and increased exposure to DPM is linked to increased cardiovascular health problems in humans. The toxicity of vehicle emissions and diesel particulate emissions in particular, in conjunction with an increased awareness of potential petroleum fuel shortages, international conflict over petroleum fuel sources and climate change science, have all contributed to the increase of biodiesel use as an additive to or replacement for petroleum fuel. The goal of this research is to determine how this increased use of biodiesel in the particular emission testing setup impacts urban air quality. To determine if biodiesel use contributes to a health or climate benefit, both the size range and general composition were investigated using a comprehensive comparison of the particulate component of the emissions in real time. The emissions from various biodiesel and diesel mixtures from a common diesel passenger vehicle were measured with a cavity ring-down transmissometer (CRDT) coupled with a condensation particle counter, a SMPS, a nephelometer, NOx, CO, CO2, and O3 measurements. From these data, key emission factors for several biodiesel and diesel fuel mixtures were developed. This approach reduces sampling artifacts and allows for the determination of optical properties, particle number concentration, and size distributions, along with several important gas phase species' concentrations. Findings indicate that biodiesel additions to diesel fuel do not necessarily have an air quality benefit for particulate emissions in this emission testing scenario. The often cited linear decrease in particulate emissions with increasing biodiesel content was not observed. Mixtures with half diesel and half biodiesel tended to have the highest particulate emissions in all size ranges. Mixtures with more than 50% biodiesel had slightly lower calculated mass for light absorbing carbon, but this reduction in mass is most likely a result of a shift in the size of the emission particles to a smaller size range, not a reduction in the total number of particles. Evaluation of the extensive optical properties from this experimental set-up indicates that biodiesel additions to diesel fuel has an impact on emission particle extinction in both visible and near-IR wavelengths. The B99 mixture had the smallest emission factor for extinction at 532 nm and at 1064 nm. For the extinction at 532 nm, the trend was not linear and the emission factor peaked at the B50 mixture. Results from intensive properties indicate that emissions from B5 and B25 mixtures have Ångström exponents close to 1, typical for black carbon emissions. The mixtures with a larger fraction of biodiesel have Ångström exponent values closer to 2, indicating more absorbing organic matter and/or smaller particle size in the emissions. Additional experimental testing should be completed to determine the application of these results and emission factors to other diesel vehicles or types of diesel and biodiesel fuel mixtures.

Storm water sediment runoff from disturbed landscapes has the potential to impair aquatic environments. Small construction sites of 1-5 acres in the United States are currently regulated by the United States Environmental Protection Agency to minimize storm water runoff damages to the environment. Gas well construction sites are similar to other construction sites in how the landscape is altered, but are not similarly regulated. This study identified sediment runoff from gas well development sites by collecting it in traps and weirs, and by measuring sediment debris lobes. Sediment primarily consisted of silt and clay sized particles. Sediments from two gas well sites formed five debris lobes that ranged in size from 325 to 3,290 square feet. Sediment loadings estimated from the debris lobes averaged 57.1 tons per year/acre. Future studies should focus on further quantification of sediment movement off of gas well sites and identify effective erosion control methods.

This thesis presents a political geography of transparency, regulation and resource making in shale gas projects in the United Kingdom (UK) and the United States (US). The emergence of shale gas as a politically and economically desirable resource occupied national political aspirations, most notably in the US and to some extent in the UK, for reasons of energy security and economic development. Although shale gas has become a globally desirable resource, this thesis shows that the resource is not same everywhere. Following knowledge making practices in distinct regulatory regimes of the UK and the US, I trace how making of shale gas resource is subjected to contestation in a range of technical fields, such as law, economics, geosciences and environmental impact assessment. The study is based on in-depth analysis of technical and policy documents, and interviews with a wide range of actors (i.e. regulators, gas companies, investors, scientists, landowners), and field visits in the US (New York, Pennsylvania and Texas) and the UK (Lancashire, Litchfield and London). Drawing on theoretical insights from the Science and Technology Studies (STS), legal and resource geographies, I empirically showed that both regulatory practices and resource materialities matter in encapsulating making of shale gas projects in different national contexts. Documenting how information production and its contestation is entangled with assemblages of materials and technologies, as well as regulatory, geoscientific and market interventions in the context of the UK and the US, this thesis offers an alternative account of the geography of transparency and regulation regarding the development of shale gas policies. The political viability of shale projects depends on how these informational spaces are generated, contested and transformed in nationally specific scientific practices and regulatory regimes.

In North Texas, the Barnett Shale underlies large areas of the Dallas-Fort Worth Metroplex (DFW), which magnifies debates about the externalities of shale gas development (SGD). Continued demand for natural gas and expansive urbanization in DFW will cause more people to come in contact with drilling rigs, gas transport, and other urban shale gas landscapes. Thousands of gas wells within the DFW region occupy a large, yet scattered land surface area. DFW city planners, elected officials, and other stakeholders must deal with current and future urban growth and the surface impacts that are associated with gas development. This research examines how shale gas landscapes affect urban land uses, landscapes, and patterns of development in DFW. The study focuses on multiple fast growing DFW municipalities that also have high numbers of gas well pad sites. This study asks what are the spatial characteristics of gas well production sites in DFW and how do these sites vary across the region; how do gas well production sites affect urban growth and development; and how are city governments and surface developers responding to gas well production sites, and what are the dominant themes of contestation arising around gas well production sites and suburban growth?

Large areas of northern peatlands have been drained and afforested in the second half of the 20th century with significant impacts on important ecosystem services, including loss of biodiversity and potential changes in C storage. A considerable effort is currently invested into restoring original peatland function and ecosystem services, with an increasing area of newly restored peatland areas over recent years. However, the effect of restoration on the greenhouse gas (GHG) budget is unknown. This study is the first quantification of CO2, CH4 and N2O fluxes from forest-to-bog restoration sites spanning 0 to 17 years in age. Further, the impact of afforestation on peat decomposition is measured in situ, and the impact of afforestation on the biochemical composition of the peat in relation to CO2 and CH4 fluxes is investigated. Results show that forest-to-bog restoration is successful from a GHG perspective, since all three major GHG fluxes of the restoration sites are changing along the chronosequence towards the fluxes from near pristine bog sites. The peat decomposition rate under the forest plantations is a big part of the total soil respiration at 126.8 ± 14.7 g C m-2 y-1 (44% of total soil CO2 efflux) and our results indicate a slowing down of peat decomposition towards the near pristine bog. CH4 fluxes increase with restoration age, whilst all sites remain a small sink for N2O. I observed changes in peat quality and nutrient availability in the pore water under forests. Different CO2 fluxes between vegetation-free peat cores from different sites for the same temperature and water level show that these differences in peat quality and nutrient availability shape the biogeochemical processes in the peatlands. However only small differences in CH4 fluxes between sites were evident, suggesting that on its own (and in absence of biotic interactions under field conditions), forestry effects on CH4 flux are limited.

The broad objective of this study was to evaluate the effects of grazing and housing management systems on greenhouse gas emissions, blood profiles and meat quality of Nguni goats. A total of 64 castrated Nguni goats were used and a housing structure was designed to accommodate the goats as well as evaluate effects of type of floor on greenhouse gases, meat quality, blood metabolites and fatty acid profiles. In the first experiment: Forty-eight castrated Nguni goats, at 6-7 months old were used for herding (H) or tethering (T) management systems and randomly allocated to pens with earth (E) or slatted (S) floors. Gas sampling was done using static chambers and analysed using a SRI 8610C gas chromatography machine. The highest CH4 fluxes were from the manure of herded goats on earth floors (HE). The highest CO2 fluxes were from manure of herded goats that were housed on slatted floors (HS): The highest N2O fluxes were from the manure of tethered goats that were sheltered on slatted floors (TS). It was concluded from the first experiment that goat manure is an important source of GHG that is influenced by grazing and floor type management systems. The second experiment was done to evaluate greenhouse gas (GHG) emission from disused (DP) vs occupied goat pens (OP) with earth (EF) or slatted (SF) floors. Eight previously occupied pens were used in this study. Sixteen goats were randomly put in the pens labelled occupied pens with earth floors (OPEF) and occupied pens with slatted floors (OPSF) resulting in four goats per OP. There were month by pen use; month by floor type; and use by floor type interaction effects (P < 0.05) on CH4 production. Floor type, use (DP vs OP) and month affected (P < 0.05) CH4 production. Manure on earth floors of occupied pens (OPEF) emitted the highest (P < 0.05) methane followed by earth floors of disused pens (DPEF). The least CH4 was emitted from DPSF. There was pen use (DP vs OP) by floor type interaction effect (P < 0.05) on CO2 emission. Floor type and pen use affected (P < 0.05) CO2 production. Manure in occupied pens with slatted floors (OPSF) produced the highest CO2 and the least CO2 was from disused pens with slatted floors (DPSF). Floor type and month influenced (P < 0.05) N2O production. It was concluded that continued use of goat pens increased GHG emissions. However, disused goat pens with manure remain an important source of GHG as they continued to emit quantifiable levels of CH4, CO2 and N2O. The third experiment was done to determine the effects of grazing and housing management systems on the concentrations of blood metabolites, activity of creatine kinase, body weight (BW), body condition score (BCS) and carcass characteristics using 48 castrated Nguni goats. Tethered goats had higher (P<0.05): urea, creatinine, total protein, globulin concentrations and more activity of CK than herded goats. On the other hand, herded goats had higher (P<0.05) plasma glucose (H: 3.39±0.020 vs T: 3.23±0.020 mmol/L), serum albumin (H: 15.30±0.147 vs T: 14.82±0.144 g/L) concentration. It was concluded that serum concentrations of all the metabolites and the activity of CK were sensitive to grazing system. Herding of goats promoted more glucose concentration and preservation of muscle protein and hence superior body weights and BCS than tethered goats. The fourth experiment was done to determine the effects of grazing and housing management systems on the activity of creatine kinase (CK) and cortisol concentration, and chevon quality. Further, the effect of muscle type [Muscularis longissimus thoracis et. Lumborum (LTL) and triceps brachii (TB)] on chevon quality was also investigated. Forty eight castrated Nguni goats aged 6- 7 months were randomly allocated to tethering (n=24) and herding (n=24) treatments. Floor type affected meat (P<0.05) pH24. Tethered goats had higher (P < 0.05) L* and CL percent than herded goats. Muscle type had a significant influence (P < 0.05) on a*, WBSF and pH. It was observed and concluded that T resulted in higher L* and more CL percent whilst SF lowered the pH24 of chevon; at the same time meat from the TB muscle was more tender, despite having a higher pH24 and more CL percent relative to LTH cuts. The fifth experiment was done to determine the effect of grazing and floor type on fatty acid composition of chevon from tethered and herded Nguni goats. Floor type had no effect on fatty acid composition. Oleic, stearic, palmitic and linoleic were the major fatty acids. Chevon from tethered goats had higher (P < 0.05) proportions of long chain polyunsaturated fatty acids (PUFAs): eicosapentaenoic, docosapentaenoic, docosahexaenoic, conjugated linoleic acid (CLA) and more total SFA, total PUFA, total Omega- 6 and total omega 3 fatty acids than herded goats. On the other hand, chevon from herded goats had more (P < 0.05) C18:1c9, C18:2t9, 12 (n-6), C20:3c11, 14, 17 (n-3) and total MUFA than tethered goats. However, there was no difference (P > 0.05) in the PUFA: SFA and n-6/n-3 fatty acid ratios between the herded and tethered goats. It was concluded that tethering promoted higher proportions of beneficial PUFAs which were more in TB than LTH muscle. The overall conclusions from the whole study were that goat manure is an important source of GHG with high CH4 being emitted from earth floors of herded goats. High CO2 and N2O are emitted from SF of herded and tethered goats, respectively. There were no major differences in meat quality between herded and tethered goats. However, herding promoted more live weight gain than tethering. On the other hand, tethering promoted more beneficial fatty acids. Therefore depending on the objective of the enterprise, smallholder farmers can safely tether or herd their goats. Further, there is need to develop technologies to harness CH4 from goat manure.

Thesis (MBA)--Stellenbosch University, 2012.
With the advent of shale gas exploration in the Karoo region, the purpose of this study was to investigate the possible socio-economic impacts of shale gas development on the town of Beaufort West in the Karoo. A qualitative study method was used to establish possible socio economic impacts by reviewing literature with regard to existing shale gas development as well as a case study from the United States of America (USA). A desktop study of Beaufort West was carried out to establish current socio economic trends in the town. Semi-structured interviews were conducted with key stakeholders to establish their concerns and opinion regarding the possibility of shale gas exploration and production in the area of Beaufort West in the Karoo. The results of the study concluded that the concerns of the key stakeholders were definitely relevant as their livelihood would be threatened if there was any possibility of contamination of their water sources. Other possible socio economic impacts included infrastructure concerns with regard to road maintenance, tourism declining and the threat of noise and air pollution. The study recommends that if the shale gas development process were to go ahead, the South African government would need to ensure that best practices are incorporated by all gas drilling companies. A team of qualified and trained regulators should monitor well pads and hydraulic fracturing methods as well as volumes of water used and the disposal of waste water. The regulations existing in the country should be revised to incorporate the stringent standards of other countries that have strict monitoring policies in place. In order to protect the people of the Karoo and the heritage of South Africa, the government must ensure that gas companies are held liable for any kind of environmental or socio economic impact.

Air pollution is a threat to the environment and human health. Freight trucking in particular is the main source of freight transportation emissions. Heavy-duty trucks emit large amounts of toxic air pollutants that cause serious diseases and harm public health. In addition, heavy-duty trucks emit great amounts of greenhouse gas (GHG), which is the leading cause of global warming. Despite increased environmental restrictions on air pollution and rising trucking greenhouse gas emissions in the past decades, no economic study has examined the potential GHG and air pollution reductions in the trucking sector and the associated private abatement costs to the industry. This study accounts for GHG emissions and toxic air pollutants in measuring and evaluating efficiency and productivity for the trucking industry in the 48 contiguous states. Moreover, the private costs of abatement to the industry were also estimated. When only GHG was incorporated in the production model, the results showed that each state could expand desirable output and reduce GHG by an average of 11 percent per year between 2000 and 2007. The Malmquist-Luenberger productivity indexes showed that omitting or ignoring GHG in trucking service production yielded biased estimates. On the other hand, due to increased environmental regulations, most of the toxic air pollutants decreased dramatically between 2002 and 2005. The analytical results showed that inefficiency decreased during this period. The private costs of abatement averaged $73 million per state in 2005. When GHG and six toxic air pollutants were incorporated in the production model, the estimated private abatement cost was $76 million per state, which was equivalent to 0.7 percent of the industry output in 2005.

The Barnett shale basin, the largest onshore gas field in the state of Texas, mainly produces natural gas. The basin’s oil and gas productions have dramatically increased over the past two decades with the enhancement via shale fracturing (fracking) technology. However, recent studies suggest that air emissions from shale fracking have significantly contributed to the growing air pollution problem in North Texas. In this study, air emissions from the Barnett shale basin during the production phase of the oil and gas activities (once the product is collected from the wells) are quantified. Oil and gas production data were acquired from the Texas Railroad Commission for the baseline years of 2010 through 2013. Methodology from prior studies on shale basins approved by the Texas Commission on Environmental Quality was employed in this study and the emission inventories from the production phase sources were quantified. Accordingly, the counties with the most gas operations in the basin, Tarrant, Johnson, Denton and Wise, were found to be the highest emitters of air pollutants. Tarrant County was responsible for the highest emitted NOx (42,566 tons) and CO (17,698 tons) in the basin, while Montague County released the maximum VOC emissions (87,601 tons) during the study period. Amongst the concerned emitted pollutants, VOC was the largest emitted pollutant during the study period (417,804 tons), followed by NOx (126,691 tons) and CO (47,884 tons). Significant Sources of air emissions include: storage tanks, wellhead compressor engines, and pneumatic devices. Storage tanks and pneumatic devices contributed to about 62% and 28% of the total VOC emissions, respectively. Whereas, wellhead compressor engines are primarily responsible for about 97% of the total NOx emissions. Finally, in Tarrant, Wise and Denton counties, the emissions increased during the study period due to increase in the oil and gas production, while Johnson County’s emission contribution declined throughout the study period.

Two long-lived halogen radionuclides (36Cl, T1/2 = 301 kyr, and 129I, T1/2 = 15.7 Myr) have been studied by means of Accelerator Mass Spectrometry (AMS) at the Uppsala Tandem Laboratory. The 36Cl measurements in natural samples using a medium-sized tandem accelerator (~1 MeV/amu) have been considered. A gas-filled magnetic spectrometer (GFM) was proposed for the separation of 36Cl from its isobar, 36S. Semi-empirical Monte-Carlo ion optical calculations were conducted to define optimal conditions for separating 36Cl and 36S. A 180° GFM was constructed and installed at the dedicated AMS beam line. 129I has been measured in waters from the Arctic and North Atlantic Oceans. Most of the 129I currently present in the Earth's surface environment can be traced back to liquid and gaseous releases from the nuclear reprocessing facilities at Sellafield (UK) and La Hague (France). The anthropogenic 129I inventory in the central Arctic Ocean was found to increase proportionally to the integrated 129I releases from these reprocessing facilities. The interaction and origin of water masses in the region have been clearly distinguished with the help of 129I labeling. Predictions based on a compartment model calculation showed that the Atlantic Ocean and deep Arctic Ocean are the major sinks for the reprocessed 129I. The variability in 129I concentration measured in seawater along a transect from the Baltic Sea to the North Atlantic suggests strong enrichment in the Skagerrak–Kattegat basin. The 129I inventory in the Baltic and Bothnian Seas is equal to ~0.3% of the total liquid releases from the reprocessing facilities. A lake sediment core sampled in northeastern Ireland was analyzed for 129I to study the history of the Sellafield releases, in particular the nuclear accident of 1957. High 129I concentration was observed corresponding to 1990 and later, while no indication of the accident was found. The results of this thesis research clearly demonstrate the uniqueness and future potential of 129I as a tracer of processes in both marine and continental archives.

The Quebec City - Windsor corridor is the busiest and most important trade and transportation corridor in Canada. The transportation sector is the second largest greenhouse gas (GHG) emission category in the country. Governments around the world, including Canada, are considering increased mode share by rail as a way to reduce transportation emissions. To understand whether freight mode shift is a realistic means to reduce transportation emissions, an analytical model is needed that can predict the effect of government policy on mode split.
This thesis provides background on the freight transportation-GHG nexus in Canada and describes the development, implementation, reasoning behind, and results of, a Stated Preference shipper carrier choice survey for the Quebec City - Windsor corridor conducted during the fall of 2005. It then describes how the resulting carrier choice models are used to estimate the potential to displace truck traffic to rail (premium-intermodal) under current conditions, as well as to test the effectiveness of different possible future policy or service offering scenarios.
The results show that premium-intermodal has the potential to capture a substantial share of traffic between the main destinations in the Quebec City - Windsor Corridor. However, its ability to contribute significantly to reducing CO2 emissions is limited. According to the analyses conducted, potential reductions are considered to be in the range of nil to 0.413 Mt---a fraction of what the federal government was hoping to be able to achieve through "further public-private collaboration to promote the use of intermodal freight opportunities and to increase the use of low-emission vehicles and modes" (Government of Canada 2002).
At the same time, these potential reductions are based on a small proportion of total truck-related emissions and a few city-pairs. Extension of the current analysis to more city-pairs separated by longer distances might arrive at different conclusions.

The oxidation of volatile organic compounds (VOCs) plays a role in both regional and global air quality through the formation of secondary organic aerosols (SOA). More than 1000TgC/yr of non-methane VOCs are emitted from biogenic sources (significantly greater than from anthropogenic sources). Despite this magnitude and potential importance for air quality, the body of knowledge around the identities, quantities and oxidation processes of these compounds is still incomplete (e.g., Goldstein & Galbally, 2007; Robinson et al., 2009). Two-dimensional gas chromatography paired with time-of-flight mass spectrometry (GC×GC/TOFMS) is a powerful analytical technique which is explored here for its role in better characterizing biogenic VOCs (BVOCs) and thus SOA precursors. This work presents measurements of BVOCs collected during two field campaigns and analyzed using GC×GC/TOFMS. The first campaign, the Bio-hydro-atmosphere Interactions of Energy, Aerosols, Carbon, H2O, Organics & Nitrogen - Rocky Mountain Biogenic Aerosol Study (BEACHON-RoMBAS), took place in a Ponderosa pine forest in Colorado. The second campaign, Particle Investigations at a Northern Ozarks Tower: NOx, Oxidant, Isoprene Research (PINOT NOIR) Study, was conducted in the Ozark region of Missouri. Tens to hundreds of BVOCs were quantified in each set of samples, including primary emissions, atmospheric oxidation products, stress indicators and semi-volatile leaf surface compounds. These findings highlight that there is a largely uncharacterized diversity of BVOCs in ambient samples. Our findings demonstrate that GC×GC can distinguish between compounds with the same molecular weight and similar structures, which have highly variable potentials for production of SOA (Lee et al., 2006). This work represents some of the first analysis of ambient BVOCs with this technology, which is anticipated to contribute greatly to characterization of atmospheric SOA precursors and ultimately, regional and global modeling of SOA and fine particulate matter.

This research paper is broken up into three sections, namely an evaluation report, a literature review and research methodology. The evaluation report section is the assessment of the current state of change readiness within the Eskom Contact Centre’s based upon what the literature on change readiness prescribes. The timing of the change readiness assessment is just prior to significant organisational change. The organisational change that was about to be initiated by the organisation was initiated from the boardroom of the most senior echelons of the organisation, and was directed in a top down approach, being a strategic organisational change. The change is deemed to be critical to the organisation being able to meet its long term strategic and sustainability objectives. A critical examination of the literature explored the meaning of change readiness, the importance of it and explained the consequences for organisations that commit to transformational agendas without being ready. Key concepts such as such resistance to change and organisational inertia are described and differentiated from change readiness. The ADKAR change model and its change readiness assessment instrument were used due to the organisations preference for the model. The ADKAR model formed the framework for the analyses of the data, the discussion of the results and the recommendations to the organisation. The research conducted was quantitative in nature; a questionnaire was distributed to the employees of the seven Eskom Contact centre sites around the country through an email. A slightly modified version of the ADKAR change readiness questionnaire was sent via email with an on-line questionnaire link on it; and questions on individual readiness for change were used to assess the level of readiness of the employees. Most of the descriptive and inferential statistics were analysed with the use of Excel (version, 2010), with Factor Analysis being done in Statistica. The results of the research showed that: [iii] - The factors as proposed by the ADKAR change readiness assessment questionnaire (i.e. Awareness, Desire, Knowledge, Ability and Reinforcement) are not different enough to be considered as independent factors for this data set. Based on factor analysis, the factors were subsequently amended from five to three, namely Readiness, Opportunity Realisation and Uncertainty. - The Contact Centre employees were somewhat ready for change. - The Contact Centres needed to focus on all amended ADKAR factors in order to improve the readiness of the department. - The readiness levels in response to the roll out were more or less uniform. The study shows that given Eskom’s preference for the ADKAR model, future research within Eskom should therefore be conducted more circumspectly with respect to ascertaining the validity of the ADKAR factors. The study also makes mention that future work and/or research will need to be conducted, specifically on the readiness of the organisation itself, in order to improve the probability of transformational success. The ADKAR assessment is a people focused assessment and therefore focuses only on the readiness of the individual. Factors such as the adequacy of the current state of resources within the organisation, which incorporate aspects such as infrastructure, technology and staffing, will also need to be assessed to make a more holistic statement of change readiness. A concise review of the literature is incorporated into the Evaluation Report of Section 1 to underpin the study. In Section 2 a more extensive review of the literature is presented. Similarly, the design of the research is discussed in more detail in Section 3 to both describe and justify the appropriateness of the research methodology, and to give a detailed account of the way in which the research was carried out.

Thesis (MA)--Stellenbosch University, 2013.
ENGLISH ABSTRACT: Since its arrival onto the U.S. energy scene in the early 2000s, shale gas has had a significant impact on the global energy market. The fact that the shale gas supply of a single country has had such a widespread influence on the global energy market hints at the power that this energy resource holds as a ‘game changer’. With the fifth largest estimated shale gas reserves in the world, South Africa now faces the challenge of developing its own shale gas resources in the Karoo Basin. Having lifted the moratorium on hydraulic fracturing in September 2012, the South African government has indicated its interest in pursuing the commercial extraction of the country’s estimated shale gas reserves. This comes in light of the country’s potential energy crisis, as well as an increased role for natural gas in the country’s energy mix. South Africa has no history of shale gas extraction and currently has no legislation or regulatory practices in place to deal specifically with shale gas and hydraulic fracturing. The South African government thus faces the challenge of drawing policy lessons from other experienced shale gas-producing nations, such as the U.S., to close these regulatory gaps and exploit its national shale gas resources in an environmentally and economically responsible way. Consequently, this thesis focuses on the regulation of the American shale gas industry by asking what policy lessons the South African government can draw from the United States of America on its regulation of shale gas extraction. Richard Rose’s lesson-drawing approach to policy learning was adopted as the theoretical framework for this study and can also be applied as an analytical tool to aid in data collection and data analysis. Furthermore, the framework was operationalised through the research methods used for this case study, which consisted of a review of literature on the U.S. regulation of shale gas extraction. This research produced a number of key findings in the form of policy lessons for South Africa. Four main policy lessons were drawn on the regulation of shale gas extraction: regulation of shale gas extraction must occur at all levels of government—national, provincial and local; policy research must be used to inform policymaking for the development of new legislation specific to shale gas and hydraulic fracturing, so as to avoid regulatory exemptions often linked to ad hoc policymaking on shale gas extraction; each level of government and their related regulatory agencies must have clearly defined regulatory roles relating to shale gas and hydraulic fracturing; and finally, there must be uniformity in terms of the regulatory focus of shale gas regulators at all levels of government.
AFRIKAANSE OPSOMMING: Sedert skaliegas vroeg in die jare sedert 2000 op die Amerikaanse energietoneel verskyn het, het dit ‘n beduidende impak op die globale energiemark gehad. Die feit dat die voorraad skaliegas van een land so ‘n wydverspreide invloed gehad het op die globale energiemark is ‘n aanduiding van die mag van hierdie energiebron as ‘n spel-wisselaar.Suid-Afrika het die vyfde-grootste skaliegasreserwes ter wêreld, en staan nou voor die uitdaging om sy eie skaliegasreserwes in die Karookom te ontwikkel. Nadat die moratorium op hidrobreking in September 2012 opgehef is, het die Suid-Afrikaanse regering aangedui dat hulle belangstel om die land se beraamde skaliegasreserwes kommersieel te ontgin. Dit het ontstaan in die lig van die potensiële energiekrisis wat Suid-Afrika in die gesig staar, asook die begeerte dat aardgas ‘n groter rol moet speel in die land se mengsel van energiebronne. Suid-Afrika het geen geskiedenis van skaliegasontginning nie en tans is daar geen wetgewing of regulerende praktyke in plek wat spesifiek te make het met skaliegas en hidrobreking nie. Die Suid-Afrikaanse regering staan dus voor die uitdaging om te leer uit die beleidsrigtings van ander ervare skaliegaslande soos die V.S.A. ten einde hierdie leemtes in regulering op te hef en sy nasionale skaliegasreserwes op ‘n omgewingsvriendelike en ekonomies-verantwoordelike manier te ontgin. Gevolglik fokus hierdie tesis op die regulering van die Amerikaanse skaliegas-industrie deur te vra watter beleidslesse die Suid-Afrikaanse regering kan leer by die Amerikaanse regering oor die regulering van hulle skaliegasontginning. Richard Rose se 'lesson-drawing'-benadering tot die leer van beleid is aanvaar as die teoretiese raamwerk vir hierdie studie en kan ook aangewend word as 'n analitiese instrument om te help met dataversameling en -analise. Die raamwerk is verder geoperasionaliseer deur die navorsingsmetodes wat gebruik is vir hierdie gevallestudie, wat bestaan het uit 'n oorsig van die literatuur oor die V.S.A. se regulering van skaliegasontginning. Hierdie navorsing het ‘n aantal sleutelbevindinge opgelewer in terme van beleidslesse vir Suid-Afrika. Die vier vernaamste beleidslesse oor die regulering van skaliegasontginning wat na vore gekom het, is die volgende: die regulering van skaliegas moet op alle vlakke van regering geskied – nasionaal, provinsiaal en op plaaslike vlak; navorsing oor beleid moet gebruik word om beleidsvorming in te lig sodat nuwe wetgewing ontwikkel kan word wat spesifiek gerig is op skaliegas en hidrobreking, ten einde uitsonderings op regulering te voorkom wat dikwels verbind word met ad hoc beleidsformulering; elke vlak van regering en sy verwante reguleringsagentskappe moet duidelik gedefinieerde reguleringsrolle hê ten opsigte van skaliegas en hidrobreking; en, ten slotte, daar moet eenvormigheid wees in die reguleringsfokus van skaliegasreguleerders op alle vlakke van regering.
National Research Foundation (DAAD-NRF)

The Altamont Pass Wind Resource Area (Altamont) near Livermore, California is the oldest and largest wind farm in the United States. It is known as a location of high avian mortality, especially for diurnal raptors such as the Golden Eagle (Aquila chrysaetos). Using the avian monitoring data collected at Altamont for over thirteen years (1998-2003, 2005- 2011), records were analyzed of 134 golden eagle deaths caused by wind turbine collisions. All wind turbines present during the same temporal range were characterized according to turbine variables, and geographic placement characteristics. Values of turbines that killed golden eagles were compared to values of turbnes that did not. It was discovered that turbines that have killed golden eagles (kill turbines) share characteristics that are significantly different from those that have not. Kill turbines are more often situated on lattice structure towers, have larger rotor blade-swept areas, placed in less dense turbine arrays, are further away from the next nearest turbine and are less often placed on top of ridgelines compared to nonkill turbines. Finally, kill turbines are more often situated at the end of a turbine row than are nonkill turbines. The differences between kill and nonkill turbine model, hill slope, tower height, generating capacity, array diversity, row count of turbines and placement in a hill saddle were found to be not significant. These findings support in part, earlier turbine studies at Altamont, but do not concur with all previous findings. The methods used in this study can be applied to any bird species at Altamont and at any wind resource area throughout the world. As the wind industry continues to grow, techniques used in studies such as this are an important tool that can be used to direct wildlife conservation policies.

Thesis (Ph. D.)--School of Public Policy, Georgia Institute of Technology, 2005. Directed by Bryan Norton.
Norton, Bryan, Committee Chair ; Rodgers, Michael, Committee Member ; Bozeman, Barry, Committee Member ; DeHart-Davis, Leisha, Committee Member ; Noonan, Douglas, Committee Member. Includes bibliographical references.

The differential role that airborne particulate matter (PM) size fractions, sources, and components play in producing adverse health effects is not fully understood. Specific gaps include the role of PM generated by traffic and the effects of PMs generated by natural sources. Source specific air pollution epidemiological research still lacks integration in the risk assessment process, a fundamental tool to inform policy makers and the public about the current situation or the impact of future or past air pollution policies. This thesis addresses both these gaps. To explore the effects of PM from different sources, we investigated the association between different PM size fractions and mortality in Barcelona, Spain and used PM chemical composition data to help determine the different sources and components linked to toxicity. To illustrate that local air pollution risk assessments are useful tools in evidence-based public health, we estimated the health and economic benefits that would result from different scenario of improved air quality in the Barcelona metropolitan area and in two communities of Southern California. These case studies include new methods to integrate into the risk assessment process the recent epidemiological evidence related to the effects of traffic exposure.This thesis contributes to a better understanding of the link between particulate matter size fraction, sources, and components and health effects, and to improve air pollution health impact assessment methods. Both contributions have important implications for public health and air pollution public policy.
El papel diferencial en que las diferentes fracciones de partículas en suspensión en el aire (PMs), sus fuentes y componentes producen efectos adversos para la salud no está completamente entendido. Las lagunas actuales incluyen el papel de las PMs generadas por el tráfico y los efectos de las PMs generadas por fuentes naturales. La investigación epidemiológica relacionada con fuentes todavía falta ser integrada en el proceso de evaluación de impacto, una herramienta fundamental para informar a los tomadores de decisiones y el público sobre la situación actual o el impacto de futuras o pasadas políticas de contaminación atmosférica. Esta tesis trata estas áreas. Para explorar el papel de las PMs generadas por diferentes fuentes, se ha investigado la asociación entre diferentes fracciones de PMs y mortalidad en Barcelona (España) y se ha usado datos de composición química de PMs para identificar las fuentes y los componentes relacionados con la toxicidad. Para ilustrar que las evaluaciones de impacto a nivel local son herramientas útiles en salud pública, se ha estimado el beneficio en salud y económico que resultaría de diferentes escenarios de mejora de la calidad del aire en el área metropolitana de Barcelona y en dos comunidades de California del Sur. Estos estudios de casos incluyen nuevos métodos para integrar en las evaluaciones de impacto las nuevas evidencias epidemiológicas que relacionan la exposición al tráfico con los efectos en salud. Esta tesis contribuye a un mayor entendimiento del vínculo entre las fracciones de PM, sus fuentes y componentes y los efectos en salud así como a la mejora de los métodos de las evaluaciones de impacto. Estas contribuciones tienen importantes implicaciones para la salud pública y las políticas públicas de contaminación atmosférica.

Thesis (MBA)--Stellenbosch University, 2012.
The objective of this research study was to investigate whether socially responsible companies that disclose their carbon emission, referred to in this research report as ‘carbon disclosure leaders’, outperform their non-disclosing counterparts, referred to in this research report as ‘carbon disclosure laggards’. This research study attempted to substantiate the relationship between companies’ carbon disclosure practices and companies’ share price performance. An empirical analysis was conducted with a focus on South African-listed Johannesburg Stock Exchange (JSE) top-100 companies. A portfolio approach was utilised to establish if any significant relationship exists between company carbon disclosure and company share price performance. Portfolios were constructed based on companies that participated in the Carbon Disclosure Project (CDP) and were thus categorised into JSE industry sectors. It was assumed that by using industry-specific sectors, the macro-economic conditions would generally affect all companies in that specific sector in a similar way, thus enabling comparative analysis. The results from this study subsequently found, having done various analyses in terms of share price growth and carbon disclosure, that no significant correlation exists in terms of the CDP. This would, however, be correct in terms of the analysed data, which is limited at times, but cannot be necessarily inferred as a broader statement. Intuitively, it can be said that carbon disclosure and greater ratings in terms of the CDP would imply that companies are more positive in dealing with their carbon footprint, which would be more positive for their long-term existence and sustainability. Equally, it could also yield various cost savings that will translate into higher earnings and earnings per share that drive share price growth. In becoming more active in reducing the carbon footprint, companies would also reduce their risk profile since they would be better aligned to potential restrictive carbon emission legislation and improve their public profile, which could again boost profitability. Further arguments can be made to suggest that disclosure of a company’s carbon initiatives and footprint would benefit the company’s value and share price performance. Thus, having observed the outcomes of the analyses conducted in this report, the more appropriate question would be if other factors exist that could have affected the outcomes as observed and whether these factors could have overshadowed the proof that there is a positive correlation between share price growth and carbon disclosure.

In order to better understand runoff characteristics from natural gas well sites in north central Texas, the City of Denton, with assistance through an EPA funded 104b3 Water Quality Cooperative Agreement, monitored storm water runoff from local natural gas well sites. Storm water runoff was found to contain high concentrations of total suspended solids (TSS). Observed TSS concentrations resulted in sediment loading rates that are similar to those observed from typical construction activities. Petroleum hydrocarbons, in contrast, were rarely detected in runoff samples. Heavy metals were detected in concentrations similar to those observed in typical urban runoff. However, the concentrations observed at the gas well sites were higher than those measured at nearby reference sites. Storm water runoff data collected from these sites were used to evaluate the effectiveness of the water erosion prediction project (WEPP) model for predicting runoff and sediment from these sites. Runoff and sediment predictions were adequate; however, rainfall simulation experiments were used to further characterize the portion of the site where drilling and extraction operations are performed, referred to as the "pad site." These experiments were used to develop specific pad site erosion parameters for the WEPP model. Finally, version 2 of the revised universal soil loss equation (RUSLE 2.0) was used to evaluate the efficiency of best management practices (BMPs) for natural gas well sites. BMP efficiency ratings, which ranged from 52 to 93%, were also evaluated in the context of site management goals and implementation cost, demonstrating a practical approach for managing soil loss and understanding the importance of selecting appropriate site-specific BMPs.