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Dissertations / Theses on the topic 'Epoxy resins'

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1

Lister, Adam Robert. "Synthesis of hyperbranched epoxy resins." Thesis, University of Cambridge, 2003. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.619943.

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2

Ertl, Johanna <1987&gt. "Fully bio-based epoxy resins." Doctoral thesis, Alma Mater Studiorum - Università di Bologna, 2015. http://amsdottorato.unibo.it/6827/1/Ertl_Johanna_tesi.pdf.

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Epoxy resins are mainly produced by reacting bisphenol A with epichlorohydrin. Growing concerns about the negative health effects of bisphenol A are urging researchers to find alternatives. In this work diphenolic acid is suggested, as it derives from levulinic acid, obtained from renewable resources. Nevertheless, it is also synthesized from phenol, from fossil resources, which, in the current paper has been substituted by plant-based phenols. Two interesting derivatives were identified: diphenolic acid from catechol and from resorcinol. Epichlorohydrin on the other hand, is highly carcinog
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3

Ertl, Johanna <1987&gt. "Fully bio-based epoxy resins." Doctoral thesis, Alma Mater Studiorum - Università di Bologna, 2015. http://amsdottorato.unibo.it/6827/.

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Epoxy resins are mainly produced by reacting bisphenol A with epichlorohydrin. Growing concerns about the negative health effects of bisphenol A are urging researchers to find alternatives. In this work diphenolic acid is suggested, as it derives from levulinic acid, obtained from renewable resources. Nevertheless, it is also synthesized from phenol, from fossil resources, which, in the current paper has been substituted by plant-based phenols. Two interesting derivatives were identified: diphenolic acid from catechol and from resorcinol. Epichlorohydrin on the other hand, is highly carcinog
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4

Zhang, Wenting. "Self healing epoxy resins and composites." Thesis, University of Sheffield, 2008. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.499990.

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5

Ingram, Sharon. "The study of nanoclay epoxy resins." Thesis, University of Strathclyde, 2007. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.438121.

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6

Gilbert, A. H. "Toughening tetrafunctional epoxy resins with thermoplastics." Thesis, Cranfield University, 1988. http://dspace.lib.cranfield.ac.uk/handle/1826/10722.

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The study described in this thesis examines how modification with different thermoplastics affects the structure and properties of a tetrafunctional epoxy re5ín_ Polyetherimide (PEI) is found to give the best improvement in fracture properties without loss in Youngs Modulus and the PEI/epoxy system is used as the basis for further study. The influences of PEI concentration, initial cure temperature, test temperature and the presence of a second thermoplastic additive, are investigated. The information provided gives insight into the likely mechanisms of toughening in tetrafunctional epoxy/ther
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7

Short, Christina Kaye. "Characterization of Epoxy Resins for use in the Resin Transfer Molding Process." W&M ScholarWorks, 1993. https://scholarworks.wm.edu/etd/1539625806.

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8

Griffiths, R. P. "Physical ageing effects in crosslinked epoxy resins." Thesis, Brunel University, 1988. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.383803.

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9

Ottemer, Xavier. "Effects of processing and environmental conditions on the properties of epoxy materials." Thesis, Georgia Institute of Technology, 2001. http://hdl.handle.net/1853/18383.

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10

Li, Yao. "Atomistic modeling of environmental aging of epoxy resins." Diss., Georgia Institute of Technology, 2012. http://hdl.handle.net/1853/43633.

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In this work, epoxy resins were modeled using all atom representations in nanoscale simulation boxes. Tetrafunctional epoxy and corresponding multifunctional amine were chosen as model materials. Algorithms of constructing interconnected network structures were invented developed to properly account for the chemical structures and computational cost. Monomers were generated in diamond lattice and crosslinked to model complex epoxy multifunctional network. The initial configurations were relaxed and equilibrated using molecular dynamics and suitable force field. Physical, thermal and mechanical
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11

Cole-Clarke, Peter. "Spectroscopic studies of the cure of aerospace epoxy resins." Thesis, Queensland University of Technology, 1990. https://eprints.qut.edu.au/35979/1/35979_Cole-Clarke_1990.pdf.

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Epoxy resins diaminodiphenylmethane A.B..S..'.IE.A.C.T based on (TGDDM) tetraglycidyl reacted with 4,4' 4 , 4 ' diaminodiphenylsulphone (DDS) form the matrix for many advanced composite materials. The achievement of optimum properties and performance from a fibrereinforced epoxy resin composite depends on the control of the cure cycle of the material. This thesis critically assesses the physical techniques such as D. C conductivity and A. C phase lag which have been employed to monitor the increase in the resin viscosity during cure, as well as alternative techniques such as
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12

Zhang, Man. "Molecular toughening of epoxy resins through siloxane modification." Related electronic resource: Current Research at SU : database of SU dissertations, recent titles available full text, 2005. http://wwwlib.umi.com/cr/syr/main.

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13

Dias, Dissanayake Anusha Shamini. "Performance enhancing oligomeric amide additives for epoxy resins." Thesis, Wichita State University, 2010. http://hdl.handle.net/10057/5438.

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Additives that enhance the mechanical properties of epoxy resins, by reducing the free volume and thereby restricting the molecular motions, are known as antiplasticizers. Antiplasticizers usually increase the modulus and strength but can decrease the glass transition temperature of the material. A series of oligomeric amide additives were synthesised, that would, when mixed with TGDDM and DDS, react to form strong hydrogen bonds and reduce the free volume in the system. The effect of end group functionality was tested by synthesising both amine terminated and acid terminated additives.
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14

Lee, Yvonne Siew Keng. "The isocyanate cured epoxy resins - isocyanurate-oxazolidone polymers." Thesis, Brunel University, 1989. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.328875.

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15

Munshi, Imran. "Reaction-induced phase separation in modified epoxy resins." Thesis, University of Manchester, 2003. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.493906.

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Studies have been carried out on reaction-induced phase separation in epoxy networks, formed from a DGEBA-type epoxy resin prepolymer, DER332, and m-xylylene diamine, MXDA, containing as modifiers either (i) butyl laurate (B) or (ii) m-cardura (C), (synthesised from Cardura El0 and 2-ethyUiexanoic acid). The reactants and modifiers were characterised using end-group analysis, Fourier transform infra-red spectroscopy (FTIR), differential scanning calorimetry (DSC), nuclear magnetic resonance and viscometry.
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16

Nightingale, Clare. "Microwave assisted curing of epoxy resins and composites." Thesis, University of Manchester, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.577136.

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17

Pierre, Dorian. "Toughening of epoxy resins with multi-phase particles." Thesis, University of Manchester, 1995. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.509817.

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18

Powell, Graham. "In-situ cure monitoring of epoxy resins systems." Thesis, Brunel University, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.242971.

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19

Karad, Sunil. "Moisture sensitivity of cyanate ester modified epoxy resins." Thesis, University of Sheffield, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.286617.

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20

Jepson, Peter. "Development of novel curing agents for epoxy resins." Thesis, University of Surrey, 2001. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.395555.

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21

Phipps, Mark Anthony. "The strength of alumina trihydrate filled epoxy resins." Thesis, Kingston University, 1995. http://eprints.kingston.ac.uk/20588/.

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The tensile and fracture properties of alumina trihydrate (ATH) filled epoxy resins have been determined up to a maximum volume fraction of 0.33 with a cold setting curing agent (Epikure T) and up to V[sub]f=0.54 with a hot curing agent (piperidine). The effect of a reactive rubber on these properties, on its own and in ATH-filled composites have also been considered. All filled compositions showed a lower tensile strength than the unfilled resin. The largest effect occurred at low volume fractions, up to V[sub]f = 0.1, loadings higher than this did not reduce the strength any further. The add
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22

Thota, Phanindra. "Electrical Properties of Copper Doped Curcuminated Epoxy Resins." Ohio University / OhioLINK, 2012. http://rave.ohiolink.edu/etdc/view?acc_num=ohiou1337031967.

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23

Rocks, Jens. "Characterization of Novel Co-Anhydride cured Epoxy Resins." Thesis, Queensland University of Technology, 2004. https://eprints.qut.edu.au/15977/1/Jens_Rocks_Thesis.pdf.

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Epoxy resins are widely used as coatings, encapsulations, structural composites, castings, and adhesives in a number of electrical applications. Recently, novel uncatalyzed co-anhydride cured epoxy formulations that exhibit a high performance property profile, have been introduced. The objective of this thesis was to perform a comprehensive material characterization of these new resin/hardener combinations, which are potentially used as electrical insulation material in medium and high voltage engineering. The thermal cure behaviour of commercial tetraglycidyl-diamino-diphenylmethane (TGDD
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24

Rocks, Jens. "Characterization of Novel Co-Anhydride cured Epoxy Resins." Queensland University of Technology, 2004. http://eprints.qut.edu.au/15977/.

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Epoxy resins are widely used as coatings, encapsulations, structural composites, castings, and adhesives in a number of electrical applications. Recently, novel uncatalyzed co-anhydride cured epoxy formulations that exhibit a high performance property profile, have been introduced. The objective of this thesis was to perform a comprehensive material characterization of these new resin/hardener combinations, which are potentially used as electrical insulation material in medium and high voltage engineering. The thermal cure behaviour of commercial tetraglycidyl-diamino-diphenylmethane (TGDD
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25

NAGUIB, IBRAHIM MOHAMED MOHAMED. "Different toughening strategies for UV-cured epoxy resins." Doctoral thesis, Politecnico di Torino, 2014. http://hdl.handle.net/11583/2528293.

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Owing to their outstanding properties, epoxy resins are widely used in different industries and recently used in novel applications such as semiconductors and lithographic inks. Due to their low fracture toughness, Toughening of epoxy is widely discussed in literature during last decades. Many toughening agents including organic and inorganic materials are used to accomplish this purpose. The objectives of this research are to synthesize and use different toughening agents and study the influence of these modifiers on the mechanical and thermal properties in general and the fracture toughness
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26

Chonkaew, Wunpen. "Modifications of epoxy resins for improved mechanical and tribological performances and their effects on curing kinetics." Thesis, University of North Texas, 2008. https://digital.library.unt.edu/ark:/67531/metadc6123/.

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A commercial epoxy, diglycidyl ether of bisphenol-A, was modified by two different routes. One was the addition of silica to produce epoxy composites. Three different silane coupling agents, glycidyloxypropyl trimethoxy silane (GPS), -methacryloxypropyl trimethoxy silane (MAMS) and 3-mercaptopropyltriethoxy silane (MPS), were used as silica-surface modifiers. The effects of silica content, together with the effects of chemical surface treatment of silica, were studied. The results indicate that epoxy composites with silica exhibit mechanical and tribological properties as well as curing ki
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27

Bilyeu, Bryan. "Characterization of Cure Kinetics and Physical Properties of a High Performance, Glass Fiber-Reinforced Epoxy Prepreg and a Novel Fluorine-Modified, Amine-Cured Commercial Epoxy." Thesis, University of North Texas, 2003. https://digital.library.unt.edu/ark:/67531/metadc4437/.

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Kinetic equation parameters for the curing reaction of a commercial glass fiber reinforced high performance epoxy prepreg composed of the tetrafunctional epoxy tetraglycidyl 4,4-diaminodiphenyl methane (TGDDM), the tetrafunctional amine curing agent 4,4'-diaminodiphenylsulfone (DDS) and an ionic initiator/accelerator, are determined by various thermal analysis techniques and the results compared. The reaction is monitored by heat generated determined by differential scanning calorimetry (DSC) and by high speed DSC when the reaction rate is high. The changes in physical properties indicating in
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28

Kaya, Elçin Dilek Tanoğlu Metin. "Development of layered silicate/epoxy nanocomposite/." [s.l.]: [s.n.], 2006. http://library.iyte.edu.tr/tezler/master/malzemebilimivemuh/T000538.pdf.

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Thesis (Master)--İzmir Institute Of Technology, İzmir, 2006.<br>Keywords: epoxy resin, nanocomposites, clay, scanning electron microscope, mechanical properties. Includes bibliographical references (leaves. 93-98).
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29

Photjanataree, Penchom. "The interaction of functional plasma polymers with epoxy resins." Thesis, University of Sheffield, 2010. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.557123.

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Previously functional plasma polymers have been demonstrated to act as protective films for reinforcing fibres and provide adhesion to matrix resins in the formation of composite. In this work, the model interphase surface from the allylamine (AAm)1 1,7-octadiene (Oct) plasma copolymer treated with DGEBA-Br epoxy was produced in order to simulate the formation of an interphase region under differing cure regimes. The fundamental interaction of epoxy with a plasma polymer coating deposited onto an electrical grade (E-glass) substrate was investigated to understand the nature of interpenetrating
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30

Liu, Shuyuan. "The development of novel curing agents for epoxy resins." Thesis, University of Surrey, 1996. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.336529.

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31

Pollock, Elizabeth A. "Study of epoxy resins and their interaction with water." Thesis, University of Strathclyde, 1989. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.338753.

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32

Bott, Caroline Frances. "Water transport in epoxy resins and carbon-fibre composites." Thesis, Imperial College London, 1991. http://hdl.handle.net/10044/1/46679.

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33

Garden, Lisa H. "The cure of, and moisture ingress into, epoxy resins." Thesis, University of Strathclyde, 2013. http://oleg.lib.strath.ac.uk:80/R/?func=dbin-jump-full&object_id=20868.

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The first aim of this project was to characterise the cure of several epoxy resin systems using dielectric spectroscopy, DSC, FT-IR spectroscopy and rheology measurements. It was hoped to build up an understanding of the cure process and correlate the results produced by the different methods to establish whether dielectric spectroscopy can be used to monitor the cure of epoxy resins in the field without specialist training in interpretation of the results. The second aim was to quantify moisture ingress through gravimetric measurements and dielectric spectroscopy. Although in certain systems
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34

Ding, C. "New insights into biobased epoxy resins : synthesis and characterization." Thesis, University of York, 2015. http://etheses.whiterose.ac.uk/11195/.

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The synthesis and characterization of a variety of novel biobased epoxy thermosets comprising plant oil-derived epoxy prepolymers and dicarboxylic acids (DCAs) and/or glutaric anhydride, in the presence of amine curing agents, in order to develop new insights on structure-property relationships, are reported. The effect of: i. different epoxy prepolymers: epoxidized linseed oil (ELO); epoxidized soybean oil (ESBO), and; their corresponding epoxidized methyl esters EML and EMS; ii. systematically increasing carbon-carbon chain length of a series of α,ω-dicarboxylic acids (DCAs); iii. different
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35

Hofmann, Klaus. "Synthesis, properties, and morphology of lignin based epoxy resins." Diss., Virginia Tech, 1991. http://hdl.handle.net/10919/37407.

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Star-like lignin-poly(propylene oxide) copolymers were prepared by chain-extending steam exploded lignins (tulipifera liriodendron) with propylene oxide and by subsequent endcapping with ethylene oxide. Epoxidation of these copolymers was carried out with epichlorohydrin at room temperature, using KOH as oxyanion forming reagent. The epoxidized compounds were fractionated by solvent precipitation to remove poly(alkylene oxide) homopolymers and to prepare fractions of narrow molecular weight distributions. The epoxides were cross-linked with meta phenylene diamine yielding thermosets which w
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36

Aziz, Roslan Abd. "The influence of thermohumid conditions on compression-after-impact properties of fibre-reinforced laminate materials." Thesis, Loughborough University, 2000. https://dspace.lboro.ac.uk/2134/34052.

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Advance composite materials based mainly on epoxy resins are being used in increasing amounts in aerospace components due to their high strength:weight ratio. Such components have to survive in a range of temperature and humid environments in different parts of the world. The current generation of epoxy resins used in high performance fibre reinforced laminates absorb moisture from the atmosphere. Moisture absorption by the epoxy resins leads to a reduction in glass transition temperature and to a softening of the resin with a loss of resin stiffness and strength. In certain applications the c
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37

Chonkaew, Wunpen Brostow Witold. "Modifications of epoxy resins for improved mechanical and tribological performances and their effects on curing kinetics." [Denton, Tex.] : University of North Texas, 2008. http://digital.library.unt.edu/permalink/meta-dc-6123.

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38

Thitipoomdeja, Somkiat. "Factors influencing the properties of epoxy resins for composite applications." Thesis, Loughborough University, 1995. https://dspace.lboro.ac.uk/2134/10852.

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The aim of the work reported here was to determine the influence of an amine curing agent, and postcure cycle on the mechanical and thermal properties of diglycidyl ether of bisphenol A (DGEBA) epoxy resin. The results of this initial study were then used as the basis for selecting material to obtain optimum toughness in epoxy/glass fibre systems. These basic materials were further used to make comparisons with the properties of modified resin systems which contained commercial elastomers. Differential Scanning Calorimetry (DSC), Dynamic Mechanical Thermal Analysis (DMTA), Fourier Transform In
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39

Becker, Lars-Ole 1973. "High performance epoxy-layered silicate nanocomposites." Monash University, School of Physics and Materials Engineering, 2003. http://arrow.monash.edu.au/hdl/1959.1/5747.

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40

Jackson, Justin Reed. "Mechanical Testing and Evaluation of Epoxy Resins at Cryogenic Temperatures." MSSTATE, 2005. http://sun.library.msstate.edu/ETD-db/theses/available/etd-11112005-091310/.

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The objective of this research is to develop a test methodology to be used in determining which material properties affect the ultimate performance of a composite overwrapped pressure vessel (COPV) at liquid nitrogen (LN2) temperatures. The test methodology being evaluated is based on that used for ambient performance of COPVs and includes: resin properties, resin/fiber interface and COPV burst data. The suitability of these tests at LN2 temperatures will be evaluated. The resin properties are investigated by use of tensile tests to determine: strain to failure (%å), failure stress (óys), and
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41

King, David Gareth. "Fibre-optic sensor development for process monitoring of epoxy resins." Thesis, University of Birmingham, 2018. http://etheses.bham.ac.uk//id/eprint/8698/.

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An investigation was undertaken to examine the performance of a Fresnel reflection sensor (FRS) incorporated into a differential scanning calorimeter (DSC) to track the cross-linking of epoxy resins. The initial design used a micrometer translation stage to lower the FRS through an orifice in the DSC platinum lid and onto the pan containing the sample. During exothermic cross-linking experiments, the resin refractive index and the heat evolved were measured simultaneously, allowing for direct comparison between the data. Combining the two measurement techniques produced a powerful hyphenated a
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42

Manzano, Garcia Miguel. "Synthesis of novel ormosil particles for modification of epoxy resins." Thesis, University of Surrey, 2004. http://epubs.surrey.ac.uk/844629/.

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The non-hydrolytic sol-gel process has been used for the synthesis of ORganically- MOdified SILicas (ORMOSILs). The effect on morphology of the ormosil particles has been investigated using different solvents, types of stirring, and additives such as surfactants or polystyrene. Dimethyl sulfoxide has been used as a novel oxygen donor for the catalyst-free formation of colourless silsesquioxanes. The products are organic- inorganic hybrid (nano)composite materials where the organic modifications (methyl, ethyl, hexyl or phenyl groups) are covalently attached to silicon. Spherical particles of c
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43

Brown, Julie. "Development of novel metal complexed curing agents for epoxy resins." Thesis, University of Surrey, 1998. http://epubs.surrey.ac.uk/843796/.

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A number of novel chloride and acetato complexes, of the type M(PGE-EMI)4X2 where M = Mn, Co, Ni, Cu and Zn and X = Cl and CH3COO-, was successfully prepared and characterised using FTIR, NMR and UV/Vis spectroscopic analysis. The majority of the complexes precipitated as brittle glasses, hence no crystallographic analysis could be carried out to evaluate the exact structure. However, the use of magnetic susceptibility measurements gave an indication of the stereochemistry of the complexes, the majority being octahedral as expected. A thermal dissociation study was undertaken to ascertain whet
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44

Balasubramani, Praveen Kumar. "Properties and Curing Kinetics of Epoxy Resins Cured by Chitosan." University of Cincinnati / OhioLINK, 2016. http://rave.ohiolink.edu/etdc/view?acc_num=ucin1480328803855009.

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45

Wu, Jiawei. "Study on Epoxidized Poly (Styrene-butadiene-styrene) Modified Epoxy Resins." University of Akron / OhioLINK, 2019. http://rave.ohiolink.edu/etdc/view?acc_num=akron1571671436341218.

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46

Battig, Alexander Philipp [Verfasser]. "Hyperbranched Polymers: Multifunctional Flame Retardants for Epoxy Resins / Alexander Battig." Berlin : Freie Universität Berlin, 2020. http://d-nb.info/1218077646/34.

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47

Gérard, Caroline. "Contribution of nanoparticles to the flame retardancy of epoxy resins." Thesis, Lille 1, 2011. http://www.theses.fr/2011LIL10034/document.

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Ce mémoire porte sur l’étude de l’ignifugation d’une résine époxyde grâce à l’utilisation de nanoparticules. L’incorporation de Polyhedral Oligomeric Silsesquioxanes (POSS) ou de nanotubes de carbone seuls dans la matrice apporte une amélioration très limitée des propriétés feu. La fonctionnalisation covalente de nanotubes de carbone par des fonctions retardatrices de flamme a été réalisée et caractérisée, mais elle n’augmente pas les performances feu de la matrice chargée en nanotubes de carbone. La combinaison entre un retardateur de flamme phosphoré (APP) et les nanotubes de carbone révèle
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48

Battig, Alexander [Verfasser]. "Hyperbranched Polymers: Multifunctional Flame Retardants for Epoxy Resins / Alexander Battig." Berlin : Freie Universität Berlin, 2020. http://d-nb.info/1218077646/34.

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49

Relosi, Natanael. "Obtenção e caracterização de tintas em pó base epóxi/poliéster com incorporação de argilominerais : montmorilonita (MMT) e mica muscovita." reponame:Repositório Institucional da UCS, 2016. https://repositorio.ucs.br/handle/11338/1176.

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Um dos sistemas de proteção de substratos metálicos mais comumente empregado na indústria é o de tintas. Os fatores favoráveis à utilização das tintas em pó incluem a não utilização de solventes, facilidades de processamento/aplicação e possibilidade de reaproveitamento do material que não aderiu na superfície da peça. As características térmicas, mecânicas e químicas da tinta são influenciadas principalmente pelo tipo de resina utilizada. As tintas em pó híbridas (epóxi/poliéster) visam conciliar a característica de resistência ao intemperismo e ação dos raios UV com as características de res
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50

Ratnam, Mamatha D. "Correlation between the dielectric, rheological and structural properties of DGEBA-DDS epoxy." Thesis, Georgia Institute of Technology, 1995. http://hdl.handle.net/1853/10203.

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