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1

Hinderberger, Dariush. "Polyelectrolytes and their counterions studied by EPR spectroscopy." [S.l. : s.n.], 2004. http://deposit.ddb.de/cgi-bin/dokserv?idn=971567441.

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2

Clarkson, Andrew C. "EPR Spectroscopy of Five-Coordinate Co(II) Complexes." Miami University / OhioLINK, 2018. http://rave.ohiolink.edu/etdc/view?acc_num=miami15348548777196.

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3

Docherty, Rebecca Jennifer. "EPR spectroscopy of antiferromagnetically-coupled Cr3+ molecular wheels." Thesis, University of Manchester, 2011. https://www.research.manchester.ac.uk/portal/en/theses/epr-spectroscopy-of-antiferromagneticallycoupled-cr3-molecular-wheels(d8e2f345-f60f-425a-a630-5b0334601ce5).html.

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Currently, there is interest in the development of molecular-scale devices for use in quantum information processing (QIP). With this application in mind, physical studies on antiferromagnetically coupled molecular wheels [Cr7MF3(Etglu)(O2CtBu)15(phpy)], where M is a divalent metal cation (M = Mn2+, Zn2+, Ni2+) have been pursued. The heterometallic wheels contain an octagon of metal centres, which are bridged by fluoride ions, pivalate groups and a chiral N-ethyl-D-glutamine molecule which is penta-deprotonated and bound to the metal sites through all available O-donors. They are deep purple i
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4

Zalma, Carre Alison. "Monitoring folding pathways for large RNAs using site-directed spin-labeling techniques." Thesis, Texas A&M University, 2005. http://hdl.handle.net/1969.1/4904.

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The function of biomolecules is very sensitive to structure. Folding in proteins and nucleic acids is a hierarchical process progressing from primary to secondary, then tertiary, and finally, quaternary structures. RNA in its folded form performs a variety of biological activities. Obtaining intramolecular distance measurements makes it possible to generate structural models along the folding pathway that may be related to the overall function of the molecule. Distances can be measured by Site-Directed Spin-Labeling (SDSL), in which nitroxyl spin-label probes are attached and observed by EPR s
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5

Håkansson, Pär. "Simulation of Relaxation Processes in Fluorescence, EPR and NMR Spectroscopy." Doctoral thesis, Umeå universitet, Kemi, 2004. http://urn.kb.se/resolve?urn=urn:nbn:se:umu:diva-244.

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Relaxation models are developed using numerical solutions of the Stochastic Liouville Equation of motion. Simplified descriptions such as the stochastic master equation is described in the context of fluorescence depolarisation experiments. Redfield theory is used in order to describe NMR relaxation in bicontinuous phases. The stochastic fluctuations in the relaxation models are accounted for using Brownian Dynamics simulation technique. A novel approach to quantitatively analyse fluorescence depolarisation experiments and to determine intramolecular distances is presented. A new Brownian Dyna
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6

Håkansson, Pär. "Simulation of relaxation processes in fluorescence, EPR and NMR spectroscopy /." Umeå : Univ, 2004. http://urn.kb.se/resolve?urn=urn:nbn:se:umu:diva-244.

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7

Rein, Stephan [Verfasser], Stefan [Akademischer Betreuer] Weber, and Christiane R. [Akademischer Betreuer] Timmel. "Development of advanced analysis and simulation programs for EPR spectroscopy." Freiburg : Universität, 2019. http://d-nb.info/1209470454/34.

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8

Mileo, Elisabetta <1981&gt. "Progress in the Characterization of Supramolecular Systems by EPR Spectroscopy." Doctoral thesis, Alma Mater Studiorum - Università di Bologna, 2010. http://amsdottorato.unibo.it/2537/1/Mileo_Elisabetta_tesi.pdf.

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9

Mileo, Elisabetta <1981&gt. "Progress in the Characterization of Supramolecular Systems by EPR Spectroscopy." Doctoral thesis, Alma Mater Studiorum - Università di Bologna, 2010. http://amsdottorato.unibo.it/2537/.

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10

Marešová, Renata. "EPR studium radikálových meziproduktů H-transferu z kyslíkatých, uhlíkatých a dusíkatých donorů." Doctoral thesis, Vysoké učení technické v Brně. Fakulta chemická, 2009. http://www.nusl.cz/ntk/nusl-233296.

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Within the PhD. thesis the problems of H-transfer from selected types of phenols, aromatic secondary amines and compounds with acidic CH bond were investigated. This process was initiated by the action of redox agents, mostly PbO2, in nonpolar solvents. The abstraction of hydrogen atom results in the formation of radical intermediates, which were detected by EPR spectroscopy. Because in most cases, highly unstable radicals were produced, it was neccessary to apply the technique of indirect detection, so called spin trapping. This method enables to interpret the character of generated radicals
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11

Twitchen, Daniel. "A study of defects and impurities in diamond." Thesis, University of Oxford, 1997. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.389024.

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12

Delf, Alexander Robert L. "Electrochemical and spectroelectrochemical characterisation of cyano and trifluoromethyl substituted polypyridines and their transition metal complexes." Thesis, University of Edinburgh, 2011. http://hdl.handle.net/1842/5026.

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This thesis is concerned with the electrochemical and spectroelectrochemical characterisation of cyano (CN) and trifluoromethyl (CF3) substituted polypyridine ligands and their metal complexes. The ligands investigated were X-CN-py (X = 3, 4 and 5, py = pyridine), X,X´-(CN)2-bpy) (X,X´ = 3,3´, 4,4´ and 5,5´ bpy = 2,2´- bipyridine) and X,X´-(CF3)2-bpy (X,X´ = 3,3´, 4,4´ and 5,5´). The Pt(II) complexes of the X-CN-py and X,X´-(CN)2-bpy ligands were studied along with the Fe(II) complexes of the X,X´-(CN)2-bpy and X,X´-(CF3)2-bpy ligands. Electrochemical studies of the X-CN-py ligands indicated t
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13

Gustafsson, Håkan. "Development of sensitive EPR dosimetry methods /." Linköping : Linköping University, 2008. http://urn.kb.se/resolve?urn=urn:nbn:se:liu:diva-11099.

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14

Lyubenova, Sevdalina. "Metalloproteins and protein-protein complexes investigated by CW and pulsed EPR spectroscopy." [S.l.] : [s.n.], 2006. http://deposit.ddb.de/cgi-bin/dokserv?idn=980698812.

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15

Meiser, Wibke. "Investigation of the Kinetics and Mechanism of RAFT Polymerization via EPR Spectroscopy." Doctoral thesis, Niedersächsische Staats- und Universitätsbibliothek Göttingen, 2012. http://hdl.handle.net/11858/00-1735-0000-000D-FB50-3.

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16

Khatib, Maher Al. "EPR Spectroscopy for the investigation of materials of technological and industrial interest." Doctoral thesis, Università di Siena, 2019. http://hdl.handle.net/11365/1070360.

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The research presented in this Doctoral Thesis discusses mainly the use of Electron Paramagnetic Spectroscopy for the characterization of materials of technological interest. The longitudinal relaxation properties of a vanadyl porphyrin complex have been investigated using pulse EPR experiments at Q (34 GHz) and J-band (263 GHz) frequencies, and the molecule proposed as suitable candidate for quantum processors engineering. The experimental knowledge developed through these relaxation studies, have been transferred to the field of melanins biopigments characterization. The interest for this cl
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17

Hargreaves, Stephen. "Novel supramolecular assemblies based on sulfur-nitrogen radicals." Thesis, Sheffield Hallam University, 2000. http://shura.shu.ac.uk/19755/.

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This thesis describes the synthesis of a range of novel dithiadiazolyl radicals. The structures of these compounds are discussed. The physical properties of several compounds have been investigated using EPR spectroscopy and magnetic susceptibility studies. Chapter one begins with an overview of the chemistry of 1,2,3,5-dithiadiazolyl radicals. A general discussion of the history of organic conductors and magnets, and the terms involved in some of the techniques used is given in order to provide a background to the work presented. The second chapter outlines the synthesis and general character
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18

Šafaříková, Lenka. "EPR studium radikálových reakcí sekundárních aminů probíhajících v kapalné fázi." Doctoral thesis, Vysoké učení technické v Brně. Fakulta chemická, 2014. http://www.nusl.cz/ntk/nusl-233399.

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In the framework of Ph.D. thesis the evaluation of radical reactions of four groups of secondary amines R1–NH–R2 in the presence of some selected types of agents was performed using EPR spectroscopy. First group was represented by peroxoagents (3-chloroperbenzoic acid, tBuO2 radicals), the second group involved compounds of PbIV+ (PbO2, Pb(OAc)4) functioning as hydrogen-abstracting agents. In the presence of peroxyagents the formation of corresponding aminoxyl radicals R1–NO–R2 was demonstrated. In the case of surplus of tBuO2 radicals these radicals enter the consecutive reactions which produ
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19

Perera, Rehani Shinuka. "Determining the Structural Dynamics and Topology of Canonical HOLIN-S05 Using EPR Spectroscopy." Miami University / OhioLINK, 2020. http://rave.ohiolink.edu/etdc/view?acc_num=miami1591797430542798.

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20

Salvadori, Enrico. "Advanced EPR spectroscopy provides new insight into triplet-triplet energy transfer in photosynthesis." Doctoral thesis, Università degli studi di Padova, 2011. http://hdl.handle.net/11577/3422010.

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Carotenoids are essential in photosynthesis. These molecules play several roles in the photosynthetic apparatus: they share with chlorophylls the light-harvesting function, stabilize the pigment-protein complexes and are responsible for the protection of the whole apparatus against the hazardous singlet oxygen. The structural function has been investigated in many different organisms by several biochemical methods: the main finding is that carotenoids are essential for the protein stability. Without carotenoids light-harvesting complexes would not fold and their selective removal from intact p
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21

Lee, Yuk Ki. "The electronic structure of the Tyr-Cys· free radical in galactose oxidase determined by EPR spectroscopy." Full text open access at:, 2007. http://content.ohsu.edu/u?/etd,252.

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22

Smith, William. "Development of techniques for magneto-spectroscopy at terahertz frequencies." Thesis, University of Manchester, 2016. https://www.research.manchester.ac.uk/portal/en/theses/development-of-techniques-for-magnetospectroscopy-at-terahertz-frequencies(b9445541-8050-4f9b-9b1f-6a2d0c2935c3).html.

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In this thesis, I present my research into the development and use of a magneto-spectrometer operating at terahertz frequencies. Molecular samples with unpaired electrons were studied using electron paramagnetic resonance (EPR) spectroscopy and the properties of semiconducting samples were measured by cyclotron resonance. A terahertz time-domain spectrometer was constructed, fine-tuned and benchmarked. The use of a large area photoconductive antenna (PCA), with a bias voltage modulated at 1 MHz, allowed for a signal-to-noise ratio of 13800:1 to be achieved, which was equal or superior to compa
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23

Beukes, Stewart Eva-Panduleni. "EPR studies of electron transfer in cadmium selenide sensitised titania." Thesis, University of Aberdeen, 2016. http://digitool.abdn.ac.uk:80/webclient/DeliveryManager?pid=232399.

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Research into renewable energy sources is crucially increasing to counteract the ever more concerning impact of non-renewable sources. Theoretically, Quantum Dot Solar Cells (QDSCs) can achieve much greater efficiencies than current, commercial solar cells, but its expansion is still in its very early stages of scientific study and development. In this project TiO2, one of the most efficient and cost-effective photocatalysts, is coupled with Cadmium Selenide (CdSe) Quantum Dots (QD) in a study of interfacial charge transfers. Thus far, in other studies, CdSe QDs have shown some of the most pro
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24

Wegner, Janine. "Synthesis of Rigid Spin Labels for the Investigation of Transmembrane Peptides by EPR Spectroscopy." Doctoral thesis, Niedersächsische Staats- und Universitätsbibliothek Göttingen, 2018. http://hdl.handle.net/11858/00-1735-0000-002E-E3CF-C.

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25

Mohammed, Faleel Fathima Dhilhani. "Investigating the Dynamic Properties and Structural Topology of Membrane Protein KCNE3 with EPR Spectroscopy." Miami University / OhioLINK, 2019. http://rave.ohiolink.edu/etdc/view?acc_num=miami1563886643270804.

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26

Reese, Annabelle Wey. "Analysis of CW-EPR spectra and the internal dynamics of DNA /." Thesis, Connect to this title online; UW restricted, 1996. http://hdl.handle.net/1773/8569.

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27

Georgiev, David Georgiev. "Selective modification of biomolecules using radical mediated hydrothiolation chemistry." Thesis, University of Edinburgh, 2018. http://hdl.handle.net/1842/31322.

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Intracellular protein-protein interactions (PPIs) play a vital role in many biological processes. Although they are viewed as of high biological interest they prove difficult to explore as potential targets for drug discovery. Numerous studies have shown α- helical peptides 'locked' in their respective bioactive structure can greatly increase their performance by increasing their target affinity, resistance to proteolysis as well as facilitating cellular uptake. A striking feature of literature to date is how few studies utilise different stapling techniques when developing inhibitors for PPIs
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28

Krudopp, Heimke [Verfasser]. "Free lipid radicals and nitroxide radicals in dispersed systems studied by EPR spectroscopy / Heimke Krudopp." Kiel : Universitätsbibliothek Kiel, 2018. http://d-nb.info/1173163212/34.

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29

Cardon, Thomas B. "X-band EPR Spectroscopy of Spin-labeled Membrane Biomolecules Incorporated into Magnetically Aligned Phospholipid Bilayers." Miami University / OhioLINK, 2006. http://rave.ohiolink.edu/etdc/view?acc_num=miami1154747640.

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30

Riemann, Lara [Verfasser]. "Termination Kinetics of Radical Homo- and Copolymerizations Studied via Time-Resolved EPR Spectroscopy / Lara Riemann." Göttingen : Niedersächsische Staats- und Universitätsbibliothek Göttingen, 2021. http://d-nb.info/1235222764/34.

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31

Westcott, Barry Lee 1972. "Investigation of molybdenum sulfur interactions via single crystal EPR and photoelectron spectroscopy: Implications to molybdoenzymes." Diss., The University of Arizona, 1997. http://hdl.handle.net/10150/282444.

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A series of MoS(n) complexes were studied to afford a better understanding of the factors which affect the electronic structures in these complexes. Molybdenum sulfur interactions are of interest because of their importance in biology, and because of the utility of such complexes as catalysts in the petroleum industry. The He I gas phase photoelectron spectra (PES) of the series LMo(E)(OR)₂ [(L=hydrotris(3,5-dimethylpyrazolyl)borate), (E=O, NO)] were explored as a point of reference to the analogous thiolate complexes. These studies show that the nitrosyl complexes (formally Mo(II)) are 0.8 eV
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32

Roessler, Maxie M. "EPR investigations of iron-sulfur cluster relays in enzymes." Thesis, University of Oxford, 2013. http://ora.ox.ac.uk/objects/uuid:ac6fa892-f54a-490d-927b-161231f00777.

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Electron paramagnetic resonance (EPR) spectroscopy is a powerful tool for obtaining structural information about chemical centres with unpaired electrons. In complex biological systems, EPR spectroscopy can be used to probe these paramagnetic centres and the long-range interactions between them. This thesis investigates two important types of enzymes, and in particular the role of the iron-sulfur electron-transfer centres they contain, with a variety of EPR techniques. Complex I (NADH:Ubiquinone Oxidoreductase) plays a key role in the electron transfer chain essential to the formation of ATP,
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33

Taghavikish, Mona. "Tetrakis(2,6-diisopropylphenyl)diphosphine and related compounds : an electrochemical and EPR spectroscopic study of radical cations." Thesis, Lethbridge, Alta. : University of Lethbridge, Dept. of Chemistry and Biochemistry, c2012, 2012. http://hdl.handle.net/10133/3310.

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In this thesis the synthesis and full characterization of a new bulky diphosphine, tetrakis-(2,6-diisopropylphenyl)diphosphine, are described. This compound displays facile oxidation and a thorough investigation of its redox properties has been studied by combining solution electrochemical techniques such as cyclic voltammetry (CV) and rotating disk electrode (RDE) voltammetry, with spectroscopic methods such as electron paramagnetic resonance (EPR) and Simultaneous Electrochemical Electron Paramagnetic Resonance (SEEPR) spectroscopy over a wide temperature range. Density functional theory (DF
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34

Niemöller, Arvid Verfasser], Rüdiger-A. [Akademischer Betreuer] [Eichel, and Bernhard [Akademischer Betreuer] Blümich. "In operando investigations of electrochemical systems by EPR spectroscopy / Arvid Niemöller ; Rüdiger-Albert Eichel, Bernhard Blümich." Aachen : Universitätsbibliothek der RWTH Aachen, 2018. http://d-nb.info/1176422138/34.

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35

Niemöller, Arvid [Verfasser], Rüdiger-A. [Akademischer Betreuer] Eichel, and Bernhard [Akademischer Betreuer] Blümich. "In operando investigations of electrochemical systems by EPR spectroscopy / Arvid Niemöller ; Rüdiger-Albert Eichel, Bernhard Blümich." Aachen : Universitätsbibliothek der RWTH Aachen, 2018. http://nbn-resolving.de/urn:nbn:de:101:1-2019012807464103127281.

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36

Darian, Eva. "Triplex formation as monitored by EPR spectroscopy and molecular dynamics studies of spin-probe labeled DNAs." Morgantown, W. Va. : [West Virginia University Libraries], 2002. http://etd.wvu.edu/templates/showETD.cfm?recnum=2591.

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Thesis (Ph. D.)--West Virginia University, 2002.<br>Title from document title page. Document formatted into pages; contains xi, 121 p. : ill. (some col.). Includes abstract. Includes bibliographical references (p. 113-115).
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37

Dal, Farra Maria Giulia. "The Photoexcited Triplet State as a Spin Probe for Distance Determination in Pulse EPR Dipolar Spectroscopy." Doctoral thesis, Università degli studi di Padova, 2018. http://hdl.handle.net/11577/3426695.

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The biological function of macromolecules such as protein, DNA, and RNA depends on their folding and on the relative movements of domains with dimensions of a few nanometers. This length scale can be accessed by distance measurements between paramagnetic spin centers employing Electron Paramagnetic Resonance (EPR) pulsed dipolar spectroscopy (PDS) techniques. In order to use this spectroscopic methods, the biomolecule has to contain either stable or transient paramagnetic centers, which can be metal ions or clusters, amino acid radicals, or organic cofactor radicals. If the biomolecule is dia
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38

Guarracino, Paola. "Photophysical processes and molecular ordering in organic materials for third generation photovoltaics studied by EPR spectroscopy." Doctoral thesis, Università degli studi di Padova, 2018. http://hdl.handle.net/11577/3424935.

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The world energy consumption is increasing at an average rate of 2.1 % per year, spurred by the economic growth in most of Asian countries, Europe and Canada. The consequent depletion of fossil fuels reservoirs and the reinforced need of environmental sustainability are making the challenge of clean and renewable energy sources one of the most urgent challenges for humankind. Solar power is among the best candidates for the leading role in the energy revolution, being clean, infinite and well distributed over the planet. For this reason, photovoltaic technologies for electricity production are
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39

Krkošková, Petra. "EPR studium radikálových reakcí, iniciovaných rozpadem vybraných typů peroxidických sloučenin." Master's thesis, Vysoké učení technické v Brně. Fakulta chemická, 2010. http://www.nusl.cz/ntk/nusl-216570.

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The products of the decomposition of selected types of peroxo compounds in the presence of redox agents (Pb and Co compounds) were investigated by EPR method. Besides some commercial peroxides the study was performed with peroxo compounds of Luperoxide group (Luperox 101, Luperox 256, Luperox 531). For the detection of the decomposition products the technique of spin-trapping using nitrosobenzene was applied. EPR spectra of radical adducts formed by the reaction of the reactive oxygenous radicals with nitrosobenzen having the character of stable nitroxyl radicals were analyzed. Their EPR param
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40

Williams, Elizabeth Mary. "Oxidation of human nitrosylhemoglobin monitored by UV-Vis and EPR Spectroscopies: detection of products and intermediates." Thesis, Montana State University, 2005. http://etd.lib.montana.edu/etd/2005/williams/WilliamsE0805.pdf.

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41

Imperatore, Mario Vincenzo. "Dielectric spectroscopy as a condition monitoring diagnostic technique for thermally aged PVC/EPR nuclear power plant cables." Master's thesis, Alma Mater Studiorum - Università di Bologna, 2017. http://amslaurea.unibo.it/13002/.

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I cavi in bassa tensione hanno ruolo fondamentale nel garantire l’operazione in sicurezza di essa pur dovendo sopportare quelle sollecitazioni comunemente presenti negli ambienti nucleari, come elevate temperature, elevati livelli di radiazione, presenza di umidità e di particelle contaminanti, sollecitazioni meccaniche. Queste sollecitazioni causano degradazione dei materiali, in particolare di guaina ed isolante. Diverse tecniche diagnostiche vengono studiate ed applicate a questi sistemi: analisi di proprietà meccaniche come l’allungamento a rottura (EaB), tecniche come l’analisi termogra
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42

Ren, Jiyun. "Analysis of free radical characteristics in biological systems based on EPR spectroscopy, employing blind source separation techniques." Click to view the E-thesis via HKUTO, 2006. http://sunzi.lib.hku.hk/hkuto/record/B36797479.

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43

Kim, Nak-Kyoon. "Metal dependent structure, dynamics, and function in RNA measured by site-directed spin labeling and EPR spectroscopy." Diss., Texas A&M University, 2005. http://hdl.handle.net/1969.1/4900.

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The structure and function of RNA molecules are dependent on RNA-metal ion interactions in both diffusive and direct ways. Structural information for RNA has been obtained using various biophysical and biochemical methods. In this study, using site-directed spin labeling (SDSL) and EPR spectroscopy, distances in RNA duplexes, TAR RNA, and the hammerhead ribozyme have been measured to investigate RNA structures. Kinetic measurements have been performed in the extended hammerhead ribozyme to correlate the catalytic function with metal dependent ribozyme folding. As a basic model system for dista
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44

Akhmetzyanov, Dmitry [Verfasser], Thomas [Gutachter] Prisner, Björn [Gutachter] Corzilius, and Olav [Gutachter] Schiemann. "Pulsed EPR dipolar spectroscopy with novel paramagnetic tags / Dmitry Akhmetzyanov ; Gutachter: Thomas Prisner, Björn Corzilius, Olav Schiemann." Frankfurt am Main : Universitätsbibliothek Johann Christian Senckenberg, 2017. http://d-nb.info/1138705349/34.

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45

Ren, Jiyun, and 任紀韞. "Analysis of free radical characteristics in biological systems based on EPR spectroscopy, employing blind source separation techniques." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2006. http://hub.hku.hk/bib/B36797479.

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46

Bottorf, Lauren Marie. "Developing Electron Paramagnetic Resonance Spectroscopy Methods for Secondary Structural Characterization of Membrane Proteins." Miami University / OhioLINK, 2017. http://rave.ohiolink.edu/etdc/view?acc_num=miami1510164534760125.

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47

Kattner, Hendrik. "Radical Polymerization Kinetics of Non-Ionized and Fully-Ionized Monomers Studied by Pulsed-Laser EPR." Doctoral thesis, Niedersächsische Staats- und Universitätsbibliothek Göttingen, 2016. http://hdl.handle.net/11858/00-1735-0000-0028-879B-7.

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48

Ahammad, Tanbir. "Probing the structural dynamics, conformational change, and topology of pinholin S21, a bacteriophage lytic protein, using electron paramagnetic resonance spectroscopy." Miami University / OhioLINK, 2020. http://rave.ohiolink.edu/etdc/view?acc_num=miami1595598100557068.

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49

Ghimire, Harishchandra. "Structure, Dynamics, and Distance Measurements in Membrane Proteins and Peptides using EPR Spectroscopic Techniques." Miami University / OhioLINK, 2010. http://rave.ohiolink.edu/etdc/view?acc_num=miami1291739688.

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50

Pierro, Annalisa. "Protein structural dynamics in bacteria via nitroxide-based SDSL-EPR spectroscopy : from method improvements to in-cell studies." Electronic Thesis or Diss., Aix-Marseille, 2021. http://theses.univ-amu.fr.lama.univ-amu.fr/211116_PIERRO_290xrxu60ryzjfl293g970fjmdnl_TH%20(1).pdf.

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L'étude des biomolécules dans leur environnement natif, la cellule, est l'un des principaux objectifs de la biologie structurale au cours de la dernière décennie. Ainsi, nous assistons à un remarquable développement des approches dites « in-cell », comme la CryoET, FRET (Förster Resonance Energy Tranfer), RMN. Parmi elles, la technique de marquage de spin couplée à la spectroscopie de Résonance Paramagnétique Electronique (SDSL-RPE) présente des caractéristiques intéressantes et avantageuses permettant de sonder la dynamique des protéines à l'intérieur des cellules. En particulier, l’utilisati
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