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1

Ray, Robyn. "Discerning Erionite from Other Zeolite Minerals During Analysis." Environmental and Engineering Geoscience 26, no. 1 (2020): 133–39. http://dx.doi.org/10.2113/eeg-2279.

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ABSTRACT Erionite, a naturally occurring fibrous mineral that belongs to the zeolite group has been designated by the International Agency for Research on Cancer (IARC) as a Group 1 Carcinogen on the basis of mesothelioma, a disease also resulting from the inhalation of asbestos fibers. Significant outcrops of fibrous erionite have been reported in California, North Dakota, Nevada, Oregon, and other states. For geologists and industrial hygienists dealing with mining, construction, or various aspects of community protection, it is vital to understand the basics of detecting and handling erioni
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2

Giordani, Matteo, Georgia Cametti, Fulvio Di Lorenzo, and Sergey V. Churakov. "Real-Time Observation of Fibrous Zeolites Reactivity in Contact with Simulated Lung Fluids (SLFs) Obtained by Atomic Force Microscope (AFM)." Minerals 9, no. 2 (2019): 83. http://dx.doi.org/10.3390/min9020083.

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Inhalation of fibrous erionite particles has been linked to malignant mesothelioma. Accordingly, erionite is considered the most carcinogenic mineral. The reactivity and the nature of erionite biotoxicity has been the subject of intensive research. Despite very close chemical and structural relationships between erionite and offretite, the reactivity of offretite in lung fluids remains unknown. In this paper, the interaction of erionite and offretite surfaces with simulated lung fluids was investigated by means of in situ atomic force microscope (AFM). To simulate different environments in the
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3

Berry, Terri-Ann, Elena Belluso, Ruggero Vigliaturo, et al. "Asbestos and Other Hazardous Fibrous Minerals: Potential Exposure Pathways and Associated Health Risks." International Journal of Environmental Research and Public Health 19, no. 7 (2022): 4031. http://dx.doi.org/10.3390/ijerph19074031.

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There are six elongate mineral particles (EMPs) corresponding to specific dimensional and morphological criteria, known as asbestos. Responsible for health issues including asbestosis, and malignant mesothelioma, asbestos has been well researched. Despite this, significant exposure continues to occur throughout the world, potentially affecting 125 million people in the workplace and causing thousands of deaths annually from exposure in homes. However, there are other EMPS, such as fibrous/asbestiform erionite, that are classified as carcinogens and have been linked to cancers in areas where it
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4

Pacella, Alessandro, Paolo Ballirano, Marzia Fantauzzi, et al. "Surface and Bulk Modifications of Fibrous Erionite in Mimicked Gamble’s Solution at Acidic pH." Minerals 11, no. 9 (2021): 914. http://dx.doi.org/10.3390/min11090914.

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This study aimed at investigating both the surface and bulk modifications occurring on fibrous erionite during leaching in a mimicked Gamble’s solution (MGS) at pH of 4.5 and T = 37 °C, up to one month of incubation. Samples were characterized by a multi-analytical approach: field-emission scanning electron microscopy (FE-SEM) was employed to investigate the morphological changes of both pristine and reacted fibres, inductively coupled plasma optical emission spectrometry (ICP-OES) was used to measure the concentration of the released cations; X-ray photoelectron spectroscopy (XPS) was exploit
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5

Rinaudo, Caterina, and Alessandro Croce. "Micro-Raman Spectroscopy, a Powerful Technique Allowing Sure Identification and Complete Characterization of Asbestiform Minerals." Applied Sciences 9, no. 15 (2019): 3092. http://dx.doi.org/10.3390/app9153092.

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Micro-Raman spectroscopy has been applied to fibrous minerals regulated as “asbestos”—anthophyllite, actinolite, amosite, crocidolite, tremolite, and chrysotile—responsible of severe diseases affecting mainly, but not only, the respiratory system. The technique proved to be powerful in the identification of the mineral phase and in the recognition of particles of carbonaceous materials (CMs) lying on the “asbestos” fibers surface. Also, erionite, a zeolite mineral, from different outcrops has been analyzed. To erionite has been ascribed the peak of mesothelioma noticed in Cappadocia (Turkey) d
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6

Тищенко, А. И., А. В. Касаткин та Е. А. Шибаев. "Новые находки цеолитов на Карадаге". Труды Карадагской научной станции им. Т.И. Вяземского - природного заповедника РАН, № 1 (3) (6 квітня 2021): 67–75. http://dx.doi.org/10.21072/eco.2021.03.06.

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The paper reports on the first find of several minerals of Zeolite group in Karadag – heulandite-Na, clinoptilolite-Са, clinoptilolite-Na, stellerite, stilbite-Na, erionite-Ca, erionite-Na. The above minerals were identified by microprobe analysis, X-ray diffraction and infrared spectroscopy. Data on their morphology, chemical composition and paragenesis are given.
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7

Carthew, P., R. J. Hill, R. E. Edwards, and P. N. Lee. "Intrapleural Administration of Fibres Induces Mesothelioma in Rats in the same Relative Order of Hazard as Occurs in Man after Exposure." Human & Experimental Toxicology 11, no. 6 (1992): 530–34. http://dx.doi.org/10.1177/096032719201100615.

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1 The dose—response data for the induction of mesothelioma, in rats, by the intrapleural administration of the fibrous zeolite, erionite, has been compared to the published data for the crocidolite and chrysotile forms of asbestos. Erionite is more than two orders of magnitude more carcinogenic than either of the two forms of asbestos examined. 2 The relative sensitivity of the intrapleural and intraperitoneal routes of injection were also examined. The sensitivity of the intraperitoneal over the intrapleural route of administration was considerably greater for all the forms of asbestos examin
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8

Anthonisen, Nick R. "Trouble in Anatolia." Canadian Respiratory Journal 11, no. 4 (2004): 273–74. http://dx.doi.org/10.1155/2004/545319.

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In this issue of theCanadian Respiratory Journal, Gulmez et al (pages 287-290) review the presentation, management and outcome of malignant mesothelioma in central Anatolia, Turkey. There is nothing particularly new about the disease here; it presents with chest pain, dyspnea and pleural effusion, is diagnosed by biopsy and has a miserable outcome whatever is done for it, just like malignant mesothelioma in Canada. Mesothelioma in Anatolia is unusual in that it is very common, with an approximately equal sex distribution, and frequently occurs in relatively young people. The reasons for this a
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9

Dogan, A. Umran. "Zeolite Mineralogy and Cappadocian Erionite." Indoor and Built Environment 12, no. 5 (2003): 337–42. http://dx.doi.org/10.1177/142032603036408.

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10

Gulmez, Inci, Levent Kart, Hakan Buyukoglan, Ozlem Er, Suleyman Balkanli, and Mustafa Ozesmi. "Evaluation of Malignant Mesothelioma in Central Anatolia: A Study of 67 Cases." Canadian Respiratory Journal 11, no. 4 (2004): 287–90. http://dx.doi.org/10.1155/2004/204793.

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BACKROUND:Malignant mesothelioma (MM) is a fatal neoplasm which frequently results from exposure to asbestos or erionite.METHOD:Sixty-seven patients with MM were seen between 1990 and 2001. Their clinical and radiological features, as well as the therapy, were retrospectively evaluated.RESULTS:In 51 patients (76.1%), the MM was confined to the pleura, in 14 patients it was exclusively peritoneal and in two patients, it involved both areas. Of the 67 cases, 35 (52.2%) were women. The mean (± SD) age for all cases was 57.6±11.5 years. Dyspnea (67.2%), cough (55.2%) and chest pain (50.7%) were th
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11

Di Giuseppe, Dario. "Characterization of Fibrous Mordenite: A First Step for the Evaluation of Its Potential Toxicity." Crystals 10, no. 9 (2020): 769. http://dx.doi.org/10.3390/cryst10090769.

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In nature, a huge number of unregulated minerals fibers share the same characteristics as asbestos and therefore have potential adverse health effects. However, in addition to asbestos minerals, only fluoro-edenite and erionite are currently classified as toxic/pathogenic agents by the International Agency for Research on Cancer (IARC). Mordenite is one of the most abundant zeolites in nature and commonly occurs with a fibrous crystalline habit. The goal of this paper is to highlight how fibrous mordenite shares several common features with the well-known carcinogenic fibrous erionite. In part
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12

Pacella, Alessandro, Carlo Cremisini, Elisa Nardi, et al. "Different Erionite Species Bind Iron into the Structure: A Potential Explanation for Fibrous Erionite Toxicity." Minerals 8, no. 2 (2018): 36. http://dx.doi.org/10.3390/min8020036.

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13

Cametti, Georgia, and Sergey V. Churakov. "Crystal structure of Ag-exchanged levyne intergrown with erionite: Single-crystal X-ray diffraction and Molecular Dynamics simulations." American Mineralogist 105, no. 11 (2020): 1631–38. http://dx.doi.org/10.2138/am-2020-7500.

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Abstract The modification of natural zeolites via ion exchange is an efficient technique used to improve their performances and tune their properties for specific applications. In this study, a natural levyne-Ca intergrown with erionite was fully exchanged by Ag+ and its structure [with idealized chemical composition Ag6(Si,Al)18O36·18H2O] was investigated by combining a theoretical and experimental approach. Single-crystal X-ray diffraction data demonstrated that Ag-levyne maintained the R3m space group, characteristic of the natural levyne. Ag ions distribute over partially occupied sites al
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14

Croce, Alessandro, Mario Allegrina, Caterina Rinaudo, Giovanni Gaudino, Haining Yang, and Michele Carbone. "Numerous Iron-Rich Particles Lie on the Surface of Erionite Fibers from Rome (Oregon, USA) and Karlik (Cappadocia, Turkey)." Microscopy and Microanalysis 21, no. 5 (2015): 1341–47. http://dx.doi.org/10.1017/s1431927615014762.

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AbstractErionite samples from Rome, Oregon (USA) and Karlik, Cappadocia (Turkey) were analyzed by environmental scanning electron microscopy (E-SEM) coupled with energy-dispersive spectroscopy (EDS) to verify the chemical composition of this mineral phase, and the presence of iron in particular. By means of backscattered electron images, a large number of particles/grains were observed on the surface of the erionite fibers from both locations. The particles were found to be micrometric on samples from Rome and submicrometric on samples from Karlik, and always lighter than the hosting crystal i
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15

Jankowska, Aldona, and Stanisław Kowalak. "Synthesis of ultramarine analogs from erionite." Microporous and Mesoporous Materials 110, no. 2-3 (2008): 570–78. http://dx.doi.org/10.1016/j.micromeso.2007.07.007.

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16

Wagner, J. C., J. W. Skidmore, R. J. Hill, and D. M. Griffiths. "Erionite exposure and mesotheliomas in rats." British Journal of Cancer 51, no. 5 (1985): 727–30. http://dx.doi.org/10.1038/bjc.1985.108.

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17

Olguín, M. T., I. García-Sosa, and M. Solache-Ríos. "Sorption of strontium by Mexican erionite." Journal of Radioanalytical and Nuclear Chemistry Articles 204, no. 2 (1996): 415–22. http://dx.doi.org/10.1007/bf02060329.

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18

Mirata, Serena, Vanessa Almonti, Dario Di Giuseppe, et al. "The Acute Toxicity of Mineral Fibres: A Systematic In Vitro Study Using Different THP-1 Macrophage Phenotypes." International Journal of Molecular Sciences 23, no. 5 (2022): 2840. http://dx.doi.org/10.3390/ijms23052840.

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Alveolar macrophages are the first line of defence against detrimental inhaled stimuli. To date, no comparative data have been obtained on the inflammatory response induced by different carcinogenic mineral fibres in the three main macrophage phenotypes: M0 (non-activated), M1 (pro-inflammatory) and M2 (alternatively activated). To gain new insights into the different toxicity mechanisms of carcinogenic mineral fibres, the acute effects of fibrous erionite, crocidolite and chrysotile in the three phenotypes obtained by THP-1 monocyte differentiation were investigated. The three mineral fibres
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19

Ballirano, Paolo, Alessandro Pacella, Andrea Bloise, Matteo Giordani, and Michele Mattioli. "Thermal Stability of Woolly Erionite-K and Considerations about the Heat-Induced Behaviour of the Erionite Group." Minerals 8, no. 1 (2018): 28. http://dx.doi.org/10.3390/min8010028.

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20

WENDLING, PATRICE. "Is Newfound U.S. Erionite the New Asbestos?" Family Practice News 41, no. 4 (2011): 48. http://dx.doi.org/10.1016/s0300-7073(11)70185-2.

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21

Komarneni, Sridhar. "Hydrothermal synthesis of mordenite needles from erionite." Zeolites 6, no. 2 (1986): 95–98. http://dx.doi.org/10.1016/s0144-2449(86)80003-3.

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22

WENDLING, PATRICE. "Erionite Deposits in Western U.S. Raise Concern." Internal Medicine News 44, no. 2 (2011): 23. http://dx.doi.org/10.1016/s1097-8690(11)70069-5.

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23

Saracci, Rodolfo. "Erionite and cancer in a Mexican village." Occupational and Environmental Medicine 72, no. 3 (2014): 163–64. http://dx.doi.org/10.1136/oemed-2014-102544.

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24

Dogan, A. Umran, Meral Dogan, and John A. Hoskins. "Erionite series minerals: mineralogical and carcinogenic properties." Environmental Geochemistry and Health 30, no. 4 (2008): 367–81. http://dx.doi.org/10.1007/s10653-008-9165-x.

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25

Hudec, Pavol, Jozef Novanský, Anna Bučinská, Štefan Morávek, and Zdenek Židek. "Changes in Physico-Chemical and Catalytic Properties of Synthetic Erionite after Various Treatment." Collection of Czechoslovak Chemical Communications 57, no. 4 (1992): 845–52. http://dx.doi.org/10.1135/cccc19920845.

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Influence of decationization by ammonium ions and dealumination by HCl as well as calcination under self-steaming conditions at 1053 K with following treatment by ammonium ions or by HCl solution on the extent of alkali metals extraction was studied together with surface, sorption, acidic and catalytic properties of synthetic erionite. Samples were also characterized by X-ray diffraction spectra and IR skeletal vibration spectra. Results showed increasing catalytic activity and acidity after thermal treatment, followed by ion exchange with HCl or ammonium ions, which can be connected with deep
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26

Quiroz-Estrada, Karla, Alessandro Pacella, Paolo Ballirano, Miguel Ángel Hernández-Espinosa, Carlos Felipe, and Marcos Esparza-Schulz. "Crystal Chemical and Structural Characterization of Natural and Cation-Exchanged Mexican Erionite." Minerals 10, no. 9 (2020): 772. http://dx.doi.org/10.3390/min10090772.

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In this work, the chemical structural characterization of the erionite-type zeolite from Agua Prieta, Sonora, México, was performed on both pristine and Na, Ca, and Mg exchanged samples in order to identify the various modifications due to cation exchange. The samples investigated were those that showed the best behaviour of CO2 and CH4 adsorption at zero coverage levels and the higher values of surface area reported in our previous studies. According to the crystal-chemical formula (Na3.44K1.96Mg0.63Ca0.62)[Al8.21Si27.79O71.85]·29.63H2O, the pristine sample has been classified as erionite-Na.
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27

Quiroz-Estrada, Karla, Miguel Hernández, Carlos Felipe-Mendoza, Juana Santamaría-Juárez, Vitalii Petranovskii, and Efraín Rubio. "Critical Admission Temperature of H2 and CH4 in Nanopores of Exchanged ERI Zeolites." Nanomaterials 9, no. 2 (2019): 160. http://dx.doi.org/10.3390/nano9020160.

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Due to the nanoporous nature of zeolitic materials, they can be used as gas adsorbents. This paper describes the effect of critical admission temperature through narrow pores of natural ERI zeolites at low levels of coverage. This phenomenon occurs by adsorption of CH4 and H2 on pores in natural erionite. The zeolite was exchanged with aqueous solutions of Na+, Mg2+, and Ca2+ salts at different concentrations, times, and temperatures of treatment. Experimental data of CH4 and H2 adsorption were treated by the Langmuir equation. Complementarily, the degree of interaction of these gases with the
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28

Ballirano, P., and G. Cametti. "Crystal chemical and structural investigation of levyne-Na." Mineralogical Magazine 77, no. 7 (2013): 2887–99. http://dx.doi.org/10.1180/minmag.2013.077.7.01.

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AbstractA sample of levyne-Na from Dunseverick, Antrim, Northern Ireland, UK, has been characterized from the crystal chemical and structural point of view. Its mean crystal chemical formula, calculated on the basis of 54(Si+Al), is Na7.72Ca4.62K1.31Sr0.08Mg0.02(Al19.55Si34.45O107.50)·50.5H2O. Levyne-Na is associated with erionite-Na whose chemical formula is Na6.08Ca0.8 5K2.55Mg0.16(Al10.41Si25.59O72.13)·30.6H2O, calculated on the basis of 36(Si+Al). Their compositions are consistent with those of levyne/erionite inter/overgrowth reported in the literature. The structural analysis, carried ou
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29

Aguilar-Armenta, Gelacio, and María Eugenia Patiño-Iglesias. "Adsorption Equilibria and Kinetics of Propylene and Propane on Natural Erionite and on Erionite Exchanged with K+and Ag+." Langmuir 18, no. 20 (2002): 7456–61. http://dx.doi.org/10.1021/la011656o.

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30

Alberti, A., A. Martucci, E. Galli, and G. Vezzalini. "A reexamination of the crystal structure of erionite." Zeolites 19, no. 5-6 (1997): 349–52. http://dx.doi.org/10.1016/s0144-2449(97)00102-4.

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31

Patrick, G. "A novel synthetic erionite fibre radiolabelled with 57Co." Annals of Occupational Hygiene 45, no. 5 (2001): 365–70. http://dx.doi.org/10.1016/s0003-4878(00)00057-0.

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32

Tekla, Justyna, Louwanda Lakiss, Valentin Valchev, et al. "Increasing the catalytic performance of erionite by hierarchization." Microporous and Mesoporous Materials 299 (June 2020): 110088. http://dx.doi.org/10.1016/j.micromeso.2020.110088.

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33

Heck, Roland H., and Nai Y. Chen. "Conversion of light naphthas over sulfided nickel erionite." Industrial & Engineering Chemistry Research 32, no. 6 (1993): 1003–6. http://dx.doi.org/10.1021/ie00018a001.

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34

Ilgren, E. B., F. D. Pooley, J. C. Larragoitia, et al. "First Confirmed Erionite Related Mesothelioma in North America." Indoor and Built Environment 17, no. 6 (2008): 567–68. http://dx.doi.org/10.1177/1420326x08099908.

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35

Passaglia, E., G. Artioli, and A. Gualtieri. "Crystal chemistry of the zeolites erionite and offretite." American Mineralogist 83, no. 5-6 (1998): 577–89. http://dx.doi.org/10.2138/am-1998-5-618.

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36

Roessner, F., and B. Staudte. "Spectroscopic Characterization of Zeolite P Contained in Erionite." Zeitschrift für Physikalische Chemie 190, Part_1 (1995): 9–18. http://dx.doi.org/10.1524/zpch.1995.190.part_1.009.

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37

García-Sosa, I., and M. Solache Ríos. "Sorption of cobalt and cadmium by Mexican erionite." Journal of Radioanalytical and Nuclear Chemistry 218, no. 1 (1997): 77–80. http://dx.doi.org/10.1007/bf02033977.

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38

Ogden, J. S., N. E. Bogdanchikova, J. M. Corker, and V. P. Petranovskii. "Structure of silver clusters embedded in erionite channels." European Physical Journal D 9, no. 1 (1999): 605–8. http://dx.doi.org/10.1007/s100530050509.

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39

Lillerud, Karl P., and Johan H. Raeder. "On the synthesis of erionite—offretite intergrowth zeolites." Zeolites 6, no. 6 (1986): 474–83. http://dx.doi.org/10.1016/0144-2449(86)90032-1.

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40

Lillerud, K. P. "Aluminium distribution in the zeolites offretite and erionite." Zeolites 7, no. 1 (1987): 14–17. http://dx.doi.org/10.1016/0144-2449(87)90112-6.

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41

Bish, David L. "Detection of Trace Amounts of Erionite Using X-ray Powder Diffraction: Erionite in Tuffs of Yucca Mountain, Nevada, and Central Turkey." Clays and Clay Minerals 39, no. 4 (1991): 437–45. http://dx.doi.org/10.1346/ccmn.1991.0390413.

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42

Demirer, Ersin, Christian F. Ghattas, Mohamed O. Radwan, and Elamin M. Elamin. "Clinical and Prognostic Features of Erionite-Induced Malignant Mesothelioma." Yonsei Medical Journal 56, no. 2 (2015): 311. http://dx.doi.org/10.3349/ymj.2015.56.2.311.

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43

Millward, G. R., J. M. Thomas, O. Terasaki, and D. Watanabe. "Direct imaging and characterization of intergrowth-defects in erionite." Zeolites 6, no. 2 (1986): 91–95. http://dx.doi.org/10.1016/s0144-2449(86)80002-1.

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44

Yang, Sanyuan, and N. P. Evmiridis. "Synthesis and characterization of an offretite/erionite type zeolite." Microporous Materials 6, no. 1 (1996): 19–26. http://dx.doi.org/10.1016/0927-6513(95)00077-1.

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45

Dikensoy, Oner. "Mesothelioma due to environmental exposure to erionite in Turkey." Current Opinion in Pulmonary Medicine 14, no. 4 (2008): 322–25. http://dx.doi.org/10.1097/mcp.0b013e3282fcea65.

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46

Antúnez-García, Joel, D. H. Galván, A. Posada-Amarillas, and Vitalii Petranovskii. "A theoretical study of Cu clusters in siliceous erionite." Journal of Molecular Structure 1059 (February 2014): 232–38. http://dx.doi.org/10.1016/j.molstruc.2013.09.019.

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47

Olguín, M. T., M. Solache, M. Asomoza, D. Acosta, P. Bosch, and S. Bulbulian. "UO22+Sorption in Natural Mexican Erionite and Y Zeolite." Separation Science and Technology 29, no. 16 (1994): 2161–78. http://dx.doi.org/10.1080/01496399408002196.

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48

Çöplü, L., AU Demir, Y. Karakoca, et al. "Mesothelioma and othermalignancies due to erionite exposure in Turkey." Lung Cancer 15, no. 2 (1996): 270. http://dx.doi.org/10.1016/0169-5002(96)81620-5.

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49

Dogan, A. Umran, and Meral Dogan. "Re-evaluation and re-classification of erionite series minerals." Environmental Geochemistry and Health 30, no. 4 (2008): 355–66. http://dx.doi.org/10.1007/s10653-008-9163-z.

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50

Cavalcante, Célio L., Mladen Eić, Douglas M. Ruthven, and Mario L. Occelli. "Diffusion of n-paraffins in offretite-erionite type zeolites." Zeolites 15, no. 4 (1995): 293–307. http://dx.doi.org/10.1016/0144-2449(94)00061-v.

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