Academic literature on the topic 'ESIPT'

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Journal articles on the topic "ESIPT"

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Joshi, Hem C., and Liudmil Antonov. "Excited-State Intramolecular Proton Transfer: A Short Introductory Review." Molecules 26, no. 5 (2021): 1475. http://dx.doi.org/10.3390/molecules26051475.

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In this short review, we attempt to unfold various aspects of excited-state intramolecular proton transfer (ESIPT) from the studies that are available up to date. Since Weller’s discovery of ESIPT in salicylic acid (SA) and its derivative methyl salicylate (MS), numerous studies have emerged on the topic and it has become an attractive field of research because of its manifold applications. Here, we discuss some critical aspects of ESIPT and tautomerization from the mechanistic viewpoint. We address excitation wavelength dependence, anti-Kasha ESIPT, fast and slow ESIPT, reversibility and irre
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Mena, Leandro D., D. M. A. Vera, Maria T. Baumgartner, and Liliana B. Jimenez. "Adiabatic deprotonation as an important competing pathway to ESIPT in photoacidic 2-phenylphenols." Physical Chemistry Chemical Physics 21, no. 23 (2019): 12231–40. http://dx.doi.org/10.1039/c9cp02028d.

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Kim, Jinyong, Sehoon Kim, Soo Young Park, and Taiha Joo. "Excited State Intramolecular Proton Transfer Dynamics of Oxadiazole‐based Dyes#." Bulletin of the Korean Chemical Society 36, no. 3 (2015): 855–61. http://dx.doi.org/10.1002/bkcs.10160.

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Excited state intramolecular proton transfer (ESIPT) dynamics of two oxadiazole‐based model compounds, 2,5‐bis‐[5‐(4‐tert‐butyl‐phenyl)‐[1,3,4]oxadiazol‐2‐yl]‐phenol (SOX) and 2,5‐bis‐[5‐(4‐tert‐butyl‐phenyl)‐[1,3,4]oxadiazol‐2‐yl]‐benzene‐1,4‐diol (DOX) have been investigated by time‐resolved fluorescence. SOX and DOX have one and two intramolecular hydrogen bond moieties, respectively, where ESIPT may occur. Time‐resolved fluorescence fully resolves the ESIPT dynamics and establishes the two‐state conversion between the enol and keto isomers in the S1 potential energy surface. The apparent i
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Basarić, Nikola, Nikola Cindro, Yunyan Hou, Ivana Žabčić, Kata Mlinarić-Majerski, and Peter Wan. "Competing photodehydration and excited-state intramolecular proton transfer (ESIPT) in adamantyl derivatives of 2-phenylphenols." Canadian Journal of Chemistry 89, no. 2 (2011): 221–34. http://dx.doi.org/10.1139/v10-102.

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2-Phenylphenol derivatives strategically substituted with a hydroxyadamantyl substituent were synthesized and their photochemical reactivity was investigated. Derivatives 9 and 10 undergo competitive excited-state intramolecular proton transfer (ESIPT) from the phenol to the carbon atom of the adjacent phenyl ring and formal ESPT from the phenol to the hydroxyl group coupled with dehydration. These two processes (both via S1) give rise to two classes of quinone methides (QMs) that revert to starting material or react with nucleophiles, respectively. ESIPT to carbon atoms was studied by perform
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LI, YUANZUO, SHASHA LIU, LILI ZHAO, MAODU CHEN, FENGCAI MA, and YONG DING. "EXCITED-STATE INTRAMOLECULAR ELECTRON TRANSFER COUPLED WITH EXCITED-STATE INTRAMOLECULAR PROTON TRANSFER IN PHOTOINDUCED ENOL TO KETO TAUTOMERIZATION." Journal of Theoretical and Computational Chemistry 08, supp01 (2009): 1073–86. http://dx.doi.org/10.1142/s0219633609005246.

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In this paper, the two-dimensional (2D) site and the three-dimensional (3D) cube representations [Sun MT, J Chem Phys124: 054903, 2006] have been further developed to study the charge transfer during excited-state relaxation. With these newly developed representations, we theoretically investigate the excited-state intramolecular electron transfer (ESIET) in enol excited-state geometry relaxation, and ESIET coupled with excited-state intramolecular proton transfer (ESIPT) in phototautomerization (in enol to keto transformation). The energy levels of highest occupied molecular orbital (HOMO) an
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Zhao, Xin, Lixia Zhu, Qi Li, Hang Yin, and Ying Shi. "The Interplay between ESIPT and TADF for the 2,2′-Bipyridine-3,3′-diol: A Theoretical Reconsideration." International Journal of Molecular Sciences 23, no. 22 (2022): 13969. http://dx.doi.org/10.3390/ijms232213969.

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Organic molecules with excited-state intramolecular proton transfer (ESIPT) and thermally activated delayed fluorescence (TADF) properties have great potential for realizing efficient organic light-emitting diodes (OLEDs). Furthermore, 2,2′-bipyridine-3,3′-diol (BP(OH)2) is a typical molecule with ESIPT and TADF properties. Previously, the double ESIPT state was proved to be a luminescent state, and the T2 state plays a dominant role in TADF for the molecule. Nevertheless, whether BP(OH)2 undergoes a double or single ESIPT process is controversial. Since different ESIPT channels will bring dif
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Ma, Pan, Fuchun Gong, Hanming Zhu, et al. "Partnered Excited-State Intermolecular Proton Transfer Fluorescence (P-ESIPT) Signaling for Nitrate Sensing and High-Resolution Cell-Imaging." Molecules 27, no. 16 (2022): 5164. http://dx.doi.org/10.3390/molecules27165164.

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Nitrite (NO2−) is a common pollutant and is widely present in the environment and in human bodies. The development of a rapid and accurate method for NO2− detection is always a very important task. Herein, we synthesized a partnered excited-state intermolecular proton transfer (ESIPT) fluorophore using the “multi-component one pot” method, and used this as a probe (ESIPT-F) for sensing NO2−. ESIPT-F exhibited bimodal emission in different solvents because of the solvent-mediated ESIPT reaction. The addition of NO2− caused an obvious change in colors and tautomeric fluorescence due to the graft
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Raeker, Tim, and Bernd Hartke. "Full-Dimensional Photodynamics of Bistable Proton Transfer Switches." Zeitschrift für Physikalische Chemie 234, no. 7-9 (2020): 1533–47. http://dx.doi.org/10.1515/zpch-2019-1587.

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AbstractExcited-state intramolecular proton transfers (ESIPT) are one of the fastest reactions in chemistry (<100 fs) which – among other features like high photostability – makes them an important reaction class for molecular switches. ESIPTs can be coupled with double bond rotation/isomerization, so that molecules can act as “molecular cranes”, facilitating long-range proton transfer. A versatile model system is 7-hydroxy-4-methylquinoline-8-carbaldehyde (HMQCA): it features two proton-accepting sites, two stable ground-state isomers and should allow for easy derivatization. There is also
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Yoon, Hojeong, Seongchul Park, Raj Kumar Koninti, and Manho Lim. "Photoexcitation Dynamics of 4-Aminopthalimide in Solution Investigated Using Femtosecond Time-Resolved Infrared Spectroscopy." International Journal of Molecular Sciences 25, no. 20 (2024): 11038. http://dx.doi.org/10.3390/ijms252011038.

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Excited-state intramolecular proton transfer (ESIPT) reactions are crucial in photoresponsive materials and fluorescent markers. The fluorescent compound 4-aminophthalimide (4-AP) has been reported to exhibit solvent-assisted ESIPT in protic solvents, such as methanol, wherein the solvent interacts with 4-AP to form a six-membered hydrogen-bonded ring that is strengthened upon excitation. Although the controversial observation of ESIPT in 4-AP has been extensively studied, the molecular mechanism has yet to be fully explored. In this study, femtosecond infrared spectroscopy was used to investi
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Lee, Junghwa, Pyoungsik Shin, Pi-Tai Chou, and Taiha Joo. "Excited State Intramolecular Proton Transfer Dynamics of Derivatives of the Green Fluorescent Protein Chromophore." International Journal of Molecular Sciences 24, no. 4 (2023): 3448. http://dx.doi.org/10.3390/ijms24043448.

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Excited state intramolecular proton transfer (ESIPT) dynamics of the o-hydroxy analogs of the green fluorescent protein (GFP) chromophore have been investigated by time-resolved spectroscopies and theoretical calculations. These molecules comprise an excellent system to investigate the effect of electronic properties on the energetics and dynamics of ESIPT and to realize applications in photonics. Time-resolved fluorescence with high enough resolution was employed to record the dynamics and the nuclear wave packets in the excited product state exclusively in conjunction with quantum chemical m
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Dissertations / Theses on the topic "ESIPT"

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Brousmiche, Darryl Wayne. "Mechanistic studies of photochemical quinone methide formation via ESPT and formal long-range ESIPT." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 2001. http://www.collectionscanada.ca/obj/s4/f2/dsk3/ftp04/NQ58560.pdf.

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Le, Gourrierec Denis. "Excited state intramolecular proton transfer (ESIPT) to nitrogen in heterocyclic compounds." Thesis, University of Central Lancashire, 1996. http://clok.uclan.ac.uk/21906/.

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Excited state intramolecular proton transfer (ESIPT) reactions have aroused considerable interest in the last 10-15 years. The ESIPT reaction is normally extremely rapid and yields excited species of considerably lower energy than the initial Franck-Condon excited state. ESIPT has therefore been used for the rapid dissipation of energy (e. g. for polymer protection against UV degradation) and to produce fluorophores with large Stokes shifts. Approximately half of the compounds studied to date involve ESIPT to nitrogen but there has been no real attempt at a coherent study of ESIPT to nitrogen.
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Fritsche, Bozaru Ramona Catalina. "o-Aminobenzophenones as Starting Material for New Dyes." [S.l. : s.n.], 2008. http://nbn-resolving.de/urn:nbn:de:bsz:352-opus-70293.

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Grasel, Fábio dos Santos. "Síntese, caracterização e estudo fotofísico de novos derivados triazínil-benzazólicos fluorescentes por ESIPT." reponame:Biblioteca Digital de Teses e Dissertações da UFRGS, 2009. http://hdl.handle.net/10183/16774.

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Neste trabalho é apresentado a síntese, caracterização e estudo fotofísico de novos derivados triazinil-benzazólicos fluorescentes por transferência protônica intramolecular no estado excitado (ESIPT). Trata-se da síntese do cloreto cianúrico com diferentes 2-(2'-hidroxifenil)benzazóis, dois grupos bastante atrativos do ponto de vista sintético e tecnológico. O cloreto cianúrico devido a sua versatilidade sintética e os 2-(2'- hidroxifenil)benzazóis por apresentarem propriedades fotofísicas muito interessantes, como uma intensa emissão de fluorescência com um grande deslocamento de Stokes. Est
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Nunes, Adan de Carvalho. "Síntese e estudo fotofísico de novas cianinas conjugadas com heterociclos fotoativos por esipt." reponame:Biblioteca Digital de Teses e Dissertações da UFRGS, 2016. http://hdl.handle.net/10183/134180.

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O objetivo deste trabalho foi sintetizar novas cianinas contendo grupos aceptores de elétrons que promovam tanto o aumento da conjugação do sistema π, bem como o aumento do deslocamento de Stokes das cianinas que, em geral, são pequenos, característica que limita as suas aplicações como sensores ópticos. Assim, foi realizada a síntese de três novas cianinas obtidas pela reação de um intermediário sal de imínio, formado via reação de Vilsmeier-Haack-Arnold, com três diferentes derivados do tipo 2-(5’-amino-2’-hidroxifenil)benzazólicos. Os rendimentos foram na faixa de 66-75 %, sendo a caracteri
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Zhang, Wanying. "Comprehensive Study on Fluorescent ESIPT Liquid Crystal Materials and the Potential for Optoelectronic Applications." Doctoral thesis, Kyoto University, 2021. http://hdl.handle.net/2433/263621.

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Munch, Maxime. "Synthèse et étude de fluorophores organiques pour la détection de maladies neurodégénératives." Thesis, Strasbourg, 2018. http://www.theses.fr/2018STRAF031.

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Ces travaux de thèse concernent la synthèse et l’étude des propriétés optiques de fluorophores organiques appliqués à la détection de deux biomarqueurs de la maladie d’Alzheimer : la protéine kinase C (PKC) et les fibrilles de peptides amyloïdes Aβ42. La détection de la PKC est réalisée à l’aide de dyades comprenant un émetteur de type boradiazaindacène (BODIPY) relié de manière covalente à un inhibiteur de cette enzyme. Ces composés obtenus via une synthèse multi-étape présentent des coefficients d’absorption molaires et des rendements quantiques de fluorescence en solution importants. Ces so
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Abella, Carlos Alberto Miranda. "Síntese de novas bases de tröger, fluorescentes via transferência protônica intramolecular no estado excitado (ESIPT)." reponame:Biblioteca Digital de Teses e Dissertações da UFRGS, 2003. http://hdl.handle.net/10183/3147.

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Neste trabalho, realizou-se a síntese e a caracterização de quatro novas bases de Tröger. Estes compostos pertencem à classe de heterociclos 2-hidroxifenibenzazóis, que caracterizam-se por apresentar uma forte emissão de fluorescência, devido à reação de transferência protônica intramolecular no estado excitado -ESIPT- por eles sofrrida quando excitados por luz ultravioleta. Os heterociclos sintetizadosapesentam ligações de hidrogênio intramolecular entrte o nitrogênio azólico e a hidroxila fenólica e um granded deslocamento de Stokes, características tíicas de compostos que sofrem a ESIPT. As
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Weragoda, Geethika K. "Excited state intramolecular proton transfer (ESIPT) and trans-cis isomerization on the triplet excited states." University of Cincinnati / OhioLINK, 2015. http://rave.ohiolink.edu/etdc/view?acc_num=ucin1439296134.

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Nano, Adela. "Towards optical memories : switchable optical systems for electron and energy transfer processes." Thesis, Strasbourg, 2015. http://www.theses.fr/2015STRAF011/document.

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Le travail de cette thèse de doctorat est axé sur le design, la synthèse et la caractérisation de systèmes moléculaires organiques et organométalliques luminescents dans le but de déclencher des processus de transfert photoinduit d’électron (PeT) ou d’énergie (EET) pour des applications dans les dispositifs optiques ou électroniques. Nous nous sommes d’abord intéressés aux molécules de type push-pull car elless’avèrent être des modèles intéressants pour l’étude du PeT. Nos systèmes sont construits autour de BτDIPY qui sert d’espaceur entre le donneur d’électron (julolidine ou triazatruxène) et
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Books on the topic "ESIPT"

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Umoetuk, Okon U. Ndon esit urua: Eket. Robertou Communications, 2004.

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Heijnen, W. J. Case studies of the Second European Symposium on Penetration Testing, ESOPT II. Delft Soil Mechanics Laboratory, 1985.

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Zambia Education Sector Investment Programme, ed. Investing in our people: Integrated Education Sector Investment Programme (ESIP) : policy framework. [Ministry of Education], 1996.

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International Conference on Environmental Science and Information Application Technology (2009 Wuhan, China). ESIAT 2009: 2009 International Conference on Environmental Science and Information Application Technology : proceedings, 4-5 July 2009, Wuhan, China. IEEE Computer Society, 2009.

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International Conference on Environmental Science and Information Application Technology (2009 Wuhan, China). ESIAT 2009: 2009 International Conference on Environmental Science and Information Application Technology : proceedings, 4-5 July 2009, Wuhan, China. IEEE Computer Society, 2009.

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Kaya, Nusret. Evrensel Esit - Kuyruklu Canli. Abis Yayinlari, 2010.

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Duval, Stephanie. Kizlar ve Oglanlar Esit Midir? Dinozor Çocuk, 2020.

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Brenifier, Oscar. Filozof Cocuk - Hepimiz Esit Miyiz? Tudem Yayinlari, 2015.

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Kaya, Nusret. Evrensel Esit Kuyruklu Canli: 4. Abis Yayinlari, 2018.

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Kolektif. OSS Esit Agirlik Soru Bankasi. Boyut Yayin Grubu, 2015.

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Book chapters on the topic "ESIPT"

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Mutai, Toshiki. "Luminescent Crystal–Control of Excited-State Intramolecular Proton Transfer (ESIPT) Luminescence Through Polymorphism." In Advances in Organic Crystal Chemistry. Springer Singapore, 2020. http://dx.doi.org/10.1007/978-981-15-5085-0_14.

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Shvadchak, Volodymyr V., Lisandro J. Falomir-Lockhart, Dmytro A. Yushchenko, and Thomas M. Jovin. "Interactions of α-Synuclein with Lipids and Artificial Membranes Monitored by ESIPT Probes." In Lipids and Cellular Membranes in Amyloid Diseases. Wiley-VCH Verlag GmbH & Co. KGaA, 2011. http://dx.doi.org/10.1002/9783527634323.ch1.

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Mitra, Sivaprasad. "Competitive ESIPT in o -Hydroxy Carbonyl Compounds: Perturbation through Solvent Modulation and Internal Torsion." In Hydrogen Bonding and Transfer in the Excited State. John Wiley & Sons, Ltd, 2010. http://dx.doi.org/10.1002/9780470669143.ch29.

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Nayak, Manoja Kumar, and Prasanta Kumar Swain. "ESIT: An Enhanced Lightweight Algorithm for Secure Internet of Things." In IoT and Analytics for Sensor Networks. Springer Singapore, 2021. http://dx.doi.org/10.1007/978-981-16-2919-8_10.

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Uahengo, Veikko. "The ESIPT-Steered Molecular Chameleon for Cations and Anions Based on Alizarin and Alizarin-S: A Comparative study." In Recent Advances in Chemical Kinetics [Working Title]. IntechOpen, 2022. http://dx.doi.org/10.5772/intechopen.103829.

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Chemosensing properties of Alizarin (A3) and Alizarin S (AS3) towards anions and cations in acetonitrile are reported. The absorption and fluorescence properties of the two molecular entities were investigated in CH3CN. Based on the excited state intermolecular proton transfer system (ESIPT), the probes were able to collectively discriminate specific cations and anions via colorimetric observations and spectrometric activities. The investigation revealed that A3 was selective to Cu2+, Fe3+, and Fe2+, compared to Cu2+, Zn2+, Fe3+, and Ni2+ for AS3. The disagreement in spectral responses were as
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Aaliya Shehzadi, Syeda, and Mustaghees Ur Rehman. "Carbazole-Based Schiff Bases: Structural Insights and Applications toward Metal Ion Detection." In Schiff Bases - Recent Developments and Application Areas [Working Title]. IntechOpen, 2025. https://doi.org/10.5772/intechopen.1011144.

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Carbazole-based Schiff bases have emerged as versatile chemosensors for detecting toxic and essential metal ions, addressing critical environmental and health concerns arising from metal pollution. This chapter explores their structural design, emphasizing the integration of the electron-rich carbazole core with imine (‒C=N‒) functionalities, which enhance π-conjugation, thermal stability, and selective metal coordination. Detection of transition metal ions such as Fe3+, Cr3+, Al3+, and Cu2+ has been successfully achieved using carbazole-based Schiff bases with a detection limit up to nanomola
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Shinde, Suvidha, and Nagaiyan Sekar. "4 Comparative studies of excited state intramolecular proton transfer (ESIPT) and azohydrazone tautomerism in naphthalene-based fluorescent acid azo dyes by computational study." In Computational Chemistry. De Gruyter, 2021. http://dx.doi.org/10.1515/9783110682045-004.

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Stol, Marten. "Esip tabal in Agriculture." In dNisaba za3-mi2. Zaphon, 2021. http://dx.doi.org/10.2307/jj.18654661.25.

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Kédia, Marianne. "9. Prédicteurs de développement d’un ESPT." In L'Aide-mémoire de psychotraumatologie. Dunod, 2013. http://dx.doi.org/10.3917/dunod.segui.2013.01.0072.

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Ducrocq, François, and Guillaume Vaiva. "20. Confrontation traumatique, stress aigu et ESPT." In Les troubles anxieux. Lavoisier, 2014. http://dx.doi.org/10.3917/lav.boule.2014.01.0219.

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Conference papers on the topic "ESIPT"

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Park, Soo Young, and Sehoon Kim. "Molecular photonics materials with excited-state intramolecular proton transfer (ESIPT) activity." In Integrated Optoelectronics Devices, edited by James G. Grote and Toshikuni Kaino. SPIE, 2003. http://dx.doi.org/10.1117/12.485821.

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Affeldt, Ricardo F., Fabiano da S. Santos, Natália G. Medeiros, and Fabiano S. Rodembusch. "New ESIPT fluorescent aldehydes as building blocks for organic photoactive compounds." In 15th Brazilian Meeting on Organic Synthesis. Editora Edgard Blücher, 2013. http://dx.doi.org/10.5151/chempro-15bmos-bmos2013_201391518231.

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Steinbacher, Andreas, Pramod Kumar Verma, Federico Koch, Patrick Nuernberger та Tobias Brixner. "Exploring the Ultrafast Excited-State Intramolecular Proton Transfer (ESIPT) of β-Diketones in the deep-UV". У International Conference on Ultrafast Phenomena. OSA, 2016. http://dx.doi.org/10.1364/up.2016.uth4a.13.

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Kim, Jun Young, Wen Hu, Dilip Sarkar, and Sanjay Jha. "ESIoT." In WiSec '17: 10th ACM Conference on Security & Privacy in Wireless and Mobile Networks. ACM, 2017. http://dx.doi.org/10.1145/3098243.3098252.

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"esIoT-2012 reviewers." In 2012 Sixth International Conference on Innovative Mobile and Internet Services in Ubiquitous Computing (IMIS). IEEE, 2012. http://dx.doi.org/10.1109/imis.2012.180.

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"esIoT-2013 Reviewers." In 2013 Seventh International Conference on Innovative Mobile and Internet Services in Ubiquitous Computing (IMIS). IEEE, 2013. http://dx.doi.org/10.1109/imis.2013.168.

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"esIoT 2015 Reviewers." In 2015 9th International Conference on Innovative Mobile and Internet Services in Ubiquitous Computing (IMIS). IEEE, 2015. http://dx.doi.org/10.1109/imis.2015.108.

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"esIoT 2016 Reviewers." In 2016 10th International Conference on Innovative Mobile and Internet Services in Ubiquitous Computing (IMIS). IEEE, 2016. http://dx.doi.org/10.1109/imis.2016.20.

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"IMIS esIoT Reviewers." In 2014 Eighth International Conference on Innovative Mobile and Internet Services in Ubiquitous Computing (IMIS). IEEE, 2014. http://dx.doi.org/10.1109/imis.2014.116.

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Tran-Thi, T.-H., C. Prayer, T. Gustavsson, and S. Pommeret. "Primary Ultrafast Events in the Proton Transfer Reaction from Excited Pyranine to Water." In International Conference on Ultrafast Phenomena. Optica Publishing Group, 1996. http://dx.doi.org/10.1364/up.1996.fe.21.

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Pyranine or tsPyOH (8-hydroxy-1,3,6-trisulfonated pyrene) belongs to the family of aromatic alcohols which have been widely studied since Förster1 and Weller2. These molecules are known to undergo proton transfer (PT) both in the ground (GSPT) and singlet excited (ESPT) states, with Ka jump of seven orders of magnitude between the two processes. The dynamics of pyranine ESPT has been studied in various polar media 3-5. In all cases, ESPT was probed by observing the disappearance of the protonated species and the formation of the deprotonated form, using time resolved fluorescence techniques wi
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