Academic literature on the topic 'Ethers'

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Journal articles on the topic "Ethers"

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Kim, Yong-Hak, and Karl-Heinrich Engesser. "Degradation of Alkyl Ethers, Aralkyl Ethers, and Dibenzyl Ether by Rhodococcus sp. Strain DEE5151, Isolated from Diethyl Ether-Containing Enrichment Cultures." Applied and Environmental Microbiology 70, no. 7 (2004): 4398–401. http://dx.doi.org/10.1128/aem.70.7.4398-4401.2004.

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ABSTRACT Twenty strains isolated from sewage sludge were found to degrade various ethers, including alkyl ethers, aralkyl ethers, and dibenzyl ether. In Rhodococcus strain DEE5151, induction of ether degradation needed substrates exhibiting at least one unsubstituted Cα-methylene moiety as the main structural prerequisite. The cleavage reaction observed with anisole, phenetole, and dibenzyl ether indicates that the initial oxidation occurs at such respective Cα positions. Diethyl ether-induced strain DEE5151 degraded dibenzyl ether via intermediately accumulated benzoic acid. Phenetole seems t
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Zmysłowski, Adam, Jerzy Sitkowski, Katarzyna Bus, Katarzyna Michalska та Arkadiusz Szterk. "Synthesis of Oxidized 3β,3′β-Disteryl Ethers and Search after High-Temperature Treatment of Sterol-Rich Samples". International Journal of Molecular Sciences 22, № 19 (2021): 10421. http://dx.doi.org/10.3390/ijms221910421.

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It was proven that sterols subjected to high-temperature treatment can be concatenated, which results in polymeric structures, e.g., 3β,3′β-disteryl ethers. However, it was also proven that due to increased temperature in oxygen-containing conditions, sterols can undergo various oxidation reactions. This study aimed to prove the existence and perform quantitative analysis of oxidized 3β,3′β-disteryl ethers, which could form during high-temperature treatment of sterol-rich samples. Samples were heated at 180, 200 and 220 °C for 0.5 to 4 h. Quantitative analyses of the oxidized 3β,3′β-disteryl e
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Dachavaram, Soma Shekar, Narsimha R. Penthala, Julie L. Calahan, Eric J. Munson, and Peter A. Crooks. "Highly sulphated cellulose: a versatile, reusable and selective desilylating agent for deprotection of alcoholic TBDMS ethers." Organic & Biomolecular Chemistry 16, no. 33 (2018): 6057–62. http://dx.doi.org/10.1039/c8ob01438h.

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A mild, effcient protocol was developed for the deprotection of alcoholic TBDMS ethers using highly sulphated HS-cellulose sulphate catalyst, which selectively cleaves alcoholic TBDMS ethers in bis-TBDMS ethers containing both alcoholic and phenolic TBDMS ether moieties.
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Palanychamy, Prakas, Steven Lim, Yeow Hong Yap, and Loong Kong Leong. "Critical Review of the Various Reaction Mechanisms for Glycerol Etherification." Catalysts 12, no. 11 (2022): 1487. http://dx.doi.org/10.3390/catal12111487.

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This review provides in-depth coverage of numerous mechanisms available for the etherification process of glycerol, including alcohol solvent, olefin solvent and solvent-free routes along with products that are formed at various stages of the reaction. Mono tert-butyl glycerol ether (MTBG), di tert-butyl glycerol ether (DTBG), and tri tert-butyl glycerol ether (TTBG) are the three general ether compounds obtained through tert-butyl alcohol (TBA) etherification. Glycerol etherification with n-butanol results in the formation of glycerol ether products that are linked to the substituted butyl gr
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Modrzakowski, Malcolm C., and William R. Finnerty. "Intermediary metabolism of Acinetobacter grown on dialkyl ethers." Canadian Journal of Microbiology 35, no. 11 (1989): 1031–36. http://dx.doi.org/10.1139/m89-171.

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The microbial dissimilation of long-chain dialkyl ethers by Acinetobacter sp. H01-N involved a terminal methyl group oxidation of the dialkyl ether substrates, resulting in the formation of ether oxygen containing fatty acids of corresponding chain length. An internal carbon–carbon scission of the dialkyl ethers resulted in the formation of end-product ether fatty acids and corresponding dicarboxylic acids. Cellular carbon and energy were derived from the subsequent metabolism of the dicarboxylic acids. Dicarboxylic acid oxidation, activation, and identification of cellular dicarboxylic acids
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Ragauskas, Arthur J., and J. B. Stothers. "13C magnetic resonance studies. 120. The Simmons–Smith reaction with some silyl enol ethers. Unusual ring expansions of some norcamphorsti." Canadian Journal of Chemistry 63, no. 11 (1985): 2969–74. http://dx.doi.org/10.1139/v85-492.

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Unexpected difficulties with Simmons–Smith cyclopropanation of the trimethylsilyl enol ether of exo-tricyclo[3.2.1.02,4]-octan-6-one led to a reexamination of this reaction with the parent norcamphor derivative which under "concentrated" conditions gave ring-expanded allylic ethers in low yield. With the tert-butyldimethylsilyl ethers, however, the allylic product is formed in high yield in the norcamphor and exo-trimethylenenorcamphor (tricyclo[5.2.1.02,6]decan-8-one) systems. The tert-butyldimethylsilyl enol ethers of bicyclo[3.2.1]octan-6-one and nopinone do not undergo ring expansion under
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Sireesha, Reddymasu, Reddymasu Sreenivasulu, Choragudi Chandrasekhar, and Mannam Subba Rao. "A Facile, Efficient and Selective Deprotection of P - Methoxy Benzyl Ethers Using Zinc (II) Trifluoromethanesulfonate." Letters in Organic Chemistry 16, no. 12 (2019): 955–58. http://dx.doi.org/10.2174/1570178616666190222151934.

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: Deprotection is significant and conducted over mild reaction conditions, in order to restrict any more side reactions with sensitive functional groups as well as racemization or epimerization of stereo center because the protective groups are often cleaved at last stage in the synthesis. P - Methoxy benzyl (PMB) ether appears unique due to its easy introduction and removal than the other benzyl ether protecting groups. A facile, efficient and highly selective cleavage of P - methoxy benzyl ethers was reported by using 20 mole% Zinc (II) Trifluoromethanesulfonate at room temperature in aceton
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Mireles, Raul, Joaquin Ramirez-Ramirez, Miguel Alcalde, and Marcela Ayala. "Ether Oxidation by an Evolved Fungal Heme-Peroxygenase: Insights into Substrate Recognition and Reactivity." Journal of Fungi 7, no. 8 (2021): 608. http://dx.doi.org/10.3390/jof7080608.

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Ethers can be found in the environment as structural, active or even pollutant molecules, although their degradation is not efficient under environmental conditions. Fungal unspecific heme-peroxygenases (UPO were reported to degrade low-molecular-weight ethers through an H2O2-dependent oxidative cleavage mechanism. Here, we report the oxidation of a series of structurally related aromatic ethers, catalyzed by a laboratory-evolved UPO (PaDa-I) aimed at elucidating the factors influencing this unusual biochemical reaction. Although some of the studied ethers were substrates of the enzyme, they w
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Ghosh, Arun, Anthony Tomaine, and Kelsey Cantwell. "Lewis Acid Mediated Cyclizations: Diastereoselective Synthesis of Six- to Eight-Membered Substituted Cyclic Ethers." Synthesis 49, no. 18 (2017): 4229–46. http://dx.doi.org/10.1055/s-0036-1589054.

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Cyclic ethers are widely abundant in natural products. Cyclic ether templates are also utilized in drug design and medicinal chemistry. Although the synthetic processes for this class of compounds have been studied extensively with respect to five- and six-membered rings, medium-sized cyclic ethers are synthetically more challenging due to a variety of factors. Herein, we report our results on the Lewis acid catalyzed synthesis of medium-sized cyclic ethers in a diastereoselective manner.
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Verevkin, Sergey P., and Aleksandra A. Zhabina. "Platform Chemicals from Ethylene Glycol and Isobutene: Thermodynamics “Pays” for Biomass Valorisation and Acquires “Cashback”." Chemistry 5, no. 2 (2023): 1171–89. http://dx.doi.org/10.3390/chemistry5020079.

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Ethylene glycol (EG) produced from biomass is a promising candidate for several new applications. In this paper, EG derivatives such as mono- and di-tert-butyl ethers are considered. However, accurate thermodynamic data are essential to optimise the technology of the direct tert-butyl ether EG synthesis reaction or reverse process isobutene release. The aim of this work is to measure the vapour pressures and combustion energies for these ethers and determine the vaporisation enthalpies and enthalpies of formation from these measurements. Methods based on the First and Second Law of Thermodynam
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Dissertations / Theses on the topic "Ethers"

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Huang, Zilin. "Synthesis and Complexation Studies of Novel Functionalized Crown Ethers and Azacrown Ethers." Thesis, University of North Texas, 2006. https://digital.library.unt.edu/ark:/67531/metadc5593/.

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Novel cage-functionalized azacrown ethers, i.e. 51, 52, 53, 55, 57, 61 and 62, which have various crown cavity and different number of nitrogen atoms incorporated, have been prepared. X-ray structures of 53, 55 and 57 have been obtained for the study of the crown topological structure. The complexation properties of crown 51, 52, 57, 61 and 62 have been evaluated via alkali metal picrate extraction, silver picrate extraction and ESI-MS study. The novel cage-fuctionalized azacrown ethers generally exhibit high avidity and selectivity towards Ag+ versus alkali metal ions and some transition meta
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Welsh, Gwendolyn L. "Polybrominated diphenyl ethers." Cincinnati, Ohio : University of Cincinnati, 2008. http://rave.ohiolink.edu/etdc/view.cgi?acc_num=ucin1216928488.

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Thesis (M.S.)--University of Cincinnati, 2008.<br>Advisors: Jodi Shann PhD (Committee Chair), Brian Kinkle PhD (Committee Member), Anne Vonderheide PhD (Committee Member), Stacy Pfaller PhD (Committee Member) Title from electronic thesis title page (viewed Oct. 5, 2008). Includes abstract. Keywords: Brominated Flame Retardants; PBDE; GC-MS; Soil Sorption; Bioavailability; GC-ECD; Microbial Degradation Includes bibliographical references.
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Lousenberg, Robert Daniel. "Synthesis of trifluorovinyl ethers." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1997. http://www.collectionscanada.ca/obj/s4/f2/dsk2/ftp04/mq29227.pdf.

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Rico, Joseph G. "Directed lithiations of enol ethers : stereoselective synthesis and reactions of substituted enol ethers." Diss., Georgia Institute of Technology, 1987. http://hdl.handle.net/1853/27166.

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Yassin-Hussan, Saad. "Photolyse des ethers aromatiques halogenes : bromo phenetole, paradibromo phenetole, parabromo phenetole, parabromodiphenyl ether." Toulon, 1990. http://www.theses.fr/1990TOUL0004.

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Nous avons etudie la photolyse, par rayonnement ultra-violet, de quatre ethers halogenes aromatiques (bromophenetole, parabromophenetole et parabromobiphenylether) dans l'acenotrile, l'eau et dans les melanges eau-acetonitrile, eau-methanol, en presence ou en absence de peroxyde d'hydrogene, compose jouant le role de photooxydant. L'irradiation ultra-violette de ces composes genere de nombreux photoproduits qui ont ete identifies, apres extraction liquide-liquide, par analyse en chromatographie liquide et gazeuse et c. P. V. Couplee a la spectrometrie de masse. Les cinetiques de photodecomposi
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Starkey, Darren Paul. "The tropospheric oxidation of ethers." Thesis, University of Hull, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.322331.

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Jones, D. "The synthesis of aryl ethers." Thesis, Swansea University, 1994. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.637726.

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The synthesis of biaryl ethers is a process of importance in many fields within the chemical industry. Generally, the Ullmann ether synthesis is employed, though improvements in the general method have not been commonplace since the inception of the process at the turn of the century. By reinvestigating the parameters present, it was found that the use of cuprous iodide in a solventless reaction led to high yields of diaryl ethers. Further improvements were developed by the implementation of ultrasound in conjunction with lower reaction temperatures, with similarly high yields being afforded.
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Vile, Sadie. "Alpha-sulphonyl ethers in synthesis." Thesis, Imperial College London, 1990. http://hdl.handle.net/10044/1/46595.

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Wild, Carl. "Trifluoroethyl enol ethers, dienol ethers, and acetals: an investigation of their preparations, reactivities, and synthetic applications." Diss., Virginia Polytechnic Institute and State University, 1988. http://hdl.handle.net/10919/54459.

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The major portion of this work details our investigation of trifluoroethoxy (TFE) substituted compounds with particular emphasis given to their preparation and possible applications. The three types of compounds studied were trifluoroethoxy substituted ketals, enol ethers, and dienol ethers. The ketal and enol ether work involved developing methodology for the large scale preparation of these structures as well as studies detailing their behavior. For the TFE ketals, preparation involved an acid-catalyzed alcohol exchange reaction. Applications included their use as non-complexing/acid-stable
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Landry, Denis Joseph Carleton University Dissertation Chemistry. "Approaches to the synthesis and sterochemical analysis of aza crown ethers." Ottawa, 1989.

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Books on the topic "Ethers"

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Forsyth, C. J. Ethers. Thieme, 2008.

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Illing, H. P. A. Glycol ethers. HMSO, 1985.

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United States. Agency for Toxic Substances and Disease Registry. Division of Toxicology. Polybrominated diphenyl ethers. Agency for Toxic Substances Disease Registry, Division of Toxicology, Dept. of Health and Human Services, Public Health Service, 2004.

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Lousenberg, Robert Daniel. Synthesis of trifluorovinyl ethers. National Library of Canada = Bibliothèque nationale du Canada, 1999.

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E, Weber, Patai Saul, and Rappoport Zvi, eds. Crown ethers and analogs. Wiley, 1989.

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Weber, Edwin, John L. Toner, Israel Goldberg, et al., eds. Crown Ethers and Analogs (1989). John Wiley & Sons, Inc., 1989. http://dx.doi.org/10.1002/9780470772232.

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Hall, K. R., and K. N. Marsh, eds. Densities of Esters and Ethers. Springer-Verlag, 2001. http://dx.doi.org/10.1007/b76770.

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Michio, Hiraoka, ed. Crown ethers and analogous compounds. Elsevier, 1992.

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Robinson, Peter Mark. Crown ethers incorporating stable carbocations. University of Manchester, 1994.

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Michio, Hiraoka, ed. Crown ethers and analogous components. Elsevier, 1992.

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Book chapters on the topic "Ethers"

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"Ethers." In Lead Optimization for Medicinal Chemists. Wiley-VCH Verlag GmbH & Co. KGaA, 2013. http://dx.doi.org/10.1002/9783527645640.ch16.

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Graedel, T. E., Donald T. Hawkins, and Larry D. Claxton. "Ethers." In Atmospheric Chemical Compounds. Elsevier, 1986. http://dx.doi.org/10.1016/b978-0-08-091842-6.50007-3.

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Kitson, Fulton G., Barbara S. Larsen, and Charles N. McEwen. "Ethers." In Gas Chromatography and Mass Spectrometry. Elsevier, 1996. http://dx.doi.org/10.1016/b978-012483385-2/50014-2.

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"Ethers." In A Comprehensive Guide to the Hazardous Properties of Chemical Substances. John Wiley & Sons, Inc., 2006. http://dx.doi.org/10.1002/9780470134955.ch18.

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"Ethers." In Lectures on Organic Chemistry. IMPERIAL COLLEGE PRESS, 1997. http://dx.doi.org/10.1142/9781848160903_0009.

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Hartung, J. "Ethers." In Chlorine, Bromine, and Iodine. Georg Thieme Verlag KG, 2007. http://dx.doi.org/10.1055/sos-sd-035-00024.

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Wypych, Anna, and George Wypych. "Ethers." In Databook of Solvents. Elsevier, 2024. http://dx.doi.org/10.1016/b978-1-77467-044-6.50015-1.

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"Ethers." In Encyclopedia of Liquid Fuels. De Gruyter, 2022. http://dx.doi.org/10.1515/9783110750287-018.

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DeRosa, Thomas F. "Ethers." In Advances in Synthetic Organic Chemistry and Methods Reported in US Patents. Elsevier, 2006. http://dx.doi.org/10.1016/b978-008044474-1/50033-5.

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"Ethers." In Methane. Elsevier, 1987. http://dx.doi.org/10.1016/b978-0-08-029200-7.50028-x.

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Conference papers on the topic "Ethers"

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McCollum, David K. "Protecting Electronic Connectors with Polyphenyl Ether Connector Lubricants." In CORROSION 1989. NACE International, 1989. https://doi.org/10.5006/c1989-89331.

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Abstract Polyphenyl ethers have been used for nearly twenty years as lubricants with long life, high reliability electronic connectors. Initially their use was for the purpose of preventing metal wear. Since then their effectiveness in preventing connector corrosion has been studied and reported. This paper is a compilation of questions frequently asked on the subject of applying these lubricants to connectors. The unique physical properties of these lubricants which help prevent corrosion are discussed in detail. Other topics include material handling, solvents, applications, and film charact
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Storfer, Stanley J., and Stephen A. Yuhas. "Mechanism of Blister Formation in Organic Coatings; Effect of Coating Solvents." In CORROSION 1987. NACE International, 1987. https://doi.org/10.5006/c1987-87232.

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Abstract It is well known that small amounts of solvents are retained in paint films for long periods of time. This is especially true of chemically- cured coatings, such as epoxy and urethane maintenance paints. Once chemical curing has occurred, solvents which have not been released from the film remain trapped in the coating, and may facilitate blistering of the coating upon water exposure, subsequently leading to corrosion of the steel substrate. The principal mechanisms for blistering were considered with respect to whether they could be influenced by solvents, adversely or beneficially.
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Narkevich, Darya, and Alena Hlushen. "Destructive activity of microorganisms in relation to glycol ethers." In 5th International Scientific Conference on Microbial Biotechnology. Institute of Microbiology and Biotechnology, Republic of Moldova, 2022. http://dx.doi.org/10.52757/imb22.25.

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Glycol ethers, especially 2-butoxyethanol (BE) and 2-ethoxyethanol (EE), have low human toxicity and are widely used as components of paints and solvents, inks, detergents, liquid soaps, hydraulic fluids, etc. [1]. The high ability of glycol ethers to dissolve in water due to their amphiphilic structure ensures their ingress and accumulation in aqueous systems. Currently, there is limited literature data on the bacterial degradation of these compounds, which makes this an urgent problem to study [2, 3]. Seventeen cultures were previously selected which showed the ability to utilize glycol este
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El-Azhary, A. A., N. Al-Jallal, A. Al-Kahtani, N. Al-Badri, K. Al-Farhan, and M. Al-Qunaibit. "Structure of crown ethers." In THEORY AND APPLICATIONS IN COMPUTATIONAL CHEMISTRY: THE FIRST DECADE OF THE SECOND MILLENNIUM: International Congress TACC-2012. AIP, 2012. http://dx.doi.org/10.1063/1.4730663.

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Lys, Leonard, Arthur Micoulet, and Maria Potop-Butucaru. "Atomic Swapping Bitcoins and Ethers." In 2019 38th Symposium on Reliable Distributed Systems (SRDS). IEEE, 2019. http://dx.doi.org/10.1109/srds47363.2019.00054.

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Leppard, William R. "The Autoignition Chemistries of Octane-Enhancing Ethers and Cyclic Ethers: A Motored Engine Study." In International Fuels & Lubricants Meeting & Exposition. SAE International, 1991. http://dx.doi.org/10.4271/912313.

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Neill, W. Stuart, Wallace L. Chippior, Ken Mitchell, et al. "The Influence of High Cetane Blending Components on Emissions From a Heavy-Duty Diesel Engine With EGR." In ASME 2004 Internal Combustion Engine Division Fall Technical Conference. ASMEDC, 2004. http://dx.doi.org/10.1115/icef2004-0887.

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The exhaust emissions form a single-cylinder version of a heavy-duty diesel engine with exhaust gas recirculation (EGR) were measured with eight high-cetane components blended into an ultra-low sulphur diesel base fuel. the blending components evaluated were conventional nitrate and peroxide cetane improver additives, paraffins from two sources, three ethers, and soy methyl ester. The blending components were used to increase the cetane number of a base fuel by ten numbers, from 44 to 54. Exhaust emissions were measured using the AVL eight-mode steady-state test procedure. PM and NOx emissions
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Vazirova, Leyla, and Govhar Abbasova. "Sorbents Based on Iron Oxide Nanoparticles for Release of Tetracyclines for Water Treatment." In 2nd International Scientific-Practical Conference "Machine Building and Energy: New Concepts and Technologies". Trans Tech Publications Ltd, 2024. http://dx.doi.org/10.4028/p-sh9pfn.

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The aim of the research was to establish and produce unfamiliar magnetic absorbents based on a commonly accessible specimen containing crown ethers via iron nanoparticles (magnetite), investigation their structural, magnetic, and absorbance properties, and analyze the possible utilization of these sorbents for the sorption and accumulation of tetracyclines. New crown complexes with biological prop ethers have been created, and the structure of the produced crown complexes has been determined using elemental analysis data from studies of these samples' IR, mass, and NMR spectra. According to th
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Atwood, David H., and Gus Ferrara. "Vapor Lock Studies for Gasolines with Ethers." In General, Corporate & Regional Aviation Meeting & Exposition. SAE International, 1993. http://dx.doi.org/10.4271/931233.

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Patil, Jagdish U., Pramod Nagraj Patil, and Nilesh S. Pawar. "Synthesis and Antibacterial Activity of Thymyl Ethers." In ECSOC-25. MDPI, 2021. http://dx.doi.org/10.3390/ecsoc-25-11747.

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Reports on the topic "Ethers"

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Bartscherer, K. A., J. J. de Pablo, M. C. Bonnin, and J. M. Prausnitz. Purification of aqueous cellulose ethers. Office of Scientific and Technical Information (OSTI), 1990. http://dx.doi.org/10.2172/6084196.

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Klier, K., R. G. Herman, M. A. Johansson, and O. C. Feeley. High octane ethers from synthesis gas-derived alcohols. [Methyl isobutyl ether(MIBE) and methyl tertiary butyl ether(MTBE)]. Office of Scientific and Technical Information (OSTI), 1993. http://dx.doi.org/10.2172/6698177.

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Bartsch, R. Metal ion complexation by ionizable crown ethers. Office of Scientific and Technical Information (OSTI), 1989. http://dx.doi.org/10.2172/5483625.

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Bartsch, R. Metal ion complexation by ionizable crown ethers. Office of Scientific and Technical Information (OSTI), 1990. http://dx.doi.org/10.2172/6737356.

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Cochoy, Robert E., Raymond R. McGuire, and Scott A. Shackelford. One-Step Synthesis of Polynitroaliphatic Acetals and Ethers. Defense Technical Information Center, 1988. http://dx.doi.org/10.21236/ada203510.

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Klier, K., R. G. Herman, S. DeTavernier, M. Johannson, M. Kieke, and R. D. Bastian. High octane ethers from synthesis gas-derived alcohols. Office of Scientific and Technical Information (OSTI), 1991. http://dx.doi.org/10.2172/6025861.

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Klier, K., R. G. Herman, O. C. Feeley, and M. A. Johansson. High octane ethers from synthesis gas-derived alcohols. Office of Scientific and Technical Information (OSTI), 1992. http://dx.doi.org/10.2172/6873548.

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Kamil Klier, Richard G. Herman, Heock-Hoi Kwon, et al. CATALYSTS FOR HIGH CETANE ETHERS AS DIESEL FUELS. Office of Scientific and Technical Information (OSTI), 2003. http://dx.doi.org/10.2172/823645.

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Kamil Klier, Richard G. Herman, James G.C. Shen, and Qisheng Ma. CATALYSTS FOR HIGH CETANE ETHERS AS DIESEL FUELS. Office of Scientific and Technical Information (OSTI), 2000. http://dx.doi.org/10.2172/823646.

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Klier, K., R. G. Herman, O. C. Feeley, and M. A. Johansson. High octane ethers from synthesis gas-derived alcohols. Office of Scientific and Technical Information (OSTI), 1992. http://dx.doi.org/10.2172/6557005.

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