To see the other types of publications on this topic, follow the link: Ethynyl ketone.

Journal articles on the topic 'Ethynyl ketone'

Create a spot-on reference in APA, MLA, Chicago, Harvard, and other styles

Select a source type:

Consult the top 50 journal articles for your research on the topic 'Ethynyl ketone.'

Next to every source in the list of references, there is an 'Add to bibliography' button. Press on it, and we will generate automatically the bibliographic reference to the chosen work in the citation style you need: APA, MLA, Harvard, Chicago, Vancouver, etc.

You can also download the full text of the academic publication as pdf and read online its abstract whenever available in the metadata.

Browse journal articles on a wide variety of disciplines and organise your bibliography correctly.

1

Yavari, Issa, Abdolali Alizadeh, and Mohammad Anary-Abbasinejad. "Stable 1,3-Diionic Organophosphorus Compounds Derived from Ethynyl Phenyl Ketone." Phosphorus, Sulfur, and Silicon and the Related Elements 177, no. 1 (2002): 81–86. http://dx.doi.org/10.1080/10426500210236.

Full text
APA, Harvard, Vancouver, ISO, and other styles
2

Sun, Yin-wei, Qin Xu, and Min Shi. "Gold-catalyzed reaction of oxabicyclic alkenes with electron-deficient terminal alkynes to produce acrylate derivatives." Beilstein Journal of Organic Chemistry 9 (October 1, 2013): 1969–76. http://dx.doi.org/10.3762/bjoc.9.233.

Full text
Abstract:
Oxabicyclic alkenes can react with electron-deficient terminal alkynes in the presence of a gold catalyst under mild conditions, affording the corresponding addition products in moderate yields. When using alkynyl esters as substrates, the (Z)-acrylate derivatives are obtained. Using but-3-yn-2-one (ethynyl ketone) as a substrate, the corresponding addition product is obtained with (E)-configuration. The proposed mechanism of these reactions is also discussed.
APA, Harvard, Vancouver, ISO, and other styles
3

Wilbur, J. M., and B. A. Bonner. "Synthesis of hydrogen-terminated aliphatic bis(ethynyl ketone)s and aliphatic poly(enamine-ketone)s and poly(enonesulfide)s." Journal of Polymer Science Part A: Polymer Chemistry 28, no. 13 (1990): 3747–59. http://dx.doi.org/10.1002/pola.1990.080281318.

Full text
APA, Harvard, Vancouver, ISO, and other styles
4

TIWARI, R. K., A. K. SAXENA, and P. S. VENKATARAMANI. "ChemInform Abstract: Nucleophilic Addition to Aryl Ethynyl Ketone: Addition of Oxygen Containing Nucleophiles to Terephthaloyl Acetylene." ChemInform 28, no. 13 (2010): no. http://dx.doi.org/10.1002/chin.199713065.

Full text
APA, Harvard, Vancouver, ISO, and other styles
5

Warrier*, Pravith P., and Madhavi R. Badole. "Comparison Study for the Phytochemical Constituents of two Curcuma Species by GC-MS Technique." Oriental Journal Of Chemistry 39, no. 4 (2023): 954–62. http://dx.doi.org/10.13005/ojc/390418.

Full text
Abstract:
Curcuma, a major Zingiberaceae genus, contains approximately 110 species throughout the Asia-Pacific region. The present work aimed to study the two Indian curcuma species, Curcuma caesia Roxb. and Curcuma angustifolia Roxb., whose rhizomes are extracted using ultrasound-assisted extraction (UAE) with chloroform solvent. The extracts are subjected to phytochemical screening and analysed employing gas chromatography-mass spectrometry (GC-MS) procedures. UAE studies of these two Curcuma species' rhizomes using chloroform as a solvent have been conducted for the first time. The chloroform extract
APA, Harvard, Vancouver, ISO, and other styles
6

Yavari, Issa, Mohammad Anary-Abbasinejad, and Abdolali Alizadeh. "On the Reaction between Alkyl Isocyanides and Ethynyl Phenyl Ketone in the Presence of N,N′-Dimethylbarbituric Acid." Monatshefte f?r Chemie / Chemical Monthly 133, no. 9 (2002): 1221–24. http://dx.doi.org/10.1007/s007060200093.

Full text
APA, Harvard, Vancouver, ISO, and other styles
7

He, QinZheng, JinYan Wang, LiShuai Zong, Rui Liu, and XiGao Jian. "Soluble and crosslinkable poly(phthalazinone ether ketone)s with pendent terminal ethynyl groups: synthesis, characterization and click modification." Polymer International 64, no. 7 (2015): 875–83. http://dx.doi.org/10.1002/pi.4860.

Full text
APA, Harvard, Vancouver, ISO, and other styles
8

Yavari, Issa, Mohammad Anary-Abbasinejad, and Abdolali Alizadeh. "On the Reaction Between Alkyl Isocyanides and Ethynyl Phenyl Ketone in the Presence of N,N′-Dimethylbarbituric Acid." ChemInform 34, no. 1 (2003): no. http://dx.doi.org/10.1002/chin.200301154.

Full text
APA, Harvard, Vancouver, ISO, and other styles
9

Lee, Hyung-Jong, Myung-Hyun Lee, Min-Cheol Oh, Joo-Heon Ahn, and Seon Gyu Han. "Crosslinkable polymers for optical waveguide devices. II. Fluorinated ether ketone oligomers bearing ethynyl group at the chain end." Journal of Polymer Science Part A: Polymer Chemistry 37, no. 14 (1999): 2355–61. http://dx.doi.org/10.1002/(sici)1099-0518(19990715)37:14<2355::aid-pola9>3.0.co;2-9.

Full text
APA, Harvard, Vancouver, ISO, and other styles
10

Mukaiyama, Teruaki, Shigekazu Matsui, Koichi Homma, and Sh\={u} Kobayashi. "Regioselective Condensation of Ethynyl Vinyl Ketone or 2-Propynyl Ether Derivatives with Silyl Enol Ethers Catalyzed by Trityl Perchlorate." Bulletin of the Chemical Society of Japan 63, no. 9 (1990): 2687–90. http://dx.doi.org/10.1246/bcsj.63.2687.

Full text
APA, Harvard, Vancouver, ISO, and other styles
11

MUKAIYAMA, T., S. MATSUI, K. HOMMA, and S. KOBAYASHI. "ChemInform Abstract: Regioselective Condensation of Ethynyl Vinyl Ketone or 2-Propynyl Ether Derivatives with Silyl Enol Ethers Catalyzed by Trityl Perchlorate." ChemInform 22, no. 4 (2010): no. http://dx.doi.org/10.1002/chin.199104110.

Full text
APA, Harvard, Vancouver, ISO, and other styles
12

Giridhar Reddy, P., K. Ramesh, S. Shylaja, K. C. Rajanna, and S. Kandlikar. "Ru (III) Catalyzed Oxidation of Aliphatic Ketones by N-Bromosuccinimide in Aqueous Acetic Acid: A Kinetic Study." Scientific World Journal 2012 (2012): 1–7. http://dx.doi.org/10.1100/2012/456516.

Full text
Abstract:
Kinetics of Ru (III) catalyzed oxidation of aliphatic ketones such as acetone, ethyl methyl ketone, diethyl ketone, iso-butylmethyl ketone by N-bromosuccinimide in the presence of Hg(II) acetate have been studied in aqueous acid medium. The order of [N-bromosuccinimide] was found to be zero both in catalyzed as well as uncatalyzed reactions. However, the order of [ketone] changed from unity to a fractional one in the presence of Ru (III). On the basis of kinetic features, the probable mechanisms are discussed and individual rate parameters evaluated.
APA, Harvard, Vancouver, ISO, and other styles
13

Liu, Hsing-Jang, Waiseng Martin Feng, Jeung Bea Kim, and Eric N. C. Browne. "Lewis acid catalyzed Diels–Alder reactions of two useful dienyl phosphate esters." Canadian Journal of Chemistry 72, no. 10 (1994): 2163–75. http://dx.doi.org/10.1139/v94-275.

Full text
Abstract:
The Lewis acid catalyzed Diels–Alder reactions of dienyl phosphate esters 1 and 2 were examined. 2-Diethylphosphoryloxy-1,3-butadiene (1) was found to react with a variety of α,β-unsaturated carbonyl compounds under Lewis acid catalysis with excellent regioselectivity to give synthetically useful cyclohexene derivatives. The adducts were produced in accordance with the normal rules governing the Diels–Alder addition. In the presence of stannic chloride acyclic α,β-unsaturated ketones such as ethyl vinyl ketone and methyl vinyl ketone reacted rapidly with diene phosphate 1 to give exclusively t
APA, Harvard, Vancouver, ISO, and other styles
14

Chen, Chan Cheng, Tsung Han Han, Sheng Xiang Hong, and Der Jen Hsu. "Auto-Ignition Temperature Data for Selected Ketones." Advanced Materials Research 560-561 (August 2012): 145–51. http://dx.doi.org/10.4028/www.scientific.net/amr.560-561.145.

Full text
Abstract:
Auto-ignition temperature (AIT) is usually defined as the lowest temperature at which a substance will produce hot-flame ignition in air at atmospheric pressure without the aid of an external energy source such as spark or flame. Its principal applications include: defining the maximum acceptable surface temperature in a particular area, usually for electrical classification purpose, to prevent fire and explosion hazards; determining the possible hazardous consequence associated with leakage of flammable chemicals in risk assessment methods. Although AIT is indispensable for safely handling an
APA, Harvard, Vancouver, ISO, and other styles
15

Nakatani, Kazuhiko, Akimitsu Okamoto, Mikito Yamanuki, and Isao Saito. "Highly Efficient Synthesis of 2-Substituted 4H-Chromen-4-ones by means of F--Induced 6-Endo-Digonal Cyclization of o-(Silyloxy)phenyl Ethynyl Ketone Derivatives." Journal of Organic Chemistry 59, no. 16 (1994): 4360–61. http://dx.doi.org/10.1021/jo00095a003.

Full text
APA, Harvard, Vancouver, ISO, and other styles
16

Stephenson, W. Kirk, and Richard Fuchs. "Enthalpies of interaction of ketones with organic solvents." Canadian Journal of Chemistry 63, no. 2 (1985): 336–41. http://dx.doi.org/10.1139/v85-057.

Full text
Abstract:
Enthalpies of solution (ΔHS) of a series of ketones (acetone, 2-butanone, 2-heptanone, 2-nonanone, 5-nonanone, 2,2,4,4-tetramethyl-3-pentanone, cyclohexanone) and alkane model compounds (n-heptane, n-nonane, 2,2,4,4-tetramethylpentane, cyclohexane) have been determined in 17 organic solvents (n-heptane, cyclohexane, CCl4, α,α,α,-trifluorotoluene, 1,2-dichloroethane, triethylamine, butyl ether, ethyl acetate, DMF, DMSO, benzene, toluene, mesitylene, 1-octanol, methanol, t-butyl alcohol, 2,2,2-trifluoroethanol), and combined with heats of vaporization to give enthalpies of transfer from vapor to
APA, Harvard, Vancouver, ISO, and other styles
17

P., Ananthakrishna Nadar, and Renuga V. "Study of substituent effects in substituted dibenzal acetones." Journal of Indian Chemical Society Vol. 83, Dec 2006 (2006): 1219–22. https://doi.org/10.5281/zenodo.5833960.

Full text
Abstract:
Krishna Engineering College, Chennai-600 134, India Department of Chemistry, P.S.G.R. Krishnammal College for Women, Peelamedu, Coimbatore-641 004, Tamilnadu, india E-mail : chem_renu@yahoo.co.in <em>Manuscript received 4 July 2005, accepted 16 October 2006</em> The present work involves a detailed study of the ultra-violet absorption spectra of various substituted dibenzylidene ketones derived from acetone, ethyl methyl ketone, diethyl ketone, cyclopentanone and cyclohexanone by condensing with several <em>meta</em>- and <em>para</em>-substituted benzaldehydes in <em>\(n\)</em>-hexane and in
APA, Harvard, Vancouver, ISO, and other styles
18

Sivak, Jacob G., Kelley L. Herbert, and Anne L. Baczmanski. "The Use of the Cultured Bovine Lens to Measure the In Vitro Ocular Irritancy of Ketones and Acetates." Alternatives to Laboratory Animals 23, no. 5 (1995): 689–98. http://dx.doi.org/10.1177/026119299502300522.

Full text
Abstract:
A novel in vitro alternative to in vivo eye toxicity testing measures the optical response (focal variability) of the cultured bovine lens (obtained from abattoirs) in response to exposure to potentially toxic chemicals. This approach involves measuring the optical quality of the lens by using a scanning laser system consisting of a low power scanning laser, a video camera and a video frame digitiser. This test was used to provide a rank order for the toxicity of four acetates (cellosolve acetate, ethyl acetate, methyl acetate and n-butyl acetate) and four ketones (methyl ethyl ketone, methyl
APA, Harvard, Vancouver, ISO, and other styles
19

NAKATANI, K., A. OKAMOTO, M. YAMANUKI, and I. SAITO. "ChemInform Abstract: Highly Efficient Synthesis of 2-Substituted 4H-Chromen-4-ones by Means of F--Induced 6-endo-digonal Cyclization of o-(Silyloxy)phenyl Ethynyl Ketone Derivatives." ChemInform 26, no. 6 (2010): no. http://dx.doi.org/10.1002/chin.199506150.

Full text
APA, Harvard, Vancouver, ISO, and other styles
20

J., S. Banait, Singh Baljit, and Kaur Harpreet. "Electrochemical synthesis of zinc(II) glycolates and their coordination compounds." Journal of Indian Chemical Society Vol. 88, May 2011 (2011): 641–46. https://doi.org/10.5281/zenodo.5769006.

Full text
Abstract:
Department of Chemistry, Punjabi University, Patiala-147 002, Punjab, India <em>E-mail</em>: js_banait@yahoo.com <em>Manuscript received 06 April 2010, revised 26 August 2010, accepted 31 August 2010</em> Zinc(II) glycolates have been synthesized by electrolyzing the solutions of aldehydes (benzaldehyde, salicylaldehyde, acetaldehyde and propionaldehyde) and ketones (acetone, isobutyl methyl ketone and ethyl meth)&middot;l ketone) in acetonitrile at sacrificial zinc anode. These glycolates do not form coordination compounds when reflul!.cd with ligands such as 1,10-phenanthroline and 2,2&#39;-
APA, Harvard, Vancouver, ISO, and other styles
21

Andraos, J., Y. Chiang, S. J. Eustace, et al. "Article." Canadian Journal of Chemistry 77, no. 4 (1999): 459–62. http://dx.doi.org/10.1139/v99-058.

Full text
Abstract:
Five ketenes, phenyl(ethyl)ketene, phenyl(methylthio)ketene, diphenylketene, pentafluorophenylketene, and 1-naphthylketene, were generated flash photolytically and solvent isotope effects (H2O vs. D2O) on their hydroxide-ion-catalyzed hydration in aqueous solution were determined. The values obtained are all weakly inverse and closely similar (kHO/kDO = 0.76-0.97), as expected for these fast, hydroxide-ion-consuming reactions, known to proceed by nucleophilic attack of hydroxide on the ketene carbonyl group. The characteristic magnitude of these isotope effects should prove useful in identifyi
APA, Harvard, Vancouver, ISO, and other styles
22

Ibaraki, Ayano, and Takaomi Kobayashi. "Phase Inversion Gelation Process and Additive Effects on Hydrogel Film Properties of Cotton Cellulose." Gels 10, no. 1 (2023): 34. http://dx.doi.org/10.3390/gels10010034.

Full text
Abstract:
During the preparation of cotton cellulose hydrogels using the phase inversion gelation method of N,N-dimethylacetamide/LiCl solution under ethanol vapor, acetone (AC), methyl ethyl ketone (MEK), or diethyl ketone (DEK) were added as additives, and their gelation state and the properties of the resulting hydrogels were evaluated. Adding the ketones to the cellulose solution caused an increase in the gelation time, but the solution viscosity decreased, indicating that the cellulose tended to aggregate in the solution. Among the hydrogels prepared by adding ketones, the water content was as high
APA, Harvard, Vancouver, ISO, and other styles
23

Sommariva, R., J. A. de Gouw, M. Trainer, et al. "Emissions and photochemistry of oxygenated VOCs in urban plumes in the Northeastern United States." Atmospheric Chemistry and Physics Discussions 8, no. 3 (2008): 12371–408. http://dx.doi.org/10.5194/acpd-8-12371-2008.

Full text
Abstract:
Abstract. Photochemical processes inside urban plumes in the Northeast of the United States have been studied using a highly detailed chemical model, based upon the Master Chemical Mechanism (MCM). The model results have been compared to measurements of oxygenated VOCs (acetone, methyl ethyl ketone, acetaldehyde, acetic acid and methanol) obtained during several flights of the NOAA WP-3D aircraft, which sampled plumes from the New York City area during the ICARTT campaign in 2004. The agreement between the model and the measurements was within 40–60% for all species, except acetic acid. The mo
APA, Harvard, Vancouver, ISO, and other styles
24

Sommariva, R., J. A. de Gouw, M. Trainer, et al. "Emissions and photochemistry of oxygenated VOCs in urban plumes in the Northeastern United States." Atmospheric Chemistry and Physics 11, no. 14 (2011): 7081–96. http://dx.doi.org/10.5194/acp-11-7081-2011.

Full text
Abstract:
Abstract. Photochemical processes inside urban plumes in the Northeast of the United States have been studied using a highly detailed chemical model, based upon the Master Chemical Mechanism (MCM). The model results have been compared to measurements of oxygenated VOCs (acetone, methyl ethyl ketone, acetaldehyde, acetic acid and methanol) obtained during several flights of the NOAA WP-3D aircraft, which sampled plumes from the New York City area during the ICARTT campaign in 2004. The agreement between the model and the measurements was within 40–60 % for all species, except acetic acid. The m
APA, Harvard, Vancouver, ISO, and other styles
25

MaGee, David I., Mahesh Ramaseshan, and James D. Leach. "Synthesis of cyclic and acyclic imides, sulfonimides, and N-carbobenzyloxyamides by ketene trapping." Canadian Journal of Chemistry 73, no. 12 (1995): 2111–18. http://dx.doi.org/10.1139/v95-260.

Full text
Abstract:
A convenient and general method for the synthesis of cyclic and acyclic imides, sulfonimides, and N-benzyloxycarbonyl amides via the inter-and intramolecular trapping of ketenes has been developed. Heating the corresponding amido, sulfonamido, and carbamamido ethyl ethynyl ethers at 150 °C for 3 h produced the desired compounds in good to excellent yields. Keywords: ketenes, imides, sulfonimides, N-benzyloxycarbonyl amides.
APA, Harvard, Vancouver, ISO, and other styles
26

Park, Hoey Kyung, June-shu Ahn, and Jungho Cho. "Simulation Study of Methyl ethyl ketone-Cyclohexane Azeotrope on the Pressure-Swing Distillation." Journal of the Korea Academia-Industrial cooperation Society 17, no. 3 (2016): 708–15. http://dx.doi.org/10.5762/kais.2016.17.3.708.

Full text
APA, Harvard, Vancouver, ISO, and other styles
27

Chun, Stephanie W., та Alison R. H. Narayan. "Biocatalytic Synthesis of α-Amino Ketones". Synlett 30, № 11 (2019): 1269–74. http://dx.doi.org/10.1055/s-0037-1611755.

Full text
Abstract:
Stereospecific generation of α-amino ketones from common α-amino acids is difficult to achieve, often employing superstoichiometric alkylating reagents and requiring multiple protecting group manipulations. In contrast, the α-oxoamine synthase protein family performs this transformation stereospecifically in a single step without the need for protecting groups. Herein, we detail the characterization of the 8-amino-7-oxononanoate synthase (AONS) domain of the four-domain polyketide-like synthase SxtA, which natively mediates the formation of the ethyl ketone derivative of arginine. The function
APA, Harvard, Vancouver, ISO, and other styles
28

Samiullah, Khan, A. Khan Jamal, K. Bhardwaj R., and Jabin Shagufta. "Effect of some organic compounds on the mobility of some trace metals through soil amended with fly ash." Journal of Indian Chemical Society Vol. 77, Jul 2000 (2000): 326–28. https://doi.org/10.5281/zenodo.5867147.

Full text
Abstract:
Department of Applied Chemistry, Z. H. College of Engineering &amp; Technology, Aligarh Muslim University, Aligarh-202 002, India Department of Chemistry, Aligarh Muslim University, Aligarh-202 002, India <em>Manuscript received R June 1999, revised 21 February 2000, accepted 3 March&nbsp;2000</em> The effects of some organic compounds, viz. formic acid, acetic acid, methanol, ethanol, formaldehyde, acetaldehyde, acetone and ethyl methyl ketone on the mobility of some trace metals, viz. Co, Zn, Cu, Ag and Pb through soil amended with fly ash have been invstigated in an alkaline fine sandy loam
APA, Harvard, Vancouver, ISO, and other styles
29

Al-Auda, Zahraa, Hayder Al-Atabi, and Keith Hohn. "Metals on ZrO2: Catalysts for the Aldol Condensation of Methyl Ethyl Ketone (MEK) to C8 Ketones." Catalysts 8, no. 12 (2018): 622. http://dx.doi.org/10.3390/catal8120622.

Full text
Abstract:
Methyl ethyl ketone (MEK) was converted to heavier ketones in one step, using a multi-functional catalyst having both aldol condensation (aldolization and dehydration) and hydrogenation properties. 15% Cu supported zirconia (ZrO2) was investigated in the catalytic gas phase reaction of MEK in a fixed bed reactor. The results showed that the main product was 5-methyl-3-heptanone (C8 ketone), with side products including 5-methyl-3-heptanol, 2-butanol, and other heavy products (C12 and up). The effects of various reaction parameters, like temperature and molar ratio of reactants (H2/MEK), on the
APA, Harvard, Vancouver, ISO, and other styles
30

Suggs, J. William, and Chul-Ho Jun. "Metal-catalysed alkyl ketone to ethyl ketone conversions in chelating ketones via carbon–carbon bond cleavage." J. Chem. Soc., Chem. Commun., no. 2 (1985): 92–93. http://dx.doi.org/10.1039/c39850000092.

Full text
APA, Harvard, Vancouver, ISO, and other styles
31

Penner, Glenn H. "Conformational preference and internal rotation about the C1—Cα bond in phenylacetaldehyde and some benzyl alkyl ketones from 1H nuclear magnetic resonance and abinitio molecular orbital calculations". Canadian Journal of Chemistry 65, № 3 (1987): 538–40. http://dx.doi.org/10.1139/v87-094.

Full text
Abstract:
Analysis of the 1H nuclear magnetic resonance spectra of the benzyl moieties in phenylacetaldehyde, benzyl methyl ketone, benzyl ethyl ketone, benzyl isopropyl ketone, and 3,5-dichlorobenzyl tert-butyl ketone yields the long-range couplings between ring and α protons. These stereospecific couplings change very little upon replacement of the aldehydic hydrogen by various alkyl groups. The couplings for all the molecules studied fall within the ranges 4J(CH2, Ho) = −0.566 ± 0.008 Hz, 5J(CH2, Hm) = 0.278 ± 0.002 Hz, and 6J(CH2, Hp) = −0.409 ± 0.010 Hz, suggesting that in the ketones the alkyl gro
APA, Harvard, Vancouver, ISO, and other styles
32

Kam, Sang-Kyu, Jin-Woo Jeon, and Min-Gyu Lee. "Effect of Methyl Ethyl Ketone and Ethyl Acetate Vapor on Photocatalytic Decomposition of n-Pentane Vapor." Journal of Environmental Science International 23, no. 6 (2014): 1151–56. http://dx.doi.org/10.5322/jesi.2014.23.6.1151.

Full text
APA, Harvard, Vancouver, ISO, and other styles
33

Gliński, Marek, Małgorzata Gidzińska, Łukasz Czerwiński, et al. "Catalytic Ketonization over Oxide Catalysts (Part XIV): The Ketonization and Cross-Ketonization of Anhydrides, Substituted Acids and Esters." Molecules 29, no. 3 (2024): 584. http://dx.doi.org/10.3390/molecules29030584.

Full text
Abstract:
A series of 20 wt.% MO2/S catalysts (where M = Ce, Mn or Zr and S = SiO2 or Al2O3) were prepared using various precursors of the active phases. The resulting catalysts were characterized using different methods (XRD, TPR and SBET). For the first time, anhydrides were used as potential starting materials for ketone synthesis. This novel reaction was performed on various aliphatic anhydrides in the presence of catalysts within a temperature range of 523–723 K. For all anhydrides, except for pivalic anhydride, the appropriate ketones were obtained with good or very good yields. The vapor-phase ca
APA, Harvard, Vancouver, ISO, and other styles
34

Yamabe, Shinichi, Guixiang Zeng, Wei Guan, and Shigeyoshi Sakaki. "Substrate dependent reaction channels of the Wolff–Kishner reduction reaction: A theoretical study." Beilstein Journal of Organic Chemistry 10 (January 23, 2014): 259–70. http://dx.doi.org/10.3762/bjoc.10.21.

Full text
Abstract:
Wolff–Kishner reduction reactions were investigated by DFT calculations for the first time. B3LYP/6-311+G(d,p) SCRF=(PCM, solvent = 1,2-ethanediol) optimizations were carried out. To investigate the role of the base catalyst, the base-free reaction was examined by the use of acetone, hydrazine (H2N–NH2) and (H2O)8. A ready reaction channel of acetone → acetone hydrazine (Me2C=N–NH2) was obtained. The channel involves two likely proton-transfer routes. However, it was found that the base-free reaction was unlikely at the N2 extrusion step from the isopropyl diimine intermediate (Me2C(H)–N=N–H).
APA, Harvard, Vancouver, ISO, and other styles
35

L. Morgan, Sandra M. Ward, Ralph E., Daniel. "INHALATION TOXICITY STUDIES OF THE α,β-UNSATURATED KETONES: Ethyl Vinyl Ketone". Inhalation Toxicology 13, № 8 (2001): 633–58. http://dx.doi.org/10.1080/08958370126864.

Full text
APA, Harvard, Vancouver, ISO, and other styles
36

Morgan, Daniel L., Sandra M. Ward, Ralph E. Wilson та ін. "INHALATION TOXICITY STUDIES OF THE α,β-UNSATURATED KETONES: Ethyl Vinyl Ketone". Inhalation Toxicology 13, № 8 (2001): 633–58. http://dx.doi.org/10.1080/08958370152409883.

Full text
APA, Harvard, Vancouver, ISO, and other styles
37

Šindelář, Karel, Jiří Holubek, Oluše Matoušová, et al. "Aminoalkylidene and aminoalkyl derivatives of 6,11-dihydrodibenzo[b,e]thiepin-2- and -9-carbonitrile and 4,10-dihydrothieno[2,3-c]-1-benzothiepin-6-carbonitrile; Antidepressants with a new activity profile." Collection of Czechoslovak Chemical Communications 53, no. 2 (1988): 340–60. http://dx.doi.org/10.1135/cccc19880340.

Full text
Abstract:
Starting from the bromo ketones VIIc, XIII, and XXIV and proceeding via the alcohols VIIIc, IXc, XIV, XVII, and XXVI, the olefinic compounds IIc (+ VI), Xc (+XI), XVc and XIXc(+XXc), and the saturated compound XVIc were prepared. The pairs of geometrical isomers were separated by crystallization of salts and the individual compounds Iic, Xc, XVc, XVIc, XIXc, and XXc were transformed by treatment with cuprous cyanide in hexamethylphosphoric triamide to the corresponding cyano compounds IIb, Xb, XVb, XVIb, XIXb, and XXb. Compound IIb was synthesized also from the ketone VIIc via the cyano ketone
APA, Harvard, Vancouver, ISO, and other styles
38

Odiljon, E. Ziyadullaev* Fazliddin X. Musaev Umid G. Narbaev. "SYNTHESIS OF AROMATIC ACETYLENIC ALCOHOLS AND THEIR VINYL ETHERS OF THE BASED PHENYLACETYLENE, ANILINE AND ACETYLENE." INTERNATIONAL JOURNAL OF ENGINEERING SCIENCES & RESEARCH TECHNOLOGY 6, no. 2 (2017): 584–97. https://doi.org/10.5281/zenodo.322492.

Full text
Abstract:
The aim of research work is opening of physical out physical characteristics of synthesis of new aromatic acetylenic alcohols and their vinyl ester on the base local raw material and waste, and also elaboration of new industrial technologies. Investigation of synthesis of aromatic acetylenic alcohols with high yields with using of different method at using of phenylacetylene ower croton aldehydes and ketones (acetone, methyl ethyl ketone, methyl isopropyl ketone, acetophenone and pinokalin) in the presence of different catalysts; carring out of chemical and structural analysis’s and on the bas
APA, Harvard, Vancouver, ISO, and other styles
39

GEETA, GUPTA, and BANERJEE SHUBHRA. "Stobbe Condensation with Ethyl Methyl Ketone." Journal of Indian Chemical Society Vol. 68, Jun 1991 (1991): 362–63. https://doi.org/10.5281/zenodo.6157952.

Full text
Abstract:
Department of Chemistry, Institute of Science,&nbsp;Nagpur-440 001 <em>Manuscript received 29 October 1990, revised 1 April 1991,&nbsp;</em><em>accepted 13 May 1991</em> Stobbe Condensation with Ethyl Methyl Ketone.
APA, Harvard, Vancouver, ISO, and other styles
40

Ringsdorf, Akima, Achim Edtbauer, Bruna Holanda, et al. "Investigating carbonyl compounds above the Amazon rainforest using a proton-transfer-reaction time-of-flight mass spectrometer (PTR-ToF-MS) with NO+ chemical ionization." Atmospheric Chemistry and Physics 24, no. 20 (2024): 11883–910. http://dx.doi.org/10.5194/acp-24-11883-2024.

Full text
Abstract:
Abstract. The photochemistry of carbonyl compounds significantly influences tropospheric chemical composition by altering the local oxidative capacity; free radical abundance in the upper troposphere; and formation of ozone, peroxycarboxylic nitric anhydride (PAN), and secondary organic aerosol particles. Carbonyl compounds can be emitted directly from the biosphere into the atmosphere and are formed through photochemical degradation of various precursor compounds. Aldehydes have atmospheric lifetimes of hours to days, whereas ketones persist for up to several weeks. While standard operating c
APA, Harvard, Vancouver, ISO, and other styles
41

Bonilla-Landa, Israel, Emizael López-Hernández, Felipe Barrera-Méndez, Nadia C. Salas, and José L. Olivares-Romero. "Hafnium(IV) Chloride Catalyzes Highly Efficient Acetalization of Carbonyl Compounds." Current Organic Synthesis 16, no. 6 (2019): 913–20. http://dx.doi.org/10.2174/1570179416666190715100505.

Full text
Abstract:
Background: Hafnium(IV) tetrachloride efficiently catalyzes the protection of a variety of aldehydes and ketones, including benzophenone, acetophenone, and cyclohexanone, to the corresponding dimethyl acetals and 1,3-dioxolanes, under microwave heating. Substrates possessing acid-labile protecting groups (TBDPS and Boc) chemoselectively generated the corresponding acetal/ketal in excellent yields. Aim and Objective: In this study. the selective protection of aldehydes and ketones using a Hafnium(IV) chloride, which is a novel catalyst, under microwave heating was observed. Hence, it is imperat
APA, Harvard, Vancouver, ISO, and other styles
42

Zhuchkov, V. I., S. L. Nazansky, O. N. Krupinova, and A. K. Frolkova. "VAPOUR-LIQUID EQUILIBRIUM IN SYSTEMS WITH ISOBUTYL ACETATE, ACETIC ACID AND METHYL ETHYL KETONE." Fine Chemical Technologies 11, no. 2 (2016): 38–45. http://dx.doi.org/10.32362/2410-6593-2016-11-2-38-45.

Full text
Abstract:
The experimental temperature dependence of the vapour pressures of isobutyl acetate, acetic acid and methyl ethyl ketone were determined, and isobaric vapour-liquid equilibrium data of binary systems of methyl ethyl ketone + isobutyl acetate and methyl ethyl ketone + acetic acid were obtained. The experimental data were processed using the Antoine and Riedel equations and the NRTL and Wilson local composition equations, respectively. Comparison of the experimental and calculated data confirmed the adequacy of the vapour-liquid equilibrium mathematical simulation.
APA, Harvard, Vancouver, ISO, and other styles
43

Dransfield, R. D., R. Brightwell, M. F. Chaudhury, T. K. Golder, and S. A. R. Tarimo. "The use of odour attractants for sampling Glossina pallidipes Austen(Diptera: Glossinidae) at Nguruman, Kenya." Bulletin of Entomological Research 76, no. 4 (1986): 607–19. http://dx.doi.org/10.1017/s000748530001511x.

Full text
Abstract:
AbstractVarious ketones and 1-octen-3-ol were used as odour attractants with biconical traps at Nguruman, south-western Kenya, to assess their effects on the catch size and composition of Glossina pallidipes Austen. Acetone, methyl ethyl ketone and 1-octen-3-ol were found to be effective in increasing catch size by up to 2–4×, but the two ketones differed in their dose-response curves. Acetone was more effective for males than females, as was 1-octen-3-ol. The age composition of samples from baited and unbaited traps differed only slightly. The level of variability between traps was reduced by
APA, Harvard, Vancouver, ISO, and other styles
44

Lin, Qianjin, Jundie Chen, Xianzhong Hu, Chun Zou, and Alexander A. Konnov. "Measurements of laminar burning velocities and kinetic modelling of two symmetrical ketones: di-ethyl ketone and di-isopropyl ketone." Combustion and Flame 268 (October 2024): 113614. http://dx.doi.org/10.1016/j.combustflame.2024.113614.

Full text
APA, Harvard, Vancouver, ISO, and other styles
45

Liu, Baoxiang, Yang Yang, Likun Ren, et al. "HS-GC-IMS and PCA to Characterize the Volatile Flavor Compounds in Three Sweet Cherry Cultivars and Their Wines in China." Molecules 27, no. 24 (2022): 9056. http://dx.doi.org/10.3390/molecules27249056.

Full text
Abstract:
The aim of this research was to characterize differences and sources of volatile flavor compounds by using headspace-gas chromatography-ion mobility spectrometry (HS-GC-IMS) and principal component analysis (PCA). Three sweet cherry fruits from different cultivars (cv. Tie, Van, and Lap) and their wines that were produced by the same yeast were detected. The results showed that 27 flavor compounds were identified in cherry fruits, including 10 alcohols, 7 esters, 7 aldehydes, 2 ketones, and 1 organic acid. Twenty-three flavor compounds were identified in cherry wines, including nine esters, ei
APA, Harvard, Vancouver, ISO, and other styles
46

Young, Jay A. "Methyl Ethyl Ketone." Journal of Chemical Education 81, no. 5 (2004): 630. http://dx.doi.org/10.1021/ed081p630.

Full text
APA, Harvard, Vancouver, ISO, and other styles
47

Luttrell, William E., and Lauren R. Bellcock. "Methyl ethyl ketone." Journal of Chemical Health and Safety 22, no. 4 (2015): 33–36. http://dx.doi.org/10.1016/j.jchas.2015.06.007.

Full text
APA, Harvard, Vancouver, ISO, and other styles
48

Glowacz-Czerwonka, Dorota. "Oligoetherols with S-Trazine Ring Based on Hydroxymethyl Derivatives of Methyl Ethyl Ketone." Chemistry & Chemical Technology 11, no. 1 (2017): 45–48. http://dx.doi.org/10.23939/chcht11.01.045.

Full text
APA, Harvard, Vancouver, ISO, and other styles
49

Kurbatova, Marina, Mariya Cherencova, Tat'yana Raskulova, Mihail Fereferov, and Aleksey Ryabcov. "LOW TEMPERATURE DEWAXING OF OILS IN PRESENCE INDIVIDUAL SOLVENT." Bulletin of the Angarsk State Technical University 1, no. 12 (2018): 69–72. http://dx.doi.org/10.36629/2686-777x-2018-1-12-69-72.

Full text
APA, Harvard, Vancouver, ISO, and other styles
50

Raskulova, Tat'yana, Mihail Fereferov, Marina Kurbatova, Mariya Cherencova, and Irina Polyak. "ON THE REPLACE ABILITY OF SOLVENT IN THE PROCESS OF LOW TEMPERATURE DE-WAXING OF OILS." Modern Technologies and Scientific and Technological Progress 2018, no. 1 (2020): 38–39. http://dx.doi.org/10.36629/2686-9896-2020-2018-1-38-39.

Full text
APA, Harvard, Vancouver, ISO, and other styles
We offer discounts on all premium plans for authors whose works are included in thematic literature selections. Contact us to get a unique promo code!