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1

Koyaguchi, Takehiro, and Katsuya Kaneko. "Thermal evolution of silicic magma chambers after basalt replenishments." Earth and Environmental Science Transactions of the Royal Society of Edinburgh 91, no. 1-2 (2000): 47–60. http://dx.doi.org/10.1017/s0263593300007288.

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In order to understand the governing factors of petrological features of erupted magmas of island-arc or continental volcanoes, thermal fluctuations of subvolcanic silicic magma chambers caused by intermittent basalt replenishments are investigated from the theoretical viewpoint. When basaltic magmas are repeatedly emplaced into continental crust, a long-lived silicic magma chamber may form. A silicic magma chamber within surrounding crust is composed of crystal-melt mixtures with variable melt fractions. We define the region which behaves as a liquid in a mechanical sense (‘liquid part’) and the region which is in the critical state between liquid and solid states (‘mush’) collectively as a magma chamber in this study. Such a magma chamber is surrounded by partially molten solid with lower melt fractions. Erupted magmas are considered to be derived from the liquid part. The size of a silicic magma chamber is determined by the long-term balance between heat supply from basalt and heat loss by conduction, while the temperature and the volume of the liquid part fluctuate in response to individual basalt inputs. Thermal evolution of a silicic magma chamber after each basalt input is divided into two stages. In the first stage, the liquid part rapidly propagates within the magma chamber by melting the silicic mush, and its temperature rises above and decays back to the effective fusion temperature of the crystal-melt mixture on a short timescale. In some cases the liquid part no longer exists. In the second stage, the liquid part ceases to propagate and cools slowly by heat conduction on a much longer timescale. The petrological features of the liquid part, such as the amount of unmelted preexisting crystals, depend on the intensity of individual pulses of the basalt heat source and the degree of fractionation during the first stage, as well as the bulk composition of the silicic magma.
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2

Wiebe, R. A. "Mafic-silicic layered intrusions: the role of basaltic injections on magmatic processes and the evolution of silicic magma chambers." Earth and Environmental Science Transactions of the Royal Society of Edinburgh 87, no. 1-2 (1996): 233–42. http://dx.doi.org/10.1017/s0263593300006647.

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ABSTRACT:Plutonic complexes with interlayered mafic and silicic rocks commonly contain layers (1–50 m thick) with a chilled gabbroic base that grades upwards to dioritic or silicic cumulates. Each chilled base records the infusion of new basaltic magma into the chamber. Some layers preserve a record of double-diffusive convection with hotter, denser mafic magma beneath silicic magma. Processes of hybridisation include mechanical mixing of crystals and selective exchange of H2O, alkalis and isotopes. These effects are convected away from the boundary into the interiors of both magmas. Fractional crystallisation aad replenishment of the mafic magma can also generate intermediate magma layers highly enriched in incompatible elements.Basaltic infusions into silicic magma chambers can significantly affect the thermal and chemical character of resident granitic magmas in shallow level chambers. In one Maine pluton, they converted resident I-type granitic magma into A-type granite and, in another, they produced a low-K (trondhjemitic) magma layer beneath normal granitic magma. If comparable interactions occur at deeper crustal levels, selective thermal, chemical and isotopic exchange should probably be even more effective. Because the mafic magmas crystallise first and relatively rapidly, silicic magmas that rise away from deep composite chambers may show little direct evidence (e.g. enclaves) of their prior involvement with mafic magma.
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3

Marsh, Bruce D. "Solidification fronts and magmatic evolution." Mineralogical Magazine 60, no. 398 (February 1996): 5–40. http://dx.doi.org/10.1180/minmag.1996.060.398.03.

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AbstractFrom G. F. Becker's and L. V. Pirsson's early enunciations linking the dynamics of magma chambers to the rock records of sills and plutons to this day, two features stand at the centre of nearly every magmatic process: solidification fronts and phenocrysts. The structure and behaviour of the envisioned solidification front, however, has been mostly that akin to non-silicate, non-multiply-saturated systems, which has led to confusion in appreciating its role in magmatic evolution. The common habit of intruding magmas to carry significant amounts of phenocrysts, which can lead to efficient fractionation, layering, and interstitial melt flow within extensive mush piles, when coupled with solidification fronts, allows a broad understanding of the processes leading to the rock records of sills and lava lakes. These same processes are fundamental to understanding all magmas.The spatial manifestation of the liquidus and solidus is the Solidification Front (SF); all magmas, stationary or in transit, are encased by SFs. In the ideal case of an initially crystal-free, cooling magma, crystallinity increases from nucleation on the leading liquidus edge to a holocrystalline rock at the trailing solidus. The package of SF isotherms advances inward, thickening with time and, depending on location — roof, floor, or walls — and the initial crystallinity of the magma, is instrumental in controlling magmatic evolution. Bimodal volcanism as well as much of the structure of the oceanic crust may arise from the behaviour of SFs.In mafic magmas, somewhere near a crystallinity (N) of 55% (vol), depending on the phase assemblage, the SF changes from a viscous fluid (suspension (0<N<25) and mush (25<N<55%)) to an elastic crystalline network (rigid crust (55<N<100%)) of some strength containing interstitial residual melt. With thickening of the roofward SF of some mafic magmas, the weight of the leading, viscous portion repeatedly tears the crust near N ∼ 55–60%, efficiently segregating the local residual melt into zones of interdigitating silicic lenses. This is SF instability (SFI), a process of possible importance in continental crust initiation and evolution, in producing silicic segregations in oceanic crust, and in recording the inability of the viscous part of the upper SF ever to detach wholly in typical (<∼ 1 km) sheet-like magmas. These granophyric and pegmatitic segregations, individually reaching 1–2 m in thickness and 30–50 m in length, form thick (∼ 50–75 m) zones that can be misconstrued as sandwich horizons where the last liquids might have accumulated. In effectively splitting the magma chemically and spatially, SFI is, in essence, a form of chaos (i.e. silicic chaos).Differentiation of initially crystal-free, stationary magmas is limited to processes occurring within SFs, which operate in competition with the rate of inward advancement of solidification. Local processes operating on characteristic time scales longer than the time for the SF to advance a distance equal to its own thickness are suppressed. Enormous increases in viscosity outward within the viscous, leading portion of the SF efficiently partition the distribution of melt accessible to eruption. Eruptible melts lie essentially inward of the SF and are thus severely restricted in silica enrichment. The silica-enriched SFI melts are thus generally inaccessible to collection and eviction unless the host SF is reprocessed or “burned back” through, respectively, later regional magmatism or massive, late-stage re-injection. And because of large viscosity contrasts between SFI melts and host basalts, once freed, SFI melts are literally impossible to homogenize back into the system and may collect and compact against the roof to form large silicic masses. Unusually voluminous, bulbous masses of silicic granophyre present along, and sometimes warping, the roofs of large diabase sills may reflect collections of remobilized blobs of SFI melts. These bulbous masses may be later added to the continental crust through solid state creep.In sheets made of phenocryst-rich, singly saturated magma, most phenocrysts are able through settling or floating to avoid capture by the advancing SFs. Significant differentiation is possible through extensive settling of initial phenocrysts and upward leakage of interstitial residual melt from the associated cumulate pile, which over-thickens the lower SF, greatly tipping the competitive edge against suppression of melt leakage by advancing solidification. Dense interstitial melts may similarly drain from roofward cumulates of light phenocrysts. The variation in crystal size and modal abundance in these cumulate piles are intimate records of prior crystallization, transport, and filling.Magmas in transit erode SFs and thoroughly charge the magma with crystals, facilitating fractionation and differentiation, especially if the body occasionally comes to rest. The key to protracted differentiation through fractional crystallization is not crystallization in stationary, closed chambers, but the repeated transport and chambering of magma or the periodic resupply to chambers of phenocryst-rich magma. This is punctuated differentiation, which may be the general case. Close corollaries are that thick, closed sheets of initially crystal-free, multiply-saturated magma undergo precious little overall differentiation, and that deciphering the sequence and crystallinity, including in transit phenocryst entrainment, growth, and sorting, of the filling events is central to unravelling intrusive history.Variations in temperature, whether on phase diagrams or in actual magmas, are intrinsically linked to commensurate variations in space and time in magmatic systems. The spectrum of all physical and chemical processes associated with magma is accordingly strongly partitioned in space and time.The idea of a magma chamber as a vat of low crystallinity melt crystallizing everywhere within and differentiating through crystal settling is unrealistic. A magma chamber formed of any number of crystal-laden inputs, encased by inward-propagating, dynamic solidification fronts, and where significant differentiation is tied to the dynamics of late-stage, interstitial melt within extensive mush piles is more in accord with the rock record.
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4

Thy, P. "Magmas and magma chamber evolution, Troodos ophiolite, Cyprus." Geology 15, no. 4 (1987): 316. http://dx.doi.org/10.1130/0091-7613(1987)15<316:mamcet>2.0.co;2.

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5

Zambra, Carlos Enrique, Luciano Gonzalez-Olivares, Johan González, and Benjamin Clausen. "Temporal Evolution of Cooling by Natural Convection in an Enclosed Magma Chamber." Processes 10, no. 1 (January 5, 2022): 108. http://dx.doi.org/10.3390/pr10010108.

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This research numerically studies the transient cooling of partially liquid magma by natural convection in an enclosed magma chamber. The mathematical model is based on the conservation laws for momentum, energy and mass for a non-Newtonian and incompressible fluid that may be modeled by the power law and the Oberbeck–Boussinesq equations (for basaltic magma) and solved with the finite volume method (FVM). The results of the programmed algorithm are compared with those in the literature for a non-Newtonian fluid with high apparent viscosity (10–200 Pa s) and Prandtl (Pr = 4 × 104) and Rayleigh (Ra = 1 × 106) numbers yielding a low relative error of 0.11. The times for cooling the center of the chamber from 1498 to 1448 K are 40 ky (kilo years), 37 and 28 ky for rectangular, hybrid and quasi-elliptical shapes, respectively. Results show that for the cases studied, natural convection moved the magma but had no influence on the isotherms; therefore the main mechanism of cooling is conduction. When a basaltic magma intrudes a chamber with rhyolitic magma in our model, natural convection is not sufficient to effectively mix the two magmas to produce an intermediate SiO2 composition.
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6

Nizametdinov, I. R., D. V. Kuzmin, S. Z. Smirnov, A. V. Rybin, and I. Yu Kulakov. "Water in parental basaltic magmasof the Menshiy Brat volcano (Iturup Island, Kurile islands)." Доклады Академии наук 486, no. 1 (May 10, 2019): 93–97. http://dx.doi.org/10.31857/s0869-5652486193-97.

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The paper presents study of the liquidus assemblage of olivine and spinel in high-magnesian basalts (MgO up to 10 mas. %) of the Menshiy Brat volcano (Iturup Island). It was possible to reconstruct the water content and evolution of volatile components in the primary parental magmas that took part in the formation of the Medvezhya Caldera, Iturup Islands. It is shown that the initial water content in the primary melts could reach 5 mas. % with oxygen fugacity corresponding to oxygen buffer NNO + 0.4 log. units. The evolution of magmas involved continuous degassing while magma rises to the surface. The water-rich fluid, which is constantly separated by evolving magma, could play a significant role in the formation of large siliceous magma chambers, which participated in catastrophic caldera eruptions.
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7

Müller, Axel, Alfons M. van den Kerkhof, Hans-Jürgen Behr, Andreas Kronz, and Monika Koch-Müller. "The evolution of late-Hercynian granites and rhyolites documented by quartz – a review." Earth and Environmental Science Transactions of the Royal Society of Edinburgh 100, no. 1-2 (March 2009): 185–204. http://dx.doi.org/10.1017/s1755691009016144.

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ABSTRACTThe potential of igneous quartz for providing a better understanding of magmatic processes is demonstrated by studying late-Hercynian rhyolites and granites from central and western Europe. Cathodoluminescence (CL) reveals growth patterns and alteration structures within igneous quartz reflecting the magma crystallisation history. The relatively stable and blue-dominant CL of zoned phenocrysts is principally related to variations in the Ti concentration, which is a function of the crystallisation temperature. The Al/Ti ratio of igneous quartz increases with progressive magma differentiation, as Ti is more compatible, compared to Al, Li, K, Ge, B, Fe, P during magma evolution. The red-dominant CL of the anhedral groundmass quartz in granite is unstable during electron bombardment and associated with OH- and H2O-bearing lattice defects. Thus, CL properties of quartz are different for rocks formed from H2O-poor and H2O-rich melts. Both groundmass and phenocrysts in granites are rich in alteration structures as a result of interaction with deuteric fluids during cooling, whereas phenocrysts in extrusive rocks do not usually contain such structures. The combined study of trace elements along with the analysis of quartz textures and melt inclusion inventories may reveal detailed PTX-paths of granite magmas. This study shows that quartz is a sensitive indicator for physico-chemical changes during the evolution of silicarich magmas. Common growth textures show a wide variety in quartz phenocrysts in rhyolites and some granites. This paper presents a classification of textures, which formed as a result of heterogeneous intra-granular lattice defects and impurities. The alternation of growth and resorption microtextures reflects stepwise adiabatic and non-adiabatic magma ascent, temporary storage of magma in reservoirs and mixing with more mafic, hotter magma. The anhedral groundmass quartz overgrowing early-magmatic phenocrysts in granites is free of growth zoning.
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8

Gualda, Guilherme A. R., Darren M. Gravley, Michelle Connor, Brooke Hollmann, Ayla S. Pamukcu, Florence Bégué, Mark S. Ghiorso, and Chad D. Deering. "Climbing the crustal ladder: Magma storage-depth evolution during a volcanic flare-up." Science Advances 4, no. 10 (October 2018): eaap7567. http://dx.doi.org/10.1126/sciadv.aap7567.

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Very large eruptions (>50 km3) and supereruptions (>450 km3) reveal Earth’s capacity to produce and store enormous quantities (>1000 km3) of crystal-poor, eruptible magma in the shallow crust. We explore the interplay between crustal evolution and volcanism during a volcanic flare-up in the Taupo Volcanic Zone (TVZ, New Zealand) using a combination of quartz-feldspar-melt equilibration pressures and time scales of quartz crystallization. Over the course of the flare-up, crystallization depths became progressively shallower, showing the gradual conditioning of the crust. Yet, quartz crystallization times were invariably very short (<100 years), demonstrating that very large reservoirs of eruptible magma were transient crustal features. We conclude that the dynamic nature of the TVZ crust favored magma eruption over storage. Episodic tapping of eruptible magmas likely prevented a supereruption. Instead, multiple very large bodies of eruptible magma were assembled and erupted in decadal time scales.
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9

Flinders, James, and John D. Clemens. "Non-linear dynamics, chaos, complexity and enclaves in granitoid magmas." Earth and Environmental Science Transactions of the Royal Society of Edinburgh 87, no. 1-2 (1996): 217–23. http://dx.doi.org/10.1017/s0263593300006623.

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ABSTRACT:Most natural systems display non-linear dynamic behaviour. This should be true for magma mingling and mixing processes, which may be chaotic. The equations that most nearly represent how a chaotic natural system behaves are insoluble, so modelling involves linearisation. The difference between the solution of the linearised and ‘true’ equation is assumed to be small because the discarded terms are assumed to be unimportant. This may be very misleading because the importance of such terms is both unknown and unknowable. Linearised equations are generally poor descriptors of nature and are incapable of either predicting or retrodicting the evolution of most natural systems. Viewed in two dimensions, the mixing of two or more visually contrasting fluids produces patterns by folding and stretching. This increases the interfacial area and reduces striation thickness. This provides visual analogues of the deterministic chaos within a dynamic magma system, in which an enclave magma is mingling and mixing with a host magma. Here, two initially adjacent enclave blobs may be driven arbitrarily and exponentially far apart, while undergoing independent (and possibly dissimilar) changes in their composition. Examples are given of the wildly different morphologies, chemical characteristics and Nd isotope systematics of microgranitoid enclaves within individual felsic magmas, and it is concluded that these contrasts represent different stages in the temporal evolution of a complex magma system driven by nonlinear dynamics. If this is true, there are major implications for the interpretation of the parts played by enclaves in the genesis and evolution of granitoid magmas.
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10

Woolley, Alan R., and R. Garth Platt. "The mineralogy of nepheline syenite complexes from the northern part of the Chilwa Province, Malawi." Mineralogical Magazine 50, no. 358 (December 1986): 597–610. http://dx.doi.org/10.1180/minmag.1986.050.358.05.

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AbstractThe mineralogy, including the accessory phases låvenite, rosenbuschite, and catapleiite, and consequent petrogenetic implications have been investigated for a group of four overlapping nepheline syenite complexes (Chikala, Chaone, Mongolowe, and Chinduzi) and for spatially associated silica-saturated and over-saturated perthosites, from the northern part of the Chilwa Alkaline Province, Malawi.The complexes are thought to have formed by injection into high-level chambers of magma pulses genetically related to a common source magma at depth. Evidence for the source magma is preserved in salitic cores observed in the pyroxenes and a trend to more hedenbergite-rich compositions is believed to have formed by evolution of this magma. Subsequent trends of acmite enrichment followed magma injection into the higher-level chambers; the actual pyroxene trend associated with each individual complex is a function of the evolution attained by the source magma, oxidation potential, and perhaps even alkali activity. On the basis of such a two-stage model, the pyroxene data suggest emplacement of the Chaone and Mongolowe magmas somewhat earlier than that of Chikala, with the Chinduzi magma migrating even later.Amphiboles and biotites are believed to have formed after high-level injection of the magmas. Their compositions broadly reflect the nature of the crystallizing pyroxenes in that magnesian hastingsitic hornblendes and more Mg-rich biotites are associated with more Mg-rich sodic pyroxenes, whereas katophorites and annite-rich micas are generally associated with sodic pyroxenes somewhat richer in hedenbergite. Sub-solidus crystallization in some of the complexes is represented by aegirine and magnesio-arfvedsonite. Nepheline compositions indicate broadly similar crystallization temperatures within the complexes, namely 950 to 750°C. Oxygen fugacities for these magmas obtained from biotite/annite compositions vary from 10−19 to 10−14 bars for this temperature range. Mineralogical data, particularly from pyroxenes and amphiboles, strongly suggest that the perthosites, spatially associated with the nepheline syenite complexes, are genetically unrelated.
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11

CHRISTIANSEN, ERIC H. "Contrasting processes in silicic magma chambers: evidence from very large volume ignimbrites." Geological Magazine 142, no. 6 (November 2005): 669–81. http://dx.doi.org/10.1017/s0016756805001445.

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Very large volume (>1000 km3 of magma) crystal-rich dacitic ignimbrites that lack pronounced evidence of fractional crystallization or vertical zonation erupt in some continental magmatic arcs (e.g. the Lund Tuff of the Great Basin and the Fish Canyon Tuff of Colorado in western USA). Apparently, their magma chambers were only modestly heterogeneous and not systematically zoned from top to bottom. These ignimbrites have 40 to 50% phenocrysts set in a high-silica rhyolite glass. Mineral assemblages and mineral compositions suggest pre-eruption temperatures were 730 to 820°C and water and oxygen fugacities were relatively high. We have speculated that these very large volume ignimbrites are unzoned because crystallization and convection in slab-shaped magma chambers inhibited separation of crystals from liquids and resulted in a chamber filled with compositionally heterogeneous magma that lacked systematic chemical zonation or strong fractionation. However, many other very large volume silicic ignimbrites are strongly fractionated and may be vertically zoned (e.g. tuffs related to the Yellowstone hotspot). These rhyolitic tuffs typically have few phenocrysts, anhydrous mineral assemblages, low oxygen fugacities, crystallization temperatures of 830 to 1050°C, and a strong imprint of fractional crystallization. Yet these Yellowstone-type rhyolites are derived from chambers 40 to 70 km across which have sill-like shapes (depth/diameter ratios much less than 1). Thus, factors other than chamber shape must be important for establishing the degree of evolution and nature of zonation in silicic magma chambers. Here, the role of crystallinity-dependent viscosity on the evolution of these two types of contrasting magmas is explored. Calculated magma viscosities for the hot, dry, crystal-poor rhyolites are significantly lower than for the cooler, wetter, crystal-rich dacites. Perhaps these hot rhyolites had low enough crystal contents and viscosities to allow efficient crystal–liquid separation, probably by a combination of unhindered crystal-settling, floor crystallization (including compaction), and crystallization on the walls of large chambers. Clean separation of melt from residual solids at their sources may have been promoted by their high temperatures and low viscosities (<104.5 Pa s). In contrast, monotonous dacitic magmas may never have been crystal-free near-liquidus magmas. Their large magma chambers may have developed by progressive growth at a shallow level with repeated input of intermediate to silicic magma. Crystallization of the water-enriched dacitic magmas occurred at lower temperatures (<800 °C) where crystallinity and hence magma viscosity (>106.5 Pa s) were significantly higher. These characteristics inhibited all forms of crystal–liquid separation, hindered development of systematic vertical zonation, and promoted quasi-equilibrium crystallization in small domains within large heterogeneous magma chambers. Eruptions of these crystal-rich dacites may only occur if the roof fails over a growing magma chamber that is becoming increasingly molten.
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12

Nathwani, Chetan L., Matthew A. Loader, Jamie J. Wilkinson, Yannick Buret, Robert H. Sievwright, and Pete Hollings. "Multi-stage arc magma evolution recorded by apatite in volcanic rocks." Geology 48, no. 4 (January 17, 2020): 323–27. http://dx.doi.org/10.1130/g46998.1.

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Abstract Protracted magma storage in the deep crust is a key stage in the formation of evolved, hydrous arc magmas that can result in explosive volcanism and the formation of economically valuable magmatic-hydrothermal ore deposits. High magmatic water content in the deep crust results in extensive amphibole ± garnet fractionation and the suppression of plagioclase crystallization as recorded by elevated Sr/Y ratios and high Eu (high Eu/Eu*) in the melt. Here, we use a novel approach to track the petrogenesis of arc magmas using apatite trace element chemistry in volcanic formations from the Cenozoic arc of central Chile. These rocks formed in a magmatic cycle that culminated in high-Sr/Y magmatism and porphyry ore deposit formation in the Miocene. We use Sr/Y, Eu/Eu*, and Mg in apatite to track discrete stages of arc magma evolution. We apply fractional crystallization modeling to show that early-crystallizing apatite can inherit a high-Sr/Y and high-Eu/Eu* melt chemistry signature that is predetermined by amphibole-dominated fractional crystallization in the lower crust. Our modeling shows that crystallization of the in situ host-rock mineral assemblage in the shallow crust causes competition for trace elements in the melt that leads to apatite compositions diverging from bulk-magma chemistry. Understanding this decoupling behavior is important for the use of apatite as an indicator of metallogenic fertility in arcs and for interpretation of provenance in detrital studies.
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Heinonen, Jussi S., Frank J. Spera, and Wendy A. Bohrson. "Thermodynamic limits for assimilation of silicate crust in primitive magmas." Geology 50, no. 1 (September 30, 2021): 81–85. http://dx.doi.org/10.1130/g49139.1.

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Abstract Some geochemical models for basaltic and more primitive rocks suggest that their parental magmas have assimilated tens of weight percent of crustal silicate wall rock. But what are the thermodynamic limits for assimilation in primitive magmas? We pursue this question quantitatively using a freely available thermodynamic tool for phase equilibria modeling of open magmatic systems—the Magma Chamber Simulator (https://mcs.geol.ucsb.edu)—and focus on modeling assimilation of wall-rock partial melts, which is thermodynamically more efficient compared to bulk assimilation of stoped wall-rock blocks in primitive igneous systems. In the simulations, diverse komatiitic, picritic, and basaltic parental magmas assimilate progressive partial melts of preheated average lower, middle, and upper crust in amounts allowed by thermodynamics. Our results indicate that it is difficult for any subalkaline primitive magma to assimilate more than 20−30 wt% of upper or middle crust before evolving to compositions with higher SiO2 than a basaltic magma (52 wt%). On the other hand, typical komatiitic magmas have thermodynamic potential to assimilate as much as their own mass (59−102 wt%) of lower crust and retain a basaltic composition. The compositions of the parental melt and the assimilant heavily influence both how much assimilation is energetically possible in primitive magmas and the final magma composition given typical temperatures. These findings have important implications for the role of assimilation in the generation and evolution of, e.g., ultramafic to mafic trans-Moho magmatic systems, siliceous high-Mg basalts, and massif-type anorthosites.
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14

Boudoire, G., Y. A. Brugier, A. Di Muro, G. Wörner, I. Arienzo, N. Metrich, V. Zanon, et al. "Eruptive Activity on the Western Flank of Piton de la Fournaise (La Réunion Island, Indian Ocean): Insights on Magma Transfer, Storage and Evolution at an Oceanic Volcanic Island." Journal of Petrology 60, no. 9 (September 1, 2019): 1717–52. http://dx.doi.org/10.1093/petrology/egz045.

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Abstract Petrological and geochemical (major element, trace element, Sr–Nd isotope) data for recent (&lt;5 kyr old) basalts that sporadically erupt on the western flank of Piton de la Fournaise (PdF), one of the most active volcanoes on Earth, allow the tracking of magma transfer and evolution from mantle to crustal depths. In the western peripheral area of PdF we document the broadly synchronous eruptions of (1) primitive olivine and olivine–clinopyroxene transitional basalts with tholeiitic affinity that are closely associated in space with (2) transitional olivine basalts with alkaline affinity, and (3) hybrid lavas, intermediate between the ‘alkaline’ and the ‘tholeiitic’ end-members. The composition of the latter overlaps with that of the lavas frequently erupted from the conduit system feeding the main summit cone. AlphaMELTS modelling, and fluid inclusion and clinopyroxene barometry, constrain the conditions of magma storage at 10–30 km, and the ascent of magma from the upper mantle to the shallow crustal plumbing system. Variable degrees of mantle melting, together with minor source heterogeneity and contamination with cumulate-derived partial melts, contribute to the diversity of PdF magmas. However, all these processes do not represent the dominant factors that produce the large variability we found in major element composition. Indeed, the composition of basalts erupted from PdF peripheral centers is strongly controlled by polybaric olivine–clinopyroxene fractionation at pressures higher than 3 kbar. Crystal textures and geochemical modelling suggest that fast magma ascent is critical to prevent clinopyroxene dissolution. Conversely, long-lasting magma stagnation promotes pyroxene resorption and magma differentiation. ‘Central’ eruptions occurring close to the PdF summit cone emit variably more evolved melts, which result from olivine–clinopyroxene–plagioclase differentiation at intermediate–shallow pressure (&lt;3 kbar and in most cases &lt;1 kbar). Deep and extensive magma mixing before injection into the crustal magma conduit system, located below the summit region, results in the apparent homogeneity of basalts erupted from the central area. As regards ‘peripheral’ eruptions, deep-seated stagnation of basaltic melts and differentiation at the mantle–crust transition zone (c. 4 kbar) produces a range of magma compositions. We demonstrate that rapid magma ascent from deep-seated reservoirs can bypass the central plumbing system. The eruptions of these magmas both in the central area and on the densely populated flanks have major consequences in terms of volcanic hazard at PdF.
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Walker, Brett H., Michael O. Garcia, and Tim R. Orr. "Petrologic Insights into Rift Zone Magmatic Interactions from the 2011 Eruption of Kīlauea Volcano, Hawaiʻi." Journal of Petrology 60, no. 11 (November 1, 2019): 2051–75. http://dx.doi.org/10.1093/petrology/egz064.

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Abstract The high frequency of historical eruptions at Kīlauea Volcano presents an exceptional opportunity to address fundamental questions related to the transport, storage, and interaction of magmas within rift zones. The Nāpau Crater area on Kīlauea’s East Rift Zone (ERZ) experienced nine fissure eruptions within 50 years (1961–2011). Most of the magma intruded during these frequent eruptions remained stored within the rift zone, creating a potential magma mixing depot within the ERZ. The superbly monitored and sampled 2011 eruption (Puʻu ʻŌʻō episode 59) presents an extraordinary opportunity to evaluate magma mixing processes within the ERZ. Whole-rock, glass, and olivine compositions were determined, not only for lava from the 2011 eruption, but also for a new suite of Nāpau Crater area samples from the 1963, 1965, 1968, 1983, and 1997 eruptions, as well as the previously undocumented 1922 eruption. Whole-rock XRF data revealed two geochemically distinct magma batches for episode 59: one less evolved (∼6·6 wt % MgO, 0·46 wt % K2O) than the other (∼6·2 wt % MgO, 0·58 wt % K2O). Episode 59 lava is remarkably aphyric (∼0·1 vol. % phenocrysts), making use of mineralogy to identify parent magma affinities problematic. Linear compositional trends of whole-rock major and trace elements, and reversely zoned olivine crystals indicate episode 59 lavas underwent magma mixing. Least squares regression calculations and plots of major and trace element data, were used to evaluate whether the episode 59 samples are products of mixing summit-derived magma with residual magma from previous Nāpau Crater area eruptions. The regression results and trace element ratios are inconsistent with previously proposed mixing scenarios, but they do support mixing between summit-derived magma and residual magma from the 1983 and 1997 Nāpau Crater area eruptions. These magmas were stored in physically and chemically distinct pods at depths of 1·6–3·0 km prior to mixing with new magma intruded from the summit to produce the episode 59 lava. One pod contained a fractionated equivalent of 1983 lava, and the other a hybrid of compositions similar to 1983 and 1997 lavas. The petrology of episode 59 lava demonstrates that magmas from two previous eruptions (1983 and 1997) were available to mix with magma intruded from the summit region. This study clarifies the pre-eruptive history of the mixed episode 59 lava, and elucidates the evolution of the volcano's magmatic system in a region of frequent eruptions.
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16

Trua, Teresa, and Michael P. Marani. "Clinopyroxene Crystals in Basic Lavas of the Marsili Volcano Chronicle Early Magmatic Stages in a Back-Arc Transcrustal Mush System." Geosciences 11, no. 4 (April 1, 2021): 159. http://dx.doi.org/10.3390/geosciences11040159.

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Constraining the pre-eruptive processes that modulate the chemical evolution of erupted magmas is a challenge. An opportunity to investigate this issue is offered by the interrogation of the crystals carried in lavas. Here, we employ clinopyroxene crystals from back-arc lavas in order to identify the processes driving basalt to andesite magma evolution within a transcrustal plumbing system. The assembled clinopyroxene archive reveals that mantle melts injected at the crust-mantle transition cool and crystalize, generating a clinopyroxene-dominated mush capped by a melt-rich domain. Magma extracted from this deep storage zone fed the eruption of basalt to basaltic andesite lavas. In addition, chemically evolved melts rapidly rising from this zone briefly stalled at shallow crustal levels, sourcing crystal-poor andesite lavas. Over time, hot ascending primitive magmas intercepted and mixed with shallower cooling magma bodies forming hybrid basic lavas. The blended clinopyroxene cargoes of these lavas provide evidence for the hybridization, which is undetectable from a whole-rock chemical perspective, as mixing involved chemically similar basic magmas. The heterogeneity we found within the clinopyroxene archive is unusual since it provides, for the first time, a complete set of mush-related scenarios by which mantle melts evolve from basalt to andesite compositions. Neither the whole-rock chemistry alone nor the record of the mineral phases crystallizing subsequent to clinopyroxene can provide insights on such early magmatic processes. The obtained clinopyroxene archive can be used as a template for interpretation of the record preserved in the clinopyroxene cargoes of basalt to andesite lavas elsewhere, giving insights into the magma dynamics of the feeding plumbing system that are lost when using whole-rock chemistry.
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Handini, Esti, Toshiaki Hasenaka, Agung Harijoko, and Yasushi Mori. "Variation of Slab Component in Ancient and Modern Merapi Products: A Detailed Look into Slab Derived Fluid Fluctuation over the Living Span of One of the Most Active Volcanoes in Sunda Arc." Journal of Applied Geology 2, no. 1 (November 13, 2017): 1. http://dx.doi.org/10.22146/jag.30253.

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Holocene eruptions of Merapi have produced both medium-K and high-K calc alkaline series which correspond to products older and younger than 1900 years respectively. The change has been attributed to increasing sediment input as the volcano matures. This study presents two Merapi samples which represent Ancient and Modern Merapi. The two samples are analyzed for subduction components including B, Ba, Sr, and Pb using X-ray fluorescence (XRF) spectrometer and prompt gamma ray analysis (PGA). Our finding shows that Ancient Merapi sample from Plawangan Hill lava is close in affinities with younger than 1900 years high-K magma series. On the other hand, Modern Merapi sample from 2006 eruption juvenile is plotted within medium-K magma series which are observed in eruption products older than 1900 years. Ratios of fluid mobile elements to high field strength element (HFSE) (i.e. B/Nb, Ba/Y, Pb/Nb) consistently show that Ancient Merapi sample has higher input of slab derived fluid than Modern Merapi sample. A model using B/Nb and Ba/Nb suggests that Plawangan magma requires 1.5 % of sediment derived fluid, higher than estimated in 2006 eruption magma (1.2 %) and medium-K series magma, and within the range of high-K series magma, to explain its slab component enrichment. This evidence suggests that slab derived component addition to the sub-arc mantle wedge highly fluctuates over short period of evolution of a volcano. One possible explanation is the presence of veined hydrous metasomatized sub-arc mantle as Merapi magma source which allows melting of different mantle area to produce fluctuation of slab components in the course of evolution of Merapi magmas.
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18

Gautneb, Håvard, Agust Gudmundsson, and Niels Oskarsson. "Structure, petrochemistry and evolution of a sheet swarm in an Icelandic central volcano." Geological Magazine 126, no. 6 (November 1989): 659–73. http://dx.doi.org/10.1017/s0016756800006956.

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AbstractStrike, dip, and thickness were measured for 504 sheets (inclined sheets and dykes) in the 4–6 Ma old Hafnarfjall central volcano in southwest Iceland. The average dip of sheets is 65°, 80% are less than 1.2 m thick, and the thickness tends to decrease with decreasing dip. In 0.5 km long traverses perpendicular to the average strike of sheets, the percentage of sheets ranges from about 6 to 11.Of 140 chemically analysed sheets most are quartz-tholeiites; a few are intermediate or acid. The sheets are chemically more evolved than the host rock and were generated by a shallow crustal magma chamber at a mature stage of the central volcano, whereas the host rock was generated earlier before the chamber was established. Trace element results suggest that the sheet magmas evolved by low-pressure fractional crystallization as well as by mixing of primitive magmas and crustal melts.A model is proposed where most of the sheets are generated by a growing shallow magma chamber. As the chamber grows its shape changes, and so does the local stress field associated with it. Because the sheets follow the stress trajectories of the local stress field, the potential pathways of the sheets change with the growth of the chamber, which may explain the common occurrence of cross-cutting sheets. From the evolved chemistry of the sheets, as well as from the pattern of the stress trajectories, it is concluded that the bulk of the sheets were injected from the upper part of the shallow magma chamber.
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19

Chen, Peijia, Nianqiao Fang, and Xiaobo Yuan. "Geochemical Insights from Clinopyroxene Phenocrysts into the Magma Evolution of an Alkaline Magmatic System from the Sanshui Basin, South China." Minerals 11, no. 11 (November 22, 2021): 1295. http://dx.doi.org/10.3390/min11111295.

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The Sanshui Basin is located at the northern continental margin of the South China Sea and characterized by a continental rift basin. The bimodal volcanic rocks in Sanshui Basin record the early Cenozoic magmatic activity in the South China Block, but the magmatic evolution that produced the bimodal volcanic rocks is poorly understood. Clinopyroxenes in bimodal volcanic rocks in the Sanshui Basin provide an opportunity to investigate magma during magma ascent. In this work, we classified nine types of clinopyroxene phenocrysts according to composition and texture in cogenetic basalt-trachyandesite-comenditic trachyte, while the composition of unzoned clinopyroxene have an evolution sequence of diopside-hedenbergite-aegirine along with an increase in trace element contents with a decrease of Mg#, indicating that the genesis of clinopyroxene was dominated by fractional crystallization in a closed magma system. However, the clinopyroxenes with reversed zoning and multiple zoning record the process of magma mixing and recharge indicating an open magma system. While fractional crystallization is the dominant process, magma mixing, recharge, and crystal settling were also found to influence magma evolution. Thermobarometric calculations showed that clinopyroxene crystallized a several structural levels in the crust during magma ascent. In this study, we established a magma plumbing system that provides new constraints for the magma evolution in the Sanshui Basin.
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20

Solovova, I. P., A. V. Girnis, I. D. Ryabchikov, and N. N. Kononkova. "Origin of carbonatite magma during the evolution of ultrapotassic basite magma." Petrology 16, no. 4 (July 2008): 376–94. http://dx.doi.org/10.1134/s0869591108040048.

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21

Halldórsson, Sæmundur A., Edward W. Marshall, Alberto Caracciolo, Simon Matthews, Enikő Bali, Maja B. Rasmussen, Eemu Ranta, et al. "Rapid shifting of a deep magmatic source at Fagradalsfjall volcano, Iceland." Nature 609, no. 7927 (September 14, 2022): 529–34. http://dx.doi.org/10.1038/s41586-022-04981-x.

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AbstractRecent Icelandic rifting events have illuminated the roles of centralized crustal magma reservoirs and lateral magma transport1–4, important characteristics of mid-ocean ridge magmatism1,5. A consequence of such shallow crustal processing of magmas4,5 is the overprinting of signatures that trace the origin, evolution and transport of melts in the uppermost mantle and lowermost crust6,7. Here we present unique insights into processes occurring in this zone from integrated petrologic and geochemical studies of the 2021 Fagradalsfjall eruption on the Reykjanes Peninsula in Iceland. Geochemical analyses of basalts erupted during the first 50 days of the eruption, combined with associated gas emissions, reveal direct sourcing from a near-Moho magma storage zone. Geochemical proxies, which signify different mantle compositions and melting conditions, changed at a rate unparalleled for individual basaltic eruptions globally. Initially, the erupted lava was dominated by melts sourced from the shallowest mantle but over the following three weeks became increasingly dominated by magmas generated at a greater depth. This exceptionally rapid trend in erupted compositions provides an unprecedented temporal record of magma mixing that filters the mantle signal, consistent with processing in near-Moho melt lenses containing 107–108 m3 of basaltic magma. Exposing previously inaccessible parts of this key magma processing zone to near-real-time investigations provides new insights into the timescales and operational mode of basaltic magma systems.
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22

Baker, Leslie L., and Malcolm J. Rutherford. "Crystallisation of anhydrite-bearing magmas." Earth and Environmental Science Transactions of the Royal Society of Edinburgh 87, no. 1-2 (1996): 243–50. http://dx.doi.org/10.1017/s0263593300006659.

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ABSTRACT:Anhydrite has been identified as a phenocrystic phase in some silicic volcanic magmas, but it is not commonly described in plutonic rocks. Anhydrite-bearing magmas tend to form in arc environments and to contain hydrous, low-temperature, oxidised mineral assemblages. Phenocrystic anhydrite coexists with sulphur-enriched apatite and sometimes with pyrrhotite, in silicate melt that contains from 50 ppm to 1 wt% S, depending on temperature and conditions. Vapour coexisting with anhydrite- and water-saturated magma may contain from a few tenths of a mole per cent to a few mole per cent sulphur gases (SO2 and H2S), with the exact composition and gas speciation depending on temperature and oxygen fugacity. Samples of one anhydrite-bearing magma, the 1991 Pinatubo dacite, have been experimentally crystallised to determine whether the magma retains its characteristic sulphur-rich mineral phases during solidification. Results show that anhydrite and sulphur-rich apatite are retained throughout crystallisation and vapour phase evolution. This suggests that anhydrite-bearing intrusive equivalents of the Pinatubo dacite should be present in arc plutonic complexes.
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23

Forni, Francesca, Wim Degruyter, Olivier Bachmann, Gianfilippo De Astis, and Silvio Mollo. "Long-term magmatic evolution reveals the beginning of a new caldera cycle at Campi Flegrei." Science Advances 4, no. 11 (November 2018): eaat9401. http://dx.doi.org/10.1126/sciadv.aat9401.

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Understanding the mechanisms that control the accumulation of large silicic magma bodies in the upper crust is key to determining the potential of volcanoes to form caldera-forming eruptions. Located in one of the most populated regions on Earth, Camp Flegrei is an active and restless volcano that has produced two cataclysmic caldera-forming eruptions and numerous smaller eruptive events over the past 60,000 years. Here, we combine the results of an extensive petrological survey with a thermomechanical model to investigate how the magmatic system shifts from frequent, small eruptions to large caldera-forming events. Our data reveal that the most recent eruption of Monte Nuovo is characterized by highly differentiated magmas akin to those that fed the pre-caldera activity and the initial phases of the caldera-forming eruptions. We suggest that this eruption is an expression of a state shift in magma storage conditions, whereby substantial amounts of volatiles start to exsolve in the shallow reservoir. The presence of an exsolved gas phase has fundamental consequences for the physical properties of the reservoir and may indicate that a large magma body is currently accumulating underneath Campi Flegrei.
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24

Kodama, Shogo, Masaaki Owada, Mariko Nagashima, and Atsushi Kamei. "Magmatic Processes of the Upper Cretaceous Susuma–Nagaho Plutonic Complex, Southwest Japan: Its Role on Crustal Growth and Recycling in Active Continental Margins." Minerals 12, no. 6 (June 15, 2022): 762. http://dx.doi.org/10.3390/min12060762.

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Magmatic processes in the active continental margins are one of the important issues to understand the evolution of the continental crust. The Cretaceous Susuma–Nagaho plutonic complex, southwest Japan, is situated at the continental arc, and made up of gabbro, quartz diorite to granodiorite, and granite. According to the field occurrence, they are coeval intrusive rocks, and the biotite K–Ar ages of the granodiorite and granite are approximately 93 Ma, corresponding to the period of a magmatic flare-up in southwest Japan. Based on the whole-rock chemical analyses including Sr–Nd isotopic compositions, the granodiorite magma has been formed through fractional crystallization of basaltic magmas, whereas the origin of granite magma involved partial melting of the continental crust. The gabbro contains calcium-rich plagioclase (An > 90) and the presence of early crystallized hornblende, indicating its derivation from a hydrous basaltic magma. Such basaltic magma intruded into the middle to lower crust and supplied the heat energy necessary for crustal partial melting and granitic magma formation. The fractional crystallization and crustal melting took place at the same time, playing an important role in the crustal growth and differentiation during the magmatic flare-up event.
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25

Cox, Daniel, Sebastian F. L. Watt, Frances E. Jenner, Alan R. Hastie, Samantha J. Hammond, and Barbara E. Kunz. "Elevated magma fluxes deliver high-Cu magmas to the upper crust." Geology 48, no. 10 (June 10, 2020): 957–60. http://dx.doi.org/10.1130/g47562.1.

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Abstract Porphyry Cu-Au ore deposits are globally associated with convergent margins. However, controls on the processing and distribution of the chalcophile elements (e.g., Cu) during convergent margin magmatism remain disputed. Here, we show that magmas feeding many Chilean stratovolcanoes fractionate sulfides with a high-Cu/Ag ratio early in their crustal evolution. These magmas show evidence of lower-crustal garnet and amphibole crystallization, and their degree of sulfide fractionation and Cu depletion increase with both crustal thickness and the extent of garnet fractionation. However, samples from a small proportion of volcanoes with elevated eruptive fluxes depart from this Cu-depleting trend, instead erupting Cu-rich magmas. This implies that at these atypical sites, elevated magma productivity and crustal throughput, potentially facilitated by “pathways” exploiting major crustal fault systems, enable rapid magma transit, avoiding lower-crustal Cu-depleting sulfide fractionation and potentially playing an important role in porphyry ore genesis.
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26

Mutch, Euan J. F., John Maclennan, Tim J. B. Holland, and Iris Buisman. "Millennial storage of near-Moho magma." Science 365, no. 6450 (July 18, 2019): 260–64. http://dx.doi.org/10.1126/science.aax4092.

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The lower crust plays a critical role in the processing of mantle melts and the triggering of volcanic eruptions by supply of magma from greater depth. Our understanding of the deeper parts of magmatic systems is obscured by overprinting of deep signals by shallow processes. We provide a direct estimate of magma residence time in basaltic systems of the deep crust by studying ultramafic nodules from the Borgarhraun eruption in Iceland. Modeling of chromium–aluminum interdiffusion in spinel crystals provides a record of long-term magmatic storage on the order of 1000 years. This places firm constraints on the total crustal residence time of mantle-derived magmas and has important implications for modeling the growth and evolution of transcrustal magmatic systems.
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27

Barbarin, Bernard, and Jean Didier. "Genesis and evolution of mafic microgranular enclaves through various types of interaction between coexisting felsic and mafic magmas." Earth and Environmental Science Transactions of the Royal Society of Edinburgh 83, no. 1-2 (1992): 145–53. http://dx.doi.org/10.1017/s0263593300007835.

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ABSTRACTThermal, mechanical and chemical exchange occurs between felsic and mafic magmas in dynamic magma systems. The occurrence and efficiency of such exchanges are constrained mainly by the intensive parameters, the compositions, and the mass fractions of the coexisting magmas. As these interacting parameters do not change simultaneously during the evolution of the granite systems, the exchanges appear sequentially, and affect magmatic systems at different structural levels, i.e. in magma chambers at depth, in the conduits, or after emplacement. Hybridisation processes are especially effective in the plutonic environment because contrasting magmas can interact over a long time-span before cooling. The different exchanges are complementary and tend to reduce the contrasts between the coexisting magmas. They can be extensive or limited in space and time; they are either combined into mixing processes which produce homogeneous rocks, or only into mingling processes which produce rocks with heterogeneities of various size-scales. Mafic microgranular enclaves represent the most common heterogeneities present in the granite plutons. The composite enclaves and the many types of mafic microgranular enclaves commonly associated in a single pluton, or in polygenic enclave swarms, are produced by the sequential occurrence of various exchanges between coexisting magmas with constantly changing intensive parameters and mass fractions. The complex succession and repetition of exchanges, and the resulting partial chemical and complete isotopic equilibration, mask the original identities of the initial components.
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28

MacDonald, R., B. Bagiński, B. G. J. Upton, H. Pinkerton, D. A. MacInnes, and J. C. MacGillivray. "The Mull Palaeogene dyke swarm: insights into the evolution of the Mull igneous centre and dyke-emplacement mechanisms." Mineralogical Magazine 74, no. 4 (August 2010): 601–22. http://dx.doi.org/10.1180/minmag.2010.074.4.601.

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AbstractGeochemical data are presented for five large Palaeogene dykes, members of the Mull swarm in southern Scotland and northern England (the Moneyacres, Hawick-Acklington, Barrmill, Muirkirk- Hartfell and Dalraith-Linburn dykes). The rock types range from basalt through andesite to dacite, although the range in individual intrusions is more restricted. The dykes are divisible into two groups; those where the compositional variation was generated by fractional crystallization of basaltic magmas, and those where it resulted from variable degrees of mixing of basaltic and silicic magmas. Several dykes are composite; the marginal facies can be more or less evolved than the central facies. The dyke magmas are thought to have originated from stratified magma chambers beneath the Mull centre and models are presented to show how the different components were derived from the chambers. Some dykes appear to have been terminated at or near the Southern Upland Fault, perhaps as a result of the chilling of early magma pulses by water in the fault. The Palaeogene dyke swarm is considerably more complex than previously recognized and has a significant input to models of the evolution of the Mull magmatic system.
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29

Salvioli-Mariani, E., L. Toscani, and D. Bersani. "Magmatic evolution of the Gaussberg lamproite (Antarctica): volatile content and glass composition." Mineralogical Magazine 68, no. 1 (February 2004): 83–100. http://dx.doi.org/10.1180/0026461046810173.

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AbstractThe lamproite of Gaussberg is an ultrapotassic rock where leucite, olivine and clinopyroxene microphenocrysts occur in a glass-rich groundmass, containing microliths of leucite, clinopyroxene, apatite, phlogopite and rare K-richterite.Abundant silicate melt inclusions occur in olivine, leucite and, rarely, in clinopyroxene microphenocrysts. Raman investigations on melt inclusions showed the presence of pure CO2 in the shrinkage bubbles. On the other hand, the glass of the groundmass is CO2-poor and contains up to 0.70 wt.% of dissolved H2O, as estimated by infrared spectra. It is inferred that CO2 was released at every stage of evolution of the lamproite magma (CO2-rich shrinkage bubbles), whereas H2O was retained for longer in the liquid. At Gaussberg, CO2 seems to have a major role at relatively high pressure where it favoured the crystallization of H2O-poor microphenocrysts; the uprise of the magma to the surface decreased the solubility of CO2 and caused a relative increase in water activity. As a consequence, phlogopite and K-richterite appeared in the groundmass.The glass composition of both the groundmass and melt inclusions suggests different evolutions for the residual liquids of the investigated samples. Sample G886 shows the typical evolution of a lamproite magma, where the residual liquid evolves toward peralkaline and Na-rich composition and crystallizes K-richterite in the latest stage. Sample G895 derives from mixing/mingling of different batches of magma; effectively glasses from melt inclusions in leucite and clinopyroxene are more alkaline than those found in early crystallized olivine. Leucite and clinopyroxene crystallized early from a relatively more alkaline batch of lamproite magma and, successively, a less alkaline, olivinebearing magma batch assimilated them during its rise to the surface.
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30

Druitt, Timothy H., and Charles R. Bacon. "Compositional zonation and cumulus processes in the Mount Mazama magma chamber, Crater Lake, Oregon." Earth and Environmental Science Transactions of the Royal Society of Edinburgh 79, no. 2-3 (1988): 289–97. http://dx.doi.org/10.1017/s0263593300014280.

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ABSTRACTThe 6845 ± 50 BP climactic eruption of Mount Mazama discharged 47 ± 9 km3 of vertically zoned calc-alkaline magma, affording a virtually complete section through the chamber. Evidence for two andesitic parents with different trace-element (particularly Sr) and water contents is preserved in the ejecta. Prior to eruption, a dominant volume of rhyodacite was underlain successively by high-Sr andesite, high-Sr crystal mushes, and low-Sr crystal mushes. Intergranular liquids in the high-Sr magmas were probably richer in water than those in the low-Sr magmas. Thermal continuity throughout the ejecta favours eruption from a single, zoned reservoir. Insight into chamber development is given by preclimactic rhyodacitic lavas and tephra erupted between about 30,000 BP and the climactic eruption. The oldest of these lavas, contaminated derivatives of low-Sr magma, contain crystal-poor magmatic inclusions of low-Sr andesite; the youngest has inclusions of high-Sr andesite and, like rhyodacitic pumice in the climactic ejecta, is hybrid magma containing an admixed high-Sr component. A model for steady-state growth of the chamber is inferred whereby repeated recharge, first by low-Sr then high-Sr andesite (± basalt), builds up a cumulate succession, while derivative liquid fractionates convectively, segregates, and mixes with an incrementally growing silicic volume. The magma chamber at Mount Mazama may provide insight into the evolution of some granitoid plutons.
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31

Nelson, Dennis O., Donald A. Morrison, and William C. Phinney. "Open-system evolution versus source control in basaltic magmas: Matachewan–Hearst dike swarm, Superior Province, Canada." Canadian Journal of Earth Sciences 27, no. 6 (June 1, 1990): 767–83. http://dx.doi.org/10.1139/e90-078.

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The 2.45 Ga Matachewan–Hearst dike swarm was emplaced over 250 000 km2 in diverse granitoid–greenstone and metasedimentary terranes of the Superior Province of Canada. The Fe-rich tholeiitic dikes host large, uniform plagioclase megacrysts and display significant trace-element variations, e.g., (La/Sm)N = 0.62–2.23, not correlated to terrane lithologies.Fractional crystallization alone cannot produce these variations or simultaneously account for both major- and trace-element abundances. Combined periodic replenishment–fractional crystallization (RFC) in shallow magma chambers is consistent with major- and trace-element concentrations and with field evidence for periodic magma injection within the dikes. RFC cannot, however, produce the observed variation in incompatible-trace-element ratios, e.g., (La/Sm)N. Models invoking mixed mantle sources are unsuccessful at reproducing trace-element trends. Combined assimilation–fractional crystallization (AFC) models, assuming depleted parental magmas and using crustal rock data from xenoliths and from the Kapuskasing Structural Zone, can accommodate the trace-element variations, including the light-rare-earth-element enrichment and the observed relative depletions of the high-field-strength elements. The AFC process apparently took place in the lower crustal regions from where evolved magmas were periodically transported to shallow chambers dominated by RFC.
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32

Holm, Paul Martin, and Niels-Ole Prægel. "The importance of in situ crystallisation and loss of interstitial melt during formation of the Kærven Syenite Complex, Kangerlussuaq, East Greenland." Bulletin of the Geological Society of Denmark 67 (October 24, 2020): 107–46. http://dx.doi.org/10.37570/bgsd-2019-67-07.

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The Kærven Syenite Complex (KSC) is one of the oldest felsic intrusions in the Tertiary East Greenland province. Here we update our previous description of the KSC and supply a greatly expanded and comprehensive geochemical dataset. New data allow us to present a more detailed petrogenetic model for the evolution of the KSC and to investigate the geochemical characteristics of igneous cumulates subjected to loss and, occasionally, replacement of residual liquid. The KSC comprises eleven mappable units that generally young westwards. Rock types range from quartz syenite to quartz alkali feldspar syenite and alkali feldspar granite. Individual intrusive units are relatively narrow and steep-sided and are collectively suggested to represent a ring dyke complex. Basement gneiss and gabbro host rocks have locally contaminated the oldest quartz syenite KSC unit, but most of the main part of the complex escaped significant influence from host rocks. A late suite of E–W to NE–SW striking peralkaline dykes of trachytic to phonolitic compositions intrude the KSC. Compositions of the KSC rocks span a considerable range in SiO2, 59–73 wt%. Concentrations of several elements vary widely for a given SiO2 (especially at SiO2 < 66 wt%), and variation diagrams do not suggest a single model for the evolution of the units of the complex. A cumulative origin is envisaged for several KSC units. Geochemical modelling suggests that KSC magmas were derived from more than one primary magma, and that the complex evolved through a four-stage process: fractional crystallisation in precursory magma chambers was followed by final emplacement of each unit, establishment of a crystal/melt mush, expulsion of part of the residual melt and, finally, crystallisation of the remaining melt. Trace element disequilibria between alkali feldspar and host rocks in two closely associated quartz alkali feldspar syenite units indicate that highly evolved residual melt was replaced by a less evolved melt phase. Modelling of potential parent melt compositions to the Kærven magmas suggests an origin not in the Iceland plume asthenosphere, but rather in a moderately enriched source, possibly in the continental lithosphere. The course of melt evolution by fractional crystallisation is indicated to have taken place in magma chambers at depth, and repeated rise of magma into the upper crustal magma chambers and crystallisation there formed the KSC. Based on our survey of published geochemical data, the inferred parental magmas seem to have few equivalents in the North Atlantic Igneous Province and may have been generated mainly from melting of enriched dry lithospheric mantle of possibly Archaean age.
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DAHLIN, PETER, ÅKE JOHANSSON, and ULF B. ANDERSSON. "Source character, mixing, fractionation and alkali metasomatism in Palaeoproterozoic greenstone dykes, Dannemora area, NE Bergslagen region, Sweden." Geological Magazine 151, no. 4 (August 13, 2013): 573–90. http://dx.doi.org/10.1017/s0016756813000551.

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AbstractThe geochemical and isotopic characteristics of metamorphosed Svecofennian mafic dykes from the Dannemora area in the NE part of the Bergslagen region in central Sweden were investigated and compared to mafic intrusive rocks in their vicinity. The dykes, with an inferred age of c. 1860–1870 Ma, are calc-alkaline, sub-alkaline and basaltic in composition and have a mixed subduction and within-plate geochemical affinity. They are the result of mixing of at least three mantle source components with similar basaltic major element composition, but different concentrations of incompatible trace elements. Magma M1 is strongly enriched both in Rare Earth Elements (REE) and High-Field-Strength Elements (HFSE); magma M2 is highly enriched in Large-Ion Lithophile Elements (LILE, except Sr) with only moderate enrichment in HFSE and REE (particularly low in Heavy Rare Earth Elements); and magma M3 is enriched in Sr and has a flat REE profile. Magma M3 also has a somewhat more positive (depleted) initial εNd value of +1.8, compared to +0.4 to +0.5 for magmas M1 and M2. The magma evolution was controlled by a mixture of fractionation (mainly affecting the compatible elements) and mixing, best seen in the incompatible element concentrations and the Nd isotope data. The basaltic overall composition indicates little or no wholesale contamination by upper continental crust, but the dykes have undergone later metasomatic changes mainly affecting the alkali elements.
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34

Ward, William R. "On the evolution of the protolunar disc." Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences 372, no. 2024 (September 13, 2014): 20130250. http://dx.doi.org/10.1098/rsta.2013.0250.

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The structure and viscous evolution of a post-impact, protolunar disc is examined. The equations for a silicate disc in two-phase (vapour–liquid) equilibrium are employed to derive an analytical solution to vertical structure. Both a vertically mixed phase disc and a stratified disc, where a magma layer exists in the mid-plane surrounded by a vapour reservoir, are considered. The former largely reproduces the low gas mass fraction, x ≪1, profiles of the disc described in earlier literature that proposed that the disc would hover on the brink of gravitational instability. In the latter, the vapour layer has x ∼1 and is generally gravitationally stable, while the magma layer is vigorously unstable. The viscous evolution of the stratified model is then explored. Initially, the disc quickly settles to a quasi-steady state with a vapour reservoir containing the majority of the disc mass. The magma layer viscously spreads on a time scale of approximately 3–4 years, during which vapour continuously condenses into droplets that settle to the mid-plane, maintaining the magma surface density in spite of disc spreading. Material flowing inwards is accreted by the Earth; material flowing outwards past the Roche boundary can become incorporated into accreting moonlets. This evolution persists until the vapour reservoir is depleted in approximately 50–100 years, depending on its initial mass.
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Ganne, Jérôme, Xiaojun Feng, Helen McFarlane, Mélina Macouin, Sonia Rousse, Seta Naba, Abraham Traoré, and Florent Hodel. "When Proterozoic Crusts Became Thick: New Insights from Magma Petrology." Geosciences 8, no. 12 (November 22, 2018): 428. http://dx.doi.org/10.3390/geosciences8120428.

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The Earth’s continental crust represents the outermost envelope of the solid Earth, controlling exchanges within the geosphere and reflecting geodynamics processes. One of the fundamental issues of Earth Science aims to determine crustal thickness in past geodynamic environments in order to discuss the evolution of certain geodynamic processes through time. Despite presenting a continuing challenge, the evolution of crustal thickness during the last 3 billion years can be investigated using indirect clues yielded by the chemical signature of mafic magmas and associated ferromagnesian minerals (pyroxene, amphibole). Here, we present a new statistical assessment of a global database of magmatic and mineral chemical information. Analysis reveals the increasing occurrence of high-temperature pyroxenes and amphiboles growing in Ca-rich, Fe-poor magma since ~1 Ga, which contrasts with lower temperature conditions of minerals crystallization throughout the Meso- and Palaeoproterozoic times. This is interpreted to reflect temporal changes in the control of Earth’s crust on mantle-derived magma composition, related to changes in lithospheric thickness and mantle secular cooling. We propose that thick existing crust is associated with deeper, hotter magmatic reservoirs, potentially elucidating the mineral chemistry and the contrasting iron content between primary and derivative mafic magmas. Based on both the chemical and mineral information of mafic magma, an integrated approach provides qualitative estimates of past crustal thickness and associated magmatic systems. Our findings indicate that the Proterozoic was characterized by thicker crustal sections (>40–50 km) relative to the Phanerozoic and Archean (<35 km). This period of crustal thickening appears at the confluence of major changes on Earth, marked by the onset of mantle cooling and Plate Tectonics and the assembly of Columbia, the first supercontinent.
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36

Rottier, Bertrand, Andreas Audétat, Peter Koděra, and Jaroslav Lexa. "Origin and Evolution of Magmas in the Porphyry Au-mineralized Javorie Volcano (Central Slovakia): Evidence from Thermobarometry, Melt Inclusions and Sulfide Inclusions." Journal of Petrology 60, no. 12 (December 1, 2019): 2449–82. http://dx.doi.org/10.1093/petrology/egaa014.

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Abstract The effect of magmatic sulfide precipitation on the potential of magmatic systems to produce porphyry-type ore deposits is still a matter of debate. In particular, we need to know whether magmatic sulfide precipitation has an impact on the Cu and Au content of the exsolving magmatic volatile phases and, by this way, on the Cu/Au ratio of porphyry deposits. The Javorie volcano is a perfect place to explore these questions. First, it hosts several Au-only porphyry-type mineralized occurrences which have among the lowest Cu/Au ratios reported in the literature. Secondly, the geology of the Javorie volcano and the timing of porphyry Au mineralization are well established. The evolution of the Javorie magmatic system was reconstructed by detailed petrographic studies and laser ablation inductively coupled plasma mass spectrometry analysis of minerals, melt inclusions and sulfide inclusions. The Javorie volcano was formed during the post-subduction magmatic activity affecting the Western Carpathians. It is a typical stratovolcano, composed dominantly of basaltic andesites and andesites which were intruded by several small stocks of dacitic to dioritic composition. According to our thermobarometric data, the volcano was fed by a transcrustal magmatic system in which two levels of magma chambers could be identified. Part of the magma evolved in the lower crust as suggested by the occurrence of magmatic garnet antecrysts in some of the studied rocks. The occurrence of magmatic sulfide inclusions in garnet indicates that sulfide saturation was reached in this lower crustal magma chamber. Most of the rocks crystallized in an upper crustal magma chamber (∼2 ± 1 kbar) that was fed by a basaltic to basaltic andesite magmas. A large variation in temperatures, ranging between 820°C and 1025°C, recorded by the extrusive and intrusive rocks suggest either that the upper crustal magma chamber was thermally zoned, or that the temperature of the whole magma chamber varied dramatically during its lifetime. Magmatic sulfide inclusions are present in all minerals and rocks of the upper crustal magma chamber, independent of their timing relative to porphyry Au mineralization (pre-, syn-, post-ore). These observations suggest that the magmatic system was sulfide saturated during its entire evolution. With very few exceptions, the precipitating sulfides were composed of monosulfide solid solution containing 0·2–9·2 wt % Cu and 0·05–11 ppm Au. The presence of these magmatic sulfides, together with results of a numerical model, suggest that the primitive magma feeding the upper crustal magma chamber contained less than 2·75 wt % H2O and that only a minor part of the magmatic sulfides was fractionated out of the system. Finally, the Cu/Au ratios measured in the magmatic sulfide inclusions and the ones predicted for the exsolved aqueous fluids are 10 to 100 times higher than the Cu/Au ratios of the porphyry deposits. Therefore, the extremely low Cu/Au ratios of the porphyry deposits must have been acquired during the hydrothermal stage.
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37

Oliver, N. H. S., and T. D. Barr. "The geometry and evolution of magma pathways through migmatites of the Halls Creek Orogen, Western Australia." Mineralogical Magazine 61, no. 404 (February 1997): 3–14. http://dx.doi.org/10.1180/minmag.1997.061.404.02.

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AbstractIn the Halls Creek Orogen of north-western Australia, the distance of melt migration through migmatitic metasedimentary rocks and adjacent metabasites is partly constrained by relationships of leucosomes and small mafic magma veins to rock boundaries and structural elements. Stromatic leucosomes in metasediments are cut by a network of small extensional fractures and shear zones, oriented steeply during melt migration. These shear zones allowed cm- to 10 m-scale migration of felsic magma derived by in situ anatexis. In the adjacent metabasite layers, a similar shear array allowed injection of H2O-undersaturated mafic to ultramafic magma, locally dehydrating and chemically modifying these rocks. However, these mafic to ultramafic veinlets are too mafic to be explained by in situ anatexis, necessitating an external magma source. Also, the lack of felsic veinlets cutting metabasites, and mafic veinlets cutting metasediments, requires that vertical inter-connectivity of these fracture systems was restricted. We propose along-layer migration of mafic to ultramafic magma through the metabasite, assisted by horizontal connection of the shear zones. This migration occurred independantly of metre-scale felsic magma migration in the adjacent metasediments, even though these two deformation-assisted magma migration systems may have been operating at the same time.
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38

Warren, P. H. "The Magma Ocean Concept and Lunar Evolution." Annual Review of Earth and Planetary Sciences 13, no. 1 (May 1985): 201–40. http://dx.doi.org/10.1146/annurev.ea.13.050185.001221.

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39

Liu, Ruoxin, Qicheng Fan, Xiangshen Zheng, Ming Zhang, and Ni Li. "The magma evolution of Tianchi volcano, Changbaishan." Science in China Series D: Earth Sciences 41, no. 4 (August 1998): 382–89. http://dx.doi.org/10.1007/bf02932689.

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40

Pe-Piper, Georgia, and David JW Piper. "Geochemical evolution of Devonian-Carboniferous igneous rocks of the Magdalen basin, Eastern Canada: Pb- and Nd-isotope evidence for mantle and lower crustal sources." Canadian Journal of Earth Sciences 35, no. 3 (March 1, 1998): 201–21. http://dx.doi.org/10.1139/e97-106.

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Magmatism associated with the extensional Magdalen basin includes voluminous tholeiitic gabbro and basalt and local granite and rhyolite. Pb- and (or) Nd-isotope determinations have been made on 70 igneous rocks from throughout the basin, and a further 15 samples of Avalonian basement from the southern margin of the basin, to characterize the contribution of lower crustal blocks and mantle sources to the magmatism and to constrain tectonic models for the basin. Five phases of magmatic evolution are distinguished in the Magdalen basin. (1) Middle to Late Devonian partial melting of lithospheric mantle, producing principally tholeiites and minor alkalic basalt. Tholeiites have Pb isotopic compositions similar to that of younger Triassic tholeiites generated from the same mantle, but experienced less crustal contamination. Regional variations in trace element composition of the mantle can be recognized. (2) The mafic magma triggered anhydrous base-of-crust melting, principally along the transpressive Cobequid and Rockland Brook faults, producing A-type granites in which radiogenic Pb increases northeastward. (3) In the latest Devonian, a large base-of-crust fractionating magma chamber evolved. It contained immiscible mafic and minor felsic magma, with uniform Nd isotopes, and high Ti in the mafic magma. (4) Although late Tournaisian dykes are not strongly fractionated, their evolution involved more crustal assimilation than earlier mafic rocks. (5) Local Viséan-Westphalian alkalic magmas, which ascended along crustal-scale faults, have Pb and Nd isotopic compositions resembling mantle plumes or their mixtures with lithospheric mantle sources. Only these youngest rocks show any isotopic evidence for input from an asthenospheric plume source, suggesting that regional extension was responsible for most of the magmatism.
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41

DINI, A., F. INNOCENTI, S. ROCCHI, S. TONARINI, and D. S. WESTERMAN. "The magmatic evolution of the late Miocene laccolith–pluton–dyke granitic complex of Elba Island, Italy." Geological Magazine 139, no. 3 (May 2002): 257–79. http://dx.doi.org/10.1017/s0016756802006556.

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Since late Miocene time, post-collisional extension of the internal parts of the Apennine orogenic belt has led to the opening of the Tyrrhenian basin. Extensive, mainly acidic peraluminous magmatism affected the Tuscan Archipelago and the Italian mainland during this time, building up the Tuscan Magmatic Province as the fold belt was progressively thinned, heated and intruded by mafic magmas. An intrusive complex was progressively built on western Elba Island by emplacement, within a stack of nappes, of multiple, shallow-level porphyritic laccoliths, a major pluton, and a final dyke swarm, all within the span from about 8 to 6.8 Ma. New geochemical and Sr–Nd isotopic investigations constrain the compositions of materials involved in the genesis of the magmas of Elba Island compared to the whole Tuscan Magmatic Province. Several distinct magma sources, in both the crust and mantle, have been identified as contributing to the Elba magmatism as it evolved from crust-, to hybrid-, to mantle-dominated. However, a restricted number of components, geochemically similar to mafic K-andesites of the Island of Capraia and crustal melts like the Cotoncello dyke at Elba, are sufficient to account for the generation by melt hybridization of the most voluminous magmas (c. εNd(t) −8.5, 87Sr/86Sr 0.715). Unusual magmas were emplaced at the beginning and end of the igneous activity, without contributing to the generation of these hybrid magmas. These are represented by early peraluminous melts of a different crustal origin (εNd(t) between −9.5 and −10.0, 87Sr/86Sr variable between 0.7115 and 0.7146), and late mantle-derived magma strongly enriched in incompatible elements (εNd(t) = −7.0, 87Sr/86Sr = 0.7114) with geochemical–isotopic characteristics intermediate between contemporaneous Capraia K-andesites and later lamproites from the Tuscan Magmatic Province. Magmas not involved in the generation of the main hybrid products are not volumetrically significant, but their occurrence emphasizes the highly variable nature of crust and mantle sources that can be activated in a short time span during post-collisional magmatism.
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42

Upton, Brian G. J. "Tectono-magmatic evolution of the younger Gardar southern rift, South Greenland." Geological Survey of Denmark and Greenland (GEUS) Bulletin 29 (November 8, 2013): 1–24. http://dx.doi.org/10.34194/geusb.v29.4692.

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The 1300–1140 Ma Gardar period in South Greenland involved continental rifting, sedimentation and alkaline magmatism. The latest magmatism was located along two parallel rift zones, Isortoq–Nunarsuit in the north and the Tuttutooq–Ilimmaasaq–Narsarsuaq zone in the south addressed here. The intrusive rocks crystallised at a depth of troctolitic gabbros. These relatively reduced magmas evolved through marked iron enrichment to alkaline salic differentiates. In the Older giant dyke complex, undersaturated augite syenites grade into sodalite foyaite. The larger, c . 1163 Ma Younger giant dyke complex (YGDC) mainly consists of structureless troctolite with localised developments of layered cumulates. A layered pluton (Klokken) is considered to be coeval and presumably comagmatic with the YGDC. At the unconformity between the Ketilidian basement and Gardar rift deposits, the YGDC expanded into a gabbroic lopolith. Its magma may represent a sample from a great, underplated mafic magma reservoir, parental to all the salic alkaline rocks in the southern rift. The bulk of these are silica undersaturated; oversaturated differentiates are probably products of combined fractional crystallisation and crustal assimilation. A major dyke swarm 1–15 km broad was intruded during declining crustal extension, with decreasing dyke widths and increasing differentiation over time. Intersection of the dyke swarm and E–W-trending sinistral faults controlled the emplacement of at least three central complexes (Narssaq, South Qôroq and early Igdlerfigssalik). Three post-extensional complexes (Tugtutôq, Ilímaussaq and late Igdlerfigssalik) along the former rift mark the end of magmatism at c . 1140 Ma. The latter two complexes have oblate plans reflecting ductile, fault-related strain. The Tugtutôq complex comprises quartz syenites and alkali granites. The Ilímaussaq complex mainly consists of nepheline syenite crystallised from highly reduced, Fe-rich phonolitic peralkaline (agpaitic) magma, and resulted in rocks with very high incompatible element concentrations. Abundant anorthositic xenoliths in the mafic and intermediate intrusions point to a large anorthosite protolith at depth which is considered of critical importance in the petrogenesis of the salic rocks. Small intrusions of aillikite and carbonatite may represent remobilised mantle metasomites. The petrological similarity between Older and Younger Gardar suites implies strong lithospheric control of their petrogenesis. The parental magmas are inferred to have been derived from restitic Ketilidian lithospheric mantle, metasomatised by melts from subducting Ketilidian oceanic crust and by small-scale melt fractions associated with Gardar rifting. There are numerous analogies between the southern Gardar rift and the Palaeogene East African rift.
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43

Kemp, A. I. S., C. J. Hawkesworth, B. A. Paterson, G. L. Foster, P. D. Kinny, M. J. Whitehouse, R. Maas, and EIMF. "Exploring the plutonic-volcanic link: a zircon U-Pb, Lu-Hf and O isotope study of paired volcanic and granitic units from southeastern Australia." Transactions of the Royal Society of Edinburgh: Earth Sciences 97, no. 4 (2008): 337–55. http://dx.doi.org/10.1017/s0263593300001498.

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AbstractThe relationship between plutonic and volcanic rocks is central to understanding the geochemical evolution of silicic magma systems, but it is clouded by ambiguities associated with unravelling the plutonie record. Here we report an integrated U-Pb, O and Lu-Hf isotope study of zircons from three putative granitic-volcanic rock pairs from the Lachlan Fold Belt, southeastern Australia, to explore the connection between the intrusive and extrusive realms. The data reveal contrasting petrogenetic scenarios for the S- and I-type pairs. The zircon Hf-O isotope systematics in an 1-type dacite are very similar to those of their plutonie counterpart, supporting an essentially co-magmatic relationship between these units. The elevated δ18O of zircons in these I-type rocks confirm a significant supracrustal source component. The S-type volcanic rocks are not the simple erupted equivalents of the granites, although the extrusive and plutonie units can be related by open-system magmatic evolution. Zircons in the S-type rocks define covariant εΗf—βO arrays that attest to mixing or assimilation processes between two components, one being the Ordovician metasedimentary country rocks, the other either an I-type magma or a mantle-derived magma. The data are consistent with models involving incremental melt extraction from relatively juvenile magmas undergoing open-system differentiation at depth, followed by crystal-liquid mixing upon emplacement in shallow magma reservoirs, or upon eruption. The latter juxtaposes crystals with markedly different petrogenetic histories and determines whole-rock geochemical and textural properties. This scenario can explain the puzzling decoupling between the bulk rock isotope and geochemical compositions commonly observed for granite suites.
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44

Shcherbakov, Vasily, Ilya Bindeman, and Viktor Gazeev. "Geochemical, Isotopic and Petrological Constraints on the Origin and Evolution of the Recent Silicic Magmatism of the Greater Caucasus." Minerals 12, no. 1 (January 16, 2022): 105. http://dx.doi.org/10.3390/min12010105.

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Significant volumes of rhyolites and granites of the Pliocene-Pleistocene age are exposed in the collision zone of the Greater Caucasus, Russia. The volcanic history of the region includes ignimbrites and lavas associated with the Chegem caldera (2.9 Ma) and Elbrus volcano (1.98 and 0.7 Ma) and rhyolitic necks and granites in Tyrnyauz (1.98 Ma). They are characterized by a similar bulk and mineral composition and close ratios of incompatible elements, which indicates their related origin. The 1.98 Ma Elbrus ignimbrites, compared to the 2.9 Ma Chegem ignimbrites, have elevated concentrations of both compatible (Cr, Sr, Ca, Ni) and incompatible elements (Cs, Rb, U). We argue that the Elbrus ignimbrites were produced from magma geochemically similar to Chegem rhyolites through fractionation crystallization coupled with the assimilation of crustal material. The 1.98 Ma Eldjuta granites of Tyrnyauz and early ignimbrites of the Elbrus region (1.98 Ma) are temporally coeval, similar mineralogically, and have comparable major and trace element composition, which indicates that the Elbrus ignimbrites probably erupted from the area of modern Tyrnyauz; the Eldjurta granite could represent a plutonic reservoir that fed this eruption. Late ignimbrites of Elbrus (0.7 Ma) and subsequent lavas demonstrate progressively more mafic mineral assemblage and bulk rock composition in comparison with rhyolites. This indicates their origin in response to the mixing of rhyolites with magmas of a more basic composition at the late stage of magma system development. The composition of these basic magmas may be close to the basaltic trachyandesite, the flows exposed along the periphery of the Elbrus volcano. All studied young volcanic rocks of the Greater Caucasus are characterized by depletion in HSFE and enrichment in LILE, Li, and Pb, which emphasizes the close relationship of young silicic magmatism with magmas of suprasubduction geochemical affinity. An important geochemical feature is the enrichment of U up to 8 ppm and Th up to 35 ppm. The trace element composition of the rocks indicates that the original rhyolitic magma of Chegem ignimbrites caldera was formed at >80%–90% fractionation of calc-alkaline arc basalts with increased alkalinity. This observation, in addition to published data for isotopic composition (O-Hf-Sr) of the same units, shows that the crustal isotopic signatures of silicic volcanics may arise due to the subduction-induced fertilization of peridotites producing parental basaltic magmas before a delamination episode reactivated the melting of the former mantle and the lower crust.
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45

Ridley, J. R., and J. D. Kramers. "The evolution and tectonic consequences of a tonalitic magma layer within Archean continents." Canadian Journal of Earth Sciences 27, no. 2 (February 1, 1990): 219–28. http://dx.doi.org/10.1139/e90-022.

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The petrological and tectonic consequences of early continent formation by localized open-system fractional crystallization of an almost global shallow-level tholeiitic magma layer are investigated. A near-surface tonalitic–trondhjemitic–granodioritic (TTG) magma "ocean", evolved by such a process near mantle sinks, would rapidly crystallize a stably floating solid upper crust several kilometres thick and could therefore be a long-lived feature of Archean geology. Given likely mantle heat fluxes, crystallization of the molten layer resulting from secular cooling and movement from mantle-upwelling to -downwelling regions would normally be from the top downward. In areas of extremely low mantle heat flow, crystallization from the base upward is also possible.The partially molten layer will convect with cells on a much smaller scale than those in the underlying mantle. This convection will influence tectonic patterns in the overlying solid crust, the history of which will be largely independent of specific mantle convection patterns. Small-amplitude surface topography is predicted. Intrusion of mafic or ultramafic magmas to high levels would not be possible through tonalite with a melt proportion greater than about 40% and is likely therefore to be concentrated at cooler, downwelling zones of the small-scale convection system. These two predictions together suggest that Archean greenstone belts form over local downwarping zones of TTG crust. Early, shelf-facies sedimentation is related to convection-induced topographic relief, whereas later, higher energy sedimentation is related to gravitational instability resulting from localized loading of the crust.So long as a continental magma layer is continually replenished by tholeiite melt, its composition remains essentially tonalitic. When it ceases to be replenished, fractionation will give rise to granitic melts that through their lower density will increase the gravitational instability of the Archean crust.
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46

Zhang, Jisheng, and Leslie A. Rogers. "Thermal Evolution and Magnetic History of Rocky Planets." Astrophysical Journal 938, no. 2 (October 1, 2022): 131. http://dx.doi.org/10.3847/1538-4357/ac8e65.

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Abstract We present a thermal evolution model coupled with a Henyey solver to study the circumstances under which a rocky planet could potentially host a dynamo in its liquid iron core and/or magma ocean. We calculate the evolution of planet thermal profiles by solving the energy-balance equations for both the mantle and the core. We use a modified mixing length theory to model the convective heat flow in both the magma ocean and solid mantle. In addition, by including the Henyey solver, we self-consistently account for adjustments in the interior structure and heating (cooling) due to planet contraction (expansion). We evaluate whether a dynamo can operate using the critical magnetic Reynolds number. We run simulations to explore how the planet mass (M pl), core mass fraction (CMF), and equilibrium temperature (T eq) affect the evolution and lifetime of possible dynamo sources. We find that the T eq determines the solidification regime of the magma ocean, and only layers with melt fraction greater than a critical value of 0.4 may contribute to the dynamo source region in the magma ocean. We find that the mantle mass, determined by M pl and CMF, controls the thermal isolating effect on the iron core. In addition, we show that the liquid core lasts longer with increasing planet mass. For a core thermal conductivity of 40 Wm−1 K−1, the lifetime of the dynamo in the iron core is limited by the lifetime of the liquid core for 1 M ⊕ planets and by the lack of thermal convection for 3 M ⊕ planets.
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47

Wade, C. E., J. L. Payne, K. Barovich, S. Gilbert, B. P. Wade, J. L. Crowley, A. Reid, and E. A. Jagodzinski. "ZIRCON TRACE ELEMENT GEOCHEMISTRY AS AN INDICATOR OF MAGMA FERTILITY IN IRON OXIDE COPPER-GOLD PROVINCES." Economic Geology 117, no. 3 (May 1, 2022): 703–18. http://dx.doi.org/10.5382/econgeo.4886.

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Abstract Extrusive and intrusive felsic magmas occur throughout the evolution of silicic-dominated large igneous province magmatism that is temporally related to numerous economically significant iron oxide copper-gold (IOCG) deposits in southern Australia. We investigate zircon trace element signatures of the felsic magmas to assess whether zircon composition can be related to fertility of the volcanic and intrusive suites within IOCG-hosted mineral provinces. Consistent with zircon forming in oxidizing magmatic conditions, the rare earth element (REE) patterns of zircon sourced from both extrusive and intrusive magmatic rocks are characterized by light REE depletions and a range of positive Ce and negative Eu anomalies. The timing of the major phase of IOCG mineralization overlaps with the early part of the first phase of Lower Gawler Range Volcanics magmatism (1593.6–1590.4 Ma) and older intrusive magmatism of the Hiltaba Suite (1593.06–1590.50 Ma). Zircon in these mineralization-related intrusives and extrusives is distinguished from zircon in younger, mineralization-absent rocks by higher Eu/Eu*, Ce/Ce*, and Ti values and separate magma evolution paths with respect to Hf. These zircon characteristics correspond to lower degrees of fractionation and/or crustal assimilation, more oxidizing magmatic conditions, and higher magmatic temperatures, respectively, in magmas coeval with mineralization. In this respect, we consider higher oxidation state, lower degrees of fractionation, and higher magmatic temperatures to be features of fertile magmas in southern Australian IOCG terrains. Similar zircon REE characteristics are shared between magmas associated with southern Australian IOCG and iron oxide-apatite (IOA) rhyolites from the St. Francois Mountains, Missouri, namely high Ce/Ce* and high Dy/Yb, indicative of oxidized and dry magmas, respectively. The dry and more fractionated nature of the IOCG- and IOA-associated magmas contrasts with the hydrous and unfractionated nature of fertile porphyry Cu deposit magmas. As indicated by high Ce/Ce* ratios, the oxidized nature is considered a key element in magma fertility in IOCG-IOA terrains. In both IOCG and IOA terrains, the trace element compositions of zircon are able to broadly differentiate fertile from nonfertile magmatic rocks.
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48

Gagnevin, D., J. S. Daly, and G. Poli. "Insights into granite petrogenesis from quantitative assessment of the field distribution of enclaves, xenoliths and K-feldspar megacrysts in the Monte Capanne pluton, Italy." Mineralogical Magazine 72, no. 4 (August 2008): 925–40. http://dx.doi.org/10.1180/minmag.2008.072.4.925.

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AbstractA detailed field study to determine quantitatively the distribution of K-feldspar megacrysts, mafic microgranular enclaves (MME) and metasedimentary xenoliths has been carried out in the Monte Capanne pluton (Elba, Italy) with a view to evaluating the utility of this approach to petrogenetic investigations. Mafic microgranular enclaves are inferred to result from interactions between mafic and felsic magmas, while xenoliths attest to crustal assimilation occurring in the Monte Capanne magma chamber. In particular, we emphasize, based on our field data, that both processes are intimately linked, such that xenolith dissolution during assimilation was triggered by replenishment with hot mafic magma. It is suggested that the previously defined ‘San Piero’ and ‘San Francesco’ facies do not differ substantially, and are thus amalgamated and renamed as the ‘Pomonte’ facies. Results also indicate that the abundance of K-feldspar megacrysts is positively correlated with the volumetric abundance of MME in the Sant’ Andrea facies, which we link to a recharging, mingling and textural coarsening event that occurred at a rather late stage of magma-chamber evolution prior to emplacement. This study demonstrates how petrogenetic processes can be deciphered by detailed field quantitative analyses of granite-forming components, thus complementing geochemical investigations.
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Piquer, José, Pablo Sanchez-Alfaro, and Pamela Pérez-Flores. "A new model for the optimal structural context for giant porphyry copper deposit formation." Geology 49, no. 5 (January 26, 2021): 597–601. http://dx.doi.org/10.1130/g48287.1.

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Abstract Porphyry-type deposits are the main global source of copper and molybdenum. An improved understanding of the most favorable structural settings for the emplacement of these deposits is necessary for successful exploration, particularly considering that most future discoveries will be made under cover based on conceptual target generation. A common view is that porphyry deposits are preferentially emplaced in pull-apart basins within strike-slip fault systems that favor local extension within a regional compressive to transpressive tectonic regime. However, the role of such a structural context in magma storage and evolution in the upper crust remains unclear. In this work, we propose a new model based on the integration of structural data and the geometry of magmatic-hydrothermal systems from the main Andean porphyry Cu-Mo metallogenic belts and from the active volcanic arc of southern Chile. We suggest that the magma differentiation and volatile accumulation required for the formation of a porphyry deposit is best achieved when the fault system controlling magma ascent is strongly misoriented for reactivation with respect to the prevailing stress field. When magmas and fluids are channeled by faults favorably oriented for extension (approximately normal to σ3), they form sets of parallel, subvertical dikes and veins, which are common both during the late stages of the evolution of porphyry systems and in the epithermal environment. This new model has direct implications for conceptual mineral exploration.
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Jäggi, Noah, Diana Gamborino, Dan J. Bower, Paolo A. Sossi, Aaron S. Wolf, Apurva V. Oza, Audrey Vorburger, André Galli, and Peter Wurz. "Evolution of Mercury’s Earliest Atmosphere." Planetary Science Journal 2, no. 6 (November 17, 2021): 230. http://dx.doi.org/10.3847/psj/ac2dfb.

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Abstract MESSENGER observations suggest a magma ocean formed on proto-Mercury, during which evaporation of metals and outgassing of C- and H-bearing volatiles produced an early atmosphere. Atmospheric escape subsequently occurred by plasma heating, photoevaporation, Jeans escape, and photoionization. To quantify atmospheric loss, we combine constraints on the lifetime of surficial melt, melt composition, and atmospheric composition. Consideration of two initial Mercury sizes and four magma ocean compositions determines the atmospheric speciation at a given surface temperature. A coupled interior–atmosphere model determines the cooling rate and therefore the lifetime of surficial melt. Combining the melt lifetime and escape flux calculations provides estimates for the total mass loss from early Mercury. Loss rates by Jeans escape are negligible. Plasma heating and photoionization are limited by homopause diffusion rates of ∼106 kg s−1. Loss by photoevaporation depends on the timing of Mercury formation and assumed heating efficiency and ranges from ∼106.6 to ∼109.6 kg s−1. The material for photoevaporation is sourced from below the homopause and is therefore energy limited rather than diffusion limited. The timescale for efficient interior–atmosphere chemical exchange is less than 10,000 yr. Therefore, escape processes only account for an equivalent loss of less than 2.3 km of crust (0.3% of Mercury’s mass). Accordingly, ≤0.02% of the total mass of H2O and Na is lost. Therefore, cumulative loss cannot significantly modify Mercury’s bulk mantle composition during the magma ocean stage. Mercury’s high core:mantle ratio and volatile-rich surface may instead reflect chemical variations in its building blocks resulting from its solar-proximal accretion environment.
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