Academic literature on the topic 'Exo-tricyclo[5.2.1.02'

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Journal articles on the topic "Exo-tricyclo[5.2.1.02"

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Bosman, W. P., J. M. M. Smits, Paul T. Beurskens, P. P. M. A. Dols, and A. J. H. Klunder. "Crystal and molecular structure ofexo,exo-8,9-diiodo-5-methyl-exo-tricyclo [5.2.1.02, 6]dec-4-en-3-one, C11H12I2O." Journal of Crystallographic and Spectroscopic Research 23, no. 12 (1993): 1025–27. http://dx.doi.org/10.1007/bf01185556.

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Vasilkevich, Oleksandr, Yurii Klimko та Svyatoslav Levandovskii. "SYNTHESIS AND BIOLOGICAL ACTIVITY OF SOME 2-SUBSTITUTED DERIVATIVES OF TRICYCLO [5.2.1.02,6]DEСAN". Deutsche internationale Zeitschrift für zeitgenössische Wissenschaft 84 (16 липня 2024): 15–18. https://doi.org/10.5281/zenodo.12752511.

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Based on individual exo- and endo-isomers of tricyclo[5.2.1.02.6]deca-2-carboxylic acid, various nitrogencontaining derivatives were synthesized: amides, thioamides, amines, alkylamines, amidines. Antiviral properties tested.
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Childs, Ronald F., Barry M. Duffey, and Mailvaganam Mahendran. "Photoisomerization of the AlEtCl2 complex of endo-tricyclo[5.2.1.02,6]deca-4,8-dien-3-one." Canadian Journal of Chemistry 64, no. 6 (1986): 1220–23. http://dx.doi.org/10.1139/v86-202.

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Irradiation of the AlEtCl2 complex of endo-tricyclo[5.2.1.02,6]deca-4,8-dien-3-one (1AL) yielded the AlEtCl2 complex of exo-tricyclo[5.3.0.02,6]deca-4,8-dien-3-one (3AL). The structure of 3, which was obtained on treatment of the irradiated solution with water, was established by its reduction to give the known exo-tricyclo[5.3.0.02,6]decan-3-one. The photoisomerization of 1AL could not be driven to completion as 3AL underwent a photoisomerization to regenerate 1AL. Control experiments showed that the interconversions of 1AL and 3AL were photochemically and not thermally induced. Irradiation o
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Ragauskas, Arthur J., and J. B. Stothers. "13C magnetic resonance studies. 120. The Simmons–Smith reaction with some silyl enol ethers. Unusual ring expansions of some norcamphorsti." Canadian Journal of Chemistry 63, no. 11 (1985): 2969–74. http://dx.doi.org/10.1139/v85-492.

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Unexpected difficulties with Simmons–Smith cyclopropanation of the trimethylsilyl enol ether of exo-tricyclo[3.2.1.02,4]-octan-6-one led to a reexamination of this reaction with the parent norcamphor derivative which under "concentrated" conditions gave ring-expanded allylic ethers in low yield. With the tert-butyldimethylsilyl ethers, however, the allylic product is formed in high yield in the norcamphor and exo-trimethylenenorcamphor (tricyclo[5.2.1.02,6]decan-8-one) systems. The tert-butyldimethylsilyl enol ethers of bicyclo[3.2.1]octan-6-one and nopinone do not undergo ring expansion under
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Kazakov, A. I., L. S. Yanovskiy, Yu V. Tomilov, et al. "Thermal Decomposition of Synthetic Cage Hydrocarbons and Their Mixtures." Нефтехимия 63, no. 2 (2023): 268–76. http://dx.doi.org/10.31857/s0028242123020119.

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The kinetics of thermal decomposition of cage hydrocarbons, specifically exo-tricyclo[5.2.1.02.6]decane (exo-TCD) and exo,endo-tetracyclo[5.3.1.02,6.08,10]undecane (TCU-1, a monocyclo­propanated analog of exo-TCD), as well as their mixture (1 : 3 w/w) has been investigated. These compounds were compared in terms of thermal stability. The molar concentrations of the resultant gaseous products were determined experimentally. The equilibrium composition of the decomposition products was quantified, and the thermal effects of the thermal decomposition under thermodynamic and kinetic reaction contr
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Clements, Michael T. M., Ross E. Klinck, Sriyawathie Peiris, Arthur J. Ragauskas та J. B. Stothers. "13C magnetic resonance studies 133. An examination of the effect of conformation on β-enolization in some bicyclo[3.2.1]octan-2-ones". Canadian Journal of Chemistry 66, № 3 (1988): 454–60. http://dx.doi.org/10.1139/v88-079.

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To assess the influence of the conformation of the cyclohexanone moiety in bicyclo[3.2.1]octan-2-ones on the reactivity for β-enolate rearrangement, the behavior of three derivatives under typical homoenolization conditions has been examined for comparison with 3,3-dimethylbicyclo[3.2.1]octan-2-one (1), which was known to be smoothly converted to the [3.3.0] isomer 2. For this purpose, endo-3-tert-butyl-exo-3-methylbicyclo[3.2.1]octan-2-one (8), endo-9-tert-butyl-exo-9-methyl-exo-tricyclo[5.3.1.02,6]undecan-8-one (9), and 9,9-dimethyl-endo-tricyclo[5.3.1.02,6]undecan-8-one (10) were prepared a
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Haufe, G�nter, Ren� Faure, and Henri Loiseleur. "Crystal and molecular structure ofanti,exo,exo-5,10,12-tribromo-13-oxa-exo-tricyclo [7.3.1.02,6] tridecane." Journal of Crystallographic and Spectroscopic Research 17, no. 5 (1987): 653–59. http://dx.doi.org/10.1007/bf01167122.

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Koshchii, I., O. Vasilkevich, and Yu. Klimko. "BECKMAN REACTION OF KETOXIMES OF THE TRICYCLO[5.2.1.02,6]DECAN SERIES WITH THIONYL CHLORIDE." Sciences of Europe, no. 145 (July 26, 2024): 15–20. https://doi.org/10.5281/zenodo.12909376.

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As a result of the Beckmann reaction, the oximes tricyclo[5.2.1.02,6]decan-9-one, tricyclo[5.2.1.02,6]dec-3-en-9-one and tricyclo[5.2.1.02,6]dec-4-ene -9-one with thionyl chloride forms transmutation products - lactams and fragmentation products - unsaturated nitriles and isomeric chloronitriles.
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Liaw, Der-Jang, Been-Yang Liaw, and En-Tang Kang. "Synthesis and characterization of new cardo polyamide-imides containing ether and tricyclo[5.2.1.02, 6]decane groups." Macromolecular Chemistry and Physics 200, no. 10 (1999): 2402–6. http://dx.doi.org/10.1002/(sici)1521-3935(19991001)200:10<2402::aid-macp2402>3.0.co;2-c.

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Burritt, Andrew, James M. Coxon, Peter J. Steel, and Barry I. Whittington. "Bromination of exo- and endo-Tricyclo[3.2.1.02,4]octane." Journal of Organic Chemistry 60, no. 9 (1995): 2812–19. http://dx.doi.org/10.1021/jo00114a034.

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Dissertations / Theses on the topic "Exo-tricyclo[5.2.1.02"

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Herberth, Edith. "Hydro- und Carboborierungs-/Oxidationsreaktionen von Tricyclo[4.1.0.02,7]heptan-Derivaten sowie Synthese und Solvolyse-Reaktionen von exo,exo-Bicyclo[1.1.0]butan-2,4-dimethanoldimethansulfonat." Doctoral thesis, 2002. https://nbn-resolving.org/urn:nbn:de:bvb:20-opus-4952.

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Die bekannte Umwandlung des Bromtricycloheptans 4 in den Homoallylalkohol 76 durch Hydroborierung/Oxidation wurde anders als früher mit einer in situ aus Natriumborhydrid und elementarem Iod erzeugten Boran-THF-Lösung bewirkt. Darüber hinaus konnten unter den gleichen Bedingungen das Chlortricycloheptan 26 und das Methyltricycloheptan 62 in den Homoallylalkohol 108 bzw. 109 überführt werden. Über 4, 26, 62 und das Phenyltricycloheptan 15 hinaus, dessen Hydroborierung/ Oxidation zum Homoallylalkohol 45a schon früher gelungen war, wurde eine Reihe von Bicyclo[1.1.0]butan-Derivaten mit Boran beha
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Herberth, Edith [Verfasser]. "Hydro- und Carboborierungs-, Oxidationsreaktionen von Tricyclo[4.1.0.02,7]heptan-Derivaten sowie Synthese und Solvolyse-Reaktionen von exo,exo-Bicyclo[1.1.0]butan-2,4-dimethanoldimethansulfonat / vorgelegt von Edith Herberth." 2003. http://d-nb.info/967860105/34.

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