Academic literature on the topic 'Fe(CN)6'

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Journal articles on the topic "Fe(CN)6"

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Ganguli, S., S. Das, and M. Bhattacharya. "Preparation of57Fe enriched K4[Fe(CN)6] and K3[Fe(CN)6]." Journal of Radioanalytical and Nuclear Chemistry 232, no. 1-2 (1998): 229–31. http://dx.doi.org/10.1007/bf02383744.

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Andriukonis, Eivydas, Almira Ramanaviciene, and Arunas Ramanavicius. "Synthesis of Polypyrrole Induced by [Fe(CN)6]3− and Redox Cycling of [Fe(CN)6]4−/[Fe(CN)6]3−." Polymers 10, no. 7 (2018): 749. http://dx.doi.org/10.3390/polym10070749.

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Stieble, M., and K. Jüttner. "Surface blocking in the redox system Pt/[Fe(CN)6]3−,[Fe(CN)6]4−." Journal of Electroanalytical Chemistry and Interfacial Electrochemistry 290, no. 1-2 (1990): 163–80. http://dx.doi.org/10.1016/0022-0728(90)87428-m.

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Nanba, Yūsuke, and Kozo Okada. "Charge Transfer Effects on Fe 2p X-ray Photoemission of RbMn[Fe(CN)6], K3Fe(CN)6, and K4Fe(CN)6." Journal of the Physical Society of Japan 80, no. 7 (2011): 074710. http://dx.doi.org/10.1143/jpsj.80.074710.

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Trung, Nguyen Dinh, Le Thi Ha Lan, and Truong Dong Phuong. "Investigate the adsorption of cesium ion (Cs+) on Zn2[Fe(CN)6] AND Zn3[Fe(CN)6]2 nanoparticles." Science and Technology Development Journal - Natural Sciences 3, no. 4 (2020): 307–16. http://dx.doi.org/10.32508/stdjns.v3i4.524.

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Adsorption of Cs+ ion from aqueous solution by Zn2[Fe(CN)6] and Zn3[Fe(CN)6]2 nanoparticle, and the effect of experimental conditions on the adsorption were investigated. Preliminary results showed that two materials were very efficient as an absorbent. Zn2[Fe(CN)6] and Zn3[Fe(CN)6]2 nanoparticle adsorbents for removal Cs+ion from solution have been successfully synthesized. Comparison between two materials, the Cs + ion adsorption capacity of Zn2[Fe(CN)6] was higher than Zn3[Fe(CN)6]2 and the reaction time was shorter. The adsorption equilibrium time of Zn3[Fe(CN)6]2 was about 20 hours, and the suitable pH range 3-7 while the Zn2[Fe(CN)6] was 15 minutes. The Cs+ ion absorption by Zn2[Fe(CN)6] nanoparticle follow the ion exchange mechanism, the best exchange capacities of the material were in the pH 3-5 range, ion exchange capacity depended on the pH, the maximum ion exchange capacity of the material at pH = 4 was 1.01 meq (Cs+) / g. After 15 min, about 98% of initial Cs+ ion concentration was removed from the solution; the adsorption data did not accord with Langmuir and Freundlich isotherms. The high adsorption capacity and good performance on other aspects, make the Zn2[Fe(CN)6] nanoparticle a promising adsorbent for the removal of Cs+ ion from water.
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Xia, Yanfang, Ge Zhang, Min Liu, and Duxin Li. "Magnetic Properties of Polycrystalline Compounds Cu0.64Mn0.86[Fe(CN)6]·7.2H2O and Cu0.84Mn0.66[Fe(CN)6]·7.1H2O." Journal of Superconductivity and Novel Magnetism 32, no. 12 (2019): 3831–35. http://dx.doi.org/10.1007/s10948-019-05166-w.

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Hurlen, T., and W. Wilhelmsen. "Kinetics of the Fe(CN)3-6/Fe(CN)4-6 couple at passive titanium electrodes." Electrochimica Acta 33, no. 12 (1988): 1729–33. http://dx.doi.org/10.1016/0013-4686(88)85007-2.

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Pechenyuk, Sofiya I., Denis P. Domonov, Alevtina N. Gosteva, Yuliya P. Semushina, and Alexey A. Shimkin. "THERMAL BEHAVIOR OF DOUBLE COMPLEXES [Co(NH3)6][Fe(CN)6] AND [CO(en)3][Fe(CN)6]·2H2O." IZVESTIYA VYSSHIKH UCHEBNYKH ZAVEDENIY KHIMIYA KHIMICHESKAYA TEKHNOLOGIYA 61, no. 4-5 (2018): 49. http://dx.doi.org/10.6060/tcct.20186104-05.5617.

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Thermal behavior of double complex compounds (DCC) of first transition metal row has been studied on the example of [СоA6][Fe(CN)6] (A = NH3, C2H8N2/2) in oxidative(air), inert(argon, nitrogen, helium) and reductive(hydrogen) atmospheres. The analysis of solid and gaseous thermolysis products has been performed for separate temperature ranges. The TG curves of the thermolysis first stage coincide with each other for all the investigated atmospheres up to approximately 300 °C. DCC [Со(NH3)6][Fe(CN)6] (I) and [Со(en)3][Fe(CN)6] (II) undergo to first stage of thermal decomposition with the removal of the part of neutral ligands and 1-2, but not more as 3 CN groups in temperature range of 160-300 and 200-350°С in oxidative and 160-400 and 210-550 °С, in inert medium, respectively. DCC I forms the intermediate [(NH3)2CoFeC4N3], [(NH3)2.6CoFe(CN)5] and [(NH3)3CoFe(CN)4.3] at 330, 350 и 430 °С in atmosphere of air, argon and hydrogen. For DCC II the intermediates are not registered. At temperatures above 300 °C the TG curves diverge and relate already to the interaction of thermolysis products with the gaseous medium. The thermolysis in argon and hydrogen is accompanied by partial reduction of ligands and central atoms of DCCs, thermolysis in the air atmosphere - complete oxidation of ligands and central ions. The thermal behavior of DCC is compared with the thermal behavior of 3d metals cationic complexes on base of literature data. The thermolysis of all the DCC and cation complexes discussed here proceeds with the removal of neutral ligands in the temperature range of 50-400 °C. For citation:Pechenyuk S.I., Domonov D.P., Gosteva A.N., Semushina Yu.P., Shimkin A.A. Thermal behavior of double complexes [Co(NH3)6][Fe(CN)6] and [Co(en)3][Fe(CN)6]·2H2O. Izv. Vyssh. Uchebn. Zaved. Khim. Khim. Tekhnol. 2018. V. 61. N 4-5. P. 49-56
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Shilov, V. P., A. A. Bessonov, and A. M. Fedoseev. "The reaction Pu(VI) + Fe(CN) 6 3− ⇄ Pu(VII) + Fe(CN) 6 4− in NaOH solutions." Radiochemistry 51, no. 6 (2009): 594–97. http://dx.doi.org/10.1134/s106636220906006x.

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Kunimatsu, K., Y. Shigematsu, K. Uosaki, and H. Kita. "Study of the Fe(CN)3−6/Fe(CN)4−6 redox system on Pt by EMIRS." Journal of Electroanalytical Chemistry and Interfacial Electrochemistry 262, no. 1-2 (1989): 195–209. http://dx.doi.org/10.1016/0022-0728(89)80022-1.

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Dissertations / Theses on the topic "Fe(CN)6"

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Stolpe, Amanda. "The Influence of Synthesis Conditions on the Formation of the Prussian Blue Analogue Cu[Fe(CN)6]2/3 ∙ nH2O." Thesis, Uppsala universitet, Institutionen för kemi - BMC, 2019. http://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-385906.

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Eni, Eni Sammy. "Determination of the Activation Parameters of Reaction Between [Fe(CN6]-4 and K[Co(HEDTA)NO2]." Digital Commons @ East Tennessee State University, 2009. https://dc.etsu.edu/etd/1798.

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The kinetics of the oxidation of [Fe(CN)6]-4 by K[Co(HEDTA)NO2] was studied in order to get the mechanism and the activation parameters of the reaction. Using a freshly-made Na3PO4 solution as the reaction medium with a pH of 6.00 the ionic strength was maintained at 0.10 M and the buffer molarity was 0.001 M. The rate constant (kobs) of the reaction between [Fe(CN)6]-4 and K[Co(HEDTA)NO2] was determined at temperatures of 25.0°C, 27.5°C, 30.0°C, 35.0°, and 40.0°C. We explored this reaction by monitoring the evolution of ferricyanide, [Fe(CN)6]-3, spectroscopically for which ε420 = 1023 cm-1 M-1 by recording the absorbance as a function of time at 420 nm wavelength. The data were plotted and results analyzed to give activation parameters, energy of activation (Ea), entropy of activation (ΔS‡), and enthalpy of activation (ΔH‡) for the two reacting complexes under the specified reaction conditions. Based on previous results, an outer-sphere electron-transfer pathway and a first order rate of reaction for each of the reacting species 1 have been proposed.
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Kpogo, Kenneth K. "X-ray crystal structures of: [Rh2(N-{2,4,6-CH3}C6H2)COCH3)4]•2NCC6H4 AND Ba1.5[Fe(C10H13N2O7)][Co(CN)6]•9H2O; two crystallographic challenges." Digital Commons @ East Tennessee State University, 2013. https://dc.etsu.edu/etd/1175.

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The novel compound, [Rh2(N-{2,4,6-CH3}C6H2)COCH3)4] was synthesized. Crystal structures of [Rh2(N-{2,4,6-CH3}C6H2)COCH3)4]·2NCC6H5 and Ba1.5[Fe(C10H13N2O7)][Co(CN)6]·9H2O were determined employing a Rigaku Mercury375R/M CCD (XtaLAB mini) diffractometer with graphite monochromated Mo-Kα radiation. For [Rh2(N-{2,4,6-CH3}C6H2)COCH3)4]·2NCC6H5, the space group was P-421c(#114) with unit cell dimensions: a =11.0169(14)Å, c =21.499(3)Å, V = 2609.4(6)Å3. Each rhodium had approximately octahedral coordination and was bound to another rhodium atom, two nitrogens (trans to each other), two oxygens (trans to each other), and one benzonitrile nitrogen (trans to rhodium). For Ba1.5[Fe(C10H13N2O7)][Co(CN)6]·9H2O the space group was: P-1(#2) with unit cell dimensions: a=13.634Å, b=13.768Å, c=17.254Å and α=84.795°, β=87.863°, γ=78.908°, V=3164.5Å3. The iron atom (nearly octahedral) was coordinated to one chelating ligand (derived from ethylenediaminetetraacetic acid) and the nitrogen of a cyanide ligand. The carbon of the cyanide ligand was bound to cobalt (octahedral). Thus, the cyanide ligand serves as a bridge between the two metals.
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Burya, Scott J. "Ferrocyanide: An Inappropriate Reagent for ds-DNA Binding Mode Determination." The Ohio State University, 2009. http://rave.ohiolink.edu/etdc/view?acc_num=osu1248721621.

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"Determination of the Activation Parameters of Reaction Between [Fe(CN)6]-4 and K[Co(HEDTA)NO2]." East Tennessee State University, 2009. http://etd-submit.etsu.edu/etd/theses/available/etd-1103109-194620/.

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Book chapters on the topic "Fe(CN)6"

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Villars, P., K. Cenzual, J. Daams, et al. "Cd2[Fe(CN)6]." In Structure Types. Part 9: Space Groups (148) R-3 - (141) I41/amd. Springer Berlin Heidelberg, 2010. http://dx.doi.org/10.1007/978-3-642-02702-4_131.

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Villars, P., K. Cenzual, J. Daams, et al. "Zn2[Fe(CN)6]∙2.3H2O." In Structure Types. Part 9: Space Groups (148) R-3 - (141) I41/amd. Springer Berlin Heidelberg, 2010. http://dx.doi.org/10.1007/978-3-642-02702-4_144.

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Holze, Rudolf. "Ionic conductance of H4[Fe(CN)6]." In Electrochemistry. Springer Berlin Heidelberg, 2016. http://dx.doi.org/10.1007/978-3-662-49251-2_868.

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Holze, Rudolf. "Ionic conductance of Mg2(Fe(CN)6)." In Electrochemistry. Springer Berlin Heidelberg, 2016. http://dx.doi.org/10.1007/978-3-662-49251-2_1085.

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Holze, Rudolf. "Ionic conductance of Na4[Fe(CN)6]." In Electrochemistry. Springer Berlin Heidelberg, 2016. http://dx.doi.org/10.1007/978-3-662-49251-2_1351.

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Holze, Rudolf. "Ionic conductance of Ca3[(Fe(CN)6)]2." In Electrochemistry. Springer Berlin Heidelberg, 2016. http://dx.doi.org/10.1007/978-3-662-49251-2_729.

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Villars, P., K. Cenzual, J. Daams, et al. "H[cis-Fe(H2O)2]Re6Se8(CN)6∙2H2O." In Structure Types. Part 8: Space Groups (156) P3m1 – (148) R-3. Springer Berlin Heidelberg, 2010. http://dx.doi.org/10.1007/978-3-540-70892-6_269.

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Holze, Rudolf. "Transference numbers of Fe(CN) 6 3− ion in aqueous electrolyte solutions." In Electrochemistry. Springer Berlin Heidelberg, 2016. http://dx.doi.org/10.1007/978-3-662-49251-2_1622.

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Holze, Rudolf. "Transference numbers of Fe(CN) 6 4− ion in aqueous electrolyte solutions." In Electrochemistry. Springer Berlin Heidelberg, 2016. http://dx.doi.org/10.1007/978-3-662-49251-2_1623.

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Pardasani, R. T., and P. Pardasani. "Magnetic properties of a cyano bridged iron(III) linear chain with alternating Fe(CN)6-Fe(cyclam)." In Magnetic Properties of Paramagnetic Compounds. Springer Berlin Heidelberg, 2017. http://dx.doi.org/10.1007/978-3-662-53971-2_193.

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Conference papers on the topic "Fe(CN)6"

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Phimg Kim Phu, Nguyen Minh Thuan, Tran Nam Trung, In-Sang Yang, and Nguyen Van Minh. "Synthesis and characterization of RbxMn[Fe(CN)6] and Mn3[Cr(CN)6]2." In 2010 IEEE 10th Conference on Nanotechnology (IEEE-NANO). IEEE, 2010. http://dx.doi.org/10.1109/nano.2010.5697929.

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Danilin, Lev, and Valery Drozhzhin. "Research on Thermal Stability of Sorbents on the Basis of Microspheres Modified With Ferrocyanides of Transient and Heavy Metals." In The 11th International Conference on Environmental Remediation and Radioactive Waste Management. ASMEDC, 2007. http://dx.doi.org/10.1115/icem2007-7374.

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The mass-spectrometer method was used to investigate the compositions of gas phases formed at thermal decomposition of inorganic sorbents on the basis of alumosilicate microspheres modified with ferrocyanides of copper, iron, cobalt, tungsten and vanadium. The research was carried out in a static mode in vacuum in the temperature range of 180–500°C. The chemical composition of modifiers corresponded to formulas: K2Cu[Fe(CN)6]; K2Cu3[Fe(CN)6]2; Fe4[Fe(CN)6]3; KFe[Fe(CN)6]; Co2[Fe(CN)6]; xH4Fe(N)6·yWO3·zH2O; xH4Fe(CN)6·yV2O5·zH2O. The basic components of gas phases after thermal effect on these structures are hydrogen, water, carbon dioxide and monoxide, nitrogen, and cyanic hydrogen. With the temperature growth the intensity of gas evolution increases, the ratio between the components vary, paraffin hydrocarbons and unsaturated hydrocarbons appear (ethane, acetylene, propene). The content of methane varies within ∼0.2–2 % vol. weakly correlating with experimental conditions. The composition of the gas phases produced during thermal effect on the modified microspheres is most probably a superposition of physical and chemical processes connected with the influence of the matrix itself, with individual heat resistance of the modifiers and products of their decomposition, as well as with that circumstance, that products of reactions can interact with each other. In general the character of the processes during thermal decomposition of mixed ferrocyanides of MxEy[Fe(CN)6]z type (where M is an alkali metal, and E is some “heavy metal”) applied onto cenocpheres is determined mostly by the polarization effect of the “heavy” metal on anion [Fe(CN)6]−4.
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Van Minh, Nguyen, Phung Kim Phu, Nguyen Minh Thuan, Duong Manh Toan, and In-Sang Yang. "Molecular-Based Magnet: A Prussian-Blue Analogue NaxMny[Fe(CN)6]." In 2008 8th IEEE Conference on Nanotechnology (NANO). IEEE, 2008. http://dx.doi.org/10.1109/nano.2008.240.

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Min Liu and MingXiang Xu. "Heat-induced magnetic properties changes of Mn3[Fe(CN)6]2·XH2O." In 8th International Vacuum Electron Sources Conference and Nanocarbon (2010 IVESC). IEEE, 2010. http://dx.doi.org/10.1109/ivesc.2010.5644191.

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Machala, Libor, and Radek Zbořil. "Thermal decomposition of ammonium ferrocyanide, (NH4)4[Fe(CN)6], in air." In MÖSSBAUER SPECTROSCOPY IN MATERIALS SCIENCE 2016. Author(s), 2016. http://dx.doi.org/10.1063/1.4966001.

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Sharma, V. K., S. Mitra, Amit Kumar, S. M. Yusuf, F. Juranyi, and R. Mukhopadhyay. "Dynamics of water in Prussian Blue Analogue Cu0.75Mn0.75[Fe(CN)6] 7H2O." In SOLID STATE PHYSICS: Proceedings of the 56th DAE Solid State Physics Symposium 2011. AIP, 2012. http://dx.doi.org/10.1063/1.4710317.

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GUO, YUAN, YONG-JUN LI, MAO-XIA HE та XI XIA. "FLATBAND POTENTIALS AND CHARGE TRANSFER AT γ-MnO2/[Fe(CN)6]3− INTERFACE". У Proceedings of the 7th Asian Conference. WORLD SCIENTIFIC, 2000. http://dx.doi.org/10.1142/9789812791979_0051.

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Kumar, Narender, Sunil Rohilla, Ankita Gupta, and Jasvir Dalal. "Structural Characterization of Mn2[Fe (CN)6].xH2O Nanocrystalites Synthesized by Coprecipitation Method." In 2021 International Conference on Advances in Electrical, Computing, Communication and Sustainable Technologies (ICAECT). IEEE, 2021. http://dx.doi.org/10.1109/icaect49130.2021.9392407.

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Mittal, R., M. Zbiri, H. Schober, S. N. Achary, A. K. Tyagi, and S. L. Chaplot. "Colossal thermal expansion behavior of Ag[sub 3]M(CN)[sub 6] (M=Co,Fe)." In SOLID STATE PHYSICS: PROCEEDINGS OF THE 57TH DAE SOLID STATE PHYSICS SYMPOSIUM 2012. AIP, 2013. http://dx.doi.org/10.1063/1.4791286.

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Narayan, Bhism, and Sunil Rohilla. "Structural Characterization and Rietveld Refinement of Li2Cu[Fe(CN)6] Nanocomposites Prepared via Coprecipitation Method." In 2021 International Conference on Advances in Electrical, Computing, Communication and Sustainable Technologies (ICAECT). IEEE, 2021. http://dx.doi.org/10.1109/icaect49130.2021.9392400.

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