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1

Solberg, Daniel. "Adsorption kinetics of cationic polyacrylamides on cellulose fibres and its influence on fibre flocculation." Licentiate thesis, KTH, Fibre and Polymer Technology, 2003. http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-1665.

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The adsorption of cationic polyacrylamide (C-PAM) and silicananoparticles onto a model surface of silicon oxide wascompared with the adsorption of C-PAM to fibres and theirinfluence on flocculation of a fibre suspension. An increase inionic strength affects the polyelectrolyte adsorption indifferent ways for these two systems. With the silica surface,an increase in the ionic strength leads to a continuousincrease in the adsorption. However, on a cellulose fibre, theadsorption increases at low ionic strength (1 to 10 mM NaCl)and then decreases at higher ionic strength (10 to 100 mMNaCl). It was shown that the adsorption of nanoparticles ontopolyelectrolyte-covered surfaces has a great effect on both theadsorbed amount and the thickness of the adsorbed layer. Theresults showed that electrostatic interactions were thedominating force for the interaction between both the fibresand the polyelectrolytes, and between the polyelectrolytes andthe silica particles. Furthermore, at higher NaClconcentrations, a significant non-ionic interaction between thesilicon oxide surface/particles and the C-PAM was observed.

The adsorption rate of C-PAM onto fibres was rapid andquantitative adsorption was detected in the time range between1 and 8 s at polyelectrolyte addition levels below 0.4 mg/g.Conversely, an increase in the amount of added polymer leads toan increased polymer adsorption up to a quasi-static saturationlevel. However, after a few seconds this quasi-staticsaturation level was significantly lower than the level reachedat electrostatic“equilibrium”. The adsorbed amountof charges at full surface coverage after 1 to 8 s contact timecorresponded to only 2 % of the total fibre charge, whereasafter 30 minutes it corresponded to 15 % of the total fibrecharge. This shows that a full surface coverage at shortcontact times is not controlled by surface charge. Based onthese results, it is suggested that a combination of anon-equilibrium charge barrier against adsorption and ageometric restriction can explain the difference between theadsorption during 1 to 8 s and the adsorption after 30 minutes.With increasing time, the cationic groups are neutralised bythe charges on the fibre as the polyelectrolyte reconforms to aflat conformation on the surface.

The addition of a high concentration of C-PAM to a fibresuspension resulted in dispersion rather than flocculation.This behaviour is most likely due to an electrostericstabilisation of the fibres when the polyelectrolyte isadsorbed. Flocculation of the fibre suspension occurred at lowadditions of C-PAM. A maximum in flocculation was found ataround 50 % surface coverage and dispersion occurred above 100% surface coverage. It was also shown that for a given level ofadsorbed polymer, a difference in adsorption time between 1 and2 seconds influenced the flocculation behaviour. An optimum inflocculation at 50 % surface coverage in combination with theimportance of polymer reconformation time at these shortcontact times showed that the C-PAM induced fibre flocculationagrees with La Mer and Healy’s description of bridgingflocculation.

A greater degree of flocculation was observed with theaddition of silica nanoparticles to the fibre suspension thanin the single polyelectrolyte system. Flocculation increased asa function of the concentration of added nanoparticles until0.5 mg/g. At higher additions the flocculation decreased againand this behaviour is in agreement with an extended model formicroparticle-induced flocculation. An increase in flocculationwas especially pronounced for the more extended silica-2particles. This effect is attributed to the more extendedpolyelectrolyte layer, since the adsorbed amount wasessentially the same for both silica particles.

Finally it was found that fines from the wood fibres had asignificant effect on the flocculation. When fines were added,a greater degree of flocculation was detected. Furthermore, itwas also more difficult to redisperse the fibres with polymerin the presence of fines.

Keywords:Adsorption, bridging, cationic polymers,cellulose fibres, electrosteric stabilisation flocculation,ionic strength, nanoparticle, polyelectrolyte, reconformation,retention aids and silica

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2

Dyson, Igor Niladri. "The fracture behaviour of carbon fibre/polyetheretherketone composites." Thesis, Imperial College London, 1996. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.309100.

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3

Bayer, Daniela, and Mike Richter. "Zur Anwendung bruchmechanischer Konzepte für die Modellierung der rissüberbrückenden Wirkung von Rovings." Saechsische Landesbibliothek- Staats- und Universitaetsbibliothek Dresden, 2009. http://nbn-resolving.de/urn:nbn:de:bsz:14-ds-1244047456442-11748.

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Textilbeton ist ein Verbundwerkstoff aus einer Feinbetonmatrix und einer textilen Bewehrung, die aus sogenannten Rovings besteht. Nach Reißen der spröden Matrix sind diese Rovings in der Lage, die Risse in der Matrix zu überbrücken. In diesem Beitrag wird ein analytisches Modell vorgestellt, welches den Einfluss der Rovings auf das Rissverhalten erfassen kann. Die Wirkung der Fasern wird durch rissüberbrückende Spannungen approximiert. Dabei kommt unter Annahme linear elastischen Materialverhaltens das bruchmechanische Konzept der Methode der Gewichtsfunktionen zum Einsatz. Als ein spezielles Anwendungsgebiet des vorgestellten bruchmechanischen Konzeptes werden Risse im Bereich von Übergreifungen der textilen Bewehrung untersucht. Hier kann es, abhängig von der vorhandenen Übergreifungslänge, zum Auszug der Rovings kommen. Um diesen Versagensmechanismus zu verhindern, ist eine Mindestübergreifungslänge erforderlich.
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4

Lin, Y. "Optimum design for sustainable 'green' overlays : controlling flexural failure." Thesis, Coventry University, 2014. http://curve.coventry.ac.uk/open/items/b5ba73e5-9cb8-4a0b-ac99-c53b3c3e54ed/1.

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The target of the ‘Green Overlays’ research was a cost effective, minimal disruption, sustainable and environmentally friendly alternative to the wholesale demolition, removal and complete reconstruction of the existing structural concrete pavement. The important problem of flexural resistance for strengthening concrete pavements with structural overlays has been scrutinised. A new mix design method for steel fibre reinforced, roller compacted, polymer modified, bonded concrete overlay has been proposed. The mixes developed were characterized of high flexural strength and high bond strength with the old concrete substrate. ‘Placeability’ and ‘compactability’ of the mix were two dominant issues during laboratory investigation. An innovative approach for establishing the relationship between Stress and Crack Face Opening Displacement for steel fibre reinforced concrete beams under flexure was developed. In addition, a new and simple method for calculating the interfacial Strain Energy Release Rate of both, a two-dimensional specimen and a three-dimensional model of the overlay pavement system were developed. This method can be readily and easily used by practicing engineers. Finally, a new test specimen and its loading configuration for measuring interfacial fracture toughness for concrete overlay pavements were established. The interfacial fracture toughness of a composite concrete beam, consisted of steel fibre-reinforced roller compacted polymer modified concrete bonded on conventional concrete and undergoing flexure, was assessed. In summary, this thesis presents four key findings: A new mix design method for steel fibre-reinforced roller compacted polymer modified concrete bonded on conventional concrete. A new method for establishing the fibre bridging law by an inverse analysis approach. A new, simplified method for calculating strain energy release rate at the interface of a composite beam. A new, innovative technique for calculating strain energy release rate at the interface of an overlaid pavement. The thesis contains a plethora of graphs, data-tables, examples and formulae, suitable for future researchers.
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5

Fernberg, Patrik. "Fiber bridging concepts applied to short fiber composites." Licentiate thesis, Luleå tekniska universitet, 2000. http://urn.kb.se/resolve?urn=urn:nbn:se:ltu:diva-18743.

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Polymer composite materials are in wide-spread use in the transportation industry. In aerospace industry the use these materials are established while in automotive industry the interest is increasing. The attention of automotive industry is to a great deal focused on various kinds of molded composites such as glass mat reinforced thermoplastics (GMT) and sheet molding compound (SMC). Their interest is to a large extent driven by the possibility to manufacture components of complex geometry in a cost- efficient process with these materials. An increasing number of car and truck manufacturers are using SMC for external panels such as trunk covers, hoods, roofs and spoilers. A property of obvious importance for an external car- or truck-panel is its capacity to withstand impact. In this context, improved understanding of crack growth and toughening mechanisms of the material is of great interest. A major part of the work presented in this thesis is driven by an interest to increase the understanding of how material composition and microstructure of short fiber composites influence their overall fracture behaviour. In materials such as metals and unreinforced polymers, linear elastic fracture mechanics (LEFM) is widely used, often with great success, both in design and in development of new materials. Unfortunately, problems arise when LEFM is applied to short fiber composites. This is due to the large process zone that develops ahead of a crack in these materials. The fundamental assumption of LEFM, that the damage zone at the tip of the crack is small compared to crack length, is often violated in experiments. The presented thesis considers a different approach, in which the damage ahead of a crack tip is described by a bridging-law. By considering the bridging-law as the major failure property of the material, a coupling between mechanisms acting on a microscale and the macroscopic failure behaviour can be established. No such information can be obtained using a LEFM approach where the material behaviour is described in terms of a single value, the fracture toughness. Bridging-laws for three different short fiber composites are experimentally determined and presented in the first paper of the thesis. A matter of key importance for future work in this field is that there are methods available for experimental verification of the suggested fiber bridging approach. Optical strain field measurement methods are therefore very useful. The thesis contains a pilot study to evaluate the use of two recently developed optical methods , Stereoscopic Digital Speckle Photography (Stereo-DSP) and combined DSP-DSPI (Digital Speckle Pattern Interferometry), for measurements of fracture behaviour of notched short fiber composites. We found Stereo-DSP to be a versatile technique that can be used when knowledge of overall displacement fields is required. The combined technique can with advantage be used when detailed information about large deformation at small areas is of interest, e.g. the complex fiber bridging interaction at the crack tip of a short fiber composite. The last paper in the thesis presents a study where the influence of fiber surface treatment on transverse cracking in cross-ply laminates was investigated. In the case of tubes and pressure vessels, the formation of transverse cracks ultimately leads to leakage since cracks connect and form a path through the wall. In the presented study, our ambition was to investigate the influence of film former polymer on transverse cracking properties of cross-ply laminates.Both onset of transverse cracking and tendency for multiple crack development were strongly affected by the different film formers. The strong film former effect was proposed to be due to a combination of improved interfacial adhesion and the plasticizing effect from the film former on the interphase region. The thesis is composed by the following papers: Patrik Fernberg, Lars Berglund, Bridging law and toughness characterisation of CSM and SMC composite, to be submitted. Angelica Andersson, Patrik Fernberg, Mikael Sjödahl, Optical methods to study fracture of notched glass mat composites. Proceedings of the International Conference on trends in Optical Nondestructive Testing, Lugano, Switzerland, May 3-6, 2000 (in press). Patrik Fernberg, Lars Berglund, Effects of glass fiber size composition (film former type) on transverse cracking in cross-ply laminates. Accepted for publication in Composites, Part A.
Godkänd; 2000; 20070318 (ysko)
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6

Fernberg, Patrik. "Toughness of short fiber composites : an approach based on crack-bridging /." Luleå : Luleå tekniska univ, 2002. http://epubl.luth.se/1402-1544/2002/12/index.html.

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7

Motamedi, Damoon. "Nonlinear XFEM modeling of delamination in fiber reinforced composites considering uncertain fracture properties and effect of fiber bridging." Thesis, University of British Columbia, 2013. http://hdl.handle.net/2429/44630.

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Initiation and propagation of a crack in composite materials can affect their global mechanical properties severely. From a numerical modeling perspective, most conventional macro-level methods reported for composite laminates are based on the assumption that a Representative Volume Element (RVE) of the material is periodically repeated over the entire sample. However, a considerable amount of spatial non-uniformity in material and geometrical parameters can exist in both unidirectional (UD) and woven fabric composites. The scattered distribution of fibers, fibers penetration between composite layers, voids within the matrix, human errors during sample preparation, and imperfect thickness distribution can be among the most common sources of such non-uniformity. In turn, these non-uniformities can make the numerical simulation of composites under the assumption of a periodic RVE unreliable, and thereby, the stochastic modeling of effective material properties becomes essential for a more precise assessment of composites’ mechanical behaviour. In the present work, a new three-dimensional (3D) stochastic extended finite element method (XFEM) is proposed and implemented to model the delamination surface in composite samples by integrating the capabilities of the finite element method (FEM) commercial software (ABAQUS) into a user-defined FORTRAN code and MATLAB package. XFEM is known to offer significant advantages over conventional FEM by enabling optimal convergence rates in the presence of pronounced discontinuities/singularities such as cracks. The effect of nonlinear modeling parameters such as cohesive zone length, penalty stiffness factor and large deformation are also considered in the proposed approach to add to the accuracy of simulations. The XFEM model is first tested and validated against previously reported data in the literature. Next, a statistical distribution is sought from data non-repeatability during a set of double cantilever beam (DCB) and end-notched flexure (ENF) tests conducted on Poly (phenylene Sulfide) PPS/Glass thermoplastic composite samples. Results from the experiments and XFEM are compared and demonstrate the capability of the new numerical approach in capturing non-repeatable material response, often seen during the fracture testing of UD composites to characterize their mode I and mode II fracture properties.
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8

Fulenwider, Thomas Edward. "Modular Laser Combat System for Remotely Operated Vehicles: Bridging the Gap Between Computer Simulation and Live Fire." DigitalCommons@CalPoly, 2010. https://digitalcommons.calpoly.edu/theses/335.

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In the emerging industry of small unmanned vehicles, pioneered by small businesses and research institutions, a suitable combat system test platform is needed. Computer simulations are useful, but do not provide the definitive proof of effective operation necessary for deployment of a combat system. What is needed is an affordable simulated weapons system that enables live flight testing without the used of live weaponry. A framework is developed here for the construction of a simulated weapon using Free Space Optical (FSO) infrared communication. It is developed in such a way to ensure compatibility with a variety of platforms including ground and aerial vehicles, so that identical but configurable modules can be used on any vehicle that is to take place in a live combat simulation. A proof-of-concept implementation of this modular laser combat system framework is also presented and tested. The implemented system shows the value of such a simulated weapons system and future areas of improvement are also explored.
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9

松原, 剛., Go MATSUBARA, 英夫 尾野, Hideo ONO, 啓介 田中, and Keisuke TANAKA. "高強度GFRPのモードⅠ層間はく離疲労き裂進展におよぼす繊維架橋の影響." 日本機械学会, 2004. http://hdl.handle.net/2237/9138.

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10

Höwer, Daniel Verfasser], Stefanie [Akademischer Betreuer] [Reese, Kai-Uwe [Akademischer Betreuer] Schröder, and Jaan-Willem [Akademischer Betreuer] Simon. "Numerical and experimental investigation of debonding accounting for severe fiber bridging / Daniel Höwer ; Stefanie Reese, Kai-Uwe Schröder, Jaan-Willem Simon." Aachen : Universitätsbibliothek der RWTH Aachen, 2020. http://d-nb.info/1221808702/34.

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11

Höwer, Daniel [Verfasser], Stefanie [Akademischer Betreuer] Reese, Kai-Uwe [Akademischer Betreuer] Schröder, and Jaan-Willem [Akademischer Betreuer] Simon. "Numerical and experimental investigation of debonding accounting for severe fiber bridging / Daniel Höwer ; Stefanie Reese, Kai-Uwe Schröder, Jaan-Willem Simon." Aachen : Universitätsbibliothek der RWTH Aachen, 2020. http://d-nb.info/1221808702/34.

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12

Lombetti, D. M. "Tufting of complex composite structures." Thesis, Cranfield University, 2015. http://dspace.lib.cranfield.ac.uk/handle/1826/11076.

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This study focuses on the effect of tufting on the mechanical and electrical properties of carbon composites using a variety of tuft materials, such as aramid, steel and copper. Several configurations were investigated based on a case study, involving the reinforcement of stiffener-to-skin interfaces of a tail cone. The effect of tuft and base composite material, tufting depth and inclination on the delamination resistance in mode I was evaluated, the associated bridging laws were determined and the failure mechanisms were identified. A simplified superposition model of the delamination response of tufted composites was developed. The electrical performance of tufted composites was determined in simulated lightning strike tests and set against the through-the-thickness electrical conductivity of the materials. The results of mechanical testing showed that the delamination performance depends strongly on the material response of the tufts, with both the bridging behaviour and final toughness levels influenced directly by the strength, ductility and ultimate strain of the tufts. Interactions between the tufts and the surrounding composite, such as interfacial shear and bridging induced by tuft pull-out, play a significant role in the overall behaviour generating a deviation from a simple superposition of the base material and tuft response. The balance between interfacial shear and tuft elongation results in a decreasing trend of delamination toughness with increasing tufting depth for low ductility materials, whilst the trend is reversed for the high ductility copper tufts. This balance is also affected by the properties of the base material, with tougher matrices leading to dominance of shear effects and a weaker enhancement introduced by tufting. Inclination of tufts leads to an increase in crack energy release rate due to the activation of a ploughing mechanism. Metallic and carbon tufts have a positive effect on lightning strike response, with copper tufting offering strike protection at an improved level compared to standard copper mesh solutions.
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13

Kaattari, S. (Satu). "“The mind is not a vessel to be filled but a fire to be kindled”:teachers’ perceptions of bridging schools and working life with ICT." Master's thesis, University of Oulu, 2015. http://urn.fi/URN:NBN:fi:oulu-201506041784.

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Globalization, digitalization and ubiquitous technology have changed the way people work, play, live and learn. The vast changes in society and working life make meeting the needs of the 21st century challenging for education systems. Despite information technology is providing various sources to receive information about working life, insecurity is increasing among youngsters in the moment when they should decide about their future professions. The aim of this research was to investigate the teachers’ own perceptions and main challenges related to this matter, and the goal was to find out if ICT can bring schools and working life closer to one another. This was a mixed-method research using grounded theory as a research approach, and the quantitative and qualitative data was collected by online survey. The theoretical framework combined the concepts of educational usage of ICT and digital media. Also the altering needs of working life and the 21st century skills built an essential part of the theoretical frame, as well as teachers’ and learners’ views about the needs of working life. The informants of this research were high school and upper secondary school teachers, student counselors and principals working in the Oulu area. They were chosen by using simple random sampling, and in total 31 informants participated in this research. Based on the findings, teachers agree schools’ cooperation with working life is important, but the shortages of educators and learners ICT skills, also the lack of information about the existing digital tools, are often preventing the educational usage of ICT in bridging schools with working life. In the findings teachers also address the ways they would most like to receive ICT training and information about school and working life cooperation. The limitations of this research lie in the fact that it was limited to 31 participants. However, as the data was collected with an online survey containing multiple quantitative and qualitative questions with open-ended answers, the responses gave diverse insights and provided local perspective about current issues relating to the topic of this research. The conclusions of this research highlight that even though ICT is just one tool in education and learning processes, ubiquitous technology is everywhere and it should not be neglected neither in teaching nor learning. The majority of teachers feel positively about using ICT in education, but they wish to train those skills, and to learn more about the existing digital tools for school and working life cooperation. Conclusions suggest that the goal of teaching and learning should enhance skills such as collaboration, communication, creativity and critical thinking to meet the needs of the 21st century and working life, and to build individuals’ career paths. Future research is recommended to focus on investigating the existing procedures in ICT skills for mapping out the current gaps in education. Another suggested topic for further research is to investigate the importance of individuals’ passion for learning, and how the current education system could enhance it.
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14

Chan, Vivian. "Long term thermal performance and application of glass fiber core vacuum insulation panels." Thesis, 2020. http://hdl.handle.net/1828/12497.

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Glass fiber core Vacuum Insulation Panels (VIPs) have thermal performance per unit thickness of about 5-10 times higher than the traditionally used building insulation materials such as mineral wool, XPS, EPS, foam, etc. This advantage of VIP has made it very attractive new option for innovative building designs. Especially in Canada, where some of the areas have long and very cold winters. Confidence in the service life of a building material is necessary before putting a product to market. Extensive research has been conducted on the product development, quality improvement, and field application of VIPs around the world. However, there is lack of consistent and simple prediction method for the long-term thermal performance of VIPs. This paper discussed the process and performance of a field project using glass fiber VIPs to retrofit a commercial building in Yukon, Canada. The thermal performance of the VIPs used in this project was continuously monitored and critically analyzed since the start in 2011. The results have shown satisfactory thermal performance of VIPs for the past 8 years. The findings were also used to validate glass fiber core VIP accelerated aging tests conducted by the National Research Council Canada (Ottawa), and the aging rate of VIPs in a cold and dry climate was determined. The second part of this study investigated the monitored performance results from two sets of simplified accelerated laboratory aging tests, the results were analyzed with the aim to separate the impact of air diffusion from water vapour on the long-term thermal performance of glass fiber VIPs. In addition, this study also investigated the potential application of VIPs in balcony constructions to reduce heat transfer through thermal bridges. Computer modeling exercises, using a benchmarked (EN ISO 10211) three-dimensional transient and steady-state heat transfer simulation tool HEAT3, were carried out on the most optimal (thermal performance) balcony assemblies of wood framed buildings using VIP as insulation. This niche application of VIPs can significantly increase the energy efficiency of building envelopes/skins in extreme climates of Canada and elsewhere in the world.
Graduate
2021-11-06
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15

Yang, Hsiu-Feng, and 楊秀鳳. "The Analysis of Graphics Context and Students’ Preference Factors in Bridging Books—A Case Study of “Funny Fire Dragon”." Thesis, 2019. http://ndltd.ncl.edu.tw/handle/bt2uc6.

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碩士
臺北市立大學
視覺藝術學系碩士在職專班
107
Text reading takes a certain amount of time to develop. Many students gradually lose their love of books. In order to help children continue to be immersed in the field of reading, "bridging book" has being designed which contents pictures and texts. Use the content analysis method to analyze the graphic scale, graphic position, space and composition, perspective and graphic relationship in the series of "Funny Fire Dragon", and cooperate with the interview bridge writer to understand the creative process of drawing bridge books. The questionnaire is used to analyze the preference factors of children in reading bridge books, in order to provide reference for subsequent production of bridge books. From the above analysis, it is found that the story text of the bridge book is close to children's life experience, the characters are simple, the theme is not complicated and interesting, and the ratio of the proposed picture to the text needs to be close to the image, and the position of the picture has various configurations. Like the performance of the lively and diverse, graphic and close relationship as the principle, and with bright colors, a holistic layout design, can attract children into the world of book, gradually accumulate into a large reader.
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16

(11197419), Alejandra Margarita Ortiz Morales. "In situ tomography investigation of crack growth in carbon fiber laminate composites during monotonic and cyclic loading." Thesis, 2021.

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As the use of fiber-reinforced polymer composites grows in aerospace structures, there is an emerging need to implement damage tolerant approaches. The use of in-situ synchrotron X-ray tomography enables direct observations of progressive damage relative to the microstructural features, which is studied in a T650/5320 laminate composite with varying layup orientations (using 45o and -45o plies) in a compact tension specimen geometry. Specifically, the interactions of micromechanical damage mechanisms at the notch tip were analyzed through 3D image processing as the crack grew. First, monotonic tests were conducted where X-ray tomography was acquired incrementally between the unloaded state and maximum load. The analysis of the monotonic tension specimens showed intralaminar cracking was dominant during crack initiation, delamination became prevalent during the later stages of crack progression, and fiber breakage was, in general, largely related to intralaminar cracking. After the monotonic tension analysis, modifications were made to the specimen geometry and the loading assembly, and fatigue tests were conducted, also using in-situ synchrotron X-ray tomography. Specifically, tomography images were acquired after select intervals of cyclic loading to examine the crack growth behavior up to 5802 cycles. The analysis of the fatigue tests showed that intralaminar cracking was also dominant, while localized delamination allowed ply cross-over. A finite element analysis was conducted by comparing the crack profile at varying intervals of loading, and the change in stored energy per cycle, dU/dN, was calculated. The combined experimental and simulation analysis showed that when the per ply values of dU/dN were examined, the intralaminar cracking rate collapsed to one curve regardless of the ply orientation, where direct observations of fiber bridging were characterized and associated with a reduction in crack growth rate for the influenced ply. Overall, this work provides a physical understanding of the micromechanics facilitating intralaminar crack growth in composites, providing engineers the necessary assessments for slow crack growth approaches in structural composite materials.
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17

Shir, Mohammadi Meisam. "Fracture properties of balsa wood and balsa core sandwich composites." Thesis, 2012. http://hdl.handle.net/1957/34601.

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Favorable properties of Balsa wood make it an interesting alternative in a number of applications including thermal insulation or as a lightweight core material in sandwich composites. Increasing use in construction necessitates a better understanding of its mechanical and failure properties. In the present work, mode I and mode II fracture toughness for different types of balsa wood and a sandwich structure (balsa as core and fiber glass as skin layer) are studied experimentally by using load-displacement diagrams and visually acquired crack growth data.
Graduation date: 2013
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