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Journal articles on the topic 'Fischer carbenes complexes'

Author: Grafiati

Published: 4 June 2021

Last updated: 3 February 2022

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1

Padilla, Rosa, Verónica Salazar-Pereda, Daniel Mendoza-Espinosa, José M. Vásquez-Pérez, Noemí Andrade-López, Joaquín Tamariz, José G. Alvarado-Rodríguez, and Julián Cruz-Borbolla. "Activation of aldehydes by exocyclic iridium(i)-η4:π2-diene complexes derived from 1,3-oxazolidin-2-ones." Dalton Transactions 45, no. 42 (2016): 16878–88. http://dx.doi.org/10.1039/c6dt02866g.

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2

Cui, Peng, Dominic C. Babbini, and Vlad M. Iluc. "C–H activation of ethers by pyridine tethered PCsp3P-type iridium complexes." Dalton Transactions 45, no. 24 (2016): 10007–16. http://dx.doi.org/10.1039/c6dt00303f.

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An iridium complex supported by a PC^PyP ligand featuring an internal pyridine tether showed selective mono-C–H activation of ethers, which represent intermediates in the synthesis of the corresponding Fischer carbenes.

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3

López, Julio, Iván Velazco-Cabral, Eloy Rodríguez-deLeón, Clarisa Villegas Gómez, Francisco Delgado, Joaquín Tamariz, Ana Arrieta, Fernando P. Cossío, and Miguel A. Vázquez. "Selective synthesis of trisubstituted pyrroles through the reactions of alkynyl Fischer carbene complexes with oxazolones." Organic & Biomolecular Chemistry 18, no. 3 (2020): 538–50. http://dx.doi.org/10.1039/c9ob02411e.

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4

Rose-Munch, Françoise, Claudine Susanne, Frédéric Balssa, and Eric Rose. "Cationic arenetricarbonylmanganese complexes: Addition of α-anionic fischer type carbenes." Journal of Organometallic Chemistry 476, no. 2 (August 1994): c25—c26. http://dx.doi.org/10.1016/0022-328x(94)87089-6.

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5

Santamaría, Javier, and Enrique Aguilar. "Beyond Fischer and Schrock carbenes: non-heteroatom-stabilized group 6 metal carbene complexes – a general overview." Organic Chemistry Frontiers 3, no. 11 (2016): 1561–88. http://dx.doi.org/10.1039/c6qo00206d.

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6

Kim, Seongjin, Soo Young Choi, Young Tak Lee, Kang Hyun Park, Helmut Sitzmann, and Young Keun Chung. "Synthesis of chromium N-heterocyclic carbene complexes using chromium Fischer carbenes as a source of chromium carbonyls." Journal of Organometallic Chemistry 692, no. 24 (November 2007): 5390–94. http://dx.doi.org/10.1016/j.jorganchem.2007.08.043.

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7

Benítez-Puebla, Luis J., Julio López, Marcos Flores-Álamo, David Cruz Cruz, Eduardo Peña-Cabrera, Francisco Delgado, Joaquín Tamariz, and Miguel A. Vázquez. "Alkynyl Fischer Carbenes as a Platform for the Production of Difluorodiazaborinine Complexes via β-Amino-azadienes." European Journal of Organic Chemistry 2019, no. 38 (October 10, 2019): 6571–78. http://dx.doi.org/10.1002/ejoc.201901047.

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8

Caputo, Christine A., Michael C. Jennings, Heikki M. Tuononen, and Nathan D. Jones. "Phospha-Fischer Carbenes: Synthesis, Structure, Bonding, and Reactions of Pd(0)− and Pt(0)−Phosphenium Complexes." Organometallics 28, no. 4 (February 23, 2009): 990–1000. http://dx.doi.org/10.1021/om800973v.

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9

Dialer, Harald, Kurt Polborn, and Wolfgang Beck. "Metal complexes of biologically important ligands, Part CXVIII. Metathesis of dehydro amino acids with Fischer carbene complexes: synthesis of complexes of amino acid- and peptide-α-carbenes and of isoindoles." Journal of Organometallic Chemistry 589, no. 1 (October 1999): 21–28. http://dx.doi.org/10.1016/s0022-328x(99)00296-x.

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10

Cabeza, Javier A., Pablo García‐Álvarez, Mar Gómez‐Gallego, Laura González‐Álvarez, Alba D. Merinero, and Miguel A. Sierra. "Two Types of σ‐Allenyl Complexes from Reactions of Silylenes and Germylenes with Chromium Fischer Alkynyl(alkoxy)carbenes." Chemistry – A European Journal 25, no. 36 (May 27, 2019): 8635–42. http://dx.doi.org/10.1002/chem.201901579.

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11

Hamui, Leon, Maria Elena Sánchez-Vergara, Ricardo Corona-Sánchez, Omar Jiménez-Sandoval, and Cecilio Álvarez-Toledano. "Innovative Incorporation of Poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate) as Hole Carrier Transport Layer and as Anode for Organic Solar Cells Performance Improvement." Polymers 12, no. 12 (November 27, 2020): 2808. http://dx.doi.org/10.3390/polym12122808.

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In this work, we present a comparative study of benzoid poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate) (PEDOT:PSS) as electrode and as hole carrier transport layer (HTL) in the manufacture of organic photovoltaic devices using Fischer metal-carbene complexes. The performance of the different devices was evaluated for solar cell applications. Scanning electronic microscopy (SEM) and X-ray diffraction (XRD) were used to characterize the thin films that integrated the devices. A more ordered and crystallized active film microstructure is observed when using benzoid PEDOT:PSS as nucleation layer. The optical gap for both direct and indirect electronic transitions was evaluated from ultraviolet-visible spectroscopy data (UV-vis), as well as the absorption coefficient (α), and the values are in the range of 2.10–2.93 eV. Photovoltaic devices with conventional architecture, using two different chromium carbenes as active layers, were manufactured, and their electrical behavior was studied. The devices were irradiated with different wavelengths between the infrared and ultraviolet regions of the electromagnetic spectrum. Using the PEDOT:PSS film as hole carrier transport layer (HTL) decreases the slope on the ohmic and space charge limited current (SCLC) regions and eliminates the trap-charge limited current (T-CLC) mechanism. Furthermore, a saturation current of ~1.95 × 10−10 A and higher current values ~1.75 × 10−2 A at 4 V, ~4 orders in magnitude larger were observed. The PEDOT:PSS films as HTL in the devices reduced the injection barrier, thus showing a better performance than as anodes in this type of organic solar cells.

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12

Arndtsen, Bruce A., Thomas K. Schoch, and Lisa McElwee-White. "Stabilization of zero-valent hydrazido complexes by phosphine ligands. Crystal structure of fac-(CO)3(DPPE)W:NNMe2, a nitrene analogue to Fischer carbenes." Journal of the American Chemical Society 114, no. 18 (August 1992): 7041–47. http://dx.doi.org/10.1021/ja00044a014.

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13

Zeng, Wei, Rui Qiu, En Yu Wang, and Fu Xue Chen. "Trifluoromethyl-Promoted Oxidation of Fischer N-Heterocyclic Carbene Complexes by DMSO." Advanced Materials Research 788 (September 2013): 164–67. http://dx.doi.org/10.4028/www.scientific.net/amr.788.164.

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A new protocol for trifluoromethyl-promoted oxidation of fischer-type N-Heterocyclic Carbene copper complexes has been developed by DMSO, which allows the preparation of imidazolinones from carbene complexes.

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14

Office, Editorial. "The steric and electronic effects of metal-containing substituents on Fischer carbene metal clusters." Suid-Afrikaanse Tydskrif vir Natuurwetenskap en Tegnologie 28, no. 3 (September 6, 2009): 237–60. http://dx.doi.org/10.4102/satnt.v28i3.61.

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15

Škoch, Karel, Ivana Císařová, Filip Uhlík, and Petr Štěpnička. "Comparing the reactivity of isomeric phosphinoferrocene nitrile and isocyanide in Pd(ii) complexes: synthesis of simple coordination compounds vs. preparation of P-chelated insertion products and Fischer-type carbenes." Dalton Transactions 47, no. 45 (2018): 16082–101. http://dx.doi.org/10.1039/c8dt03564d.

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16

García-Rodríguez, Jaime, Jairo González, Javier Santamaría, Ángel L. Suárez-Sobrino, and Miguel A. Rodríguez. "Higher-order cyclization reactions of alkenyl Fischer carbene complexes: a new selective all-carbon [8 + 2] cyclization with 8-methoxyheptafulvene and computational mechanistic analysis." Dalton Transactions 45, no. 28 (2016): 11353–61. http://dx.doi.org/10.1039/c6dt01465h.

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17

D'Acunto, M., S. Tommasone, C. Talotta, G. Brancatelli, S. Geremia, E. Valletta, F. Marino Merlo, et al. "Installing tungsten Fischer carbene complexes into a calixarene framework." RSC Advances 6, no. 78 (2016): 75002–5. http://dx.doi.org/10.1039/c6ra17326h.

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18

Barluenga, José. "Fischer carbene complexes. A new tool for heterocyclic synthesis." Pure and Applied Chemistry 74, no. 8 (January 1, 2002): 1317–25. http://dx.doi.org/10.1351/pac200274081317.

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This short review covers our contribution in the field of the application of group 6 Fischer carbene complexes toward the synthesis of heterocyclic compounds. Alkenyl and alkynyl carbene complexes are suitable partners in [2+2], [3+2], [4+2], and [4+3] cycloaddition reactions. Moreover, chiral alkenyl carbene complexes react in sequential processes involving an initial Michael addition of a ketone lithium enolate to afford lactones with up to five consecutive stereogenic centers. Based on this strategy, we have devised a new method for the enantioselective synthesis of eight-membered carbocycles.

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19

Lamprecht, Zandria, Nina A. van Jaarsveld, Daniela I. Bezuidenhout, David C. Liles, and Simon Lotz. "Synthesis and properties of mono- and dimetal Fischer multicarbene complexes derived from thiophene and thieno[2,3-b]thiophene." Dalton Transactions 44, no. 44 (2015): 19218–31. http://dx.doi.org/10.1039/c5dt03555d.

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20

Landman, Marilé, Armand Jansen van Rensburg, Petrus H. van Rooyen, Marrigje M. Conradie, and Jeanet Conradie. "Triphenylstibine-substituted Fischer carbene complexes of tungsten(0): synthesis, structure, DFT and electrochemistry." New Journal of Chemistry 42, no. 9 (2018): 7301–13. http://dx.doi.org/10.1039/c8nj01008k.

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21

Raubenheimer, H. G. "Fischer carbene complexes remain favourite targets, and vehicles for new discoveries." Dalton Trans. 43, no. 45 (2014): 16959–73. http://dx.doi.org/10.1039/c4dt01943a.

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22

Lamprecht, Zandria, Shankara G. Radhakrishnan, Alexander Hildebrandt, Heinrich Lang, David C. Liles, Nora-ann Weststrate, Simon Lotz, and Daniela I. Bezuidenhout. "Mono-, di- and tetrarhenium Fischer carbene complexes with thienothiophene substituents." Dalton Trans. 46, no. 40 (2017): 13983–93. http://dx.doi.org/10.1039/c7dt02969a.

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23

Hu, Fangdong, Jinghui Yang, Ying Xia, Chen Ma, Haiping Xia, Yan Zhang, and Jianbo Wang. "Catalyst-free cross-coupling of N-tosylhydrazones with chromium(0) Fischer carbene complexes: a new approach to diarylethanone." Organic Chemistry Frontiers 2, no. 11 (2015): 1450–56. http://dx.doi.org/10.1039/c5qo00241a.

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24

Cabrera-Trujillo, Jorge Juan, and Israel Fernández. "Understanding exo-selective Diels–Alder reactions involving Fischer-type carbene complexes." Organic & Biomolecular Chemistry 17, no. 11 (2019): 2985–91. http://dx.doi.org/10.1039/c9ob00132h.

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25

Landman, Marilé, Armand Jansen van Rensburg, Petrus H. van Rooyen, Marrigje M. Conradie, and Jeanet Conradie. "Correction: Triphenylstibine-substituted Fischer carbene complexes of tungsten(0): synthesis, structure, DFT and electrochemistry." New Journal of Chemistry 42, no. 12 (2018): 10432. http://dx.doi.org/10.1039/c8nj90048e.

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26

Dotz, Karl Heinz, and Jurgen Pfeiffer. "ChemInform Abstract: Fischer-type Carbene Complexes." ChemInform 30, no. 12 (June 17, 2010): no. http://dx.doi.org/10.1002/chin.199912305.

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27

Hoskovcová, Irena, and Jiří Ludvík. "Electrochemical approach to Fischer carbene complexes." Current Opinion in Electrochemistry 15 (June 2019): 165–74. http://dx.doi.org/10.1016/j.coelec.2019.06.005.

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28

IWASAWA, Nobuharu. "Fischer-type Carbene Complexes in Organic Synthesis." Journal of Synthetic Organic Chemistry, Japan 56, no. 5 (1998): 413–23. http://dx.doi.org/10.5059/yukigoseikyokaishi.56.413.

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29

Barluenga, José, and Silvia Martínez. "New heterocyclization reactions with Fischer carbene complexes." Arkivoc 2006, no. 7 (January 10, 2006): 129–47. http://dx.doi.org/10.3998/ark.5550190.0007.712.

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30

Busetto, L., V. Zanotti, S. Bordoni, L. Carlucci, and A. Palazzi. "Fischer type carbene ligands in dinuclear complexes." Journal of Cluster Science 4, no. 1 (March 1993): 9–18. http://dx.doi.org/10.1007/bf01028381.

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31

Maas, Gerhard, and Dieter Mayer. "(Diazomethyl)silyl-functionalized Fischer-type carbene complexes." Journal of Organometallic Chemistry 617-618 (January 2001): 339–45. http://dx.doi.org/10.1016/s0022-328x(00)00616-1.

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32

Wang, Yu, C. C. Wang, H. J. Liu, K. J. Lin, L. K. Chou, and K. S. Chan. "Bond characterization of chromium-Fischer carbene complexes." Acta Crystallographica Section A Foundations of Crystallography 52, a1 (August 8, 1996): C351. http://dx.doi.org/10.1107/s0108767396085492.

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33

Merlic, Craig A., and Feng Wu. "Synthesis of β-keto Fischer carbene complexes." Journal of Organometallic Chemistry 553, no. 1-2 (February 1998): 183–91. http://dx.doi.org/10.1016/s0022-328x(97)00593-7.

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34

Ghorai, Binay K., and James W. Herndon. "Coupling of Fischer Carbene Complexes witho-Alkynylbenzamides." Organometallics 22, no. 19 (September 2003): 3951–57. http://dx.doi.org/10.1021/om030383k.

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35

SCHMALZ, H. G. "ChemInform Abstract: Photolysis of Fischer Carbene Complexes." ChemInform 25, no. 41 (August 18, 2010): no. http://dx.doi.org/10.1002/chin.199441260.

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36

Kiehl, Oliver, and Hans-Gunther Schmalz. "ChemInform Abstract: Photolysis of Fischer Carbene Complexes." ChemInform 33, no. 18 (May 21, 2010): no. http://dx.doi.org/10.1002/chin.200218232.

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37

Sierra, Miguel A., Juan C. del Amo, Marı́a J. Mancheño, and Mar Gómez-Gallego. "Low temperature carbene transfer from alkoxychromium(0) (Fischer) carbene complexes." Tetrahedron Letters 42, no. 32 (August 2001): 5435–38. http://dx.doi.org/10.1016/s0040-4039(01)01082-6.

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38

Lamprecht, Zandria, Frederick P. Malan, Israel Fernández, Simon Lotz, and Daniela I. Bezuidenhout. "Chelated Fischer carbene complexes of annulated thiophenes: synthesis, structure and electrochemistry." Dalton Transactions 49, no. 43 (2020): 15339–54. http://dx.doi.org/10.1039/d0dt03298k.

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39

Gostynski, Roxanne, Marilé Landman, and Jeanet Conradie. "Electrochemical Behaviour of Cr and W Fischer Ethoxy Carbene Complexes: A Comparative Study." Journal of Nano Research 44 (November 2016): 1–9. http://dx.doi.org/10.4028/www.scientific.net/jnanor.44.1.

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A comparative electrochemical study of a series Fischer carbene complexes (FCCs) of Cr and W containing an ethoxy and an aryl group as carbene substituents, showed that the Cr-FCCs generally exhibit two one-electron oxidation processes, namely Cr (0) to Cr (I) to Cr (II) while W-FCCs are oxidized in two two-electron oxidation processes, namely W(0) to W(II) to W(IV). The first one-electron oxidation processes of Cr-FCCs is generally reversible, while the first two-electron oxidation processes of all W-FCCs are found to be irreversible. The first reduction process observed for both the W-FCCs and Cr-FCCs is a one-electron process located on the carbene ligand. Both the metal oxidation, as well as the carbene reduction of Cr-FCCs, occurs at lower potentials than for W-FCCs. Substitution of carbonyls coordinated to the metal, or the group attached to the carbene ligand, led to similar trends related to the ease of oxidation or reduction of Cr-FCC and W-FCCs. Density functional theory calculations support and led to a better understanding of experimental electrochemical behaviour.

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40

Barluenga, José, Narendra Panday, Javier Santamaría, Ana de Prado, and Miguel Tomás. "Synthesis of new chiral alkenyl Fischer carbene complexes." Arkivoc 2003, no. 10 (December 27, 2003): 576–83. http://dx.doi.org/10.3998/ark.5550190.0004.a53.

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41

MAYER, D., and G. MAAS. "ChemInform Abstract: Novel Diazomethylsilyl-Substituted Fischer Carbene Complexes." ChemInform 27, no. 51 (August 4, 2010): no. http://dx.doi.org/10.1002/chin.199651230.

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42

Nandi, Malay, Kashinath M. Sathe, and Amitabha Sarkar. "Unusual rearrangement of Fischer carbene complexes to ketones." Journal of the Chemical Society, Chemical Communications, no. 10 (1992): 793. http://dx.doi.org/10.1039/c39920000793.

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43

Yu, Z., Z. Zheng, N. Luo, and X. Han. "Synthesis of Bicyclic Pyrazolinones Using Fischer Carbene Complexes." Synfacts 2007, no. 3 (March 2007): 0253. http://dx.doi.org/10.1055/s-2007-968256.

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44

Amin, S. Rasidul, Sudhir S. Sawant, Vedavati G. Puranik, and Amitabha Sarkar. "Novel Alkylation-Annulation Reaction of Fischer Carbene Complexes." Organometallics 14, no. 8 (August 1995): 3617–19. http://dx.doi.org/10.1021/om00008a004.

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45

Sabat, Michal, Michael F. Gross, and M. G. Finn. "Structure and bonding of heterobimetallic Fischer carbene complexes." Organometallics 11, no. 2 (February 1992): 745–51. http://dx.doi.org/10.1021/om00038a037.

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46

Herrmann, Wolfgang A., Karl Öfele, Denise v. Preysing, and Eberhardt Herdtweck. "Metal complexes of acyclic diaminocarbenes: links between N-heterocyclic carbene (NHC)- and Fischer-carbene complexes." Journal of Organometallic Chemistry 684, no. 1-2 (November 2003): 235–48. http://dx.doi.org/10.1016/s0022-328x(03)00754-x.

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47

Sierra, Miguel A., Juan C. del Amo, Maria J. Mancheno, and Mar Gomez-Gallego. "ChemInform Abstract: Low Temperature Carbene Transfer from Alkoxychromium(0) (Fischer) Carbene Complexes." ChemInform 32, no. 44 (May 24, 2010): no. http://dx.doi.org/10.1002/chin.200144078.

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48

Lamprecht, Zandria, Frederick P. Malan, Simon Lotz, and Daniela I. Bezuidenhout. "Synthesis and structure of thienyl Fischer carbene complexes of PtII for application in alkyne hydrosilylation." New Journal of Chemistry 45, no. 14 (2021): 6220–30. http://dx.doi.org/10.1039/d1nj00791b.

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49

Barluenga, José, Javier Santamaría, and Miguel Tomás. "Synthesis of Heterocycles via Group VI Fischer Carbene Complexes." Chemical Reviews 104, no. 5 (May 2004): 2259–84. http://dx.doi.org/10.1021/cr0306079.

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50

Barluenga, José, Josefa Flórez, and Francisco J. Fañanás. "Carbon nucleophile addition to sp2-unsaturated Fischer carbene complexes." Journal of Organometallic Chemistry 624, no. 1-2 (April 2001): 5–17. http://dx.doi.org/10.1016/s0022-328x(00)00837-8.

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