Academic literature on the topic 'Flory-Huggins Theory'

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Journal articles on the topic "Flory-Huggins Theory"

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Venetsanos, Fotis, Stefanos D. Anogiannakis, and Doros N. Theodorou. "Thermodynamic analysis of oligomeric blends by applying the Kirkwood-Buff theory of solutions." Journal of Physics: Conference Series 2090, no. 1 (2021): 012079. http://dx.doi.org/10.1088/1742-6596/2090/1/012079.

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Abstract The accurate prediction of the thermodynamic properties of oligomeric blends and, in general, binary liquid mixtures from atomistic simulations is a challenging task. In this work we develop a methodology for the full thermodynamic analysis of oligomeric blends and the extraction of the Flory-Huggins interaction parameter from the Gibbs energy of mixing, combining Flory-Huggins thermodynamics with Kirkwood-Buff theory of solutions. We perform a series of Molecular Dynamics (MD) simulations of 2-methylpentane/n-heptane mixtures, at various mole fractions. Firstly we validate the forcef
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Taylor, P. L., Yi‐Kuo Yu, and X. Y. Wang. "Kinetic theory and the Flory–Huggins approximation." Journal of Chemical Physics 105, no. 3 (1996): 1237–41. http://dx.doi.org/10.1063/1.471964.

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Mohan, Vijitha, Parthasakha Neogi, and Baojun Bai. "Flory-Huggins solution theory for heavy oils." Canadian Journal of Chemical Engineering 95, no. 4 (2016): 796–98. http://dx.doi.org/10.1002/cjce.22707.

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Cowen, Todd, Kal Karim, and Sergey A. Piletsky. "Solubility and size of polymer nanoparticles." Polymer Chemistry 9, no. 36 (2018): 4566–73. http://dx.doi.org/10.1039/c8py00829a.

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Milczewska, Kasylda, and Adam Voelkel. "The Use of Flory-Huggins Parameters in Characterization of Polymer-Filler Compositions." Materials Science Forum 587-588 (June 2008): 667–71. http://dx.doi.org/10.4028/www.scientific.net/msf.587-588.667.

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Inverse gas chromatography (IGC) has been applied to observe the interactions in filled polymer/organic solvent as well as modified filler/polymer systems under conditions approaching infinite dilution of the volatile component. In our study we will show that the Flory-Huggins theory is useful in the characterization of the interaction in polymer-filler systems. Authors propose to express the magnitude of modified filler/polymer interactions by Flory–Huggins ' 23 χ parameter. We examined the series of compositions of polyethylene (M= 35000) with different amount of modified silica filler (5, 1
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Yamamoto, Tetsuya, Tomohiro Yamazaki, and Tetsuro Hirose. "Phase separation driven by production of architectural RNA transcripts." Soft Matter 16, no. 19 (2020): 4692–98. http://dx.doi.org/10.1039/c9sm02458a.

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van der Sman, R. G. M. "Predicting the solubility of mixtures of sugars and their replacers using the Flory–Huggins theory." Food & Function 8, no. 1 (2017): 360–71. http://dx.doi.org/10.1039/c6fo01497f.

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Klueppelberg, Jana, Ulrich A. Handge, Markus Thommes, and Judith Winck. "Composition Dependency of the Flory–Huggins Interaction Parameter in Drug–Polymer Phase Behavior." Pharmaceutics 15, no. 12 (2023): 2650. http://dx.doi.org/10.3390/pharmaceutics15122650.

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An innovative strategy to address recent challenges in the oral administration of poorly soluble drugs is the formulation of amorphous solid dispersions (ASDs), where the drug is dissolved in a highly soluble carrier polymer. Therefore, special knowledge of the drug–polymer phase behavior is essential for an effective product and process design, accelerating the introduction of novel efficacious ASD products. Flory–Huggins theory can be applied to model solubility temperatures of crystalline drugs in carrier polymers over the drug fraction. However, predicted solubility temperatures lack accur
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Radovanovic, Philip, and Stephen W. Thiel. "Partition Coefficients at Infinite Dilution from Flory-Huggins Theory." Journal of Liquid Chromatography 13, no. 8 (1990): 1571–83. http://dx.doi.org/10.1080/01483919008048976.

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Wang, Jian, Yunchuan Xie, Yifei Zhang, et al. "The ultrahigh discharge efficiency and energy density of P(VDF-HFP) via electrospinning-hot press with St-MMA copolymer." Materials Chemistry Frontiers 5, no. 9 (2021): 3646–56. http://dx.doi.org/10.1039/d1qm00105a.

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Flory–Huggins theory combined with experimental tests and phase-field simulation proves that electrospinning improves the homogeneity and E<sub>b</sub> in composite films, and MS can limit the ferroelectric relaxation of PVDF and significantly increase U<sub>e</sub> and η.
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Dissertations / Theses on the topic "Flory-Huggins Theory"

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McCarney, Joseph Michael. "Reflection from interfaces." Thesis, University of Oxford, 1995. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.318860.

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Sant'Anna, Junior Walcyr. "Equilibrio de fase liquido-liquido entre poli(etilenoglicol) e hidrocarbonetos aromaticos." [s.n.], 2001. http://repositorio.unicamp.br/jspui/handle/REPOSIP/250154.

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Orientador: Edvaldo Sabadini<br>Dissertação (mestrado) - Universidade Estadual de Campinas, Instituto de Quimica<br>Made available in DSpace on 2018-08-13T13:40:57Z (GMT). No. of bitstreams: 1 Sant'AnnaJunior_Walcyr_M.pdf: 635340 bytes, checksum: 1249edac738f7933eee08fdecb6d0d7f (MD5) Previous issue date: 2001<br>Resumo: Este trabalho envolve o estudo do equilíbrio de fase líquido-líquido apresentado pelo sistema poli(etileno glicol), (PEG) e hidrocarbonetos aromáticos (HA). Os diagramas de fase são do tipo UCST (upper critical solution temperature), sendo que o grau de miscibilidade é forte
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Chun, Byeongjae. "Characterization of nano-phase segregation in multicompartment micelle and its applications: Computational approaches." Diss., Georgia Institute of Technology, 2015. http://hdl.handle.net/1853/54416.

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Computational methodologies were employed to study a supramolecular micellar structure and its application, nanoreactor. This task was done through rigorous scale-up procedure using both atomistic and mesoscopic simulations. Primarily, density functional theory (DFT) calculation was used to characterize the smallest unit of complex molecules in the multicomponent mixture system. The following step involved transferring the information achieved by DFT calculation to larger scale simulation, such as molecular dynamics (MD) simulation. Lastly, based on the atomistic simulation results, we perform
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Zhu, Yan. "Rational design of plastic packaging for alcoholic beverages." Thesis, Université Paris-Saclay (ComUE), 2019. http://www.theses.fr/2019SACLA020.

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La perception des emballages alimentaires est passée d’utile à source majeure de contaminants dans les aliments et menace pour l’environnement. La substitution du verre par des con-tenants en plastiques recyclés ou biosourcés réduit l’impact environnemental des boissons embouteillées. La thèse a développé de nouveaux outils de simulation 3D et d’optimisation pour accélérer le prototypage des emballages éco-efficaces pour les boissons alcoolisées. La durée de conservation des boissons, la sécurité sanitaire des matériaux plastiques recyclés, les contraintes mécaniques, et la quantité de déchets
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Imberg, Anna. "On Phase Behaviours in Lipid/Polymer/Solvent/Water Systems and their Application for Formation of Lipid/Polymer Composite Particles." Doctoral thesis, Uppsala : Acta Universitatis Upsaliensis : Univ.-bibl. [distributöt], 2003. http://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-3795.

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Le, Treut Guillaume. "Models of chromosome architecture and connection with the regulation of genetic expression." Thesis, Université Paris-Saclay (ComUE), 2016. http://www.theses.fr/2016SACLS411/document.

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Plusieurs indices suggèrent que le repliement du chromosome et la régulation de l’expression génétique sont étroitement liés. Par exemple, la co-expression d’un grand nombre de gènes est favorisée par leur rapprochement dans l’espace cellulaire. En outre, le repliement du chromosome permet de faire émerger des structures fonctionnelles. Celles-ci peuvent être des amas condensés et fibrillaires, interdisant l’accès à l’ADN, ou au contraire des configurations plus ouvertes de l’ADN avec quelques amas globulaires, comme c’est le cas avec les usines de transcription. Bien que dissemblables au prem
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LEE, XIAN-ZHE, and 李賢哲. "The Phase Diagram Measurements of Polyether-Poly(L-lactic acid)Diblock Copolymers in Aqueous Solutions by Rheology, Dynamic Light Scattering and Flory-Huggins Mean Field Theory." Thesis, 2018. http://ndltd.ncl.edu.tw/handle/nghkk6.

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碩士<br>國立臺灣科技大學<br>材料科學與工程系<br>106<br>Monomethoxy Poly(ethyl glycol)-Poly(L-lactic acid)(mPEG-PLLA) diblock copolymers with fixed mPEG length with degree of polymerization 113 and various PLLA with degree of polymerization from 35 to 98 were synthesized. The molecular weights were determined by gel permeation chromatography (GPC). The critical gelation concentration (CGC) was measured by tube-inverting method. We calculated the power-law exponents for the CGC versus the degree of polymerization. The phase transition temperatures were determined by rheological measurement. We used Flory-Huggins
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Book chapters on the topic "Flory-Huggins Theory"

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Gooch, Jan W. "Flory-Huggins Theory." In Encyclopedic Dictionary of Polymers. Springer New York, 2011. http://dx.doi.org/10.1007/978-1-4419-6247-8_5128.

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Scherer, Philipp, and Sighart F. Fischer. "Flory–Huggins Theory for Biopolymer Solutions." In Biological and Medical Physics, Biomedical Engineering. Springer Berlin Heidelberg, 2010. http://dx.doi.org/10.1007/978-3-540-85610-8_2.

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Scherer, Philipp O. J., and Sighart F. Fischer. "Flory–Huggins Theory for Biopolymer Solutions." In Biological and Medical Physics, Biomedical Engineering. Springer Berlin Heidelberg, 2017. http://dx.doi.org/10.1007/978-3-662-55671-9_2.

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Frank, Curtis W., Muhammad Amin Gashgari, and Steven N. Semerak. "Polymer Blend Thermodynamics: Flory Huggins Theory and Its Application to Excimer Fluorescence Studies." In Photophysical and Photochemical Tools in Polymer Science. Springer Netherlands, 1986. http://dx.doi.org/10.1007/978-94-009-4726-9_23.

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"Flory–Huggins theory." In Encyclopedic Dictionary of Polymers. Springer New York, 2007. http://dx.doi.org/10.1007/978-0-387-30160-0_5045.

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van der Sman, R. G. M. "Modelling Thermodynamics of Food Plasticizers." In Soft Matter in Foods. Royal Society of Chemistry, 2025. https://doi.org/10.1039/9781837676699-00072.

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In this chapter we introduce the thermodynamical modelling of plasticizers like sugars, which are commonly used in food materials. The thermodynamics of these plasticizers can largely be described by Flory–Huggins theory, including its extension to the glassy state. After a tutorial introduction of this theory, we describe the various phase transitions that apply to aqueous solutions containing such plasticizers. Complete phase diagrams can be constructed using this theory. We conclude with a discussion of how plasticizers modulate the phase transition of biopolymers like starch and proteins,
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Hari Naik, Ramavath, and Jyoti Sahu. "THERMODYNAMIC STUDY OF OSMOTIC COEFFICIENT OF FATTY ACID SALTS." In Futuristic Trends in Chemical Material Sciences & Nano Technology Volume 3 Book 24. Iterative International Publishers, Selfypage Developers Pvt Ltd, 2024. http://dx.doi.org/10.58532/v3becs24p4ch2.

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Fatty acid salts are used in numerous industrial applications. Understanding thermodynamics is crucial for achieving the desired quality of products in industries and for addressing a variety of environmental issues. we must understand thermodynamics. From sodium formate to sodium heptylate, we've taken a solution of seven sodium fatty acid salts and divided them into electrostatic and non-electrostatic depending on their constituents. An electrostatic contribution to the osmotic coefficient is given by the carboxylic group in the salt, while a non-electrostatic contribution is given by the hy
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Conference papers on the topic "Flory-Huggins Theory"

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Mullins, Oliver, Andrew Pomerantz, and Yunlong Zhang. "Asphaltenes: Fundamental Principles to Oilfield Applications." In SPE Annual Technical Conference and Exhibition. SPE, 2021. http://dx.doi.org/10.2118/206091-ms.

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Abstract The sophisticated molecular imaging methods, atomic force microscopy (AFM) and scanning tunneling microscopy (STM), have been utilized to image individual asphaltene molecules, both their atoms and bonds, and their electronic structure. The stunning images have confirmed previous results and have all but resolved the long-standing uncertainties regarding asphaltene molecular architecture. Asphaltenes are also known to have a strong propensity to aggregate. The dominante asphaltene molecular structure and hierarchical nanocolloidal structures have been resolved and codified in the Yen-
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Jensen, Melanie, Lalitha Venkataramanan, Li Chen, Sandip Bose, Peter Tilke, and Oliver C. Mullins. "AUTOMATED WORKFLOW TO INDICATE RESERVOIR CONNECTIVITY THROUGH ASPHALTENE EQUILIBRIUM." In 2021 SPWLA 62nd Annual Logging Symposium Online. Society of Petrophysicists and Well Log Analysts, 2021. http://dx.doi.org/10.30632/spwla-2021-0113.

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The evaluation of downhole fluid analysis (DFA) measurements of asphaltene gradients provides the ability to determine the extent of asphaltene equilibrium and the operative reservoir fluid geodynamics (RFG) processes. Typically, equilibrium of reservoir fluids indicates reservoir connectivity, a primary concern in field development planning. Currently, the modeling of asphaltene gradients is done through the manual evaluation of the DFA optical density gradients. The optical density measurements are fit to an equation of state (EOS), such as the Flory-Huggins-Zuo EOS, and evidence for asphalt
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Mohamed, Tarek S., Carlos Torres-Verdin, and Oliver C. Mullins. "Abnormal Viscosity and Other Implications of Reservoir Connectivity Inferred from Reservoir Fluid Geodynamics: A Case Study from Deepwater Gulf of Mexico." In International Petroleum Technology Conference. IPTC, 2024. http://dx.doi.org/10.2523/iptc-23723-ms.

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Abstract Reservoirs are often compartmentalized owing to the presence of barriers including structural flow barriers resulting from geodynamic processes such as faulting, or depositional stratigraphic barriers such as shale breaks. Concurrent with structural geodynamics, reservoir fluid geodynamics (RFG) processes take place such as fluid mixing, hence defining fluid systems that respond to their evolving reservoir container. RFG processes account for reservoir fluid compositional variation, spatial redistribution, and phase change from time of charge to present day. Accordingly, hydraulic con
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Blanco, Yon, Rolando di Primio, Øyvind Stirø, Julian J. Pop, Scotty Paul, and Velerian Sanjao Lopez. "Asphaltene Characterization Using Downhole Fluid Mapping While Drilling – Fluid Characterization Case Study for Completion Optimization." In 2024 SPWLA 65th Annual Symposium. Society of Petrophysicists and Well Log Analysts, 2024. https://doi.org/10.30632/spwla-2024-0037.

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A novel workflow is presented where logging-while-drilling downhole fluid analysis (LWD-DFA) data are combined with surface mudlogging to identify and quantify asphaltene distribution in the development phase of a North Sea field known to have complex fluid variations and compartmentalization. Data from two pilot wells were used for calibration and validation of optical densities from LWD-DFA and wireline downhole fluid analysis (WL-DFA) acquired in wells drilled during the appraisal phase vs. historical laboratory-measured asphaltene data. Subsequently, three horizontal producer wells were dr
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