Relevant bibliographies by topics / Fluorination

Contents

  1. Journal articles
  2. Dissertations / Theses
  3. Books
  4. Book chapters
  5. Conference papers
  6. Reports

Academic literature on the topic 'Fluorination'

Author: Grafiati
Published: 4 June 2021
Last updated: 26 July 2025

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Journal articles on the topic "Fluorination"

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Lantaño, Beatriz, and Al Postigo. "Radical fluorination reactions by thermal and photoinduced methods." Organic & Biomolecular Chemistry 15, no. 47 (2017): 9954–73. http://dx.doi.org/10.1039/c7ob02402a.

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Radical fluorination reactions of aliphatic Csp<sup>3</sup> and Csp<sup>2</sup> atoms, decarboxylative fluorination, and fluorination of (hetero)aromatics can be accomplished with electrophilic fluorinating reagents such as Selectfluor and NFSI.
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Bailey III, Wade H., William J. Casteel, and Robert G. Syvret. "Fluorination of Methyl 3-Oxopentanoate (MOP) Using Difluorobis(fluoroxy)methane, BDM." Collection of Czechoslovak Chemical Communications 67, no. 10 (2002): 1416–20. http://dx.doi.org/10.1135/cccc20021416.

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Difluorobis(fluoroxy)methane, BDM, is an electrophilic fluorinating agent that is capable of affecting selective monofluorination of 1,3-dicarbonyls such as diketones and ketoesters with very high regioselectivity. For example, in highly acidic anhydrous HF (AHF) solvent, fluorination of methyl 3-oxopentanoate (MOP) with BDM provides methyl 2-fluoro-3-oxopentanoate (MFOP) with 100% conversion and 95% selectivity. In mixtures of HF and methanol, fluorination conversions and selectivity are markedly lower. In comparison, direct fluorination of MOP with dilute F2 typically affords a fluorinated p
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Karelin, Vladimir A., Son Hai Le, Nadezhda V. Karelina, Alexander N. Strashko, Alexander V. Sazonov, and Huong M. T. Le. "Thermodynamics and Kinetics Research of the Fluorination Process of the Concentrate Rutile." Metals 12, no. 1 (2021): 34. http://dx.doi.org/10.3390/met12010034.

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The growth in the production of titanium metal and its compounds leads to an increase in the amount of toxic waste. As a result, at the legislative level, emissions of such wastes are limited, which leads to a drop in the production of titanium-containing products and a shortage of titanium in the international market. This paper presents the results of the process of fluorination of rutile concentrate from the Tarsky deposit (Russia, Omsk region) with elemental fluorine using a laboratory setup of a special design. For fluorination, samples of rutile concentrate weighing 0.1–1.0 g were used.
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Shibatomi, Kazutaka, Misaki Katada, Kazumasa Kitahara та Seiji Iwasa. "Catalyst-Free Decarboxylative Fluorination of Tertiary β-Keto Carboxylic Acids". Synlett 29, № 18 (2018): 2408–11. http://dx.doi.org/10.1055/s-0037-1611019.

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Decarboxylative fluorination of tertiary β-keto carboxylic ­acids was performed using an electrophilic fluorinating reagent. The reaction proceeded in the absence of a catalyst or base to yield the corresponding α-fluoroketones with tertiary fluorocarbons in good to high yields. Considering that the α-fluorination of asymmetrical ketones ­often causes problems with the regioselectivity between the α- and α′-positions, this method could be a good alternative to the α-fluorination of simple ketones for the synthesis of tertiary fluoroketones.
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Kharitonov, Alexander P., and Larisa N. Kharitonova. "Surface modification of polymers by direct fluorination: A convenient approach to improve commercial properties of polymeric articles." Pure and Applied Chemistry 81, no. 3 (2009): 451–71. http://dx.doi.org/10.1351/pac-con-08-06-02.

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The fundamental features and industrial applications of the direct fluorination of polymers are reviewed. Direct fluorination of polymers (i.e., treatment of a polymer surface with gaseous fluorine mixtures) proceeds spontaneously at room temperature and is a surface modification process. More than 25 polymers have been studied with the aid of a variety of analytical and spectroscopic techniques. The fundamental features of the direct fluorination, such as influence of treatment conditions (composition of the fluorinating mixture, fluorine partial pressure, temperature, and fluorination durati
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Haas, Alois, and Max Lieb. "Modern Synthetic Procedures for the Fluorination of Organic Molecules." CHIMIA 39, no. 5 (1985): 134. https://doi.org/10.2533/chimia.1985.134.

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In view of the number and diversity of publications on organofluorine chemistry in the recent years, it is evident that, since presenting the first series «Fluorierungsmethoden in der Organischen Chemie», fluorination reactions remain of general interest. The objectives of research in the various studies are quite similar. These include selective fluorination of biologically active substances such as steroids, nucleobases, pharmaceuticals, carbohydrates like sugars and glycosides; systematic studies for developing universally applicable fluorinating agents or improving reaction conditions; opt
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Cui, Benqiang, Shichong Jia, Etsuko Tokunaga, Norimichi Saito, and Norio Shibata. "Silver-induced self-immolative Cl–F exchange fluorination of arylsulfur chlorotetrafluorides: synthesis of arylsulfur pentafluorides." Chemical Communications 53, no. 95 (2017): 12738–41. http://dx.doi.org/10.1039/c7cc07222h.

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Oh, Young-Ho, Wonhyuck Yun, Chul-Hee Kim, et al. "Inter- and Intra-Molecular Organocatalysis of SN2 Fluorination by Crown Ether: Kinetics and Quantum Chemical Analysis." Molecules 26, no. 10 (2021): 2947. http://dx.doi.org/10.3390/molecules26102947.

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We present the intra- and inter-molecular organocatalysis of SN2 fluorination using CsF by crown ether to estimate the efficacy of the promoter and to elucidate the reaction mechanism. The yields of intramolecular SN2 fluorination of the veratrole substrates are measured to be very small (&lt;1% in 12 h) in the absence of crown ether promoters, whereas the SN2 fluorination of the substrate possessing a crown ether unit proceeds to near completion (~99%) in 12 h. We also studied the efficacy of intermolecular rate acceleration by an independent promoter 18-crown-6 for comparison. We find that t
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Iskra, Jernej, Stojan Stavber, and Marko Zupan. "Fluorination of Fluorene, Dibenzofuran and Their Open Analogues with Caesium Fluoroxysulfate and Related Fluorinating Reagents." Collection of Czechoslovak Chemical Communications 73, no. 12 (2008): 1671–80. http://dx.doi.org/10.1135/cccc20081671.

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Fluorination of fluorene (1) with caesium fluoroxysulfate (CFS), 2,6-dichloro-1-fluoropyridinium tetrafluoroborate (FP-B800) and 1-fluoro-4-hydroxy-1,4-diazoniabicyclo[2.2.2]- octane bis(tetrafluoroborate) (Accufluor NFTh) occurred only on the aromatic ring in the position ortho and para to the biphenyl central bond with the ratio 2-fluoro- (2a) vs 4-fluorofluorene (2b) 1.7-2.4:1. Regioselectivity of fluorination of both open-chain analogues - diphenylmethane (3a) and biphenyl (3b) was different and more ortho-fluorinated product was formed. Furthermore, the reaction of diphenylmethane (3a) wi
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Meublat, Laurent, Monique Lance, and Roland Bougon. "Reaction of RuO4 with KrF2: A clear-cut method to prepare ruthenium oxide tetrafluoride." Canadian Journal of Chemistry 67, no. 11 (1989): 1729–31. http://dx.doi.org/10.1139/v89-266.

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The fluorination of ruthenium tetroxide RuO4 was attempted by using either fluorine or krypton difluoride KrF2 in HF solution. Of the two fluorinating agents, only KrF2 was found to be powerful enough to react with RuO4 and to transform it into ruthenium oxide tetrafluoride RuOF4. This oxide fluoride of ruthenium VI was characterized by elemental analysis, X-ray powder diffraction, and infrared absorption spectroscopy. Keywords: ruthenium tetroxide, ruthenium oxide tetrafluoride, krypton difluoride, fluorination.
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Dissertations / Theses on the topic "Fluorination"

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Breen, Jessica Ruth. "Selective fluorination strategies." Thesis, Durham University, 2012. http://etheses.dur.ac.uk/3479/.

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There is a great interest in the synthesis of fluorinated aromatic and heterocyclic compounds, which have a range of applications in the pharmaceutical industry. Many common routes to these compounds, however, are low yielding and or/expensive. This thesis is concerned with novel methods for the synthesis of fluoro-aromatics and fluoro-pyrazoles using conventional fluorinating agents, such as Selectfluor™, as well as using elemental fluorine and the flow reactor technology developed in Durham. Firstly, elemental fluorine was used to fluorinate a range of aromatics containing electron-donating
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Thomas, Emmanuelle Maitrise de Chimie. "Electrophilic fluorination methodology." Thesis, Durham University, 2002. http://etheses.dur.ac.uk/4151/.

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Chapter One This chapter reviews the historical background of the fluorination using both elemental fluorine and N-F reagents. It relates the properties and preparations of these electrophilic reagents. And finally it discusses the use of these reagents in selective electrophilic fluorination (formation of C-F bond from C-H bond) of organic compounds. Chapter Two, Three and Four These chapters present our investigations into the fluorination of hydrocarbon systems containing an electron withdrawing group (ewg).Chapter Two shows the difference in reactivity of elemental fluorine and Selectfluor
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Scott, William Duncan Semion. "Catalytic fluorination of haloethanes." Thesis, University of Glasgow, 1997. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.337526.

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Greaney, Michael Francis. "Fluorination studies using difluoroiodotoluene." Thesis, University College London (University of London), 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.322308.

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Hollingworth, Charlotte. "Palladium mediated allylic fluorination." Thesis, University of Oxford, 2013. http://ora.ox.ac.uk/objects/uuid:8c61b9e9-b143-4c5e-b151-7e62bf4ecc03.

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In this thesis, the construction of the allylic fluorides under palladium catalysis was investigated. Chapter 1 provides a general introduction to organofluorine compounds and the use of palladium for the formation of both Csp<sup>2</sup>- and Csp<sup>3</sup>-F bonds. The aims of the thesis are presented. In Chapter 2 the identification that a p-nitrobenzoate is the optimum leaving group under Pd-catalysis to give allyl fluorides is described. A range of allylic fluorides was synthesized in 35->95% yield using the nucleophilic fluorinating reagent, TBAF(tBuOH)<sub>4</sub>. To further develop t
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Cresswell, Alex. "New methods for nucleophilic fluorination." Thesis, University of Oxford, 2011. http://ora.ox.ac.uk/objects/uuid:612ea592-2f52-407b-b761-36b02b746e9d.

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This thesis describes investigations into the utility of boron fluorides and tetrafluoroborates as sources of nucleophilic fluorine. Chapter 1 discusses the history and importance of the field of organofluorine chemistry and outlines some of the principle motivations for the site-selective fluorination of organic molecules. Some of the most commonly useed methods of nucleophilic fluorination are briefly surveyed, with an emphasis on the formation of fluorinated stereogenic centres. Literature precedent for the use of tetrafluoroborates and boron trifluoride as nucleophilic fluorinating agents
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Murray, Christopher B. "New methodology for nucleophilic fluorination." Thesis, Durham University, 2003. http://etheses.dur.ac.uk/3687/.

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This work describes the development of three methods for the fluorination of electrophilic substrates:1.) The reaction of caesium fluoride with perfluoro(2-methylpent-2-ene) leads to the formation of perfluoro(2-methylpentan-2-yl)caesium. This perfluoroalkyl carbanion has been shown to undergo significant fluoride ion exchange at temperatures above 60 C. Thus, reaction of a solution of the carbanion with a suitable electrophile resulted in the selective formation of a carbon-fluorine bond or perfluoroalkylation of the electrophile.2.) Caesium fluoride has been developed as a moderately effecti
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Mullins, Stephen T. "New methods for selective fluorination." Thesis, Durham University, 1986. http://etheses.dur.ac.uk/7056/.

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New methods have been developed for the selective introduction of fluorine into benzenoid aromatic compounds involving the cleavage of aryl-metal bonds by various ‘electrophilic’ fluorinating agents. Cleavage of aryl-metal bonds has been achieved using trifluoromethyl hypofluorite (CF(_3)OF), caesium fluoroxysulphate (CsSO(_4)F) and elemental fluorine and, by the nature of the process, is regiospecific. Attempts have been made to extend this method to the introduction of fluorine into imidazole bases with some success. This approach has involved the synthesis of trialkylstannyl derivatives of
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Nakano, Takashi. "Methodologies for selective electrophilic fluorination." Thesis, Durham University, 2004. http://etheses.dur.ac.uk/2989/.

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Chapter 1 Chapter 1 contains a discussion of the effects of the introduction of fluorine atoms into organic molecules. A review of electrophilic fluorination reactions which have been reported recently, from the viewpoint of selectivity is given. Chapter 2 As a new methodology for selective fluorination of unactivated C-H sites, geometrically directed remote fluorination of steroid derivatives was investigated. Steroid derivatives bearing a variety of tethers which possess an ability to interact with elemental fluorine were prepared. Direct fluorination of 3ɑ-(3-cyanobenzoyloxy)- 5ɑ-androstan-
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Parsons, Mandy. "Electrophilic fluorination at saturated carbon." Thesis, Durham University, 2000. http://etheses.dur.ac.uk/4415/.

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Chapter 1 - Chapter 1 contains a discussion of the preparation and properties of elemental fluorine. A review of the use of elemental fluorine as a selective fluorinating in organic chemistry is given and the preparation and use of other selective fluorinating agents is also described. Chapter 2 - Direct fluorination methodology for the preparation of selectively fluorinated hydrocarbon compounds was developed and used to prepare a range of both cyclic and acyclic fluoroalkanes. Selectfluor™ a commercial fluorinating agent of the N-F class, was also used to prepare selectively fluorinated hydr
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Books on the topic "Fluorination"

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Hu, Jinbo, and Teruo Umemoto, eds. Fluorination. Springer Singapore, 2020. http://dx.doi.org/10.1007/978-981-10-1855-8.

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David, Wails, and Bastock T. W, eds. Aromatic fluorination. CRC Press, 1996.

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Clayton, Peter Paul. Studies in selective fluorination. University of Birmingham, 1989.

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Kharitonov, A. P. Direct fluorination of polymers. Nova Science Publishers, 2008.

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Welch, John T., ed. Selective Fluorination in Organic and Bioorganic Chemistry. American Chemical Society, 1991. http://dx.doi.org/10.1021/bk-1991-0456.

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T, Welch John, American Chemical Society. Division of Fluorine Chemistry., and American Chemical Society Meeting, eds. Selective fluorination in organic and bioorganic chemistry. American Chemical Society, 1991.

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Popplewell, A. L. Electrophilic fluorination of organic compounds using selectfluorTM. UMIST, 1997.

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1931-, German L., and Novosibirskiĭ institut organicheskoĭ khimii, eds. Novye ftorirui͡u︡shchie reagenty v organicheskom sinteze. Izd-vo "Nauka," Sibirskoe otd-nie, 1987.

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Symposium on Electrochemistry in the Preparation of Fluorine and Its Compounds (1997 Montréal, Québec). Proceedings of the Symposium on Electrochemistry in the Preparation of Fluorine and Its Compounds. Edited by Childs W. Ves, Fuchigami Toshio, Electrochemical Society. Industrial Electrolysis and Electrochemical Engineering Division., and Electrochemical Society. Organic and Biological Electrochemistry Division. Electrochemical Society, 1997.

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Shcherbakov, V. I. Kinetika i mekhanizm ftorirovanii͡a︡ soedineniĭ urana, plutonii͡a︡ i neptunii͡a︡ ftorom i galogenftoridami. Ėnergoatomizdat, 1985.

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Book chapters on the topic "Fluorination"

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Yan, Hong, and Chen Zhu. "NFSI Radical Fluorination for Preparing Alkyl Fluorides." In Fluorination. Springer Singapore, 2017. http://dx.doi.org/10.1007/978-981-10-1855-8_1-1.

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Guo, Shuo, and Pingping Tang. "PhenoFluor Deoxofluorination." In Fluorination. Springer Singapore, 2017. http://dx.doi.org/10.1007/978-981-10-1855-8_10-1.

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Qu, Wenchao, and Ximin Li. "TASF Fluorination for Preparing Alkyl Fluorides." In Fluorination. Springer Singapore, 2017. http://dx.doi.org/10.1007/978-981-10-1855-8_11-1.

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Qu, Wenchao, and Ximin Li. "Fluorination of Diaryliodonium Salts for Preparing Aryl Fluorides." In Fluorination. Springer Singapore, 2017. http://dx.doi.org/10.1007/978-981-10-1855-8_12-1.

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Qu, Wenchao, and Ximin Li. "Fluorination of Diaryliodonium Salts for Preparing Aryl Fluorides." In Fluorination. Springer Singapore, 2018. http://dx.doi.org/10.1007/978-981-10-1855-8_12-2.

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Qu, Wenchao, and Ximin Li. "Fluorination of Aryl-Alkenyl-Iodonium Salts for Preparing Alkenyl Fluorides." In Fluorination. Springer Singapore, 2017. http://dx.doi.org/10.1007/978-981-10-1855-8_13-1.

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Sun, Haoran, and Stephen G. Dimagno. "TBAF Fluorination for Preparing Alkyl Fluorides." In Fluorination. Springer Singapore, 2017. http://dx.doi.org/10.1007/978-981-10-1855-8_14-1.

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Sun, Haoran, and Stephen G. DiMagno. "TBAF Fluorination for Preparing Alkyl Fluorides." In Fluorination. Springer Singapore, 2018. http://dx.doi.org/10.1007/978-981-10-1855-8_14-2.

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Liang, Shengzong, Gerald B. Hammond, and Bo Xu. "Functionalization of Alkynes for Preparing Alkenyl Fluorides." In Fluorination. Springer Singapore, 2017. http://dx.doi.org/10.1007/978-981-10-1855-8_15-1.

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Zhu, Lin, and Chaozhong Li. "Transition Metal-Mediated Radical Fluorination for Preparing Alkyl Fluorides." In Fluorination. Springer Singapore, 2017. http://dx.doi.org/10.1007/978-981-10-1855-8_16-1.

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Conference papers on the topic "Fluorination"

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Ha, Heeju, Yongjae Kim, Minsung Jeon, and Heeyeop Chae. "Plasma atomic layer etching of molybdenum with surface fluorination for next-generation interconnect." In Advanced Etch Technology and Process Integration for Nanopatterning XIV, edited by Efrain Altamirano-Sánchez and Nihar Mohanty. SPIE, 2025. https://doi.org/10.1117/12.3050967.

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Quijada, Manuel A., Javier G. Del Hoyo, Luis V. Rodriguez-de-Marcos, et al. "Enhanced far ultra-violet optical properties of physical vapor deposited aluminum mirrors through fluorination." In Space Telescopes and Instrumentation 2024: Ultraviolet to Gamma Ray, edited by Jan-Willem A. den Herder, Kazuhiro Nakazawa, and Shouleh Nikzad. SPIE, 2024. http://dx.doi.org/10.1117/12.3021592.

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Park, Jaewoo, Amanda Leong, and Jinsuo Zhang. "Interactions Between U-Bearing Fluoride Fuel Salts and Graphite." In AM-EPRI 2024. ASM International, 2024. http://dx.doi.org/10.31399/asm.cp.am-epri-2024p1331.

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Abstract A thorough understanding of interactions between graphite and fluoride fuel salts is crucial, as graphite is a promising candidate for the moderator of molten salt reactors. This study investigates the infiltration of fluoride fuel salts into graphite and the fluorination of graphite by these salts under various pressures and temperatures. A high-pressure salt infiltration test apparatus was developed to examine the infiltration of NaF-KF-UF4 and NaF-BeF2-UF4-ZrF4 fuel salts into two types of graphite at high temperatures. For tests using NaF-BeF2-UF4-ZrF4, two different temperatures
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Weltschev, Margit, Manuela Haufe, Anka Kohl, and Rainer Rehfeldt. "Resistance of Polyethylene Grades with Permeation Barriers in Biofuels." In CORROSION 2018. NACE International, 2018. https://doi.org/10.5006/c2018-10543.

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Abstract Biofuels including ethanol and biodiesel (FAME) represent a renewable fuel alternative to petroleum- derived transport fuels. The aim of this work was to study the interaction between high density polyethylene (HDPE) with permeation barriers in form of polyamide (PA) and fluorination, and biofuels such as E85 (fuel with 85 % ethanol), biodiesel and B10 (heating oil with 10 % biodiesel). 10 l jerrycans made of polyethylene with permeation barrier of PA were filled with E85 and biodiesel and exposed to temperatures of 20 °C and 40 °C for 5 years. Half of the 20 l jerrycans of HDPE for f
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Ritter, Tobias. "Late-Stage Fluorination." In 15th Brazilian Meeting on Organic Synthesis. Editora Edgard Blücher, 2013. http://dx.doi.org/10.5151/chempro-15bmos-speech9.

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Hartwig, John F. "Borylation, Silylation, Fluorination and Fluoroalkylation." In 15th Brazilian Meeting on Organic Synthesis. Editora Edgard Blücher, 2013. http://dx.doi.org/10.5151/chempro-15bmos-speech11.

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Ovshinsky, Stanford R., and Rosa T. Young. "Unusual fluorination effects on superconducting films." In San Dieg - DL Tentative, edited by Michael R. Jacobson. SPIE, 1990. http://dx.doi.org/10.1117/12.22413.

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Montgomery, Patrick K., Richard D. Peters, Cesar Garza, et al. "Improved ion implantation masking through photoresist fluorination." In SPIE 31st International Symposium on Advanced Lithography, edited by Qinghuang Lin. SPIE, 2006. http://dx.doi.org/10.1117/12.651047.

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Garza, Cesar M., and Willard E. Conley. "Elimination of photoresist linewidth slimming by fluorination." In Microlithography 2004, edited by John L. Sturtevant. SPIE, 2004. http://dx.doi.org/10.1117/12.533331.

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Ueno, Yuichiro, Toshiki Katsuta, Koudai Taguchi, Mayuko Nakagawa, Naohiro Yoshida, and Alexis Gilbert. "Application of fluorination method to isotopologue biogeochemistry." In Goldschmidt2021. European Association of Geochemistry, 2021. http://dx.doi.org/10.7185/gold2021.7358.

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Reports on the topic "Fluorination"

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Sedath, R. H., S. F. Yates, and N. N. Li. Reduced fouling of ultrafiltration membranes via surface fluorination. Office of Scientific and Technical Information (OSTI), 1993. http://dx.doi.org/10.2172/6695060.

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Sedath, R. H., S. F. Yates, and N. N. Li. Reduced fouling of ultrafiltration membranes via surface fluorination. Office of Scientific and Technical Information (OSTI), 1993. http://dx.doi.org/10.2172/10130600.

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Padgett, Henry C. DOE SBIR Phase I Grant No. DE-FG02-00ER83067, ''A Flexible and Economical Automated Nucleophilic [{sup 18}F]Fluorination synthesis System for PET Radiopharmaceuticals.'' Final Technical Report. Office of Scientific and Technical Information (OSTI), 2001. http://dx.doi.org/10.2172/808241.

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