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Journal articles on the topic 'Fluorine gauche effect'

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1

Thiehoff, Christian, Yannick P. Rey, and Ryan Gilmour. "The Fluorine Gauche Effect: A Brief History." Israel Journal of Chemistry 57, no. 1-2 (2016): 92–100. http://dx.doi.org/10.1002/ijch.201600038.

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2

Silla, Josué M., Claudimar J. Duarte, Rodrigo A. Cormanich, Roberto Rittner, and Matheus P. Freitas. "Conformational analysis of 2,2-difluoroethylamine hydrochloride: double gauche effect." Beilstein Journal of Organic Chemistry 10 (April 16, 2014): 877–82. http://dx.doi.org/10.3762/bjoc.10.84.

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The gauche effect in fluorinated alkylammonium salts is well known and attributed either to an intramolecular hydrogen bond or to an electrostatic attraction between the positively charged nitrogen and the vicinal electronegative fluorine atom. This work reports the effect of adding a fluorine atom in 2-fluoroethylamine hydrochloride on the conformational isomerism of the resulting 2,2-difluoroethylamine chloride (2). The analysis was carried out using NMR coupling constants in D2O solution, in order to mimic the equilibrium conditions in a physiological medium, in the gas phase and in implici
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3

Baranac-Stojanović, Marija, Milovan Stojanović, and Jovana Aleksić. "Theoretical study of azido gauche effect and its origin." New Journal of Chemistry 41, no. 11 (2017): 4644–61. http://dx.doi.org/10.1039/c7nj00369b.

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4

Port, Vinicius C., and Rodrigo A. Cormanich. "There and back again: the role of hyperconjugation in the fluorine gauche effect." Physical Chemistry Chemical Physics 23, no. 32 (2021): 17329–37. http://dx.doi.org/10.1039/d1cp02806e.

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The fluorine gauche effect was revisited by comparing the rotational profile of 1,2-difluoroethane (DFE) with several analogues, such as peroxides and dissulfides. Hyperconjugative effects are the most important ones for the gauche preference of DFE.
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5

Andrade, Laize A. F., Lucas A. Zeoly, Rodrigo A. Cormanich, and Matheus P. Freitas. "Conformational signature of Ishikawa´s reagent using NMR information from diastereotopic fluorines." Beilstein Journal of Organic Chemistry 15 (February 20, 2019): 506–12. http://dx.doi.org/10.3762/bjoc.15.44.

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The active species of the Ishikawa´s reagent [N,N-diethyl-(1,1,2,3,3,3-hexafluoropropyl)amine] is a fluorinating hexafluoropropylamine used to convert alcohols into alkyl fluorides. On the other hand, it is also an example of model compound useful to probe conformational preferences using spectroscopic information from diastereotopic fluorines. Moreover, the possibility of experiencing both the generalized anomeric and gauche effects makes the Ishikawa´s reagent an ideal choice to study the governing stereoelectronic interactions of the conformational equilibrium of organofluorine compounds. T
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6

Paul, Susann, W. Bernd Schweizer, Graham Rugg, Hans Martin Senn, and Ryan Gilmour. "The fluorine-NHC gauche effect: a structural and computational study." Tetrahedron 69, no. 27-28 (2013): 5647–59. http://dx.doi.org/10.1016/j.tet.2013.02.071.

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7

Thiehoff, C., M. C. Holland, C. Daniliuc, K. N. Houk, and R. Gilmour. "Can acyclic conformational control be achieved via a sulfur–fluorine gauche effect?" Chemical Science 6, no. 6 (2015): 3565–71. http://dx.doi.org/10.1039/c5sc00871a.

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Herein detailed conformational analyses of β-fluorosulfides, -sulfoxides and -sulfones are disclosed, thus extending the scope of the fluorine gauche effect to the 3<sup>rd</sup> Period (X = SR, SOR, SO<sub>2</sub>R; ϕ<sub>FCCS</sub> ≈ 60°).
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8

Thiehoff, Christian, Lukas Schifferer, Constantin G. Daniliuc, Nico Santschi, and Ryan Gilmour. "The influence of electronic perturbations on the Sulfur–Fluorine Gauche Effect." Journal of Fluorine Chemistry 182 (February 2016): 121–26. http://dx.doi.org/10.1016/j.jfluchem.2016.01.003.

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9

Andrade, Laize A. F., та Matheus P. Freitas. "Not all third-row elements experience the fluorine gauche effect: β-fluorinated organophosphorus compounds". New Journal of Chemistry 41, № 20 (2017): 11672–78. http://dx.doi.org/10.1039/c7nj02463k.

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Conformational analyses of β-fluorinated organophosphorus compounds were theoretically carried out to probe the role of a possible fluorine–phosphorus gauche effect in conformer stabilization, specifically using a phosphine, a phosphine oxide, phosphinic and phosphonic acids, and the corresponding anions as model compounds.
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10

Aufiero, Marialuisa, and Ryan Gilmour. "Informing Molecular Design by Stereoelectronic Theory: The Fluorine Gauche Effect in Catalysis." Accounts of Chemical Research 51, no. 7 (2018): 1701–10. http://dx.doi.org/10.1021/acs.accounts.8b00192.

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11

Buissonneaud, David Y., Tanja van Mourik, and David O'Hagan. "A DFT study on the origin of the fluorine gauche effect in substituted fluoroethanes." Tetrahedron 66, no. 12 (2010): 2196–202. http://dx.doi.org/10.1016/j.tet.2010.01.049.

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12

Santschi, Nico, Christian Thiehoff, Mareike C. Holland, Constantin G. Daniliuc, K. N. Houk, and Ryan Gilmour. "The Sulfur–Fluorine Gauche Effect in Coinage-Metal Complexes: Augmenting Conformational Equilibria by Complexation." Organometallics 35, no. 17 (2016): 3040–44. http://dx.doi.org/10.1021/acs.organomet.6b00564.

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13

O’Hagan, David, Clair Bilton, Judith A. K. Howard, Lee Knight та David J. Tozer. "The preferred conformation of N-β-fluoroethylamides. Observation of the fluorine amide gauche effect". Journal of the Chemical Society, Perkin Transactions 2, № 4 (2000): 605–7. http://dx.doi.org/10.1039/b000205o.

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14

Aleksić, Jovana, Milovan Stojanović та Marija Baranac-Stojanović. "Origin of Fluorine/Sulfur Gauche Effect of β-Fluorinated Thiol, Sulfoxide, Sulfone, and Thionium Ion". Journal of Organic Chemistry 80, № 20 (2015): 10197–207. http://dx.doi.org/10.1021/acs.joc.5b01779.

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15

Molnar, Istvan Gabor, Eva-Maria Tanzer, Constantin Daniliuc, and Ryan Gilmour. "ChemInform Abstract: Enantioselective Aziridination of Cyclic Enals Facilitated by the Fluorine-Iminium Ion Gauche Effect." ChemInform 45, no. 28 (2014): no. http://dx.doi.org/10.1002/chin.201428086.

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16

Briggs, Caroline R. S., David O’Hagan, Henry S. Rzepa та Alexandra M. Z. Slawin. "Solid state and theoretical evaluation of β-fluoroethyl esters indicate a fluorine-ester gauche effect". Journal of Fluorine Chemistry 125, № 1 (2004): 19–25. http://dx.doi.org/10.1016/j.jfluchem.2003.08.011.

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17

Martins, Francisco A., and Matheus P. Freitas. "The Fluorine gauche Effect and a Comparison with Other Halogens in 2-Halofluoroethanes and 2-Haloethanols." European Journal of Organic Chemistry 2019, no. 37 (2019): 6401–6. http://dx.doi.org/10.1002/ejoc.201901234.

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18

Scheidt, Felix, Christian Thiehoff, Gülay Yilmaz, et al. "Fluorocyclisation via I(I)/I(III) catalysis: a concise route to fluorinated oxazolines." Beilstein Journal of Organic Chemistry 14 (May 9, 2018): 1021–27. http://dx.doi.org/10.3762/bjoc.14.88.

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Herein, we describe a catalytic fluorooxygenation of readily accessible N-allylcarboxamides via an I(I)/I(III) manifold to generate 2-oxazolines containing a fluoromethyl group. Catalysis is conditional on the oxidation competence of Selectfluor®, whilst HF serves as both a fluoride source and Brønsted acid activator. The C(sp3)–F bond of the mono-fluoromethyl unit and the C(sp3)–O bond of the ring are aligned in a synclinal relationship thereby engaging in stabilising hyperconjugative interactions with vicinal, electron-rich σ-bonds (σC–C→σ*C–F and σC–H→σ*C–O). This manifestation of the stere
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19

Tanzer, Eva-Maria, Lucie E. Zimmer, W. Bernd Schweizer, and Ryan Gilmour. "Fluorinated Organocatalysts for the Enantioselective Epoxidation of Enals: Molecular Preorganisation by the Fluorine-Iminium Ion Gauche Effect." Chemistry - A European Journal 18, no. 36 (2012): 11334–42. http://dx.doi.org/10.1002/chem.201201316.

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20

Bentler, Patrick, Klaus Bergander, Constantin G. Daniliuc, et al. "Inverting Small Molecule–Protein Recognition by the Fluorine Gauche Effect: Selectivity Regulated by Multiple H→F Bioisosterism." Angewandte Chemie International Edition 58, no. 32 (2019): 10990–94. http://dx.doi.org/10.1002/anie.201905452.

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21

Bentler, Patrick, Klaus Bergander, Constantin G. Daniliuc, et al. "Inverting Small Molecule–Protein Recognition by the Fluorine Gauche Effect: Selectivity Regulated by Multiple H→F Bioisosterism." Angewandte Chemie 131, no. 32 (2019): 11106–10. http://dx.doi.org/10.1002/ange.201905452.

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22

Sparr, Christof, Evdokiya Salamanova, W. Bernd Schweizer, Hans Martin Senn, and Ryan Gilmour. "Theoretical and X-ray Crystallographic Evidence of a Fluorine-Imine Gauche Effect: An Addendum to Dunathan’s Stereoelectronic Hypothesis." Chemistry - A European Journal 17, no. 32 (2011): 8850–57. http://dx.doi.org/10.1002/chem.201100644.

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23

Tanzer, Eva-Maria, W. Bernd Schweizer, Marc-Olivier Ebert та Ryan Gilmour. "Designing Fluorinated Cinchona Alkaloids for Enantioselective Catalysis: Controlling Internal Rotation by a Fluorine-Ammonium Ion gauche Effect (φNCCF)". Chemistry - A European Journal 18, № 7 (2012): 2006–13. http://dx.doi.org/10.1002/chem.201102859.

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24

Teschers, Charlotte S., Constantin G. Daniliuc, Gerald Kehr та Ryan Gilmour. "Conformational control enabled by the fluorine gauche effect in a model of the β2-AR agonist salbutamol (Ventolin™)". Journal of Fluorine Chemistry 210 (червень 2018): 1–5. http://dx.doi.org/10.1016/j.jfluchem.2018.02.007.

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25

Martins, Francisco A., Josué M. Silla, and Matheus P. Freitas. "Conformational impact of structural modifications in 2-fluorocyclohexanone." Beilstein Journal of Organic Chemistry 13 (August 24, 2017): 1781–87. http://dx.doi.org/10.3762/bjoc.13.172.

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2-Haloketones are building blocks that combine physical, chemical and biological features of materials and bioactive compounds, while organic fluorine plays a fundamental role in the design of performance organic molecules. Since these features are dependent on the three-dimensional chemical structure of a molecule, simple structural modifications can affect its conformational stability and, consequently, the corresponding physicochemical/biological property of interest. In this work, structural changes in 2-fluorocyclohexanone were theoretically studied with the aim at finding intramolecular
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26

Thacker, Joseph C. R., and Paul L. A. Popelier. "Fluorine Gauche Effect Explained by Electrostatic Polarization Instead of Hyperconjugation: An Interacting Quantum Atoms (IQA) and Relative Energy Gradient (REG) Study." Journal of Physical Chemistry A 122, no. 5 (2018): 1439–50. http://dx.doi.org/10.1021/acs.jpca.7b11881.

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27

Tavasli, Mustafa, David O’Hagan, Christopher Pearson, and Michael C. Petty. "The fluorine gauche effect. Langmuir isotherms report the relative conformational stability of (±)-erythro- and (±)-threo-9,10-difluorostearic acidsElectronic supplementary information (ESI) available: characterisation of compounds 4, 5, 7–9, 11–13. See http://www.rsc.org/suppdata/cc/b2/b202891c/." Chemical Communications, no. 11 (May 7, 2002): 1226–27. http://dx.doi.org/10.1039/b202891c.

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28

Emenike, Bright U., and Simran S. Dhami. "Determining the Ionization Constants of Organic Acids Using Fluorine Gauche Effects." Journal of Organic Chemistry 85, no. 7 (2020): 4896–900. http://dx.doi.org/10.1021/acs.joc.0c00062.

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29

Mohamed, Shifaza, Elizabeth H. Krenske, and Vito Ferro. "The stereoselectivities of tributyltin hydride-mediated reductions of 5-bromo-d-glucuronides to l-iduronides are dependent on the anomeric substituent: syntheses and DFT calculations." Organic & Biomolecular Chemistry 14, no. 10 (2016): 2950–60. http://dx.doi.org/10.1039/c6ob00283h.

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30

Tian, Li, Xiang Jian Meng, Jing Yang, et al. "Relaxor Properties and Tunability of Electron-Irradiated Thin Poly(vinlidene fluoride-trifluoroethylene) Copolymer Film." Advanced Materials Research 560-561 (August 2012): 892–98. http://dx.doi.org/10.4028/www.scientific.net/amr.560-561.892.

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The effect of high energy electron irradiation on poly(vinlidene fluoride-trifluoroethylene) copolymer film with thickness about 180 nm has been studied. Both dielectric spectroscopy investigation and X-Ray Diffraction show that all-trans conformation of pre-irradiated films is transformed to trans-gauche conformation after irradiation. The relaxor behavior of irradiated sample obeys the modified Curie-Weiss and Vogel-Fulcher law. And the tunability is increased from 42% to 63% after irradiation.
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31

Ma, Lei, Shreyes N. Melkote, John B. Morehouse, James B. Castle, James W. Fonda, and Melissa A. Johnson. "Design of thin-film polyvinylidene fluoride sensor rosettes for isolation of various strain components." Journal of Intelligent Material Systems and Structures 23, no. 10 (2012): 1119–30. http://dx.doi.org/10.1177/1045389x12443597.

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Thin-film polyvinylidene fluoride piezoelectric sensors have long been recognized as a promising alternative to traditional metal foil strain gauges in applications where only dynamic or quasistatic signals are of interest. Compared to metal foil strain gauges, polyvinylidene fluoride sensors feature high sensitivity, high dynamic range, and broad frequency bandwidth. However, transverse sensitivity of the polyvinylidene fluoride sensor is higher than that of a metal foil strain gauge, making it more difficult to isolate a particular strain component or a deformation mode when the host structu
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32

Pfund, Emmanuel, and Thierry Lequeux. "Synthesis of Fluoropyrrolidines and (Fluoroalkyl)pyrrolidines." Synthesis 49, no. 17 (2017): 3848–62. http://dx.doi.org/10.1055/s-0036-1589078.

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Pyrrolidines and their derivatives are of great interest in medicinal chemistry and organic synthesis. Fluoropyrrolidines and (fluoroalkyl)pyrrolidines have been utilized in the preparation of medicinal drugs and also as organocatalysts. The synthesis of such compounds is achieved through the fluorination of pyrrolidine derivatives or by multistep synthesis from already containing fluoroalkyl precursors.1 Introduction1.1 General Interest of Fluorine-Containing Pyrrolidines1.2 Fluoroalkylpyrrolidines and the Gauche Effect2 Fluoropyrrolidines2.1 3-Fluoropyrrolidines2.2 3,3- and 3,4-Difluoropyrro
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33

Gilmour, Ryan, István Molnár, Mareike Holland, Constantin Daniliuc, and K. Houk. "Organocatalysis Intermediates as Platforms to Study Noncovalent Interactions: Integrating Fluorine Gauche Effects in Iminium Systems to Facilitate Acyclic Conformational Control." Synlett 27, no. 07 (2016): 1051–55. http://dx.doi.org/10.1055/s-0035-1561199.

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34

Sufarnap, Erliera, Kholidina Imanda Harahap, and Terry Terry. "Effect of sodium fluoride in chlorhexidine mouthwashes on force decay and permanent deformation of orthodontic elastomeric chain." Padjadjaran Journal of Dentistry 33, no. 1 (2021): 74. http://dx.doi.org/10.24198/pjd.vol33no1.26370.

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Introduction: Orthodontic elastomeric chain is polyurethane elastomer that is widely used among orthodontists due to its functions. Chlorhexidine (CHX) and sodium fluoride (NaF) are listed in mouthwash composition which could affect the mechanical properties of the elastomeric chain. This study was aimed to analyze the effect of sodium fluoride in chlorhexidine mouthwashes on force decay and permanent deformation of orthodontic elastomeric chains. Methods: This research is an experimental analytic laboratory with pretest-posttest control group design. 150 samples of orthodontic chains were div
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35

ABOLHASANI, MOHAMMAD MAHDI, MINOO NAEBE, AZAM JALALI-ARANI та QIPENG GUO. "CRYSTALLINE STRUCTURES AND α → β AND γ POLYMORPHS TRANSFORMATION INDUCED BY NANOCLAY IN PVDF-BASED NANOCOMPOSITE". Nano 09, № 06 (2014): 1450065. http://dx.doi.org/10.1142/s1793292014500659.

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Poly(vinylidene fluoride) (PVDF) nanocomposites were prepared by melt-mixing. The dispersion of clay platelets and rheology of nanocomposites were analyzed using X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and rheometric mechanical spectrometer (RMS). The transformation of α to β and γ phase in PVDF was induced by the addition of nanoclay and subsequently the isothermal crystallization kinetics of neat PVDF and its nanocomposite have been investigated. The interaction between clay nanofillers and PVDF macromolecular chains induced the cha
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36

Tashiro, Kohji, Rieko Tanaka, Kazumi Ushitora, and Masamichi Kobayashi. "Annealing effect on ferroelectric phase transitional behavior of vinylidene fluoride-trifluoroethylene copolymers: An interpretation based on the concept of domain and trans-gauche conformational disorder." Ferroelectrics 171, no. 1 (1995): 145–62. http://dx.doi.org/10.1080/00150199508018428.

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37

Quock, RL, JA Barros, SW Yang, and SA Patel. "Effect of Silver Diamine Fluoride on Microtensile Bond Strength to Dentin." Operative Dentistry 37, no. 6 (2012): 610–16. http://dx.doi.org/10.2341/11-344-l.

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SUMMARY The aim of this in vitro study was to investigate the effect of the cariostatic and preventive agent silver diamine fluoride (SDF) on the microtensile bond strength of resin composite to dentin. Forty-two caries-free, extracted molars were flattened occlusally and apically using a diamond saw, and the exposed occlusal dentin was polished with a series of silicon carbide papers, all under water irrigation. The teeth were then randomly divided into six groups of seven teeth each that were treated as follows: 1) Peak SE self-etch bonding agent; 2) 12% SDF + Peak SE; 3) 38% SDF + Peak SE;
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38

Zhang, Yue Xian, and Bin Li. "Research on the Technology of Flexible Tactile Type Sensor." Applied Mechanics and Materials 226-228 (November 2012): 1993–98. http://dx.doi.org/10.4028/www.scientific.net/amm.226-228.1993.

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The application filed and characteristics of flexible tactile sensor are introduced in this paper. Main technologies including microelectronics mechanical system and other new material of flexible tactile sensor are proposed. The structure and the working principle of microelectronics mechanical system used in flexible sensor are described and explained. The principle of piezoresistive of strain gauge is researched on. The piezoelectric properties of polyvinylidene fluoride is also narrated. The coupling effect of the dielectric mechanical properties and the dielectric mechanical properties ar
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39

Hu, Bin, Yaolu Liu, Ning Hu, et al. "Conductive PVDF-HFP/CNT composites for strain sensing." Functional Materials Letters 09, no. 02 (2016): 1650024. http://dx.doi.org/10.1142/s1793604716500247.

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A strain sensor based on the composites of poly (vinylidene fluoride-hexafluoropropylene) (PVDF-HFP) filled by multi-walled carbon nanotube (MWNT) was prepared using a proposed fabrication process. Three kinds of MWNT loadings, i.e., 1.0[Formula: see text]wt.%, 2.0[Formula: see text]wt.% and 3.0[Formula: see text]wt.% were employed. Due to good dispersion state of MWNT in PVDF-HFP matrix, which was characterized by scanning electron microscope (SEM), this sensor was found to be of high sensitivity and stable performance. The sensor’s piezoresistivity varied in a weak nonlinear pattern, which w
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40

Xu, Jinglin, Jianqing Liu, Wenbin Gu, Xin Liu, and Tao Cao. "Shock Wave Attenuation Characteristics of Aluminum Foam Sandwich Panels Subjected to Blast Loading." Shock and Vibration 2018 (2018): 1–10. http://dx.doi.org/10.1155/2018/2686389.

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Comparative experiments were conducted with two different structures to study the mechanism of aluminum foam sandwich attenuating blast shock wave. The sandwich structure is composed of “steel–aluminum foam–steel,” and the mild steel structure is composed of “steel–steel.” In the experiment, the polyvinylidene fluoride transducers were used to directly test the load of stress wave between different interfaces of sandwich and mild steel structures. The strain of back sheet was simultaneously measured using high-precision strain gauge. The accuracy of the test results was verified by Henrych’s f
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41

Sparr, Christof, W. Bernd Schweizer, Hans Martin Senn, and Ryan Gilmour. "ChemInform Abstract: The Fluorine-Iminium Ion Gauche Effect: Proof of Principle and Application to Asymmetric Organocatalysis." ChemInform 40, no. 34 (2009). http://dx.doi.org/10.1002/chin.200934100.

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42

Moslehyani, A., M. Mobaraki, A. F. Ismail, et al. "PVDF MEMBRANE FOR OIL-IN-WATER SEPARATION VIA CROSS-FLOW ULTRAFILTRATION PROCESS." Jurnal Teknologi 78, no. 1 (2015). http://dx.doi.org/10.11113/jt.v78.4469.

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The objective of this study is to investigate the potential of ultrafiltration polyvinylidene fluoride (PVDF)-titanium dioxide (TiO2) membrane for oil-in-water separator. PVDF polymeric matrix membrane is excellent in term of chemical and thermal stabilities, which make it very promising to be used as a membrane matrix for water separation. However, poor hydrophilic property of the PVDF has led to the severe fouling during operation. Thus, current work was performed to investigate the effect of incorporation of two additives i.e. polyvinylpyrrolidone (PVP) and polyethylene glycol (PEG) in PVDF
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