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Journal articles on the topic 'Formic acid synthesis'

Author: Grafiati

Published: 4 June 2021

Last updated: 7 February 2022

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1

Liu, Ying, Yingxi Geng, Renyong Zhao, Huabao Zheng, and Wenqiao Yuan. "Effects of Formic and Levulinic Acids on Butyric Acid Synthesis by Clostridium tyrobutyricum in Xylose Media." Transactions of the ASABE 62, no. 6 (2019): 1803–9. http://dx.doi.org/10.13031/trans.13669.

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Abstract. Weak acids released during hydrolysis of lignocellulosic biomass are potential inhibitors of microorganism fermentation. In this study, the effects of formic and levulinic acids on butyric acid synthesis by were investigated. With the addition of 1.2 to 4.8 g L-1 of formic acid, increased lag time, decreased cell density, and lower butyric acid productivity were observed. Up to 15% and 56% reduction in peak cell density and butyric acid productivity, respectively, were caused by formic acid addition, whereas there was no significant difference in butyric acid yield between the contro

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2

Höckendorf, Robert F., Chi-Kit Siu, Christian van der Linde, O. Petru Balaj, and Martin K. Beyer. "Selective Formic Acid Synthesis from Nanoscale Electrochemistry." Angewandte Chemie 122, no. 44 (2010): 8433–35. http://dx.doi.org/10.1002/ange.201004134.

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3

Höckendorf, Robert F., Chi-Kit Siu, Christian van der Linde, O. Petru Balaj, and Martin K. Beyer. "Selective Formic Acid Synthesis from Nanoscale Electrochemistry." Angewandte Chemie International Edition 49, no. 44 (2010): 8257–59. http://dx.doi.org/10.1002/anie.201004134.

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4

Wang, Ligeng, Jun Hu, Hualong Zhang, Qin Yu, and Chun Feng. "Green Synthesis of Haloformates from Olefins Using Formic Acid as Reactant, Protonic Acid, and Solvent." Synlett 29, no. 12 (2018): 1611–16. http://dx.doi.org/10.1055/s-0037-1610028.

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Bromoformates and iodoformates are successfully synthesized in high yields with regioselectivity and stereoselectivity by using ZnAl-BrO3 – layered double hydroxides (LDHs) and KX (X = Br, I) in the presence of formic acid (HCOOH). The protocol exploits the versatile function of formic acid as solvent, nucleophilic reagent, and acidic medium simultaneously, simplifying the reaction and separation of the products.

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5

Jiang, Kun, Han-Xuan Zhang, Shouzhong Zou, and Wen-Bin Cai. "Electrocatalysis of formic acid on palladium and platinum surfaces: from fundamental mechanisms to fuel cell applications." Phys. Chem. Chem. Phys. 16, no. 38 (2014): 20360–76. http://dx.doi.org/10.1039/c4cp03151b.

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A brief overview is presented on recent progress in mechanistic studies of formic acid oxidation, synthesis of novel Pd- and Pt-based nanocatalysts and their practical applications in direct formic acid fuel cells.

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6

Lin, Hongyan, Ziling Zhou, Xiaopeng Ma, et al. "One pot synthesis of aryl nitriles from aromatic aldehydes in a water environment." RSC Advances 11, no. 39 (2021): 24232–37. http://dx.doi.org/10.1039/d1ra03559b.

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In a formic acid–H<sub>2</sub>O solution (60% : 40%), most aromatic aldehydes react efficiently with hydroxylamine hydrochloride and sodium acetate to form nitriles, where formic acid acts as both catalyst and solvent.

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7

Perich, JW, PF Alewood, and RB Johns. "Synthesis of Casein-Related Peptides and Phosphopeptides. IX. A Modified Method for the Synthesis of Ser(P) Peptides by Using Ppoc-Ser(PO3bzl2)-OH." Australian Journal of Chemistry 44, no. 3 (1991): 377. http://dx.doi.org/10.1071/ch9910377.

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Benzyl phosphate groups were found to be sensitive to acid conditions, and a stability study with dibenzyl isobutyl phosphate under various acid conditions is described. While extensive acidolytic debenzylation of the dibenzyl phosphorotriester occurred on treatment with either 4 M hydrogen chloride/ dioxan or 50% trifluoroacetic acid/dichloromethane, only minor benzyl loss occurred with the use of formic acid or 1 M hydrogen chloride/acetic acid. Minimization of benzyl phosphate loss during the synthesis of a Ser(PO3Bzl2)-containing tripeptide was effected by the use of 98% formic acid (or 1

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8

Takale, Nilesh, Neelakandan Kaliyaperumal, Gopalakrishnan Mannathusamy, and Rajarajan Govindasamy. "A Headspace Gas Chromatographic Method for Determination of Formic Acid Content in Isosulfan Blue and Various Drug Substances." Oriental Journal of Chemistry 37, no. 02 (2021): 321–29. http://dx.doi.org/10.13005/ojc/370209.

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The Pharmaceutical industry uses formic acid in the manufacturing of various drug substances or API. At the time of manufacturing of API formic acid is use as an oxidizing agent. Formic acid is the simplest carboxylic acid. It also called methanoic acid.Formic acid present in API at high concentrations is very hazardous but in low concentrations is very beneficial. The developed and validated method was short, precise, cost effective and reproducible with FID detector and easy to use. The method is a selective and superficial analytical method for determination of formic acid in different drug

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9

Takale, Nilesh, Neelakandan Kaliyaperumal, Gopalakrishnan Mannathusamy, and Rajarajan Govindasamy. "A Headspace Gas Chromatographic Method for Determination of Formic acid Content in Isosulfan Blue and in Various Drugs." Oriental Journal Of Chemistry 37, no. 2 (2021): 321–29. http://dx.doi.org/10.13005//ojc/370209.

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The Pharmaceutical industry uses formic acid in the manufacturing of various drug substances or API. At the time of manufacturing of API formic acid is use as an oxidizing agent. Formic acid is the simplest carboxylic acid. It also called methanoic acid.Formic acid present in API at high concentrations is very hazardous but in low concentrations is very beneficial. The developed and validated method was short, precise, cost effective and reproducible with FID detector and easy to use. The method is a selective and superficial analytical method for determination of formic acid in different drug

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10

Ahmed, Ajaz, Nazar Hussain, Monika Bhardwaj, Anuj Kumar Chhalodia, Amit Kumar, and Debaraj Mukherjee. "Palladium catalysed carbonylation of 2-iodoglycals for the synthesis of C-2 carboxylic acids and aldehydes taking formic acid as a carbonyl source." RSC Advances 9, no. 39 (2019): 22227–31. http://dx.doi.org/10.1039/c9ra03626a.

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Pd catalyzed carbonylative reaction of 2-iodo-glycals has been developed taking formic acid as a carbonyl source for the synthesis of 2-carboxylic acids of sugars by the hydroxycarbonylation strategy.

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11

Perich, JW, and RB Johns. "Synthesis of Casein-Related Peptides and Phosphopeptides. X. A Modified Method for the Synthesis of Ser(P)-Containing Peptides Through 4-Bromobenzyl Phosphate Protection." Australian Journal of Chemistry 44, no. 3 (1991): 389. http://dx.doi.org/10.1071/ch9910389.

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The three 4-halobenzyl phosphoramidite reagents di (4-fluorobenzyl) N,N- diisopropylphosphor-amidite, di (4-chlorobenzyl) N,N- diisopropylphosphoramidite and di (4-bromobenzyl) N,N-diethylphosphoramidite were prepared and used for the efficient phosphite-triester phosphorylation of isobutyl alcohol. While all three 4-halobenzyl groups were cleaved at similar rates from the 4-halobenzyl phosphorotriesters by 4 M HCl/dioxan or 50% CF3CO2H/CH2Cl2, the 4-bromobenzyl group had greater stability than either the 4-fluorobenzyl or 4-chlorobenzyl groups in formic acid or 1 M HCl /acetic acid solutions.

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12

Otamiri, J. C., and A. Andersson. "Preparation of YBa2Cu3O6+x by a formic acid method." Journal of Materials Research 5, no. 7 (1990): 1388–91. http://dx.doi.org/10.1557/jmr.1990.1388.

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Synthesis of YBa2Cu3O6+x from formic acid solutions of stoichiometric amounts of the initial materials has been investigated in the temperature range 750–950°C. The reaction is strongly influenced by the concentration of formic acid. Dilute solutions favor synthesis of purer samples under moderate conditions of temperature and sintering time. At lower temperature the same effect can be achieved if sintering time is longer, while at higher temperature, multiple grinding and heating at very short intervals are necessary to avoid formation of Y2BaCuO5. The observed effect of HCOOH concentration i

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13

Suo, Yange, and I.-Ming Hsing. "Synthesis of bimetallic PdAu nanoparticles for formic acid oxidation." Electrochimica Acta 56, no. 5 (2011): 2174–83. http://dx.doi.org/10.1016/j.electacta.2010.12.037.

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14

Shin, Minguk, Jeongbae Seo, Yesol Baek, Taek Lee, Min Jang, and Chulhwan Park. "Novel and Efficient Synthesis of Phenethyl Formate via Enzymatic Esterification of Formic Acid." Biomolecules 10, no. 1 (2020): 70. http://dx.doi.org/10.3390/biom10010070.

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Current methods for the production of esters, including chemical synthesis and extraction from natural sources, are hindered by low yields and environmental pollution. The enzymatic synthesis of these compounds could help overcome these problems. In this study, phenethyl formate, a commercially valuable formate ester, was synthesized using commercial immobilized lipases. The effects of specific enzymes, enzyme concentration, formic acid:phenethyl alcohol molar ratio, temperature, and solvent were studied in order to optimize the synthesis conditions, which were identified as 15 g/L of Novozym

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15

Zeng, Xu, Fang Ming Jin, Han Song Yao, and Min Cheng. "Study of Catalytic Reduction of Formic Acid to Methanol under Mild Hydrothermal Conditions." Advanced Materials Research 347-353 (October 2011): 3677–80. http://dx.doi.org/10.4028/www.scientific.net/amr.347-353.3677.

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In this paper, catalytic reduction of formic acid to methanol with different catalyst under mild hydrothermal conditions was investigated. Formic acid was successfully converted into methanol using Al as reductant and Cu as a catalyst under mild hydrothermal conditions. The selectivity of conversion from formic acid to methanol was found to be as high as 30% at 300 °C for 9 h with formic acid 60 g∙L-1, filling rate 35% and 4.35 mmol Al and 12 mmol Cu. The addition of Al2O3was favorable for the synthesis of methanol. Comparing the yield of methanol with the same reaction condition for 3 h witho

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16

Maleki, Behrooz, Davood Azarifar, Khodaverdian Moghaddam, Fatemeh Hojati, Mostafa Gholizadeh, and Hafezeh Salehabadi. "Synthesis and characterization of a series of 1,3,5-trisubstituted-2-pyrazolines derivatives using methanoic acid under thermal condition." Journal of the Serbian Chemical Society 74, no. 12 (2009): 1371–76. http://dx.doi.org/10.2298/jsc0912371m.

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An efficient and practical synthesis of 1,3,5-trisubstituted 2-pyrazoline structures was achieved through cyclization of phenylhydrazine with ?,? -unsaturated ketones (chalcones) using methanoic acid (formic acid) as catalyst under thermal condition.

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17

Islam, Md Tariqul, Jose A. Rosales, Ricardo Saenz-Arana, Shahrouz J. Ghadimi, and Juan C. Noveron. "Rapid synthesis of ultrasmall platinum nanoparticles supported on macroporous cellulose fibers for catalysis." Nanoscale Advances 1, no. 8 (2019): 2953–64. http://dx.doi.org/10.1039/c9na00124g.

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18

Karthikeyan, Iyyanar, Dhanarajan Arunprasath, and Govindasamy Sekar. "An efficient synthesis of pyrido[1,2-a]indoles through aza-Nazarov type cyclization." Chemical Communications 51, no. 9 (2015): 1701–4. http://dx.doi.org/10.1039/c4cc08783f.

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Transition metal free Brønsted acid mediated synthesis of pyrido[1,2-a]indole scaffolds has been developed through aza-Nazarov type cyclization of readily available diaryl(2-pyridyl)methanol using formic acid for the synthesis of biologically and medicinally important pyrido[1,2-a]indole, indolo[1,2-a]quinoline and pyrimido[1,2-a]indole derivatives.

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19

Sönmez Çelebi, Mutlu, and Ayşe Nur Yılmaz. "PVF-PPy Composite as Support Material for Facile Synthesis of Pt@PVF-PPy Catalyst and Its Electrocatalytic Activity Towards Formic Acid Oxidation." Journal of New Materials for Electrochemical Systems 21, no. 3 (2018): 157–62. http://dx.doi.org/10.14447/jnmes.v21i3.502.

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Preparation and characterization of a Pt-based catalyst supported on poly(vinylferrocenium)-poly(pyyrole) conducting polymer composite (Pt@PVF-PPy) was described for electrocatalytic oxidation of formic acid. Pt precursor was aqueous solution of K2PtCl4 and electrochemical and chemical reduction methods were compared for optimum catalyst performance. Other experimental parameters such as polymer film thickness and Pt loading were also optimized with respect to the formic acid oxidation peak current values. Scanning electron microscopy, cyclic voltammetry and chronoamperometry methods were used

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20

Popovic, Ksenija, and Jelena Lovic. "Formic acid oxidation at platinum-bismuth catalysts." Journal of the Serbian Chemical Society 80, no. 10 (2015): 1217–49. http://dx.doi.org/10.2298/jsc150318044p.

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The field of heterogeneous catalysis, specifically catalysis on bimetallic surfaces, has seen many advances over the past few decades. Bimetallic catalysts, which often show electronic and chemical properties that are distinct from those of their parent metals, offer the opportunity to obtain new catalysts with enhanced selectivity, activity, and stability. The oxidation of formic acid is of permanent interest as a model reaction for the mechanistic understanding of the electrooxidation of small organic molecules and because of its technical relevance for fuel cell applications. Platinum is on

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21

Kang, F., Y. Leng, and T. Y. Zhang. "Electrochemical synthesis and characterization of formic acid-graphite intercalation compound." Carbon 35, no. 8 (1997): 1089–96. http://dx.doi.org/10.1016/s0008-6223(97)00065-1.

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22

Edwards, James F., and G. L. Schrader. "Methanol, formaldehyde, and formic acid adsorption on methanol synthesis catalysts." Journal of Physical Chemistry 89, no. 5 (1985): 782–88. http://dx.doi.org/10.1021/j100251a015.

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23

Wu, Dengfeng, Changqing Dai, Shaojie Li, and Daojian Cheng. "Shape-controlled Synthesis of PdCu Nanocrystals for Formic Acid Oxidation." Chemistry Letters 44, no. 8 (2015): 1101–3. http://dx.doi.org/10.1246/cl.150386.

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24

Dan, Ananya, and P. K. Sengupta. "Synthesis and characterization of polyaniline prepared in formic acid medium." Journal of Applied Polymer Science 91, no. 2 (2003): 991–99. http://dx.doi.org/10.1002/app.13204.

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25

Barlocco, Ilaria, Sofia Capelli, Elisa Zanella, et al. "Synthesis of palladium-rhodium bimetallic nanoparticles for formic acid dehydrogenation." Journal of Energy Chemistry 52 (January 2021): 301–9. http://dx.doi.org/10.1016/j.jechem.2020.04.031.

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26

Wu, Fengxia, Jianping Lai, Ling Zhang, et al. "Hierarchical concave layered triangular PtCu alloy nanostructures: rational integration of dendritic nanostructures for efficient formic acid electrooxidation." Nanoscale 10, no. 19 (2018): 9369–75. http://dx.doi.org/10.1039/c8nr00385h.

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27

Sadeghi, Samira, Meghdad Karimi, Iman Radfar, Reza Ghahremani Gavinehroudi, Dariush Saberi, and Akbar Heydari. "Efficient strategy for interchangeable roles in a green and sustainable redox catalytic system: IL/PdII-decorated SBA-15 as a mesoporous nanocatalyst." New Journal of Chemistry 45, no. 15 (2021): 6682–92. http://dx.doi.org/10.1039/d0nj05459c.

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Green synthesis of catalyst for the aerobic oxidation of alcohols using air as a green oxidant, and efficient and straightforward synthesis method for amine formation using formic acid as a green reductant.

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28

Mardini, Nour, and Yusuf Bicer. "Direct synthesis of formic acid as hydrogen carrier from CO2 for cleaner power generation through direct formic acid fuel cell." International Journal of Hydrogen Energy 46, no. 24 (2021): 13050–60. http://dx.doi.org/10.1016/j.ijhydene.2021.01.124.

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29

Gromov, Nikolay V., Tatiana B. Medvedeva, Yulia A. Rodikova, et al. "One-pot synthesis of formic acid via hydrolysis–oxidation of potato starch in the presence of cesium salts of heteropoly acid catalysts." RSC Advances 10, no. 48 (2020): 28856–64. http://dx.doi.org/10.1039/d0ra05501h.

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30

Li, Si-jia, Yun Ping, Jun-Min Yan, Hong-Li Wang, Ming Wu, and Qing Jiang. "Facile synthesis of AgAuPd/graphene with high performance for hydrogen generation from formic acid." Journal of Materials Chemistry A 3, no. 28 (2015): 14535–38. http://dx.doi.org/10.1039/c5ta03111g.

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31

Enteshari, Maryam, and Sergio I. Martínez-Monteagudo. "One-Pot Synthesis of Lactose Derivatives from Whey Permeate." Foods 9, no. 6 (2020): 784. http://dx.doi.org/10.3390/foods9060784.

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The simultaneous production of lactulose (LAU), lactobionic acid (LBA), and organic acids from sweet and acid whey permeate (SWP and AWP) via catalytic synthesis (5% Ru/C) was studied in a continuous stirred-tank reactor. At selected conditions (60 °C, 60 bar, and 600 rpm), a maximum conversion of lactose (37 and 34%) was obtained after 90 min for SWP and AWP, respectively. The highest yield calculated with respect to the initial concentration of lactose for LAU was 22.98 ± 0.81 and 15.29 ± 0.81% after only 30 min for SWP, and AWP, respectively. For LBA, a maximum yield was found in SWP (5.23%

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32

Peng, Guowen, Lang Xu, Vassiliki-Alexandra Glezakou, and Manos Mavrikakis. "Mechanism of methanol synthesis on Ni(110)." Catalysis Science & Technology 11, no. 9 (2021): 3279–94. http://dx.doi.org/10.1039/d1cy00107h.

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Planewave density functional theory (DFT-PW91) calculations are employed to study the methanol synthesis through CO<sub>2</sub> and CO hydrogenation, as well as the two side reactions: the water gas shift (WGS) reaction and the formic acid formation, on Ni(110).

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33

Blohm, Sascha, Thomas Heinze, and Haisong Qi. "Starch Formates: Synthesis and Modification." Molecules 26, no. 16 (2021): 4882. http://dx.doi.org/10.3390/molecules26164882.

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Starch can be efficiently converted into the corresponding formates homogeneously using N-formyl imidazole obtained by the reaction of 1,1′-carbonyldiimidazole and formic acid in dimethyl sulfoxide as a solvent. Starch formates are soluble in polar aprotic solvents, not susceptible against hydrolysis, and not meltable. Thermoplastics could be generated by conversion of starch formates with long-chain fatty acids exemplified by the conversion with lauroyl chloride in N,N-dimethylacetamide, leading to mixed starch laurate formates. The mixed esters show melting temperatures mainly dependent on t

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34

Yang, Qian, Lijie Shi, Beibei Yu, et al. "Correction: Facile synthesis of ultrathin Pt–Pd nanosheets for enhanced formic acid oxidation and oxygen reduction reaction." Journal of Materials Chemistry A 8, no. 22 (2020): 11460. http://dx.doi.org/10.1039/d0ta90113j.

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Correction for ‘Facile synthesis of ultrathin Pt–Pd nanosheets for enhanced formic acid oxidation and oxygen reduction reaction’ by Qian Yang et al., J. Mater. Chem. A, 2019, 7, 18846–18851, DOI: 10.1039/C9TA03945G.

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35

Ye, Wanyue, Wei Pei, Si Zhou, et al. "Controlling the synthesis of uniform electron-deficient Pd clusters for superior hydrogen production from formic acid." Journal of Materials Chemistry A 7, no. 17 (2019): 10363–71. http://dx.doi.org/10.1039/c9ta02035g.

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36

Embrechts, Heidemarie, Martin Kriesten, Matthias Ermer, Wolfgang Peukert, Martin Hartmann, and Monica Distaso. "In situ Raman and FTIR spectroscopic study on the formation of the isomers MIL-68(Al) and MIL-53(Al)." RSC Advances 10, no. 13 (2020): 7336–48. http://dx.doi.org/10.1039/c9ra09968a.

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37

Sohilait, Hanoch J., Hardjono Sastrohamidjojo, Sabirin Matsjeh, and J. Stuart Grossert. "SYNTHESIS of 3.4-METHYLENEDIOXYPHENYL-2-PROPANONE from SAFROLE." Indonesian Journal of Chemistry 1, no. 3 (2010): 145–48. http://dx.doi.org/10.22146/ijc.21941.

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The Synthesis of 3.4-methylenedioxyphenyl-2-propanone from safrole has been achieved through conversion of allyl group to secondary alcohol, followed by oxidation with pyridinium chlorochromate(PCC). The secondary alcohol has been achieved by two methods. The first method was formic acid adition reaction, followed by hydrolysis in aqueous ethanolic solution of potassium hydroxide. The second method was the oxymercuration-demercuration reaction of safrole. The addition reaction of safrole with formic acid yield safrylformate (34,70%). The hydrolysis of safrylformate with 3M KOH produced safryla

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38

Lee, Jin-Yeon, Da-Hee Kwak, Young-Woo Lee, Seul Lee, and Kyung-Won Park. "Synthesis of cubic PtPd alloy nanoparticles as anode electrocatalysts for methanol and formic acid oxidation reactions." Physical Chemistry Chemical Physics 17, no. 14 (2015): 8642–48. http://dx.doi.org/10.1039/c5cp00892a.

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39

Shi, Lei, Dong Sun, Yuxin Wang, et al. "Formic acid-assisted synthesis of highly efficient Cu/ZnO catalysts: effect of HCOOH/Cu molar ratios." Catalysis Science & Technology 6, no. 13 (2016): 4777–85. http://dx.doi.org/10.1039/c5cy02010g.

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40

Yadav, Dolly, Abhishek Kumar, Jae Young Kim, No-Joong Park, and Jin-Ook Baeg. "Interfacially synthesized 2D COF thin film photocatalyst: efficient photocatalyst for solar formic acid production from CO2 and fine chemical synthesis." Journal of Materials Chemistry A 9, no. 15 (2021): 9573–80. http://dx.doi.org/10.1039/d1ta00802a.

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Easy fabrication of multi-functional, free standing, centimeter sized, thin film photocatalyst for sustainable solar fine chemical synthesis and photoreduction of CO<sub>2</sub> to formic acid under visible light.

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41

Haidukevich, V. A., S. K. Petkevich, E. G. Karankevich, et al. "Synthesis of acylic derivatives of prolylleucylglycinamide." Proceedings of the National Academy of Sciences of Belarus, Chemical Series 55, no. 4 (2019): 429–35. http://dx.doi.org/10.29235/1561-8331-2019-55-4-429-435.

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Tert-butyloxycarbonylprolylleucylglycinamide is obtained both by the interaction of tert-butyloxycarbonylprol ylleucylglycine ethyl ester with a methanolic ammonia solution and by the reaction of glycine amide with a mixed anhydride which was synthesized from tert-butyloxycarbonylprolylleucine and isobutylchloroformate. The removal of the tert-butyloxycarbonyl group by the action of formic acid or a dioxane solution of hydrogen chloride and treatment of the resulting salts with the corresponding base yielded a prolylleucylglycinamide, by the interaction of which with acetic, benzoic or 5-pheny

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42

Gautam, Prashant, та Vivek Srivastava. "Active γ –Alumina -Supported Ru Nanoparticles for CO2 Hydrogenation Reaction". Letters in Organic Chemistry 17, № 8 (2020): 603–12. http://dx.doi.org/10.2174/1570178617666191107112429.

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A series of alumina supported Ru nanoparticles (Ru γ -Al2O3-x (x=2-10 Ru wt%) was synthesized using the ethylene glycol reduction method. XRD, TEM, EDX, H2-chemisorption, XPS and H2-TPD analytical techniques were used to understand the physiochemical nature of alumina supported Ru nanoparticles. All the well-characterized Ru#Al2O3-x (x=2-10 Ru wt%) catalysts were used for high-pressure CO2 hydrogenation to formic acid synthesis. A clear correlation was recorded between the physiochemical properties of developed catalysts and the molar quantity of formic acid. Among all the developed catalysts,

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43

Zhang, Lei, Shengnan Yu, Jijie Zhang, and Jinlong Gong. "Porous single-crystalline AuPt@Pt bimetallic nanocrystals with high mass electrocatalytic activities." Chemical Science 7, no. 6 (2016): 3500–3505. http://dx.doi.org/10.1039/c6sc00083e.

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44

Li, Hao-Peng, Han-Jun Ai, Xinxin Qi, Jin-Bao Peng, and Xiao-Feng Wu. "Palladium-catalyzed carbonylative synthesis of benzofuran-2(3H)-ones from 2-hydroxybenzyl alcohols using formic acid as the CO source." Organic & Biomolecular Chemistry 15, no. 6 (2017): 1343–45. http://dx.doi.org/10.1039/c6ob02782b.

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A palladium-catalyzed carbonylative intramolecular synthesis of benzofuran-2(3H)-ones from 2-hydroxybenzyl alcohols has been developed with formic acid as the CO source, various desired products were obtained in moderate to good yields.

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45

Singh, Amit Kumar, Saptak Rarotra, Viswanath Pasumarthi, Tapas Kumar Mandal, and Dipankar Bandyopadhyay. "Formic acid powered reusable autonomous ferrobots for efficient hydrogen generation under ambient conditions." Journal of Materials Chemistry A 6, no. 19 (2018): 9209–19. http://dx.doi.org/10.1039/c8ta02205d.

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In this study, we report the synthesis of ferrobots, which utilize aqueous formic acid as fuel for pH sensing and efficient H<sub>2</sub> production at room temperature to power a fan integrated with a PEM fuel cell.

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Bao, Shixiong, Xuan Yang, Ming Luo, et al. "Shape-controlled synthesis of CO-free Pd nanocrystals with the use of formic acid as a reducing agent." Chemical Communications 52, no. 85 (2016): 12594–97. http://dx.doi.org/10.1039/c6cc07055h.

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This paper reports the use of formic acid as a reducing agent for the shape-controlled synthesis of Pd nanocrystals with no chemisorption of CO on the surface, as confirmed by attenuated total reflection Fourier transform infrared (ATR-FT-IR) spectroscopy.

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Lewis, David E., and Glen C. Gullickson. "Synthesis ofN-Benzhydrylamides from Nitriles by Ritter Reactions in Formic Acid." Synthesis, no. 5 (2003): 0681–84. http://dx.doi.org/10.1055/s-2003-38069.

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Liu, Xinyue, Changqing Dai, Dengfeng Wu, Adrian Fisher, Zhiping Liu, and Daojian Cheng. "Facile Synthesis of PdAgCo Trimetallic Nanoparticles for Formic Acid Electrochemical Oxidation." Chemistry Letters 45, no. 7 (2016): 732–34. http://dx.doi.org/10.1246/cl.160243.

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Wang, Qinchao, Yiqian Wang, Peizhi Guo, et al. "Formic Acid-Assisted Synthesis of Palladium Nanocrystals and Their Electrocatalytic Properties." Langmuir 30, no. 1 (2014): 440–46. http://dx.doi.org/10.1021/la404268j.

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Mazumder, Vismadeb, and Shouheng Sun. "Oleylamine-Mediated Synthesis of Pd Nanoparticles for Catalytic Formic Acid Oxidation." Journal of the American Chemical Society 131, no. 13 (2009): 4588–89. http://dx.doi.org/10.1021/ja9004915.

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