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Relevant bibliographies by topics / Four-membered ring compounds

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Academic literature on the topic 'Four-membered ring compounds'

Author: Grafiati

Published: 4 June 2021

Last updated: 1 February 2022

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Journal articles on the topic "Four-membered ring compounds"

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Kotha, Sambasivarao, Vital Seema, Deepak Deodhar, and Mobin Shaikh. "Crystal structures of 3,6-diallyltetracyclo[6.3.0.04,11.05,9]undeca-2,7-dione and 1,7-diallylpentacyclo[5.4.0.02,6. 03,10.05,9]undecane-8,11-dione: allylated caged compounds." Acta Crystallographica Section E Structure Reports Online 70, no. 11 (2014): 410–14. http://dx.doi.org/10.1107/s1600536814023149.

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The title compounds, C17H20O2(1) and C17H18O2(2), are allylated caged compounds. In (1), the carbon atoms bearing the allyl groups are far apart [2.9417 (17) Å], hence the expected ring-closing metathesis (RCM) protocol failed to give a ring-closing product. When these carbon atoms are connected by a C—C bond as in (2), the distance between them is much smaller [1.611 (3) Å] and consequently the RCM process was successful. The caged carbon skeleton of (1) can be described as a fusion of four five-membered rings and one six-membered ring. All four five-membered rings exhibit envelope conformations. The structure of compound (2) consists of four five-membered rings, of which two are cyclopentanone rings bonded at the 2, 4 and 5 positions and linked at the 3-carbons by a methylene bridge. It also consists of one four-membered and two six-membered rings. All four five-membered rings adopt envelope conformations. In the crystal of (1), molecules are linkedviaC—H...O hydrogen bonds, forming sheets lying parallel to (010). In the crystal of (2), molecules are linkedviaC—H...O hydrogen bonds forming chains along [100].

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Block, Eric, Evgeny V. Dikarev, Jin Jin, Bo Li, Marina A. Petrukhina, and Shao-Zhong Zhang. "Synthesis, structure, and chemistry of selenium-containing four-membered rings." Pure and Applied Chemistry 77, no. 12 (2005): 2029–32. http://dx.doi.org/10.1351/pac200577122029.

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Recent chemistry of four-membered ring selenium compounds is reviewed followed by a summary of work in our laboratories in this area. 2-Thia-6-selenaspiro[3.3]heptane has been synthesized for the first time. X-ray structures for the latter compound as well as for 2,6-dithiaspiro[3.3]heptane and 2,6-diselenaspiro[3.3]heptane have been determined. These compounds are useful as "rigid-rod" ligands for coordination to transition-metal complexes.

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Klingebiel, U., D. Stalke, and S. Vollbrecht. "Lithiumverbindungen von Adamantyl-, Silyl- und Arylaminofluorsilanen/Lithium Compounds of Adamantyl-, Silyl- and Arylaminofluorosilanes." Zeitschrift für Naturforschung B 47, no. 1 (1992): 27–30. http://dx.doi.org/10.1515/znb-1992-0108.

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Dimeric lithium-adamantylimino-di-tert-butylfluorosilane, [(Me3C)2 SiF Li N Ad]2, adds one molecule of THF per dimer when crystallized from THF. A bicyclic compound is obtained with four- [F2Li(THF)N] and two-coordinated [NLiN] lithium. Lithiated di-tert-butyl-[{tert-butyldiphenylsilyl)]aminofluorosilane and di-ter-butyl-4-fluoroanilinofluorosilane both add two molecules of THF with formation of (SiFLi(THF)2N)-four-membered rings when crystallized from THF. THF can be replaced by TMEDA with retention of the (SiFLiN )- four-membered ring. The crystal structure of (Me3C)-,SiFLi(TMEDA)NC6H4F is reported.

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Liu, Tao, Guo-Dong Liu, and Zhang-Yu Yu. "Ab initio study of hydrogen bond complexes of ring compounds containing the H2N-C=Y moiety with water." Open Chemistry 8, no. 5 (2010): 1117–26. http://dx.doi.org/10.2478/s11532-010-0088-x.

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AbstractAb initio calculations, including natural charge population and natural resonance theory analyses, have been carried out to study the two-way effects between hydrogen bonds (H-bonds) and the intramolecular resonance effect by using the H-bonded complexes of ring compounds containing the H2N-C=Y moiety (C=Y bond is contained in the six-membered or five-membered rings) with water as models. The amino groups in the four monomers of ring compounds (FAYs, Y represents the heavy atoms in the substituent groups, =CH, =N, =SiH, and =P, respectively) can all serve as H-bond donors (HD) and H-bond acceptors (HA) to form stable H-bonded complexes with water. The HD H-bond and resonance effect enhance each other (positive two-way effects) whereas the HA H-bond and resonance effect weaken each other (negative two-way effects). The resonance effect in FAY(1) (C=Y bond is contained in the six-membered rings) is weaker than that in formamide, and those in FAY(2) and FAY(3) (C=Y bonds are contained in the five-membered rings). The two-way effects between H-bond and resonance effect exist in the H-bonded complexes of ring compounds containing the H2N-C=Y moiety with water.

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Roesky, Herbert W., Ulrich Seseke, Mathias Noltemeyer, and George M. Sheldrick. "Darstellungen und Strukturen viergliedriger Metall-Stickstoff-Ringe." Zeitschrift für Naturforschung B 43, no. 9 (1988): 1130–36. http://dx.doi.org/10.1515/znb-1988-0908.

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Abstract Ph3P=NSiMe3 (1) reacts with InCl3 , SnCl2 and FeCl3 to yield (Ph3P=N)2(InCl2)2 • 2DMF (2a), (Ph3P=N)2Sn2Cl4 • 2 CH3CN (3a) and (Ph3P=N)2 (FeCl2)2 (4). The X-ray single crystal structures of 2a, 3a and 4 are reported. The compounds form four-membered rings consisting of alternating metal and nitrogen atoms. 2a and 4 are symmetrical, but 3a has both a Sn(II)Cl and a Sn(IV)Cl3 group in the four-membered ring.

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Tan, Xiaojun, and Xiuhui Lu. "Ab initio study of the mechanism of formation of a spiro-Sn-heterocyclic ring compound by the cycloaddition reaction of H2C=Sn: and ethylene." Journal of the Serbian Chemical Society 84, no. 3 (2019): 293–301. http://dx.doi.org/10.2298/jsc180603072t.

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X2C=Sn: (X = H, Me, F, Cl, Br, Ph, Ar?) are new species of chemistry. The cycloaddition reactions of X2C=Sn: is a new study field of stannylene chemistry. The mechanism of cycloaddition reaction of singlet H2C=Sn: with ethylene is studied for the first time using the MP2/GENECP (C, H in 6-311++G**; Sn in LanL2dz) method in this paper. From the potential energy profile, it could be predicted that the reaction has one dominant reaction channel. The reaction rule presented is that the 5p unoccupied orbital of tin in H2C=Sn: sidewise overlaps with the bonding ? orbital of ethylene resulting in the formation of an intermediate. The instability of the intermediate makes it isomerise to a four-membered ring stannylene. As the 5p unoccupied orbital of the Sn atom in the four-membered ring stannylene and the ? orbital of ethylene form a ??p donor?acceptor bond, the four-membered ring stannylene further combines with ethylene to form another intermediate, and this intermediate further isomerises to a spiro-Sn-heterocyclic ring compound. The Sn in the spiro-Sn-heterocyclic ring compound is combined with adjacent atoms by sp3 hybridization. The results of this study reveal the mechanism of cycloaddition reaction of X2C=Sn: with symmetric ?-bond compounds.

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NizamMohideen, M., S. Syed Abuthahir, V. Viswanathan, D. Velmurugan, and M. Karthik Ananth. "The crystal structures and Hirshfeld surface analyses of four 3,5-diacetyl-2-methyl-2,3-dihydro-1,3,4-thiadiazol-2-yl derivatives." Acta Crystallographica Section E Crystallographic Communications 75, no. 10 (2019): 1436–44. http://dx.doi.org/10.1107/s2056989019011915.

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The title compounds, 4-(5-acetamido-3-acetyl-2-methyl-2,3-dihydro-1,3,4-thiadiazol-2-yl)phenyl benzoate, C20H19N3O4S (I), 4-(5-acetamido-3-acetyl-2-methyl-2,3-dihydro-1,3,4-thiadiazol-2-yl)phenyl isobutyrate 0.25-hydrate, C17H21N3O4S·0.25H2O (II), 4-(5-acetamido-3-acetyl-2-methyl-2,3-dihydro-1,3,4-thiadiazol-2-yl)phenyl propionate, C16H19N3O4S (III) and 4-(5-acetamido-3-acetyl-2-methyl-2,3-dihydro-1,3,4-thiadiazol-2-yl)phenyl cinnamate chloroform hemisolvate, C22H21N3O4S·0.5CHCl3 (IV), all crystallize with two independent molecules (A and B) in the asymmetric unit in the triclinic P\overline{1} space group. Compound II crystallizes as a quaterhydrate, while compound IV crystallizes as a chloroform hemisolvate. In compounds I, II, III (molecules A and B) and IV (molecule A) the five-membered thiadiazole ring adopts an envelope conformation, with the tetrasubstituted C atom as the flap. In molecule B of IV this ring is flat (r.m.s. deviation 0.044 Å). The central benzene ring is in general almost normal to the mean plane of the thiadiazole ring in each molecule, with dihedral angles ranging from 75.8 (1) to 85.5 (2)°. In the crystals of all four compounds, the A and B molecules are linked via strong N—H...O hydrogen bonds and generate centrosymmetric four-membered R 4 4(28) ring motifs. There are C—H...O hydrogen bonds present in the crystals of all four compounds, and in I and II there are also C—H...π interactions present. The intermolecular contacts in the crystals of all four compounds were analysed using Hirshfeld surface analysis and two-dimensional fingerprint plots.

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LITTLE, J. H. "ChemInform Abstract: Five-Membered Heterocyclic Compounds with Four Heteroatoms in the Ring." ChemInform 26, no. 4 (2010): no. http://dx.doi.org/10.1002/chin.199504300.

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LITTLE, J. H. "ChemInform Abstract: Five-Membered Heterocyclic Compounds with Four Heteroatoms in the Ring." ChemInform 29, no. 43 (2010): no. http://dx.doi.org/10.1002/chin.199843313.

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Tan, Xiaojun, and Xiuhui Lu. "Theoretical study of the formation of a spiro-Sn-heterocyclic compound by cycloaddition reaction of Me2C=Sn: and ethene." Heterocyclic Communications 24, no. 6 (2018): 311–15. http://dx.doi.org/10.1515/hc-2018-0129.

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AbstractX2C=Sn: compounds (X=H, Me, F, Cl, Br, Ph, Ar) are new species. The cycloaddition reactions of X2C=Sn: are also a new study field of unsaturated stannylene chemistry. The mechanism of cycloaddition reaction between singlet Me2C=Sn: and ethene was investigated for the first time using the MP2/GENECP (C, H in 6-311++G**; Sn in LanL2dz) method. From the potential energy profile, it was predicted that the reaction has one dominant channel in which the 5p unoccupied orbital of Sn: in Me2C=Sn: and theπorbital of ethene form aπ→pdonor-acceptor bond in an intermediate product. Instability of the intermediate product results in its isomerization to a four-membered ring of stannylene. The four-membered stannylene further combines with ethene to form another intermediate product that further isomerizes to a spiro-Sn-heterocyclic ring compound.

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Dissertations / Theses on the topic "Four-membered ring compounds"

1

Namavari, Mohammad 1950. "Thermal Reactions of Four-Membered Rings Containing Silicon or Germanium." Thesis, University of North Texas, 1988. https://digital.library.unt.edu/ark:/67531/metadc330607/.

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The synthesis of E- and Z-1,1,2,3-tetramethylsilacyclobutanes is described. Pyrolysis of either isomer at 398.2 °C provides the same products but in different amounts: propene, E- and Z-2-butene, allylethyldimethylsilane, dimethylpropylsilane, the respective geometric isomers, 1,1,2,3,3-pentamethyl-1,3-disilacyclobutane, 1,1, l-ethyldimethyl-2,2,2-vinyldimethyl-disilane and E- and Z-1,1,2,3,3,4-hexamethyl-1,3-disilacyclobutane. Mechanisms involving di- and trimethylsilenes are described for disilane formation and rate constants of the elementary steps for the fragmentation reactions are reported. Photochemically generated dimethylsilylene in the hydrocarbon solution inserts into the cyclic Ge-C or Si-C bonds of 1,1-dimethylgerma- or silacyclobutane to produce 1-germa-2-sila- or 1,2-disilacyclopentane. The relative reactivities of 1,1-dimethylgerma- and silacyclobutanes toward the dimethylsilylene have been determined. The carbenoid resulting from the cuprous chloride catalyzed decomposition of diazomethane at 25 °C in cyclohexane reacts with 1,1-dimethylgermacyclobutane to give, surprisingly 1,1,5,5-tetramethyl-1,5-digermacyclooctane as the major product. The reactions of the carbenoid with 1,1-dimethylsilacyclobutane are described. The kinetics of gas phase thermal decomposition of 1,1-dimethylgermacyclobutane has been studied over the temperature range, 684 - 751 K at pressures near 14 Torr. The Arrhenius parameters for the formation of ethylene are k_1 (s^-1) = 10^(14.6 ± 0.3) exp (62.7 ± 2.9 kcal mol^-1/RT) and those for the formation of propene and cyclopropane are k_2 (s^-1) = 10^(14.0 ± 0.1 ) exp (60.4 ± 2.8 kcal mol^-1/RT). Static gas phase pyrolyses of 1,1-dimethyl-lsilacyclobutene, DMSCB, in the presence of a variety of alkenes and alkynes at 260 - 365 °C have been studied. Our experimental results suggest that under these conditions the DMSCB ring opens to 1,1-dimethyl-l-silabutadiene, which either recyclizes to DMSCB or reacts with alkenes or alkynes in competing 4 + 2 and 2 + 2 cycloadditions.

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Okumura, Shintaro. "New Ring-opening Reactions of Four-membered Carbo- and Sila-cyclic Compounds and Synthesis of 2-Alkoxy-1、3-dienes from Propargylic Alcohol Derivatives." Kyoto University, 2018. http://hdl.handle.net/2433/232487.

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Ocando, Mavarez Edgar. "Phosphonitriles, nouveaux synthons en chimie heterocyclique." Toulouse 3, 1988. http://www.theses.fr/1988TOU30069.

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Amine, Maria El. "Heterocycles germanies : synthese, reactivite, nouvelles voies d'acces aux especes du germanium a coordinence non usuelle." Toulouse 3, 1987. http://www.theses.fr/1987TOU30202.

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Ce travail concerne l'etude d'heterocycles germanies precurseurs d'especes du germanium tricoordine. La premiere partie est consacree a une mise au point bibliographique concernant les especes a germanium doublement lie. La deuxieme partie concerne l'etude des reactions de thermolyse, pyrolyse et photolyse de thiagermetannes-3,1 photolyse de dithiagermolannes-2,4,1 et pyrolyse de dioxydes-3,3 de thiagermetannes-3,1 qui font intervenir des intermediaires et de nouvelles especes du germanium pi lie, les sulfenes. Cette partie concerne egalement des tentatives de synthese du dimethyl-1,1 oxagermetanne-3,1. La synthese et la decomposition de nouveaux petits cycles tendus, les dioxagermetannes-1,3,2 ainsi que l'etude de la thermolyse de l'octamethylcyclotetragermoxane sont decrites dans la troisieme partie. La mise en evidence par spectroscopie photoelectronique de germanones est rapportee au quatrieme chapitre. Dans le cinquieme chapitre, sont exposees les syntheses, thermolyse et photolyse de diverses structures heterocycliques originales a 6 et 5 chainons du type dithiadigermannes-1,4,2,3 dithia-1,4 trigermolannes et dithia-1,4 tetragermannes qui sont egalement d'excellents precurseurs de germathiones et de germylenes. La derniere partie concerne l'etude des premiers phosphonates germanies cycliques a 4 et 5 chainons. Les reactions d'echange entre les phosphonates et divers chlorures metalles (m::(14)) et sc1::(2) sont decrites

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Calet, Serge. "Chimie organometallique d'heterocycles a trois chainons (carbonylation, desulfuration, couplage)." Paris 6, 1987. http://www.theses.fr/1987PA066292.

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Lazraq, Mohamed. "Derives doublement lies du bore, du phosphore et du germanium : phosphaborenes et germenes." Toulouse 3, 1988. http://www.theses.fr/1988TOU30141.

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De nouvelles methodes de synthese de diphosphadiboretannes-1,3,2,4 sont decrites. Un derive a double liaison bore-phosphore du type rb=par (avec r=tetramethyl-2,2,6,6 piperidyl et ar=tri-t-butyl-2,4,6 phenyl) a ete mis en evidence par piegeage in situ. Le premier derive stable a double liaison germanium-carbone a ete prepare: il s'agit du dimesityl fluoremylidene germane. Sa caracterisation a ete effectuee par diverses methodes physicochimiques et sa reactivite chimique, etudiee

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Poquet-Dhimane, Anne-Lise. "Reactivite photochimique de cetones insaturees : preparation et aromatisation d'aryl et heteroarylcyclohexanediones-1,2, preparation et etude stereochimique d'oxetannes insatures." Reims, 1987. http://www.theses.fr/1987REIMS003.

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Henrot, Serge. "Synthese stereo et enantioselective de beta-hydroxy esters fonctionnalises par voie chimique et par voie microbiologique : application a la preparation de la (-) alpha multistriatine et du r (-) gabob." Paris 6, 1987. http://www.theses.fr/1987PA066428.

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Books on the topic "Four-membered ring compounds"

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Meijere, Armin De, (Ed.), ed. Carbocyclic Three- and Four-membered Ring Compounds. G.Thieme Verlag,Germany, 1996.

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Carbocyclic Three- and Four-membered Ring Compounds. G.Thieme Verlag,Germany, 1997.

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Carbocyclic Three- and Four-membered Ring Compounds. G.Thieme Verlag,Germany, 1996.

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Houben-Weyl. Carbocyclic Three-and-four-membered Ring Compounds: Vols A-F (E17 Series). Thieme Publishing Group, 1997.

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Gmelin Institute for Inorganic Chemistry of the Max Planck Society for the Advancement of Science. P Phosphorus - Supplement Volume: Cyclic Phosphorus-Nitrogen Compounds - Three-, Four- And Five-Membered Ring Systems (Gmelin - Handbooks of Inorganic and Organometallic Chemistry , Part C, Sec. 5a). 8th ed. Springer, 1997.

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Book chapters on the topic "Four-membered ring compounds"

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Matsuda, Takanori. "Reactions of Four-Membered Ring Compounds." In Cleavage of Carbon-Carbon Single Bonds by Transition Metals. Wiley-VCH Verlag GmbH & Co. KGaA, 2015. http://dx.doi.org/10.1002/9783527680092.ch3.

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"3.1. Formation of Four-Membered Rings." In Carbocyclic Three- and Four Membered Ring Compounds, edited by Armin de Meijere. Georg Thieme Verlag, 1997. http://dx.doi.org/10.1055/b-0035-112514.

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"4.1. From Four-Membered Rings (I)." In Carbocyclic Three- and Four Membered Ring Compounds, edited by Armin de Meijere. Georg Thieme Verlag, 1997. http://dx.doi.org/10.1055/b-0035-112717.

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"4.1. From Four-Membered Rings (II)." In Carbocyclic Three- and Four Membered Ring Compounds, edited by Armin de Meijere. Georg Thieme Verlag, 1997. http://dx.doi.org/10.1055/b-0035-112718.

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"4.1. From Four-Membered Rings (III)." In Carbocyclic Three- and Four Membered Ring Compounds, edited by Armin de Meijere. Georg Thieme Verlag, 1997. http://dx.doi.org/10.1055/b-0035-112719.

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"3. By Ring Contraction." In Carbocyclic Three- and Four Membered Ring Compounds, edited by Armin de Meijere. Georg Thieme Verlag, 1997. http://dx.doi.org/10.1055/b-0035-112506.

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"2. By Ring Contraction." In Carbocyclic Three- and Four Membered Ring Compounds, edited by Armin de Meijere. Georg Thieme Verlag, 1997. http://dx.doi.org/10.1055/b-0035-112522.

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"2. With Ring Opening." In Carbocyclic Three- and Four Membered Ring Compounds, edited by Armin de Meijere. Georg Thieme Verlag, 1997. http://dx.doi.org/10.1055/b-0035-112548.

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"2.1.1. Rearrangement of Homoallylic Compounds." In Carbocyclic Three- and Four-Membered Ring Compounds, edited by Armin de Meijere. Georg Thieme Verlag, 1997. http://dx.doi.org/10.1055/b-0035-113163.

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"B.Transformations : 2. Ring-Opening Reactions (I)." In Carbocyclic Three- and Four-Membered Ring Compounds, edited by Armin de Meijere. Georg Thieme Verlag, 1997. http://dx.doi.org/10.1055/b-0035-110793.

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Reports on the topic "Four-membered ring compounds"

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Wells, Richard L., James W. Pasterczyk, Andrew T. McPhail, James D. Johnson, and Abbas Alvanipour. Synthesis and Characterization of Gallium-Arsenic Compounds Containing a Four-Membered Ga-As-Ga-Cl or Ga-AS-Ga-As Ring: Crystal Structures of (Me3SiCH2) 2GaAs(SiMe3)2)2. Defense Technical Information Center, 1990. http://dx.doi.org/10.21236/ada229513.

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Wells, R. L., L. J. Jones, A. T. McPhail, and A. Alvanipour. Synthesis and Characterization of Indium-Arsenic Compounds Containing a Four-Membered In-Ad-In-As or In-As-In-Cl Ring: Crystal Structures of ((Me3SiCH2) 2InAs(SiMe3)2)2 and (Me3SiCH2)2InAs(SiMe3)2In(CH2SiMe3)2Cl. Defense Technical Information Center, 1991. http://dx.doi.org/10.21236/ada232368.

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Wells, Richard L., William K. Holley, Soheila Shafieezad, Andrew T. McPhail, and Colin G. Pitt. The First Organogallium Four-Membered Ring Compound with Arsenic, Halogen Mixed Bridging: Synthesis and Crystal Structure of Ph2GaAs(SiMe3)2Ga(Ph) 2Cl. Defense Technical Information Center, 1988. http://dx.doi.org/10.21236/ada198571.

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