Relevant bibliographies by topics / Free radical reaction

Contents

  1. Journal articles
  2. Dissertations / Theses
  3. Books
  4. Book chapters
  5. Conference papers
  6. Reports

Academic literature on the topic 'Free radical reaction'

Author: Grafiati
Published: 4 June 2021
Last updated: 1 February 2022

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Journal articles on the topic "Free radical reaction"

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Wu, Yuh-Wern, Hsu-Ting Huang, Yi-Jing Chen, and Jyh-Ferng Yang. "Free radical SH2′ reaction mechanism study by comparing free radical SH2′ reaction with free radical addition reaction." Tetrahedron 62, no. 25 (2006): 6061–64. http://dx.doi.org/10.1016/j.tet.2006.03.106.

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Mohammad, Mahboob, Muhammad Tariq, and Muhammad Tahir Soomro. "“Long-life” atom-free radical: Generation and reactions of bromine atom-free radical." Collection of Czechoslovak Chemical Communications 75, no. 11 (2010): 1061–74. http://dx.doi.org/10.1135/cccc2010066.

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In order to study the damaging or beneficial properties of bromine atom-free radical, reaction of the free radical (Br•) with some biologically important compounds were investigated. Br• was generated through electrochemical oxidation of bromide ion (Br–). First the reactivity of Br• atom-free radical vis a vis its dimerization to form Br2, was studied using cyclic voltammetry and spectroelectrochemistry. Through these techniques it was ascertained that the substrates understudy and the under experimental conditions used, underwent reactions with Br• and not with dibromine (Br2). The monitorin
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Chuang, Che-Ping, Sheng-Shu Hou, and Ru-Rong Wu. "Allylsulfone in Free Radical Reaction." Synthetic Communications 22, no. 3 (1992): 467–76. http://dx.doi.org/10.1080/00397919208055425.

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Davies, M. J., S. Fu, and R. T. Dean. "Protein hydroperoxides can give rise to reactive free radicals." Biochemical Journal 305, no. 2 (1995): 643–49. http://dx.doi.org/10.1042/bj3050643.

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Proteins damaged by free-radical-generating systems in the presence of oxygen yield relatively long-lived protein hydroperoxides. These hydroperoxides have been shown by e.p.r. spectroscopy to be readily degraded to reactive free radicals on reaction with iron(II) complexes. Comparison of the observed spectra with those obtained with free amino acid hydroperoxides had allowed identification of some of the protein-derived radical species (including a number of carbon-centred radicals, alkoxyl radicals and a species believed to be the CO2 radical anion) and the elucidation of novel fragmentation
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Li, Guoxiang, Zhongyang Luo, Wenbo Wang, and Jianmeng Cen. "A Study of the Mechanisms of Guaiacol Pyrolysis Based on Free Radicals Detection Technology." Catalysts 10, no. 3 (2020): 295. http://dx.doi.org/10.3390/catal10030295.

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In order to understand the reaction mechanism of lignin pyrolysis, the pyrolysis process of guaiacol (o-methoxyphenol) as a lignin model compound was studied by free radical detection technology (electron paramagnetic resonance, EPR) in this paper. It was proven that the pyrolysis reaction of guaiacol is a free radical reaction, and the free radicals which can be detected mainly by EPR are methyl radicals. This paper proposes a process in which four free radicals (radicals 1- C6H4(OH)O*, radicals 5- C6H4(OCH3)O*, methyl radicals, and hydrogen radicals) are continuously rearranged during the py
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Pinet, Sandra, Mathieu Pucheault, Virginie Liautard, and Mégane Debiais. "Radical Metal-Free Borylation of Aryl Iodides." Synthesis 49, no. 21 (2017): 4759–68. http://dx.doi.org/10.1055/s-0036-1588431.

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A simple metal-free borylation of aryl iodides mediated by a fluoride sp2–sp3 diboron adduct is described. The reaction conditions are compatible with various functional groups. Electronic effects of substituents do not affect the borylation while steric hindrance does. The reaction proceeds via a radical mechanism in which pyridine serves to stabilize the boryl radicals, generated in situ.
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Packer, JE, and RER Taylor. "Free-Radical Reductions of Arenediazonium Ions in Aqueous Solution. VI. On Iododediazoniation." Australian Journal of Chemistry 38, no. 6 (1985): 991. http://dx.doi.org/10.1071/ch9850991.

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γ-Irradiation of aqueous solutions of p-ClC6H4N2+BF4- and KI initiates a chain reaction in which dichloroazobenzene is the major product. When iodine is also present the chain reaction is longer and the major product is chloroiodobenzene . The reaction � ������������������������� I2-·+ArN2+ → I2+Ar·+N2 is suggested to be propagation step in both reactions, with Ar · reacting with I3- in the presence of iodine and with ArN2+ in its absence. The relevance of these reactions to iododediazoniation is discussed.
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Goodman, B. A. "The involvement of oxygen-derived free radicals in plant–pathogen interactions." Proceedings of the Royal Society of Edinburgh. Section B. Biological Sciences 102 (1994): 479–93. http://dx.doi.org/10.1017/s0269727000014500.

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SynopsisPlants have evolved a multiplicity of defence mechanisms against pathogen attack. Their modes of action may be to (i) kill the pathogen directly, (ii) block the action of enzymes required for infection, or (iii) erect barriers to pathogen growth. Some of these reactions proceed via free radical intermediates and make use of either atmospheric oxygen or reactive oxygen species. This paper reviews the various types of reaction involving oxygen-derived free radicals that are initiated in plant tissue when it is invaded by pathogenic organisms. Both the production of free radicals by plant
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Fletcher, R. J., and J. A. Murphy. "Chapter 4. Reaction mechanisms. Part (iii) Free-radical reactions." Annual Reports Section "B" (Organic Chemistry) 88 (1991): 83. http://dx.doi.org/10.1039/oc9918800083.

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Hewlins, S. A., and J. A. Murphy. "Chapter 4. Reaction mechanisms. Part (iii) Free-radical reactions." Annual Reports Section "B" (Organic Chemistry) 89 (1992): 75. http://dx.doi.org/10.1039/oc9928900075.

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Dissertations / Theses on the topic "Free radical reaction"

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Zhao, Zhijun. "Laser flash photolysis studies of some gas phase reactions of atmospheric interest." Diss., Atlanta, Ga. : Georgia Institute of Technology, 2009. http://hdl.handle.net/1853/31790.

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Thesis (Ph.D)--Earth and Atmospheric Sciences, Georgia Institute of Technology, 2010.<br>Committee Chair: Wine, Paul; Committee Member: Huey, Greg; Committee Member: Mulholland, James; Committee Member: Nenes, Athanasios; Committee Member: Weber, Rodney. Part of the SMARTech Electronic Thesis and Dissertation Collection.
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Hart-Smith, Gene On Chemistry Faculty of Science UNSW. "Mass spectrometric investigations into free radical polymerisation reaction mechanisms." Awarded by:University of New South Wales. Chemistry, 2009. http://handle.unsw.edu.au/1959.4/44621.

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Contemporary mass spectrometry (MS) instrumentation featuring electrospray ionisation (ESI) or matrix-assisted laser desorption/ionisation (MALDI) ion sources were used to characterise the polymer distributions generated in various free radical polymerisations, allowing insights to be gained into the reaction mechanisms operating in these systems. In studying atom transfer radical polymerisation (ATRP) mediated star polymerisations of methyl acrylate (MA), ESI was found to be more effective in obtaining a comprehensive list of the distinct products present in the samples under investigation wh
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Friedline, Robert Alan. "The Reaction Kinetics of Neutral Free Radicals and Radical Ions Studied by Laser Flash Photolysis." Diss., Virginia Tech, 2004. http://hdl.handle.net/10919/11157.

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t-Butoxyl radical has been used as a chemical model for hydrogen abstractions in many enzymatic and biological systems. However, the question has arisen as to how well this reactive intermediate mimics these systems. In addressing this concern, absolute rate constants and Arrhenius parameters for hydrogen abstraction by t-butoxyl radical were measured for a broad class of substrates including amines, hydrocarbons, and alcohols using laser flash photolysis. Initially, no obvious reactivity relationship between rate constant and substrate structure was observed for these homolytic reactions.
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Sadeghipour, Mitra Jr. "Hydrocarbon Functionalization via a New Free Radical-Based Condensation Reaction." Diss., Virginia Tech, 1998. http://hdl.handle.net/10919/30627.

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A new free radical chain process for the allylation of hydrocarbons and some other substrates utilizing substituted allyl bromides (R-H + C=C-C-Br -> R-C-C=C + HBr) has been developed. Good to excellent yields were observed in all cases. Kinetic chain measurements and competition experiments were performed in order to elucidate the mechanism of the reaction. Overall, the results are consistent with a free radical chain process with bromine atom as the chain carrier. Substitution effects on the reactivity of the allyl bromides (CH2=C(Z)CH2Br) and their i
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Tirumala, Vijaya Raghavan. "Reaction control in quiescent systems of free-radical retrograde-precipitation polymerization /." Available online. Click here, 2003. http://sunshine.lib.mtu.edu/ETD/DISS/tirumalav/Dissertation.pdf.

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Jatoi, Ashique Hussain. "Some recent developments in free-radical additions to olefins and heteroarenes." Thesis, Bordeaux, 2019. http://www.theses.fr/2019BORD0055/document.

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Dans le cadre de cette thèse, nous avons étudié plusieurs processus radicalaires et en particulier l'addition de radicaux libres sur des systèmes insaturés tels que les alcènes et les hétérocycles aromatiques. Nous avons ainsi montré la réactivité unique des radicaux carbamoyles, issus de la décarboxylation des acides oxamiques. La carbamoylation "sans métal" photocatalysée des hétérocycles a donc été réalisée en présence d'un réactif iodé hypervalent, conduisant à des bases hétéroaromatiques fonctionnalisées, généralement avec de bons rendements. Le processus a été étendu aux acides oxamiques
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Minakata, Daisuke. "Development of aqueous phase hydroxyl radical reaction rate constants predictors for advanced oxidation processes." Diss., Georgia Institute of Technology, 2010. http://hdl.handle.net/1853/37127.

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Emerging contaminants are defined as synthetic or naturally occurring chemicals or microorganisms that are not currently regulated but have the potential to enter the environment and cause adverse ecological and/or human health effects. With recent development in analytical techniques, emerging contaminants have been detected in wastewater, source water, and finished drinking water. These environmental occurrence data have raised public concern about the fate and ecological impacts of such compounds. Concerns regarding emerging contaminants and the many chemicals that are in use or producti
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Zhang, Tao. "State-selected study of ion-molecule reaction dynamics, photodissociation dynamics and free radical studies using synchrotron radiation /." For electronic version search Digital dissertations database. Restricted to UC campuses. Access is free to UC campus dissertations, 2003. http://uclibs.org/PID/11984.

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Zhu, Lei. "Aqueous phase reaction kinetics of organic sulfur compounds of atmospheric interest." Diss., Available online, Georgia Institute of Technology, 2004:, 2004. http://etd.gatech.edu/theses/available/etd-11172004-142820/unrestricted/zhu%5Flei%5F200412%5Fphd.pdf.

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Thesis (Ph. D.)--Earth and Atmospheric Sciences, Georgia Institute of Technology, 2005.<br>Davis, Douglas, Committee Member ; Huey, Greg, Committee Member ; Nenes, Athanasios, Committee Member ; Weber, Rodney, Committee Member ; Whetten, Robert, Committee Member ; Wine, Paul H., Committee Chair. Includes bibliographical references.
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Imaram, Witcha. "Reaction of peroxynitrite and uric acid studied by ESR spin trapping and mass spectrometry free radical formation and product identification /." [Gainesville, Fla.] : University of Florida, 2008. http://purl.fcla.edu/fcla/etd/UFE0022880.

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Books on the topic "Free radical reaction"

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Edney, Edward. Validation of OH radical reaction rate constant test protocol. U.S. Environmental Protection Agency, Atmospheric Sciences Research Laboratory, 1986.

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Fehér, J. Free radical reactions in medicine. Springer-Verlag, 1987.

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G, Csomós, and Vereckei A, eds. Free radical reactions in medicine. Springer-Verlag, 1987.

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Postigo, J. Alberto. Organic radical reactions in water and alternative media. Nova Science Publishers, 2011.

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1972-, Satō Kōtarō, ed. Rajikaru jūgō. Kyōritsushuppan, 2013.

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A, Porter Ned, and Giese Bernd 1940-, eds. Stereochemistry of radical reactions: Concepts, guidelines, and synthetic applications. VCH, 1996.

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Radical reactions in aqueous media. RSC Publishing, 2010.

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Paulauskas, Irena O. Radical polymerization: New developments. Nova Science Publishers, 2011.

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Moniz-Barreto, João Pedro. Dioxygen free radical reactions. Oxford Brookes University, 1997.

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Tōgō, Hideo. Yūki furī rajikaru no kagaku. Kōdansha, 2001.

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Book chapters on the topic "Free radical reaction"

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Grossman, Robert B. "Free-Radical Reactions." In The Art of Writing Reasonable Organic Reaction Mechanisms. Springer New York, 2003. http://dx.doi.org/10.1007/0-387-21545-x_5.

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Grossman, Robert B. "Free-Radical Reactions." In The Art of Writing Reasonable Organic Reaction Mechanisms. Springer International Publishing, 2019. http://dx.doi.org/10.1007/978-3-030-28733-7_5.

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Grossman, Robert B. "Free-Radical Reactions." In The Art of Writing Reasonable Organic Reaction Mechanisms. Springer New York, 1999. http://dx.doi.org/10.1007/978-1-4757-3030-2_5.

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Nakamura, H., M. Uzura, K. Uchida, et al. "Effects of edaravone on experimental brain injury in view of free radical reaction." In Brain Edema XII. Springer Vienna, 2003. http://dx.doi.org/10.1007/978-3-7091-0651-8_67.

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Walling, Cheves. "Free Radical Reactions." In Energetics of Organic Free Radicals. Springer Netherlands, 1996. http://dx.doi.org/10.1007/978-94-009-0099-8_1.

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Norman, Richard, and James M. Coxon. "Free-radical reactions." In Principles of Organic Synthesis. Springer Netherlands, 1993. http://dx.doi.org/10.1007/978-94-011-2166-8_17.

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Carey, Francis A., and Richard J. Sundberg. "Free-Radical Reactions." In Advanced Organic Chemistry. Springer US, 1990. http://dx.doi.org/10.1007/978-1-4613-9795-3_12.

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Went, C. "Free Radical Reactions." In Work Out Organic Chemistry. Macmillan Education UK, 1988. http://dx.doi.org/10.1007/978-1-349-09726-5_12.

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Zhdanov, R. I. "Nitroxyl Radicals and Non-Radical Reactions of Free Radicals." In Bioactive Spin Labels. Springer Berlin Heidelberg, 1992. http://dx.doi.org/10.1007/978-3-642-48724-8_2.

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Ide, Nathan D. "Selected Free Radical Reactions." In Practical Synthetic Organic Chemistry. John Wiley & Sons, Inc., 2011. http://dx.doi.org/10.1002/9781118093559.ch11.

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Conference papers on the topic "Free radical reaction"

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Ehrenberg, Anders. "Protein dynamics, free radical transfer and reaction cycle of ribonucleotide reductase." In The third international symposium on biological physics. AIP, 1999. http://dx.doi.org/10.1063/1.59887.

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Wylde, Jonathan J. "The Challenges Associated with Reaction Products Left in Scale Inhibitor Species after Radical Polymerization." In SPE International Oilfield Scale Conference and Exhibition. SPE, 2014. http://dx.doi.org/10.2118/spe-169778-ms.

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Abstract The use of polymeric scale inhibitors has been ubiquitously accepted by the oil and gas industry for many years. There are many benefits to the use of this type of chemistry that include aspects such as high performance, scale species selectivity, enhanced brine compatibility, favorable environmental properties and high thermal stability. A very common way to manufacture polymeric scale inhibitors is via free radical polymerization. Here an initiator is used to propagate the generation of free radicals from a species, such as hydrogen peroxide. The initiator chemistry can be very vari
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Shewhart, Andrew T., Marc D. Polanka, Jacob J. Robertson, Nathan J. Greiner, and James L. Rutledge. "Minimization of Heat Load due to Secondary Reactions in Fuel Rich Environments." In ASME Turbo Expo 2014: Turbine Technical Conference and Exposition. American Society of Mechanical Engineers, 2014. http://dx.doi.org/10.1115/gt2014-25703.

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The demand for increased thrust, higher engine efficiency, and reduced fuel consumption has increased the turbine inlet temperature and pressure in modern gas turbine engines. The outcome of these higher temperatures and pressures is the potential for unconsumed radical species to enter the turbine. Because modern cooling schemes for turbine blades involve injecting cool, oxygen rich air adjacent to the surface, the potential for reaction with radicals in the mainstream flow and augmented heat transfer to the blade arises. This result is contrary to the purpose of film cooling. In this environ
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Cheenkachorn, Kraipat, Wallis A. Lloyd, and Joseph M. Perez. "Use of Pressurized Differential Scanning Calorimetry (PDSC) to Evaluate Effectiveness of Additives in Vegetable Oil Lubricants." In ASME 2003 Internal Combustion Engine Division Spring Technical Conference. ASMEDC, 2003. http://dx.doi.org/10.1115/ices2003-0657.

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Use of renewable resources to replace petroleum base stocks in lubricants is attractive. Research on additives enhanced by current advances in genetic and chemical modifications has resulted in improved oxidative stability of vegetable oils. Like most oxidation processes, the oxidative degradation of vegetable oils is complex. The auto-oxidation free radical mechanisms and hydroperoxide theories of oxidation have been well studied. Factors that influence the degradation of oils include temperature, surface reactivity, rates of formation of radicals, chemical composition factors such as olefin
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Serra, Christophe, Nicolas Sary, and Guy Schlatter. "Numerical Simulations of Macromolecular Syntheses in Micro-Mixers: Towards a Better Control of the Polymerization." In ASME 3rd International Conference on Microchannels and Minichannels. ASMEDC, 2005. http://dx.doi.org/10.1115/icmm2005-75044.

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This paper investigates the modeling of styrene free radical polymerization in two different types of micro-mixer for which the wall temperature is kept constant. The simulations are performed with the help of the finite elements method which allows solving simultaneously partial differential equations resulting from the hydrodynamics, thermal and mass transfer (convection, diffusion and chemical reaction). The different micro-mixers modeled are on one hand an interdigital multilamination micro-mixer with a large focusing section and on the other hand a simple T-junction with three different r
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Ugarte, Sergio, Mohamad Metghalchi, and James C. Keck. "Methanol Oxidation Induction Times Using the Rate-Controlled Constrained-Equilibrium Method." In ASME 2003 International Mechanical Engineering Congress and Exposition. ASMEDC, 2003. http://dx.doi.org/10.1115/imece2003-55289.

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Methanol oxidation has been modeled using the Rate-Controlled Constrained-Equilibrium method (RCCE). In this method, composition of the system is determined by constraints rather than by species. Since the number of constraints can be much smaller than the number of species present, the number of rate equations required to describe the time evolution of the system can be considerably reduced. In the present paper, C1 chemistry with 29 species and 140 reactions has been used to investigate the oxidation of stoichiometric methanol/oxygen mixture at constant energy and volume. Three fixed element
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Zhang, Chen, Ke Li, and Zongxuan Sun. "Modeling of Piston Trajectory-Based HCCI Combustion." In ASME 2014 Dynamic Systems and Control Conference. American Society of Mechanical Engineers, 2014. http://dx.doi.org/10.1115/dscc2014-6256.

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Previously, the authors have designed and implemented an active motion control “virtual crankshaft” for a free piston engine, which enables precise piston tracking of desired trajectories. With this mechanism, the volume of the combustion chamber can be regulated, and therefore the pressure, temperature and species concentrations of in-cylinder gas can be adjusted in real-time which affect the combustion process directly. This new degree of freedom enables us to conduct trajectory-based combustion control. In this paper, a model of the free piston engine running homogeneous charge compression
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Steinfeld, Jeffrey I., J. A. Shorter, J. Langan, and Xu Xin. "Reactions Of Photogenerated Neutral Free Radicals At Semiconductor Surfaces." In OE/LASE '89, edited by Thomas F. George. SPIE, 1989. http://dx.doi.org/10.1117/12.951633.

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Pfaendtner, Jim, Linda J. Broadbelt, and Q. Jane Wang. "Quantum Chemical Studies of Free-Radical, Hindered Phenol Stabilizers." In World Tribology Congress III. ASMEDC, 2005. http://dx.doi.org/10.1115/wtc2005-64007.

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Quantum chemical investigations of the action of hindered phenol radical stabilizers in lubricant degradation chemistry have been completed. We are currently developing the first mechanistic models of lubricant degradation with the aim of including the chemistry of additives such as radical stabilizers that are found in commercial lubricant formulations. A key component of development of these models is obtaining reliable estimates of the kinetic parameters for all reactions. Specifically, rate constants and structure-reactivity correlations for the interaction of hindered phenol radical stabi
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Gauduel, Yann, Stanislas Pommeret, Noelle Yamada, and Andre Antonetti. "Recent developments by femtosecond spectroscopy in biological ultrafast free radical reactions." In Moscow - DL tentative, edited by Sergei A. Akhmanov and Marina Y. Poroshina. SPIE, 1991. http://dx.doi.org/10.1117/12.57301.

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Reports on the topic "Free radical reaction"

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Curl, R. F., and G. P. Glass. Infrared absorption spectroscopy and chemical kinetics of free radicals. [HCCN; CCH-H[sub 2] reaction; propargyl radical recombination]. Office of Scientific and Technical Information (OSTI), 1993. http://dx.doi.org/10.2172/6566601.

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Blank, D. A., N. Hemmi, A. G. Suits, and Y. T. Lee. Free radical hydrogen atom abstraction from saturated hydrocarbons: A crossed-molecular-beams study of the reaction Cl + C{sub 3}H{sub 8} {yields} HCl + C{sub 3}H{sub 7}. Office of Scientific and Technical Information (OSTI), 1997. http://dx.doi.org/10.2172/603612.

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Terry A. Miller. Unimolecular reaction dynamics of free radicals. Office of Scientific and Technical Information (OSTI), 2006. http://dx.doi.org/10.2172/890741.

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Brennecke, Joan F. Studies of Ionic and Free Radical Reactions in Supercritical Water. Defense Technical Information Center, 2001. http://dx.doi.org/10.21236/ada396304.

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Bise, Ryan T. Photoisomerization and photodissociation dynamics of reactive free radicals. Office of Scientific and Technical Information (OSTI), 2000. http://dx.doi.org/10.2172/767628.

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Jacox, Marilyn E. Free Radical Detection and Reactions in the Decomposition of Energetic Materials. Defense Technical Information Center, 1987. http://dx.doi.org/10.21236/ada184677.

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Dagdigian, Paul J., and Millard H. Alexander. Study of Elementary Reactions and Energy Transfer Processes Involving the NH and CN Free Radicals. Defense Technical Information Center, 1991. http://dx.doi.org/10.21236/ada238461.

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R. Will Grimes, Norman Merriam, L.J. Fahy, et al. 1.PRELIMINARY EVALUATION OF A PROCESS USING PLASMA REACTIONS TO DESULFURIZE HEAVY OILS; 2.PROCESS SUPPORT AND DEVELOPMENT FOR COMPCOAL; 3.MISCIBLE/IMMISCIBLE GAS INJECTION PROCESSES; 4.COMPCOAL: A PROFITABLE PROCESS FOR PRODUCTION OF A STABLE HIGH-BTU FUEL FROM POWDER RIVER BASIN COAL; 5.EVALUATION OF ALTERNATE FREE RADICAL INITIATORS FOR HEAVY OIL/PLASTICS CO-PROCESSING; 6.DEVELOPMENT OF AN ON-LINE ALKALI MONITORING PROBE; 7.DEVELOPMENT OF A PORTABLE DATA ACQUISITION SYSTEM; 8.BENCH-SCALE TESTING AND VERIFICATION OF PYROLYSIS CONCEPT FOR REMEDIATION OF TANK BOTTOMS; 9.HAZ-FLOTE: EX-SITU DECONTAMINATION OF MATERIALS; 10.IN-SITU AMELIORATION OF ACID MINE DRAINAGE PROBLEMS; 11.THE SYNAG PROCESS: COAL COMBUSTION ASH MANAGEMENT OPTION; 12.CONDITIONING AND HYDRATION REACTIONS ASSOCIATED WITH CLEAN COAL TECHNOLOGY ASH DISPOSAL/HYDRATION. Office of Scientific and Technical Information (OSTI), 1999. http://dx.doi.org/10.2172/767235.

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