Academic literature on the topic 'Friedel-Crafts Reactions'

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Journal articles on the topic "Friedel-Crafts Reactions"

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Đud, Mateja, Anamarija Briš, Iva Jušinski, Davor Gracin, and Davor Margetić. "Mechanochemical Friedel–Crafts acylations." Beilstein Journal of Organic Chemistry 15 (June 17, 2019): 1313–20. http://dx.doi.org/10.3762/bjoc.15.130.

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Friedel–Crafts (FC) acylation reactions were exploited in the preparation of ketone-functionalized aromatics. Environmentally more friendly, solvent-free mechanochemical reaction conditions of this industrially important reaction were developed. Reaction parameters such as FC catalyst, time, ratio of reagents and milling support were studied to establish the optimal reaction conditions. The scope of the reaction was explored by employment of different aromatic hydrocarbons in conjunction with anhydrides and acylation reagents. It was shown that certain FC-reactive aromatics could be effectivel
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El-Zohry, Maher F. "Nonconventional Friedel-Crafts Chemistry. VII. On Homoannular and Heteroannular Reactions of Ferrocene with Bifunctional Moieties under Friedel-Crafts Conditions." Collection of Czechoslovak Chemical Communications 58, no. 5 (1993): 1203–7. http://dx.doi.org/10.1135/cccc19931203.

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The utilization of ferrocene in the organic synthesis and its uses in Friedel-Crafts chemistry, together with our interest in this area, prompted us to investigate the reaction of ferrocene with halo acid chlorides and α,β-unsaturated acid chlorides under different Friedel-Crafts conditions with the aim to employ these reactions in the syntheses of polycyclic ferrocene derivatives.
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Biswas, Anup. "Aromatic C–H bond functionalization through organocatalyzed asymmetric intermolecular aza-Friedel–Crafts reaction: a recent update." Beilstein Journal of Organic Chemistry 19 (June 28, 2023): 956–81. http://dx.doi.org/10.3762/bjoc.19.72.

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The aza-Friedel–Crafts reaction allows an efficient coupling of electron-rich aromatic systems with imines for the facile incorporation of aminoalkyl groups into the aromatic ring. This reaction has a great scope of forming aza-stereocenters which can be tuned by different asymmetric catalysts. This review assembles recent advances in asymmetric aza-Friedel–Crafts reactions mediated by organocatalysts. The mechanistic interpretation with the origin of stereoselectivity is also explained.
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Dmitrieva, A., and A. Stepacheva. "Friedel-Krafts alkylation." Bulletin of Science and Practice, no. 8 (August 15, 2017): 43–48. https://doi.org/10.5281/zenodo.842942.

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The mechanism of the reaction of alkylation of aromatic compounds according to Friedel–Crafts is considered. Unlike the acylation reaction, alkylation is a reversible process. The general principle of the reaction is the intermediate formation of carbenium ions capable of reacting as an electrophile in the aromatic reactions of electrophilic substitution. It is established that the mechanism of this reaction is ensured by the detection of the σ–complex at low temperatures. The possibility of using the intramolecular variant of Friedel–Crafts alkylation is considered; li
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Huang, Luo, and Wang. "Hafnium-Doped Mesoporous Silica as Efficient Lewis Acidic Catalyst for Friedel–Crafts Alkylation Reactions." Nanomaterials 9, no. 8 (2019): 1128. http://dx.doi.org/10.3390/nano9081128.

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The development of an efficient solid catalyst for Friedel–Crafts (FC) reactions is of great importance to organic synthetic chemistry. Herein, we reported the hafnium-doped mesoporous silica catalyst Hf/SBA-15 and its first use for Friedel–Crafts alkylation reactions. Catalysts with different Si/Hf ratios were prepared and characterized, among which Hf/SBA-15(20) (Si/Hf = 20:1) was the most active catalyst, offering up to 99.1% benzylated product under mild reaction conditions. The influences of reaction conditions on the product were systematically investigated and compared. Pyridine-IR char
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Olah, George A., Imre Bucsi, Dong Soo Ha, Robert Aniszfeld, Chang Soo Lee, and G. K. Surya Prakash. "Friedel-Crafts Reactions of Buckminsterfullerene." Fullerene Science and Technology 5, no. 2 (1997): 389–405. http://dx.doi.org/10.1080/15363839708011999.

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Terrasson, Vincent, Renata Marcia de Figueiredo, and Jean Marc Campagne. "Organocatalyzed Asymmetric Friedel-Crafts Reactions." European Journal of Organic Chemistry 2010, no. 14 (2010): 2635–55. http://dx.doi.org/10.1002/ejoc.200901492.

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Nayak, Yogeesha N., Swarnagowri Nayak, Y. F. Nadaf, Nitinkumar S. Shetty, and Santosh L. Gaonkar. "Zeolite Catalyzed Friedel-Crafts Reactions: A Review." Letters in Organic Chemistry 17, no. 7 (2020): 491–506. http://dx.doi.org/10.2174/1570178616666190807101012.

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Friedel-Crafts reaction is one of the most useful synthetic tools in organic chemistry, mainly in the synthesis of aromatic ketones. The active catalysts for this reaction are modified zeolites and are preferable catalysts when shape selectivity affects the formation of the expected product. In this review, our aim is to corroborate recent literature available on zeolite catalyzed Friedel-Crafts alkylation and acylation reaction.
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S., B. Mahato. "Advances in the chemistry of Friedel-Crafts acylation." Journal of Indian Chemical Society Vol. 77, Apr 2000 (2000): 175–91. https://doi.org/10.5281/zenodo.5862471.

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Indian Institute of Chemical Biology, 4 RajaS. C. Mullick Road, Jadavpur, Calcutta-700 032, India <em>Manuscript received 2 July 1999, accepted 20 September 1999</em> The scope and application of Friedel-Crafts reactions have proliferated tremendously. The advances in Friedel-Crafts acylation reactions in areas such as regioselective synthesis, new synthetic methods, cycloacylation, synthesis of secondary products of acylation of arenes, stereoselective and other miscellaneous syntheses are reviewed. Developments in Friedel-Crafts catalysts including Lewis and Bronsted acids, Bronsted-Lewis su
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Yıldız, Tülay, İrem Baştaş, and Hatice Başpınar Küçük. "Transition-metal-free intramolecular Friedel–Crafts reaction by alkene activation: A method for the synthesis of some novel xanthene derivatives." Beilstein Journal of Organic Chemistry 17 (August 30, 2021): 2203–8. http://dx.doi.org/10.3762/bjoc.17.142.

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In this work, new derivatives (substituted 9-methyl-9-arylxanthenes) of xanthene compounds (5a–l) of possible biological significance were synthesized by developing a new synthesis method. In order to obtain xanthene derivatives, the original alkene compounds to be used as the starting materials were synthesized in four steps using appropriate reactions. A cyclization reaction by intramolecular Friedel–Crafts alkylation was carried out in order to synthesize the desired xanthene derivatives using the alkenes as starting compounds. The intramolecular Friedel–Crafts reaction was catalyzed by tri
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Dissertations / Theses on the topic "Friedel-Crafts Reactions"

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Davies, Timothy James. "New catalysts for friedel-crafts reactions." Thesis, Heriot-Watt University, 2001. http://hdl.handle.net/10399/505.

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Skeffington, Ian. "Friedel-crafts reactions over various catalysts." Thesis, University of Manchester, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.682191.

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The work contained in this thesis covers the sulfonylation reaction between toluene and one of methanesulfonic anhydride and methanesulfonyl chloride. The desired products of these reactions are the three isomers (onho. meta and para) of methyl tolyl sulfone and the by-products are methanesulfonic acid, when methanesulfonic anhydride was used as the sulfonylating agent, and hydrogen chloride when methanesulfonyI chloride was the sulfonylating agent. When this reaction was carried out using the traditional Friedel-Crafts catalyst, AlCl) the thermodynamic isomer ratio of 60 % ortlw, 30 % para an
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Jayne, A. J. "Friedel-Crafts acylation reactions catalysed by solids." Thesis, Swansea University, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.637410.

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The various inorganic solids that may be employed as heterogeneous catalysts in organic reactions are discussed in Chapter 1. In the present climate, heterogeneous catalysts are seen as more environmentally acceptable alternatives to homogeneous Lewis acid type catalysts. Chapter 2 describes the Friedel-Crafts acylation of aromatics. Discussion focuses on both the classical and solid catalysed reactions. The study of a pharmaceutical intermediate is described in Chapter 3. The aims of the work described were to develop an efficient and commercially viable process for the production of 1-(4-met
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Gomez, Rodrigo Amandi. "Continuous Friedel-Crafts reactions in carbon dioxide." Thesis, University of Nottingham, 2004. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.429082.

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Burguin, Emilie. "Zirconia based solid acids for Friedel-Crafts alkylation reactions." Thesis, University of York, 2004. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.420266.

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Landon, Philip. "Novel heterogeneous catalysts for oxidations and Friedel-Crafts reactions." Thesis, University of York, 1993. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.358154.

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Gardner, June Ann. "Friedel-Crafts acylation reactions using heterogeneous catalysts stimulated by microwave radiation." Thesis, University of Central Lancashire, 2004. http://clok.uclan.ac.uk/20208/.

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Ion exchanged zeolites, ion exchanged clays, sulphated zirconia and silica supported phosphotungstic acid were prepared. Characterisation of the catalysts using pyridine adsorption revealed the catalysts contained both Brønsted and Lewis acid sites. When the catalytic activities for the acylation of toluene and anisole were studied there was found to be a correlation between the Brønsted acidity and the catalytic activity. The reactivity of the catalysts is dependant upon both the concentration and the chain length of the carboxylic acid. An optimum chain length being in the range Cm-C12. An a
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Laidlaw, Paul. "Catalysis of organic reactions by cation-exchanged zeolites." Thesis, University of Liverpool, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.366734.

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Hashimoto, Sigma. "Syntheses of Polycyclic Aromatic Compounds with Heteroatom Junctions via Tandem Hetero-Friedel-Crafts Reactions." 京都大学 (Kyoto University), 2013. http://hdl.handle.net/2433/174950.

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Vukovic, Vuk. "Synergistic effect of acids and HFIP on Friedel-Crafts reactions of alcohols and cyclopropanes." Thesis, Strasbourg, 2018. http://www.theses.fr/2018STRAF068.

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L'activation catalytique d'alcools vers la formation déshydrative de liaisons chimiques sans pré-activation est devenue un intérêt de recherche majeur au cours des deux dernières décennies. Dans cette thèse, l’effet synergique particulier des acides forts en tant que catalyseurs dans l’hexafluoroisopropanol (HFIP) comme solvant de diverses classes de carbocations instables dans la chimie de Friedel-Crafts a été étudié. Il a été constaté que pour la première fois, les réactions de Friedel-Crafts d'alcools benzyliques primaires fortement désactivés, catalysées par un acide, se déroulaient facile
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Books on the topic "Friedel-Crafts Reactions"

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Sartori, Giovanni. Advances in Friedel-Crafts acylation reactions: Catalytic and green processes. Taylor & Francis, 2010.

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Sartori, Giovanni. Advances in Friedel-Crafts acylation reactions: Catalytic and green processes. Taylor & Francis, 2010.

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Parman, Toufan. Laser flash photolysis of 9-substituted-9-fluorenols. A Friedel-crafts cyclization reaction. National Library of Canada, 1993.

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Maggi, Raimondo, and Sartori Giovanni Maggi Raimondo. Advances in Friedel-Crafts Acylation Reactions. Taylor & Francis Group, 2009.

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Sartori, Giovanni. Advances in Friedel-Crafts Acylation Reactions: Catalytic and Green Processes. CRC, 2009.

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Maggi, Raimondo, and Giovanni Sartori. Advances in Friedel-Crafts Acylation Reactions: Catalytic and Green Processes. Taylor & Francis Group, 2009.

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Maggi, Raimondo, and Giovanni Sartori. Advances in Friedel-Crafts Acylation Reactions: Catalytic and Green Processes. Taylor & Francis Group, 2009.

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Maggi, Raimondo, and Giovanni Sartori. Advances in Friedel-Crafts Acylation Reactions: Catalytic and Green Processes. Taylor & Francis Group, 2017.

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Olah, George A., Marco Bandini, and Achille Umani-Ronchi. Catalytic Asymmetric Friedel-Crafts Alkylations. Wiley & Sons, Limited, John, 2009.

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Walter A. (Walter Albert) Lawrance. Friedel and Crafts' Reaction -Nitro-phthalic Anhydrides and Acetylamino-phthalic Anhydrides with Benzene and Aluminum Chloride [microform]. Creative Media Partners, LLC, 2021.

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Book chapters on the topic "Friedel-Crafts Reactions"

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Li, Jie Jack. "Friedel-Crafts reaction." In Name Reactions. Springer Berlin Heidelberg, 2003. http://dx.doi.org/10.1007/978-3-662-05336-2_112.

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Li, Jie Jack. "Friedel–Crafts reaction." In Name Reactions. Springer International Publishing, 2014. http://dx.doi.org/10.1007/978-3-319-03979-4_109.

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Li, Jie Jack. "Friedel-Crafts reaction." In Name Reactions. Springer Berlin Heidelberg, 2002. http://dx.doi.org/10.1007/978-3-662-04835-1_104.

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Li, Jie Jack. "Friedel–Crafts reaction." In Name Reactions. Springer Berlin Heidelberg, 2009. http://dx.doi.org/10.1007/978-3-642-01053-8_101.

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Li, Jie Jack. "Friedel–Crafts Reaction." In Name Reactions. Springer International Publishing, 2021. http://dx.doi.org/10.1007/978-3-030-50865-4_53.

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Sereda, Grigoriy. "Friedel-Crafts Reactions." In Methods in Pharmacology and Toxicology. Springer New York, 2021. http://dx.doi.org/10.1007/978-1-0716-1579-9_5.

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Hui, Yonghai, Lili Lin, Xiaohua Liu, and Xiaoming Feng. "Zinc-Catalyzed Friedel-Crafts Reactions." In Zinc Catalysis. Wiley-VCH Verlag GmbH & Co. KGaA, 2015. http://dx.doi.org/10.1002/9783527675944.ch4.

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Sartori, Giovanni, Raimondo Maggi, and Veronica Santacroce. "Catalytic Friedel-Crafts Acylation Reactions." In Arene Chemistry. John Wiley & Sons, Inc, 2015. http://dx.doi.org/10.1002/9781118754887.ch3.

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Chen, Chuan-Feng, and Yun Shen. "Diels–Alder and Friedel–Crafts-Type Reactions." In Helicene Chemistry. Springer Berlin Heidelberg, 2016. http://dx.doi.org/10.1007/978-3-662-53168-6_4.

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Wilkes, John S. "Friedel-Crafts Reactions in Chloroaluminate Molten Salts." In Molten Salt Chemistry. Springer Netherlands, 1987. http://dx.doi.org/10.1007/978-94-009-3863-2_19.

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Conference papers on the topic "Friedel-Crafts Reactions"

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Bykov, Alexey, Galina Demidenko, Linda Nikoshvili, and Elena Bakhvalova. "INFLUENCE OF THE NATURE OF AROMATIC POLYMER AS A PT PARTICLE STABILIZER ON ITS ACTIVITY AND SELECTIVITY IN THE LIQUID-PHASE HYDROGENATION OF AROMATIC AND POLYAROMATIC SUBSTRATES." In 24th SGEM International Multidisciplinary Scientific GeoConference 24. STEF92 Technology, 2024. https://doi.org/10.5593/sgem2024/4.1/s17.16.

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A series of platinum catalytic systems stabilized in aromatic polymers were obtained in this work. Commercially available styrene-divinylbenzene (MN100) and polymers synthesized by one-stage crosslinking by the Friedel-Crafts reaction from benzene, naphthalene, and an equimolar benzene-naphthalene mixture were used as polymers. The obtained systems were tested in liquid-phase hydrogenation reactions of benzene, toluene, and benzene-toluene mixture, as well as anthracene in a dodecane medium. The reaction products were studied using GC-MS. Polymers and catalytic systems were studied using diffu
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Inokuma, Tsubasa, Kodai Nishida, Akira Shigenaga, Ken-Ichi Yamada, and Akira Otaka. "Novel methodology for the synthesis of a-indolyl-glycine containing peptide via direct asymmetric Friedel–Crafts reaction to peptidyl imine." In 35th European Peptide Symposium. Prompt Scientific Publishing, 2018. http://dx.doi.org/10.17952/35eps.2018.016.

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