Academic literature on the topic 'Fullerene'

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Journal articles on the topic "Fullerene"

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Lin, Hao-Sheng, and Yutaka Matsuo. "Functionalization of [60]fullerene through fullerene cation intermediates." Chemical Communications 54, no. 80 (2018): 11244–59. http://dx.doi.org/10.1039/c8cc05965a.

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Fullerene cations, namely [60]fullerene radical cation (C<sub>60</sub>˙<sup>+</sup>) and organo[60]fullerenyl cation (RC<sub>60</sub><sup>+</sup>), open paths for the efficient derivatization of a great variety of fullerenes.
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Lun-Fu, Aleksandr V., Alexey M. Bubenchikov, Mikhail A. Bubenchikov, and Vyacheslav A. Ovchinnikov. "Numerical Simulation of Interaction between Kr+ Ion and Rotating C60 Fullerene towards for Nanoarchitectonics of Fullerene Materials." Crystals 11, no. 10 (2021): 1204. http://dx.doi.org/10.3390/cryst11101204.

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Dynamics of charged fullerene in a surface layer of fullerite is studied under the influence of neutral or charged particles of the gas phase surrounding the fullerite material. The translational displacements of the nodes of the crystal lattice structure are determined by the equations of motion of the centers of mass of fullerenes. Central fullerene, which is described as a discrete set of sixty carbon atoms, plays a special role in the presented mathematical model. Angular oscillations and rotations of the central fullerene are described by the dynamic Euler equations. All other fullerenes
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Pacor, Sabrina, Alberto Grillo, Luka Đorđević, et al. "Effects of Two Fullerene Derivatives on Monocytes and Macrophages." BioMed Research International 2015 (2015): 1–13. http://dx.doi.org/10.1155/2015/915130.

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Two fullerene derivatives (fullerenes1and2), bearing a hydrophilic chain on the pyrrolidinic nitrogen, were developed with the aim to deliver anticancer agents to solid tumors. These two compounds showed a significantly different behaviour on human neoplastic cell linesin vitroin respect to healthy leukocytes. In particular, the pyrrolidinium ring on the fullerene carbon cage brings to a more active compound. In the present work, we describe the effects of these fullerenes on primary cultures of human monocytes and macrophages, two kinds of immune cells representing the first line of defence i
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Suvorov, S. V., A. V. Severiuchin, and A. V. Vakhrushev. "The effect of the angle of «meeting» of fullerite C60 with a solid substrate on the deposition process." PNRPU Mechanics Bulletin, no. 3 (December 15, 2020): 90–97. http://dx.doi.org/10.15593/perm.mech/2020.3.09.

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Carbon forms a large number of allotropic forms, one of which is fullerene. Fullerene is a convex closed polyhedron with carbon atoms at its vertices. The most common is fullerene, consisting of 60 carbon atoms and designated - C60. In turn, fullerenes are able to agglomerate, forming a molecular crystal - fullerite. In the interaction of fullerite C60 with a solid, it is possible to deposit on the surface of the body both whole fullerite and the fullerenes that form it. The interaction process in the C60 fullerite system - the substrate of a solid, and then on - the fullerite - substrate syst
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Bubenchikov, Alexey, Mikhail Bubenchikov, Dmitriy Mamontov, and Alexandr Lun-Fu. "Md-Simulation of Fullerene Rotations in Molecular Crystal Fullerite." Crystals 9, no. 10 (2019): 496. http://dx.doi.org/10.3390/cryst9100496.

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The present paper describes rotations of C60 fullerene molecules in the solid phase of a fullerite. The conducted studies show that these relatively large molecules rotate according to the same laws as macroscopic bodies, i.e., according to the laws of classical mechanics. The performed calculations confirm that fullerene rotations do not cause friction. We suggest a method for a strong increase in the internal energy of the material that does not lead to its destruction. It is theoretically shown that in standard fullerite, in the absence of electric and magnetic fields, fullerene rotations o
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Sabirov, Denis Sh. "Polarizability as a landmark property for fullerene chemistry and materials science." RSC Adv. 4, no. 85 (2014): 44996–5028. http://dx.doi.org/10.1039/c4ra06116k.

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The review summarizes data on dipole polarizability of fullerenes and their derivatives, covering the most widespread classes of fullerene-containing molecules (fullerenes, fullerene exohedral derivatives, fullerene dimers, endofullerenes, fullerene ions, and derivatives with ionic bonds).
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Chen, Guoping, Lok Kumar Shrestha, and Katsuhiko Ariga. "Zero-to-Two Nanoarchitectonics: Fabrication of Two-Dimensional Materials from Zero-Dimensional Fullerene." Molecules 26, no. 15 (2021): 4636. http://dx.doi.org/10.3390/molecules26154636.

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Nanoarchitectonics of two-dimensional materials from zero-dimensional fullerenes is mainly introduced in this short review. Fullerenes are simple objects with mono-elemental (carbon) composition and zero-dimensional structure. However, fullerenes and their derivatives can create various types of two-dimensional materials. The exemplified approaches demonstrated fabrications of various two-dimensional materials including size-tunable hexagonal fullerene nanosheet, two-dimensional fullerene nano-mesh, van der Waals two-dimensional fullerene solid, fullerene/ferrocene hybrid hexagonal nanosheet,
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M.M., Kasumov. "Structural Changes of C60, C70 Mixture Fullerite at Heating by the Action of Pulsed Laser Beam." Chemistry Research Journal 2, no. 6 (2017): 194–96. https://doi.org/10.5281/zenodo.13941977.

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Structural transformations take place in the near-surface layer during the recording of fullerene mass spectrum under the action of laser beam. The changes are associated with the sequential degradation of fullerite on the scheme: crystallites &rarr;fullerenes&rarr;carbon clusters, soot.
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Manchado, A., J. J. Díaz-Luis, D. A. García-Hernández, and F. Cataldo. "A Catalog of Diffuse Interstellar Bands in Fullerene-Containing Planetary Nebulae." Proceedings of the International Astronomical Union 9, S297 (2013): 223–25. http://dx.doi.org/10.1017/s1743921313015901.

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AbstractLarge fullerenes and fullerene-based molecules have been proposed as carriers of diffuse interstellar bands (DIBs). The recent detection of the most common fullerenes (C60 and C70) around some Planetary Nebulae (PNe) now enable us to study the DIBs in fullerene-rich space environments. We have studied the presence of DIBs in the optical spectra (~3300-9400 Å) of two fullerene-containing PNe (Tc 1 and M 1-20). Special attention is given to DIBs which are found to be unusually intense in fullerene-containing PNe; several of these DIBS have not previously been reported. Fullerenes larger
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Iyoda, Masahiko, Hideyuki Shimizu, Shinobu Aoyagi, Hiroshi Okada, Biao Zhou, and Yutaka Matsuo. "Structures and properties of Saturn-like complexes composed of oligothiophene macrocycle with methano[60]fullerene and [70]fullerene." Canadian Journal of Chemistry 95, no. 3 (2017): 315–19. http://dx.doi.org/10.1139/cjc-2016-0461.

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π-Expanded oligothienylene macrocycle with a large inner cavity incorporates fullerenes such as methano[60]fullerene (C61H2) and [70]fullerene (C70) inside to form Saturn-like complexes. Although the oligothiophene macrocycle weakly interacts with fullerenes in solution, it forms stable Saturn-like fullerene complexes in the solid state. X-ray analysis of the Saturn-like complexes exhibited short contacts between the sulfur atoms of the oligothiophene macrocycle and fullerene carbons, which hinder the rotation of fullerenes. As a result, the non-covalent interaction between the oligothiophene
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Dissertations / Theses on the topic "Fullerene"

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Dybek, Aneta. "Production and Characterisation of Fullerenes, Fullerene Derivatives and Fullerene-Based Electronic Devices." Thesis, Queen Mary, University of London, 2008. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.522327.

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Rathna, A. "Theoretical Studies Of Fullerenes And Fullerene Derivatives." Thesis, Indian Institute of Science, 1994. https://etd.iisc.ac.in/handle/2005/111.

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The detection of Ceo and Cro in 1985 and the subsequent development of a preparative procedure have opened up a new area of research in carbon chemistry. The study of physico-chemical properties of these molecules is currently being pursued with great interest. The goal of the present thesis is to provide simple generalization concerning the structure and bonding which would be of useful interpretive value in understanding the reactivity patterns. The stability of a large number of derivatives have been examined at uniform levels of semiempirical MO theories. The results are shown to be consis
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Rathna, A. "Theoretical Studies Of Fullerenes And Fullerene Derivatives." Thesis, Indian Institute of Science, 1994. http://hdl.handle.net/2005/111.

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The detection of Ceo and Cro in 1985 and the subsequent development of a preparative procedure have opened up a new area of research in carbon chemistry. The study of physico-chemical properties of these molecules is currently being pursued with great interest. The goal of the present thesis is to provide simple generalization concerning the structure and bonding which would be of useful interpretive value in understanding the reactivity patterns. The stability of a large number of derivatives have been examined at uniform levels of semiempirical MO theories. The results are shown to be consis
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Wessendorf, Florian. "Supramolecular fullerene-porphyrin architectures = Supramolekulare Fulleren-Porphyrin-Architekturen." kostenfrei, 2010. http://d-nb.info/1000613593/34.

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Mo^n, Dyfrig. "Fullerene crystallisation in Fullerene/Polymer bilayers." Thesis, Swansea University, 2014. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.678620.

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Peel, Jason Alexander. "The synthesis and characterisation of some new organometallic derivatives of [60]fullerene." Thesis, University of Reading, 1997. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.389639.

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Rahmer, Jürgen. "Electronic spin states in fullerides and endohedral fullerenes." [S.l. : s.n.], 2003. http://www.bsz-bw.de/cgi-bin/xvms.cgi?SWB10934928.

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Samoylova, Nataliya. "Cluster-based redox activity in Endohedral Metallofullerenes:." Doctoral thesis, Saechsische Landesbibliothek- Staats- und Universitaetsbibliothek Dresden, 2017. http://nbn-resolving.de/urn:nbn:de:bsz:14-qucosa-230132.

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Endohedral fullerenes are closed carbon shells encapsulating molecular or ionic species in their inner space. Obtained for the first time in 1985, endohedral metallofullerenes (EMFs) remain in focus of research for many years with a broad variety of metal atoms, endohedral cluster and cage sizes being reported. Electrochemical studies of endohedral metallofullerenes are of particular interest because of the more complex redox behavior in comparison to empty fullerenes. The EMF molecules can be considered as a combinations of positively charged cluster and negatively charged carbon shell “liga
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Duggan, Andrew Charles. "Fullerene intercalation chemistry." Thesis, University of Oxford, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.298749.

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Henry, Paul Francis. "Fullerene intercalation chemistry." Thesis, University of Oxford, 1997. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.363757.

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Books on the topic "Fullerene"

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C, Eklund P., and Rao Apparao M. 1961-, eds. Fullerene polymers and fullerene polymer composites. Springer, 2000.

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Andreas, Hirsch. The chemistry of the fullerenes. G. Thieme Verlag, 1994.

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Dettmann, Joachim. Fullerene. Birkhäuser Basel, 1994. http://dx.doi.org/10.1007/978-3-0348-5705-5.

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Eklund, Peter C., and Apparao M. Rao, eds. Fullerene Polymers and Fullerene Polymer Composites. Springer Berlin Heidelberg, 2000. http://dx.doi.org/10.1007/978-3-662-04269-4.

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B, Smith Amos, ed. Fullerene chemistry. Pergamon, 1996.

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N, Kramer Carl, ed. Fullerene research advances. Nova Science Publishers, 2007.

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Prassides, Kosmas, ed. Fullerene-Based Materials. Springer Berlin Heidelberg, 2004. http://dx.doi.org/10.1007/b84247.

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Campbell, Eleanor E. B. Fullerene Collision Reactions. Springer Netherlands, 2004.

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Andreoni, Wanda, ed. The Physics of Fullerene-Based and Fullerene-Related Materials. Springer Netherlands, 2000. http://dx.doi.org/10.1007/978-94-011-4038-6.

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Ōsawa, Eiji, ed. Perspectives of Fullerene Nanotechnology. Springer Netherlands, 2002. http://dx.doi.org/10.1007/978-94-010-9598-3.

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Book chapters on the topic "Fullerene"

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Kitagawa, Toshikazu, Yasujiro Murata, and Koichi Komatsu. "Fullerene Reactivity - Fullerene Cations and Open-Cage Fullerenes." In Carbon-Rich Compounds. Wiley-VCH Verlag GmbH & Co. KGaA, 2006. http://dx.doi.org/10.1002/3527607994.ch9.

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Hebard, A. F. "Fullerene and Fulleride Films." In Physics and Chemistry of Finite Systems: From Clusters to Crystals. Springer Netherlands, 1992. http://dx.doi.org/10.1007/978-94-017-2645-0_166.

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Dettmann, Joachim. "Der Fußball, der vom Himmel fiel." In Fullerene. Birkhäuser Basel, 1994. http://dx.doi.org/10.1007/978-3-0348-5705-5_1.

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Dettmann, Joachim. "Das ABC des Elements Kohlenstoff." In Fullerene. Birkhäuser Basel, 1994. http://dx.doi.org/10.1007/978-3-0348-5705-5_2.

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Dettmann, Joachim. "Was sind Cluster?" In Fullerene. Birkhäuser Basel, 1994. http://dx.doi.org/10.1007/978-3-0348-5705-5_3.

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Dettmann, Joachim. "Die Fulleren Story." In Fullerene. Birkhäuser Basel, 1994. http://dx.doi.org/10.1007/978-3-0348-5705-5_4.

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Dettmann, Joachim. "Richard Buckminster Fuller (1895 bis 1983)." In Fullerene. Birkhäuser Basel, 1994. http://dx.doi.org/10.1007/978-3-0348-5705-5_5.

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Dettmann, Joachim. "In Form — Symmetrie, Topologie, Strukturen." In Fullerene. Birkhäuser Basel, 1994. http://dx.doi.org/10.1007/978-3-0348-5705-5_6.

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Dettmann, Joachim. "Fullerenähnliche Mikroarchitekturen." In Fullerene. Birkhäuser Basel, 1994. http://dx.doi.org/10.1007/978-3-0348-5705-5_7.

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Dettmann, Joachim. "Chemie der Fullerene." In Fullerene. Birkhäuser Basel, 1994. http://dx.doi.org/10.1007/978-3-0348-5705-5_8.

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Conference papers on the topic "Fullerene"

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Marciu, D., C. Figura, S. Wang, et al. "Enhanced Degenerate Four-Wave Mixing in an Endohedral Metallofullerene Through Metal-to-Cage Charge-Transfer." In Organic Thin Films for Photonic Applications. Optica Publishing Group, 1997. http://dx.doi.org/10.1364/otfa.1997.the.15.

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Since the initial discovery and development of a technique for macroscopic preparation of the archetypal and most abundant fullerene C60, a wealth of fullerene-based structures have been produced including higher fullerenes, charge-transfer complexes, fullerene derivatives, superconducting exohedral-doped fullerenes, and carbon nanotubes. One of the most intriguing fullerene classes is the endohedral fullerene in which the spheroidal molecular structure is employed to encapsulate a small number of atoms (one to four) internal to the cage.1,2 Until recently, the difficult separation process of
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Kuzmany, H., J. Fink, M. Mehring, and S. Roth. "FULLERENES AND FULLERENE NANOSTRUCTURES." In International Winterschool on Electronic Properties of Novel Materials. WORLD SCIENTIFIC, 1996. http://dx.doi.org/10.1142/9789814530552.

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Shibahara, Masahiko, Tsubasa Shimizu, Nilson Kunioshi, and Hiroshi Takada. "Experimental Study on Fullerene Formation Process in Toluene Flame at Low Pressure Condition." In 2007 First International Conference on Integration and Commercialization of Micro and Nanosystems. ASMEDC, 2007. http://dx.doi.org/10.1115/mnc2007-21122.

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Polycyclic Aromatic Hydrocarbons generated in the combustion processes of fuel rich hydrocarbon flames are considered to be important precursors of soot that causes environmental pollution. On the other hand, in a combustion process under low pressure conditions, the generation of fullerenes which are one of large cage-shaped carbon clusters was reported. Combustion synthesis of fullerenes is expected to be one of the mass production methods of fullerenes and a premixed flame of toluene and oxygen is utilized in real mass production process of fullerenes. However, the fullerene formation mecha
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Marcy, H. O., M. J. Rosker, Tallis Y. Chang, J. Khoury, K. Hansen, and R. L. Whetten. "Near-Resonance, Time-Resolved Degenerate Four Wave Mixing Studies for Thin Films of C60 and C70 Fullerenes Using Femtosecond Optical Pulses." In Nonlinear Optics. Optica Publishing Group, 1992. http://dx.doi.org/10.1364/nlo.1992.ma6.

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The availability of gram-scale quantities of fullerenes allows for the study the of the physical properties of these unique molecules. The large number of highly polarizable electrons associated with fullerene molecules make them potentially attractive as nonlinear optical materials. Structural studies indicate that fullerenes are bound together in the solid state by relatively weak van der Waals forces. An enhancement of the nonlinear optical response for excitation near the band edge, similar to that observed for semiconductor clusters in passive glass matrices, may occur due to the relative
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Saika, Tatsuya, Youhei Sakita, and Masahiko Shibahara. "The Effect of the Residence Time in the High Temperature Field on the Fullerene and PAH Formation Mechanism." In ASME/JSME 2011 8th Thermal Engineering Joint Conference. ASMEDC, 2011. http://dx.doi.org/10.1115/ajtec2011-44543.

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Fullerenes were generated and observed in the combustion processes of hydrocarbon fuel under reduced pressure conditions however the fullerene formation mechanism from PAHs in fuel rich hydrocarbon flames under reduced pressure conditions has not been clarified yet. In the present study, the effects of the residence time in the high temperature reaction field were investigated experimentally and the effects of the residence time on the contents of fullerenes and PAHs were discussed. The experimental results showed that the contents of fullerenes as well as PAHs in the total soot collected from
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Ji, W., S. H. Tang, G. Q. Xu, H. S. O. Chan, S. C. Ng, and W. W. Ng. "Nonlinear Optical Response of Fullerene-doped Polymethyl Methacrylate Films." In Organic Thin Films for Photonic Applications. Optica Publishing Group, 1993. http://dx.doi.org/10.1364/otfa.1993.wd.18.

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Recently fullerenes (a mixture of C60 and C70) have received considerable attention because these molecules possess strong nonlinear-optical behaviour. Both optical limiting response [1] and photorefractive properties [2] of C60-doped polymers have been observed. In this article, we report the observation of a large third-order nonlinear optical susceptibility in fullerene-doped polymer thin films with nanosecond laser pulses and discuss the mechanism responsible for the observed nonlinear susceptibility.
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Robles Hernandez, Francisco C., and Goran Majkic. "Multi-Functional Fullerene Soot/Alumina Composites." In ASME 2012 International Mechanical Engineering Congress and Exposition. American Society of Mechanical Engineers, 2012. http://dx.doi.org/10.1115/imece2012-89865.

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Here are presented the results of characterization and mechanical testing of composites consisting of alumina matrix reinforced with fullerene soot. The composites were manufactured by mechanical milling, sonication, and spark plasma sintering. Small amounts of Ni and Ti were added as catalyst to in situ synthesize complex carbon structures during thermomechanical processing. Some of the carbon in the soot showed phase transformations to diamond, fullerite, graphene-like particles, etc. that act as effective reinforcement. This resulted in significant improvements in fracture toughness in full
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Nicodemos, Diego S., Sulamita Klein, and Luerbio Faria. "Frustração de Arestas em (3, 6)-Fullerenes." In I Encontro de Teoria da Computação. Sociedade Brasileira de Computação - SBC, 2018. http://dx.doi.org/10.5753/etc.2016.9765.

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Grafos (3, 6)-fullerenes são grafos planares, 3-conexos, cúbicos cujas faces têm tamanho 3 ou 6. Determinar o menor número de arestas a serem deletadas de um grafo de modo a obter um subgrafo gerador bipartido é conhecido na literatura [Doslic and Vukicevic 2007] como o Problema de Frustração de Arestas. Neste trabalho, abordamos o Problemas da Frustração de Arestas em grafos (3, 6)- fullerenes. Mostramos que todo grafo (3, 6)-fullerene com n vértices torna-se bipartido após a retirada de no máximo q4 3n arestas.&#x0D;
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Guillard, Tony, Gilles Flamant, and Daniel Laplaze. "Heat, Mass and Fluid Flow in a Solar Reactor for Fullerene Synthesis." In ASME 2001 Solar Engineering: International Solar Energy Conference (FORUM 2001: Solar Energy — The Power to Choose). American Society of Mechanical Engineers, 2001. http://dx.doi.org/10.1115/sed2001-161.

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Abstract A 2 kW solar furnace was used to vaporize a graphite target for fullerene synthesis. Tests were performed in a wide range of vaporization rates (0.1–4 g/h), under variable pressure and argon flow rate. Experimental results are interpreted with numerical simulation to define key parameters for large-scale synthesis of fullerenes with solar energy. We demonstrate that the vaporization process is controlled by diffusion in the temperature and pressure ranges 3000–3700 K and 70–250 hPa respectively. Experimental data and numerical simulation suggest that in the solar reactor, fullerene yi
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Cui, Liu, Yanhui Feng, Xinxin Zhang, and Wei Li. "Molecular Dynamic Simulation of Thermal Conductivity of Carbon Nano-Peapods." In ASME 2013 Heat Transfer Summer Conference collocated with the ASME 2013 7th International Conference on Energy Sustainability and the ASME 2013 11th International Conference on Fuel Cell Science, Engineering and Technology. American Society of Mechanical Engineers, 2013. http://dx.doi.org/10.1115/ht2013-17589.

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The thermal conductivity of carbon nano-peapods, carbon nanotube (10,10) filled with fullerene molecules, is investigated by Equilibrium Molecular Dynamic Simulation based on Green-Kubo’s equation. Carbon nano-peapods structures are built by HyperChem. C-C bonding interactions are determined by the AIREBO potential, and the Lennard-Jones potential is used for expressing nonbonding interactions. The results show that filled fullerenes lead to the increment of thermal conductivity, relative to the bare carbon nanotubes. The thermal conductivity of carbon nano-peapods always increases with the ri
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Reports on the topic "Fullerene"

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Kwei, G. H., J. D. Jorgensen, J. E. Schirber, and B. Morosin. Rare-gas intercalation into fullerene interstices. Office of Scientific and Technical Information (OSTI), 1995. http://dx.doi.org/10.2172/132650.

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McElvany, Stephen W., Mark M. Ross, Nancy S. Goroff, and Francos Diederich. Cyclocarbon Coalescence: Mechanisms for Tailormade Fullerene Formation. Defense Technical Information Center, 1993. http://dx.doi.org/10.21236/ada265489.

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Rinzler, A. G., J. H. Hafner, P. Nilolaev, D. T. Colbert, and R. E. Smalley. Field emission and growth of fullerene nanotubes. Office of Scientific and Technical Information (OSTI), 1994. http://dx.doi.org/10.2172/650265.

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McBranch, D., R. Kohlman, V. Klimov, et al. New fullerene-based mixed materials: Synthesis and characterization. Office of Scientific and Technical Information (OSTI), 1998. http://dx.doi.org/10.2172/676884.

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Zagitova, Liana, Ilya Abramov, and Svetlana Gainanova. Levofloxacin enantioselective voltammetric sensing based on functionalized fullerene. Peeref, 2023. http://dx.doi.org/10.54985/peeref.2307p8077405.

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Lawson, Del R., Daniel L. Feldheim, Colby A. Foss, et al. Near-IR Absorption Spectra for the C70 Fullerene Anions. Defense Technical Information Center, 1992. http://dx.doi.org/10.21236/ada253658.

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Cahill, P. A., C. C. Henderson, C. M. Rohlfing, et al. Fullerene-based materials research and development. LDRD final report. Office of Scientific and Technical Information (OSTI), 1995. http://dx.doi.org/10.2172/83027.

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Biener, M. M. Fullerene-grafted 3D graphene as electrical energy storage material. Office of Scientific and Technical Information (OSTI), 2019. http://dx.doi.org/10.2172/1574619.

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Schirber, J. E., R. A. Assink, B. Morosin, D. A. Loy, and G. A. Carlson. LDRD final report on gas separation by fullerene membranes. Office of Scientific and Technical Information (OSTI), 1996. http://dx.doi.org/10.2172/270715.

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Brosha, E. L., J. R. Davey, F. H. Garzon, and S. Gottesfeld. The development of a fullerene based hydrogen storage system. Office of Scientific and Technical Information (OSTI), 1998. http://dx.doi.org/10.2172/677006.

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