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Journal articles on the topic 'Fullerene'

Author: Grafiati

Published: 4 June 2021

Last updated: 25 July 2025

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1

Lin, Hao-Sheng, and Yutaka Matsuo. "Functionalization of [60]fullerene through fullerene cation intermediates." Chemical Communications 54, no. 80 (2018): 11244–59. http://dx.doi.org/10.1039/c8cc05965a.

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Fullerene cations, namely [60]fullerene radical cation (C<sub>60</sub>˙<sup>+</sup>) and organo[60]fullerenyl cation (RC<sub>60</sub><sup>+</sup>), open paths for the efficient derivatization of a great variety of fullerenes.

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2

Lun-Fu, Aleksandr V., Alexey M. Bubenchikov, Mikhail A. Bubenchikov, and Vyacheslav A. Ovchinnikov. "Numerical Simulation of Interaction between Kr+ Ion and Rotating C60 Fullerene towards for Nanoarchitectonics of Fullerene Materials." Crystals 11, no. 10 (2021): 1204. http://dx.doi.org/10.3390/cryst11101204.

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Dynamics of charged fullerene in a surface layer of fullerite is studied under the influence of neutral or charged particles of the gas phase surrounding the fullerite material. The translational displacements of the nodes of the crystal lattice structure are determined by the equations of motion of the centers of mass of fullerenes. Central fullerene, which is described as a discrete set of sixty carbon atoms, plays a special role in the presented mathematical model. Angular oscillations and rotations of the central fullerene are described by the dynamic Euler equations. All other fullerenes

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3

Pacor, Sabrina, Alberto Grillo, Luka Đorđević, et al. "Effects of Two Fullerene Derivatives on Monocytes and Macrophages." BioMed Research International 2015 (2015): 1–13. http://dx.doi.org/10.1155/2015/915130.

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Two fullerene derivatives (fullerenes1and2), bearing a hydrophilic chain on the pyrrolidinic nitrogen, were developed with the aim to deliver anticancer agents to solid tumors. These two compounds showed a significantly different behaviour on human neoplastic cell linesin vitroin respect to healthy leukocytes. In particular, the pyrrolidinium ring on the fullerene carbon cage brings to a more active compound. In the present work, we describe the effects of these fullerenes on primary cultures of human monocytes and macrophages, two kinds of immune cells representing the first line of defence i

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4

Suvorov, S. V., A. V. Severiuchin, and A. V. Vakhrushev. "The effect of the angle of «meeting» of fullerite C60 with a solid substrate on the deposition process." PNRPU Mechanics Bulletin, no. 3 (December 15, 2020): 90–97. http://dx.doi.org/10.15593/perm.mech/2020.3.09.

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Carbon forms a large number of allotropic forms, one of which is fullerene. Fullerene is a convex closed polyhedron with carbon atoms at its vertices. The most common is fullerene, consisting of 60 carbon atoms and designated - C60. In turn, fullerenes are able to agglomerate, forming a molecular crystal - fullerite. In the interaction of fullerite C60 with a solid, it is possible to deposit on the surface of the body both whole fullerite and the fullerenes that form it. The interaction process in the C60 fullerite system - the substrate of a solid, and then on - the fullerite - substrate syst

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5

Bubenchikov, Alexey, Mikhail Bubenchikov, Dmitriy Mamontov, and Alexandr Lun-Fu. "Md-Simulation of Fullerene Rotations in Molecular Crystal Fullerite." Crystals 9, no. 10 (2019): 496. http://dx.doi.org/10.3390/cryst9100496.

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The present paper describes rotations of C60 fullerene molecules in the solid phase of a fullerite. The conducted studies show that these relatively large molecules rotate according to the same laws as macroscopic bodies, i.e., according to the laws of classical mechanics. The performed calculations confirm that fullerene rotations do not cause friction. We suggest a method for a strong increase in the internal energy of the material that does not lead to its destruction. It is theoretically shown that in standard fullerite, in the absence of electric and magnetic fields, fullerene rotations o

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6

Sabirov, Denis Sh. "Polarizability as a landmark property for fullerene chemistry and materials science." RSC Adv. 4, no. 85 (2014): 44996–5028. http://dx.doi.org/10.1039/c4ra06116k.

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The review summarizes data on dipole polarizability of fullerenes and their derivatives, covering the most widespread classes of fullerene-containing molecules (fullerenes, fullerene exohedral derivatives, fullerene dimers, endofullerenes, fullerene ions, and derivatives with ionic bonds).

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7

Chen, Guoping, Lok Kumar Shrestha, and Katsuhiko Ariga. "Zero-to-Two Nanoarchitectonics: Fabrication of Two-Dimensional Materials from Zero-Dimensional Fullerene." Molecules 26, no. 15 (2021): 4636. http://dx.doi.org/10.3390/molecules26154636.

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Nanoarchitectonics of two-dimensional materials from zero-dimensional fullerenes is mainly introduced in this short review. Fullerenes are simple objects with mono-elemental (carbon) composition and zero-dimensional structure. However, fullerenes and their derivatives can create various types of two-dimensional materials. The exemplified approaches demonstrated fabrications of various two-dimensional materials including size-tunable hexagonal fullerene nanosheet, two-dimensional fullerene nano-mesh, van der Waals two-dimensional fullerene solid, fullerene/ferrocene hybrid hexagonal nanosheet,

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8

M.M., Kasumov. "Structural Changes of C60, C70 Mixture Fullerite at Heating by the Action of Pulsed Laser Beam." Chemistry Research Journal 2, no. 6 (2017): 194–96. https://doi.org/10.5281/zenodo.13941977.

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Structural transformations take place in the near-surface layer during the recording of fullerene mass spectrum under the action of laser beam. The changes are associated with the sequential degradation of fullerite on the scheme: crystallites →fullerenes→carbon clusters, soot.

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9

Manchado, A., J. J. Díaz-Luis, D. A. García-Hernández, and F. Cataldo. "A Catalog of Diffuse Interstellar Bands in Fullerene-Containing Planetary Nebulae." Proceedings of the International Astronomical Union 9, S297 (2013): 223–25. http://dx.doi.org/10.1017/s1743921313015901.

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AbstractLarge fullerenes and fullerene-based molecules have been proposed as carriers of diffuse interstellar bands (DIBs). The recent detection of the most common fullerenes (C60 and C70) around some Planetary Nebulae (PNe) now enable us to study the DIBs in fullerene-rich space environments. We have studied the presence of DIBs in the optical spectra (~3300-9400 Å) of two fullerene-containing PNe (Tc 1 and M 1-20). Special attention is given to DIBs which are found to be unusually intense in fullerene-containing PNe; several of these DIBS have not previously been reported. Fullerenes larger

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10

Iyoda, Masahiko, Hideyuki Shimizu, Shinobu Aoyagi, Hiroshi Okada, Biao Zhou, and Yutaka Matsuo. "Structures and properties of Saturn-like complexes composed of oligothiophene macrocycle with methano[60]fullerene and [70]fullerene." Canadian Journal of Chemistry 95, no. 3 (2017): 315–19. http://dx.doi.org/10.1139/cjc-2016-0461.

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π-Expanded oligothienylene macrocycle with a large inner cavity incorporates fullerenes such as methano[60]fullerene (C61H2) and [70]fullerene (C70) inside to form Saturn-like complexes. Although the oligothiophene macrocycle weakly interacts with fullerenes in solution, it forms stable Saturn-like fullerene complexes in the solid state. X-ray analysis of the Saturn-like complexes exhibited short contacts between the sulfur atoms of the oligothiophene macrocycle and fullerene carbons, which hinder the rotation of fullerenes. As a result, the non-covalent interaction between the oligothiophene

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11

Cataldo, F., D. A. García-Hernández, A. Manchado, and S. Iglesias-Groth. "Spectroscopy of Fullerenes, Fulleranes and PAHs in the UV, Visible and Near Infrared Spectral Range." Proceedings of the International Astronomical Union 9, S297 (2013): 294–96. http://dx.doi.org/10.1017/s1743921313016025.

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AbstractThe spectra of fullerenes C60 and C70, higher fullerenes C76, C78 and C84 and hydrogenated fullerenes (fulleranes) were studied in laboratory in the UV and in the visible spectral range and could be used for searching and recognizing these molecules in space. Furthermore, the radical cation spectra of all the mentioned fullerene series and also of a series of large and very large polycyclic aromatic hydrocarbons (PAHs) were generated in the laboratory and studied in the near infrared spectral range.

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12

Matsuo, Yutaka, and Hao-Sheng Lin. "(Invited) Evaporable Fullerene-Fused Ketone Via One-Step Direct Oxidation of Alkoxy to Ketone: Fullerene As a Redox Active Pendant." ECS Meeting Abstracts MA2022-01, no. 11 (2022): 812. http://dx.doi.org/10.1149/ma2022-0111812mtgabs.

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We developed a direct oxidation reaction from a methoxy group to a keto group using a mild oxidizing agent with the aid of an oxidizable fullerene pendant. By using this key reaction, we developed a fullerene derivative that is stable even at high temperatures of 400 deg-C or higher and can be used for vacuum deposition to make thin films in organic electronic devices. A highly efficient CuBr2 promoted one-step direct oxidation of alkoxy indano[60]fullerenes to [60]fullerene-fused ketones is showcased. It is shown that the fullerene can behave as an electron-pool controlling the electron trans

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13

Chen, Guoping, Biswa Nath Bhadra, Linawati Sutrisno, Lok Kumar Shrestha, and Katsuhiko Ariga. "Fullerene Rosette: Two-Dimensional Interactive Nanoarchitectonics and Selective Vapor Sensing." International Journal of Molecular Sciences 23, no. 10 (2022): 5454. http://dx.doi.org/10.3390/ijms23105454.

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The simplicity of fullerenes as assembled components provides attractive opportunities for basic understanding in self-assembly research. We applied in situ reactive methods to the self-assembly process of C60 molecules with melamine/ethylenediamine components in solution, resulting in a novel type of fullerene assemblies, micron-sized two-dimensional, amorphous shape-regular objects, fullerene rosettes. ATR–FTIR spectra, XPS, and TGA results suggest that the melamine/ethylenediamine components strongly interact and/or are covalently linked with fullerenes in the fullerene rosettes. The broad

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14

Athira.A.S, S.M.Sandhya A.S William Arputha Sundar. "A REVIEW ON FULLERENE EARTH." INDO AMERICAN JOURNAL OF PHARMACEUTICAL SCIENCES 05, no. 11 (2018): 11932–42. https://doi.org/10.5281/zenodo.1484422.

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<em>A fullerene is an allotrope of carbon in the form of a hollow sphere or in many other shapes. Spherical fullerenes are also referred to as Buckminster fullerenes or buckyballs. Cylindrical fullerenes are also called as buckey tubes. </em><em>Fullerenes composed of less than 300 carbon atoms, or endohedral fullerenes, are commonly known as “buckyballs” and include the most common fullerene, buckminsterfullerene, C<sub>60</sub>. Giant fullerenes, or fullerenes with more than 300 carbon atoms, include single-shelled or multi-shelled carbon structures, onions, and nanotubes. The fi

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15

Barrera, E. V., J. Sims, and D. L. Callahan. "Development of fullerene-reinforced aluminum." Journal of Materials Research 10, no. 2 (1995): 366–71. http://dx.doi.org/10.1557/jmr.1995.0366.

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Powder metallurgy and casting have been used to produce aluminum with 1.3, 4, and 8 vol. % fullerene additions. Fullerene extract was mixed with Al and heat-treated to obtain various levels of dispersion of the fullerenes. Intergranular dispersion of stable fullerenes was accomplished by both powder metallurgy and casting; however, x-ray diffraction indicated the formation of some Al4C3. Homogeneous dispersion did not occur because of limited diffusion in the solid state or limited solubility of fullerene in Al in the liquid state. Enhancements in hardness over that for Al were observed yet we

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16

Pérez, Emilio M., and Nazario Martín. "Molecular tweezers for fullerenes." Pure and Applied Chemistry 82, no. 3 (2010): 523–33. http://dx.doi.org/10.1351/pac-con-09-09-27.

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The search for molecular receptors capable of forming stable associates with fullerenes is a very active field of research in fullerene chemistry, with the purification from fullerite and the self-assembly of nanoscale electronic devices as driving forces. The construction of bivalent, tweezer-like receptors featuring two recognizing units connected through a spacer is one of the most successful design strategies employed in this field. Here, we present an overview of the most significant examples of these “molecular tweezers” for fullerenes.

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17

Nisoh, Nililla, Viwan Jarerattanachat, Mikko Karttunen, and Jirasak Wong-ekkabut. "Fullerenes’ Interactions with Plasma Membranes: Insight from the MD Simulations." Biomolecules 12, no. 5 (2022): 639. http://dx.doi.org/10.3390/biom12050639.

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Understanding the interactions between carbon nanoparticles (CNPs) and biological membranes is critically important for applications of CNPs in biomedicine and toxicology. Due to the complexity and diversity of the systems, most molecular simulation studies have focused on the interactions of CNPs and single component bilayers. In this work, we performed coarse-grained molecular dynamic (CGMD) simulations to investigate the behaviors of fullerenes in the presence of multiple lipid components in the plasma membranes with varying fullerene concentrations. Our results reveal that fullerenes can s

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18

Sokolovska, Lība, Maksims Čistjakovs, Alīna Sultanova, and Modra Murovska. "Aqueous C60 Fullerene Solution Effects on Cell Viability." Proceedings of the Latvian Academy of Sciences. Section B. Natural, Exact, and Applied Sciences. 75, no. 2 (2021): 86–91. http://dx.doi.org/10.2478/prolas-2021-0014.

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Abstract Fullerenes are carbon nanoparticles with the ability to quench reactive oxygen species. The biomedical potential of fullerenes is diminished by their low solubility in water, but many approaches have been developed to bypass this problem, like chemical modification of the carbon cage and the use of the solvent exchange method to transfer fullerenes from one solvent to the other. These two approaches were used in this study. Carboxylated fullerene aqueous solution was acquired using solvent exchange method transferring fullerene nanoparticles (C60) from toluene to water. Effects of var

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Khamatgalimov, Ayrat R., and Valeri I. Kovalenko. "Substructural Approach for Assessing the Stability of Higher Fullerenes." International Journal of Molecular Sciences 22, no. 7 (2021): 3760. http://dx.doi.org/10.3390/ijms22073760.

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This review describes the most significant published results devoted to the study of the nature of the higher fullerenes stability, revealing of correlations between the structural features of higher fullerene molecules and the possibility of their producing. A formalization of the substructure approach to assessing the stability of higher fullerenes is proposed, which is based on a detailed analysis of the main structural features of fullerene molecules. The developed substructure approach, together with the stability of the substructures constituting the fullerene molecule, helps to understa

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20

Konarev, Dmitri V., Salavat S. Khasanov, Gunzi Saito, and Rimma N. Lyubovskaya. "Fullerene complexes with cobalt(II) tetraphenylporphyrin: from molecular to ionic crystals." Journal of Porphyrins and Phthalocyanines 07, no. 12 (2003): 801–6. http://dx.doi.org/10.1142/s1088424603000999.

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The complexes of cobalt(II) tetraphenylporphyrin ( Co II TPP ) with fullerenes C 60, C 70 and C 60( CN )2 are presented. It is shown that Co II TPP forms complexes with fullerenes in different solvents: [ Co II TPP •fullerene•solvent] ( solvent = C 6 H 6, C 6 H 5 Me , C 6 H 4 Cl 2, CS 2, CHCl 3). The use of additional donors ( Cp 2 Fe , Cr 0( C 6 H 6)2, and TDAE ) in the synthesis of Co II TPP /fullerene complexes allows one to obtain multi-component complexes ranging from neutral [( Co II TPP • Py )2• Cp 2 Fe • fullerene • solvent ] to ionic [ Co II TPP •( D 2•+)•( fullerene •−)• solvent ] (

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21

Silant'ev A. V. "Energy Spectrum and Optical Absorption Spectraof endohedral Fullerenes Lu-=SUB=-3-=/SUB=-N\@C-=SUB=-80-=/SUB=- and Y-=SUB=-3-=/SUB=-N\@C-=SUB=-80-=/SUB=-within the Hubbard Model." Physics of the Solid State 64, no. 2 (2022): 287. http://dx.doi.org/10.21883/pss.2022.02.52978.213.

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Anticommutator Green's functions and energy spectra of fullerene C80,endohedral fullerenes Lu3N@C80 and Y3N@C80 with the Ih symmetry groups have been obtained in an analytical form within the Hubbard model and static fluctuation approximation. The energy states have been classified using the methods of group theory, and the allowed transitions in the energy spectra of molecules C80, Lu3N@C80 andY3N@C80 have been determined. On the basis ofthese spectra, an interpretation of experimentally observed opticalabsorption bands endohedral fullerenes Lu3N@C80 andY3N@C80. Keywords: Hubbard model, Green

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22

Yao, Sai, Xingzhong Yuan, Longbo Jiang, Ting Xiong, and Jin Zhang. "Recent Progress on Fullerene-Based Materials: Synthesis, Properties, Modifications, and Photocatalytic Applications." Materials 13, no. 13 (2020): 2924. http://dx.doi.org/10.3390/ma13132924.

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Solar light is an inexpensive energy source making up for energy shortage and solving serious environmental problems. For efficient utilization of solar energy, photocatalytic materials have attracted extensive attention over the last decades. As zero-dimensional carbon nanomaterials, fullerenes (C60, C70, etc.) have been extensively investigated for photocatalytic applications. Due to their unique properties, fullerenes can be used with other semiconductors as photocatalyst enhancers, and also as novel photocatalysts after being dispersed on non-semiconductors. This review summarizes fulleren

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23

Keszler, Anna Mária, Éva Kováts, Eszter Bódis, Zoltán Károly, and János Szépvölgyi. "Effect of Metallic and Non-Metallic Additives on the Synthesis of Fullerenes in Thermal Plasma." Condensed Matter 7, no. 3 (2022): 44. http://dx.doi.org/10.3390/condmat7030044.

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The effect of metallic (Fe, Cu, Co, Ni, Ti) and non-metallic additives (Si, B) on the formation of fullerenes from graphite powders was studied in radiofrequency (RF) thermal plasma. The main component of the synthesized fullerene mixtures was C60, but higher fullerenes (C70, C82, and C84) could be detected as well. Fe and Cu additives increased the fullerene content in the soot. In contrast, the fullerene formation decreased in the presence of Ti, Si, and B as compared to the synthesis without additives. However, Ti and B addition enhanced the formation of higher fullerenes. We provide experi

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24

HASHIZUME, T., and T. SAKURAI. "FULLERENES ADSORPTION ON Cu(111) AND Ag(111) SURFACES." Surface Review and Letters 03, no. 01 (1996): 905–13. http://dx.doi.org/10.1142/s0218625x96001637.

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Initial stage adsorption and film growth of C 60, C 70, C 60(x) C 70(1−x), and Sc 2@ C 84 fullerene molecules on Cu (111) and Ag (111) surfaces have been investigated by field-ion scanning tunneling microscopy. Fullerene molecules are mobile on the terrace and initially segregate to the step edges. A well-ordered monolayer films form with a close-packed arrangement upon annealing the fullerence-covered surfaces. The (4×4) phases form in the case of the C 60, C 70, and C 60(x) C 70(1−x) adsorption on the Cu (111)-(1×1) surface, indicating a strong interaction between the Cu substrate and fuller

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25

Blagov, Maksim A., Nataliya G. Spitsina та Sergei V. Konovalikhin. "CO-CRYSTALLIZATION OF C60 AND С70 FULLERENES IN CRYSTAL-SOLVATE [(C70)X+(С60)Y]• TMTSeF•2(C6H6) (х+у=3)". IZVESTIYA VYSSHIKH UCHEBNYKH ZAVEDENIY KHIMIYA KHIMICHESKAYA TEKHNOLOGIYA 59, № 9 (2018): 21. http://dx.doi.org/10.6060/tcct.20165909.3y.

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The compexation of (С70/C60) fullerenes with organic p-donor of electrons tetramethyl-(tetra selenium)fulvalene (TMTSeF) in benzene (С6Н6) was studied. Comparison of experimental and calculated X-ray patterns showed that in the investigated single crystals of [(C70)x+(С60)y]· TMTSeF·2(C6H6) (х+у=3) (1) С70 and C60 fullerens are co-crystallized. IR spectral data and electroconductivity of 1 indicate the absence of the charge transfer on fullerene molecule for complexes under study.

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Piotrovsky, Levon B., Elena V. Litasova, and Marina A. Dumpis. "Why do we need fullerenes today?" Reviews on Clinical Pharmacology and Drug Therapy 17, no. 2 (2019): 5–15. http://dx.doi.org/10.17816/rcf1725-15.

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The review focuses on the possibilities and prospects of the use of fullerenes and their derivatives in cosmetics, the only industrial area where fullerenes have found practical application today. Based on the literary data and the results of their own experiments, the authors substantiate the safety of using fullerene for living organisms, as well as the usefulness of introducing fullerene as antioxidant in cosmetic compositions. Other useful properties of fullerene used in cosmetics and dermatology are discussed.

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27

Muz, İskender. "Fluoroquinolone Antibiotic Adsorption on the Functional C70 Fullerenes: A Computational Insight on Adsorbent Applications." Bitlis Eren Üniversitesi Fen Bilimleri Dergisi 14, no. 1 (2025): 385–97. https://doi.org/10.17798/bitlisfen.1592320.

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Fluoroquinolone (FQ) adsorption on functional (Ca-, Fe-, Mg- and Zn-doped) C70 fullerenes was investigated for the first time by density functional theory (DFT). Mg, Ca, Fe, and Zn doping were found to enhance sensitivity to the FQ. The adsorption energies of functional C70 fullerenes after the FQ adsorption were found in the range of 23 – 37 kcal.mol-1. The UV-Vis spectra after the FQ adsorption showed a red shift in Ca- and Fe-doped C70 fullerenes but indicated a blue shift in Mg- and Zn-doped C70 fullerenes. The FQ adsorption significantly lowered the LUMOs in the Fe-doped C70 fullerene. Th

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Silant'ev A. V. "Energy Spectrum and Optical Absorption Spectra of endohedral Fullerenes Lu-=SUB=-3-=/SUB=-N\@C-=SUB=-80-=/SUB=- and Y-=SUB=-3-=/SUB=-N\@C-=SUB=-80-=/SUB=- within the Hubbard Model." Physics of the Solid State 64, no. 2 (2022): 287. http://dx.doi.org/10.21883/pss.2022.02.53979.213.

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Anticommutator Green's functions and energy spectra of fullerene C80, endohedral fullerenes Lu3N@C80 and Y3N@C80 with the Ih symmetry groups have been obtained in an analytical form within the Hubbard model and static fluctuation approximation. The energy states have been classified using the methods of group theory, and the allowed transitions in the energy spectra of molecules C80, Lu3N@C80 and Y3N@C80 have been determined. On the basis of these spectra, an interpretation of experimentally observed optical absorption bands endohedral fullerenes Lu3N@C80 and Y3N@C80. Keywords: Hubbard model,

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Katin, Konstantin P., Alexey I. Kochaev, Savas Kaya, Fadoua El-Hajjaji, and Mikhail M. Maslov. "Ab Initio Insight into the Interaction of Metal-Decorated Fluorinated Carbon Fullerenes with Anti-COVID Drugs." International Journal of Molecular Sciences 23, no. 4 (2022): 2345. http://dx.doi.org/10.3390/ijms23042345.

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We theoretically investigated the adsorption of two common anti-COVID drugs, favipiravir and chloroquine, on fluorinated C60 fullerene, decorated with metal ions Cr3+, Fe2+, Fe3+, Ni2+. We focused on the effect of fluoridation on the interaction of fullerene with metal ions and drugs in an aqueous solution. We considered three model systems, C60, C60F2 and C60F48, and represented pristine, low-fluorinated and high-fluorinated fullerenes, respectively. Adsorption energies, deformation of fullerene and drug molecules, frontier molecular orbitals and vibrational spectra were investigated in detai

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Uchida, Noriyuki, Masayoshi Yanagi, and Hiroki Hamada. "Fullerene Nanoparticles Using Technol PG for Inexpensive Preparation." Natural Product Communications 17, no. 7 (2022): 1934578X2211155. http://dx.doi.org/10.1177/1934578x221115556.

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Fullerene has attracted much attention for applications in biomaterials because of its high antioxidant activity. In this study, C60 and C70 fullerenes were mixed with a commercially available anionic phospholipid mixture, Technol PG, and sodium cholate, resulting in effective dispersion of the fullerenes to give small-sized fullerene nanoparticles.

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Loktev, V. M. "Doped fullerite–the first three-dimensional organic superconductor (review)." Soviet Journal of Low Temperature Physics 18, no. 3 (1992): 149–64. https://doi.org/10.1063/10.0033109.

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The results of investigations of fullerene (the C60 molecule), solid fullerene (fullerite), and doped fullerite are surveyed. The metallization (insulator–metal transition) of fullerite by doping with alkali metals and the mechanisms of the resulting superconductivity are discussed.

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32

Zhen, Junfeng, Weiwei Zhang, Yuanyuan Yang, and Qingfeng Zhu. "Laboratory study on the fullerene–PAH-derived cluster cations in the gas phase." Monthly Notices of the Royal Astronomical Society 490, no. 3 (2019): 3498–507. http://dx.doi.org/10.1093/mnras/stz2680.

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ABSTRACT It is possible that fullerene–polycyclic aromatic hydrocarbon (PAH) clusters or associations of fullerenes with PAHs contain a large fraction of interstellar fullerenes in the interstellar medium. Herein, we report the formation and photofragmentation behaviour of fullerene–PAH derivatives, fullerene/9-vinylanthracene (C16H12) and fullerene/9-methylanthracene (C15H12) cluster cations. Experiments are carried out using a quadrupole ion trap in combination with time-of-flight mass spectrometry in the gas phase. The results show that fullerene (C60)/9-vinylanthracene (e.g. [(C16H12)3C60]

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Kintigh, Jeremy, Jonathan B. Briggs, Kristine Letourneau, and Glen P. Miller. "Fulleranes produced via efficient polyamine hydrogenations of [60]fullerene, [70]fullerene and giant fullerenes." Journal of Materials Chemistry 17, no. 44 (2007): 4647. http://dx.doi.org/10.1039/b709354c.

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Powell, W. H., F. Cozzi, G. P. Moss, C. Thilgen, R. J. R. Hwu, and A. Yerin. "Nomenclature for the C60-Ih and C70-D5h(6) fullerenes (IUPAC Recommendations 2002)." Pure and Applied Chemistry 74, no. 4 (2002): 629–95. http://dx.doi.org/10.1351/pac200274040629.

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Fullerenes are a new allotrope of carbon characterized by a closed-cage structure consisting of an even number of three-coordinate carbon atoms devoid of hydrogen atoms. This class was originally limited to closed-cage structures with 12 isolated five-membered rings, the rest being six-membered rings. Although it was recognized that existing organic ring nomenclature could be used for these structures, the resulting names would be extremely unwieldy and inconvenient for use. At the same time it was also recognized that established organic nomenclature principles could be used, or adapted, to p

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35

Dolmatov, Valeriy K., and Steven T. Manson. "A Glimpse into Photodetachment Spectra of Giant and Nested Fullerene Anions." Atoms 10, no. 4 (2022): 99. http://dx.doi.org/10.3390/atoms10040099.

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We focus on the study of the photodetachment of bare, i.e., single-cage (CN)− as well as nested (multi-cage) (CN@CM@…)− singly charged fullerene anions. We calculate the attached electron’s wavefunctions, energies, oscillator strengths and photodetachment cross sections of the C60−, C240−, C540−, (C60@C240)−, (C60@C540)−, (C240@C540)− and (C60@C240@C540)− fullerene anions, where the attached electron is captured into the ground s-state by the resultant external field provided by all fullerene cages in the anion. The goal is to gain insight into the changes in behavior ofphotodetachment of this

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36

Wang, C. Z., B. L. Zhang, C. H. Xu, C. T. Chan, and K. M. Ho. "STRUCTURES AND STABILITIES OF CARBON FULLERENES." International Journal of Modern Physics B 06, no. 23n24 (1992): 3833–38. http://dx.doi.org/10.1142/s0217979292001894.

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The structures and stabilities of carbon fullerenes C n( n =20–94) are studied with tight-binding molecular dynamics in combination with a new scheme for generating energetically favorable fullerene networks. Magic numbers for fullerene formation energy are observed at n =60, 70 and 84. The experimental observation of the more abundant fullerenes is related to the fragmentation stabilities and chemical reactivities of the fullerenes obtained from our calculations.

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37

Jeon, Il, Han-Young Woo, Kyusun Kim, and Ziang Wu. "(Digital Presentation) Homogeneously Miscible Fullerene Inducing Vertical Gradient in Perovskite Thin-Film Towards Highly Efficient Solar Cells." ECS Meeting Abstracts MA2022-01, no. 1 (2022): 140. http://dx.doi.org/10.1149/ma2022-011140mtgabs.

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Fullerene-based n-type charge-collecting materials have emerged as a solution to high-performance perovskite solar cells. However, their application to perovskite solar cells was limited in the device architecture and only a small amount of fullerene additives could be introduced to the device system, because of the immiscibility of the fullerene species with polar solvents. To overcome this, triethylene glycol monomethyl ether chain-attached fullerene derivatives are synthesized and applied to normal-type perovskite solar cells. The newly synthesized fullerenes exhibit excellent solubility in

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38

Ma, Yue, and Yoko Yamakoshi. "(Invited, Digital Presentation) Aggregation Switchable Fullerene-Peptides Conjugates." ECS Meeting Abstracts MA2022-01, no. 11 (2022): 810. http://dx.doi.org/10.1149/ma2022-0111810mtgabs.

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Intensive research has been applied on chemical functionalization of fullerenes over the past decades, aiming at utilizing their broad availabilities in chemical biology field. Chemical moieties was induced to improve their water solubility and thus enhance their properties or interaction with biomolecules. In our previous study, we reported the synthesis of fullerene-PEG conjugates and demonstrated their ability for photoinduced DNA damage and ROS generation under visible light irradiation. In this work, we report a water-soluble fullerene derivative by constructing a fullerene-peptide conjug

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39

Farmanzade, Davood, and Leila Tabari. "Characterization of the fullerene end-functionalized ZnO nanotube: A computational study." Journal of Theoretical and Computational Chemistry 15, no. 04 (2016): 1650031. http://dx.doi.org/10.1142/s0219633616500310.

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The electronic and field emission properties of the fullerene end-functionalized zinc oxide nanotube (ZnONT) are investigated by density functional theory (DFT) to search for novel field emitter nano material. The interaction energies of ZnONT/fullerenes complexes gradually increase, with increasing the nanotube lengths which indicate that ZnONTs with higher lengths could improve the stability of the complexes. The band gaps of connected construction of fullerene molecules with ZnONTs gradually reduced by increasing the tube length, but were not sensitive to the tubes diameter. It is found tha

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Fazylov, S. D., О. А. Nurkenov, Z. M. Muldakhmetov, et al. "Biologically active derivatives of fullerene C60. Current state and development prospects." Bulletin of the Karaganda University. "Chemistry" series 99, no. 3 (2020): 11–20. http://dx.doi.org/10.31489/2020ch3/11-20.

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The article presents literature review on the physicochemical and biological properties of fullerene C60, as well as the authors' own experimental data on the synthesis of fullerene derivatives of amines and natural alkaloids. It is shown that the presence of a fullerene fragment in the structure of the compound provides a significant improvement or the appearance of qualitatively new mechanical, chemical, physical, biological and other properties associated with the manifestation of nanoscale factors. The issues of the relationship of the structure, water solubility and biological activity of

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Silant'ev A. V. "Energy Spectrum and Optical Absorption Spectrum of exohedral Fullerene C-=SUB=-50-=/SUB=-Cl-=SUB=-10-=/SUB=- within the Hubbard Model." Physics of the Solid State 64, no. 6 (2022): 750. http://dx.doi.org/10.21883/pss.2022.06.53843.290.

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Energy spectra of fullerene C50 and exohedral fullerene C50Cl10 with the D5h symmetry groups have been obtained within the Hubbard model and static fluctuation approximation. The energy states have been classified using the methods of group theory, and the allowed transitions in the energy spectra of molecules C50 and C50Cl10 have been determined. On the basis of the energy spectrum of exohedral fullerene C50Cl10 is given an interpretation of experimentally observed optical absorption bands molecule C50Cl10. Keywords: Hubbard model, Green's functions, energy spectrum, fullerenes, nanosystems,

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Xu, Piao-Yang, Xiao-Qing Li, Wei-Guang Chen, et al. "Progress in Antiviral Fullerene Research." Nanomaterials 12, no. 15 (2022): 2547. http://dx.doi.org/10.3390/nano12152547.

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Unlike traditional small molecule drugs, fullerene is an all-carbon nanomolecule with a spherical cage structure. Fullerene exhibits high levels of antiviral activity, inhibiting virus replication in vitro and in vivo. In this review, we systematically summarize the latest research regarding the different types of fullerenes investigated in antiviral studies. We discuss the unique structural advantage of fullerenes, present diverse modification strategies based on the addition of various functional groups, assess the effect of structural differences on antiviral activity, and describe the poss

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Barrera, E. V., J. Sims, D. L. Callahan, V. Provenzano, J. Milliken, and R. L. Holtz. "Processing of fullerene-reinforced composites." Journal of Materials Research 9, no. 10 (1994): 2662–69. http://dx.doi.org/10.1557/jmr.1994.2662.

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This work has been motivated by the current interest in using fullerenes as a possible reinforcement in structural materials. The fullerenes (of which C60 is the most common) are nanometer in size and have been observed to be stable in contact with various metal systems. Therefore, they offer a nanosize reinforcement that is lightweight and hollow. In this research the emphasis was on processing metals with fullerene additions where the fullerenes were dispersed throughout the metal. Various processing approaches were employed to produce nanocrystalline materials, thin films, and powder-proces

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Gao, Yang, and Heping Zhang. "Clar Structure and Fries Set of Fullerenes and (4,6)-Fullerenes on Surfaces." Journal of Applied Mathematics 2014 (2014): 1–11. http://dx.doi.org/10.1155/2014/196792.

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Fowler and Pisanski showed that the Fries number for a fullerene on surface Σ is bounded above by|V|/3, and fullerenes which attain this bound are exactly the class of leapfrog fullerenes on surface Σ. We showed that the Clar number of a fullerene on surface Σ is bounded above by(|V|/6)-χ(Σ), whereχ(Σ)stands for the Euler characteristic of Σ. By establishing a relation between the extremal fullerenes and the extremal (4,6)-fullerenes on the sphere, Hartung characterized the fullerenes on the sphereS0for which Clar numbers attain(|V|/6)-χ(S0). We prove that, for a (4,6)-fullerene on surface Σ,

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Ma, Yue, Lorenzo Persi, and Yoko Yamakoshi. "(Invited) Reactive Oxygen Generation from Photoexcited Fullerene-Peptide Conjugates." ECS Meeting Abstracts MA2023-01, no. 12 (2023): 1265. http://dx.doi.org/10.1149/ma2023-01121265mtgabs.

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Fullerenes have been considered as excellent candidates for photosensitizers (PSs) in photodynamic therapy (PDT). Fullerenes are reported to generate reactive oxygen species (ROSs), through energy transfer (singlet oxygen 1O2, Type II reaction) and electron transfer (reduced active oxygen radicals such as superoxide anion radical O2-• and hydroxyl radical •OH, Type I reaction) in an effective way (Figure 1a).1,2 In our previous study, we reported the synthesis of fullerene-PEG conjugates and demonstrated their ability for photoinduced DNA damage and ROS generation upon visible light irradiatio

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46

Alshehri, Mansoor H. "An Analytical Model for Lithium Storage in Spherical Fullerenes." Energies 15, no. 19 (2022): 7154. http://dx.doi.org/10.3390/en15197154.

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In this paper, the encapsulation of lithium atoms in spherical fullerenes of varying sizes is investigated. The 6–12 Lennard–Jones potential function and the continuum approximation, in which it is assumed that the atoms can be replaced with a uniform distribution across the surface of the molecules, are exploited to model the interaction energies between lithium atoms and spherical fullerenes. Thus, the total interaction energies can be approximated by applying surface integrations. The results show that for a lithium atom interacting inside a spherical fullerene, the interaction energies are

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47

Tanuma, Yuri, Toru Maekawa, and Chris Ewels. "Methodological Investigation for Hydrogen Addition to Small Cage Carbon Fullerenes." Crystals 11, no. 11 (2021): 1334. http://dx.doi.org/10.3390/cryst11111334.

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Hydrogenated small fullerenes (Cn, n < 60) are of interest as potential astrochemical species, and as intermediates in hydrogen-catalysed fullerene growth. However, the computational identification of key stable species is difficult due to the vast configurationally space of structures. In this study, we explored routes to predict stable hydrogenated small fullerenes. We showed that neither local fullerene geometry nor local electronic structure analysis was able to correctly predict subsequent low-energy hydrogenation sites, and sequential stable addition searches also sometimes failed to

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48

Djordjevic, Aleksandar, and Gordana Bogdanovic. "Fullerenol: A new nanopharmaceutic?" Archive of Oncology 16, no. 3-4 (2008): 42–45. http://dx.doi.org/10.2298/aoo0804042d.

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Chemical modification of fullerenes to hydrosoluble cluster molecules made fullerenes interesting for biological investigation. Among them, polycarbonated and polyhydroxylated fullerene C60 derivatives showed the most interesting biological activities. In this paper, we present the most important recent results of in vitro and in vivo biological studies with fullerenol C60(OH)24. Fullerenol C60(OH)24 was strong antioxidant: it reacted with superoxide anion radical, hydroxy radical and nitrous oxide radical in chemical and biological systems. Fullerenol C60(OH)24 did not inhibit human breast ca

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Sánchez-Bernabe, Francisco J. "Study of fullerenes C₁₂₆ and C₁₅₆ with seven heptagon rings." Journal of Physics: Conference Series 2321, no. 1 (2022): 012028. http://dx.doi.org/10.1088/1742-6596/2321/1/012028.

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Abstract We consider fullerenes C126 and C156, both of them with seven heptagon rings. The first of them is C126 with 19 pentagons, and 39 hexagons. It is also considered C156 with 19 pentagons, and 54 hexagons. From previous work, a couple of fullerenes, C130 and C134, are mentioned for comparative reasons. These two fullerenes also contain seven heptagon rings. Fullerene C130 is constituted of 19 pentagons, and 41 hexagons. On the other hand, fullerene C134 has 19 pentagons, and 43 hexagons. Therefore, the four fullerenes considered, with seven heptagon rings, also share the property that, t

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Khamatgalimov, Ayrat R., Valeri I. Kovalenko, and Anna S. Egorova. "Instability of molecular structure of non-IPR isomer 17984 (C1) of the C76 fullerene and probable ways of its stabilization." Butlerov Communications 63, no. 9 (2020): 1–9. http://dx.doi.org/10.37952/roi-jbc-01/20-63-9-1.

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It is well-known that non-IPR fullerenes are highly unstable. For this reason, they cannot be obtained as pristine fullerenes; however, some of them become stable as derivatives (exohedral or endohedral). In this article, we attempted to elucidate in detail molecular structure for such a non-IPR fullerene. Using theoretical approach supported by DFT calculations, the features of molecular structure of isomer 17894 (C1) of fullerene C76 with data about distribution of single, double and delocalized π-bonds as well its structural formula has been determined for the first time. The instability of

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