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Journal articles on the topic 'Furan; Solvents; Polymers'

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1

Belmokhtar, Abdelkader, Ahmed Yahiaoui, Aïcha Hachemaoui, Benyoucef Abdelghani, Nabahat Sahli, and Mohammed Belbachir. "A Novel Poly{(2,5-diyl furan) (benzylidene)}: A New Synthetic Approach and Electronic Properties." ISRN Physical Chemistry 2012 (November 20, 2012): 1–7. http://dx.doi.org/10.5402/2012/781879.

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A new conjugated aromatic poly[(furan-2, 5-diyl)-co-(benzylidene)] has been prepared by polycondensation of benzaldehyde and furan catalyzed by Maghnite-H+. Maghnite-H+ is a montmorillonite sheet silicate clay, which exchanged with protons. These polymers can be dissolved in high polar solvents such as DMSO, DMF, THF, or CHCl3 A kind of band-gap conjugated poly[(furan-2, 5-diyl)-co-(benzylidene)] has been synthesized by a simple method and characterized by 1HNMR, 13CNMR, FT-IR, and UV-Vis. The result reveals that the band-gap of the PFB conjugated polymer has an optical band gap of 2.2 eV.
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2

de Oliveira, Davi Rabelo, Selma Elaine Mazzetto, and Diego Lomonaco. "Synthesis and Polymerization of Naphthoxazines Containing Furan Groups: An Approach to Novel Biobased and Flame-Resistant Thermosets." International Journal of Polymer Science 2018 (November 25, 2018): 1–13. http://dx.doi.org/10.1155/2018/4201681.

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Naphthoxazines are a class of compounds with potential application in obtaining high-performance polymeric materials. Such application of these compounds, however, is still scarcely explored in the literature. Combined with the search for new high-performance materials, the development of biobased polymers has gained a lot of attention. In this sense, the inclusion of furan groups in polymers has been explored as a strategy that combines the search for high-performance materials with the search for the development of biobased materials. In this work, novel naphthoxazine monomers containing fur
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3

Cruz-Izquierdo, Álvaro, Lambertus A. M. van den Broek, Juan L. Serra, María J. Llama, and Carmen G. Boeriu. "Lipase-catalyzed synthesis of oligoesters of 2,5-furandicarboxylic acid with aliphatic diols." Pure and Applied Chemistry 87, no. 1 (2015): 59–69. http://dx.doi.org/10.1515/pac-2014-1003.

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Abstract2,5-Furandicarboxylic acid is a platform chemical for the production of biobased polymers and materials. This study reports the synthesis of furan oligoesters via polytransesterification of dimethyl furan-2,5-dicarboxylate and linear α, ω-aliphatic diols with chain length ranging from C2 to C12, using immobilized lipase B from Candida antarctica (Novozym 435) in dry organic solvents. Dimethyl furan-2,5-dicarboxylic acid (A) and 1,4-butanediol (B) were used as model substrates under different conditions producing a mixture of cyclic (CEOs) and linear (LEOs) ester oligomers up to decamer
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4

Druzhinina, A. V., M. Sh Suleimenova, O. A. Almabekov, and A. K. Kusainova. "SYNTHESIS OF POLYIMIDES OF ARILACYCLIC STRUCTURE." Chemical Journal of Kazakhstan 74, no. 2 (2021): 124–32. http://dx.doi.org/10.51580/2021-1/2710-1185.34.

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The article describes methods for producing polymeric materials based on tetra-carboxylic acid dianhydrides obtained by photochemical or solar irradiation from furan and maleic anhydride. The procedure of synthesis of aryl-alicyclic polyimides based on 7-оxsоdiciklo (2,2,1)-gepten -2,3- dicarboxylic acid(MAF) and diaminodiphenyl oxide diamines (DADFO) and dioxytriphenyldiamine (DOTFDA) in polar aprotic amide-type solvents has been studied in detail in the presence of a basic catalyst type: trimethyl-amine.The nature and reactivity of staring monomers affect the process of obtaining polyimides.
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5

Patel, Yogesh S. "Studies on polyimides containing thermoplastic-thermosetting merged segments." Journal of Polymer Engineering 34, no. 5 (2014): 451–57. http://dx.doi.org/10.1515/polyeng-2014-0026.

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Abstract Polyimides (PIs) containing thermoplastic and thermosetting merged segments in a chain were developed via Diels-Alder (DA) polymerization of a bisfuran (BF), namely 2,5-bis(furan-2-ylmethylcarbamoyl)terephthalic acid and bismaleimides (BMI1 and BMI2). The intermediate DA polyadducts thus obtained, DAA1 and DAA2, were aromatized and imidized (cyclized) through carboxylic and amide groups in the presence of acetic anhydride, to afford PI1 and PI2. Synthesized DA polyadducts and PIs were characterized by elemental analysis, spectral features, number average molecular weight (Mn), degree
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6

Wattanathana, Worawat, Yuranan Hanlumyuang, Suttipong Wannapaiboon, et al. "Novel Dihydro-1,3,2H-benzoxazine Derived from Furfurylamine: Crystal Structure, Hirshfeld Surface Analysis, Photophysical Property, and Computational Study." Crystals 11, no. 5 (2021): 568. http://dx.doi.org/10.3390/cryst11050568.

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Dihydro-1,3,2H-benzoxazines (or benzoxazine monomers) are a class of compounds that have been widely utilized in many areas such as the production of the functional polymers and optoelectronic materials. The structure variety of the benzoxazines plays a vital role in their desired properties. The effort of synthesizing functionalized benzoxazines from bioresources is of interest for sustainable development. Herein, we report the synthesis of the novel benzoxazine monomer referred to as 3-(furan-2-ylmethyl)-6-methyl-3,4-dihydro-2H-benzo[e][1,3]oxazine or benzoxazine (I) from a one-pot Mannich r
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7

Iqbal, Muhammad, Remco Knigge, Hero Heeres, Antonius Broekhuis, and Francesco Picchioni. "Diels–Alder-Crosslinked Polymers Derived from Jatropha Oil." Polymers 10, no. 10 (2018): 1177. http://dx.doi.org/10.3390/polym10101177.

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Methyl oleate, methyl linoleate, and jatropha oil were fully epoxidized using in situ-generated performic acid. The epoxidized compounds were further reacted with furfurylamine in a solvent-free reaction to obtain furan-functionalized fatty esters which, then, functioned as oligomers for a network preparation. Thermoreversible crosslinking was obtained through a (retro) Diels–Alder reaction with bismaleimide, resulting in the formation of a brittle network for furan-functionalized methyl linoleate and jatropha oil. The furan-functionalized fatty esters were mixed with alternating (1,4)-polyket
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8

Zhao, Deyang, Frederic Delbecq, and Christophe Len. "One-Pot FDCA Diester Synthesis from Mucic Acid and Their Solvent-Free Regioselective Polytransesterification for Production of Glycerol-Based Furanic Polyesters." Molecules 24, no. 6 (2019): 1030. http://dx.doi.org/10.3390/molecules24061030.

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A one pot-two step procedure for the synthesis of diethyl furan-2,5-dicarboxylate (DEFDC) starting from mucic acid without isolation of the intermediate furan dicarboxylic acid (FDCA) was studied. Then, the production of three different kinds of furan-based polyesters— polyethylene-2,5-furan dicarboxylate (PEF), polyhydropropyl-2,5-furan dicarboxylate(PHPF) and polydiglycerol-2,5-furandicarboxylate (PDGF)—was realized through a Co(Ac)2·4H2O catalyzed polytransesterification performed at 160 °C between DEFDC and a defined diol furan-based prepolymer or pure diglycerol. In parallel to polymeriza
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9

Mao, Yimin, and Peter Y. Zavalij. "Two- and three-dimensional coordination polymers based on zinc(II) and furan-2,5-dicarboxylic acid: structure variation due to metal-to-linker ratio." Acta Crystallographica Section C Structural Chemistry 74, no. 12 (2018): 1719–24. http://dx.doi.org/10.1107/s2053229618015759.

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Two ZnII-based coordination polymers (CPs) were synthesized by the hydrothermal method, using Zn(NO3)2·6H2O and furan-2,5-dicarboxylic acid (FDCA) in dimethylformamide (DMF) solvent, at 95 °C. Poly[tetrakis(dimethylazanium) [tetrakis(μ2-furan-2,5-dicarboxylato-κ2 O 2:O 5)dizinc(II)]], {(C2H8N)4[Zn2(C6H2O5)4]} n or {[DMA]4[ZnII 2(FDC)4]} n (DMA = dimethylazanium and FDC = furan-2,5-dicarboxylate), (1), was obtained with a 1:1 molar ratio of ZnII and FDCA. It crystallized in the monoclinic space group C2/c. Coordinated by ZnII ions, FDC2− ligands form 21 double-stranded helices propagating along
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10

Li, Zheng, Jin-Lan Yu, Jing-Ya Yang, Sheng-Yi Shi, and Xi-Cun Wang. "Polymer-supported Dichlorophosphate: A Recoverable New Reagent for Synthesis of 2-amino-1,3,4-thiadiazoles." Journal of Chemical Research 2005, no. 5 (2005): 341–43. http://dx.doi.org/10.3184/0308234054323913.

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Poly(ethylene glycol) (PEG) supported dichlorophosphate was efficiently used as a recoverable new dehydration reagent for rapid synthesis of 2-amino-5-substituted-1,3,4-thiadiazoles under microwave irradiation and solvent-free condition by reactions of thiosemicarbazide with aliphatic acids, benzoic acid, aryloxyacetic acids or furan-2-carboxylic acids.
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11

Todea, Bîtcan, Aparaschivei та ін. "Biodegradable Oligoesters of ε-Caprolactone and 5-Hydroxymethyl-2-Furancarboxylic Acid Synthesized by Immobilized Lipases". Polymers 11, № 9 (2019): 1402. http://dx.doi.org/10.3390/polym11091402.

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Following the latest developments, bio-based polyesters, obtained from renewable raw materials, mainly carbohydrates, can be competitive for the fossil-based equivalents in various industries. In particular, the furan containing monomers are valuable alternatives for the synthesis of various new biomaterials, applicable in food additive, pharmaceutical and medical field. The utilization of lipases as biocatalysts for the synthesis of such polymeric compounds can overcome the disadvantages of high temperatures and metal catalysts, used by the chemical route. In this work, the enzymatic synthesi
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12

Polgar, L. M., J. Keizer, R. Blom, et al. "THERMOREVERSIBLE CROSS-LINKING OF RUBBER COMPOUNDS: FROM PROOF-OF-CONCEPT TOWARD AN INDUSTRIAL PROCESS." Rubber Chemistry and Technology 91, no. 2 (2018): 492–508. http://dx.doi.org/10.5254/rct-18-82638.

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ABSTRACT It is demonstrated that the concept of thermoreversible cross-linking of functionalized maleic anhydride grafted ethylene–propylene (EPM-g-MA) rubber using Diels–Alder chemistry is limited neither to laboratory scale using a solvent route nor to gum rubber. The use of an internal mixer is the first step toward an industrial process, since it greatly reduces the processing time and allows for a solventless process for the furan-functionalization and subsequent bismaleimide cross-linking of EPM rubber. Practical rubber compounds were prepared by mixing thermoreversibly cross-linked EPM
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13

Zhou, Weilong, Huajie Chen, Junjie Lv, et al. "Improving the efficiency of polymer solar cells based on furan-flanked diketopyrrolopyrrole copolymer via solvent additive and methanol treatment." Nanoscale 7, no. 38 (2015): 15945–52. http://dx.doi.org/10.1039/c5nr04393j.

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14

Kucharska, Małgorzata. "Furan. Determination in workplace air with gas chromatography." Podstawy i Metody Oceny Środowiska Pracy 37, no. 2 (2021): 133–60. http://dx.doi.org/10.5604/01.3001.0014.9943.

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Furan is colorless, highly volatile and flammable liquid with a specific ether odor. In nature it occurs in some species of wood, it is formed during burning process of wood, tobacco, fuels and also in thermal food processing. In industry furan is used as an intermediate in organic synthesis, resins solvent, during production of lacquer, drugs, stabilizers, insecticides and also in production of chemical compounds which have polymeric and coordination structure. Carcinogenic effect on animals was a base of recognition that furan is a substance which is probably also carcinogenic on humans. The
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15

Luo, Kai Ju, Yan Wang, Jun Rong Yu, Jing Zhu, and Zu Ming Hu. "Copolymerization Modification of PPTA with 2,5-Furandicarboxylic Acid: Towards High-Performance Material with Enhanced Solubility." Materials Science Forum 898 (June 2017): 2174–80. http://dx.doi.org/10.4028/www.scientific.net/msf.898.2174.

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The preparation and characterizations of soluble copolymers poly (p-phenylene terephthamide-co-furandicarboxylic p-Phenylenediamine)(PPTA-co-PPF) by direct polycondensation was described. The chemical structure of polyamides was investigated by 1H NMR and FT-IR. The good solubility of copolymers in organic solvents was certified at room temperature. Their thermal stability and mechanical properties were observed by TGA and tensile testing and then compared with that of traditional high performance aromatic polyamides (PPTA and PMIA, for example, with trademarks of Kevlar® and Nomex®). The fura
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16

Kashparova, Vera P., Victor A. Klushin, Veronika E. Andreeva, Nina V. Smirnova, Irina Yu Zhukova, and Ivan I. Kashparov. "2,5–FURANDICARBOXYLIC ACID DICINAMIL ETHER AND NEW COPOLYMERS ON ITS BASIS." IZVESTIYA VYSSHIKH UCHEBNYKH ZAVEDENII KHIMIYA KHIMICHESKAYA TEKHNOLOGIYA 63, no. 9 (2020): 4–11. http://dx.doi.org/10.6060/ivkkt.20206309.6246.

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A method for the synthesis of dicinamyl ester of 2,5-furandicarboxylic acid (DCF) a new unsaturated compound of the furan series and potential monomer for producing copolymers with various vinyl compounds and based on them a new generation of construction and ion-exchange materials has been developed. DCF does not form homopolymers as in bulk as in solution (toluene solvent). However, DCF is actively copolymerized with styrene, methyl methacrylate, methacrylic and acrylic acids to form cross-linked polymers with varying degrees of crosslinking. The copolymerization constants of DCF with all in
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17

Bazin, Alfred, Luc Avérous, and Eric Pollet. "Lipase-catalyzed synthesis of furan-based aliphatic-aromatic biobased copolyesters: Impact of the solvent." European Polymer Journal 159 (October 2021): 110717. http://dx.doi.org/10.1016/j.eurpolymj.2021.110717.

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18

Zolghadr, Mohsen, Alireza Shakeri, Mohammad Jalal Zohuriaan‐Mehr, and Ali Salimi. "Self‐healing semi‐IPN materials from epoxy resin by solvent‐free furan–maleimide Diels–Alder polymerization." Journal of Applied Polymer Science 136, no. 40 (2019): 48015. http://dx.doi.org/10.1002/app.48015.

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19

Ding, Shang, Zhenjie Ni, Mengxiao Hu, et al. "An Asymmetric Furan/Thieno[3,2-b ]Thiophene Diketopyrrolopyrrole Building Block for Annealing-Free Green-Solvent Processable Organic Thin-Film Transistors." Macromolecular Rapid Communications 39, no. 15 (2018): 1800225. http://dx.doi.org/10.1002/marc.201800225.

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20

Zou, Ji-Yong, Ling Li, Sheng-Yong You, et al. "A Solvent-Stable Zinc(II)–Gadolinium(III) Metal–Organic Framework Assembled with Furan-2,5-Dicarboxylic Acid: Synthesis, Crystal Structure and Magnetic Property." Journal of Inorganic and Organometallic Polymers and Materials 29, no. 2 (2018): 359–64. http://dx.doi.org/10.1007/s10904-018-1006-5.

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21

Mohajeri, S., MJ Zohuriaan-Mehr, and S. Pazokifard. "Epoxy matrix toughness improvement via reactive bio-resin alloying." High Performance Polymers 29, no. 7 (2016): 772–84. http://dx.doi.org/10.1177/0954008316656743.

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A facile solvent-less approach to toughen epoxy thermosets by means of a bio-based resin, that is, poly(furfuryl alcohol) (PFA; furan resin) is reported. The bio-resin PFA was firstly synthesized through polycondensation reaction of furfuryl alcohol as a bio-monomer and maleic anhydride as a catalyst. Different amounts of PFA were blended with diglycidyl ether of bisphenol A epoxy resin and cured by diethylenetriamine as a hardener, which simultaneously cross-linked both of the epoxy and PFA resins. The curing process was studied by Furrier transform infrared spectroscopy and differential scan
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22

Zhang, Xue-Ying, Zhong-Hua Xu, Min-Hua Zong, Chuan-Fu Wang, and Ning Li. "Selective Synthesis of Furfuryl Alcohol from Biomass-Derived Furfural Using Immobilized Yeast Cells." Catalysts 9, no. 1 (2019): 70. http://dx.doi.org/10.3390/catal9010070.

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Furfuryl alcohol (FA) is an important building block in polymer, food, and pharmaceutical industries. In this work, we reported the biocatalytic reduction of furfural, one of the top value-added bio-based platform chemicals, to FA by immobilized Meyerozyma guilliermondii SC1103 cells. The biocatalytic process was optimized, and the tolerance of this yeast strain toward toxic furfural was evaluated. It was found that furfural of 200 mM could be reduced smoothly to the desired product FA with the conversion of 98% and the selectivity of >98%, while the FA yield was only approximately 81%. The
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23

Zhang, Su-Meng, Jian-Qiao Zhao, Yun Liu, Yin-xuan Liu, and Cheng-Mei Liu. "Renewable furan-derived diamine as primary amine source to prepare fully bio-based bis-benzoxazine monomer under solvent-free condition." Reactive and Functional Polymers, June 2021, 104957. http://dx.doi.org/10.1016/j.reactfunctpolym.2021.104957.

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