Academic literature on the topic 'Gallium(m) chloride'

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Journal articles on the topic "Gallium(m) chloride"

1

Naskar, Nabanita, and Susanta Lahiri. "Separation of no-carrier-added 71,72As from 46 MeV alpha particle irradiated gallium oxide target." Radiochimica Acta 109, no. 5 (2021): 389–95. http://dx.doi.org/10.1515/ract-2020-0120.

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Abstract No-carrier-added (NCA) 71,72As radionuclides were produced by irradiating gallium oxide target by 46 MeV α-particles. NCA 71,72As was separated from the target matrix by liquid-liquid extraction (LLX) using trioctyl amine (TOA) and tricaprylmethylammonium chloride (aliquat-336) diluted in cyclohexane. The bulk gallium was quantitatively extracted into the organic phase leaving 71,72As in the aqueous phase. Complete separation was observed at 3 M HCl + 0.1 M TOA and 2 M HCl + 0.01 M aliquat-336.
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2

Chen, Wei-Sheng, Ko-Wei Tien, Li-Pang Wang, Cheng-Han Lee, and Yi-Fan Chung. "Recovery of Gallium from Simulated GaAs Waste Etching Solutions by Solvent Extraction." Sustainability 12, no. 5 (2020): 1765. http://dx.doi.org/10.3390/su12051765.

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Gallium arsenide is used in semiconductor industries worldwide. Numerous waste etching solutions are produced during the processes of GaAs wafer production. Therefore, a complete and eco-friendly technology should be established to recover gallium as a gallium chloride solution and remove arsenic ion from waste GaAs etching solution. In this study, the gallium trichloride and arsenic trisulfide powders were dissolved in ammonia solutions to prepare the simulated solutions, and the pH value was adjusted to pH 2 by nitric acid. In the extraction step, the GaAs etching solutions were extracted us
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3

Nnaji, Nnaemeka, Njemuwa Nwaji, and Tebello Nyokong. "Electrodeposited Benzothiazole Phthalocyanines for Corrosion Inhibition of Aluminium in Acidic Medium." International Journal of Electrochemistry 2020 (September 30, 2020): 1–11. http://dx.doi.org/10.1155/2020/8892559.

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Tetrakis[(benzo[d]thiazol-2-yl-thio) phthalocyaninato] gallium(III)chloride (1) and tetrakis[(benzo[d]thiazol-2ylphenoxy) phthalocyaninato] gallium(III)chloride (2) were successfully electrodeposited onto aluminium for corrosion retardation in 1.0 M hydrochloric acid solution. The aim of this study was to compare the corrosion resistance of electrodeposited metallated phthalocyanines. Scanning electron microscopy, X-ray diffraction, electrochemical impedance spectroscopy (EIS), and polarization confirmed the aluminium corrosion inhibition potentials of complexes 1 and 2. EIS and polarization t
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4

Mitzel, Norbert W., and Christian Lustig. "Organoaluminium and -gallium Lewis-Acid Adducts of Tetramethylmethylenediamine." Zeitschrift für Naturforschung B 59, no. 11-12 (2004): 1532–39. http://dx.doi.org/10.1515/znb-2004-11-1225.

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The compounds Me3Al-Me2NCH2NMe2-AlMe3 (1) and Me3Ga-Me2NCH2NMe2-GaMe3 (2) were prepared by reacting Me2NCH2NMe2 (TMMDA) with two equivalents of the metal trialkyls in hydrocarbon solutions.With the ether adduct Me3Ga·OEt2 Me2NCH2NMe2 reacts to give the monoadduct Me2NCH2NMe2-GaMe3 (3). These compounds were characterized by NMR spectroscopy (1H, 13C and 27Al) and by elemental analyses. Crystal structure investigations show 1 and 2 to be monomeric and to a adopt a trans,trans-conformation for their M-N-C-N-M backbones. 3 is also monomeric in the solid state, but adopts a cis,trans-conformation.
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5

M. M. Kinsman, Luke, Carole A. Morrison, Bryne T. Ngwenya, and Jason B. Love. "Reducing the Competition: A Dual-Purpose Ionic Liquid for the Extraction of Gallium from Iron Chloride Solutions." Molecules 25, no. 18 (2020): 4047. http://dx.doi.org/10.3390/molecules25184047.

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The separation of gallium from iron by solvent extraction from chloride media is challenging because the anionic chloridometalates, FeCl4− and GaCl4−, display similar chemical properties. However, we report here that the selective separation of gallium from iron in HCl solution can be achieved using the dual-purpose ionic liquid methyltrioctylammonium iodide in a solvent extraction process. In this case, the reduction of Fe3+ to Fe2+ by the iodide counterion was found to inhibit Fe transport, facilitating quantitative Ga extraction by the ionic liquid with minimal Fe extraction from 2 M HCl.
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6

Akdeniz, Z., M. Çaliskana, and M. P. Tosib. "Polymerie Structures in Aluminium and Gallium Halides." Zeitschrift für Naturforschung A 55, no. 6-7 (2000): 575–80. http://dx.doi.org/10.1515/zna-2000-6-703.

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54a,The anionic species (Aln X3n + 1) − with X = CI or Br and n ≥ 1 have been recognized for a number of years to form in acidic liquid mixtures of aluminium chloride or bromide with the corresponding halides of alkali or organic cations, in relative proportions which vary with the composition of the mixture. In this work we evaluate the structure and the energetics of such polymeric series in a comparative study of Al and Ga compounds. To this end we first extend an earlier study of the ionic interactions in the Al2Cl6 molecule [Z. Akdeniz and M. P. Tosi, Z. Naturforsch. 180 (1999)] to determ
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7

Gustafsson, Anna M. K., Fredrik Björefors, Britt-Marie Steenari, and Christian Ekberg. "Investigation of an Electrochemical Method for Separation of Copper, Indium, and Gallium from Pretreated CIGS Solar Cell Waste Materials." Scientific World Journal 2015 (2015): 1–11. http://dx.doi.org/10.1155/2015/494015.

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Recycling of the semiconductor material copper indium gallium diselenide (CIGS) is important to ensure a future supply of indium and gallium, which are relatively rare and therefore expensive elements. As a continuation of our previous work, where we recycled high purity selenium from CIGS waste materials, we now show that copper and indium can be recycled by electrodeposition from hydrochloric acid solutions of dissolved selenium-depleted material. Suitable potentials for the reduction of copper and indium were determined to be −0.5 V and −0.9 V (versus the Ag/AgCl reference electrode), respe
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8

Dhruva, Kumar, Saini Anil, Suresh, and S. Sandhu Jagir. "Gallium(III) chloride as an efficient new catalyst for the production of Hantzsch 1 ,4-dihydropyridines." Journal of Indian Chemical Society Vol. 86, Sep 2009 (2009): 996–1000. https://doi.org/10.5281/zenodo.5820069.

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Department of Chemistry, Punjabi University, Patiala-147 002, Punjab, india <em>E-mail</em> : j_sandhu2002@yahoo.com <em>Manuscript received 16 March 2009, accepted 26 May 2009</em> Hantzsch 1,4-dihydropyridines (DHPs) are synthesized In good to excellent yields from aldehydes, 1,3-dicarbonyl compounds and ammonium acetate using gallium(lll) chloride which acts as dehydrating agents and 5 mol% is enough for this protocol under solvent free conditions.
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9

Seredin, P. V., N. A. Kurilo, Ali O. Radam, et al. "Study of semi-polar gallium nitride grown on m-sapphire by chloride vapor-phase epitaxy." Конденсированные среды и межфазные границы 25, no. 1 (2023): 103–11. http://dx.doi.org/10.17308/kcmf.2023.25/10978.

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10

Myasoedov A.V., Pavlov I. S., Pechnikov A. I., Stepanov S.I. та Nikolaev V. I. "Defect structure of α-Ga-=SUB=-2-=/SUB=-O-=SUB=-3-=/SUB=- film grown on a m-face sapphire substrate, according to transmission electron microscopy investigation". Technical Physics Letters 49, № 1 (2023): 67. http://dx.doi.org/10.21883/tpl.2023.01.55353.19365.

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The results of a study by transmission electron microscopy of the structural state of α-Ga2O3 film with a thickness of about 1 micron, grown on the prismatic m-face sapphire by the method of chloride vapor phase epitaxy, are presented. The influence of the substrate orientation on the formation of the dislocation structure is discussed. Threading dislocations, including those with the Burgers vector 1/3&amp;lt; 1120 &amp;gt;, and dislocation half-loops are revealed. The inclined propagation of dislocations and the formation of dislocation half-loops result in the reduction of the threading dis
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