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1

Clough, Robert, Chris F. Harrington, Steve J. Hill, Yolanda Madrid, and Julian F. Tyson. "Atomic spectrometry update: review of advances in elemental speciation." Journal of Analytical Atomic Spectrometry 35, no. 7 (2020): 1236–78. http://dx.doi.org/10.1039/d0ja90026e.

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Clough, Robert, Chris F. Harrington, Steve J. Hill, Yolanda Madrid, and Julian F. Tyson. "Atomic Spectrometry Update: review of advances in elemental speciation." Journal of Analytical Atomic Spectrometry 31, no. 7 (2016): 1330–73. http://dx.doi.org/10.1039/c6ja90030e.

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3

Clough, Robert, Chris F. Harrington, Steve J. Hill, Yolanda Madrid, and Julian F. Tyson. "Atomic spectrometry update: review of advances in elemental speciation." Journal of Analytical Atomic Spectrometry 34, no. 7 (2019): 1306–50. http://dx.doi.org/10.1039/c9ja90028d.

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4

Clough, Robert, Chris F. Harrington, Steve J. Hill, Yolanda Madrid, and Julian F. Tyson. "Atomic Spectrometry Update: review of advances in elemental speciation." Journal of Analytical Atomic Spectrometry 33, no. 7 (2018): 1103–49. http://dx.doi.org/10.1039/c8ja90025f.

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5

Clough, Robert, Chris F. Harrington, Steve J. Hill, Yolanda Madrid, and Julian F. Tyson. "Atomic spectrometry update: review of advances in elemental speciation." Journal of Analytical Atomic Spectrometry 32, no. 7 (2017): 1239–82. http://dx.doi.org/10.1039/c7ja90028g.

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6

Harrington, Chris F., Robert Clough, Steve J. Hill, Yolanda Madrid, and Julian F. Tyson. "Atomic Spectrometry Update: review of advances in elemental speciation." Journal of Analytical Atomic Spectrometry 30, no. 7 (2015): 1427–68. http://dx.doi.org/10.1039/c5ja90028j.

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7

Clough, Robert, Chris F. Harrington, Steve J. Hill, Yolanda Madrid, and Julian F. Tyson. "Atomic Spectrometry Update: review of advances in elemental speciation." Journal of Analytical Atomic Spectrometry 36, no. 7 (2021): 1326–73. http://dx.doi.org/10.1039/d1ja90026a.

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8

Sánchez, Raquel, Fabien Chainet, Vincent Souchon, Sylvain Carbonneaux, Charles-Philippe Lienemann, and José-Luis Todolí. "Silicon speciation in light petroleum products using gas chromatography coupled to ICP-MS/MS." Journal of Analytical Atomic Spectrometry 35, no. 10 (2020): 2387–94. http://dx.doi.org/10.1039/d0ja00156b.

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A gas chromatography method coupled to ICP-tandem mass spectrometry (GC-ICP-MS/MS) was validated for silicon speciation method for light petroleum products with a detector response independently of sample matrix and silicon chemical form.
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9

Wehmeier, Silvia, Rob Ellam, and J�rg Feldmann. "Isotope ratio determination of antimony from the transient signal of trimethylstibine by GC-MC-ICP-MS and GC-ICP-TOF-MS." Journal of Analytical Atomic Spectrometry 18, no. 9 (2003): 1001. http://dx.doi.org/10.1039/b302242k.

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10

Faßbender, Sebastian, Marcus von der Au, Maren Koenig, et al. "Species-specific isotope dilution analysis of monomethylmercury in sediment using GC/ICP-ToF-MS and comparison with ICP-Q-MS and ICP-SF-MS." Analytical and Bioanalytical Chemistry 413, no. 21 (2021): 5279–89. http://dx.doi.org/10.1007/s00216-021-03497-z.

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AbstractA recently introduced inductively coupled plasma-time-of-flight-mass spectrometer (ICP-ToF-MS) shows enhanced sensitivity compared to previous developments and superior isotope ratio precision compared to other ToF and commonly used single-collector ICP-MS instruments. Following this fact, an improvement for isotope dilution ICP-MS using the new instrumentation has been reported. This study aimed at investigating whether this improvement also meets the requirements of species-specific isotope dilution using GC/ICP-MS, where short transient signals are recorded. The results of the analysis of monomethylmercury (MMHg) of a sediment reference material show that isotope ratio precision of ICP-MS instruments equipped with quadrupole, sector-field, and time-of-flight mass analyzers is similar within a broad range of peak signal-to-noise ratio when analyzing one isotopic system. The procedural limit of quantification (LOQ) for MMHg, expressed as mass fraction of Hg being present as MMHg, w(Hg)MMHg, was similar as well for all investigated instruments and ranged between 0.003 and 0.016 μg/kg. Due to the simultaneous detection capability, the ICP-ToF-MS might, however, be more favorable when several isotopic systems are analyzed within one measurement. In a case study, the GC/ICP-ToF-MS coupling was applied for analysis of MMHg in sediments of Finow Canal, a historic German canal heavily polluted with mercury. Mass fractions between 0.180 and 41 μg/kg (w(Hg)MMHg) for MMHg, and 0.056 and 126 mg/kg (w(Hg)total) for total mercury were found in sediment samples taken from the canal upstream and downstream of a former chemical plant. Graphical abstract
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11

González-Gago, Adriana, Juan Manuel Marchante-Gayón, Miguel Ferrero, and J. Ignacio Garcia Alonso. "Synthesis of81Br-Labeled Polybrominated Diphenyl Ethers and Their Characterization Using GC(EI)MS and GC(ICP)MS." Analytical Chemistry 82, no. 7 (2010): 2879–87. http://dx.doi.org/10.1021/ac902889u.

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12

Hippler, J., H. W. Hoppe, F. Mosel, A. W. Rettenmeier, and A. V. Hirner. "Comparative determination of methyl mercury in whole blood samples using GC–ICP-MS and GC–MS techniques." Journal of Chromatography B 877, no. 24 (2009): 2465–70. http://dx.doi.org/10.1016/j.jchromb.2009.06.004.

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13

Chong, N. S., and R. S. Houk. "Inductively Coupled Plasma-Mass Spectrometry for Elemental Analysis and Isotope Ratio Determinations in Individual Organic Compounds Separated by Gas Chromatography." Applied Spectroscopy 41, no. 1 (1987): 66–74. http://dx.doi.org/10.1366/0003702874867963.

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A gas chromatograph (GC) with a packed column was interfaced to an inductively coupled plasma-mass spectrometer (ICP-MS) to yield atomic mass spectra from volatile organic compounds. Atomization of injected compounds was nearly complete and independent of molecular structure, so that elemental ratios could be determined. Detection limits were in the range 0.001 to 400 ng s−1, depending on the ionization energy of the element and its abundance in the background spectrum. The relative standard deviation of measured isotope ratios varied from 0.4% for Br (i.e., a ratio close to unity) to 18% for N (a very large ratio). Thus, GC-ICP-MS provides elemental and isotope ratio information that is complementary to the molecular information derived from GC-MS with conventional ionization methods.
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14

Krupp, Eva M., and Olivier F. X. Donard. "Isotope ratios on transient signals with GC–MC–ICP-MS." International Journal of Mass Spectrometry 242, no. 2-3 (2005): 233–42. http://dx.doi.org/10.1016/j.ijms.2004.11.026.

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15

Zhang, Huiling, Yuxiong Huang, Jianqiang Gu, et al. "Single particle ICP-MS and GC-MS provide a new insight into the formation mechanisms during the green synthesis of AgNPs." New Journal of Chemistry 43, no. 9 (2019): 3946–55. http://dx.doi.org/10.1039/c8nj06291a.

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16

Gonzalez-Gago, Adriana, Daniel Pröfrock, and Andreas Prange. "Comparison of GC–NCI MS, GC–ICP-MS, and GC–EI MS–MS for the determination of PBDEs in water samples according to the Water Framework Directive." Analytical and Bioanalytical Chemistry 407, no. 26 (2015): 8009–18. http://dx.doi.org/10.1007/s00216-015-8973-y.

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17

Grümping, R., D. Mikolajczak, and A. V. Hirner. "Determination of trimethylsilanol in the environment by LT-GC/ICP-OES and GC-MS." Fresenius' Journal of Analytical Chemistry 361, no. 2 (1998): 133–39. http://dx.doi.org/10.1007/s002160050849.

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18

Al-Onazi, Wedad, Amal M. Al-Mohaimeed, Musarat Amina, and Maha F. El-Tohamy. "Identification of Chemical Composition and Metal Determination of Retama raetam (Forssk) Stem Constituents Using ICP-MS, GC-MS-MS, and DART-MS." Journal of Analytical Methods in Chemistry 2021 (February 24, 2021): 1–9. http://dx.doi.org/10.1155/2021/6667238.

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This study aims to investigate the chemical constituents of the stem of Retama raetam growing in Saudi Arabia. The organic and inorganic composition of ethanol extract of R. raetam stem has been explored using direct analysis in real time-mass spectrometry (DART-MS), gas chromatography-mass spectrometry (GC-MS), and inductively coupled plasma-mass spectrometry (ICP-MS). Analysis conducted by DART-MS and GC-MS reveals the presence of several interesting organic constituents identified as 2,4-di-tert-butylphenol, sparteine, benzenepropanoic acid, 3,5-bis(1,1-dimethylethyl)-4-hydroxy-, methyl ester, phthalic acid, 1-octadecanol, squalene, argentamin, 2,4-di-tert-butylphenol, sparteine, benzene propanoic acid, 3,5-bis(1,1-dimethylethyl)-4-hydroxy-, methyl ester, phthalic acid, 1-octadecanol, squalene, argentamin, and hentriacontane in the ethanol extract of the R. raetam stem. The ICP-MS analysis of stem extract showed the presence of a significant amount of important inorganic elements including aluminum, chlorine, calcium, bromine magnesium, phosphorus, scandium, and chromium. The current study complements other R. raetam extract investigations carried out in the past and provides the additional data for the future research studies.
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19

Ahamad, Syed Rizwan, Mohammad Raish, Ajaz Ahmad, and Faiyaz Shakeel. "Potential Health Benefits and Metabolomics of Camel Milk by GC-MS and ICP-MS." Biological Trace Element Research 175, no. 2 (2016): 322–30. http://dx.doi.org/10.1007/s12011-016-0771-7.

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20

Ahamad, Syed Rizwan, Mohammad Raish, Syed Hilal Yaqoob, Altaf Khan, and Faiyaz Shakeel. "Metabolomics and Trace Element Analysis of Camel Tear by GC-MS and ICP-MS." Biological Trace Element Research 177, no. 2 (2016): 251–57. http://dx.doi.org/10.1007/s12011-016-0889-7.

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21

Queipo-Abad, Silvia, Pablo Rodríguez-González, and José Ignacio García Alonso. "Measurement of compound-specific Hg isotopic composition in narrow transient signals by gas chromatography coupled to multicollector ICP-MS." Journal of Analytical Atomic Spectrometry 34, no. 4 (2019): 753–63. http://dx.doi.org/10.1039/c8ja00453f.

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22

Yang, Lu, Ralph E. Sturgeon, Wayne R. Wolf, Robert J. Goldschmidt, and Zolt�n Mester. "Determination of selenomethionine in yeast using CNBr derivatization and species specific isotope dilution GC ICP-MS and GC-MS." Journal of Analytical Atomic Spectrometry 19, no. 11 (2004): 1448. http://dx.doi.org/10.1039/b410543e.

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23

Montes Bayón, María, Manuel Gutiérrez Camblor, J. Ignacio García Alonso, and Alfredo Sanz-Medel. "An alternative GC-ICP-MS interface design for trace element speciation." J. Anal. At. Spectrom. 14, no. 9 (1999): 1317–22. http://dx.doi.org/10.1039/a901760g.

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24

García-Bellido, Javier, Laura Freije-Carrelo, Mariella Moldovan, and Jorge Ruiz Encinar. "Recent advances in GC-ICP-MS: Focus on the current and future impact of MS/MS technology." TrAC Trends in Analytical Chemistry 130 (September 2020): 115963. http://dx.doi.org/10.1016/j.trac.2020.115963.

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25

Ahamad, Syed Rizwan, Abdul Qader Alhaider, Mohammad Raish, and Faiyaz Shakeel. "Metabolomic and elemental analysis of camel and bovine urine by GC–MS and ICP–MS." Saudi Journal of Biological Sciences 24, no. 1 (2017): 23–29. http://dx.doi.org/10.1016/j.sjbs.2015.09.001.

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26

Ahamad, Syed Rizwan, Syed Hilal Yaqoob, Altaf Khan, and Faiyaz Shakeel. "Metabolite profile and elemental determination of camel follicular fluid by GC–MS and ICP-MS." Tropical Animal Health and Production 51, no. 8 (2019): 2447–54. http://dx.doi.org/10.1007/s11250-019-01920-3.

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27

Shi, Yi Ni, Kai Pei, Yin Feng Zhao, et al. "Impurity Detection Method for High-Purity BCl3." Materials Science Forum 815 (March 2015): 76–79. http://dx.doi.org/10.4028/www.scientific.net/msf.815.76.

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A method for detecting impurities in high purity BCl3 was described in the present work. GC, ICP-MS, FTIR and colorimetric method were applied to analyze high-purity BCl3. The quantitative results of the impurities such as N2, CO, CO2 and Fe demonstrated that these methods had excellent repeatability (RSD<3%), reproducibility. The ICP-MS detection accuracy can achieve ppb limiter. The FTIR method provided opportunities for the determination of HCl, COCl2, which have difficulties in quantification with other method.
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28

Jackson, Brian, Vivien Taylor, R. Arthur Baker, and Eric Miller. "Low-Level Mercury Speciation in Freshwaters by Isotope Dilution GC-ICP-MS." Environmental Science & Technology 43, no. 7 (2009): 2463–69. http://dx.doi.org/10.1021/es802656p.

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29

Ayoub Momani, Kamal. "Chemical Assessment of Bottled Drinking Waters by IC, GC, and ICP‐MS." Instrumentation Science & Technology 34, no. 5 (2006): 587–605. http://dx.doi.org/10.1080/10739140600811740.

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30

Riechmann, Thomas, Alfred V. Hirner, and J. Feldmann. "Determination of organometallics in intra-oral air by LT-GC/ICP-MS." Analytical and Bioanalytical Chemistry 354, no. 5-6 (1996): 620–23. http://dx.doi.org/10.1007/s0021663540620.

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31

Mathison, Sally, Al Sattler, Robin Lile, et al. "Determination of Siloxanes and other Volatile Silicon Compounds in Biogas Samples Using Sample Preconcentration with GC-MS and GC-ICP-MS." Proceedings of the Water Environment Federation 2010, no. 3 (2010): 399–424. http://dx.doi.org/10.2175/193864710802768352.

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32

González-Gago, Adriana, Daniel Pröfrock, and Andreas Prange. "Optimizing GC-ICP-MS for ultra-trace quantification of PBDEs in natural water samples using species-specific isotope dilution." Journal of Analytical Atomic Spectrometry 30, no. 1 (2015): 180–90. http://dx.doi.org/10.1039/c4ja00112e.

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A new approach based on the use of GC-ICP-MS and <sup>81</sup>Br-labelled PBDEs for species-specific isotope dilution has been developed for the reliable quantification of PBDEs according to the EU WFD.
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33

Vacchina, V., E. N. Epova, S. Bérail, B. Médina, O. F. X. Donard, and F. Séby. "Tin and mercury and their speciation (organotin compounds and methylmercury) in worldwide red wine samples determined by ICP-MS and GC-ICP-MS." Food Additives & Contaminants: Part B 13, no. 2 (2020): 88–98. http://dx.doi.org/10.1080/19393210.2020.1734669.

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34

Wahlen, Raimund, and C�line Wolff-Briche. "Comparison of GC?ICP?MS and HPLC?ICP?MS for species-specific isotope dilution analysis of tributyltin in sediment after accelerated solvent extraction." Analytical and Bioanalytical Chemistry 377, no. 1 (2003): 140–48. http://dx.doi.org/10.1007/s00216-003-2094-8.

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35

Clases, David, Maiken Ueland, Raquel Gonzalez de Vega, Philip Doble, and Daniel Pröfrock. "Quantitative speciation of volatile sulphur compounds from human cadavers by GC-ICP-MS." Talanta 221 (January 2021): 121424. http://dx.doi.org/10.1016/j.talanta.2020.121424.

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36

Yang, Lu, Zoltán Mester, and Ralph E. Sturgeon. "Determination of methylmercury in fish tissues by isotope dilution SPME-GC-ICP-MS." Journal of Analytical Atomic Spectrometry 18, no. 5 (2003): 431–36. http://dx.doi.org/10.1039/b301299a.

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37

Alonso, Ignacio J., Jorge Encinar, Pablo González, and Alfredo Sanz-Medel. "Determination of butyltin compounds in environmental samples by isotope-dilution GC–ICP–MS." Analytical and Bioanalytical Chemistry 373, no. 6 (2002): 432–40. http://dx.doi.org/10.1007/s00216-002-1294-y.

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38

Freije-Carrelo, Laura, Javier García-Bellido, Francisco Calderón-Celis, Mariella Moldovan, and Jorge Ruiz Encinar. "GC-ICP-MS/MS Instrumental Setup for Total and Speciation Sulfur Analysis in Gasolines using Generic Standards." Analytical Chemistry 91, no. 11 (2019): 7019–24. http://dx.doi.org/10.1021/acs.analchem.9b01199.

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39

Wang, Zhi-Guo, Zeng-Ping Chen, Fan Gong, Hai-Long Wu, and Ru-Qin Yu. "Inner chromatogram projection (ICP) for resolution of GC-MS data with embedded chromatographic peaks." Analyst 127, no. 5 (2002): 623–28. http://dx.doi.org/10.1039/b200114b.

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40

Ojo, Abiodun A., and Amos Onasanya. "Characterization of Arsenic Biotransformation Products from an Open Anaerobic Degradation of Fucus distichus by Hydride Generation Gas Chromatography Atomic Absorption Spectrometry and High Performance Liquid Chromatography Inductively Coupled Plasma Mass Spectrometry." ISRN Spectroscopy 2013 (November 2, 2013): 1–6. http://dx.doi.org/10.1155/2013/431801.

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This work reports on the isolation and determination of biotransformation products obtained from the organoarsenic compounds that are present in Fucus distichus when it was subjected to an open anaerobic decomposition by using the Hydride Generation Gas Chromatography Atomic Absorption Spectrometry (HG-GC-AAS) and High Performance Liquid Chromatography Inductively Coupled Plasma Mass Spectrometry (HPLC-ICP-MS). The seaweed and filtrate residues obtained from the open anaerobic degradation procedure were extracted in methanol and partitioned in phenol-ether-water mixtures to obtain water soluble extracts. The water soluble extracts were cleaned up and separated on a gel permeation Sephadex G15 column. Arsenic species concentrations were determined by using HG-GC-AAS. Final characterization of the biotransformation isolates was carried out on HPLC-ICP-MS. Only two arsenic species, 2-dimethylarsinoyl ethanol (DMAE) and dimethylarsinic acid (DMAA), were positively identified in the water soluble extract of the marine brown algae. The two arsenic species are strong intermediate candidates in the biosynthesis of arsenobetaine from oceanic arsenate in marine food webs.
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41

Holz, J., J. Kreutzmann, R. D. Wilken, and R. Falter. "Methylmercury monitoring in rainwater samples using in situ ethylation in combination with GC-AFS and GC-ICP-MS techniques." Applied Organometallic Chemistry 13, no. 10 (1999): 789–94. http://dx.doi.org/10.1002/(sici)1099-0739(199910)13:10<789::aid-aoc908>3.0.co;2-n.

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42

Roussou, Konstantina, Alexandros K. Nikolaidis, Fani Ziouti, Aristidis Arhakis, Konstantinos Arapostathis, and Elisabeth A. Koulaouzidou. "Cytotoxic Evaluation and Determination of Organic and Inorganic Eluates from Restorative Materials." Molecules 26, no. 16 (2021): 4912. http://dx.doi.org/10.3390/molecules26164912.

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Over the last years, diverse commercial resin-based composites have dominated as dental filling materials. The purpose of the present study was to determine organic and inorganic eluates from five restorative materials using GC/MS and ICP–OES and to compare the effect on cell survival of human gingival fibroblasts of a conventional and a bioactive resin. Five commercially available restorative materials were employed for this study: ActivaTM Bioactive Restorative, ENA HRi, Enamel plus HRi Biofunction, Fuji II LC Capsule, and Fuji IX Capsule. Disks that were polymerized with a curing LED light or left to set were immersed in: 1 mL methanol or artificial saliva for GC/MS analysis, 5mL deionized water for ICP–OES, and 5mL of culture medium for cell viability. Cell viability was investigated with a modified staining sulforhodamine B assay.The following organic substances were detected: ACP, BHT, BPA, 1,4-BDDMA, CQ, DBP, DMABEE, HEMA, MCE, MeHQ, MOPA, MS, TMPTMA, and TPSb and the ions silicon, aluminum, calcium, sodium, and barium. Activa Bioactive Restorative was found to be biocompatible. Elution of organic substances depended on material’s composition, the nature of the solvent and the storage time. Ions’ release depended on material’s composition and storage time. The newly introduced bioactive restorative was found to be more biocompatible.
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43

Ritsema, R., T. de Smaele, L. Moens, A. S. de Jong, and O. F. X. Donard. "Determination of butyltins in harbour sediment and water by aqueous phase ethylation GC-ICP-MS and hydride generation GC-AAS." Environmental Pollution 99, no. 2 (1998): 271–77. http://dx.doi.org/10.1016/s0269-7491(97)00128-0.

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44

Laffont, Laure, Laurence Maurice, David Amouroux, et al. "Mercury speciation analysis in human hair by species-specific isotope-dilution using GC–ICP–MS." Analytical and Bioanalytical Chemistry 405, no. 9 (2012): 3001–10. http://dx.doi.org/10.1007/s00216-012-6116-2.

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45

Gajdosechova, Zuzana, Enea Pagliano, Andre Zborowski, and Zoltan Mester. "Headspace In-Tube Microextraction and GC-ICP-MS Determination of Mercury Species in Petroleum Hydrocarbons." Energy & Fuels 32, no. 10 (2018): 10493–501. http://dx.doi.org/10.1021/acs.energyfuels.8b02201.

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46

Pavageau, Marie-Pierre, Christophe Pécheyran, Martine Demange, and Olivier F. X. Donard. "Phosphine emission measurements from a tobacco factory using cryogenic sampling and GC-ICP-MS analysis." Journal of Analytical Atomic Spectrometry 18, no. 4 (2003): 323–29. http://dx.doi.org/10.1039/b212715f.

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47

Glindemann, Dietmar, Gunter Ilgen, Reimer Herrmann, and Thomas Gollan. "Advanced GC/ICP-MS design for high-boiling analyte speciation and large volume solvent injection." Journal of Analytical Atomic Spectrometry 17, no. 10 (2002): 1386–89. http://dx.doi.org/10.1039/b109951p.

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48

Rodríguez-González, Pablo, Jorge Ruiz Encinar, J. Ignacio García Alonso, and Alfredo Sanz-Medel. "Determination of butyltin compounds in coastal sea-water samples using isotope dilution GC-ICP-MS." J. Anal. At. Spectrom. 17, no. 8 (2002): 824–30. http://dx.doi.org/10.1039/b204169n.

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49

Vázquez Peláez, Marta, María Montes Bayón, J. Ignacio García Alonso, and Alfredo Sanz-Medel. "A comparison of different derivatisation approaches for the determination of selenomethionine by GC-ICP-MS." J. Anal. At. Spectrom. 15, no. 9 (2000): 1217–22. http://dx.doi.org/10.1039/b000505n.

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50

Ahamad, Syed Rizwan, Abdul Rahman Al-Ghadeer, Raisuddin Ali, Wajhul Qamar, and Suliman Aljarboa. "Analysis of inorganic and organic constituents of myrrh resin by GC–MS and ICP-MS: An emphasis on medicinal assets." Saudi Pharmaceutical Journal 25, no. 5 (2017): 788–94. http://dx.doi.org/10.1016/j.jsps.2016.10.011.

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