Dissertations / Theses: 'Geochemistry – South Africa – Rooiberg'

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Naude, Karin. "A mineralogical and geochemical study of the tin deposit at NAD-mine in the Rooiberg tin field." Thesis, Stellenbosch : Stellenbosch University, 1994. http://hdl.handle.net/10019.1/58243.

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Thesis (MSc.)--Stellenbosch University, 1994. ENGLISH ABSTRACT: The NAD deposit forms part of the A-Mine Complex in the Rooiberg tin field in the north-western Transvaal. Mining started in 1986 and the mine was closed recently following a decline of tin prices and metallurgical problems with ore recovery. The deposit is hosted by the Boschoffsberg Quartzite Member of the Pretoria Group sediments and is structurally controlled within the so-called Tin Zone. Extensive alteration of the original host rocks occurred during the mineralisation event. Potassic remobilisation and redistribution appear to have taken place pervasively. The nature of the original host rock was altered to such an extent that it cannot be classified correctly. Previous workers refer to the host rock as an arkose because of its feldspathic nature. Wall rock alteration in the hanging- and foot wall of the different ore lodes (fractures) is generally similar. Very little change is observed in whole rock chemistry away from the lodes. The mineral chemistry of the ore lode minerals is indicative of fluid composition and mineralising conditions in the NAD deposit. The FeO/(FeO + MgO) ratio of tourmalines indicates deposition at a distance from the source of the mineralising fluids. Pyrite trace element chemistry differs from that of the Leeuwpoort deposit, indicating changing fluid chemistry. Contrary to previous assumptions that the carbonate present is ankerite, abundant siderite occurrences were found. Pyrite may co-precipitate with siderite under specific physico-chemical conditions. Cassiterite is generally trace element poor and relatively enriched in Fe. Hydraulic brecciation of the fractures as well as the tourmaline chemistry are strong indicators of a hydrothermal origin for the NAD deposit. However, the origin of the hydrothermal fluids is still uncertain. AFRIKAANSE OPSOMMING: Die NAD- tinafsetting vorm dee/ van die A-Myn-kompleks in die Rooiberg tinveld in die noord-wes Transvaal. Die myn is in 1986 geopen en is onlangs gesluit weens swak tinpryse en metallurgiese ertsherwinningsprobleme. Die tinafsetting kom voor in die Boschoffsberg Kwartsiet lid van die Pretoria Groep sedimente. Dit is strukturee/ gekontroleer binne die sogenaamde Tin Sone. Vorige navorsers het na die waardgesteente as 'n arkose verwys op grand van die hoe veldspaat-inhoud. lntensiewe en uitgebreide verandering van die oorspronklike waardgesteentes het plaasgevind tydens mineralisasie. Deurdringende kalium-hermobilisering en -herverspreiding het plaasgevind. Die aard van die oorspronklike waardgesteente is egter tot so 'n mate verander, dat dit chemies nie korrek gek/assifiseer kan word nie. Wandrotsverandering van die verskil/ende ertsskeute in beide die voet- en dakgesteentes is baie soortge/yk. Die heelrotsgeochemie van die wandgesteentes verskil baie min weg van die ertsskeute af. Die mineraalchemie van die ertsskeut-minerale is aanduidend van die v/oeistofsamestelling en mineralisasietoestande van die NAD-tinafsetting. Die FeO/(FeO + MgO) verhouding van toermalyne dui daarop dat afsetting op 'n afstand vanaf die bron van die mineralisasie-vloeistowwe plaasgevind het. Die spoor-elementchemie van die NAD-piriete verskil van die piriete van die Leeuwpoort tinafsetting, wat verandering in vloeistofsamestelling aandui. In teenstelling met vorige aannames dat die karbonate in die Rooiberg tinafsettings as ankeriet bekend staan, is daar volop sideriet gevind. Piriet kristalliseer dikwels saam met sideriet onder spesifieke fisiese en chemiese toestande. Kassiteriet is meestal arm aan spoor-elemente, maar is relatief verryk in Fe. Hidroliese breksiering van die skeute en die toermalyn-chemie dui sterk op 'n hidrotermale oorsprong vir die NAD afsetting. Die bron van die vloeistowwe is nog nie definitief vasgestel nie. Digitized at 300 dpi Colour PDF format (OCR), using ,KODAK i 1220 PLUS scanner. Digitised, Ricardo Davids on request from IBL 10 September 2013

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Strauss, Toby Anthony Lavery. "Petrology and geochemistry of the basal gabbro unit, Uitkomst complex." Thesis, Rhodes University, 1996. http://hdl.handle.net/10962/d1005601.

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The Cu/(Cu+Ni) ratios associated with the Basal Gabbro also display the vertical reverse fractionation trend, supporting the supercooled margin model. The disseminated sulphides in the lowermost units, are regarded as being the result of sulphur saturation induced by contamination from the dolomitic and quartzitic xenoliths. This is supported by isotope data which indicate the high degree of contamination in the lowermost units of the Complex. The results of this study are used to propose a model for the petrogenesis and metallogenesis of the Uitkomst Complex, whereby the Complex is closely related to the Bushveld Complex. The Basal Gabbro, as supported by its chemistry and style of mineralisation (Cu-rich), represents a supercooled margin to the lowermost units of the Uitkomst Complex, which stoped upwards into the surrounding sediments, assimilating the country rock xenoliths, and precipitating sulphides. Following this was a period in which large quantities of magma moved laterally through the system before the magma flow waned, and closed system crystallisation ensued. As the body cooled, the primarily magmatic water was superceded by the hydrothermal magmatic water released from the xenoliths, and later by geothermally driven circulating meteoric water, producing the extensive alteration. This alteration was accompanied by considerable stress and the development of fractures and shears. Finally the Complex was itself intruded by diabase sills and later dolerite dykes.

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Faure, Kevin. "A stable isotope study of the Kaap Valley Tonalite, Barberton Mountain Land, South Africa." Master's thesis, University of Cape Town, 1989. http://hdl.handle.net/11427/15849.

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Bibliography: pages 100-109. The Kaap Valley Tonalite (KVT) was a homogenous hornblende+ biotite tonalite that had been subjected to overail propylitic and potassic alteration. Petrographic studies reveal that carbonate alteration and increased proportions of hydrous minerals occur along the KVT and Barberton greenstone belt contact zone, and along major shear zones within the KVT.

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Azzie, Bernadette Ann-Marie. "Coal mine waters in South Africa : their geochemistry, quality and classification." Doctoral thesis, University of Cape Town, 2002. http://hdl.handle.net/11427/4186.

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Folefoc, Asongbecap Daniel. "Geochemical study of soil salinity in a toposequence near Riebeeck West, South Africa." Master's thesis, University of Cape Town, 2005. http://hdl.handle.net/11427/10448.

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Bibliography: leaves 84-91. A geochemical investigation of salt distribution in soils of the semi-arid of Western Cape, South Africa, was carried out following a pilot study which revealed widespread soil salinity in the Berg River catchment. The present study looks at the distribution of the salts along a toposequence in a subcatchment of the Berg River underlain by Malmesbury Group shale. The objectives were: to investigate salt distribution in relation to landscape topography; to identify potentially harmful trace elements associated with the salinity; and to determine the processes responsible for salt distribution. Ten soil profiles were dug to a depth of 200 cm at points along a slope of angle 10.20 along and 367 m long. The profiles at the crest of the toposequence are underlain by silcrete and alluvium while Malmesbury shale parent material underlies the rest of the profiles. Contour drains disrupt the natural shape of the slope. The soil texture is loamy sand to clay loam at the crest and loamy to sandy-clay loam in the midslope. Mineralogy at the crest is quartz dominated and kaolinite occurs in the mid and lower slope.

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Tsikos, Harilaos. "The mineralogy and geochemistry of the Voëlwater banded iron-formation, Northern Cape Province." Thesis, Rhodes University, 1995. http://hdl.handle.net/10962/d1005589.

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Banded iron-formations (BIFs) are chemically precipitated sedimentary rocks in which Fe-rich bands or laminae alternate with Fe-poor ones. They formed within a specific time-span of the geological record. Their occurrence is restricted between 2.3 and 1.9 Ga, and characterises virtually all the major Precambrian-aged sedimentary basins of the world. The Precambrian Transvaal Basin in Griqualand West, South Africa, is noted for its well-developed BIF units. The Kuruman and Griquatown BIFs comprising the Asbesheuwels Subgroup (up to 1000m thick) are the best known and thickest of these. As far as metallogenesis is concerned, the Kuruman BIF is of major importance, for it carries the world's largest crocidolite (blue asbestos) deposits. The uppermost, youngest member of iron-formation deposition in the Griqualand West Sequence is represented by the Voëlwater BIF. The direct association between the latter and the giant Mn-deposits of the Kalahari Field, renders the Voëlwater association unusual, if not unique, in the geological record. The Voëlwater BIF represents a typical example of the so-called "Superior-type", and in the area of study it has undergone late-diagennetic to low-grade metamorphic processes. This is evident from the mineralogical composition and textural signature of the various BIF lithologies. Specifically, the minerals that make up the Voëlwater BIF are mainly chert(quartz), Fe-oxides (magnetite and hematite), Fe-silicates (greenalite, stilpnomelane, minnesotaite, riebeckite, Fe-mica), Fe-carbonates (members of the dolomite-ankerite series and siderite), calcite and pyrite. Soft-sediment deformation structures and shear-stress indicators are abundant in carbonate-rich and granular, silicate-rich BIF lithologies respectively. The bulk chemical composition of the study rocks is relatively simple and is characterised by the abundance of essentially three elements, namely Si, Fe, and Ca, which make up more than 90% of the total chemical composition of the Voëlwater BIFs. The detrital component of the study rocks is negligible. Mn-enrichments characterise all the transitional lithologies towards the interbedded Mn-orebodies, as well as the well-developed, hematitic BIF-unit between the Ongeluk lavas and the lower Mn-horizon. In terms of trace element composition, no significant enrichments or depletions, were encountered, except for some unusually high values of Sr and Ba and Co in carbonate-rich and Mn-rich lithologies respectively. Geochemical comparisons on the basis of major, trace and light rare-earth element composition verified the similarity between the Voëlwater BIF and other major Superior-type BIFs of the world (e.g. Kuruman, Griquatown, Sokoman, Biwabik, Gunflint, Mara-Mamba, Brockman, etc.). The processes that led to the formation of the Voëlwater BIFs may have been very similar to the ones described in various genetic models proposed in recent years. They would have involved a combination of: i. hydrothermal processes related to mid-ocean ridge (MOR) or hot-spot activity that acted as major iron suppliers; ii. storm-mixing in stratified oceans (bottom, anoxic, Fe⁺² reservoir-thermo- pycnocline zone-upper, mixed, SiO₂-saturated layer), largely dictated by seasonal changes and contemporaneous volcanism; iii. periodic, convection-driven upwelling mechanisms acting as major Fe-precipitators; and, iv. organic carbon productivity that was responsible for the anoxic diagenesis of the initial sediment. However, the origin of Fe and Mn for the genesis of the Voëlwater sediments was difficult to explain with typical convection-cell models in active mid-ocean ridges, in contrast to previous hypotheses. Instead, large-scale endogenous processes in the form of magma convection, underplating, differentiation and associated degassing, may have played a critical role in the supply of metals for the formation of large amounts of BIFs in the Precambrian. The present study of the Voëlwater BIF also bears strong implications regarding the metallogenesis of Mn in the Precambrian. The common association of Mn with carbonate-bearing sediments, the transitional character of the Voëlwater BIF towards carbonate lithologies (Mooidraai dolomites) and the critical timing of the deposition of the former in terms of the Precambrian atmospheric-lithospheric- hydrospheric evolution, may be important indicators for the exploration of large Mn-deposits in Precambrian sedimentary basins of the world.

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Riganti, Angela. "The geology and geochemistry of the north-western portion of the Usushwana Complex, South-Eastern Transvaal." Thesis, Rhodes University, 1992. http://hdl.handle.net/10962/d1005570.

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The 2.9 Ga old Usushwana Complex in the Piet Retief-Amsterdam area (south-eastern Transvaal) represents an exposed segment of a layered intrusion. It has the form of a dyke-like body elongated in a northwesterly direction, and extends to an estimated depth of 3000 -5500 m. Lithologically, the Complex consists of a cumulate succession of mafic rocks capped by granitoids and has intruded along the contact between the basement and the supracrustal sequences of the Kaapvaal Craton. Differentiation of an already contaminated gabbroic magma resulted in an ordered stratigraphic sequence comprising progressively more evolved lithotypes, with at least two imperfect cyclic units developed over a stratigraphic thickness of about 700 metres (Hlelo River Section). Meso- to orthocumulate textured gabbros and quartz gabbros grade upwards into magnetite- and apatite-bearing quartz gabbros, interlayered with discontinuous magnetitite horizons. The gabbros in turn grade into hornblende-rich, granophyric granodiorites. The differentiation process is regarded as having been considerably enhanced by the assimilation of acidic material, derived by partial melting of the felsic country rocks at the roof of the magma chamber. Recrystallisation of these rocks gave rise to the microgranites that locally overlie the granodiorites. Mineralogical, textural and geochemical features indicate a relatively advanced fractionation stage, suggesting that the exposed sequence of the Usushwana Complex in the study area represents the upper portion of the intrusion. No significant mineralised occurrences were identified. However, on the basis of similarities between the Usushwana Complex and other mafic layered intrusions which host significant ore deposits, it is suggested that economic concentrations of base metal(Cu-Ni) sulphides, PGE and chromitites are likely to be developed at lower stratigraphic levels.

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Tainton, Kenneth Melbourne. "The petrogenesis of Group-2 kimberlites and lamproites from the northern Cape Province, South Africa." Thesis, University of Cambridge, 1992. https://www.repository.cam.ac.uk/handle/1810/283683.

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Lanyon, Ruth. "Arsenic dispersion associated with the Barbrook gold mine in the Mpumalanga Province of South Africa." Master's thesis, University of Cape Town, 1997. http://hdl.handle.net/11427/22169.

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Bibliography: pages 123-137. Arseniferous sulphide-hosted gold deposits associated with the Barberton greenstone belt, located in the Mpumalanga province of South Africa, have been mined on various scales since late last century. The Barbrook mine is located close to the Swaziland border in an area of the Barberton mountainlands which forms part of the Kaap subcatchment of the Crocodile River. Scattered small communities depend on local streams and boreholes in the area for drinking and irrigation water. Hence, the prime motivation for this study was the potential risk to human health associated with enhanced As mobility as a result of the sulphide mineral weathering which accompanies gold mining and processing. Sampling of local waters, soils and sediments, as well as the ore and waste rock at Barbrook was undertaken during a week of fieldwork in August 1996. A range of chemical analyses were performed on the various samples, including As analysis by hydride generation-atomic absorption spectroscopy and inductively coupled plasma - mass spectrometry. The Barbrook ore bodies are structurally controlled and hosted by banded iron formation, carbonaceous shales and carbonate-bearing schists. Within these ore bodies, As is mainly associated with auriferous arsenopyrite (FeAsS), although minor amounts also occur within pyrite (FeS₂) and ullmannite (NiSbS). Of the streams which flow through the mining lease, those at most risk of As contamination are Barbrook Creek, Low's Creek and Crystal Stream. Low's Creek flows through the main mine area, adjacent to the level 1O mine adit entrance, and past the processing plant before converging with Barbrook Creek. The latter receives water from the Shiyalongubo Dam which is the main water source for the area. Immediately downstream of the level 10 mine adit entrance, the steep eastern bank of Low's Creek is lined for several hundred metres with waste rock containing low grade ore. Tailings material from the processing plant is pumped to two tailings dams located about 5 km to the northwest of the plant and close to Crystal Stream.

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Jolayemi, Olutula Olumayowa. "Chemical evolution of the Paleoproterozoic Rooiberg Group Kaapvaal Craton South Africa : new insights into the formation of a silicic large igneous province (SLIP)." Diss., University of Pretoria, 2017. http://hdl.handle.net/2263/63309.

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With an estimated erupted volume of 300,000 km3 and an areal extent of more than 200,000 km2, the Paleoproterozoic (2.06 Ga) silicic volcanic rocks of the Rooiberg Group (Kaapvaal Craton) in northern South Africa forms one of the largest and to the same time oldest silicic large igneous provinces (SLIPs) known. This large volume of rocks can be sub-divided into four formations: the Dullstroom, Damwal, Kwaggasnek and Schrikkloof Formations. The results of this study show that a clear chemostratigraphy (by using major elements such as TiO2, SiO2, Na2O, K2O, P2O2, MgO, and Fe2O3) can be established in the area north of Loskop Dam, dividing the rocks of the study area into the Damwal, Kwaggasnek and Schrikkloof formations. The studied rocks are characterized by aphanitic lavas bearing amygdales, spherulitic textures and flow-bands with some sedimentary and pyroclastic interbeds. The dacites could mainly be described as high-Mg felsites (HMF), whereas the rhyolites could be described as low-Mg felsites (LMF). The negative Eu anomaly, Nb and Ta values of the upper part of the Rooiberg Group range between 5.38-24.2 and 0.45-1.86 ppm, respectively, similar to crustal compositions. Furthermore, Nb/Ta values range from 10.91-14.83 (also similar to typical crustal compositions) while few samples from the Damwal Formation exhibit higher values of 15.13-16.02, similar to mantle-derived compositions. Tectonic discriminant diagrams show that the rocks used in this study evolved from fractional crystallization of a mafic liquid although all samples plot in fields with crustal signatures. Plot of ƐNd and 87Sr/86Sr show a mantle-derived origin for the upper part of the Rooiberg Group. However, ƐNd values of the upper part of the Rooiberg Group range between ~-10 to ~-6, typical of crustal composition or continental basalts formed in the crust. From the results, the Rooiberg Group exhibit both mantle (as observed in the Dullstroom and lower Damwal formations) and crustal signatures as exhibited by the Kwaggasnek and Schrikkloof formations. This is interprested as a result of the interaction of the thick crust and a shallow mantle source within the Bushveld Province during magmatism. Furthermore, similarities in geochemical signatures between the Rooiberg Group and selected SLIPs around the world suggest a similar origin for SLIPs by fractional crystallization of a mafic melt and melted (or assimilated) crustal material. Thesis (PhD)--University of Pretoria, 2017. Geology PhD Unrestricted

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Ramokgaba, Lesego. "Geochemistry and petrogenesis of kimberlite intrusions from the eastern lobe the Du Toitspan kimberlite pipe, South Africa." Master's thesis, University of Cape Town, 2020. http://hdl.handle.net/11427/32534.

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The Du Toitspan kimberlite pipe located on the outskirts of Kimberley South Africa, is one four Cretaceous aged major kimberlite pipes from the well-known Kimberley cluster, the type locality for archetypal group I kimberlites. Twenty-seven samples representative of various kimberlite intrusions from the eastern lobe of the Du Toitspan kimberlite pipe have been analysed for their whole-rock geochemistry and mineral chemistry (olivine and phlogopite) with the aim of developing semi-quantitative models that constrain their petrogenesis and characterise their respective source region(s). Investigated intrusions include; D13-phlogopite kimberlite, D14-monticellite kimberlite, D17-serpentinized phlogopite kimberlite, and several narrow (<1m) calcite kimberlite dykes ranging in texture from aphanitic to macrocrystic. The aphanitic calcite dykes were further sub-divided into; a phlogopite-rich calcite kimberlite, a perovskite-rich calcite kimberlite, opaque-rich calcite kimberlites and serpentine calcit e kimberlites.

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Mitchell, Andrew Alexander. "The petrology, mineralogy and geochemistry of the main zone of the Bushveld Complex at Rustenburg Platinum Mines, Union Section." Thesis, Rhodes University, 1988. http://hdl.handle.net/10962/d1001563.

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Union Section of Rustenburg Patinum Mines is situated in the northwestern part of the Bushveld Complex, some twenty kilometres north of the Pilanesberg Alkaline Complex. The mining lease area covers a roughly triangular segment of Lower, Critical and Main Zone rocks, transgressed to the north and south by magnetite-bearing ferrogabbro of the Upper Zone. The Main Zone at Union Section is the focus of this study. The prime source of sample material for the study is the deep exploration borehole SK2, but additional, supplementary samples were collected on surface and underground, as well as from a second surface exploration borehole, SK4. In line with the recommendations of SACS (1980), the top of the Critical Zone, and therefore the base of the Main Zone, is taken to be the top of the Bastard Cyclic Unit. Sharpe (1985) suggested that the succession from the base of the Main is an isotopically separate entity Zone up to the Pyroxenite Marker from the rest of the Bushveld layered succession. This is not strictly true, as there is evidence that more than one parental magma was involved in the formation of this interval. It is, however, true that there are fundamental differences, particularly in isotopic makeup, between the Main Zone rocks below the pyroxenite Marker and those above (the latter having been assigned by Molyneux (1970) to subzone C of the Main Zone). Kruger et al. (1986, in press) suggested that the Pyroxenite Marker marks the base of the Upper Zone, and this convention is adhered to here. The implication of this is that the rocks which formerly constituted subzone C of the Main Zone are now considered part of the Upper Zone. The Main Zone rocks below the pyroxenite Marker were originally subdivided by Molyneux (1970) into two subzones, A and B. The results of the present study indicate that this subdivision is not justified. Instead, eight units have been distinguished in the Main Zone on geochemical, petrological and mineralogical bases. Each of these units is characterized by a coherent set, or progression, of chemical and petrological characteristics. The specific assignment of genetic connotations to these units has been deliberately avoided , at least until further studies of the Main Zone prove this to be justified. The demarcation of the eight units is illustrated in the composite diagram (Fig. 34) in the back pocket of this work, and the reasons for the subdivisions are listed in Table 6 (at the end of chapter 7 of this thesis). Until the late 1970's, it was thought that most layered cumulates formed by crystal settling (Wager and Brown, 1968). More recently, there has been a fundamental conceptual change, and many workers now believe that most cumulate rocks formed by in situ crystallization at the floor and walls of the magma chamber (McBirney and Noyes, 1979, Irvine, 1980a; Campbell, 1987). There is, however, some evidence for the physical separation of phases undergoing cotectic crystallization, particularly in the Upper Critical Zone and lower part of the Main Zone (Eales et al., 1986). This process, which has been alluded to in the past by various authors (Ferguson and Botha, 1963; Vermaak, 1976) involves the flotation of early-formed plagioclase crystals due to their positive bouyancy in tholeiitic liquids. The result is an apparent decoupling of the chemistry of pyroxene and plagioclase, as in unit IV of the Main Zone, where plagioclase becomes more anorthitic upwards, whilst pyroxene becomes more iron-rich. There is some substantial evidence, particularly in reversals in the strontium isotope initial ratio and the orthopyroxene Mg/(Mg+Fe) ratio , for multiple intrusion in the Main Zone. Although the largest and most important magma influx in the Main Zone was a high-R₀ aluminous tholeiite, as suggested by Sharpe (1985), the intrusive history of the Main Zone is believed to be far more complex than Sharpe (op. cit.) suggested. Significantly, there is strong evidence for small influxes of Upper Zone-type (Fe-rich tholeiite) magma in the upper reaches of the Main Zone. These are believed to be precursors to the major influx of Upper Zone-type magma at the pyroxenite Marker (Kruger et al, 1986, in press). The fate of intercumulus liquids in cumulate rocks has recently recieved substantial attention (Sparks et al., 1985; Morse, 1986; Barnes, 1986: Campbell, 1987). It is believed that the migration, or at least redistribution, of intercumulus liquids has played a vital role in modifying fractionation trends in the Main Zone. More importantly, the accumulation of late-stage intercumulus liquids is believed to be responsible for the formation of the Fe-rich ultramafic pegmatite bodies that interrupt the layered cumulates in borehole SK2 Adobe Acrobat 9.53 Paper Capture Plug-in

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Polteau, Stéphane. "Stratigraphy and geochemistry of the Makganyene formation, Transvaal supergroup, Northern Cape, South Africa." Thesis, Rhodes University, 2001. http://hdl.handle.net/10962/d1005616.

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The Makganyene Formation forms the base of the Postmasburg Group in the Transvaal Supergroup of the Northern Cape Province. The Makganyene Formation has diamictite as the main rock type, but siltstone, sandstone, shale, and iron-formations are also present. A glacial origin has been proposed in the past due to the presence of dropstones, faceted and striated pebbles. Typically, the Makganyene Formation contains banded iron-formations interbedded with clastic rocks (shale, siltstone, sandstone and diamictites) at the contact with the underlying iron-formations. This transitional zone is generally overlain by massive or layered diamictites which contain poorly sorted clasts (mainly chert) within a shaly matrix. Striated pebbles have been found during field work, and dropstones have been observed in diamictites and banded iron-formations during the study. The top of the Makganyene Formation contains graded cycles interbedded with diamictites and thin layers of andesitic lavas from the Ongeluk Formation. The basal contact of the Makganyene Formation with the underlying Koegas Subgroup was described as unconformable by previous workers. However field work localised in the Rooinekke area shows a broadly conformable and interbedded contact with the underlying Koegas Subgroup. As described above, banded iron-formations are interbedded with the clastic rocks of the Makganyene Formation. Moreover, boreholes from the Sishen area display the same interbedding at the base of the Makganyene Formation. This suggests that no significant time gap is present in the whole succession between the Ghaap and Postmasburg Group. The Transvaal Supergroup in the Northern Cape displays the following succession : carbonates-BIFs-diamictites/ lava-BIFs-carbonates. The Makganyene Formation is thus at the centre of a symmetrical lithologic succession. Bulk rock compositions show that the diamictites have a similar composition to banded iron-formation with regard to their major element contents. Banded iron-formations acted as a source for the diamictites with carbonates and igneous rocks representing minor components. Differences in bulk composition between the Sishen and Matsap areas emphasize that the source of the diamictite was very localised. The Chemical Index of Alteration (CIA) has been calculated, but since the source dominant rock was iron-formation, this index cannot be usefully applied to the diamictites. ACN, A-CN-K, and A-CNK-FM diagrams confer a major importance in sorting processes due to the separation between the fine and coarse diamictites. The interbedded iron-formations display little clastic contamination indicating deposition in clear water conditions. However, dropstones are present in one borehole from the Matsap area, indicating that iron-formation took place under ice cover, or at least under icebergs. Stable isotope studies show that the iron-formations, interbedded towards the base of the Makganyene Formation, have similar values to the iron-formations of the Koegas Subgroup. As a result of the above observations, new correlations are proposed in this study, relating the different Transvaal Supergroup basins located on the Kaapvaal Craton. The Pretoria Group of the Transvaal Basin has no correlative in the Griqualand West Basin, and the Postmasburg Group of the Northern Cape Basin has no lateral equivalent in the Transvaal Basin. These changes have been made to overcome problems present in the current correlations between those two basins. The Makganyene Formation correlates with the Huronian glaciations which occurred between 2.4 and 2.2 Ga ago in North America. Another Precambrian glaciation is the worldwide and well-studied Neoproterozoic glaciation (640 Ma). At each of these glaciations, major banded iron-formation deposition took place with associated deposition of sedimentary manganese in post-glacial positions. The central position of the Makganyene Formation within the Transvaal Supergroup in the Northern Cape emphasizes this glacial climatic dependence of paleoproterozoic banded iron-formation and manganese deposition. However these two Precambrian glaciations are interpreted in paleomagnetic studies as having occurred near to the equator. The controversial theory of the Snowball Earth has been proposed which proposes that the Earth was entirely frozen from pole to pole. Results from field work, sedimentology, petrography and geochemistry were integrated in a proposed depositional model of the Makganyene Formation occurring at the symmetrical centre of the lithologic succession of the Transvaal Supergroup. At the beginning of the Makganyene glaciation, a regression occurred and glacial advance took place. The diamictites are mostly interpreted as being deposited from wet-based glaciers, probably tidewater glaciers, where significant slumping and debris flows occurred. Any transgression would cause a glacial retreat by rapid calving, re-establishing the chemical sedimentation of banded iron-formations. These sea-level variations are responsible for the interbedding of these different types of rocks (clastic and chemical). The end of the Makganyene glacial event is characterised by subaerial eruptions of andesitic lava of the Ongeluk Formation bringing ashes into the basin. Banded iron-formation and associated manganese accumulations are climate-dependant. Glacial events are responsible for the build up of metallic ions such as iron and manganese in solution in deep waters. A warmer climate would induce a transgression and precipitation of these metallic ions when Eh conditions are favourable. In the Transvaal Supergroup, the climatic variations from warm to cold, and cold to warm are expressed by the lithologic succession. The warm climates are represented by carbonates. Cold climates are represented by banded iron-formations and the peak in cold climate represented by the diamictites of the Makganyene Formation. These changes in climate are gradual, which contradict the dramatic Snowball Earth event: a rapid spread of glaciated areas over low-latitudes freezing the Earth from pole-to-pole. Therefore, to explain low-latitude glaciations at sea-level, a high obliquity of the ecliptic is most likely to have occurred. This high obliquity of the ecliptic was acquired at 4.5 Ga when a giant impactor collided into the Earth to form the Moon. Above the critical value of 54° of the obliquity of the ecliptic, normal climatic zonation reverts, and glaciations will take place preferentially at low-latitudes only when favourable conditions are gathered (relative position ofthe continents and PC02 in the atmosphere).

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Teigler, Bernd. "Mineralogy, petrology and geochemistry of the lower and lower critical zones, Northwestern Bushveld Complex." Thesis, Rhodes University, 1991. http://hdl.handle.net/10962/d1005590.

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This study of the lower part of the Rustenburg Layered Suite in the Western Bushveld Complex is based mainly on drill core samples from three localities, which are approximately 130 km apart. The NG-sequence, situated in the northwestern sector of the complex (Union Section, R.P.M.) extends from the floor of the complex to the base of the upper Critical Zone. The sequence is ca. 1800 m thick and it comprises mainly ultramafic cumulates, namely pyroxenites, olivine pyroxenites, harzburgites and dunites. Norites and anorthos ites are present only in minor proportion. Within the upper half of the NG-sequence ten prominent chromitite layers are correlated with the LGI MG4-interval. Correlation is also established between published sequences and the two other sequences studied, located 8 km and 55 km, respectively, east of Rustenburg. Whole-rock chemical data (major and trace elements), microprobe and Sr isotope data are presented. Petrographic studies provide modal analyses and measurements of grain size. All petrographic, mineralogical and other geochemical data point to an origin of the cumulates of the NG-sequence by crystallization from liquids of the U-type lineage and derivatives thereof. No evidence is found for the involvement of parental liquids with a distinctly different composition or crystallization order (A-liquids). However, subtle compositional variations of the parental liquids are evident in slight changes of the Cr content in orthopyroxene or in variations of Sr isotope ratio. The NG-sequence is characterized by intervals with reversed fractionation trends caused by repeated influxes of pristine magma (during periods of high magmatic activity) resulting in a high degree of rejuvenation. These intervals are overlain by others with a normal fractionation trend, interpreted as cumulates formed in periods with low or no magmatic activity, in which fractional crystallization controlled bulk composition of the evolving liquid. The Lower Zone in the NG-sequence is dominated by a progressive shift towards more primitive compositions, while in the Critical Zone fractionation was the major operating process in the magma chamber. However, during deposition of the pyroxenitic lower Critical Zone several replenishment events occurred, during which fresh Cr-rich magma was emplaced. Massive chromitite layers were deposited after mixing between the newly emplaced magma and the resident residual liquid shifted bulk compositions into the primary field of chrome-spinel. Cumulus plagioclase crystallized after bulk composition of the residual liquid was driven to the orthopyroxene plagioclase cotectic by continued fractional crystallization; this occurred once in the Lower Zone, yielding a single, thin norite layer, and again in the upper Critical Zone of the NG-sequence. A facies model is proposed based on the stratigraphic and compositional variations along strike in the Western Bushveld Complex. This model explains the variations by means of the position of the sequence with regard to a feeder system. The olivine- and orthopyroxene-rich, but plagioclase-poor NG-sequence represents the proximal facies, while the SF-sequence (poor in ferromagnesian phases, but plagioclase-rich) is developed as a distal facies, close to the Brits graben.

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Lanz, Johann. "A geochemical investigation of the waters and sediments of De Hoop Vlei, Bredasdorp district, South Africa." Master's thesis, University of Cape Town, 1997. http://hdl.handle.net/11427/20190.

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Bibliography: pages 117-121. De Hoop Vlei is a saline coastal lake situated 53 kilometres north-east of Cape Agulhas in the Western Cape Province of South Africa. It is probably of estuarine origin but is now separated from the sea by mobile sand dunes and, therefore, has no surface outflow. Inflow to the vlei is from a catchment area of approximately 1200 km2 in which intensive grain farming is practised. The vlei is situated within the De. Hoop Nature Reserve and its ecological value, particularly as a breeding ground for water birds, has been recognised in its designation as an international RAMSAR conservation site. Agricultural practices in the catchment have been identified as a potential threat to the ecology of the vlei. The overall objective of this study was to provide a geochemical characterisation of De Hoop Vlei. It focused on identifying the geochemical factors and processes which control the water chemistry of the vlei and attempted to identify any influence of agricultural activities on water quality. This was achieved through a geochemical interpretation of the results obtained from analyses of water and sediment samples collected during the study. Use was also made of Department of Water Affairs and Forestry monitoring data in order to examine long term behaviour of the system, particularly with respect to the effect of evaporative concentration on water composition. Furthermore, chemical equilibrium was modelled, using the geochemical model MINTEQA2, in order to give an indication of processes likely to occur in the water as well as the behaviour of certain possible pollutants in the vlei. Water and sediment core samples, collected during two separate sampling trips, were taken along the entire length of the vlei and some water samples were taken in the catchment. Interstitial waters were obtained by suction from sediment cores. Samples of secondary precipitates, found along the edge of the vlei, were also taken. The following laboratory analyses were performed on water samples: pH, EC, alkalinity, major cations and anions, dissolved P, fluoride, and the trace metals Fe, Mn, Al, Ni, Cu, Zn, and Pb. The following laboratory analyses were performed on sediment samples: pH of wet and dried sediments, organic C content, carbonate content, total elemental concentrations of major and trace elements, mineralogy, clay percentage and extractable P, Zn and K. Scanning electron microscopy and mineralogical analyses were performed on samples of secondary precipitates.

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16

Merrett, Greg Lee. "Groundwater redox conditions at a petroleum contaminated site, Kuils River, South Africa : pathways for BTEX biodegradation." Master's thesis, University of Cape Town, 2003. http://hdl.handle.net/11427/8588.

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Includes bibliographical references (leaves 84-88). A shallow sandy aquifer, contaminated by petrol from an underground storage tank, was studied to determine if intrinsic bioremediation of the hydrocarbons is taking place. Groundwater samples taken from 32 monitoring wells were analysed for NO₃-,NH₄+, Mn²+, Fe²+, SO₄²-, and ΣH₂S. Portable electrodes were used to make field measurements of electrical conductivity, redox potential, and pH. The variation and distribution of these redox-sensitive groundwater constituents show that bioremediation via NO₃- reduction, Fe³+ reduction, and SO₄²- reduction (and possibly methanogenesis in the most reduced part of the plume) is occurring. In some cases redox processes are taking place simultaneously resulting in redox zones that overlap. Iron and sulphate reduction are the dominant processes taking place.

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Palmer, David A. S. "The evolution of carbonatite melts and their aqueous fluids : evidence from Amba Dongar, India, and Phalaborwa, South Africa." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1998. http://www.collectionscanada.ca/obj/s4/f2/dsk1/tape11/PQDD_0025/NQ50232.pdf.

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18

Marageni, Manoka. "The geochemistry and petrogenesis of the Saltpeterkop carbonatite complex near Sutherland, Northern Cape, South Africa." Master's thesis, University of Cape Town, 2018. http://hdl.handle.net/11427/29818.

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The Saltpeterkop Carbonatite Complex is a Late Cretaceous (≈76 Ma) volcanic and shallow intrusive magmatic feature located approximately 20 km southeast of Sutherland in the Northern Cape. It is unusual among southern African carbonatite complexes in that it has not been deeply eroded, and retains a significant vestige of its original volcanic features. The main geologic expression of the Complex is a ≈1.5 km diameter tuff ring, located on top of prominently updomed and fractured Beaufort Group (Karoo) sediments, that appears to have formed as the result of a major diatreme-type eruption. The volcaniclastic breccias making up the tuff ring have been heavily altered and silicified by hydrothermal activity, and thick (mm to tens of cm) Fe oxide-rich crusts, which appear to represent the alteration products of Fe-rich carbonatites, are common in this area. Outside of the central ring structure are numerous shallow intrusions (dykes, sills and irregular shapes), satellite breccia pipes and pipe-shaped intrusions that host fresh to only moderately altered igneous rocks. The main igneous rock types include (in decreasing order of abundance): carbonatite, potassic trachyte, olivine melilitite and ultramafic lamprophyre. This thesis provides the first detailed petrographic and geochemical description of these rocks (e.g., major and trace elements) and attempts to explain several aspects of their petrogenesis. The olivine melilitites and ultramafic lamprophyres are the most primitive igneous rocks in the complex and have experienced only minor to moderate extents of differentiation, respectively. They apppear to have been derived by low-degrees of partial melting of a carbonated, likely phlogopite-bearing mantle source. The lamprophyres appear to have been derived by melting at shallower depths than the melilitites based on REE constraints. The carbonatites range from relatively primitive to highly differentiated and they form a nearly continuous compositional range with the ultramafic lamprophyres and melilitites. This seems to argue against a major role for liquid immiscibility in their origin. Their REE content (up to 2 wt.% total REE oxides) correlates with their extent of differentiation. The potassic trachytes are plausibly linked to melts of mafic lower continental crust that has been metasomatised by hydrous potassium-rich carbonatitic melts and which have experienced significant fractional crystallization and assimilation of upper crustal sedimentary rocks during emplacement.

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Mc, Keown Stephen. "Geochemistry and amelioration of a sulphur contaminated environment near Somerset West, South Africa." Master's thesis, University of Cape Town, 2000. http://hdl.handle.net/11427/4211.

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Bibliography: leaves 100-104. The key objectives of this study are, firstly, to determine the extent and effects of the S contamination and secondly, to determine an effective means of ameliorating the site.

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Sugarman, David R. "Soil chemical properties in pine plantations of different ages in the Eastern Escarpement region of South Africa." Master's thesis, University of Cape Town, 1999. http://hdl.handle.net/11427/9880.

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Bibliography: leaves 71-78. It is widely accepted that afforestation adversely affects soil chemical properties. A significant decrease in pH, base cation status and acid neutralising capacity (ANC), coupled with increasing acidity have been observed to occur in acid coniferous forest soils both in the Northern and Southern Hemispheres. International and local studies in Southern Africa have observed declining productivity over successive rotations in pine plantations. Increasing acidity loads in the Northern Hemisphere and their adverse effects on forest health have generated a search for chemical indices that would assist in pursuing thresholds beyond which forest vitality is damaged. A common and widely used chemical index is the Ca/Al ratio. The most common parameter adopted is the Ca/Al molar ratio in soil solutions. Recent studies in Southern Africa (Swaziland. Kwazulu-Natal) and in the Sabie area (Eastern Escarpment) have indicated that some forest compartments (Pinus sp.) may experience Ca/Al molar ratios dropping below unity. The value of unity is widely used and proposed as a threshold beyond which tree vitality may be adversely affected. This study was conducted to determine the state of surface (0-20cm) soils underlying pine plantations of different ages in the Sabie area on the Eastern Escarpment of Southern Africa. The pine plantations were selected in areas overlying a uniform bedrock (shale), high attitude, high rainfall, north facing aspect and confined to 3 pine species (P. elliottii, P. patuia and P. taeda). A composite sample was taken from each of 22 forest compartments varying in age (between 22 and 67 years) and rotation (first, second and third). In addition, the results of previous investigations of forest soils in the Eastern Escarpment region were considered in order to expand the array of forest compartment ages and the size of the overall data set used for statistical analysis, so that comparisons could be made.

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Haikney, Susan Ann. "The nature of olivine-rich cumulate rocks of the lower critical and lower zones of the northwestern Bushveld Complex." Thesis, Rhodes University, 1993. http://hdl.handle.net/10962/d1005592.

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Boreholes NG1 and NG2 were drilled on the farm Nooitgedacht 406 KQ to intersect the lower Critical and lower Zones of the western Bushveld Complex. The aim of this study is to describe the textural features and chemical characteristics of the olivine-bearing rocks in the intersections, as determined by petrographic studies, XRF analysis and microprobe analysis. The olivine-bearing rocks are dunites, harzburgites and olivine pyroxenites. They comprise olivine and orthopyroxene, with minor chromite, clinopyroxene and plagioclase, and their textures vary between adcumulate, mesocumulate and poikilitic. The sequence intersected can be broadly correlated with that in the eastern Bushveld Complex. Of the whole-rock inter-element ratios, the MMF (MgO)/[MgO+FeO])ratio is the clearest indicator of cyclicity. The olivine-rich rocks are more primitive than the associated rocks, and seem to become more primitive with height in most intervals. The plagioclase in the olivine-bearing rocks is unusually sodic in corrposition, having a maximum Na₂0 content of 8.12%. A comparison of olivine and plagioclase compositions with those in other intrusions has revealed that the only other major intrusion with sodic plagioclase is the Kiglapait intrusion of Canada. In the Kiglapait intrusion the sodic plagioclase occurs in conjunction with fayalitic olivine as opposed to the forsteritic variety of this study. Chemical variations in the rocks sampled indicate that periodic replenishment of the magma from which the rocks crystallised must have occurred. In some of the olivine-bearing intervals where little fractionation is evident, replenishment seems to have been continuous. In other intervals fractionation appears to have continued uninterrupted for significant periods, prior to rejuvenation by fresh influxes of magma.

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22

Terracin, Matthew Theodore. "Petrography, geochemistry and origin of atypical sedimentary-igneous contact relationships at the base of the Hotazel Formation around Middelplaats, Northern Cape Province, RSA." Thesis, Rhodes University, 2014. http://hdl.handle.net/10962/d1012985.

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In the Middelplaats mine area of the Kalahari manganese field, two drill holes (MP53 and MP54) intersected anomalously high-grade manganese ore sitting stratigraphically just above an igneous body (likely a dike or sill). Manganese ore located within approximate 5 meters of the contact with the underlying igneous rocks has been substantially metasomatically upgraded from 25 percent manganese, to over 40 percent whilst the dominant manganese species within the ore has been altered to hausmannite. This report demonstrates the metasomatic alteration is related to devolatilization (removal and/or remobilization of H₂O, CO₂ and CaO) due to contact metamorphism caused by the underlying igneous rocks. The Middelplaats mine is situated in the southwest corner of the Kalahari manganese field where the paleo basin shallows out and ends. Within the mine area, several stratigraphic units pinch out or are truncated by the side of the basin. This pinching out of lithological formations has led to the underlying Ongeluk Formation being in contact with the much younger units of the Hotazel Formation. Therefore, geochemical investigation into the nature and source of the igneous rocks was also undertaken to see if the rocks from the two drill holes were related to one another and/or the underlying Ongeluk Formation. Results of these geochemical studies have demonstrated that the Middelplaats igneous rocks (dolerites) from the two drill holes (MP53 and MP54) share a co-genetic source region. There is also reasonable geochemical evidence that the source region of the Middelplaats igneous rocks was substantially similar to the source region of the Ongeluk Formation. This may indicate that the source region of the Ongeluk Formation was reactivated at some later stage resulting in the emplacement of doleritic dikes or sills in the Middelplaats mine area. The Middelplaats igneous rocks were also found to have undergone a slight but pervasive potassic alteration; with most of the original plagioclase feldspar showing some level of replacement by a potassium enriched feldspar. Although no source for this potassic fluid was found, the devolatilization reaction within the manganese ore appears to have released some potassium into the surrounding rocks. This additional potassium may be responsible for some localized potassic alteration.

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Rasmeni, Sonwabile. "Lithostratigraphic correlation, mineralogy and geochemistry of the lower manganese orebody at the Kalagadi Manganese Mine in the Northern Cape Province of South Africa." Thesis, University of Fort Hare, 2012. http://hdl.handle.net/10353/d1016155.

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The Kalagadi Manganese mine in the Kuruman area of the Northern Cape Province of South Africa contains reserves of Mn ore in excess of 100Mt. Mineralization in the mine lease area is restricted within the Hotazel Formation of the Voȅlwater Subgroup, belonging to the Postmasburg Group, the upper subdivision of the Transvaal Supergroup. Surface topography is characterized by flat lying, undulation with minimal faulting and the ore are slightly metarmophosed. This study investigates the general geology of the mine, lithostratigraphic subdivision and correlation of the economic Lower Manganese Orebody (LMO) of the Kalagadi Manganese Mine in order to guide mining plan and operations once the mine is fully commissioned. At the commencement of this study, Kalagadi Manganese mine was a project under exploration with no specific geology of the mine lease area and no lithostratigraphic subdivision. The study also aimed determining the extent of lithostratigraphic correlation between the LMO economic orebodies of the Kalagadi Manganese mine with that of underground Gloria and open-pit Mamatwan mines. Four methods including petrographic microscope, Scanning electron Microscope (SEM), X-ray diffraction (XRD) and X-ray fluorescence (XRF) analyses were applied mainly for the mineral identification, chemical composition and ore characterization of the Lower Manganese Orebody (LMO) at Kalagadi Manganese mine. The results of this study indicates the following: (1) Eleven textural distinct zones with economic zones restricted to the middle while the lower grade zones are confined to the top and bottom of the LMO; (2) The economic zones, comprising of Y, M, C and N subzones attain an average thickness of 10 m and are graded at an average of 40% Mn while the Mn/Fe ratio varies from 6 to 9; (3) The most economic zones are M and N subzones which are mostly characterized by oxidized ovoids and laminae, a characteristic applicable even to other zones of economic interest; (4) Braunite is the main mineral of the manganese ore and is often integrown with kutnahorite and other minerals (hematite, hausmannite, Mg-calcite, calcite, jacobsite, serpentine and garnet) which are present in variable amounts; (5) The Mg-rich calcite (Ca, Mg)CO3 is the second dominant manganese carbonate mineral and it corresponds to elevated MgO concentration and is often associated with marine environment. The occurrence of the Mgcalcite is not common in the manganese ore of this area except for the Mn-calcite, which was not determined by XRD analyses in this study; (6) MnO is the most abundant major oxide in the manganese ore while other major oxides present in decreasing order of abundance are CaO, SiO2, Fe2O3, and MgO. The oxides TiO2, Na2O, K2O, Al2O3, and Cr2O3 are depleted and are mostly  0.01wt% and  0.001wt% respectively while P2O5 concentrations are low ranging from 0.02wt% to 0.3wt%. The trace element concentrations of Ba, Zn and Sr in most borehole samples are slightly elevated ranging from 100ppm to 3.9% (36000pm) while Co, Cu, Ni, Y, As, Zr, V and La rarely exceed 50ppm. The enrichments of Cu, Zn, Ni, Co and V that are commonly associated with volcanogenic hydrothermal input in chemicals may reach up to 70ppm; (7) The mineralogical and geochemical characteristics of the manganese ore in the Kalagadi Manganese mine lease area are similar to that of Low-Grade Mamatwan-Type ore. The cyclicity (Banded Iron Formation ↔ Hematite lutite ↔ braunite lutite) and alternation of manganese and iron formation have been confirmed; and (8) The oxygen δ18O isotope values (18‰ to 22‰) indicate a slight influence of metamorphism of the manganese ore. No positive correlation exists between δ13C vs δ18O values and Mn vs δ13C values. Such observations indicate minimal action of organic carbon during manganese precipitation where the organic matter was oxidized and manganese content reduced. On the other hand, the manganese carbonates (CaO) are positively correlated with carbon isotope, this indicates diagenetic alteration and the involvement of biogenic carbonate during the formation of manganese carbonates. It is concluded that the lithostratigraphic subdivision at Kalagadi Manganese mine is best correlated physically, mineralogically and geochemically with that of Gloria mine operating in the Low Grade Mamatwan - Type ore while correlation with an open-pit Mamatwan mine is also valid.

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Viljoen, K. S. "Petrology of the Sutherland Commonage melilitite intrusives." Master's thesis, University of Cape Town, 1988. http://hdl.handle.net/11427/22496.

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The petrology of the Sutherland Commonage olivine melilitite intrusives have been investigated using petrographic and chemical methods. The occurrence consists of a ring dyke which surrounds a centrally located sill complex. The rock of the ring dyke is a typical melilitite which consists of olivine in a groundmass of melilite, clinopyroxene, opaque spinel, nepheline and perovskite. The sill complex is a multiple intrusion and is comprised of a lower green melilitite and an overlying (and younger) grey melilitite. The green melilitite is deuterically altered and the original mineralogy is destroyed to a large extent. The grey melilitite contains autoliths of the green and is a fairly typical monticellitic melilitite in which phenocrysts of olivine are set in a groundmass of melilite, monticellite, opaque spine!, nepheline and perovskite. Microprobe analyses of clinopyroxenes indicate that they are aluminous titanian diopsides and salites which exhibit complex zonation patterns. They record magmatic conditions ranging from the intrusive stage to a final phase of magmatic evolution during which a vapour phase evolved after the majority of the groundmass minerals had crystallised. The chemistry of olivine phenocrysts suggests that the parent magma to the Commonage intrusives accumulated in a temperature-zoned reservoir at the base of the lithosphere. Large, unzoned olivine phenocrysts crystallised in this chamber. Subsequent rupture of the chamber and ascent of magma led to supercooling and the crystallisation of abundant, strongly zoned phenocrysts of smaller size. Olivine crystallisation continued until the magma reached crustal levels. It is inferred from the chemistry of chromites and magnetites that the magma in the ring dyke was more evolved than those in the sill complex and that very oxidising conditions prevailed in the grey melilitite during the crystallisation of magnetite in this intrusive type. The high fO₂ may have resulted from the degassing of CO₂ after intrusion. Major and trace elements have been analysed for in eleven whole rock samples and the ⁸⁷Sr/⁸⁶Sr ratio was determined for seven of the same samples. The results of the geochemical study suggest that the Commonage melilitites were derived by the melting of a recently metasomatised region of the asthenosphere, probably under the influence of an ocean-island-type hotspot situated in the lower mantle.

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Appleyard, Clare M. "The geochemistry of a suite of eclogite xenoliths from the Rietfontein Kimberlite, South Africa." Master's thesis, University of Cape Town, 2000. http://hdl.handle.net/11427/4185.

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Includes bibliography. The Rietfontein kimberlite is an off-craton kimberlite pipe, located west of the Kaapvaal Craton at 26.75°, 20.04°E and hosts a range of xenocryst lithologies, including peridotite, eclogite and a suite of megacryst minerals. This study focuses on a suite of eclogite xenoliths, which were subject to a detailed petrographical and geochemical study, aimed at their characterisation and comparison to eclogites from on-craton and other off-craton localities. Garnet, clinopyroxene, accessory and secondary minerals were analysed for major element compositions using electron microprobe techniques and garnet and clinopyroxene trace element compositions were determined by Laser Ablation Inductively-Coupled-Plasma Mass Spectrometry (LA-ICP-MS) techniques. Oxygen isotopic compositions of five garnet samples were obtained using laser flourination techniques, followed by analysis by gas source mass spectrometry.

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26

Slabber, Nina. "The geology and geochemistry of the Bridgetown Formation of the Malmesbury Group, Western Cape Province." Thesis, Stellenbosch : Stellenbosch University, 1995. http://hdl.handle.net/10019.1/54889.

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Thesis (MSc) -- Stellenbosch University , 1995. ENGLISH ABSTRACT: A number of small greenstone bodies of the Bridgetown Formation are exposed as elongated lenses and dykes within metasediments of the Malmesbury Group in the Western Cape Province, South Africa. The Malmesbury Group is part of the Neoproterozoic to Cambrian (Namibian) Saldania Subprovince which is the southern continuation of a Pan-African mobile belt system. A detailed geological and geochemical study was conducted on the largest outcrop of the Bridgetown Formation, situated 20km east of the town Moorreesburg. The Bridgetown Formation consists of a meta-volcano-sedimentary sequence that experienced polyphase deformation and metamorphism up to the lower greenschist facies. Tectonically, the Bridgetown Formation is included in the Boland tectonic domain, east of the Piketberg-Wel lington fault zone that is suggested to run Skm west of Heuningberg and subparallel to the Berg River. This agrees with Rabie's (1974) original subdivision of the tectonic domains. The Bridgetown Formation consists of: i) A basal unit of poorly differentiated alkaline metabasalt with a within-plate tectonomagmatic fingerprint. ii) An intermediate unit of poorly differentiated tholeiitic metabasalt, intruded by a younger tholeiitic metabasite with a low degree of differentiation. Both members of the intermediate unit have ocean-floor basalt (P-type MORB) and island arc basalt fingerprints. iii) An upper unit of poorly differentiated as well as more evolved alkaline metabasalts, interlayered with metatuff with an alkaline basaltic composition, metasedimentary rocks with a marine origin, and graphitic schists and muscovitequartz schists, both with a continental crust provenance. iv) An overlying metasedimentary sequence including dolomite, massive and oolitic chert, jasper and jaspilite. The Bridgetown Formation probably also comprises a lower metamorphosed ultramafic unit, indicated by the association of Ni- and Cr-rich talc bodies, Ni-and errich banded chert, chlorite schist and small dolomite-talc-chlorite bodies at Spitskop, situated directly northwest of the main greenstone body. The sequence of eruptive stages and the geochemistry of the metavolcanics resemble Hawaiian volcanism , indicated by an initial deep water stage of alkaline magmatism, followed by main tholeiitic edifice and post-caldera alkaline magmatism. Post-caldera alkaline magmatism occurred contemporaneously with deposition . of sediments and chemical precipitates (carbonates and cherts). The Bridgetown metavolcanics have no magmatic association with either the Bloubergstrand volcanics or mafic and intermediate plutonic rocks in the Malmesbury Group. However, some physical and geochemical similarities exist between the Bridgetown Formation and the age related Grootderm Formation of the Marmora Terrane (Gariep Supergroup) which is considered to represent ophiolitic material. The Bridgetown Formation probably represents segments of oceanic crust, including seamounts of oceanic islands, which were tectonically emplaced in an accretionary prism zone during subduction of oceanic crust underneath the Kalahari Craton, 600 to 700 Ma ago. This resulted in the present spatial configuration of various small greenstone bodies in the Malmesbury Group. To date no exploitable mineral deposits have been found 1n the Bridgetown Formation. However, Au and As anomalies in stream sediment and soil samples, taken in the Spitskop area, require further attention. lt is suggested that the gold and arsenic is hosted in brittle deformed clear to milky quartz veins which developed at zones of competency contrasts in all the li tholog ies in the Spitskop area. AFRIKAANSE OPSOMMING: 'n Aantal klein groenskisliggame van die Bridgetown Formasie is blootgestel as verlengde lense en gange binne metasedimente van die Malmesbury Groep in die Wes-Kaap Provinsie, Suid-Afrika. Die Malmesbury Groep is deel van die Neoproterozo·iese tot Kambriese (Namibiese) Saldania Subprovinsie wat die suidelike voortsetting is van 'n Pan-Afrikaanse mobiele gordel sisteem. 'n Gedetaileerde geologiese en geochemiese studie is gedoen op die grootste dagsoom van die Bridgetown Formasie, gelee 20km oos van die dorp Moorreesburg. Die Bridgetown Formasie bestaan uit 'n metavulkanies-sedimentere opeenvolging wat pol ifase vervorming en metamorfisme tot en met die laer groenskis fasies ondergaan het. Die Bridgetown Formasie word hier in die Boland tektoniese domein ingedeel deur die Piketberg-Wellington verskuiwingsone 5km wes van Heuningberg, subparallel a an die Bergrivier, te plaas. Dit stem ooreen met Rabie ( 197 4) se oorspronkl ike verdeling van die tektoniese domeine. Die Bridgetown Formasie bestaan uit: i) 'n Basale eenheid wat hoofsaaklik bestaan uit min gedifferens ieerde alkali-metabasalte met binneplaat tektonomagmatiese eienskappe. ii) 'n lntermediere eenheid wat bestaan uit min gedifferensieerde tholeiitiese metabasalt en 'n jonger intrusiewe tholeiitiese metabasiet wat 'n lae graad van differensias ie ondergaan het. Beide intermediere eenhede het oseaanvloer-basalt (P-t ipe MORB) en eilandboog basaltiese eienskappe. iii) 'n Boonste eenheid wat bestaan uit min gedifferensieerde asook meer gedifferensieerde alkal i-metabasalte, tussengelaagd met metatuf met 'n alka libasaltiese samestelling; metasedimentere gesteentes met 'n mariene oorsprong, en grafitiese ski ste en kwarts-muskoviet skiste, beide met 'n kontinentale kors oorsprong . iv) 'n Oorliggende metasedimentere opeenvolging wat dolomiet, massiewe en ooli tiese chert, jaspis en jaspiliet insluit. Die Bridgetown Formasie slu it moontlik ook 'n onderliggende gemetamorfiseerde ultramafiese eenheid in; aangedui deur die assosiasie van Ni- en Cr-ryke ta lkl iggame, Ni- en Cr-ryke gebande chert, chlorietskis en klein dolomiet-talk-chloriet liggame by Spitskop, gelee direk noordwes van die hoof groensteenliggaam. Die opeenvolg ing van magmatisme en die geochemie van die metavulkaniese gesteentes stem ooreen met Hawaiiese vulkanisme, naamlik 'n diepwater stadium, gekarakteriseer deur alkaliese magmatisme, gevolg deur 'n hoof tholeiitiese opbouing en post-kaldera alkaliese magmatisme. Die post-kaldera alkaliese magmatisme het gelyktydig plaasgevind met afsetting van sedimente en chemiese presipitate (karbonate en cherte ). Die Bridgetown metavulkaniese gesteentes het geen magmatiese assosiasie met 6f die Bloubergstrand vulkaniese gesteentes 6f mafiese en intermediere plutoniese gesteentes in die Malmesbury Groep nie. Fisiese en geochemiese ooreenkomste bestaan egter tussen die Bridgetown Formasie en die Grootderm Formasie van die Marmora Terrein (Gariep Supergroep) wat beskou word as ofiolitiese materiaal. Die Bridgetown Formasie verteenwoordig moontlik segmente van oseaankors, insluitende oseaan-eilande, wat tektonies in 'n melange sone ingeplaas is tydens subduksie van oseaankors onder die Kalahari Kraton in (600 tot 700 Mj gelede). Dit verklaar die huidige ruimte like verspreiding van verske ie klein groensteenliggame in die Malmesbury Groep. Tot en met hede is geen ontginbare mineraalafsettings in die Bridgetown Formasie ontdek nie. Au en As anomalie in stroomsediment- en grondmonsters, geneem in die Spitskop area, behoort egter verdere aandag te geniet. Daar is voorgestel dat die goud en arseen voorkom in brosvervormde helder tot melkerige kwartsare wat ontwikkel het in swak sones in al die litologie in die Spitskop area.

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27

Bowen, Teral Barbara. "The geochemical stratigraphy of the volcanic rocks of the Witwatersrand triad in the Klerksdorp area, Transvaal." Thesis, Rhodes University, 1985. http://hdl.handle.net/10962/d1004932.

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This study lias initiated with the aim of identifying the existence of any geochemical criteria which may be used to distinguish between the various volcanic formations within the Witwatersrand triad. The Witwatersrand triad comprises three sequences: the Dominion Group at the base, the Witwatersrand Supergroup in the middle, and the Ventersdorp Supergroup at the top. It is underlain by Archaean basement rocks, and covered by rocks of the Transvaal sequence. The Dominion Group consists of the sedimentary Rhenosterspruit quartzite Formation at the base, overlain by a bimodal component of the Syferfontein Porphyry succession of lavas. Basaltic lavas are the major component of the Rhenosterhoek Formation, while the overlying Formation consists primarily of dacitic porphyries. Intercalations of one lava type within the other are common, however, so each formation is not the exclusive domain of only one lava type. The Witwatersrand Supergroup, a predominantly argillaceous and arenaceous sequence, contains two narrow volcanic horizons, one of wbich, the Jeppestown Amygdaloid (now Crown Formation), consisting of tholeiitic andesites, occurs in the study area. The overlying Ventersdorp Supergroup has, at its base, the basaltic Klipriviersberg Group, of which four out of six formations are present in the study area, namely, the Alberton, Orkney, Loraine and Edenville Formations. This group is succeeded unconformably by the PIatberg Group, consisting of the sedimentary Kameel doorns Formation, followed by the (informal) Goedgenoeg, Makwassie Quartz Porphyry and Rietgat Formations. The Goedgenoeg and Rietgat Formations are basaltic, whil e the Mawassie rocks range from basaltic to dacitic, the majority being tholeiitic andesites and andesites . The Pniel sequence at the top of the Ventersdorp Supergroup consists of the sedimentary Bothaville Formation, and the Allarridge Formation, the lavas of which are basaltic with some andesitic tendencies. A well-defined geochemical stratigraphy was found to exist. From the eleven volcanic formations examined, nine distinct geochemical units emerged, as the Loraine and Edenville Formations were found to have the same geochemical characteristics, as did the Goedgenoeg and Rietgat Formations. Despite having undergone law-grade greenschist facies metamorphism, very clear variation patterns with height are displayed by the immobile elements Ti, P, Kb, Zr and Y, and the light rare earth elements La, Ce and Nd. In contrast, much scatter was observed in the variation patterns of Na, K, Mn, Ba and Rb. Three techniques were employed to effect discrimination between formations - orthosonal discrimination, interelement and ratio vs ratio plots, and discriminant analysis. Confidence limits placed on normal probability plots served to isolate outlier samples for further examination by the various discrimination techniques. A successful test of the efficacy of the discrimination techniques was afforded when fourteen samples from an unknown succession were positively identified as representative of the Klipriviersberg Group

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28

Hops, Jennifer Jane. "Some aspects of the geochemistry of high-temperature peridotites and megacrysts from the Jagersfontein kimberlite pipe, South Africa." Doctoral thesis, University of Cape Town, 1989. http://hdl.handle.net/11427/22415.

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Bibliography: pages 188-203. The Jagersfontein kimberlite contains an abundance of both deformed high-temperature peridotites and Cr-poor megacrysts. The Cr-poor megacryst suite is represented by olivine, orthopyroxene, clinopyroxene and garnet. The megacrysts show features which are unique to Jagersfontein, a particularly notable feature being the absence of ilmenite and ilmenite-silicate intergrowths. Major element and REE compositions of the Cr-poor megacryst suite are consistent with a magmatic fractionation sequence. ⁸⁷Sr/⁸⁶Sr and ¹⁴³Nd/¹⁴⁴Nd ratios of the Cr-poor clinopyroxene megacrysts indicate a source similar to that of non-DUPAL ocean island basalts. Deformed peridotites at Jagersfontein have high calculated temperatures of equilibration (1132-1361°C), which are slightly lower but which overlap with those of the Cr-poor megacryst suite. Both the high-temperature peridotites and the Cr-poor megacrysts yield similar pressures of equilibration (51±2 kbar), indicating their association with a thermal perturbation and supporting a close spatial association between them. Olivine and pyroxenes in the high-temperature peridotites appear homogeneous, but compositional gradients were observed in several garnet porphyroclasts. These garnets show rim enrichments in TiO₂ and Na₂O. This zonation in the garnets is evidence for enrichment of the deformed peridotites shortly before kimberlite eruption. This enrichment is likely to be due to interaction with the megacryst magma. In addition, the high-temperature peridotites show a general enrichment in Fe, Ti, Na and Al with decreasing Ca/(Ca+Mg). Such features support a magmatic aureole model, in that temperature and degree of enrichment might be expected to increase with proximity to the megacryst magma body. ⁸⁷Sr/⁸⁶Sr and ¹⁴³Nd/¹⁴⁴Nd ratios of clinopyroxene separates from the high-temperature peridotites are similar to those from oceanic peridotites. Modal abundances and olivine forsterite contents of the high-temperature peridotites are consistent with an origin as residues of partial melting events involving basalt formation. It is suggested that partial melting events, in the upper mantle beneath Jagersfontein, resulted in the formation of a depleted protolith which underplated the base of the Archaean lithosphere. This depleted protolith was subsequently enriched by interaction with the Cr-poor megacryst magma just prior to kimberlite eruption. The high-temperature peridotites therefore represent samples from the base of the lithosphere rather than from the convecting asthenosphere.

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29

Soderberg, Keir. "Geochemistry of the fynbos ecosystem in a Table Mountain Group sub catchment of the Olifants River, Western Cape, South Africa." Master's thesis, University of Cape Town, 2003. http://hdl.handle.net/11427/4225.

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Bibliography: leaves 104-118. This study gives a first-order estimation of the chemical composition of the recharge, discharge, and ground waters, along with the bedrock, soil, and vegetation of the Olifants River Valley around Citrusdal. The valley occurs in a synclinal fold with the main aquifers, the Table Mountain Group (MG) sandstones of the Peninsula Formation and the Nardouw Subgroup, folded beneath the central valley.

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30

Crous, Stephanus Philippus. "The geology, geochemistry and stratigraphic correlations of the farm Rietfontein 70 JS on the south -eastern flank of the Dennilton Dome, Transvaal, South Africa." Thesis, Rhodes University, 1996. http://hdl.handle.net/10962/d1005572.

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The study area is located between Loskop Dam and the town of Groblersdal, on the southeastern flank of the Dennilton dome, and is underlain by lithologies of the Pretoria Group, Bushveld Complex mafics and ultramafics and acid lavas that resort under the Rooiberg felsites. Field work comprised of geological mapping, soil-, hard-rock- and stream sediment geochemistry, various geophysical techniques and diamond drilling. The rocktypes that resembles the Rustenburg Layered Suite on the farm Rietfontein 70JS is subdivided into a Mixed Zone, Critical Zone and Main Zone, on grounds of geochemical and certain geophysical attributes. The Mixed Zone that overlies the Bushveld Complex floor-rocks, is furthermore separated into an i) Lower-, ii) Middle- and, iii) Upper Unit. The Lower Unit of the Mixed Zone consists primarily of magnetite-gabbros, iron-rich pegmatites, harzburgites and feldspathic pyroxenites. The Fe-rich constituents of this stratigraphic horizon generates a pronounced magnetic anomaly within the study area. On the basis of; amongst other parameters, Zr/Rb and Sr/Al₂0₃ ratios, the magnetite-gabbros are postulated to conform to lithotypes in the vicinity of magnetite layers 8 to 14 of Upper Zone Subzone B in a normal Bushveld Complex stratigraphical scenario. Similarly, it is argued that the feldspathic pyroxenites and norites that display elevated chromium values are analogues to normal Critical Zone rocktypes of the Rustenburg Layered Snite. A more elaborate and precise stratigraphic correlation for the Critical zone was, however, not possible. It is advocated that a volume imbalance was created by the hot, ascending mafic magmas of the intruding Bushveld Complex, resulting in the updoming of certain prevailing basement features such as the Dennilton Dome. In addition to this ideology, it is proposed that the Mineral Range Fragment is in fact a large xenolith underlain by mafics, after being detached from the Dennilton Dome during the intrusion event. Evidence generated by this study unequivocally indicate that the potential for viable PGE's, Ni, Cu and Au within a Merensky Reef- type configuration or a Plat Reef-type scenario under a relatively thin veneer of acid Bushveld Complex roof-rocks on the eastern flank of the Dennilton Dome, appears feasible.

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Davies, Christopher Paul Norman, A. Rozendaal, and B. V. Burger. "Hydrocarbon evolution of the Bredasdorp Basin, offshore South Africa : from source to reservoir." Thesis, Stellenbosch : University of Stellenbosch, 1997. http://hdl.handle.net/10019.1/4936.

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Thesis (PhD (Geology))--University of Stellenbosch, 1997. 1123 leaves printed on single pages, preliminary pages and numbered pages 1-286. Includes bibliography, list of figures and tables and explanation of abbreviations used. Digitized at 600 dpi grayscale to pdf format (OCR), using a Bizhub 250 Konica Minolta Scanner. ENGLISH ABSTRACT: This first comprehensive study of the petroleum geochemistry of the Bredasdorp Basin, and the adjacent Southern Outeniqua Basin, documents the characteristic large number of hydrocarbon shows and the four regionally distinctive marine source rocks. Detailed correlation of reservoired hydrocarbons with source rock bitumens shows that two source rocks have expelled oil in commercial quantities and two others have expelled commercial quantities of wet gas/condensate. In contrast with earlier studies which indicated that thermal 'gradualism' prevailed, this study indicates that the post-rift thermal history of the basin is very complex. Post-rift cool-down is punctuated by periods of rapidly increasing heat flow resulting in much of the maturation being localised in time. These periods of increased heating coincide with regional plate tectonism. The associated thermal uplift and downwarp effects govern the periods of trap formation and control the hydrocarbon migration direction. Migration distances of these hydrocarbons are described and show inter alia that oil migrates no more than -7-10 km but gas migrates regionally. Two regional episodes of meteoric water flushing reduce sandstone cementation in palaeo-highs forming potential reservoirs at specific times. The unusually low salinity of remnants of this water in some sandstones help characterise these two main migration conduits. A highly detailed hydrocarbon correlation scheme derived from gas, light oil and biomarker data has been established which differentiates products of the four active source rocks and helps characterise the oil-oil, oil-source and source-source pairs. It is evident from these correlations that two periods of migration and reservoiring occurred at 50-60 Ma and 0-10 Ma. As a result, source-reservoir plays which characterise certain areas of the basin as predominantly oil or gas prone can be described. These correlations also highlight areas where mixtures of hydrocarbons are common and where some of the early reservoired oil has been displaced to new locations, constituting potential new exploration plays. Source rocks for some of the analysed hydrocarbons have yet to be found and may not even have been drilled to date. One such source rock appears to be located in the Southern Outeniqua Basin, making that area a potential target for further exploration. This study resolved the common heritage of the source rocks and reservoir sandstones which form part of the Outeniqua petroleum system. The hydrocarbon volumes available to this system show that by world standards it is indeed significant. AFRIKAANSE OPSOMMING: Die groot aantal koolwaterstof voorkomste asook vier streekskenmerkende mariene brongesteentes word in hierdie eerste omvattende studie van die petroleumgeochemie van die Bredasdorp-kom en die aangrensende Suidelike Outeniqua-kom saamgevat. Gedetaileerde korrelasies van die opgegaarde koolwaterstowwe met brongesteente bitumen, dui daarop dat twee van die vier geidentifiseerde brongesteentes olie in kommersiele hoeveelhede uitgeset het. Die ander twee het kommersiele hoeveelhede nat gas-kondensaat uitgeset. In teenstelling met vroeer studies wat daarop gedui het dat termale 'gradualisme' voorgekom het, dui hierdie studie daarop dat die na-riftermale geskiedenis van die kom baie meer kompleks is. Verskeie periodes van versnelde toename in hittevloei het voorgekom in die na-rifse verkoeling. Dit het daartoe gelei dat veroudering plaaslik binne 'n beperkte tydsverloop plaasvind. Hierdie periodes van hittetoename stem ooreen met die regionale plaattektoniek. Die geassosieerde termiese opheffing en afwaartse vervormingseffek, beheer die totstandkoming van opvanggebiede en die migrasierigting van die koolwaterstowwe. Migrasie-afstande van die koolwaterstowwe word bespreek en wys inter alia daarop dat olie nie verder as -7-10 km beweeg nie, maar gasmigrasie vind regionaal plaas. Twee kort episodes van meteoriese wateruitsetting, het sandsteensementasie in palaeohoogsliggende gebiede verminder wat potensiele reservoirs gevorm het op spesifieke tye. Die ongewone lae soutvlakte van oorblyfsels van die water in sekere sandstene help om die twee vernaamste migrasieroetes te kenmerk. 'n Hoogs omvattende koolwaterstof-korrelasieskema wat van gas, ligte olie en biomerkerdata verkry is, is opgestel. Die skema het onderskei tussen produkte van die vier aktiewe brongesteentes en help om die olie-olie, olie-bron en bron-bron pare te karakteriseer. Dit is duidelik van die korrelasies dat twee periodes van migrasie en opgaring plaasgevind het ongeveer teen -50-60 Ma en 0-10 Ma. Gevolglik kan bronreservoir omskrywings wat sekere dele van die kom karakteriseer as grotendeels olie of gas-ontvanklik beskryf word. Hierdie korrelasies beklemtoon ook areas waar mengsels van koolwaterstowwe algemeen voorkom en waar sekere van die vroeer opgegaarde olie verplaas is na nuwe lokaliteite, wat nuwe eksplorasieteikens daarstel. Brongesteentes vir sekere van die ge-analiseerde koolwaterstowwe, moet nog gevind word en is tot op hede nog nie raakgeboor nie. Een so 'n brongesteente kom voor in die Suidelike Outeniqua-kom, wat daardie area 'n potenslele teiken vir verdere eksplorasie maak. Die studie het die gesamentlike oorsprong van die brongesteente en reservoirsandsteen, wat deel is van die Outeniqua Petroleumsisteem, geidentifseer. Die koolwaterstofvolumes wat beskikbaar is vir die sisteem wys dat, gemeet teen wêreldstandaarde, dit wel beduidend is.

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32

Rafuza, Sipesihle. "Carbonate petrography and geochemistry of BIF of the Transvaal supergroup : evaluating the potential of iron carbonates as proxies for palaeoproterozoic ocean chemistry." Thesis, Rhodes University, 2015. http://hdl.handle.net/10962/d1018611.

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The subject of BIF genesis, particularly their environmental conditions and ocean chemistry at the time of deposition and their evolution through time, has been a subject of much contentiousness, generating a wealth of proposed genetic models and constant refinements thereof over the years. The prevailing paradigm within the various schools of thought, is the widespread and generally agreed upon depositional and diagenetic model(s) which advocate for BIF deposition under anoxic marine conditions. According to the prevailing models, the primary depositional environment would have involved a seawater column whereby soluble Fe²⁺ expelled by hydrothermal activity mixed with free O₂ from the shallow photic zone produced by eukaryotes, forming a high valence iron oxy-hydroxide precursor such as FeOOH or Fe(OH)₃. An alternative biological mechanism producing similar ferric precursors would have been in the form of photo-ferrotrophy, whereby oxidation of ferrous iron to the ferric form took place in the absence of biological O₂ production. Irrespective of the exact mode of primary iron precipitation (which remains contentious to date), the precipitated ferric oxy-hydroxide precursor would have reacted with co-precipitated organic matter, thus acting as a suitable electron acceptor for organic carbon remineralisation through Dissimilatory Iron Reduction (DIR), as also observed in many modern anoxic diagenetic environments. DIR-dominated diagenetic models imply a predominantly diagenetic influence in BIF mineralogy and genesis, and use as key evidence the low δ¹³C values relative to the seawater bicarbonate value of ~0 ‰, which is also thought to have been the dissolved bicarbonate isotope composition in the early Precambrian oceans. The carbon for diagenetic carbonate formation would thus have been sourced through a combination of two end-member sources: pore-fluid bicarbonate at ~0 ‰ and particulate organic carbon at circa -28 ‰, resulting in the intermediate δ¹³C values observed in BIFs today. This study targets 65 drillcore samples of the upper Kuruman and Griquatown BIF from the lower Transvaal Supergroup in the Hotazel area, Northern Cape, South Africa, and sets out to explore key aspects in BIF carbonate petrography and geochemistry that are pertinent to current debates surrounding their interpretation with regard to primary versus diagenetic processes. The focus here rests on applications of carbonate (mainly siderite and ankerite) petrography, mineral chemistry, bulk and mineral-specific carbon isotopes and speciation analyses, with a view to obtaining valuable new insights into BIF carbonates as potential records of ocean chemistry for their bulk carbonate-carbon isotope signature. Evaluation of the present results is done in light of pre-existing, widely accepted diagenetic models against a proposed water-column model for the origin of the carbonate species in BIF. The latter utilises a combination of geochemical attributes of the studied carbonates, including the conspicuous Mn enrichment and stratigraphic variability in Mn/Fe ratio of the Griquatown BIF recorded solely in the carbonate fraction of the rocks. Additionally, the carbon isotope signatures of the Griquatown BIF samples are brought into the discussion and provide insights into the potential causes and mechanisms that may have controlled these signatures in a diagenetic versus primary sedimentary environment. Ultimately, implications of the combined observations, findings and arguments presented in this thesis are presented and discussed with particular respect to the redox evolution and carbon cycle of the ocean system prior to the Great Oxidation Event (GOE). A crucial conclusion reached is that, by contrast to previously-proposed models, diagenesis cannot singularly be the major contributing factor in BIF genesis at least with respect to the carbonate fraction in BIF, as it does not readily explain the carbon isotope and mineral-chemical signatures of carbonates in the Griquatown and uppermost Kuruman BIFs. It is proposed instead that these signatures may well record water-column processes of carbon, manganese and iron cycling, and that carbonate formation in the water column and its subsequent transfer to the precursor BIF sediment constitutes a faithful record of such processes. Corollary to that interpretation is the suggestion that the evidently increasing Mn abundance in the carbonate fraction of the Griquatown BIF up-section would point to a chemically evolving depositional basin with time, from being mainly ferruginous as expressed by Mn-poor BIFs in the lower stratigraphic sections (i.e. Kuruman BF) to more manganiferous as recorded in the upper Griquatown BIF, culminating in the deposition of the abnormally enriched in Mn Hotazel BIF at the stratigraphic top of the Transvaal Supergroup. The Paleoproterozoic ocean must therefore have been characterised by long-term active cycling of organic carbon in the water column in the form of an ancient biological pump, albeit with Fe(III) and subsequently Mn(III,IV) oxy-hydroxides being the key electron acceptors within the water column. The highly reproducible stratigraphic isotope profiles for bulk δ¹³C from similar sections further afield over distances up to 20 km, further corroborate unabatedly that bulk carbonate carbon isotope signatures record water column carbon cycling processes rather than widely-proposed anaerobic diagenetic processes.

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33

Echeverría, Marietta Elena. "Impact of pine plantations on the form and mobility of nitrogen in soils of the eastern escarpment region of South Africa." Master's thesis, University of Cape Town, 2000. http://hdl.handle.net/11427/7680.

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Bibliography: leaves 96-101. Recent research in the eastern escarpment area of South Africa has documented enhanced NO₃- concentrations in soil solution and stream water resulting from afforestation. There has been much research in the Northern Hemisphere regarding the qualitative and quantitative causes and consequences of N saturation in forest ecosystems. In order to assess the significance of local observations of afforestation-induced NO₃- enhancement in a global context, a study was conducted to evaluate the influence of forest plantations (Pinus spp.) on N form and mobility in soils in the eastern escarpment area of South Africa. Twenty soil samples were taken, half in grassland and half in forest, in the Graskop and Kaapsehoop areas of the eastern escarpment. Forest samples were taken as composites of approximately five individual samples in each stand from the top 20-25 em of soil, combining partially decomposed organic litter layer with the subjacent upper mineral soil horizon. Grassland samples were taken, again as composites, consisting of the upper mineral soil horizon (an organic litter layer was for the most part absent). Approximately three-quarters of each sample was air-dried, and crushed to pass through a 2-mm sieve and stored for analysis. The remaining quarter of each sample was passed through a 2-mm sieve and refrigerated at about 4°C in order to maintain field-moist conditions and to inhibit microbial transfornlations. Refrigerated samples were used for KCI-extractable NO₃- and NH₄+ analyses and N mineralisation experiments. The remaining analyses were performed on the air-dried samples. This study included two facets: physical and chemical characterisation of soil samples; and a series of laboratory experiments. The solid phase of the soils was analysed for organic carbon, total nitrogen and particle size distribution. The soil solution was investigated by making saturated paste extracts which were analysed for major ions, trace elements, electrical conductivity (EC) and pH. Extractable base cations, acidity and inorganic nitrogen (NH₄+ and NO₃-) were also analysed after extraction with NH₄OAc or KCl solutions. The laboratory experiments, intended to investigate the apparent differences in soil N transformations and mobility resulting from vegetation, consisted of both aerobic and anaerobic incubation to assess N mineralisation, a NO₃- sorption experiment and a soil to extract ratio dilution experiment.

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Campbell, Ross. "The chemical response of deep, leached and weathered soils of the Mpumalanga Highveld, South Africa, to irrigation with saline mine water." Master's thesis, University of Cape Town, 2000. http://hdl.handle.net/11427/4189.

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Includes bibliographical references. Coal mining in the Highveld region of Mpumalanga Province, South Africa generates between 14 and 30 million litres of waste water per day. Much of the water is saline (TDS> 2500 mg/I) and has high concentrations of dissolved SO₄²⁻, Ca²⁺ and Mg²⁺. Crop irrigation has been proposed as a useful way to dispose of saline mine water and enhance agricultural productivity in this low rainfall (˂800 mm/year) region. In order to avoid undesirable salinization of the regional groundwater, it is necessary that soils immobilize, at least partially, the dissolved salt load of irrigation water.

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Abanda, Peter Azah. "Impact on soil chemistry of atmospheric sulfur fallout near Arnot coal-fired power station, in the Eastern Transvaal highveld region, South Africa." Master's thesis, University of Cape Town, 2000. http://hdl.handle.net/11427/4184.

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Includes bibliographical references. The objective of the study was to evaluate the potential impact of atmospheric sulfur deposition on the soils surrounding Arnot power station. In particular, the study focused on the relationship between sulfur and organic carbon (OC) and on the various pools of sulfur in the soil. A representative selection of collected soil samples was characterized both physically and chemically in the laboratory. In addition to the representative soils sampled in 2000, archived soils sampled in 1996 and 1999 from the same area were included in some of the chemical analyses.

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De, Klerk William Johan. "Petrogenesis of the upper critical zone in the Western Bushveld Complex with emphasis on the UG1 Footwall and Bastard units." Thesis, Rhodes University, 1992. http://hdl.handle.net/10962/d1005598.

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This study is an account of the stratigraphic sequence, the petrography, mineralogy (microprobe investigations of orthopyroxene, clinopyroxene, olivine and plagioclase feldspar), and whole-rock major- and traceelement geochemistry of the silicate cumulates of the Upper Critical Zone in the western Bushveld Complex. Two parts of the study - an investigation of a 350m column incorporating the MG3 and UGI Footwall Units, and a comparison of two additional Upper Critical Zone profiles with a previously compiled profile between the UGI and Bastard Units - are focused on RPM Union Section in the northwestern sector of the Complex. The third part is a detailed vertical and lateral investigation of the Bastard Unit at the top of the Critical Zone, which draws on sampling and data compilation from seventeen profiles in the western limb of the Complex. The MG3 Unit (45m) is made up of a lower chromitite layer overlain by a norite-pyroxenite-anorthosite sequence while the UGlFW Unit (295m) is composed of a related series of lower chromitite layers (MG4) overlain by a pyroxenite-norite-anorthosite sequence capped by the UGI chromitite layer. These mafic cumulates display a distinctive pattern of oscillating cryptic variation in whole-rock Mg/(Mg+Fe), FeO/Ti0₂, Cr/Co and Ni/V ratios through the sequence. Sympathetic oscillations are recorded for compositions of orthopyroxene and plagioclase feldspar and eight subcycles are recognised through the UGlFW Unit. The entire sequence is characterised by the presence of small, spheroidal, embayed and irregularly shaped plagioclase grains which are poikilitically enclosed in cumulus orthopyroxene grains of both pyroxenites and norites. This texture is indicative of partial resorption of pre-existing feldspar primocrysts within the melt prior to their being incorporated into the host orthopyroxene grains. Textural, geochemical and isotopic data suggest that this sequence was built up by periodic additions of fresh, relatively primitive liquid into fractionated resident liquid, and subsequent mixing within the magma chamber. The Bastard Unit sequence, described in Chapter 4, is the last and most complete cyclic unit (c. 60m) of the Critical Zone, and its upper contact defines the boundary between the Critical and Main Zones of the Complex. This Unit can conveniently be sub-divided into a lower part, where orthopyroxene occurs as a cumulus phase, and the upper part which is composed entirely of anorthosite (Giant Mottled Anorthosite). The basal part of the Unit (≤ 18m) comprises a thin chromitite layer < O.5cm) overlain by a pyroxenite-melanorite-norite-leuconorite sequence. The basal pyroxenite is orthocumulate in character and rapidly gives way to norites and leuconorites. A distinct threefold subdivision emerges within the Giant Mottled Anorthosite which is predominantly an adcumulate which becomes orthocumulate in character at its top. Apart from minor deviations in thicknesses these lithologies are recorded over the entire strike-length covered in this study. Profiles of cryptic variation are compiled for orthopyroxene, plagioclase and whole-rock data and show that the Bastard Unit displays a characteristic pattern which is maintained throughout the western Bushveld Complex. A minor yet distinctive reversal in cryptic variation is revealed at a level which is stratigraphically variable within the lower Giant Mottled Anorthosite, and results in a double cuspate pattern. A remarkable feature of the basal Bastard pyroxenites is that although the modal proportion of mafic to felsic constituents varies systematically away from the northwestern sector, the Mg/(Mg+Fe) ratio of orthopyroxenes remains constant at 0.804 over a lateral strike distance of 171km. Within the upper part of the Unit the orthopyroxene is markedly Fe-rich and it is here that inverted primary pigeonite appears for the first time as a cumulus phase. In addition, K-feldspar, oscillatory zoned plagioclase grains and high levels of incompatible trace elements are noted at this level. On the basis of the data presented it is concluded that the Bastard Unit represents the crystallisation of a final, relatively large influx of hotter primitive liquid, with upper Critical Zone affinities, and subsequent mixing with a column of cooler (less dense) supernatant liquid which had in part hybridized with the overlying Main Zone magma. It is hypothesised that this new liquid was emplaced as a basal flow beneath supernatant liquid and that it initiated the deposition of mafic cumulates at its base. The supernatant liquid is interpreted as representing the fractionated residuum produced by crystallisation of earlier cyclic units, with plagioclase on the liquidus, and that it contained an abundance of small plagioclase primocrysts in suspension. Development of the Unit can be viewed as a two-stage process. In the lower half of the unit, chemical and physical parameters typical of the new magma dominated the crystallisation process, and resulted in cumulates very similar to other relatively complete Upper Critical Zone units. In the upper, leucocratic sequence, above a minor reversal, crystallisation was from a liquid which was the product of mixing of a minor pulse of primitive liquid with the reservoir of hybridized supernatant liquid. Although the Bastard Unit is not continuous around the entire Western limb of the Complex, it is concluded that it developed in a single, or connected, magma chamber and that its irruptive feeder zone was located in the proximal northwestern facies of the Complex.

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Nethenzheni, Sedzani Shane. "The geochemistry, geochronology and petrogenetic characteristics of two granitic suites on the eastern margin of the Namaqua Sector, Namaqua-Natal Mobile Belt, South Africa." Thesis, University of the Western Cape, 2016. http://hdl.handle.net/11394/5209.

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>Magister Scientiae - MSc The group of granites on the eastern margin of the Mesoproterozoic Namaqua sector of the polydeformed and highly metamorphosed Namaqua-Natal Province of southern Africa is known as the Keimoes Suite. The suite includes mixtures of diverse rock types not belonging to a single intrusive series and so it should be subdivided into more than one intrusive suite. The exact definition, extent, distribution and petrogenesis of these granites have been poorly defined in the past, with various authors defining the suite differently due to the lack of proper geochronology and geochemical data. The exact contact between the Namaqua sector and Kaapvaal Craton together with the role of the suite to the Namaqua tectonic evolution is still unclear. The granites of the Keimoes Suite are thought to mark the contact between the Namaqua sector and the Kaapvaal Craton. This study seeks to address the above mentioned problems by making use of new geochronology, isotope, major and trace element geochemistry together with petrography. The granites of the Keimoes Suite were previously grouped based on their degree of deformation. The geochronology, undertaken as part of this study, has proven that this classification is unfounded. The degree of foliation in these granites appears to be largely controlled by the abundance of platy minerals, such as biotite and muscovite, together with the intrusion mechanism, with deformational processes, such as shearing, playing a secondary role. The geochronology, together with geochemistry has helped to redefine the previously defined Keimoes Suite so that two well defined separate suites are recognized and the third is poorly defined due to lack of more samples of that age group. The new classification or grouping of the granites of the eastern Namaqua sector allows a more detailed examination of the tectonic evolution of this region. A member of the 1225 to 1200 Ma early syn-tectonic granites, the Josling Granite, shows a strongly developed foliation and was derived from a depleted source with a relatively low continental crustal component. This granite intruded during the time of arc accretion, and is associated with, and partly responsible for the D₁ deformation and M₁ metamorphism recognized in most of the rocks of the eastern terranes of the Namaqua sector. In terms of age, the syn-tectonic granites of the Augrabies Suite extend from 1200 to 1120 Ma and were largely derived from depleted sources with variable but more substantial amounts of continental crustal components as compared to the early syn-tectonic granite. The granites of this suite intruded during the period of peak D₂ deformation with peak magmatism between 1180 - 1135 Ma, and particularly around 1150 Ma, during the peak of metamorphism (M₂) caused by, and associated with these voluminous intrusions. The Keimoes Suite can now be defined as comprising granites of late- to post-tectonic age relative to the 1.2 - 1.08 Ga Namaquan Orogeny with magmatism occurring on the western side of the Kaapvaal Craton. The 1116 to 1066 Ma Keimoes Suite intruded during the stage of the Namaquan Orogeny in which there was continued indentation of the Kaapvaal Craton into the Namaqua sector with wrenching and shearing causing the development of rifting into which the granites intruded. The Keimoes Suite granites were derived from continental crustal sources and incorporated varying degrees of depleted source components. The intrusives and extrusives of this age occured after the main collisional event between the Namaqua Sector and the Kaapvaal Craton and are associated with the D₃ deformational event, imparting the thermal conditions leading to the M₃ metamorphic event of the rocks within both the Kakamas and Areachap Terranes. The suites mark the suture between the Archean Kaapvaal Craton and the Proterozoic Namaqua sector. The compositions of the granites of the individual suites were mainly controlled by the source with the degree of partial melting exerting a major control. The proportion of entrained peritectic assemblages and accessory minerals played a major role in controlling the compositions of the granites, particularly those of the trace elements. Variations within the compositions of the same suite are due to source heterogeneities. Generally, fractionation processes played a secondary role in influencing the composition of the granites. Council for Geoscience and National Research Foundation

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Hammond, Napoleon Quaye. "The geochemistry of ore fluids and control of gold mineralization in banded iron-formation at the Kalahari Goldridge deposit, Kraaipan greenstone belt, South Africa." Thesis, Rhodes University, 2003. http://hdl.handle.net/10962/d1008370.

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The Kalahari Goldridge mine is located within the Archaean Kraaipan Greenstone Belt about 60 km SW of Mafikeng in the Northwestern Province, South Africa. Several gold deposits are located within approximately north - south-striking banded iron-formation (BIF). Current opencast mining operations are focused on the largest of these (D Zone). The orebody is stratabound and hosted primarily in the BIF, which consists of alternating chert and magnetite-chloritestilpnomelane-sulphide-carbonate bands ranging from mm to cm scale. The ore body varies in thickness from 15 to 45 m along a strike length of about 1.5 km. The BlF is sandwiched between a sericite-carbonate-chlorite schist at the immediate footwall and carbonaceous meta-pelites in the hanging-wall. Further west in the footwall, the schists are underlain by mafic meta-volcanic amphibolite. Overlying the hanging-wall carbonaceous metapeiites are schist units and meta-greywackes that become increasingly conglomeratic up the stratigraphy. Stilpnomelane-, chlorite- and minnesotaite-bearing assemblages in the BlFs indicate metamorphic temperatures of 300 - 450°C and pressures of less than 5 kbars. The BIF generally strikes approximately 3400 and dips from 60 to 75°E. Brittle-ductile deformation is evidenced by small-scale isoclinal folds, brecciation, extension fractures and boudinaging of cherty BIF units. Fold axial planes are sub-parallel to the foliation orientation with sub-vertical plunges parallel to prominent rodding and mineral lineation in the footwall. Gold mineralization at the Kalahari Goldridge deposit is associated with two generations of subhorizontal quartz-carbonate veins dips approximately 20 to 40°W. The first generation consists of ladder vein sets (Group lIA) preferentially developed in Fe-rich meso bands, whilst the second generation consists of large quartz-carbonate veins (Group lIB), which crosscut the entire ore body extending into the footwall and hanging-wall in places. Major structures that control the ore body are related to meso-scale isoclinal folds with fold axes subparallel to mineral elongation lineations, which plunge approximately 067°E. These linear structures form orthogonal orientation with the plane of the mineralized shallowdipping veins indicating stretching and development of fluid - focusing conduits. A second-order controlling feature corresponds to the intersection of the mineralized veins and foliation planes of host rock, plunging approximately 008°N and trending 341°. G0ld is closely associated with sulphides, mainly pyrite and pyrrhotite and to a lesser extent with bismuth tellurides, and carbonate gangue. The ore fluid responsible for the gold deposition is in the C-O-H system with increased CH₄ contents attributed to localized hydrolysis reaction between interbedded carbonaceous sediment and ore fluid. The fluid is characterized by significant C0₂ contents and low salinities below 7.0 wt % NaCl equivalent (averages of 3.5 and 3.0 wt % NaCl equivalent for the first and second episodes of the mineralization respectively) . Calculated values of f0₂. ranging from 10⁻²⁹·⁹⁸ to 10⁻³²·⁹⁶ bars, bracket the C0₂-CH₄ and pyrite-pyrrhotite-magnetite buffer boundaries and reveal the reducing nature of the ore fluid at deposition. Calculated total sulphur content in the ore fluid (mΣs), ranges from 0.011 to 0.018M and is consistent with the range (10⁻³·⁵ to 10⁻¹M) reported for subamphibolite facies ore fluids. The close association of sulphides with the Au and nature of the fluid also give credence that the Au was carried in solution by the Au(HS)₂ - complex. Extensive epigenetic replacement of magnetite and chlorite in BIF and other meta-pelitic sediments in the deposit by sulphides and carbonates, both on meso scopic and microscopic scales gives evidence of an interaction by a CO₂- and H₂S-bearing fluid with the Fe-rich host rocks in the deposit. This facilitated Au precipitation due to changes in the physico-chemical conditions of the ore fluid such as a decrease in the mΣs and pH leading to the destabilization of the reduced sulphur complexes. Local gradients in f0₂ may account for gold precipitation in places within carbonaceous sediments. The fineness of the gold grams (1000*Au/(Au + Ag) ranges from 823 to 921. This compares favourably with the fineness reported for some Archaean BIFhosced deposits (851 - 970). Mass balance transfer calculations indicate that major chemical changes associated with the hydrothermal alteration of BIF include enrichment of Au, Ag, Bi, Te, volatiles (S and CO₂), MgO, Ba, K and Rb but significant depletion of SiO₂ and minor losses of Fe₂O₃. In addition, anomalous enrichment of Sc (average, 1247%) suggests its possible use as an exploration tool in the ferruginous sediments in the Kraaipan greenstone terrane. Evidence from light stable isotopes and fluid inclusions suggests that the mineralized veins crystallized from a single homogeneous fluid source during the two episodes of mineralization under the similar physicochemical conditions. Deposition occurred at temperatures rangmg from 350 to 400°C and fluid pressures ranging from 0.7 to 2.0kbars. Stable isotope constraints indicate the following range for the hydrothermal fluid; θ¹⁸H₂O = 6.65 to 10.48%0, 8¹³CΣc = -6.0 to -8.0 %0 and 8³⁴SΣs = + 1.69 to + 4.0%0 . These data do not offer conclusive evidence for the source of fluid associated with the mineralization at the Kalahari Goldridge deposit as they overlap the range prescribed for fluid derived from devolatization of deep-seated volcano-sedimentary piles near the brittle-ductile transition in greenstone belts during prograde metamorphism, and magmatic hydrothermal fluids. KMBT_363 Adobe Acrobat 9.54 Paper Capture Plug-in

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Maier, Wolfgang Derek. "Geochemical and petrological trends in the UG2-Merensky unit interval of the upper critical zone in the Western Bushveld Complex." Thesis, Rhodes University, 1992. http://hdl.handle.net/10962/d1005563.

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One of the most remarkable features of the layered sequence of the Bushveld Complex is its lateral consistency in lithology. This work has established a geochemical and lithological correlation along 170 km of strike of the interval between the UG2 chromitite and the Merensky Reef within the Upper Critical zone of the western limb of the Bushveld Complex. The correlation is based on geochemical investigations of 10 borehole intersections and lithological comparisons of more than 20 borehole intersections around the western lobe of the complex. The basic data presented include 123 whole-rock analyses for major and 12 trace elements, 97 analyses for ' 12 trace elements, and ca. 5500 microprobe analyses of all major phases. Patterns of cryptic variation are established. Some layers (the UG2 chromitite and pyroxenite) show considerable consistency with regard to geochemistry and lithology. Others can be traced along most of the investigated strike length, such as the Lone Chrome Seam, the Footwall Marker anorthosite and the immediate anorthosite footwall to the Merensky Unit. Most of the distinguishable members within the study section, however, show great variation along strike (i.e., the Lower and Upper Pseudoreef Markers, the central noritic sequence in the southern arm of the western limb and parts of the immediate Merensky Reef footwall succession). Several models have been evaluated to interpret the geochemical and lithological data. The author comes to the conclusion that the degree of lithological consistency depends on the variability of magmatic parameters within different parts of the chamber. The most important of these parameters are: (i) the size of fresh primitive influxes and consequently the heat flux, (ii) the composition of the residual liquid, and (iii) the frequency of the influxes. Fresh influxes of more or less similar composition thus spread out along the floor if the residual liquid was less dense than the fresh primitive liquid, but intruded the chamber as a plume where plagioclase had crystallized for some time and the residual liquid had become relatively dense. The size of the influx may be regarded as a measure of the amount of heat flux from the feeder into the chamber. A large influx created uniform physicochemical conditions in the chamber whereas a smaller influx created a strong lateral gradient of physicochemical parameters in the chamber, with subsequent differences in viscosity, density, convection currents, yield strength and thus different mixing behaviour of different liquids. Furthermore, a persistent heat flux from the feeder may have delayed crystallization of successive phases in those parts of the chamber proximal to the feeder . Therefore, new influxes would have been deposited on a footwall of varying thickness and lithology in response to different degrees of crystallization and accumulation along strike. The development of a normal cyclic unit (chromititeharzburgite-pyroxenite-norite (+anorthosite?)) may thus have been interrupted at various stages in different parts of the chamber. The ability to correlate anorthosites over great strike distances implies that their formation did not follow entirely random processes but was dependent on specific magmatic conditions which prevailed over laterally extensive portions of the chamber at certain stages during the evolution of the crystallizing liquid.

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40

Williams, Craig Milton. "Petrogenesis of the New Amalfi sheet a highly differentiated Karoo intrusion." Thesis, Rhodes University, 1995. http://hdl.handle.net/10962/d1005597.

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The New Amalfi Sheet is a highly differentiated tholeiitic intrusion which is situated between the towns of Matatiele and Swartberg in East Griqualand. It lies within the Central area of the Karoo Igneous Province. Rock types range from dolerites at the base and top through to a highly differentiated granophyre which is found as a 'sandwich horizon' within the top half of the sheet. The most evolved granophyre represents 15.86% of the initial liquid, which was found to be very similar in composition to the average Lesotho-type magma of Marsh and Eales (1984). The paragenetic sequence was found to be chromite → olivine → plagioclase → pigeonite and augite. Cumulus magnetite and ilmenite enter the paragenetic sequence together with immiscible sulphide droplets after 35% crystallization. In the late stages of crystallization, augite changes composition towards ferrohedenbergite. The reappearance of iron-rich olivine coincides with the disappearance of pigeonite and apatite appears as a cumulus phase for the first time after 70% crystallization. Granophyric intergrowth, which contains coarse perthitic Kfeldspar, becomes the most abundant modal entity within the most evolved granophyres. Differentiation was dominated by fractionation of plagioclase and pyroxene, with subordinate olivine and opaque-oxide fractionation. A minor amount of assimilation of country rock occurred within the topmost granophyres. The intrusion has been dated, using the Rb-Sr isochron method, at 178.37 ± 5.52 Ma. Extensive subsolidus deuteric alteration has resulted in the formation of a complete series of hydrothermally altered clinopyroxenes which are enriched in CaO but depleted in TiO₂ compared to the unaltered magmatic clinopyroxenes. It has also resulted in the formation of abundant vermiform ilmenite in the most evolved rocks, recognized by the fact that this phase is enriched in MnO compared to magmatic ilmenites. The very iron-rich orthopyroxene, ferrohypersthene, was found to have crystallized, during cooling of the sheet from the intercumulus liquid. Olivine in the dolerite re-equilibrated with the intercumulus liquid, becoming more iron-rich in composition.

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Botha, Pieter W. S. K. "The mineralogy and geochemistry of the Rooikoppies iron-rich ultramafic pegmatite body, Karee Mine, Bushveld Complex, South Africa [electronic resource] /." Pretoria : [s.n.], 2008. http://upetd.up.ac.za/thesis/available/etd-01272009-172307/.

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42

Schloemann, Hendrik. "The geochemistry of some common Western Cape soils (South Africa) with emphasis on toxic and essential elements." Thesis, University of Cape Town, 1995. http://hdl.handle.net/11427/26084.

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43

Misrole, Matthew. "A re-assessment of the geochronology and geochemistry of the Postberg Ignimbrites, Saldanha, Western Cape, South Africa." University of the Western Cape, 2020. http://hdl.handle.net/11394/7733.

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>Magister Scientiae - MSc The Saldania Belt in southern Africa, a product of the Pan-African Saldanian Orogeny, forms part of a system of Neoproterozoic mobile belts that border and weld older cratons on the African continent. It is a low-grade orogenic belt situated along the southwestern margin of the Kalahari Craton and is composed of several inliers of greenschist facies metasedimentary and metavolcanic rocks (Malmesbury Group), unroofed in megaanticlinal hinges of the Permo-Triassic Cape Fold Belt. The Malmesbury Group rocks were syn- and post-tectonically intruded in a pervasive transpressive regime between 555 Ma and 515 Ma by Neoproterozoic to early Cambrian S-, I- and A-type granites, monzodiorites, gabbros and quartz syenites, which collectively constitute the rocks of the Cape Granite Suite (CGS). Along the south-western coastline of South Africa, the Saldanha Bay Volcanic Complex (which forms part of the CGS) is divided into two eruption centres both of which have been identified as “intra-caldera pyroclastic ignimbrites”. The Postberg eruption centre is situated to the south of the Saldanha Bay entrance and the Saldanha eruption centre is situated to the north of the entrance. Both eruption centres display distinct geochemical signatures, the most apparent being the greater TiO2 concentrations (> 0.25 wt. %) of the Saldanha centre ignimbrites when compared to its Postberg centre counterparts. The Postberg eruption centre consists of S-type rhyolitic ignimbrites which are subdivided into the two geochemically distinct Plankiesbaai and Tsaarsbank Ignimbrites. Small amounts of the Jacobs Bay and Saldanha Ignimbrites (less felsic tephra from the Saldanha eruption centre) are also present in the Postberg eruption centre. A robust geochemical analysis of both the Plankiesbaai and Tsaarsbank magma groups display high SiO2 content (>76 wt. %), a lack of variation in TiO2 and Zr, high Al2O3 and ASI (aluminium saturation index) values (> 1.0 and generally >1.1 which, on average, is higher than the Saldanha eruption centre ignimbrites), low CaO and Na2O, and a highly ferroan character. The Plankiesbaai ignimbrite also display lower #Mg concentration compared to the Tsaarsbank ignimbrite. Typical geochemical trends in the Postberg eruption centre include the lack of variation in Zr content, higher Rb content and lower Sr, Ba, V and Zn concentrations when compared to the tephra of the Saldanha eruption centre found in the Postberg area.

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Yang, Jin. "Exploration geochemical mapping in the north-eastern sector of the Morokweng impact structure, South Africa." Thesis, University of the Western Cape, 2006. http://etd.uwc.ac.za/index.php?module=etd&action=viewtitle&id=gen8Srv25Nme4_8373_1189147095.

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The Morokweng impact structure which is located in the North West province of South Africa, has attracted attention as a potential host for Ni-PGE mineralization. Geochemical exploration techniques using hydroxylamine partial extraction were used to determine the nature and source of surface geochemical anomalies known to occur in the overlying aeolian sang regolith. About 40 aeolian samples were taken from an area of about 35 square kilometer, located in the north eastern sector of the Morokweng impact structure. The samples were sieved to various grain size fractions and partially extracted using varying concentration of hydroxylamine hydrochloride at 50&deg C.

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45

Field, Matthew. "The petrology and geochemistry of the upper critical zone of the Bushveld complex at the Amandelbult section of Rustenberg Platinum Mines Limited, Northwestern Transvaal, South Africa." Thesis, Rhodes University, 1987. http://hdl.handle.net/10962/d1007499.

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A study of petrological and geochemical variations through the upper Critical Zone of the Bushveld Complex at Amandelbult section of R.P,M. was undertaken. The sequence at this locality may be divided into seven "units" two of which appear to be complete, possessing the sequence harzburgite-pyroxenite-norite-anorthosite. The other five Units lack basal, intermediate or upper members. Considerable lateral variations are apparent in this sequence, but these are restricted to the Lower Pseudo Reef-Merensky Reef interval, tne same portion of the succession which is affected by pothole structures. The single most important petrographic feature of genetic significance is the occurrence of annealed, recrystallized anorthosite immediately underlying ulstramafic layers. This, together with the undulatory nature of the contact between the two rock layers, suggests that the ultramafic layer was emplaced as a hot liquid over a pre-existing, crystalline anorthosite floor, and that some remelting of this layer occurred. Variations in the chemical make-up of constituent silicate minerals reveal a number of significant processes which may have been operative in the magma chamber prior to crystallization, Olivine grains, for instance, exhibit extremely wide chemical variations both within single layers and from one layer to the next. These variations are best explained by re-equilibration processes with spinel and base metal sulphides, rather than by wide variations in original liquidus compositions. It appears that the compositions of the initial liquids from which each basal olivine-bearing layer crystallized, were approximately similar. Variations in the iron-magnesium ratio of ortho-pyroxenes indicate well defined continuous fractionation trends in units which are considered to be complete. Magnesian compositions are recorded in ultramfic members, while increasingly iron-enriched values are recorded upwards through the sequence pyroxenite-norite-antorthosite. Plagioclase grains exhibit less well defined fractionation trends, but it is clear that an upward increase in An is encountered through indivitual Units. This is in direct contrast to the trend exhibited by orthopyroxene. A further feature of plagioclase grains is the considerable degree of chemical zonation exhibited by them. In cumulus grains this is commonly manifested as strongly reversed rims, while in intercululus grains normal zoning is ubiquitous. Whole-rock chemical variations through the succession indicate that cyclical variations occur through successive Units, but that these merely reflect changes in modal mineralogy and not liquid fractionation trends. Such trends can be shown for selected element ratios, where these elements are known to partition into a single mineral phase. Rations of pyroxene components such as the nickel/scandium ratio, exhibit a saw tooth pattern through successive Units, while ratios of plagioclase components such as the strontium/alumina ratio have unique, fairly constant values for each individual Unit but different values for successive Units. The latter type of cyclicity is not always strictly confined to lithologically recognized boundaries between Units, and a slight overlap into overlying ultramafic layers is apparent. An investigation of variations in trace element levels in a single layer in five widely separated boreholes revealed that there is some evidence for a lateral fractionation trend from the southwest (more primitive) to the northeast (more evolved), although the small number of data points available preclude definite conclusions. There exists in the data some evidence that the Giant Mottled Anorthosite differs chemically from the other anorthosites in the study section, and that it more closely resembles rocks of the Main Zone. This evidence is particularly apparent in variations of the chromium/aluminium ratio of orthoyroxene grains, and in the An content of plagioclase grains, both of whose trends exhibit distinct inflections at the base of this member. The features of the succession at Amandelbult are best explained by the model of Eales et al. (in press, a), which visualizes the input of a number of pulses of new, hot liquid into a magma chamber containing the fractionated residua of previous influxes. At a critical point in time, just prior to the mafic Merensky Reef input, a large input of gabboic liquid was intruded at high levels in the chamber. The lower portions of this liquid mixed with the residua of earlier mafic inputs, which in turn mixed with new inputs of mafic, typical Critical Zone liquids. Thus the lower portions of the study section represent mixtures of new Critical Zone liquids with the residua of previous such influxes, while the upper portions have the added complication of mixture with a Main Zone-type liquid. The unique chemical character of the Giant Mottled Anorthosite appears to be a direct manifestation of the influence of the Main Zone liquid. KMBT_363 Adobe Acrobat 9.54 Paper Capture Plug-in

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Ntholi, Thakane Thato Prudence. "A technical and economic evaluation of a passive underground mine-water purification system (PUMPS): a geothermally powered geo-engineering system designed for in-situ bio-remediation of acid mine water." Thesis, Nelson Mandela Metropolitan University, 2017. http://hdl.handle.net/10948/19586.

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PUMPS mimics natural geothermal vents as a conceptual model designed for the remediation of acid mine water (AMW) in voids of abandoned gold mines of the Witwatersrand Basin in South Africa. In this system, a reaction chamber containing Desulfotomaculum kuznetsovii sulfate reducing bacteria will be set at the bottom of a 3-4 km deep mine that will be flooded. A geothermal system with at least one (1) doublet will be drilled from the bottom of the mine to the depth of 8km, where the temperatures are sufficient for geothermal energy harvesting. AMW, used as a geothermal fluid, will be pumped down the injection well and circulate through hot rock. The hot water is then used to generate electricity and then channelled into the reaction chamber to undergo bio-remediation. Following treatment, the water flows back into the mine voids where it will improve the quality of untreated AMW through dilution. Eventually, the mine will be flooded with clean water that can be stored underground and/or pumped up to surface for social and ecosystem services. Following an introduction and proof of concept for the PUMPS, the research builds further on the technical and economic evaluation of the PUMPS in order to assert its viability and sustainability. The technical viability includes testing the ability for Desulfotomaculum kuznetsovii to survive in high pressure condition; quantifying the amount of energy that can be drawn from the geothermal reservoir; determining the placement and scheme of the geothermal wells; and, finally, developing a robust economic model of the system. Experiments show that Desulfotomaculum Kuznetsovii can tolerate high pressure conditions in of at least 100bar at their ideal sulfate reducing temperature of 63°C. Geochemical modelling shows that AMW can be used effectively as a geothermal fluid for PUMPS. To achieve highest efficiency and minimal fluid loss, the geothermal wells should be placed along the SSE-NNW direction, based on the known stress field across the Witwatersrand Basin. With a flow rate of 30l/s the energy drawn from the geothermal reservoir is sufficient to drive PUMPS and the surplus energy is determined by the volume of AMW treated per day. All results indicate that the PUMPS is technically and economically viable. The economic model shows that the value and viability of the PUMPS is best reflected with a comprehensive inclusion of potential revenue (for example from chemical solution mining of deep seated gold) and financial/environmental incentives.

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47

Bokana, Reddy Ngili. "The lithogeochemical characterization of the Hondekloof nickel mineralization, Kliprand area, Garies Terrane, Namaqualand, South Africa." University of the Western Cape, 2015. http://hdl.handle.net/11394/5024.

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>Magister Scientiae - MSc A magmatic Ni-Cu (±Co-Zn) sulphide deposit, named the Hondekloof prospect, is present in the Kliprand area at the border between the Northern Cape and Western Cape Provinces of South Africa. The deposit occurs in the central part of the polyphase deformed and highly metamorphosed Garies Terrane, in the Namaqua Sector, along the south-western margin of the Mesoproterozoic Namaqua-Natal Metamorphic Province. Given the sub-economic concentrations yielded from evaluation of three of its known massive-sulphide lenses evaluated, the Hondekloof prospect has received relatively little consideration in terms of ongoing scientific research. Consequently, many aspects related to the genesis, classification and tectonic evolution of the deposit, to date, remain relatively unclear and unknown. The present contribution has therefore been geared to addressing some of those issues in view of the new data obtained on the country rocks and host rocks to the mineralization.Six exploration boreholes were logged, sampled and examined at the deposit site in Kliprand. A total of seven host rocks, namely meta-gabbronorite, biotite gneiss, feldspathic-biotite-garnet gneiss, pink gneiss, meta-syenite as well as enderbite along with a garnetiferous quartzofeldspathic rock occur in association with the sulphide mineralization. The origin, protoliths and tectonic settings of the host lithological units were determined and discussed in terms of modern plate tectonic principles. The meta-gabbronorite (the actual ore host), which had a magmatic protolith and forms part of the pre- to syn-tectonic Oorkraal Suite, displays the chemical characteristics of a depleted mantle origin (source of MORB-like melt), generated within a continental tectonic rift environment. Country rocks with sedimentary protoliths have chemical characteristics indicating a psammitic, felsic to intermediate provenance deposited within a regional subduction-related tectonic setting. A number of geochemical indices, of which the combination of element-ratios (such as Fe2O3/Al2O3 vs. TiO2/Al2O3, as well as Cr vs. Ni, amongst others) created as exploration vectors towards mineralisation, have shown potential for pointing towards the direction of the mineralization. Based on classification schemes of magmatic Ni sulphide deposits, it is has been suggested that the Hondekloof prospect could be classified as a low MgO, conduit-type, disseminated magmatic nickel sulphide deposit.

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Nguema, Mve Oliver Patrice. "Petrology, geochronology and provenance of the Laingsburg and Tanqua Karoo submarine fan systems, Ecca Group, South Africa." Thesis, Stellenbosch : University of Stellenbosch, 2005. http://hdl.handle.net/10019.1/2018.

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Thesis (MSc (Earth Sciences))—University of Stellenbosch, 2005. The integration of whole-rock chemistry, heavy mineral chemistry, detrital zircon morphology and age dating has enabled high-resolution characterization of the Permian Laingsburg and Tanqua submarine fan provenance in the Karoo Basin, upper Ecca Group, South Africa. Geochemically, the Laingsburg and Tanqua sandstones are classified as greywacke and litharenite. The chemical index of alteration values for these sandstones suggest low to moderately weathered sources and a relatively cold climate. Abundant angular clastic grains and lithic fragments as well as the predominance of pristine zircons indicate a near provenance and a first cycle derivation. The investigated sandstones originated from a continental island arc and an active continental margin. The source is dominantly intermediate to felsic and includes tonalites, granodiorites, and adamellites or their volcanic equivalents.

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Polteau, Stéphane. "The early proterozoic Makganyene glacial event in South Africa : its implication in sequence stratigraphy interpretations, paleoenvironmental conditions and iron and manganese ore deposition." Thesis, Rhodes University, 2005. http://hdl.handle.net/10962/d1007612.

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The Makganyene Formation forms the base of the Postmasburg Group in the Transvaal Supergroup in the Griqualand West Basin. It consists of diamictites, sandstones, banded iron-formations (BIFs), shales, siltstones and carbonates. It is generally accepted that the Makganyene Formation rests on an erosive regional unconformity throughout the Northern Cape Province. However this study demonstrates that this stratigraphic relationship is not universal, and conformable contacts have been observed. One of the principal aims of this study is to identify the nature of the Makganyene basal contact throughout the Griqualand West Basin. Intensive fieldwork was carried out from Prieska in the south, to Danielskuil in the north. In the Sishen and Hotazel areas, only borehole material was available to assess the stratigraphy. The Griquatown Fault Zone delimits the boundary between the deep basin and platform facies. The Koegas Subgroup is only present south of the Griquatown Fault Zone, where it pinches out. However, the transition Griquatown BIFs-Koegas Subgroup occurs in lacustrine deposits on the Ghaap platform (Beukes, 1983). The Griquatown Fault Zone represents the edge of the basin, which corresponds to a hinge rather than a fault zone. The Makganyene Formation rests with a conformable contact on the Koegas Subgroup south of the Griquatown Hinge Zone, and north of it the Makganyene Formation lies unconformably on the Asbestos Hills Subgroup. The Makganyene Formation displays lateral facies changes that reflect the paleogeography of the Griqualand West Basin, and the development of ice sheets/shelves. The Ghaap platform is characterised by coarse immature sand interbedded with the diamictites. The clasts in this area contain local Asbestos Hills material and no dropstones are present. Such settings are typical of sediments that are being deposited below a grounded ice mass. At the Griquatown Hinge Zone, the sandstone lenses are smaller, and the clasts consist of chert, of which a great number are striated and faceted. In the Matsap area, the presence of dropstones is strong evidence for the presence of a floating ice shelf that released its material by basal melting. Further south, the Makganyene Formation contains stromatolitic bioherms that only form if clastic contamination is minimal and therefore the ice that transported the detritus to the basin did not extend far into open sea conditions. The base of the Hotazel Formation also contains diamictite levels. Dropstones have been identified, implying a glacial origin. The Hotazel diamictites are interbedded with hyaloclastites and BIFs. The Makganyene glacial event, therefore, was not restricted to the Makganyene Formation, but also included the Ongeluk Formation, through to the base of the Hotazel Formation. Petrographic studies of the Makganyene Formation and the base of the Hotazel Formation reveal mineral assemblages that are diagnostic of early to late diagenetic crystallisation and of low-grade metamorphism not exceeding the very low green-schist facies. The facies identified display the same sense of basin deepening, from shallow high-energy Hotazel area on the Ghaap platform, to the deep basin in the Matsap area. Whole-rock geochemical analyses reveal that the elemental composition of the Makganyene Formation is very similar to that of the Asbestos Hills BIFs, which were the most important source of clastic detritus for the Makganyene Formation. However, minor amounts of carbonates of the Campbellrand Subgroup, as well as a felsic crustal input from the Archean granitoid basement, made contributions. On the Ghaap platform, the Makganyene diamictite is enriched in iron, calcium, and magnesium, while in the deeper parts of the basin the diamictites are enriched in detrital elements, such as titanium and aluminium, which occur in the fine clay component. The Hotazel diamictite displays a distinct mafic volcanic input, related to the extrusion of the Ongeluk basaltic andesites, which was incorporated in the glacial sediments. Sequence stratigraphy is based on the recognition of contacts separating the different systems tracts that compose a depositional sequence. However, because the basal contact of the Makganyene Formation has not been properly identified in previous work, no correct model has been proposed so far. Therefore correlations between the Griqualand West and the Transvaal basins, based on lithostratigraphic similarities and extrapolations of unconformities, have to be reviewed, especially since the publication of new radiometric ages contradict all previously proposed correlations. It is proposed here that the Transvaal Supergroup in the Griqualand West Basin represents a continuous depositional event that lasted about 200 Ma. The Makganyene glacial event occurred during changing conditions in the chemistries of the atmosphere and ocean, and in the continental configuration. A Snowball Earth event has been proposed as the causative process of such paleoenvironmental changes. However, evidence presented here of less dramatic glacial conditions, with areas of ice-free waters, implies an alternative to the Snowball Earth event. The paleoenvironmental changes are thought to represent a transition from an anaerobic to aerobic atmosphere, that was responsible for the global cooling of the surface of the Earth, Such a glacial event may have aided in the large-scale precipitation of iron and manganese in areas of intense upwellings.

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Manyeruke, Tawanda Darlington. "The petrography and geochemistry of the Platreef on the farm Townlands near Potgietersrus, northern Bushveld Complex." Pretoria : [s.n.], 2005. http://upetd.up.ac.za/thesis/available/etd-04282005-110052/.

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Dissertations / Theses on the topic 'Geochemistry – South Africa – Rooiberg'

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