Dissertations / Theses on the topic 'Geology - South Africa - Bandelierkop'

The Bandelierkop Formation of the Southern Marginal Zone (SMZ) of the Limpopo Belt consists of metamorphosed ultramafic, mafic and sedimentary rocks. Metamorphic conditions indicated by the petrography of these different rock groups are consistent with upper amphibolite to granulite facies. The ultramafic and mafic rocks are geochemically akin to peridotitic-pyroxenitic intrusive rocks and high-Mg basalts respectively. Metamorphism of these two rock groups in the SMZ was an essentially closed system process, except for the highly volatile phases such as H₂O and CO₂. The metasediments appear to represent a sequence of high (Mg+Fe)-greywackes and/or deep-water shales with minor amounts of iron formation material. The unusually mafic character of the metasediments can be ascribed to a high ultramafic + mafic source component to the original sediment. Some modification of the major and trace element compositions of the pelitic rocks has been caused by the removal of partial melts and the metamorphism of the pelitic rocks is not therefore considered to have occurred under closed system conditions. Variable extraction of partial melts is implied by the chemical variations shown by the pelitic rocks and is also suggested by the presence of large pegmatitic felsic bodies which are commonly found close to the pelitic rocks. Detailed petrographic study of the Bandelierkop Formation rocks suggests an increase in metamorphic grade, and/or a decrease in water activity, from south to north within the Southern Marginal Zone. Peak metamorphic conditions of 730°C + 65°C at pressures of 6.1 ± 1.5 kbars may be deduced from a careful application of several cation thermometers and barometers on selected mineral analyses. A rigorous application of garnet-biotite thermometry to the pelitic rocks indicates that the transition from orthoamphibole gneisses in the south to orthopyroxene-bearing rocks in the north of the SMZ terrane, is a function of changing biotite composition and/or decreasing water activities rather than an increase in metamorphic temperatures. In contrast to the major and trace element data, the stable isotope data for the ultramafic and mafic rocks in the SMZ indicate open system behaviour for some of these rocks, but closed system behaviour for the pelites. Extraction of SO to 70% partial melts from the pelitic rocks, should not, however, have affected the δ¹⁸O value of the restite. Petrological and stable isotope data in the SMZ rocks are consistent with retrogression in all these rocks and open system behaviour for oxygen in some ultramafic and mafic rocks, being caused by the crystallization and accompanying fluid release of melts produced during prograde metamorphism of the pelitic rocks. Small scale (-5 to 30m's) heterogeneity is implied by both oxygen and carbon stable isotope compositions of closely spaced rock samples, even for those collected from within large "shear zones", suggesting small fluid/rock ratios for most of the samples in the high-grade terrane or heterogeneous stable isotopic compositions of the fluids. Furthermore, a similarity in mineral-mineral stable isotope fractionation factors is observed for all the pelitic rocks, including the orthoamphibole gneisses found immediately south of the orthopyroxene isograd. These features preclude the presence of pervasive fluid infiltration after peak metamorphism. Two implications are, that granulite facies metamorphism in the SMZ terrane was not caused by an influx of mantle derived CO₂-rich fluid and, that the orthoamphibole gneisses are not retrogressed equivalents of the granulites found to the north of the orthopyroxene isograd. It is suggested that this isograd represents a change in the water activities of the rocks during metamorphism. Apparent disequilibria in mineral - mineral stable isotope fractionations observed amongst different minerals within any one pelitic rock, may be explained by a combination of the crystallization of residual melt within these rocks and oxygen diffusion amongst minerals which have not reached their oxygen-closure. The concordant quartz-plagioclase, quartz-biotite and plagioclase-biotite oxygen isotope equilibration temperatures are taken to represent minimum crystallization temperatures for the melts (-560°C), while successively higher quartz-orthopyroxene, quartz-amphibole and quartz-garnet oxygen isotope equilibration temperatures are a function of increasing closure temperatures for the orthopyroxene, amphibole and garnet respectively. The minimum estimate to peak metamorphic temperatures is given by the quartz-garnet oxygen isotope temperature averaging 736 + 52°C. If oxygen diffusion experiments performed in hydrothermal systems are appropriate for the SMZ rocks, then cooling rates for the SMZ terrane could have been as low as 12 to 25°C/My over a temperature range of 480 to 600°C. Stable isotope modeling of hypothetical fluids that may have been in equilibrium with the high-grade rocks, suggests that a mixture of CO₂ and H₂O, with CO₂/H₂O mole ratios > 0.1 can precipitate both quartz and carbonate of stable isotope composition similar to those determined for quartz and carbonate from the mineralized Archaean lode gold deposits of the Murchison and Pietersburg greenstone belts. A model involving granulite facies metamorphism, partial melt extraction and subsequent release of fluids, Au, K and S upon crystallization of such melts, appears to be viable for gold mineralization occuring in the adjacent lower grade greenstone belts and in the high-grade terrane of the Southern Marginal Zone.

Includes bibliographical references.
This thesis presents work undertaken to better understand the complex evolution of the terrestrial landscape now submerged by high sea levels offshore of Mossel Bay along the South Coast of South Africa. Three marine geophysical surveys and scuba diving were used to examine evidence of past sea-level fluctuations and interpret geological deposits on the seafloor. Additional geological mapping of coastal outcrops was carried out to link land and sea features and rock samples were dated using Optically Stimulated Luminescence (OSL). Geophysical investigations include a regional seismic survey extending from Still Bay in the west to Buffels Bay in the east out to a maximum water depth of 110 m; a high-resolution investigation of the Mossel Bay shelf using multibeam bathymetry, side-scan sonar and sub-bottom profiling; and a shallow seismic pinger survey of Swartvlei, the most prominent coastal lake in the Wilderness Embayment. This study presents 9 discrete seismic sequences, and describes major offshore geomorphic features such as submerged sea cliffs, palaeo-coastal zones and fluvial systems. Oscillation in sea level between ca. 2.7 and 0.9 Ma likely resulted in the formation of the prominent -45 m terrace, which separates a relatively steep inner from a low-gradient mid shelf. Beach and dune deposits span from Marine Isotope Stage 15 (MIS 15) (582 ka) to Recent based on an age model that integrates OSL ages and the established eustatic sea-level record. The most prominent deposits date from the MIS 6 glacial to MIS 5 interglacial periods and include incised lowstand river channels and regressive aeolianites that extended at least 10 km inland from their associated palaeoshorelines. The MIS 5 deposits include transgressive beachrock, an extensive foreshore unit which prograded on the MIS 5e highstand, and regressive beach and dune deposits on the shelf associated with the subsequent fall in sea level. MIS 4 lowstand incised river channels were infilled with sediment truncated during rapid landward shoreface migration at the MIS 4 termination. Lowenergy, back-barrier MIS 4/3 sediments are preserved as a result of overstepping associated with meltwater pulses of the MIS 2 termination. The MIS 1 sediment wedge comprises reworked sediment and is best developed on the inner shelf. Holocene highstand sedimentation continues to prograde. Accommodation space for coastal deposits is controlled by antecedent drainage pathways and the gradient of the adjacent inner continental shelf. The geological deposits on the emergent shelf indicate a greatly expanded glacial coastal plain that potentially received more rain feeding low-gradient meandering rivers and wetland lakes. These extensive wetland environments provided a rich source of diverse food types which along with abundant marine resources on the shoreline made the Southern Coastal Plain an ideal habitat for our ancestors.

The Cretaceous (133Ma) Kroonstad Group II Kimberlite Cluster is located approximately 200km south west of Johannesburg on the Kaapvaal Craton. The cluster is made up of six kimberlite pipes and numerous other intrusive dike/sill bodies. Three of the pipes are analysed in this study, which includes the: Voorspoed, Lace (Crown) and Besterskraal North pipes. These pipes were emplaced at surface into the Karoo Supergroup, which is comprised of older sedimentary rocks (300-185Ma) overlain by flood basalts (185Ma). At depth the pipes have intruded the Transvaal (2100-2600Ma) and Ventersdorp (2700Ma) Supergroups, which are comprised dominantly of carbonates and various volcanic units respectively. The pipes have typical morphology of South African pipes with circular to sub-circular plan views and steep 82o pipe margins. The Voorspoed pipe is 12ha in size and is characterised by the presence of a large block of Karoo basalt approximately 6ha in size at the current land surface. This large basalt block extends to a maximum of 300m below the current land surface. The main Lace pipe is 2ha is size with a smaller (<0.5ha) satellite pipe approximately 50m to the west. No information is available on the morphology of the Besterskraal North pipe as it is sub-economic and no mining has occurred. Samples from the Besterskraal North pipe were collected from the De Beers archives. The Kroonstad Cluster has been subjected to approximately 1750m of erosion post-emplacement, which has been calculated by the analysis of the crustal xenoliths with the pipe infill. The hypabyssal kimberlite from the three pipes shows a gradational evolution in magma compositions, indicated by the mineralogy and geochemistry. The Lace pipe is the least evolved and has characteristics more similar to Group I kimberlites. The Voorspoed and Besterskraal North kimberlite are intermediately and highly evolved respectively. The gradational evolution is marked by an increase in SiO2 and Na2O contents. Furthermore the occurrence of abundant primary diopside, aegirine, sanidine, K-richterite and leucite indicates evolution of the magma. The root zones of the pipes are characterised by globular segregationary transitional kimberlite, which is interpreted to be hypabyssal and not the result of pyroclastic welding/agglutination. The hypabyssal transitional kimberlite (HKt) is characterised by incipient globular segregationary textures only and the typical tuffisitic transitional kimberlite (TKt) end member (Hetman et al. 2004) is not observed. The HKt contact with the overlying volcaniclastic kimberlite (VK) infill is sharp and not gradational. The presence of HKt in the satellite blind pipe at Lace further indicates that the distinct kimberlite rock type must be forming sub-volcanically. The HKt is distinctly different at the Voorspoed and Lace pipes, which is likely a result of differing compositions of the late stage magmatic liquid. Microlitic clinopyroxene is only observed at the Lace HKt and is interpreted to form as a result of both crustal xenolith contamination and CO2 degassing. Furthermore the HKt is intimately associated with contact breccias in the sidewall. The root zones of the Kroonstad pipes are interpreted to form through the development of a sub-volcanic embryonic pipe. The volcaniclastic kimberlite (VK) infill of the Kroonstad pipes is not typical of South African tuffisitic Class 1 kimberlite pipes. The VK at Voorspoed is characterised by numerous horizontally layered massive volcaniclastic kimberlite (MVK) units, which are interpreted to have formed in a deep open vent through primary pyroclastic deposition. MVK is the dominant rock type infilling the Voorspoed pipe, however numerous other minor units occur. Normally graded units are interpreted to form through gravitational collapse of the tuff ring. MVK units rich in Karoo basalt and/or Karoo sandstone are interpreted to form through gravitational sidewall failure deep within an open vent. Magmaclasts are interpreted to form in the HKt during the development of an embryonic pipe and therefore the term autolith or nucleated autolith may be applied. Debate on the validity of the term nucleated autolith is beyond this study and therefore the term nucleated magmaclast is used to refer to spherical magmaclasts in the VK. The emplacement of the Kroonstad pipes is particularly complex and is not similar to typical Class 1 tuffisitic kimberlites. However the initial stage of pipe emplacement is similar to typical South African kimberlites and is interpreted to be through the development of an embryonic pipe as described by Clement (1982). The vent clearing eruption is interpreted to be from the bottom up through the exsolution of juvenile volatiles and the pipe shape is controlled by the depth of the eruption (+/-2km) (Skinner, 2008). The initial embryonic pipe development and explosive eruption is similar to other South African kimberlites, however the vent is cleared and left open, which is typical of Class 2 Prairies type and Class 3 Lac de Gras type pipes. The latter vent infilling processes are similar to Class 3 kimberlites from Lac de Gras and are dominated at the current level by primary pyroclastic deposition.

The present investigation examines the relationship between the Proterozoic Richtersveld and Bushmanland Subprovinces in the westernmost part of the Namaqua Province, near Eksteenfontein, Republic of South Africa. There is a controversy about this relationship because isotopic data contrast with field evidence. On a regional scale the Richtersveld Subprovince is separated from the Bushmanland Subprovince by the northward-dipping Groothoek Thrust. North of the thrust the Richtersveld Subprovince is comprised of low grade volcano/ plutonic rocks of the Vioolsdrif Terrane and medium grade volcano sedimentary sequences of the Pella Terrane. Medium grade rocks of the Steinkopf Terrane (Bushmanland Subprovince) lie immediately south of the thrust. Late Proterozoic strata of the Stinkfontein Formation (Gariep Group) overlie the Namaqua Province in the west; Cambrian Nama Group outliers occur east of the Stinkfontein Formation. Isotopic data show that lithologies of the Richtersveld Subprovince formed between 2000 - 1730 Ma, whereas those of the Bushmanland Subprovince are younger. It is not clear whether the Namaqua metamorphic imprint (at 1200 - 1100 Ma), which is manifest in terranes south of the Groothoek Thrust, extended as far as the Vioolsdrif Terrane in the north. Early Proterozoic structural and metamorphic imprints are inferred to have been obliterated during this event. The westernmost part of the Namaqua Province was overprinted for a distance of 100 km from the coast, during the Pan-African event at 700 Ma and 500 Ma. An area measuring nearly 500 km2 , traversing the western extremity of the boundary between the Richtersveld and Bushmanland Subprovinces was mapped on a scale of 1:36,000. Field mapping was carried out with the aid of aerial photographs, whereas laboratory techniques included map compilation, structural analysis, X-ray diffractometry, geochemical (XRF) and electron microprobe analyses. Supracrustal units of the Richtersveld Subprovince are composed of quartzo-feldspathic gneisses, schists, and minor meta-pelites. Supracrustals of the Bushmanland Subprovince are less diverse than those of the Richtersveld Subprovince and have a disconformable relationship with them. Most intrusive rock-types are thick granitic sheets, except the Early Proterozoic Vioolsdrif Granodiorite which forms part of a batholithic pluton in the north. The Sabieboomrante adamellite gneiss, Kouefontein granite gneiss and Dabbieputs granite gneiss could not be correlated with lithologies commonly occurring in the Richtersveld and Bushmanland Subprovinces. They have been given the new rock names. Mafic and ultramafic rocks of the Klipbok complex occur along the strike of the Groothoek Thrust. They form part of the Richtersveld Subprovince.

This thesis evaluates the utility of lead (Pb) isotopes, in combination with strontium (Sr) isotopes, as a geochemical tracer for studying the palaeodiets and palaeo-landscape usage in southwestern South Africa. Isotopes of light elements, carbon (C), nitrogen (N), oxygen (O), and sulphur (S), are widely used as (palaeo) environmental tracers, but do not yield information on the geological substrates on which individuals have lived. Sr isotopes in bones and teeth are useful in distinguishing between areas of distinct bedrock geology, however, the efficiency of Sr is limited at near-coastal areas, which forms a major part of this study area. This is because Sr has a relatively high concentration and long residence time in seawater. In addition, coastal soils contain not only aerosol-derived marine Sr, but frequently also include fragments of shells and other marine carbonates, so their 87Sr/86Sr is like the ocean. This study analysed Pb and Sr concentrations and isotopic compositions of animals and plants derived from the various geological substrates of southwestern South Africa. In order to do this, a detailed Sr-Pb separation scheme was developed, involving the separation and pre-concentration of Sr and Pb from a single digested sample by means of ion-exchange chromatography. Elemental concentrations were measured with a Thermo X-series II quadrupole ICP-MS instrument. Sr concentrations ranged between 111 ppm and 1862 ppm, while Pb concentrations were lower, ranging between 0.012 ppm and 2.30 ppm. Isotopic ratios were determined by means of a Nu Instruments high resolution multi-collector inductively-coupled plasma mass spectrometry (HR-MC-ICP-MS). Samples were introduced into the system as solutions, producing an order of magnitude more precise results than laser ablation analysis on the same material. Sr isotopes are useful for distinguishing between individuals living in near-coastal environments and those living further inland, while Pb isotopes could differentiate between granites and shales/sandstones. Pb isotopes proved to be a valuable palaeodietary tracer and can be used in combination with Sr isotopes to extent our knowledge of palaeo-landscape usage at coastal-marine environments.

Bibliography: pages 55-58.
The seafloor geology of Walker Bay on the southern Cape coastline is described by making use of geophysical information obtained over a period of 4 years, between 1986 and 1990. The data include side-scan sonar images, seismic profiles, seabed samples and observations by a Remotely Operated underwater Vehicle (ROV). Four sonograph facies were identified, based on their distinctly different reflectivity patterns. Using the seabed samples and R.O.V. observations, the physical characteristics of these facies are determined and presented in map format. Facies 1 consists of Bokkeveld Group rock outcrops with relatively high relief, occupying approximately 45 percent of the study area. Facies 2 represents similar outcrops but with low relief and partially covered by a thin veneer of unconsolidated sediment, including localized occurrences of loose cobbles and boulders. Facies 3 and 4 relate to sediment-covered areas displaying different bedform types. Facies 3 is dominated by well-defined patches of megarippled gravelly sand, whereas Facies 4 consists of small-scale rippled sand. The characteristics of the Facies 3 megarippled patches are discussed in detail and their relationships with the local wave pattern and nearby Facies 1 and 2 rock outcrops are investigated.

This research was aimed at employing the broad use of petrophysical analysis and reservoir modelling techniques to explore the petroleum resources in the sandstone units of deep marine play in the Bredasdorp Basin.

Tectonics plays an important role in the genesis and subsequent mlnlng development of the Kwaggashoek East ore body. Lithological key units control the effectiveness of the ore forming processes, affecting the in situ ore reserve, The Kwaggashoek East deposit is the product of primary and secondary processes. A genetic model focussed on the source, migration and deposition of iron suggests a possible original source of iron as the product of very dilute hydrothermal input into deep ocean waters, with subsequent migration through structural conduits. Supergene processes account for the upgrading of the ore and the phosphorus redistribution. A good correlation between samples in a preliminary geostatistical study reflects the effectiveness of this process in the high grade ore zone. A broad overview of the economic issues which affect the commercialization of iron, indicates a balanced supply-demand situation for the five next years. The reserve estimation procedure requires accurate scientific terminology and appropriate methodology. Documentation is essential and should be detailed enough to allow for future reassessment. The results of three estimation methods in Kwaggashoek East differ by less than 5%. The accuracy of the final results depends more on geological interpretation and assumptions than on the method applied. Although optimization of grade and tonnage in the Kwaggashoek East deposit seems to be met with the actual cut-off grade used in the Thabazimbi mine district, the grade-quality concept introduced in this thesis indicates a decrease in the estimated reserves for the deposit

The Platreef, located in the northern limb of the Bushveld Complex in South Africa, is a world-class Ni-Cu-PGE deposit. The complexity of the deposit has meant that despite the numerous studies, developing an accepted genetic model to account for the variations observed has been difficult. While some authors have suggested that it is part of the Upper Critical Zone, correlating it to the Merensky Reef, others have suggested that the Platreef is unrelated to mineralisation found elsewhere in the Bushveld Complex. The model tested is the multiple staging chamber model developed by McDonald and Holwell, that proposes that the parental magma was upgraded in PGE (plus Ni and Cu) prior to emplacement. Key to testing this model has been the analysis of immiscible sulphide inclusions trapped within chromite grains, believed to represent the early parental magma. Analysis has shown that they contain high PGE tenors, significant semi-metal (Bi, Te and As) content and the low S/Se ratios of the inclusions suggest a mantle source. Interaction of the sulphide liquid with multiple batches of magma in the staging chamber is proposed to have enabled enrichment to occur prior to emplacement through a process known as multi-stage dissolution upgrading. The analysis of chromite grains from the three study farms has shown that the variation in chromite composition is dependent on host lithology and the location of the sample along strike of the Platreef. Some correlation can be made with chromites from the UG2 but Platreef chromites cannot be directly correlated to those from the Merensky Reef. Investigation of PGE concentrations within the BMS from Zwartfontein has shown a strong association between PGE and BMS and that the distribution of PGE is consistent with fractional crystallisation of a sulphide liquid. The PGM study has shown that variation along strike and down dip of the Platreef is not strictly controlled by footwall lithologies as previously proposed. Variation is suggested to be the result of differing temperatures and ƒO2 conditions due to the proximity around proposed feeder zones. In order to further test the staging chamber model, S isotope analysis should be carried out on the sulphide inclusions to ascertain if a magmatic signature is present. In addition, further support to the model may be achieved by examining other Lower Zone bodies for chalcophile element depletion.

Detailed field mapping (Map, Appendix B) has been conducted in and around the boundaries of a 14x18km, volcanic complex 35km northeast of Molteno in the Eastern Cape Province, South Africa. The structure is interpreted as a subsidence structure, and is filled with two volcaniclastic breccias, numerous lava flows, a number of sedimentary facies, and lies on a base of Clarens Formation overlying Elliot Formation rocks. This is an important study because 'widespread, voluminous fields of basaltic breccias are very rare (see Hanson and Elliot, 1996) and this is the first time that this type of volcanic complex and its deposits have been described. Detailed analyses of the two volcaniclastic breccias revealed changes in colour, clast types, clast sizes, and degree of alteration over relatively short distances both vertically and laterally within a single breccia unit. The variation in clast sizes implies a lack of sorting of the breccias. The lower of the two volcaniclastic breccias fills the subsidence structure, and outcrops between the Stormberg sedimentary sequence and the overlying Drakensberg basalts and was produced from phreatomagmatic eruptions signalling the start of the break-up of Gondwanaland in the mid-Jurassic. The upper volcaniclastic breccia is interbedded with the flood basalts and is separated from the lower breccia by up to 100m of lava flows in places, it is finer-grained than the lower volcaniclastic breccia, and it extends over 10km south, and over 100km north from the volcanic complex. The upper breccia is inferred to have been transported from outside the study area, from a source presumably similar to the subsidence structure in the volcanic complex. The pyroclastic material forming the upper breccia was transported to the subsidence structure as a laharic debris flow, based on its poorly sorted, unwelded and matrix-supported appearance. However, both breccias are unlikely to have been derived from epiclastic reworking of lava flows as they contain glass shards which are atypical of those derived from the autoclastic component of lava flows. The breccias are therefore not "secondary" lahars. There is also no evidence of any palaeotopographic highs from which the breccias could have been derived as gravity-driven flows. Based on the occurrence of three, 1m thick lacustrine deposits, localised peperite, fluvial reworking of sandstone and breccia in an outcrop to the south of the subsidence structure, and channel-lags encountered only in the upper units of the Clarens Formation and only within the subsidence structure, the palaeoenvironment inferred for the subsidence structure is one of wet sediment, possibly a shallow lake, in a topographic depression fed by small streams. Magmatic intrusions below the subsidence structure heated the water-laden, partly consolidated Clarens Formation sandstones, causing the circulation of pore fluid which resulted in the precipitation of minerals forming pisoliths in the sandstones. Intruding magma mixed, nonexplosively, with the wet, unconsolidated sediments near the base of the Clarens Formation (at approximately 100m below the surface), forming fluidal peperite by a process of sediment fluidisation where magma replaces wet sediment and cools slowly enough to prevent the magma fracturing brittly. Formation of fluidal peperite may have been a precursor to the development of FCIs (Fuel Coolant Interactions) (Busby-Spera and White, 1987). The breccias may represent the products of FCIs and may be the erupted equivalents of the peperites, suggesting a possible genetic link between the two. The peperites may have given way to FCI eruptions due to a number of factors including the drying out of the sediments and/or an increase in the volume of intruded magma below the subsidence structure which may have resulted in a more explosive interaction between sediment and magma. Phreatic activity fragmented and erupted the Clarens Formation sandstone, and stream flows reworked the angular sandstone fragments, pisoliths and sand grains into channelised deposits. With an increase in magmatic activity below the subsidence structure, phreatic activity became phreatomagmatic. The wet, partly consolidated Clarens Formation, and underlying, fully consolidated Elliot Formation sediments were erupted and fragmented. Clasts and individual grains of these sediments were redeposited with juvenile and non-juvenile basaltic material probably by a combination of back fall, where clasts erupted into the air fell directly back into the structure, and backflow where material was erupted out of the structure, but immediately flowed back in as lahars. This material formed the lower volcaniclastic breccia. A fault plane is identified along the southwestern margin of the subsidence structure, and is believed to continue up the western margin to the northwestern corner. A large dolerite body has intruded along the inferred fault plane on the western margin of the structure, and may be related to the formation of the lower volcaniclastic breccia, either directly through fluidisation of wet sediment during its intrusion, or as a dyke extending upwards from a network of sill-like intrusions below the subsidence structure. Geochemical analysis of the Drakensberg basalt lava flows by Mitchell (1980) and Masokwane (1997) revealed four distinct basalt types; the Moshesh's Ford, the Tafelkop, the Roodehoek, and the Vaalkop basalts. Basalt clasts sampled from the lower volcaniclastic breccia were shown to belong to the Moshesh's Ford basalt type which does not outcrop in situ within the subsidence structure. This implies that the Moshesh's Ford basalts were emplaced prior to the formation of the lower volcaniclastic breccia, and may have acted as a "cap-rock" over the system, allowing pressure from the vaporised fluids, heated by intruding basalt, to build up. The Moshesh's Ford basalt type was erupted prior to the resultant phreatomagmatic events forming the lower volcaniclastic breccia.

The variations in the composition, specifically the Cr20 S content and the Cr:Fe ratio, and the morphology of the Lower Group (LG) and Middle Group (MG) chromitite seams of the Critical Zone (CZ) across the western Bushveld Complex, including the Ruighoek and Brits sections, is investigated by means of whole-rock chemical data, both major and trace elements analysis, XRD and electron microprobe data. As a result ofthe paucity of exposed or developed LG1 - LG5 chromitite seams in the western Bushveld Complex, this study is confined to the investigation of the compositional variations of the LG6 to MG4 chromitite seams. In only one section, the Ruighoek section, was the entire succession of chromitite seams, from the LG1 - MG4, exposed. The silicate host rocks from the LG6 pyroxenite footwall to the collar of the CC2 drillcore (lower uCZ) in the Rustenburg section were sampled. This study reviews the compositional trends of the silicate host rocks, as the compositional variations of the chromitite seams reflect the chemical evolution of the host cumulate environment and, to a lesser degree, the composition onhe interstitial mineral phases in the chromitite seams. The compositional variations of the LG and MG chromitite seams are attributed to the compositional contrast between the replenishing magma and the resident magma. The chemical trends of the LG and MG chromitite layers and the host cumUlate rOCKS do not support the existence of two compositionalfy dissimilar magmas in the CZ, rather the cyclic layering of the CZ and the chemical variations of the chromitite seams are attributed to the mixing of primitive magma with the resident magma, both of which have essentially similar compositions. The compositional variations of the LG and MG chromitite seams along strike away from the supposed feeder site (Union section) to the distal facies (Brits section) are attributed to the advanced compositional contrast between the resident magma and the replenishing primitive magma pulses. The CZ is characterized by reversals in fractionation trends and this is attributed to the compositional evolution of the parental magma and not to the replenishment of the resident magma by influxes of grossly dissimilar magma compositions. The Cr20 S content and the Cr:Fe ratio of the MG chromitite layers increase from the Ruighoek (near proximal) section to the Brits section (distal facies). This is attributed to the advanced compositional contrasts between the resident magma and the replenishing primitive magma. In contrast, the Cr20 3 content and Cr:Fe ratios ofthe LG6 and LG8a chromitite seams decreases eastwards from the Ruighoek section. The average Cr:Fe ratio for the western Bushveld Complex is between 1.5 and\2.0, nonetheless, a progressively lower Cr:Fe ratio is noted from the LG1 chromitite up through to the MG4 chromitite seam in the Ruighoek section. tn the LG2 - LG4 chromitite interval a deviation to higher.lratios is encountered. A progressive substitution of Cr by AT and Fe in the Cr-spinel crystal lattice characterizes the chromitite succession from the LG1 seam up through the chromitite succession to MG4. The petrogeneSiS of the chromitite seams of the CZ is attributed to magma mixing and fractional crystallization of a single magma type.

The giant Palaeoproterozoic manganese deposits of the Kalahari manganese field (KMF), Northern Cape Province, South Mrica, have been a world renowned resource of manganese ore for many decades. In recent years, the mineralogical composition, geochemistry and genesis of these deposits have been the objects of many geological investigations, yet their origin remains contentious up to the present day. A characteristic feature of the Kalahari deposits is the intimate association of manganese ore and iron-formation of the Superior-type, in the form of three discrete sedimentary cycles constituting the Hotazel Formation. This striking lithological association is an almost unique feature on a global scale. From that point of view, the present study is effectively the first attempt to shed light on the origin and post-depositional history of the Hotazel succession, using as prime focus the petrographic and geochemical characteristics ofthe host iron-formation. Petrographic and whole-rock geochemical information of iron-formation from the southern parts of the KMF, suggests that the Hotazel iron-formation is almost identical to other iron-formations of the world of similar age and petrological character. The rock exhibits essentially no high-grade metamorphic or low-temperature alteration effects. Mineralogically, it contains abundant chert, magnetite, subordinate amounts of silicate minerals (greenalite, minnesotaite, stilpnomelane) and appreciable concentrations of carbonate constituents in the form of coexisting calcite and ankerite. Such mineralogical composition is indicative of processes occurring in a diagenetic" to burial (up to very low-greenschist facies) metamorphic environment. Bulk-rock geochemical data point towards a simple composition with Si02, total Fe-oxide and CaO being the chief major oxide components. Whole-rock rare-earth element data suggest that the iron-formation precipitated from a water column with chemical signatures comparable to modern, shallow oceanic seawater. The virtual absence of positive Eu anomalies is a feature that compares well with similar data from Neoproterozoic, glaciogenic iron-formations of the Rapitan type, and suggests but only a dilute hydrothermal signal, poten!ially derived from distal submarine volcanic activity. Carbon and oxygen isotope data from iron-formation and Mn-bearing carbonates as well as overlying ferriferous limestone of the Mooidraai Formation, compare well with the literature. The former exhibit variable depletion relative to seawater in terms of both BC and 180, while the latter have signatures comparable to normal marine bicarbonate. Isotopic variations appear to be related to fluctuations in the amount of co-precipitated marine carbonate, in conjunction with processes of coupled organic matter oxidation - FelMn reduction in the diagenetic environment. Oxygen isotope data from quartz-magnetite-calcite triplets suggest that crystallisation took place under open-system conditions, with magnetite being the most susceptible phase in terms of fluid-rock isotopic exchange. Data also suggest that the calcite-magnetite pair may constitute a more reliable geothermometer than the quartz-magnetite one, mainly due to the interlinked diagenetic histories between calcite and magnetite. Iron-formation from the northern parts of the KMF can by categorised into three main classes, namely pristine, altered and oxidised. Pristine iron-formation is identical to the one seen in the southernmost parts of the field. Altered iron-formation corresponds to a carbonate-free derivative of intense oxidation and leaching processes at the expense ofpristine iron-formation, and contains almost exclusively binary quartz-hematite mixtures. The rock appears to have lost essentially its entire pre-existing carbonate-related components (i.e., Ca, Mg, Sr, most Mn and Ba) and displays residual enrichments in elements such as Cr, Th, V, Ni and Pb, which would have behaved as immobile constituents during low-temperature alteration. The low temperature origin of altered iron-formation is supported by oxygen isotope data from quartz-hematite pairs which indicate that isotopically light hematite would have derived from oxidation of magneftte and other ferroussilicate compounds in the presence of a low-temperature meteoric fluid, while quartz would have remained isotopically unchanged. Occasional occurrences of acmite-hematite assemblages suggest localised metasomatic processes related to the action ofNaCI-rich fluids at the expense of altered iron-formation. The conditions of acmite genesis are very poorly constrained due to the very broad stability limits of the mineral in environments ranging from magmatic to surface-related. Oxidised iron-formation constitutes a distinct rock-type and shares common attributes with both the pristine and the altered iron-formation. The rock contains hematite as an important constituent while the amount of magnetite is substantially reduced. With regard to carbonate nlinerals, calcite contents are clearly very low or absent, having being replaced in most instances by a single, Mgenriched, dolomite/ankerite:type species. Oxidised iron-formation contains somewhat higher amounts of iron and reduced amounts of Sr and Ba relative to pristine iron-formation, whereas enrichments in elements such as Ni, Th, Pb, Cr, and V are seen, similar to altered iron-formation. Oxidised iron-formation appears to have originated from processes of dissolution-mobilisationreprecipitation of solutes derived primarily from leaching that produced altered iron-formation. It is proposed that the Hotazel iron-formation and associated manganese deposits were formed as a result of episodic sea-level fluctuations in a stratified depositional environment that gradually evolved into a shallow carbonate platform. A critical parameter in the development of manganese sediment may include regional climatic patterns related to a glacial event (Makganyene diamictite) prior to deposition of the Hotazel strata. This suggestion draws parallels with processes that are believed to have led to the formation of worldwide iron-formations and associated manganese deposits subsequent to Neoproterozoic episodes of glaciation. Submarine volcanism related to the underlying Ongeluk lavas appears to have had very little (if any) metallogenic significance, while evidence for a sudden rise in the oxygen contents of the atmosphere and ambient waters is lacking. With regard to later alteration processes, combination of geological and geochemical data point towards the potential influence of surface weathering prior to deposition of rocks of the unconformably overlying Olifantshoek Supergroup, possibly coupled with fault- and/or thrustcontrolled fluid-flow and leaching of the Hotazel succession during post-Olifantshoek times.

The Msikaba Formation is a Late Devonian fluvial and marine succession which outcrops from Hibberdene to Port Edward along the south coast of KwaZulu-Natal Province, South Africa. The Formation is composed of brownish conglomerate at the bottom and white-greyish quartz arenite sequence in the middle and mixed quartz-arenite with feldspathic sandstone in the upper sequence. Previous studies put more emphasis on the correlation of Msikaba Formation with the Natal Group and Cape Supergroup, whereas this study revised the stratigraphy, and also put new insight on the petrography, sedimentary facies, depositional environments and diagenesis of the Formation. The total stratigraphic section attains a thickness of 184 m at Margate area and 186 m at Port Edward area. The stratigraphy of Msikaba Formation is well exposed on the outcrops along the KwaZulu-Natal coastline. The stratigraphy is subdivided into 4 new members along Margate to Shelly beach section; namely Manaba Member, Uvongo Member, Mhlangeni Member and Shelly Beach Member from bottom upward. Twelve sedimentary facies were identified and the sedimentary facies were integrated into 4 facies association: Facies association 1 (Gmm+Sm) represents braided fluvial deposits, Facies association 2 (Gcm+St+Sp+Sl+Shb) represents tidal channel and tidal flat deposit, Facies association 3 (St+Sp+Sr+Sl) is result of shallow marine deposit and Facies association 4 (Sp+Sl+St+Sm) is a mixed marine and fluvial deposit. Each facies association represents a specific stratigraphic unit and were deposited in a specific sedimentary environment. Grain size analysis was conducted on seventeen thin sections and 500 grains were counted from each thin section. The sandstone grain size parameters of mean, sorting, skewness and kurtosis fell under the average of 0.75, 0.78, 0.4 and 1.2φ respectively. The results show that most of the grain size are coarse to medium grained throughout the study areas and sorting of the sandstones are moderate to poorly sorted. The cumulative frequency diagrams and bivariate plots show positive skewness and negative kurtosis, which indicate a high hydrodynamic environment. Modal composition analysis and petrography studies show that detrital components of the Msikaba Formation are dominated by monocrystalline quartz, feldspar (mostly K-feldspar) and lithic fragments of igneous and metamorphic rocks. The sandstones could be classified as quartz arenite, sub-arkosic sandstone and feldspathic litharenite; and the provenance analysis indicates that the sandstones were derived from craton interior, recycled or quartzose recycled sources which may derived from weathering and erosion of igneous and metamorphic rocks. Diagenetic processes of the Msikaba Formation have been passed through early, mid- and late diagenetic stages. Cementation, mineral conversion and compaction affect early diagenetic stage; authigenic minerals, quartz and feldspar overgrowth are presented in mid-diagenetic stage, whereas recrystallization, replacement, deformation and dissolution have been strongly affected late diagenetic stage. Microscopy, XRD and SEM-EDX studies have identified five types of cements including smectite clay, kaolinite, hematite, quartz and feldspar cements. Quartz cement, pore-filling and pore-lining clay are the major type of cements in the Msikaba Formation. Based on the lithology, sedimentary structure and facies variations, the Manaba Member was most probably deposited in a braided fluvial environment, the Uvongo Member was deposited in a tidal channel environment, the Mhlangeni Member was formed in shallow marine storm-influenced environment, whereas the Shelly Beach Member was represented mixed marine and fluvial environment. The sequence stratigraphy of Msikaba Formation constitutes a transgressive sequence from Manaba Member to Uvongo Member, whereas it ended as a regressive sequence from Mhlangeni Member to Shelly beach Member. The Msikaba Formation shows major differences with the Natal Group and Table Mountain Group (Cape Supergroup) in the lithology, stratigraphic sequence, sedimentary structures, facies system, palaeocurrent styles, fossil contents and depositional environments, which demonstrate that they are not the equivalent stratigraphic unit. Therefore, the Msikaba Formation is a separate, younger stratigraphic unit, and cannot correlate with the Natal Group and Table Mountain Group as suggested by previous researchers.

A number of outcrops of the Witteberg Group and lowermost Karoo Supergroup rocks were studied in the area south of the Darlington Dam, Jansenville District, with the aim of documenting structural characteristics of the area. All lithologies are folded with fold styles varying from gentle to near isoclinal (based on interlimb angle). Fold axes are either sub-horizontal or plunging at gentle to moderate angles whereas axial planes dip gently to vertically (predominantly steep to sub-vertical). Folds verge predominantly towards the north but where southward verging they are associated with faulting or strongly folded areas. Folds plunge gently to the east-southeast and west-northwest. The area consists of a large anticlinorium with both first and second order folds occurring. Eastwest striking faults occur in the study area and are classified as normal, reverse and thrust faults. A study of the joint sets shows that there are four dominant joint directions, namely 18o, 33o, 97o and 107o (in order from least to most important). An interpretation of the tectonic history is presented in which the relationships between faults and folds show that faults formed during and after folding. Folding, and reverse and thrust faulting, occurred during the compressional events that formed the Cape Fold Belt, whereas the normal faults formed during the relaxation of these compressional forces or during the break-up of Gondwana.

Scheelite, wolfram Ite and cassIterIte mIneralizat ion is hosted wIthin numerous quartz-tourmaline-feldspar-fluorite veins at Van Rooi's Vley, N.W. Cape Province . MineralizatIon and hydrothermal alteration within, and around, these veins is hIghly complex and reflects the intricate interaction of hydrotherma l activity upon a structurally deformed sequence of ProterozoIc med ium to high-grade gneisses. Four distinct stages of alteration and mineralization occurred, including a l ate 'epithermal stage'. Although the location of mineralization was strongly controlled by st ructure, the concentration of mineralizati on was controlled by physicochemical variables, of which host-rock geochemistry was particularly important . Further W/Sn mineralization occurs on a local scale, some of which is spatia lly related to minor leucogranite dykes. Leucogranite bodies are not uncommon within the region and some are enriched in Wand Sn. By comparing FIB ra tio s,W/Sn ratios, the alteration mineralogy, the ore mineralogy and the Fe-content of tourmaline, the deposits within the Van Rooi's Vley area can be placed into a 'proximal' to 'distal' classification, with respect to a common source of mineralizing hydrothermal fluids. The Van Rooi's Vley deposit, whilst affiliated to greisen-style deposits, represents a ' distal' quartz-vein lode deposit.
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The study area is located between Loskop Dam and the town of Groblersdal, on the southeastern flank of the Dennilton dome, and is underlain by lithologies of the Pretoria Group, Bushveld Complex mafics and ultramafics and acid lavas that resort under the Rooiberg felsites. Field work comprised of geological mapping, soil-, hard-rock- and stream sediment geochemistry, various geophysical techniques and diamond drilling. The rocktypes that resembles the Rustenburg Layered Suite on the farm Rietfontein 70JS is subdivided into a Mixed Zone, Critical Zone and Main Zone, on grounds of geochemical and certain geophysical attributes. The Mixed Zone that overlies the Bushveld Complex floor-rocks, is furthermore separated into an i) Lower-, ii) Middle- and, iii) Upper Unit. The Lower Unit of the Mixed Zone consists primarily of magnetite-gabbros, iron-rich pegmatites, harzburgites and feldspathic pyroxenites. The Fe-rich constituents of this stratigraphic horizon generates a pronounced magnetic anomaly within the study area. On the basis of; amongst other parameters, Zr/Rb and Sr/Al₂0₃ ratios, the magnetite-gabbros are postulated to conform to lithotypes in the vicinity of magnetite layers 8 to 14 of Upper Zone Subzone B in a normal Bushveld Complex stratigraphical scenario. Similarly, it is argued that the feldspathic pyroxenites and norites that display elevated chromium values are analogues to normal Critical Zone rocktypes of the Rustenburg Layered Snite. A more elaborate and precise stratigraphic correlation for the Critical zone was, however, not possible. It is advocated that a volume imbalance was created by the hot, ascending mafic magmas of the intruding Bushveld Complex, resulting in the updoming of certain prevailing basement features such as the Dennilton Dome. In addition to this ideology, it is proposed that the Mineral Range Fragment is in fact a large xenolith underlain by mafics, after being detached from the Dennilton Dome during the intrusion event. Evidence generated by this study unequivocally indicate that the potential for viable PGE's, Ni, Cu and Au within a Merensky Reef- type configuration or a Plat Reef-type scenario under a relatively thin veneer of acid Bushveld Complex roof-rocks on the eastern flank of the Dennilton Dome, appears feasible.

The Atlantic Seaboard is an 18 km stretch of coastline located on the Cape Peninsula, South Africa, roughly between the Cape Town suburbs of Mouille Point in the north and Hout Bay in the south. It borders heavy shipping traffic and contains a mix of urban and natural environments including up-market seaside neighbourhoods and is part of the Table Mountain National Park. The predominantly rocky coastline has a northeast–southwest orientation with interspersed sandy pocket beaches. A narrow, low-lying coastal plain (marine terrace) in the north merges with coastal cliffs further south. The geomorphology and sedimentology of the coast are closely linked to the underlying geology, influencing the shape of coastal embayments and promontories, as well as the composition and distribution of sediment. Hydrographic, geophysical and sedimentological techniques were used to collect high-resolution bathymetry, seafloor geology and sediment distribution data to better understand modern coastal processes. The results indicate a low-relief seafloor consisting of Malmesbury Group rocks in the north. To the south the seafloor consists of high-relief Cape Granite reefs interspersed with fine to medium grain sand and bioclastic (shelly) gravel. Sediment transport is generally northward by longshore drift. In the south, the high-relief granite reef and headlands form sediment traps resulting in several large pocket beaches and offshore sediment deposits. In the north, the low-relief Malmesbury bedrock is largely free of sediment, except within narrow erosional gullies. Most sediment rapidly passes through to the north resulting in a sediment-starved rocky seafloor. The three principal sources of beach sand are aeolian fine sand transported by the Karbonkelberg headlands bypass dune entering the sea at Sandy Bay, biogenic carbonate production along the coast, and weathering of Table Mountain Group sandstone and granite bedrock. A fourth source is sediment entering the system via longshore drift from the south of Duiker Point. The water depth around the Duiker Point headland is presently too deep for sediment to be transported easily through longshore drift, other than during large storm events, but during past sea-level low stands this would have played an important part in supplying sediment to the coast. Changes in sea level play an important part in shaping the geomorphology of the coastline. Beach deposits, both sandy and boulder beaches have been left at various elevations along the coast, both offshore and onshore. Although today the Sea Point area is protected by sea walls and man-made structures, a higher sea level was responsible for shaping the narrow coastal plain. Increasing rates of global sea-level change are becoming an important issue all over the world and the Atlantic Seaboard coast is not immune to the effects of sea-level rise. The frequency and magnitude of storm events that breach the sea defences erode beaches and sea cliffs and cause damage to private and public property are likely to increase in the future

The 2.9 Ga old Usushwana Complex in the Piet Retief-Amsterdam area (south-eastern Transvaal) represents an exposed segment of a layered intrusion. It has the form of a dyke-like body elongated in a northwesterly direction, and extends to an estimated depth of 3000 -5500 m. Lithologically, the Complex consists of a cumulate succession of mafic rocks capped by granitoids and has intruded along the contact between the basement and the supracrustal sequences of the Kaapvaal Craton. Differentiation of an already contaminated gabbroic magma resulted in an ordered stratigraphic sequence comprising progressively more evolved lithotypes, with at least two imperfect cyclic units developed over a stratigraphic thickness of about 700 metres (Hlelo River Section). Meso- to orthocumulate textured gabbros and quartz gabbros grade upwards into magnetite- and apatite-bearing quartz gabbros, interlayered with discontinuous magnetitite horizons. The gabbros in turn grade into hornblende-rich, granophyric granodiorites. The differentiation process is regarded as having been considerably enhanced by the assimilation of acidic material, derived by partial melting of the felsic country rocks at the roof of the magma chamber. Recrystallisation of these rocks gave rise to the microgranites that locally overlie the granodiorites. Mineralogical, textural and geochemical features indicate a relatively advanced fractionation stage, suggesting that the exposed sequence of the Usushwana Complex in the study area represents the upper portion of the intrusion. No significant mineralised occurrences were identified. However, on the basis of similarities between the Usushwana Complex and other mafic layered intrusions which host significant ore deposits, it is suggested that economic concentrations of base metal(Cu-Ni) sulphides, PGE and chromitites are likely to be developed at lower stratigraphic levels.

Bibliography: pages 295-307.
The exposures in diamond mines on the Namaqualand west coast of South Africa provide a rare opportunity to examine a record that is normally inaccessible beneath a thick cover of aeolian sands. This study presents the main results of fieldwork in mine excavations on the farms Hondeklip and Avontuur-A, near Hondeklip Bay. Sections in the deposits were described in detail and the vertebrate and invertebrate faunas were sampled. The buried topography of the gneiss bedrock, obtained by prospecting, is complex, with the main feature consisting of a coast-parallel ridge flanking a wide palaeochannel on its landward side. Advanced kaolinitic weathering affected both the bedrock and a diamondiferous, basal kaolinitic sediment patchily preserved in the channel. The incision of the channel is related to the Oligocene regression and the basal kaolinitic sediment is interpreted as a fluvial arkose deposited in the channel. Both the bedrock and the deposit in the channel were then kaolinized during humid climatic conditions in the late Oligocene and early Miocene. Weathering-profile silcrete also developed in the basal kaolinitic sediment. It is tentatively proposed that this weathering period may be represented in the Namib Desert by the thick laterite capping Eocene sediments at Kakaoberg. Subsequently, the palaeochannel was exhumed and was ultimately filled by late Tertiary marine deposits. The marine deposits were laid down in shallowing-upwards sequences of the shore face environment. Two regressive, progradational packages (alloformations) are recognized. The older extends seawards from at least -50 m asl. and is the "45-50 m Complex" of Carrington and Kensley (1969), now called the 50 m Package. East of the channel, on the exposed coast, high-wave-energy storm-deposition in the lower shoreface dominates the preserved record. With lowering of sea-level, the bedrock ridge emerged to the seaward of the prograding palaeoshoreline, reduced the level of incident wave energy and profoundly influenced the development of sub-environments within the progradational regime. Ultimately, low-energy bay deposits filled the palaeochannel in the bedrock. On the basis of vertebrate evidence and correlation with global sea-level trends, the age of the 50 m Package is middle Pliocene. The upper facies of the 50 m Package (foreshore and upper shoreface) have been extensively removed by later subaerial erosion. The subsequent transgression truncated the seaward extent of the 50 m Package, reached ~30 m asl. and prograded seaward from that elevation. It is called the 30 m Package and combines the "29-34 m Beach" and "17-21 m Complex" of Carrington and Kensley (1969). A late Pliocene age is envisaged. The upper-shoreface facies of the 30 m Package is usually preserved, but may be disguised by pedogenesis. The diamondiferous marine gravels mined in the area are mainly lower-shoreface storm deposits and pre-existing transgressive lags and shelf deposits have generally been reworked during regression. Enigmatic, muddy and/or phosphatic units, previously called "E-stage," are patchily preserved in the base of the 50 m Package and are revealed to be distal storm deposits laid down in the transitional shoreface to offshore environment. They are part of the overlying regressive sequence, but may include a fragmentary , petrified, mixed, vertebrate remanie. Nevertheless, eroded remnants of older deposits must also occur in places.

This thesis examines the geology of the Daspoort Formation (Pretoria Group, Transvaal Supergroup) of South Africa, with the accent on describing and interpreting its sedimentology. The Palaeoproterozoic Daspoort Formation (c. 2.1‐2.2 Ga) forms part of the Pretoria Group on the Kaapvaal craton. This sandstone‐ and quartzite‐dominated lithological formation covers an elliptical geographical area stretching from the Botswana border in the west to the Drakensberg escarpment in the east, with its northern limit in the Mokopane (Potgietersrus) area and Pretoria in the south; altered outliers are also found in the overturned units of the Vredefort dome in the Potchefstroom area. Deposition of the Daspoort Formation was in a postulated intracratonic basin which applies equally to the entire Transvaal Supergroup succession in the Transvaal depository. Various characteristics from the formation, such as sedimentary architectural elements (e.g., channel–fills etc.), maturity trends and distribution of lithofacies assemblages across the preserved basin give insight into the developing conditions during deposition and genesis of the Daspoort Formation. Subordinate evidence from basic geochemistry, ripple mark data and optical microscope petrology studies support the sedimentary setting inferred for this Palaeoproterozoic deposit. Fluvial and epeiric marine conditions prevailed during the deposition of the Daspoort clastic sediments into the intracratonic basin. This shallow epeiric sea was fed by fluvial influx, predominantly from the west when a transgressive regional systems tract led to the filling of the basin, evolving into the deeper marine Silverton Formation setting, laid down above the Daspoort. Transgression from the east (marine facies predominate) to the west (fluvial facies) is supported by cyclical trends, palaeoenvironmental and palaeogeographical interpretations. Accompanying poorly preserved microbial mat features contribute to the postulated shallow marine environment envisaged for the eastern part of the basin whereas ripple marks and grain size distribution support a fluvial setting for the west, with lithofacies assemblages accounting for both areas’ depositional interpretation.
Dissertation (MSc)--University of Pretoria, 2013.
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Geology
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Modern analysis of Table Mountain Group sediments began with I. C. Rust's D.Sc. thesis "On the sedimentation of the Table Mountain Group in the western Cape Province" in 1967. Rust defined the stratigraphy of the Table Mountain Group, produced computer generated isopach and palaeocurrent maps for each formation and attempted palaeoenvironmental analyses based on what data he had available. For work dated prior to 1967 the reader is directed to Rust's excellent review in Chapter 2 of his thesis. The thesis served as a basis for Rust's later published work on the Cape Supergroup. Current published palaeoenvironmental models of the lower Table Mountain Group (the Piekenierskloof, Graafwater and Peninsula Formations) are based on a transgressive fluvial - littoral - shallow shelf model (Tankard et al., 1982) following earlier facies and palaeoenvironmental analyses (Tankard and Hobday, 1977: Rust, 1977; Hobday and Tankard, 1978: Vos and Tankard, 1981). The validity of this model has recently been questioned (Turner, 1986; 1987) although no comprehensive alternative has been proposed to date. The sedimentology of the upper Table Mountain Group i.e. the Pakhuis, Cedarberg, Rietvlei, Skurweberg and Goudini Formations (the latter three the newly named Nardouw Subgroup) has not been studied systematically. Good progress has recently been made on the fossil content of the Cedarberg Formation (Gray et al., 1986; Cocks and Fortey, 1986) and palaeoenvironmental analyses initiated in the Nardouw Formation. This thesis documents contributions to the geology of the Table Mountain Group. It is not the intention of the author to present an extensive overview and treatise on the lower Table Mountain Group, but rather to concentrate on three topics that can provide some insight into Table Mountain Group geology. The following three topics were selected 1) Petrology and Diagenesis of lower Palaeozoic sandstones in the s.w. Cape Sandveldt (Clanwilliam and Piketberg Discricts). 2) Palaeoenvironmental indicators in the Faroo Member, (Graafwater Formation) at Carstensberg Pass, R364. 3) Facies analysis of conglomerates and sandstones in the Piekenierskloof Formation: Processes and implications for pre-Devonian braid-plain sedimentology. These topics form the basis of the thesis.

Thesis (MSc) -- Stellenbosch University , 1995.
ENGLISH ABSTRACT: A number of small greenstone bodies of the Bridgetown Formation are exposed as elongated lenses and dykes within metasediments of the Malmesbury Group in the Western Cape Province, South Africa. The Malmesbury Group is part of the Neoproterozoic to Cambrian (Namibian) Saldania Subprovince which is the southern continuation of a Pan-African mobile belt system. A detailed geological and geochemical study was conducted on the largest outcrop of the Bridgetown Formation, situated 20km east of the town Moorreesburg. The Bridgetown Formation consists of a meta-volcano-sedimentary sequence that experienced polyphase deformation and metamorphism up to the lower greenschist facies. Tectonically, the Bridgetown Formation is included in the Boland tectonic domain, east of the Piketberg-Wel lington fault zone that is suggested to run Skm west of Heuningberg and subparallel to the Berg River. This agrees with Rabie's (1974) original subdivision of the tectonic domains. The Bridgetown Formation consists of: i) A basal unit of poorly differentiated alkaline metabasalt with a within-plate tectonomagmatic fingerprint. ii) An intermediate unit of poorly differentiated tholeiitic metabasalt, intruded by a younger tholeiitic metabasite with a low degree of differentiation. Both members of the intermediate unit have ocean-floor basalt (P-type MORB) and island arc basalt fingerprints. iii) An upper unit of poorly differentiated as well as more evolved alkaline metabasalts, interlayered with metatuff with an alkaline basaltic composition, metasedimentary rocks with a marine origin, and graphitic schists and muscovitequartz schists, both with a continental crust provenance. iv) An overlying metasedimentary sequence including dolomite, massive and oolitic chert, jasper and jaspilite. The Bridgetown Formation probably also comprises a lower metamorphosed ultramafic unit, indicated by the association of Ni- and Cr-rich talc bodies, Ni-and errich banded chert, chlorite schist and small dolomite-talc-chlorite bodies at Spitskop, situated directly northwest of the main greenstone body. The sequence of eruptive stages and the geochemistry of the metavolcanics resemble Hawaiian volcanism , indicated by an initial deep water stage of alkaline magmatism, followed by main tholeiitic edifice and post-caldera alkaline magmatism. Post-caldera alkaline magmatism occurred contemporaneously with deposition . of sediments and chemical precipitates (carbonates and cherts). The Bridgetown metavolcanics have no magmatic association with either the Bloubergstrand volcanics or mafic and intermediate plutonic rocks in the Malmesbury Group. However, some physical and geochemical similarities exist between the Bridgetown Formation and the age related Grootderm Formation of the Marmora Terrane (Gariep Supergroup) which is considered to represent ophiolitic material. The Bridgetown Formation probably represents segments of oceanic crust, including seamounts of oceanic islands, which were tectonically emplaced in an accretionary prism zone during subduction of oceanic crust underneath the Kalahari Craton, 600 to 700 Ma ago. This resulted in the present spatial configuration of various small greenstone bodies in the Malmesbury Group. To date no exploitable mineral deposits have been found 1n the Bridgetown Formation. However, Au and As anomalies in stream sediment and soil samples, taken in the Spitskop area, require further attention. lt is suggested that the gold and arsenic is hosted in brittle deformed clear to milky quartz veins which developed at zones of competency contrasts in all the li tholog ies in the Spitskop area.
AFRIKAANSE OPSOMMING: 'n Aantal klein groenskisliggame van die Bridgetown Formasie is blootgestel as verlengde lense en gange binne metasedimente van die Malmesbury Groep in die Wes-Kaap Provinsie, Suid-Afrika. Die Malmesbury Groep is deel van die Neoproterozo·iese tot Kambriese (Namibiese) Saldania Subprovinsie wat die suidelike voortsetting is van 'n Pan-Afrikaanse mobiele gordel sisteem. 'n Gedetaileerde geologiese en geochemiese studie is gedoen op die grootste dagsoom van die Bridgetown Formasie, gelee 20km oos van die dorp Moorreesburg. Die Bridgetown Formasie bestaan uit 'n metavulkanies-sedimentere opeenvolging wat pol ifase vervorming en metamorfisme tot en met die laer groenskis fasies ondergaan het. Die Bridgetown Formasie word hier in die Boland tektoniese domein ingedeel deur die Piketberg-Wellington verskuiwingsone 5km wes van Heuningberg, subparallel a an die Bergrivier, te plaas. Dit stem ooreen met Rabie ( 197 4) se oorspronkl ike verdeling van die tektoniese domeine. Die Bridgetown Formasie bestaan uit: i) 'n Basale eenheid wat hoofsaaklik bestaan uit min gedifferens ieerde alkali-metabasalte met binneplaat tektonomagmatiese eienskappe. ii) 'n lntermediere eenheid wat bestaan uit min gedifferensieerde tholeiitiese metabasalt en 'n jonger intrusiewe tholeiitiese metabasiet wat 'n lae graad van differensias ie ondergaan het. Beide intermediere eenhede het oseaanvloer-basalt (P-t ipe MORB) en eilandboog basaltiese eienskappe. iii) 'n Boonste eenheid wat bestaan uit min gedifferensieerde asook meer gedifferensieerde alkal i-metabasalte, tussengelaagd met metatuf met 'n alka libasaltiese samestelling; metasedimentere gesteentes met 'n mariene oorsprong, en grafitiese ski ste en kwarts-muskoviet skiste, beide met 'n kontinentale kors oorsprong . iv) 'n Oorliggende metasedimentere opeenvolging wat dolomiet, massiewe en ooli tiese chert, jaspis en jaspiliet insluit. Die Bridgetown Formasie slu it moontlik ook 'n onderliggende gemetamorfiseerde ultramafiese eenheid in; aangedui deur die assosiasie van Ni- en Cr-ryke ta lkl iggame, Ni- en Cr-ryke gebande chert, chlorietskis en klein dolomiet-talk-chloriet liggame by Spitskop, gelee direk noordwes van die hoof groensteenliggaam. Die opeenvolg ing van magmatisme en die geochemie van die metavulkaniese gesteentes stem ooreen met Hawaiiese vulkanisme, naamlik 'n diepwater stadium, gekarakteriseer deur alkaliese magmatisme, gevolg deur 'n hoof tholeiitiese opbouing en post-kaldera alkaliese magmatisme. Die post-kaldera alkaliese magmatisme het gelyktydig plaasgevind met afsetting van sedimente en chemiese presipitate (karbonate en cherte ). Die Bridgetown metavulkaniese gesteentes het geen magmatiese assosiasie met 6f die Bloubergstrand vulkaniese gesteentes 6f mafiese en intermediere plutoniese gesteentes in die Malmesbury Groep nie. Fisiese en geochemiese ooreenkomste bestaan egter tussen die Bridgetown Formasie en die Grootderm Formasie van die Marmora Terrein (Gariep Supergroep) wat beskou word as ofiolitiese materiaal. Die Bridgetown Formasie verteenwoordig moontlik segmente van oseaankors, insluitende oseaan-eilande, wat tektonies in 'n melange sone ingeplaas is tydens subduksie van oseaankors onder die Kalahari Kraton in (600 tot 700 Mj gelede). Dit verklaar die huidige ruimte like verspreiding van verske ie klein groensteenliggame in die Malmesbury Groep. Tot en met hede is geen ontginbare mineraalafsettings in die Bridgetown Formasie ontdek nie. Au en As anomalie in stroomsediment- en grondmonsters, geneem in die Spitskop area, behoort egter verdere aandag te geniet. Daar is voorgestel dat die goud en arseen voorkom in brosvervormde helder tot melkerige kwartsare wat ontwikkel het in swak sones in al die litologie in die Spitskop area.

Nodules within the lower Bokkeveld shales often contain well-preserved invertebrate fossil material. The aim of this study was to describe some characteristics seen at various scales (macro-, micro- and ultra -) within nodules that might contribute to an understanding of aspects of nodule formation and the reasons for the excellent preservation of the fossil material within these nodules. Detailed, high quality macro-photographs were taken of sliced and whole nodule surfaces and a catalogue was produced to tentatively identify fossils present and illustrate the variations seen within nodules. Selected nodules were then subjected to petrographic, ultra-structural (SEM) and some chemical (EDS, XRD & XRF) analysis to investigate the possible reasons for these variations. The chemical results have indicated that nodules are enriched with quartz compared to the surrounding shale. Quartz is also the dominant mineral replacing trilobite carapace material within nodules, while trilobite material within shales is replaced with equal proportions of hematite, biotite and quartz. It appears that the higher resistance of quartz to weathering is the dominant factor leading to the preservation of both nodules within the shales and trilobite material within the nodules examined. A comparison with some Western Cape nodules highlighted possible variations in overall nodule chemical composition along strike. Western Cape nodules are predominantly composed of apatite whereas the Cockscomb nodules are mainly composed of quartz. This quartz-apatite compositional variation in nodules occurring within a single formation has been reported from nodules found in the Armorican Massif of France which are very similar in a number of respects to the Bokkeveld nodules described in this study. Based on various features of the fossils present and the structure of nodules they were probably formed during early diagenesis within an epeiric marine deposit greatly affected by sea level fluctuations.

Thesis (MSc)--University of Stellenbosch, 2006.
ENGLISH ABSTRACT: The Barremian to Albian siliciclastic deep-water deposits of the central Bredasdorp Basin were investigated primarily in terms of their stratigraphic evolution, depositional characteristics and facies distribution. Cores from the deep-water deposits reveal that the facies successions are composed of massive, ripple cross- to parallel-laminated sandstones, conglomerate, massive claystone, alternating laminated to interbedded sandstone/siltstone and claystone, laminated and clay-rich siltstone. These facies are grouped into channel-fill, sheet-lobe, overbank and basin plain deposits, by inference. The application of sequence stratigraphy, based on gamma ray and resistivity log patterns, reveals that all 3rd-order depositional sequences comprise 4thorder cycles. The latter are subdivided into three components (lowstand, transgressive and highstand systems tracts), based on vertical facies changes and internal stratigraphic key surfaces. Taking the 13Amfs as the stratigraphic datum for each well, correlation was possible on a regional basis. Lowstand deposits, comprising thick amalgamated massive sandstones, were interpreted to represent channelfills. Their vertical and horizontal stacking forms channel-fill complexes above Type 1 unconformities. Adjacent thin-bedded intervals, comprising parallel- to ripple cross-laminated sandstones, were interpreted as levee/overbank deposits, whereas clay-rich intervals were interpreted to represent basin plain deposits of hemipelagic origin. Facies associations and their distribution have revealed that channel-fills are associated with overflow deposits and sheet sand units. These deposits, as well as downdip sheet sands associated with small channel-fills within the 9A, 11A/12A, 13A Sequences and the 14A Sequence were interpreted to have been deposited in a middle fan to upper fan setting. A similar association occurs in the 10A Sequence, except that thick conglomerate units are present at the base of proximal channel-fills. This led to interpret the 10A Sequence as being deposited in a base-of-slope to upper fan setting. The thickness of each sequence, as revealed by isochore maps, shows sinuous axial flow path which corresponds to channel-fill conduit. The continuous decrease of this sinuosity upward in the succession was interpreted as being related to basin floor control along the main sand fairways. Successive flows result in erosion-fill-spill processes, which locally favour connectivity of reservoirs over large areas. Recognition of higher-order sequences and key stratigraphic surfaces helps to understand internal stratigraphic relationships and reveals a complex and dynamic depositional history for 3rd-order sequences. However, sparse well control and uneven distribution of boreholes, as well as lack of seismic and other data, limited the models derived for this study.
AFRIKAANSE OPSOMMING: Die Barremiaanse tot Albiaanse silisiklastiese diepwater afsettings van die sentrale Bredasdorp Kom is hoofsaaklik in terme van stratigrafiese evolusie, afsettingskarakteristieke en fasies distribusie ondersoek. Kerne van die diepwater afsettings toon dat die fasies opeenvolgings uit massiewe, riffelkruis- tot parallel-gelamineerde sandstene, konglomerate, massiewe kleistene, afwisselende gelamineerde tot intergelaagde sandstene/slikstene en kleistene, sowel as gelamineerde en klei-ryke slikstene bestaan. Hierdie fasies word onderverdeel in kanaalopvulsel, plaatlob, oewerwal en komvlakte afsettings. Die toepassing van opeenvolgingsstratigrafie gebaseer op gammastraal en resistiwiteit log patrone toon dat alle 3de-orde afsettingsopeenvolgings uit 4deorde siklusse bestaan. Laasgenoemde word onderverdeel in drie komponente (lae-stand, transgressie en hoë-stand sisteemgedeeltes), gebaseer op vertikale fasies veranderinge en interne stratigrafiese sleutel vlakke. Korrelasie op ‘n regionale basis is moontlik gemaak deur die 13Amfs as die stratigrafiese verwysing vir elke boorgat te neem. Lae-stand afsettings, wat uit dik saamgevoegde massiewe sandstene bestaan, word geïnterpreteer as kanaalopvulsels. Die vertikale en horisontale stapeling van die sandstene vorm kanaalopvulsel komplekse bo Tipe 1 diskordansies. Naasliggende dungelaagde intervalle, wat uit parallel- tot kruisgelaagde sandstene bestaan, word geïnterpreteer as oewerwal afsettings, terwyl klei-ryke intervalle geïnterpreteer word as verteenwoordigend van komvlakte afsettings van hemipelagiese oorsprong. Fasies assosiasies en hul verspreiding toon dat kanaalvul geassosieër word met oorvloei afsettings en plaatsand eenhede. Hierdie afsettings, sowel as distale plaatsande geassosieër met klein kanaalopvulsels binne die 9A, 11A/12A, 13A en die 14A Opeenvolgings, word geïnterpreteer as afgeset in ‘n middelwaaier tot bo-waaier omgewing. ‘n Soortgelyke assosiasie bestaan in die 10A Opeenvolging, behalwe dat dik konglomeraat eenhede teenwoordig is by die basis van proksimale kanaalopvullings. Dit het gelei tot die interpretasie van die 10A Opeenvolging as afgeset in ‘n basis-van-helling tot bo-waaier omgewing. Die dikte van elke opeenvolging, soos verkry vanaf isochoor kaarte, toon ‘n kronkelende aksiale vloeipad wat ooreenkom met ‘n kanaalopvulling toevoerkanaal. Die aaneenlopende afname van hierdie kronkeling na bo in die opeenvolging word geïnterpreteer as verwant aan komvloer-beheer langs die hoof sand roetes. Opeenvolgende vloeie veroorsaak erosie-opvul-oorspoel prosesse, wat lokaal die konnektiwiteit van reservoirs oor groot areas bevoordeel. Herkenning van hoër-orde opeenvolgings en sleutel stratigrafiese vlakke dra by tot ‘n goeie begrip van die interne stratigrafiese verhoudings en ontbloot ‘n komplekse en dinamiese afsettingsgeskiedenis vir 3de-orde opeenvolgings. Beperkte boorgatbeheer en ‘n tekort aan seismiese en ander data het egter ‘n beperkende rol gespeel in die daarstel van modelle vir hierdie studie.

This dissertation is based largely on data that was accumulated during the execution of an exploration program by Iscor Ltd in the Northern Transvaal. The program included geological mapping, geophysical surveys and drilling, on Precambrian iron-formations in the Central Zone of the Limpopo Belt. The structure, stratigraphy, metamorphism, and economic importance of the magnetite quartzites and associated lithologies of the Moonlight prospect are discussed. The lithologies underlying the Moonlight prospect area consist of various pink- and grey-banded gneisses and pink granulite, together with a variety of metasedimentary supracrustal rock-types and concordant serpentinite bodies. The gneissic rock-types consist of chlorite-quartz-feldspar gneiss, chlorite-quartz-feldspar augen gneiss, hornblende-quartz-feldspar gneiss, biotite-quartz-feldspar gneiss, felsic and mafic granulite, and foliated amphibolite. The metasedimentary lithologies are represented by calc-silicates and marble, white quartz-feldspar granulite, magnetite quartzite, metaquartzite and garnet-bearing granulite and gneiss (metapelites). The concordant ultramafic bodies consist of serpentinite with lesser amphibolite, dunite, and chromitite. Intrusive pegmatites and diabase dykes are also present in the prospect area. Metamorphism reached granulite-facies, and more than one retrqgrade metamorphic event is recognized . Amphibolite-facies assemblages are present, but it is uncertain whether they represent another retrograde event . Polyphase deformation has produced intense and complex folding , resulting in irregular magnetite quartzite orebodies. The high metamorphic grades have resulted in medium- grained recrystallization of the magnetite-quartzites with a loss of prominent banding often associated with these rock-types . The magnetite quartzite occurs as three seperate but related ore zones, consisting of one or more ore-bands seperated by other lithologies. All three zones form poor outcrops and suboutcrops in a generally flat lying and sand covered area. · Although representing a low-grade iron ore (32% total Fe), the magnetite quartzite deposits at Moonlight are regarded as potentially viable due to the large opencast tonnages available at low stripping ratios, and the relatively cheap and easy beneficiation process needed to produce a magnetite concentrate with 69-70% total Fe.

Thesis (PhD)--Stellenbosch University, 2003.
ENGLISH ABSTRACT: The Swartland region in the western Cape, South Africa, covers approximately 5000 km2 and forms part of the Pan-African Saldania Belt that represents the southernmost extremity of the Pan-African orogenic belts in southern Africa. Regional mapping of the Swartland area shows that lithologies can be classified using predominantly structural and to a lesser extent lithological criteria. This led to the proposal of a new classification, were rocks of the previous classification of the Malmesbury Group are divided into two new groups, namely the Swartland and Malmesbury groups. The Swartland group can be divided into the Berg River and Moorreesburg formations, a series of quartz-chlorite-muscovite-feldspar schists, quartz schists, graphitic schists and limestones; and the Bridgetown formation, a series of metavolcanic rocks with WPB-MORB affinities that possibly represent seafloor. Deposition of the sediments is suggested to have occurred concurrently with deformation in an accretionary prism/fore-arc and was initiated with the opening of the lapetus Ocean at ca. 600 Ma. This early deformation event, Dt (ca. 575 Ma), only affected the Swartland group and exhibits pervasive bedding transposition, thrusting and imbrication of units creating a tectonostratigraphic sequence. Where identified, kinematic indicators and fold vergence indicate a top-to-the-west transport direction during the early, low-angle Di deformation. The Malmesbury group overlies the Swartland group, being locally separated by an unconformity. The Malmesbury group is a succession of conglomerates, grits and shales (Piketberg Formation), grading into greywackes, shales, siltstones, sandstones and minor limestones of the Tygerberg and Porterville formations. Sedimentation probably commenced after ca. 575 Ma and lasted until shortly after 560 Ma. Both the Swartland and Malmesbury groups were then deformed by the deformation event, D2 (ca. 552-545 Ma), and were intruded by the 552 to 510 Ma Cape Granite Suite. The Franschhoek Formation, formally part of the Malmesbury Group is now classified, along with the inferred ca. 535-510 Ma Magrug and Populierbos Formations of the previous Klipheuwel Group. The redefined Klipheuwel group documents a change in depositional environment from the continental slope/ocean trench, marine and flyschoid deposits of the Malmesbury group to continental, fluvial half-graben and graben deposits. Exhumation, extensive erosion and the formation of a peneplain, was followed by the deposition of the Table Mountain Sandstone Group around 550-510 Ma. The Spitskop gold prospect, located 10 km south of Piketberg, represents the first identified occurrence of mesothermal gold mineralisation in the Saldania Belt. Metamorphic devolatilisation of the Swartland group during Di led to the scavenging and transportation of gold along shallow-dipping shear zones that are contained within the early, sub-horizontal So/Si tectonic fabric. Pervasive fluid movement in the Spitskop area led to elevated gold values compared to background values throughout the lithologies at Spitskop. The lack of any economic-grade gold mineralisation is probably related to the absence of suitably orientated structures, such as high-angle faults, that are commonly believed to represent the prerequisite for large fluid throughputs that could result in economic-grade gold deposits. The mineralisation at Spitskop, however, provides a genetic model for further exploration of gold in the Swartland group.
AFRIKAANSE OPSOMMING: Die Swartland streek in die Wes-Kaap, Suid-Afrika, beslaan ongeveer 5000 km2 en vorm deel van die Pan-Afrikaanse Saldania-gordel wat die mees suidelike deel van die Pan-Afrikaanse orogene gordels in suidelike Afrika verteenwoordig. Regionale kartering van die Swartland streek dui aan dat die gesteentes geklassifiseer kan word deur oorwegend strukturele, en tot 'n mindere mate litologiese kriteria te gebruik. Gevolglik word ‘n nuwe klassifikasie voorgestel, waar gesteentes volgens die vorige klassifikasie van die Malmesbury groep verdeel word in twee groepe, naamlik die Swartland en Malmesbury groepe. Die Swartland groep kan verdeel word in die Bergrivier en Moorreesburg formasies, ‘n reeks kwarts-chloriet-muskoviet-veldspaat skis, kwarts skis, grafitiese skis en kalksteen; en die Bridgetown formasie, ‘n reeks metavulkaniese gesteentes met WPB-MORB affiniteite wat moontlik oseaanvloer verteenwoordig. Daar word voorgestel dat afsetting van die sedimente gelyktydig plaasgevind het saam met vervorming in ‘n akkresionere prisma/voorboog, geinisieer deur die opening van die lapetus Oseaan (ca. 600 Ma). Hierdie vroee vervorming, Di (ca. 575 Ma), het slegs die Swartland groep geaffekteer en vertoon deurdringende verplasing van gelaagdheid, oorskuiwing en imbrikasie van eenhede en het ‘n tektonostratigrafiese opeenvolging gevorm. Waar identifiseer, dui kinematiese aanwysers en plooi kanteling op ‘n bokant-na-wes beweging gedurende die vroee, lae hoek Di vervorming. Die Malmesbury groep oordek die Swartland groep, plaaslik geskei deur ‘n diskordansie. The Malmesbury groep bestaan uit ‘n opeenvolging konglomeraat, grintsteen en skalie (Piketberg formasie), wat gradeer in grouwak, skalie, sliksteen, sandsteen en ondergeskikte kalksteen van die Tygerberg en Porterville formasies. Sedimentasie het waarskynlik begin na ca. 575 Ma en het voortgeduur tot kort na 560 Ma. Beide die Swartland en Malmesbury groepe is hierna vervorm deur D2, (ca. 552-545 Ma) en daaropvolgend ingedring deur die 552 tot 510 Ma Kaap Graniet Suite. Die Franschhoek Formasie, voorheen deel van die Malmesbury Groep, word nou geklassifiseer tesame met die afgeleide ca. 535-510 Ma Magrug en Populierbos formasies as deel van die voorheen geklassifiseerde Klipheuwel groep. Die hergedefinieerde Klipheuwel groep dui op 'n verandering in afsettingsomgewing vanaf die kontinentale glooiing/oseaantrog, mariene en flyschoiede afsettings van die Malmesbury groep na kontinentale, fluviale half-graben en graben afsettings. Herblootstelling, omvattende erosie en die vorming van ‘n skiervlakte is gevolg deur die afsetting van die Tafelberg Sandsteen Groep random 520-510 Ma. Die Spitskop goudvoorkoms, 10 km suid van Piketberg, verteenwoordig die eerste identifiseerde voorkoms van mesotermale goudmineralisasie in die Saldania Gordel. Metamorfe ontvlugtiging van die Swartland groep gedurende Dt het aanleiding gegee tot die roofuitruiling en vervoer van goud langs laaghellende skuifskeursones in die vroee, subhorisontale S0/Si tektoniese maaksel. Deurdringende vloeistofbeweging in die Spitskop omgewing het aanleiding gegee tot verhoogde goudwaardes in vergelyking met agtergrond waardes dwarsdeur die litologiee by Spitskop. Die gebrek aan ekonomiese graad goud mineralisasie is waarskynlik verwant aan die afwesigheid van geskikte georienteerde strukture, soos hoe hoek verskuiwings, wat oor die algemeen beskou word as ‘n voorvereiste vir die toevoer van groot hoeveelhede vloeistof wat kon aanleiding gegee het tot ekonomiese graad goudafsettings. Die mineralisasie by Spitskop verskaf egter 'n model vir verdere goud eksplorasie in die Swartland groep.

This work examines the use of gravity data and its application to subsurface water reservoirs in the immediate vicinity of the South African Geodynamic Observatory, Sutherland (SAGOS), situated in a semi-arid region of the Karoo region of South Africa, and underlain by the Karoo sedimentary rocks intruded by dolerite dykes and sills. SAGOS houses the only supergravity metre (SG) in Africa, and this thesis sets out to test its use in monitoring groundwater dynamics using hydrological and gravity data. The main aim of this work is the application of the SG data, in conjunction with hydrological data, to better understand episodic recharge of subsurface reservoirs. The importance of water as a resource, globally and specifically the Karoo, is reviewed in conjunction with supply and demand of water. This is to contextualise the socio-economic, technical as well as policy issues related to water resource management. Applicable technologies for water resource management and efficient water use are highlighted and the application of gravity to hydrology is introduced, including satellite as well as ground based tools. In addition, arid zone hydrology as well as recharge and its mechanisms are analysed in order to better understand these processes when examined from gravity measurements. Issues related to understanding flow within the vadose zone as well as in secondary aquifers are examined, and gravity residuals and subsurface hydrology are highlighted. Thereafter, a conceptual groundwater flow modelof the study area is developed using multiple tools. First, the geology around SAGOS was mapped using SPOT 5 imagery and then ground truthed. Second, stable isotopes and water chemistry analysis was undertaken on water samples from selected boreholes. The results allude to preferential flow acting as the main mechanism for groundwater recharge. Follow-up pump-tests illustrate that fracture connectivity is greatest at close proximity to the dyke. Soil mapping, using aerial photography was also undertaken. Duplex soils, enriched with clay at depth, dominate the study area. Using in-situ infiltration tests, it is shown that the alluvium, which lines the river beds, has a higher hydraulic conductivity than the other soils, confirming that these streams act as preferential conduits for subsurface recharge. Precipitation events were correlated against gravity residuals at 4 wells, over different time periods. The results are examined using time series analyses. Gravity residuals from well SA BK07, over a period of 24 hours after the rainfall event, delineate instances of negative correlations, as well as strong positive correlations (of up to 0.9). On the whole however, correlations between gravity and groundwater at SA BK07 are variable and weak, and in conjunction with water level measurements and water chemistry, the data suggest that this well is located in a dynamic conduit (throughflow) and not in a permanent groundwater reservoir. By contrast, other wells show strong positive correlations between gravity residuals and water levels following episodic recharge events for a later time series. Correlations between the water levels and gravity residuals in wells SA BK04, SA BK05 and SA BK 01 are in excess of 0.7 for specific rainfall events. In summary, the results suggests that gravity is an excellent tool for measuring episodic groundwater recharge within the immediate vicinity of the SAGOS. This implies that gravity can aid in monitoring groundwater losses/gains in arid and semi-arid areas. Recommendations for future work are highlighted at the end; these include the possible use of hydrological modelling of reservoirs at various scales and then comparing these results to the SG as well as GOCE and GRACE satellites data, and then improving numerical modelling of the groundwater dynamics for sites like Sutherland and the surrounding arid Karoo region, where sparse water shortages, and potential pollution related to fracking for shale-gas, are likely to compete with established water needs for farming and human consumption. It is also suggested that the gravity modelling be examined to better understand site specific scenarios and thus aid in improving the processing of the gravity signal.

The Lower Permian Whitehill Formation (WHF) is an important hydrocarbon resource unit in the main Karoo Basin where it occurs in outcrops and up to 4 400 m in the subsurface and thus it is distributed over an area in excess of 260 000 km² in the southern half of South Africa. Although the formation is composed predominantly of black laminated carbonaceous shales, earlier studies detected significant spatiotemporal variability in its stratigraphy and composition, particularly the distribution of its organic carbon content across the basin. Because these stratigraphic variations and compositional heterogeneities remained largely uninvestigated, there are conflicting interpretations of not only the hydrocarbon potential of this resource unit but also the paleoenvironmental conditions that prevailed in the Karoo Basin during its accumulation. Following the recent global proliferation of unconventional hydrocarbon resources originating in organic-rich shale successions, the WHF is seriously being considered for gas shale exploitation in South Africa. Consequently, re-characterizing and explaining the spatiotemporal variations in its geometry and composition would be invaluable to the energy industry as well as the larger scientific community. With this aim, this study applied a combination of field descriptions, vintage borehole data, micro- to nano-scale petrographic observations, and multiple geochemical data so that a more critical understanding of the sedimentological controls responsible for the variability can be established. Using this integrated approach, five primary sedimentary facies (F1-F5, i.e., stratigraphic subunits in the WHF) were identified, which show specific and systematic variations in nature and content of organic carbon, stable isotopic composition (of δ¹³Corg and δ¹⁵N), C/N ratio, major and trace elemental enrichment, nature and content of iron sulfides, quartz texture, and CIA across the basin. The lower dark grey to black thinly laminated pyritic, carbonaceous fine shales (facies F1 and F2) contain up to 16.5 % TOC, δ¹³Corg of -15.57‰, δ¹⁵N of 12.49‰, C/N ratio of 1.50, average CIA of 68.11, Rb/K (x10⁻³) and Sr/Ba ratios of 6.56 and 0.67, respectively. Relative to average shale, this unit is up to 6.27 and 3.11 times richer in Mo and Fe, respectively. The organic materials in this facies comprise Tasmanites cysts, colonial algae cells, and amorphous macerals and occur in well-defined laminae (lamalginites) as well as in discrete organic domains loosely associated with mineral grains (organo-minerallic aggregates). At least 25% of the silicate in this facies is of early diagenetic origin, possibly derived from alteration of air-fall volcanic ash. Iron sulfides occur dominantly in form of framboidal aggregates of pyrite. Marcasite in form of lags cement and nodules is also reported. A binary mixture of organic matter and phosphorites with botryoidal textures is also abundant. The upper medium to light grey calcareous-siliceous silty lenticular shale (F3-F5) contain up to 2.04% TOC, δ¹³Corg of -24.71‰, δ¹⁵N of 4.93‰, C/N ratio of 17.62, average CIA of 74.33, Rb/K (x10⁻³) and Sr/Ba ratios of 3.83 and 0.36, respectively. Relative to average shale, this unit was up to 2.65 and 0.43 times richer in Mo and Fe, respectively. Their organic macerals comprise disarticulated plant remains in disseminations with few amorphous macerals. At least 85% of the quartz content is of detrital origin likely sourced from the basin margins and transported to the basin by the action of bottom-hugging currents. Few iron sulfides occur dominantly in form of octa- and euhedral pyrite grains. The data presented in this thesis suggest that the lower WHF (subunits F1 and F2) may have accumulated in a marine setting with high bioproductivity of organic carbon delivered in form of flocculated organo-minerallic aggregates (pelagic snow) onto an anoxic seabed overlain by dysoxic to oxic waters. Reduced terrigenous input, presence of phosphorites, increasing CIA and increasing δ¹³Corg values with higher TOC point to a depositional setting that resulted from an interplay of sea-level highstand and climatic warm-ups. In contrast, the upper WHF (subunits F3-F5) was deposited largely under non-marine conditions with OM in the company of great detrital debris sourced from terrestrial settings, transported into the basin mainly in form of fluid mud flows and deposited above storm wave base. The presence various body and trace fossils, as well as the variations in bioturbation styles and intensities in subunits F3-F5, indicate that colonisation of the basin by invertebrate and vertebrate organisms is related to the different stages in the oxygenation of the sediment-water interface in an increasingly oxygenated setting.

The Oudtshoorn Basin is the largest onshore Mesozoic depocentre along the southern margin of South Africa, and is among the sedimentary basins that have been linked to the break-up of southern Gondwana. Filled by the continental lower Uitenhage Group, which for the most part is sparsely fossiliferous, difficult to correlate on a regional scale and void of non-renewable natural resources, the Oudtshoorn Basin is relatively poorly studied. This project aims at carrying out an in depth, field- and lab-based investigation of the sediment supply processes and directions, location of sediment sources and palaeoclimate during the deposition of the lower Uitenhage Group in the Oudtshoorn Basin. In addition to the sediment transit patterns from source to sink via palaeocurrent measurements and petrographic studies, the sedimentary architecture was assessed via modern facies analysis techniques, which also permitted the investigation of the reason, the nature and the mode of sediment transport (traction currents vs. mass movements) in the early stages of Gondwana fragmentation. The study identified nine facies associations, the composition, clast size and orientation of which suggest steep vs. gentle gradients along the northern and southern basin margins, respectively, and very gentle gradients in the basin centre. Furthermore, the common mass movement-deposits in the north contrast the sediments laid down by traction current and in turbid waters in the south, southwest, west and centre of the basin. Sediments were sourced from the northern and southern margins in alluvial fans, and moved toward the centre, where axial fluvial system dominated. Sedimentary facies distribution, grain size, and petrological composition collectively indicate sediment transport distances that were shorter and more rigorous in the north than in the south. Geochemical proxies and mineralogy indicate moderate weathering and deposition under an arid palaeoclimate. The lack of clear lithostratigraphic markers and the sparse distribution of isolated outcrops in the basin prevent the relative age assessment of the facies associations. This study highlights the need for systematic high-precision geochronological studies, if possible from drill core samples, of the facies associations identified herein to constrain the stratigraphic relationships in the Oudtshoorn Basin. Until these reconstructed palaeoenvironments are in temporal isolation, the history of the Oudtshoorn Basin and its relationship to the other Mesozoic grabens and half grabens of the southern Cape remain elusive.

The aim of the research focuses on characterizing heavy mineral assemblages and interpretation of the provenance of the Ecca Group of in the Eastern Cape Province, South Africa. In South Africa, the Ecca Group outcrops extensively in the Main Karoo Basin. Mudstone, siltstone, sandstone, minor conglomerate and coal are the major constituent lithologies within the group. For descriptive purposes, the Ecca is categorized into three different geographical areas: the southern area, the western and northwestern area and the northeastern area. Six of the sixteen geological formations, namely the Prince Albert, Whitehill, Collingham, Ripon, Fort Brown, Waterford and Koonap Formations are present in the study area and are best exposed in road cuttings. For purposes of comparison, the underlying Witteberg Group, the Dwyka (which has Formation status here), and the overlying Koonap Formation of the Beaufort Group, are included in the study. This study is motivated by the relatively little information that is available on the heavy minerals of the Ecca Group, and that research of this nature had not been undertaken in the study area before. Another contributing motivation was to determine whether heavy mineral assemblages could be used to identify formations of the Ecca Group and for correlating between different localities in accordance with studies done elsewhere. Additionally, diagnostic heavy mineral assemblages could aid with stratigraphic selection of future boreholes in the Ecca Group. Heavy minerals are natural provenance tracers because of their stable nature and hydrodynamic behaviour. They are both non-opaque and opaque, with apatite, epidote, garnet, rutile, staurolite, tourmaline and zircon being good examples of non-opaque grains while ilmenite and magnetite are the most common opaques. Heavies are either derived from stable minor accessory minerals or from abundant but unstable mafic components of the host rock. They are very useful in interpreting the provenance due to the fact that some minerals are diagnostic of certain source rocks. However, sediments are exposed to several factors (conditions) such as weathering, erosion, breakage due to abrasion, mixing and recycling during transportation from the source to the depositional area. This implies that there are parameters other than the parent lithology that determine their final composition.

Gold mineralization is hosted within gossanous quartz-haematite veins in volcano-sedimentary lithologies of the Klein Aub - Rehoboth basin of the Irumide Belt, Namibia. Mineralization and hydrothermal alteration are restricted to deformed lithologies particularly the metasediments. Lithological relationships, geochemistry and metallogenic characteristics of the Irumide Belt suggest an intra-continental rift setting. Copper mineralization is well known along the length of the belt, from Klein Aub in the southwest to Ghanzi in the northeast, whereas gold mineralization appears restricted to the Klein Aub Rehoboth basin. The gold is envisaged as having being leached initially from graben fill sequences during rift closure and basin dewatering. Location of the mineralization is strongly controlled by structure and lithological contact zones. Such zones are percieved as having acted as conduit zones for escaping mineralized fluids during basin closure and deformation. Apart from the lack of an effective mineralizing trap, all features consistent with the development of an ore deposit are present. The largest mineralization traps within the area studied are shear zones followed by lithological contact zones. The Mebi and Blanks gold mines are developed over large shear zones while the Swartmodder and Neuras gold mines are situated over mineralized lithological contacts. The Swartmodder copper mine yielded ore from a mineralized schist enclave within granite. Copper and gold occurrences are attributed to two contrasting styles of mineralization. Copper mineralization is suggested to have developed during initial rifting of the belt (ie. stratabound sedimentary exhalative type), while the gold and minor copper resulted from rift closure and basin dewatering. Although no economical orebody was realized during the course of this study a model is proposed for the development of mineralization within the Irumide basement lithologies as a working hypothesis for future exploration.

Thesis (MSc)--Stellenbosch University, 2012.
ENGLISH ABSTRACT: Basin subsidence analysis, employing the backstripping method, indicates that fundamentally two different basin-generating mechanisms controlled Tanqua depocentre development in SW Karoo Basin. The subsidence curves display initial dominantly decelerating subsidence, suggesting an extensional and thermal control possibly in a strikeslip setting during the depocentre formation; on the other hand, subsequent accelerating subsidence with time suggests that the dominant control on the depocentre formation in SW Karoo was flexure of the lithosphere. Based on these observations on the subsidence curves, it is possible to infer that the first stage of positive inflexion (~ 290 Ma) is therefore recognised as the first stage of Tanqua depocentre formation. Petrographic study show that most of the studied sandstones of the Tanqua depocentre at depth of ~ 7.5 Km were subjected to high pressure due to the overlying sediments. They are tightly-packed as a result of grains adjustment made under such pressure which led also to the development of sutured contacts. It is clear the high compaction i.e. grain deformation and pressure solution occurred on the sediments; leading to total intergranular porosity reduction of the quartz-rich sediments and dissolution of the mineral grains at intergranular contacts under non-hydrostatic stress and subsequent re-precipitation in pore spaces. Furthermore, siliciclastic cover in the Tanqua depocentre expanded from minimal values in the early Triassic (Early to Late Anisian) and to a maximum in the middle Permian (Wordian -Roadian); thereby accompanying a global falling trend in eustatic sea-level and favoured by a compressional phase involving a regional shortening due to orogenic thrusting and positive inflexions (denoting foreland basin formation). The estimate of sediment volume obtained in this study for the Permian Period to a maximum in the middle Permian is therefore consistent with published eustatic sea-level and stress regime data. In addition, this new data are consistent with a diachronous cessation of marine incursion and closure of Tanqua depocentre, related to a compressional stress regime in Gondwana interior during the late Palaeozoic.
AFRIKAANSE OPSOMMING: Die ontleding van komversakking met behulp van die terugstropingsmetode bring aan die lig dat die ontwikkeling van die Tankwa-afsettingsentrum in die Suidwes-Karoo-kom hoofsaaklik deur twee verskillende komvormende meganismes bepaal is. Die versakkingskurwes toon aanvanklike, hoofsaaklik verlangsaamde versakking, wat daarop dui dat ekstensie- en termiese beheer gedurende die vorming van die afsettingsentrum plaasgevind het, waarskynlik in strekkingwaartse opset. Aan die ander kant toon daaropvolgende versnellende versakking wat mettertyd plaasgevind het dat die vorming van die afsettingsentrum in die Suidwes-Karoo eerder oorwegend deur kromming van die litosfeer beheer is. Op grond van hierdie waarnemings met betrekking tot die versakkingskurwes, kan mens aflei dat die eerste stadium van positiewe infleksie (~ 290 Ma) dus as die eerste stadium van die vorming van die Tankwa-afsettingsentrum beskou kan word. Petrografiese studie toon dat die meeste van die sandsteen wat van die Tankwaafsettingsentrum bestudeer is, op diepte van ~ 7,5 Km aan hoë druk onderwerp was weens die oorliggende sedimente. Die sandsteen is dig opmekaar as gevolg van die korrelaanpassing wat onder sulke hoë druk plaasvind, wat op sy beurt ook tot die ontwikkeling van kartelnaatkontakte aanleiding gegee het. Dit is duidelik dat die sediment aan hoë verdigting, dit wil sê korrelvervorming en drukoplossing, onderwerp was, wat gelei het tot algehele afname in interkorrelporeusheid by die kwartsryke sedimente; die ontbinding van die mineraalkorrels in interkorrelkontaksones onder niehidrostatiese spanning, en daaropvolgende herpresipitasie in poreuse ruimtes. Voorts het silisiklastiese dekking in die Tankwa-afsettingsentrum toegeneem van minimale waardes in die vroeë Triassiese tydperk (vroeë tot laat Anisiaanse tydperk) tot hoogtepunt in die mid-Permiaanse tydperk (Wordiaans–Roadiaans). Dié ontwikkeling het gepaardgegaan met algemene dalingstendens in die eustatiese seevlak, en is verder aangehelp deur saamdrukkingsfase wat gekenmerk is deur regionale verkorting weens orogeniese druk en positiewe infleksies (wat met voorlandkomvorming saamhang). Die geraamde sedimentvolume wat in hierdie studie vir die Permiaanse tydperk bepaal is, met die hoogtepunt in die middel van dié tydperk, is dus in pas met gepubliseerde data oor die eustatiese seevlak en spanningstoestand. Daarbenewens strook hierdie nuwe data met diachroniese staking van mariene instroming en die afsluiting van die Tankwaafsettingsentrum wat met spanningstoestand in die Gondwana-binneland gedurende die laat Paleosoïkum verband hou.

Kimberlites are igneous rocks that originate by small degrees of melting of the mantle. Notably, kimberlites carry large variety of crustal and mantle xenoliths. Geochemical data on xenoliths can provide insights into the processes occurring in the subcontinental lithosphere (SCLM) and deeper. The Kaapvaal craton in South Africa hosts one of the best-studied kimberlite populations on Earth. In this thesis, a total of 24 thin sections of peridotite xenoliths from Group I Letlhakane, Letseng, Premier and Frank Smith kimberlites were investigated to constrain the pressure, temperature and depth of these mantle xenoliths. To do so, olivine, orthopyroxene, clinopyroxene, garnet and spinel were analyzed for their major element chemistry using electron microprobe analysis (EPMA). P-T calculations were performed using the PTEXL3 spreadsheet program, which contains different geothermobarometers. Depth constraints were fitted to the characteristic Kaapvaal craton geotherm. According to geochemical results and rough modal mineral estimations, the majority of the mantle xenoliths were identified as depleted harzburgites or lherzolites. Mineral major element compositions show trends of depletion, which correlate with the corresponding mantle xenolith sampling depth. Olivine and orthopyroxene have high average Mg# values of 92.1 and 93.0, respectively, at shallower depth ~70–160 Km. Below ~160 km, Mg# starts to drop rapidly and transition towards a more typical asthenospheric composition. The majority of garnet compositions fall into the G9 classification field. Titanium shows a distinct partition trend that correlates with depletion. Garnets have well developed alteration reaction rims, especially at shallower depths. Geothermobarometric calculations for four-phase peridotites are comparable with the results from other studies. However, the temperature estimates obtained by T(BKN90) are slightly overestimated and, in contrast, the pressure estimates from P(BBG08) are slightly underestimated. Other assemblages have considerable calculated pressure and temperature conditions and were best fitted for the regional conductive geotherm. The mantle xenoliths show pressures ranging from 22 to 56 kb and temperatures from 753 to 1344 °C that characterize an extensive sampling depth range from 70 to 190 km. Three of the samples extend into the diamond stability field. The obtained P-T data for mantle xenoliths cluster along a 44.0±2.0 mWm⁻² conductive Kaapvaal craton continental geotherm, being slightly higher than that of the average thermal state estimate for the craton.

In South Africa, fossils found in the upper part of the Elliot Formation (Stormberg Group, Karoo Supergroup) are often associated with genetically poorly-constrained carbonate nodules. The origin of carbonate nodules i.e., pedogenic versus diagenetic, is important as pedogenic carbonate nodules can be used as palaeoclimate indicators, while diagenetic nodules carry limited palaeoclimatic information on the depositional setting. This research aims to characterize the carbonate nodules of the Elliot Formation macroscopically, petrographically and geochemically and to establish a diagnostic set of criteria to enable the differentiation between pedogenic and diagenetic nodules and/or diagenetic overprint. The research techniques employed in this study range from a) macroscopic field observations of the stratigraphic relationships of the nodules to the sedimentary features of the host rocks; b) sedimentary petrography of the textural features in the nodules; and c) X-ray diffraction for the assessment of the clay composition trapped within the nodules as compared to host rocks. Macroscopic field observations have shown that carbonate nodules found in the UEF are strongly associated with host rocks that contain pedogenic features such as root traces, burrows, colour mottling, and desiccation cracks, and thus are suggestive of ancient soils. However, the microscopic analysis of the nodules reveal no evidence for biological activities but rather a range of abiotic features such as septarian cracks, circumgranular cracks, and micronodules which are more likely have resulted from physicochemical processes that may have occurred during diagenesis. Clay minerals identified by X-ray diffraction include illite, muscovite, and montmorillonite confirm the generation of the sediments under arid to semi-arid climatic conditions.

Deformation of the western part of the Table Mountain Group rocks during the Cape Orogeny created a series of folds and associated fractures. The subsequent continental break-up of Gondwana led to the development of large fault systems. These exert a major influence on deep and shallow groundwater flow. There are 3 main types of structures that are investigated. The geological contacts between hydraulically different lithologies, the primary characteristics of the sediments comprising the main geological units and the secondary structures developed from the tectonic events. These inter-alia include lithological boundaries, bedding and conjugate joints and large faults. Compartmentalisation of the aquifers by lithological and fault boundaries are the main regional level controls on flow in the study area. Joints are important for local control of flow, but cumulatively exert a regional effect as well. These controls exert a strong 3 dimensional impact on flow patterns within the area. Geological cross sections and detailed fieldwork combined with the conceptual models proposed are used to determine groundwater flow and the extent of the flow constraints. There is heterogeneity in the fault characteristics whilst there isconsistence in the impermeable aquitards. These effect boundaries at the base of the aquifer, divide the aquifer into upper and lower units and cap the top of the aquifer. Using water level data, EC and pH an attempt is made to establish patterns created by structures, mainly faults. There appears to be some control of these shown by patterns seen on contour plots of the data. Understanding of the structures can significantly alter the way the available data could be interpreted. The integration of all available data into the conceptual model provides an effective research tool, which opens up further avenues for new approaches and methods for continued research in this area.

The Mesoproterozoic rocks of the Bysteek and Koenap Formations of the Arribees Group are exposed within a NW-SE striking antiformal structure comprised of mafic granulites and metapelitic diatexites, and a number of marble and calc-silicate rock layers. The mafic granulites of the Bysteek Formation show a typological variety of anatectic features, including nebulitic, stromatitic mesosomes, melanosomes, quartz syenitic leucocratic vein networks and syenitic pools. Melanosomes consist of hedenbergitic to diopside-rich clinopyroxene (XMg: 0.40), anorthitic plagioclase (An90), with some quartz, minor apatite and titanite. Anatexis was caused by biotite dehydration melting and formed a melt of probably granitic composition. The leucosome composition ranges from either alkali-feldspar-granitic to plagioclase rich or granitic. This variation is interpreted as a result of variable extraction of melt from the source to granitic pools. The diatexites of the Koenap Formation are most likely of metapelitic or meta-greywacke origin. They are texturally variable but always contain high modal contents of alkali feldspar and quartz which generally form magmatic textures. Almandine-rich garnet (XMg: 0.18-0.25), cordierite (XMg: 0.71) form secondary biotite, sillimanite and magnetite during retrograde breakdown. Thermodynamic modelling of mafic granulite compositions suggests peak P-T conditions of ~865 °C and 8.6 kbar. Occasionally, garnet rich in ferric iron (XAdr: 0.55) forms by plagioclase-clinopyroxene breakdown under oxidising conditions at ~6 kilobar and ~ 800 °C. At the same stage amphibole forms in some melanosomes. P-T estimations for the diatexites based on thermodynamic modelling suggest the equilibration of the assemblage garnet, cordierite, alkali feldspar and melt at ~860 °C and 5.5 kbar. Conditions comparable to the peak pressure in the mafic granulites could not be established. However, since the diatexites and the mafic granulites are closely related in the field and no evidence of juxtaposition after the thermal peak exists, the P-T record of the diatexites might be incomplete

The research examines the sedimentary environments and provenance of the Balfour Formation of the Beaufort Group (Karoo Supergroup) in the Eastern Cape Province, South Africa. This Formation occurs in the southeastern part of the Karoo Basin. It consists of sedimentary rocks, which are an alternating siltstone, shale and mudstone succession with subordinate interbedded sandstone and subsequently intruded by Karoo dolerite in the form of sills and dykes. ithostratigraphically, the Balfour Formation is subdivided into five units namely, from the base to the top, the Oudeberg, Daggaboersnek, Barberskrans, Elandsberg and Palingkloof Members. The Balfour Formation is overlain by the Katberg Formation. This study involved field investigations in the vicinity of the towns of Bedford and Adelaide with integrated stratigraphical, sedimentological and petrological studies. A geological map was constructed after field investigations. Lithofacies of the Balfour Formation that were studied are characterised by sandstone facies (Sh, Sm, St, Sr, Sp) and fine-grained sediments (Fl or Fsm) which reflect point-bar, cut-bank, channel and floodplain deposits. Lithologically, the Oudeberg Member consists of sandstone of which some units are internally massive alternating with thin laminated siltstone and mudstone. The Daggaboersnek Member is characterised by regular, generally non-lenticular, overall stratification, in the Barberkrans Member consists of sandstone lithosomes, while the Elandsberg Member is an argillaceous unit, similar to the Daggaboersnek Member. The Palingkloof Member is composed predominantly of red mudstone that can be used to distinguish the Balfour Formation from the overlying Katberg Formation, which consists predominantly of sandstone. The stratigraphic sequence displays two fining upward megacycles of sedimentary deposits with change in the sediment supply pattern from low-sinuosity to high-sinuosity river systems which reflect both braid and meandering deposits, respectively. Sedimentary structures in the sandstone units and the provenance of the Balfour Formation indicate that these deposits were produced by rivers flowing from the southeast with minor drift towards the northwest. According to the composition of the sediments and their sequence of deposition the Formation represents a fluvial environment. Mineralogical and grain size data from the sandstones of the various members of the Balfour Formation indicate the same source area of granitic, metamorphic and older sedimentary rocks and show no significant petrographic differences. The petrographic and geochemical investigations confirmed the sandstone to be feldspathic litharenite and ultralithofeldspathic sandstone. The palaeocurrent investigation indicates the main provenance to have been situated to the southeast of the Karoo basin. Heavy-mineral concentrations within the sandstones also give an indication that the source had a transitional arc plate tectonic setting.

The Pletersburg greenstone belt Is located In South Africa, about 300 km northeast of Johannesburg. It hosts a significant amount of gold mineralization and just over 1000 kg of gold have been produced from Its various reefs and secondary deposits. The greenstone belt is interpreted as an Archean ophiolite complex. It comprlses a volcano-sedimentary succession (the Pletersburg Group) which Is subdivided Into a basal greenstone sequence, interpreted as oceanic crust, and an upper sedimentary cover sequence. A number of major shear zones, which are thought to represent thrusts that developed during the subduction of the greenstone sequence, form an integral part of the stratigraphy . Four stages of deformation (D₁-D₄) and four phases of metamorphism (H₁-H₄) (three of which are correlatable with the peak stages of deformation) are recognized. The primary gold deposits are all shear zones related. but they are subdivided into greenstone, sedimentation and granIte-hosted types. Geographically, they occur In three distinct goldfields: Eerstellng, Roodepoort and Marbastad. The greenstone-hosted · Plenaar-Doreen shear complex Is In the Eersteiing goldfield and hosts eight gold occurrences. Within the complex, Girlie North Reef is the 640m-long "pay" section of the Girlie North shear zone. This reef is characterized, macroscopically, by a Quartz-carbonate-chlorite-sulphlde assemblage and, mlcroscoplcally, by the presence of tourmaline, arsenopyrlte and Au. Geochemical evidence Indicates that mineralizing fluids were H₂O and CO₂-bearing and rich In S, K and Al. The wall rock alteratlon was Isochemlcal but Is manifest as a change In mineralogy from a hornblende + plagioclase assemblage to an actlnollte/tremollte + Quartz + clay assemblage. This Is best developed In the hangIng wall of the reef and is thought to have been caused by hydrogen ion metasomatism. The Arsenopyrite Reef was one of the main sediment-hosted shear zone gold producers In the Harabastad goldfield. This reef Is Interpreted as the basal margin of a shear zone whose top contact Is probably represented by the Quartz Vein Reef. The shear zone consists predomonantly of quartz and carbonate, and the two "pay" reefs are characterized by tourmallne. arsenopyrite and Au. No wall rock alteration was identified In this study, Based on the mineralogy and geochemical signature of the Girlie Nortn Reef and the Arsenopyrite Reef, It Is proposed that both were formed at the $The Pletersburg greenstone belt Is located In South Africa, about 300 km northeast of Johannesburg. It hosts a significant amount of gold mineralization and just over 1000 kg of gold have been produced from Its various reefs and secondary deposits. The greenstone belt is interpreted as an Archean ophiolite complex. It comprlses a volcano-sedimentary succession (the Pletersburg Group) which Is subdivided Into a basal greenstone sequence, interpreted as oceanic crust, and an upper sedimentary cover sequence. A number of major shear zones, which are thought to represent thrusts that developed during the subduction of the greenstone sequence, form an integral part of the stratigraphy . Four stages of deformation (D₁-D₄) and four phases of metamorphism (H₁-H₄) (three of which are correlatable with the peak stages of deformation) are recognized. The primary gold deposits are all shear zones related. but they are subdivided into greenstone, sedimentation and granIte-hosted types. Geographically, they occur In three distinct goldfields: Eerstellng, Roodepoort and Marbastad. The greenstone-hosted · Plenaar-Doreen shear complex Is In the Eersteiing goldfield and hosts eight gold occurrences. Within the complex, Girlie North Reef is the 640m-long "pay" section of the Girlie North shear zone. This reef is characterized, macroscopically, by a Quartz-carbonate-chlorite-sulphlde assemblage and, mlcroscoplcally, by the presence of tourmaline, arsenopyrlte and Au. Geochemical evidence Indicates that mineralizing fluids were H₂O and CO₂-bearing and rich In S, K and Al. The wall rock alteratlon was Isochemlcal but Is manifest as a change In mineralogy from a hornblende + plagioclase assemblage to an actlnollte/tremollte + Quartz + clay assemblage. This Is best developed In the hangIng wall of the reef and is thought to have been caused by hydrogen ion metasomatism. The Arsenopyrite Reef was one of the main sediment-hosted shear zone gold producers In the Harabastad goldfield. This reef Is Interpreted as the basal margin of a shear zone whose top contact Is probably represented by the Quartz Vein Reef. The shear zone consists predomonantly of quartz and carbonate, and the two "pay" reefs are characterized by tourmallne. arsenopyrite and Au. No wall rock alteration was identified In this study, Based on the mineralogy and geochemical signature of the Girlie Nortn Reef and the Arsenopyrite Reef, It Is proposed that both were formed at the same time. Textural evidence Indicates that tourmaline, arsenopyrite and Au were all very late In the paragenesis of minerallzatlon. The presence of tourmaline also Indicates a probable granite association. It Is proposed that the maln gold mineralizing event was synchronous with the Intrusion of granitoids (and therefore also with (D₁-D₄) and (H₁-H₄) and that most of the Au was derived from felsic magma. Gold was partitioned Into a magmatic hydrothermal fluid and then transported into the greenstone belt as a chlorIde complex. These magmatiC fluids were channelled up shear zones whIch had already been mineralized with a quartz-carbonate-chlorlte - sulphide assemblage by previous metamorphic fluidS. generated during the dynamic (D₂-related) H₂-phase of metamorphism. The Au was then deposIted as the result of a change In a fluid variable, such as temperature, pH, f0₂, or the activity of Cl (some Au may have been transported In a sulphur complex and so the activity of reduced 5 could also have been Important).

The Beattie Magnetic Anomaly is the world’s longest terrestrial magnetic anomaly with a strike length of over 1000 km and a wavelength in excess of 100 km. Collinear with this is a large belt of elevated crustal conductivities called the Southern Cape Conductive Belt. Historical crustal interpretations proposed a common source of serpentinized ophiolite as an explanation for both the anomalous crustal magnetic susceptibility and electrical conductivities. Spreading between the Western and Eastern Cape of South Africa the mid- to lower crust that hosts these anomalies is obscured by the overlying Cape and Karoo Supergroups. Between 2003 and 2006, three high resolution geophysical experiments were completed across the surface maximum of the Beattie Magnetic Anomaly (BMA) and the Southern Cape Conductive Belt (SCCB). These included a magnetotelluric (MT) survey and near vertical reflection and wide angle refraction seismic profiles. Within the MT inversion model the SCCB appeared as a composite anomaly, which included a mid-crustal conductor which is spatially associated with the BMA and a laterally continuous upper crustal conductor which is located at depths equivalent to the lower Karoo Supergroup. Subsequently; the upper crustal conductor was identified in northern and eastern extensions of the magnetotelluric profile; a distance in excess of 400 km. Historical magnetometer and Schlumberger Sounding experiments have previously identified elevated conductivities in the Karoo sequences which were attributed to the Whitehill and Prince Albert formations. These carboniferous, transgressive sediments are known to be conductive from borehole conductivity surveys and direct measurements at surface. In order to constrain the conductive properties of these sediments, impedance spectroscopy (IS) experiments were completed on core samples collected from a historical borehole drilled near to the MT profile. Part One of this thesis presents the results of these experiments, which support the proposition that the Whitehill and Prince Albert Formations are responsible for the laterally continuous, sub-horizontal, upper crustal conductor visible in the MT inversion model. Vitrinite reflectance studies were performed on the same samples by the Montanuniversität, in Leoben, these results corroborate the proposition that elevated organic carbon, of meta-anthracite rank, is the primary conductive phase for the Whitehill and Prince Albert formations. Part two of this thesis completed forward modelling exercises using historical aeromagnetic data previously collected across the Beattie Magnetic Anomaly. Preliminary models were unable to fit the geometry of any single magnetic model with conductors present in the MT inversion model discounting the proposition that the SCCB and BMA arise from a single crustal unit. Two constrained models were arrived at through an iterative process that sought a best fit between the measured data and the NVR crustal interpretations. The first model, proposes a largely resistive unit which incorporates portions of elevated crustal conductivity; these conductors are spatially correlated to crustal portions also characterised by high seismic reflectivity. The size of this modelled body suggest the likely host of the BMA is an intermediate plutonic terrane, analogous with the Natal sector of the Namaqua Natal Mobile Belt as well as the Heimefrontfjella in Dronning Maud Land, Antarctica, with magnetite hosted within shear zones. This is in agreement with previous studies. The second model proposes a lower crustal sliver imaged in the NVR data at depths proximal to the Curie Isotherm for magnetite and hematite as the source of the BMA. At these depths geomagnetic properties such as burial magnetisation or thermo-viscous remanent magnetism (TVRM) can potentially be linked to regional scale tectonic processes and can theoretically elevate a body’s net magnetic susceptibility. TVRM has been proposed for long wavelength crustal anomalies elsewhere.

Bibliography: pages 346-370.
A regional study of highly metamorphosed supracrustal rocks was undertaken in the western portions of the Namaqualand Metamorphic Complex. The study area was essentially restricted to a north-south section some 50 kilometres wide and 220 kilometres long. Eight east-west-trending belts of supracrustal rocks were examined, together with several smaller paragneiss remnants, in an area dominated by quartzo-feldspathic gneisses of granitic composition. The supracrustal rocks were classified into seven major lithological groups: quartzitic rocks, metapelitic and metapsammitic rocks, quartzo feldspathic rocks, metabasites, metacarbonate rocks, magnesium-rich cordierite rocks and iron formations. Further subdivision, based on variations in mineral constituents within each group, also occurred, as well as the presence of lithologies with compositions transitional between certain groups. The various supracrustal sequences were subdivided into formations containing minor distinctive members on an informal lithostratigraphic basis. Correlation between the major supracrustal belts was then undertaken. Four subgroups were identified across the study area, comprising a quartzo feldspathic gneiss subgroup and an overlying feldspathic quartzite/garnetcordierite gneiss subgroup that both predominate in the southern and central part of the area, a glassy quartzite/mica- sillimanite schist subgroup that predominates in the northern part, and a cordierite gneiss/metacarbonate subgroup that is restricted to the Geselskapbank synform. The supracrustal rocks appear to have been emplaced on a basement of augen gneisses. This relationship is, however, complicated by the intrusion of granit i c rocks within the contact zone.

Thesis (MScAgric)--University of Stellenbosch, 2001.
ENGLISH ABSTRACT: This study is an integral part of a multidisciplinary research project concerning the effects of soil and climate on wine quality. The motive, which led to the setting up of this project, was that producers could not determine beforehand whether a specific location would yield wines of high or low quality. If a specific cultivar were to be planted at the wrong location, then it was likely that wine of table quality would result, rather than the export quality wine that was intended. The long term objectives of this multidisciplinary project were the compilation of guidelines by means of which different sites may be classified according to their potential for the production of high quality wines, and the identification of the most important climatic and soil factors responsible for differences in wine quality and character. In this multidisciplinary project, measurements (soil water, leaf water potential, cane mass and yield) were made under dry land conditions in Sauvignon blanc vineyards at six different localities: five in the Stellenbosch district (Simonsberg, Kuils River, Helshoogte, Papegaaiberg and Devon Valley) and one in Durbanville. Each vineyard was owned by a private commercial producer. The vines were approximately 10 years old in all cases, and were trained on a hedge system. Measurements were made in plots, each of which contained 20 vines. Two different soil types were identified at each locality. Vine growth and wine quality differed markedly on these contrasting soils, even though they were located in close physical proximity. The measurements that were made at high and low production plots at each locality during this study were obtained from points which were not more than 60 m metres apart. An automatic weather station was erected halfway between the two, contrasting, experimental plots. Within the overall scope of the multidisciplinary project, the study which forms the subject of this thesis, concentrated on the effects of soil parent material as a soil forming parameter and as a possible predetermining character with regard to vine growth and wine character. From literature it was clear at the outset of this work that the geology of the coastal wine region is very complex and varies over short distances. The geological history indicates different types of rock formation and rock forming process (sedimentary, igneous as well as metamorphic), plate tectonic activity, mountain building, erosion and weathering, over a period of approximately 1 000 million years. The present landscape includes a coastal plane, hills, and eroding mountains. Statistical analyses indicated that the soils from the different localities could mainly be characterised in terms of differences in their sand size fractions. Soils from Durbanville are dominated by fine sand and correlates with the underlying phyllitic shales. Soils from Kuils River contain significantly more coarse sand when compared with the other sites. This appears to be a reflection of the underlying coarse granitic material, and implies that in situ weathering played an important role in soil development. .The data did not, however, prove that the Kuils River soils formed solely from underlying rocks. The gravel and stone fraction for the Kuils River soils were nevertheless correlated with those of the underlying parent material. Soils from Helshoogte and Simonsberg (both of which are underlain by granites), Papegaaiberg and Devon Valley (both underlain by hornfels) were not significantly dominated by any particular sand fraction. Soils from these localities therefore did not only reflect the underlying material as a source of soil parent material. This implied mixing of parent material and/or the incursion of eolian sand at Helshoogte, Simonsberg and Devon Valley. A marine incursion may have affected the soil parent material at Papegaaiberg. In order to obtain more information concerning the origins and possible mixing of parent materials prior to and during soil formation, samples from the different soil horizons in each profile were subjected to a chemical analysis. Particular emphasis was placed on potassium, which is an extremely important nutrient mineral element, from the viewpoints of vine growth and wine quality. Because the soils used in this study were all located in production vineyards, the probability that fertiliser residues would have contaminated the soils was high. The lower soil horizons were considered to be least affected by this contamination and therefore most likely to be indicative of the natural soil chemical composition. However, the lower horizon K content of the soils in this study could not be reliably correlated with any known or predicted characteristic that might link the soil parent material with local rock types. At Durbanville, both soils contained small quantities of K in the lower horizons, reflecting the underlying phyllitic shales, but at Devon Valley and Papegaaiberg, the lower horizons contained more K than expected. The soils at these localities are situated on hornfels, containing low quantities of K. The large quantities of K in the soils may have indicated that these soils are situated close to a granite/Malmesbury contact zone. Soils from Kuils River, Simonsberg and Helshoogte are situated on K-rich porhyritic granites and it was expected that these soils would contain relatively large quantities of K in the lower horizons. This, however, was not the case. It was therefore concluded that dilution with K-poor material had taken place. Such material could have been derived from higher-lying sandstones, or from eolian processes during the Cenozoic. Alternatively, the K content of the soil might have been depleted by long continued leaching. A semi-quantitative analysis of the minerals in the soil clay fractions was also carried out. The objective was to identify the clay minerals that were present in the different soil horizons and to relate the minerals to weathering conditions. Evidence linking the minerals in the clay fractions of the soil samples with the mineralogical composition of the soil parent materials was sought. The clay fraction mineralogy data indicated that all soils in the study area are in an advanced stage of weathering and are dominated by kaolinite, and in certain soils quartz. It was difficult to relate these minerals directly with soil parent material because the primary minerals originating from the soil parent materials have been extensively broken down. The simultaneous presence of quartz and gibbsite in the clay fraction of both soils at Simonsberg, Helshoogte and Durbanville as well as one soil form from bath Kuils River and Simonsberg, indicated non-uniform distribution of clay fraction minerals, indicating that different stages of weathering were present during soil formation. This could have been a result of mixing of parent materials, but may also reflect different periods of weathering of the same material. Both soils at Papegaaiberg, both soils at Devon Valley and other soils at Simonsberg and Kuils River indicated uniform clay fraction mineralogy distribution, mainly because the absence of gibbsite is related to the presence of quartz in the clay fraction. The soil characteristics, as determined in this study, were also compared with vine growth, wine quality and wine character, as obtained in the broader multidisciplinary research project. For most soils in this study, an increase in clay fraction kaolinite was associated with a reduction in vegetative growth, overall wine quality, and fresh vegetative character. An increase in clay fraction quartz was associated with higher overall wine quality. Increased shoot growth also affected fresh vegetative character positively. Better growth occurred on higher altitudes and this resulted, for Sauvignon blanc, in higher wine quality. Wines produced from vines situated on both phyllitic shales and porhyritic granites showed high quality (Durbanville and Helshoogte), but both were related to low clay fraction kaolinite content and high altitude. It was not possible to relate parent material directly with vine growth, wine quality and/or wine character. The lowest quality wines, however, were produced from vines situated on hornfels (Papegaaiberg and Devon Valley), both containing high quantities of clay fraction kaolinite and situated on low altitudes. High levels of K in soils containing high levels of clay fraction kaolinite may have been partly responsible for low wine quality obtained on such soils.
AFRIKAANSE OPSOMMING: Hierdie studie vorm 'n integrale deel van 'n multi-dissiplinêre navorsingsprojek oor die effek van grond en klimaat op wynkwaliteit. Die motivering wat gelei het tot die beplanning van hierdie projek, was dat produsente nie vooraf kon bepaal of 'n spesifieke lokaliteit wyne kan produseer van hoë of lae kwaliteit nie. Indien 'n spesifieke kultivar op die verkeerde lokaliteit geplant word, sou dit waarskynlik tot In gewone tafelwyn lei, instede van 'n wyn van uitvoergehalte. Die langtermyn doelwitte van die multi-dissiplinêre projek was om riglyne te ontwikkel om verskillende lokaliteite te klassifiseer na aanleiding van·hul potensiaal om hoë kwaliteit wyne te produseer, asook om die belangrikste klimaats- en grondfaktore verantwoordelik vir die produksie van hoê kwalitiet wyne te identifiseer. In hierdie multidissiplinêre projek was metings (plant beskikbare water, blaarwater potensiaal, lootmassa en oes) onder droêland toestande bepaal in Sauvignon blanc wingerde by ses verskillende lokaliteite: vyf in die Stellenbosch distrik (Simonsberg, Kuilsrivier, Helshoogte, Papegaaiberg and Devon Valley) en een in Durbanville. Elke wingerd is besit deur 'n kommersiêle privaatprodusent. Die stokke was ongeveer 10 jaar oud in alle gevalle en opgelei op 'n heining sisteem. Metings was in eksperimentele blokke van 20 stokke elk uitgevoer. Twee verskillende grondtipes is by elke lokaliteit identifiseer. Lootgroei en wynkwaliteit het merkbaar verskilop die kontrasterende gronde, selfs waar gronde nabyaanmekaar was. Die metings is Liitgevoer op hoë- en lae produksie eksperimentele blokke waar gronde by spesifieke lokaliteite nie verder as 60 meter was nie. 'n Outomatiese weerstasie was halfpad tussen die twee kontrasterende grondtipes by elk van die ses lokaliteite opgerig. Binne die algemene omvang van die multi-clissiplinêre projek, het die studie wat die onderwerp van hierdie tesis is, gekonsentreer op die effek van moedermateriaal as grondvormende parameter asook as moontlike voorspeller van wingerdgroei en wynkarakter. Dit was duidelik uit die literatuur dat die geologie van die Wynkusstreek baie kompleks is en oor kort afstande varieer. Die geologiese geskiedenis dui daarop dat verskillende tipes gesteentes en verskillende prosesse van gesteente-vorming (sedimentêr, stollings- en metamorfe), plaattektoniese aktiwiteit, orogenese, erosie en verwering, oor 'n periode van ongeveer 1 000 miljoen jaar plaasgevind het. Die huidige landskap sluit kusvlaktes, heuwels en geêrodeerde berge in. Statistiese analises het aangetoon dat die gronde van die verskillende lokaliteite hoofsaaklik in terme van verskille in sandgrootte fraksies onderskei kon word. Gronde van Durbanville is gedomineer deur fyn sand en korreleer met onderliggende fillietiese skalies. Gronde van Kuilsrivier bevat betekenisvol meer growwe sand wanneer dit vergelyk word met die ander lokaliteite. Dit is waarskynlik afkomstig vanaf die onderliggende growwe granitiese materiaal en impliseer dat in situ verwering 'n belangrike rol gespeel het in grondontwikkeling. Die data het egter nie bewys dat die gronde van Kuilsrivier slegs uit die onderliggende graniete gevorm het nie. Die gruisfraksies in die gronde by Kuilsrivier was tog vergelykbaar met die onderliggende materiaal. Gronde vanaf Helshoogte and Simonsberg (beide onderlê deur graniete), Papegaaiberg and Devon Valley (beide onderlê deur hornfels) was nie betekenisvol gedomineer deur 'n spesifieke sandfraksie nie. Gronde vanaf hierdie lokaliteite het dus nie slegs die onderliggende gesteentes verteenwoordig nie. Dit dui op vermenging van moedermateriaal en/of eoliese prosesse by Helshoogte, Simonsberg and Devon Valley. 'n Styging in seevlak kon die moedermateriaal by Papegaaiberg beïnvloed het. Om meer inligting omtrent die oorsprong en moontlike vermening van moedermateriaal voor grondvorming te verkry, is die verskillende grondmonsters chemies ontleed. Kalium is In uiters belangrike voedingselement wat lootgroei en wynkwaliteit kan beïnvloed. Aangesien die gronde in hierdie studie in bestaande produksieblokke voorkom, was daar 'n goeie kans dat bemestingstowwe die chemiese samestelling kon beïnvloed. Die C horisonte van die verskillende gronde was beskou as dié wat die minste deur bemesting beYnvloedsou word en die naaste aanduiding van natuurlike grondchemiese samestelling. Die C horison K-inhoude van die gronde in die studie het egter nie gekorreleer met enige eienskap wat die moedermateriaal van die gronde met die lokale gesteentetipe kon verbind nie. By Durbanville, het beide gronde klein hoeveelhede K in die C horisonte bevat, wat die onderliggende fillietiese skalies reflekteer, maar by Devon Valley en Papegaaiberg, het die C horisonte meer K bevat as wat verwag is. Die gronde by hierdie lokaliteite word onderlê deur hornfels, wat lae hoeveelhede K bevat. Die groot hoeveelhede K in hierdie gronde dui moontlik op 'n kontaksone tussen graniet en Malmesbury gesteentes in die area. Gronde vanaf Kuilsrivier, Simonsberg en Helshoogte word onderlê deur K-ryke porfiritiese graniete wat groot hoeveelhede K in die ondergronde sou bevat. Dit was egter nie die geval nie en dit was aanvaar dat verdunning van K-arme materiaal plaasgevind het. Die oorsprong van Karme materiaal was waarskynlik vanaf hoêr-liggende sandstene, of vanaf eoliese prosesse gedurende die Cenozoikum. Alternatiewelik is K inhoude van die gronde verlaag deur lang en aanhoudende loging. 'n Semi-kwantitatiewe analise van minerale in die kleifraksie was uitgevoer om te bepaal watter minerale in die kleifraksie van die verskillende gronde teenwoordig is en om die minerale met stadia van verwering te vergelyk. Dan kon die mineralogiese samestelling in verband met moedermateriaal gebring word. Resultate het aangetoon dat al die gronde in die studie in 'n gevorderde stadium van verwering is en gedomineer word deur kaoliniet, en in sekere gronde, klei fraksie kwarts. Aangesien die primêre minerale in 'n groot mate afgebreek is, was dit moeilik om die minerale in die kleifraksie direk in verband met moedermateriaal te bring. Die voorkoms van kwarts en gibbsiet in die kleifraksie in beide gronde van Simonsberg, Helshoogte en Durbanville asook een grondvorm vanaf beide Kuilsrivier en Simonsberg, het aangetoon dat verskillende stadia van verwering gedurende grondvorming in hierdie gronde voorgekom het. Dit kan die gevolg wees van vermenging van verskillende moedermateriaal, maar kan ook verskillende periodes van verwering van dieselfde materiaal aandui. Beide gronde by Papegaaiberg, beide gronde van Devon Valley die ander gronde by Simonsberg en Kuilsrivier het slegs een fase van verwering tydens grondvorming aangedui, hoofsaaklik as gevolg van die afwesigheid van gibbsiet wanneer kwarts voorkom. Grondeienskappe, soos bepaal in hierdie studie, was ook vergelyk met lootgroei, wynkwaliteit en wynkarakter, soos verkry uit die resultate van die multi-dissiplinêre projek. Vir die meeste gronde in die studie was 'n toename in kleifraksie kaoliniet geassosieer met afname in vegetatiewe groei, algemene wynkwaliteit, asook vars vegetatiewe wynkarakter. 'n Toename in kleifraksie kwarts was geassosieer met hoër algehele wynkwaliteit. 'n Toeneme in vegetatiewe groei het ook die vars vegetatiewe karakter van die wyn positief beïnvloed. Beter vegetatiewe groei het op hoër hoogtes voorgekom en dit het gelei tot hoër wynkwaliteit vir Sauvignon blanc. Wyne afkomstig van wingerde op beide fillietiese skalies en porfiritiese graniete, was van hoër kwaliteit (Durbanville and Helshoogte), maar beide was geassosieer met lae kleifraksie kaoliniet en hoë ligging. Dit was nie moontlik om moedermateriaal direk met vegetatiewe groei, wynkwaliteit en/of wynkarakter te vergelyk nie. Wyne met die laagste kwaliteit kom egter voor op hornfels (Papegaaiberg and Devon Valley), wat beide groot hoeveelhede kleifraksie kaoliniet bevat en geleê is op lae hoogtes. Hoê vlakke van K in gronde wat groot hoeveelhede kleifraksie kaoliniet bevat kan gedeeltelik verantwoordelik wees vir lae kwaliteit wyne op sulke gronde.