Dissertations / Theses on the topic 'Geology – South Africa – Witteberg Group'

Selected outcrops of the Upper Devonian to Lower Carboniferous, Witteberg Group, Cape Supergroup were mineralogically and structurally analyzed. The study area is located approximately 30km northwest of Kirkwood and 10km south of Darlington Dam, Eastern Cape, South Africa. Strata predominantly consist of arenaceous Witpoort Formation, which includes the Perdepoort, and Rooirand Members. The Perdepoort Member is a thinly bedded quartzite also known as the "white streak". The Rooirand Member quartzite is a highly iron stained red-brown quartzite. The dark-grey, pyritic rich shales of the Kweekvlei Formation overlie the Witpoort Formation in the southern half of the study site. These shales are highly deformed and display closely spaced thrust faults and close folds. The study area encapsulates a range of folding from tight to open folds. Faulting consists of low angle north verging thrust fault, south verging back thrusts, south and north dipping normal faults, and strike-slip faults. Closely spaced, fore-land verging thrusts faults predominate over hinterland verging back thrusts. Normal faulting post-dates thrust faulting and utilized weaknesses in axial planar cleavage and in certain instances existing thrust fault planes. Strike-slip faulting post-dates thrusting and has in places reactivated pre-existing thrust fault planes. Macro scale folding includes overturned synclines and large anticlines which have been eroded, exposing older strata. Fold axes plunge at low to moderate angles west-southwest. This correlates with tension gashes which indicate north westward directed forces. Eastward directed forces are confirmed by the presence of tension gashes and strike-slip movement. The local geology displays north westward directed compression followed by strike-slip movement. Normal faulting post-dates all other structures and is associated with the Mesozoic break-up of Gondwana. The Perdepoort Member was sampled along strike, at different outcrop latitudes. Seven samples were selected for scanning electron microscope analysis. Samples are composed almost entirely of quartz; accessories include, biotite, muscovite, sericite, baryte, and apatite. Epigenetic hematite is present along cracks within certain samples Epigenetic hematite occur along cracks with oxides and phosphates in the form of rutile, apatite and monazite present in a number of samples. When compared to other silica extraction operations the Perdepoort Member appears viable for explotation. However, for the solar cell industry the purity of this horizon is clearly far below that required for industy.

A number of outcrops of the Witteberg Group and lowermost Karoo Supergroup rocks were studied in the area south of the Darlington Dam, Jansenville District, with the aim of documenting structural characteristics of the area. All lithologies are folded with fold styles varying from gentle to near isoclinal (based on interlimb angle). Fold axes are either sub-horizontal or plunging at gentle to moderate angles whereas axial planes dip gently to vertically (predominantly steep to sub-vertical). Folds verge predominantly towards the north but where southward verging they are associated with faulting or strongly folded areas. Folds plunge gently to the east-southeast and west-northwest. The area consists of a large anticlinorium with both first and second order folds occurring. Eastwest striking faults occur in the study area and are classified as normal, reverse and thrust faults. A study of the joint sets shows that there are four dominant joint directions, namely 18o, 33o, 97o and 107o (in order from least to most important). An interpretation of the tectonic history is presented in which the relationships between faults and folds show that faults formed during and after folding. Folding, and reverse and thrust faulting, occurred during the compressional events that formed the Cape Fold Belt, whereas the normal faults formed during the relaxation of these compressional forces or during the break-up of Gondwana.

A structural study of Witteberg Group Rocks was conducted along the Soutkloof River, approximately 14 km east of Steytlerville, Eastern Cape Province of South Africa. Here a north to south geotraverse was studied in an attempt at unravelling the structural geology of the rocks belonging to the Upper Devonian to Lower Carboniferous Witteberg Group (Upper Cape Supergroup). These rocks are mostly arenaceous and include quartzite, sandstone, siltstone and shale which have been folded, faulted and metamorphosed. Thrust, normal and strike-slip faulting occur in the area. Shallow south-dipping low-angle thrust fault planes are displaced by steep south-dipping thrust planes and subordinate north-dipping backthrusts. Displacement along thrust planes is predominantly northwards. Steeply dipping thrust fault planes are often reactivated as east-west striking normal faults. Strike-slip faulting postdates all observed structural features and displaces normal and thrust fault planes. Open to tight folds are present and are mostly northvergent and often steepened or truncated by steep south-dipping thrust fault planes. South-vergent folds are related to backthrusting and post-fold faulting. The study has revealed that the current geological map and the local stratigraphy were compiled without recognising major structural features such as thrust, normal and strike-slip faulting and their (the map and currently accepted stratigraphy) validity are therefore questioned. The presence of extensive faulting suggests that the conventional stratigraphic interpretation of the Witteberg Group should be revised.

The variations in the composition, specifically the Cr20 S content and the Cr:Fe ratio, and the morphology of the Lower Group (LG) and Middle Group (MG) chromitite seams of the Critical Zone (CZ) across the western Bushveld Complex, including the Ruighoek and Brits sections, is investigated by means of whole-rock chemical data, both major and trace elements analysis, XRD and electron microprobe data. As a result ofthe paucity of exposed or developed LG1 - LG5 chromitite seams in the western Bushveld Complex, this study is confined to the investigation of the compositional variations of the LG6 to MG4 chromitite seams. In only one section, the Ruighoek section, was the entire succession of chromitite seams, from the LG1 - MG4, exposed. The silicate host rocks from the LG6 pyroxenite footwall to the collar of the CC2 drillcore (lower uCZ) in the Rustenburg section were sampled. This study reviews the compositional trends of the silicate host rocks, as the compositional variations of the chromitite seams reflect the chemical evolution of the host cumulate environment and, to a lesser degree, the composition onhe interstitial mineral phases in the chromitite seams. The compositional variations of the LG and MG chromitite seams are attributed to the compositional contrast between the replenishing magma and the resident magma. The chemical trends of the LG and MG chromitite layers and the host cumUlate rOCKS do not support the existence of two compositionalfy dissimilar magmas in the CZ, rather the cyclic layering of the CZ and the chemical variations of the chromitite seams are attributed to the mixing of primitive magma with the resident magma, both of which have essentially similar compositions. The compositional variations of the LG and MG chromitite seams along strike away from the supposed feeder site (Union section) to the distal facies (Brits section) are attributed to the advanced compositional contrast between the resident magma and the replenishing primitive magma pulses. The CZ is characterized by reversals in fractionation trends and this is attributed to the compositional evolution of the parental magma and not to the replenishment of the resident magma by influxes of grossly dissimilar magma compositions. The Cr20 S content and the Cr:Fe ratio of the MG chromitite layers increase from the Ruighoek (near proximal) section to the Brits section (distal facies). This is attributed to the advanced compositional contrasts between the resident magma and the replenishing primitive magma. In contrast, the Cr20 3 content and Cr:Fe ratios ofthe LG6 and LG8a chromitite seams decreases eastwards from the Ruighoek section. The average Cr:Fe ratio for the western Bushveld Complex is between 1.5 and\2.0, nonetheless, a progressively lower Cr:Fe ratio is noted from the LG1 chromitite up through to the MG4 chromitite seam in the Ruighoek section. tn the LG2 - LG4 chromitite interval a deviation to higher.lratios is encountered. A progressive substitution of Cr by AT and Fe in the Cr-spinel crystal lattice characterizes the chromitite succession from the LG1 seam up through the chromitite succession to MG4. The petrogeneSiS of the chromitite seams of the CZ is attributed to magma mixing and fractional crystallization of a single magma type.

Modern analysis of Table Mountain Group sediments began with I. C. Rust's D.Sc. thesis "On the sedimentation of the Table Mountain Group in the western Cape Province" in 1967. Rust defined the stratigraphy of the Table Mountain Group, produced computer generated isopach and palaeocurrent maps for each formation and attempted palaeoenvironmental analyses based on what data he had available. For work dated prior to 1967 the reader is directed to Rust's excellent review in Chapter 2 of his thesis. The thesis served as a basis for Rust's later published work on the Cape Supergroup. Current published palaeoenvironmental models of the lower Table Mountain Group (the Piekenierskloof, Graafwater and Peninsula Formations) are based on a transgressive fluvial - littoral - shallow shelf model (Tankard et al., 1982) following earlier facies and palaeoenvironmental analyses (Tankard and Hobday, 1977: Rust, 1977; Hobday and Tankard, 1978: Vos and Tankard, 1981). The validity of this model has recently been questioned (Turner, 1986; 1987) although no comprehensive alternative has been proposed to date. The sedimentology of the upper Table Mountain Group i.e. the Pakhuis, Cedarberg, Rietvlei, Skurweberg and Goudini Formations (the latter three the newly named Nardouw Subgroup) has not been studied systematically. Good progress has recently been made on the fossil content of the Cedarberg Formation (Gray et al., 1986; Cocks and Fortey, 1986) and palaeoenvironmental analyses initiated in the Nardouw Formation. This thesis documents contributions to the geology of the Table Mountain Group. It is not the intention of the author to present an extensive overview and treatise on the lower Table Mountain Group, but rather to concentrate on three topics that can provide some insight into Table Mountain Group geology. The following three topics were selected 1) Petrology and Diagenesis of lower Palaeozoic sandstones in the s.w. Cape Sandveldt (Clanwilliam and Piketberg Discricts). 2) Palaeoenvironmental indicators in the Faroo Member, (Graafwater Formation) at Carstensberg Pass, R364. 3) Facies analysis of conglomerates and sandstones in the Piekenierskloof Formation: Processes and implications for pre-Devonian braid-plain sedimentology. These topics form the basis of the thesis.

This thesis examines the geology of the Daspoort Formation (Pretoria Group, Transvaal Supergroup) of South Africa, with the accent on describing and interpreting its sedimentology. The Palaeoproterozoic Daspoort Formation (c. 2.1‐2.2 Ga) forms part of the Pretoria Group on the Kaapvaal craton. This sandstone‐ and quartzite‐dominated lithological formation covers an elliptical geographical area stretching from the Botswana border in the west to the Drakensberg escarpment in the east, with its northern limit in the Mokopane (Potgietersrus) area and Pretoria in the south; altered outliers are also found in the overturned units of the Vredefort dome in the Potchefstroom area. Deposition of the Daspoort Formation was in a postulated intracratonic basin which applies equally to the entire Transvaal Supergroup succession in the Transvaal depository. Various characteristics from the formation, such as sedimentary architectural elements (e.g., channel–fills etc.), maturity trends and distribution of lithofacies assemblages across the preserved basin give insight into the developing conditions during deposition and genesis of the Daspoort Formation. Subordinate evidence from basic geochemistry, ripple mark data and optical microscope petrology studies support the sedimentary setting inferred for this Palaeoproterozoic deposit. Fluvial and epeiric marine conditions prevailed during the deposition of the Daspoort clastic sediments into the intracratonic basin. This shallow epeiric sea was fed by fluvial influx, predominantly from the west when a transgressive regional systems tract led to the filling of the basin, evolving into the deeper marine Silverton Formation setting, laid down above the Daspoort. Transgression from the east (marine facies predominate) to the west (fluvial facies) is supported by cyclical trends, palaeoenvironmental and palaeogeographical interpretations. Accompanying poorly preserved microbial mat features contribute to the postulated shallow marine environment envisaged for the eastern part of the basin whereas ripple marks and grain size distribution support a fluvial setting for the west, with lithofacies assemblages accounting for both areas’ depositional interpretation.<br>Dissertation (MSc)--University of Pretoria, 2013.<br>tm2014<br>Geology<br>Unrestricted

Thesis (MSc) -- Stellenbosch University , 1995.<br>ENGLISH ABSTRACT: A number of small greenstone bodies of the Bridgetown Formation are exposed as elongated lenses and dykes within metasediments of the Malmesbury Group in the Western Cape Province, South Africa. The Malmesbury Group is part of the Neoproterozoic to Cambrian (Namibian) Saldania Subprovince which is the southern continuation of a Pan-African mobile belt system. A detailed geological and geochemical study was conducted on the largest outcrop of the Bridgetown Formation, situated 20km east of the town Moorreesburg. The Bridgetown Formation consists of a meta-volcano-sedimentary sequence that experienced polyphase deformation and metamorphism up to the lower greenschist facies. Tectonically, the Bridgetown Formation is included in the Boland tectonic domain, east of the Piketberg-Wel lington fault zone that is suggested to run Skm west of Heuningberg and subparallel to the Berg River. This agrees with Rabie's (1974) original subdivision of the tectonic domains. The Bridgetown Formation consists of: i) A basal unit of poorly differentiated alkaline metabasalt with a within-plate tectonomagmatic fingerprint. ii) An intermediate unit of poorly differentiated tholeiitic metabasalt, intruded by a younger tholeiitic metabasite with a low degree of differentiation. Both members of the intermediate unit have ocean-floor basalt (P-type MORB) and island arc basalt fingerprints. iii) An upper unit of poorly differentiated as well as more evolved alkaline metabasalts, interlayered with metatuff with an alkaline basaltic composition, metasedimentary rocks with a marine origin, and graphitic schists and muscovitequartz schists, both with a continental crust provenance. iv) An overlying metasedimentary sequence including dolomite, massive and oolitic chert, jasper and jaspilite. The Bridgetown Formation probably also comprises a lower metamorphosed ultramafic unit, indicated by the association of Ni- and Cr-rich talc bodies, Ni-and errich banded chert, chlorite schist and small dolomite-talc-chlorite bodies at Spitskop, situated directly northwest of the main greenstone body. The sequence of eruptive stages and the geochemistry of the metavolcanics resemble Hawaiian volcanism , indicated by an initial deep water stage of alkaline magmatism, followed by main tholeiitic edifice and post-caldera alkaline magmatism. Post-caldera alkaline magmatism occurred contemporaneously with deposition . of sediments and chemical precipitates (carbonates and cherts). The Bridgetown metavolcanics have no magmatic association with either the Bloubergstrand volcanics or mafic and intermediate plutonic rocks in the Malmesbury Group. However, some physical and geochemical similarities exist between the Bridgetown Formation and the age related Grootderm Formation of the Marmora Terrane (Gariep Supergroup) which is considered to represent ophiolitic material. The Bridgetown Formation probably represents segments of oceanic crust, including seamounts of oceanic islands, which were tectonically emplaced in an accretionary prism zone during subduction of oceanic crust underneath the Kalahari Craton, 600 to 700 Ma ago. This resulted in the present spatial configuration of various small greenstone bodies in the Malmesbury Group. To date no exploitable mineral deposits have been found 1n the Bridgetown Formation. However, Au and As anomalies in stream sediment and soil samples, taken in the Spitskop area, require further attention. lt is suggested that the gold and arsenic is hosted in brittle deformed clear to milky quartz veins which developed at zones of competency contrasts in all the li tholog ies in the Spitskop area.<br>AFRIKAANSE OPSOMMING: 'n Aantal klein groenskisliggame van die Bridgetown Formasie is blootgestel as verlengde lense en gange binne metasedimente van die Malmesbury Groep in die Wes-Kaap Provinsie, Suid-Afrika. Die Malmesbury Groep is deel van die Neoproterozo·iese tot Kambriese (Namibiese) Saldania Subprovinsie wat die suidelike voortsetting is van 'n Pan-Afrikaanse mobiele gordel sisteem. 'n Gedetaileerde geologiese en geochemiese studie is gedoen op die grootste dagsoom van die Bridgetown Formasie, gelee 20km oos van die dorp Moorreesburg. Die Bridgetown Formasie bestaan uit 'n metavulkanies-sedimentere opeenvolging wat pol ifase vervorming en metamorfisme tot en met die laer groenskis fasies ondergaan het. Die Bridgetown Formasie word hier in die Boland tektoniese domein ingedeel deur die Piketberg-Wellington verskuiwingsone 5km wes van Heuningberg, subparallel a an die Bergrivier, te plaas. Dit stem ooreen met Rabie ( 197 4) se oorspronkl ike verdeling van die tektoniese domeine. Die Bridgetown Formasie bestaan uit: i) 'n Basale eenheid wat hoofsaaklik bestaan uit min gedifferens ieerde alkali-metabasalte met binneplaat tektonomagmatiese eienskappe. ii) 'n lntermediere eenheid wat bestaan uit min gedifferensieerde tholeiitiese metabasalt en 'n jonger intrusiewe tholeiitiese metabasiet wat 'n lae graad van differensias ie ondergaan het. Beide intermediere eenhede het oseaanvloer-basalt (P-t ipe MORB) en eilandboog basaltiese eienskappe. iii) 'n Boonste eenheid wat bestaan uit min gedifferensieerde asook meer gedifferensieerde alkal i-metabasalte, tussengelaagd met metatuf met 'n alka libasaltiese samestelling; metasedimentere gesteentes met 'n mariene oorsprong, en grafitiese ski ste en kwarts-muskoviet skiste, beide met 'n kontinentale kors oorsprong . iv) 'n Oorliggende metasedimentere opeenvolging wat dolomiet, massiewe en ooli tiese chert, jaspis en jaspiliet insluit. Die Bridgetown Formasie slu it moontlik ook 'n onderliggende gemetamorfiseerde ultramafiese eenheid in; aangedui deur die assosiasie van Ni- en Cr-ryke ta lkl iggame, Ni- en Cr-ryke gebande chert, chlorietskis en klein dolomiet-talk-chloriet liggame by Spitskop, gelee direk noordwes van die hoof groensteenliggaam. Die opeenvolg ing van magmatisme en die geochemie van die metavulkaniese gesteentes stem ooreen met Hawaiiese vulkanisme, naamlik 'n diepwater stadium, gekarakteriseer deur alkaliese magmatisme, gevolg deur 'n hoof tholeiitiese opbouing en post-kaldera alkaliese magmatisme. Die post-kaldera alkaliese magmatisme het gelyktydig plaasgevind met afsetting van sedimente en chemiese presipitate (karbonate en cherte ). Die Bridgetown metavulkaniese gesteentes het geen magmatiese assosiasie met 6f die Bloubergstrand vulkaniese gesteentes 6f mafiese en intermediere plutoniese gesteentes in die Malmesbury Groep nie. Fisiese en geochemiese ooreenkomste bestaan egter tussen die Bridgetown Formasie en die Grootderm Formasie van die Marmora Terrein (Gariep Supergroep) wat beskou word as ofiolitiese materiaal. Die Bridgetown Formasie verteenwoordig moontlik segmente van oseaankors, insluitende oseaan-eilande, wat tektonies in 'n melange sone ingeplaas is tydens subduksie van oseaankors onder die Kalahari Kraton in (600 tot 700 Mj gelede). Dit verklaar die huidige ruimte like verspreiding van verske ie klein groensteenliggame in die Malmesbury Groep. Tot en met hede is geen ontginbare mineraalafsettings in die Bridgetown Formasie ontdek nie. Au en As anomalie in stroomsediment- en grondmonsters, geneem in die Spitskop area, behoort egter verdere aandag te geniet. Daar is voorgestel dat die goud en arseen voorkom in brosvervormde helder tot melkerige kwartsare wat ontwikkel het in swak sones in al die litologie in die Spitskop area.

The Oudtshoorn Basin is the largest onshore Mesozoic depocentre along the southern margin of South Africa, and is among the sedimentary basins that have been linked to the break-up of southern Gondwana. Filled by the continental lower Uitenhage Group, which for the most part is sparsely fossiliferous, difficult to correlate on a regional scale and void of non-renewable natural resources, the Oudtshoorn Basin is relatively poorly studied. This project aims at carrying out an in depth, field- and lab-based investigation of the sediment supply processes and directions, location of sediment sources and palaeoclimate during the deposition of the lower Uitenhage Group in the Oudtshoorn Basin. In addition to the sediment transit patterns from source to sink via palaeocurrent measurements and petrographic studies, the sedimentary architecture was assessed via modern facies analysis techniques, which also permitted the investigation of the reason, the nature and the mode of sediment transport (traction currents vs. mass movements) in the early stages of Gondwana fragmentation. The study identified nine facies associations, the composition, clast size and orientation of which suggest steep vs. gentle gradients along the northern and southern basin margins, respectively, and very gentle gradients in the basin centre. Furthermore, the common mass movement-deposits in the north contrast the sediments laid down by traction current and in turbid waters in the south, southwest, west and centre of the basin. Sediments were sourced from the northern and southern margins in alluvial fans, and moved toward the centre, where axial fluvial system dominated. Sedimentary facies distribution, grain size, and petrological composition collectively indicate sediment transport distances that were shorter and more rigorous in the north than in the south. Geochemical proxies and mineralogy indicate moderate weathering and deposition under an arid palaeoclimate. The lack of clear lithostratigraphic markers and the sparse distribution of isolated outcrops in the basin prevent the relative age assessment of the facies associations. This study highlights the need for systematic high-precision geochronological studies, if possible from drill core samples, of the facies associations identified herein to constrain the stratigraphic relationships in the Oudtshoorn Basin. Until these reconstructed palaeoenvironments are in temporal isolation, the history of the Oudtshoorn Basin and its relationship to the other Mesozoic grabens and half grabens of the southern Cape remain elusive.

Nodules within the lower Bokkeveld shales often contain well-preserved invertebrate fossil material. The aim of this study was to describe some characteristics seen at various scales (macro-, micro- and ultra -) within nodules that might contribute to an understanding of aspects of nodule formation and the reasons for the excellent preservation of the fossil material within these nodules. Detailed, high quality macro-photographs were taken of sliced and whole nodule surfaces and a catalogue was produced to tentatively identify fossils present and illustrate the variations seen within nodules. Selected nodules were then subjected to petrographic, ultra-structural (SEM) and some chemical (EDS, XRD & XRF) analysis to investigate the possible reasons for these variations. The chemical results have indicated that nodules are enriched with quartz compared to the surrounding shale. Quartz is also the dominant mineral replacing trilobite carapace material within nodules, while trilobite material within shales is replaced with equal proportions of hematite, biotite and quartz. It appears that the higher resistance of quartz to weathering is the dominant factor leading to the preservation of both nodules within the shales and trilobite material within the nodules examined. A comparison with some Western Cape nodules highlighted possible variations in overall nodule chemical composition along strike. Western Cape nodules are predominantly composed of apatite whereas the Cockscomb nodules are mainly composed of quartz. This quartz-apatite compositional variation in nodules occurring within a single formation has been reported from nodules found in the Armorican Massif of France which are very similar in a number of respects to the Bokkeveld nodules described in this study. Based on various features of the fossils present and the structure of nodules they were probably formed during early diagenesis within an epeiric marine deposit greatly affected by sea level fluctuations.

The aim of the research focuses on characterizing heavy mineral assemblages and interpretation of the provenance of the Ecca Group of in the Eastern Cape Province, South Africa. In South Africa, the Ecca Group outcrops extensively in the Main Karoo Basin. Mudstone, siltstone, sandstone, minor conglomerate and coal are the major constituent lithologies within the group. For descriptive purposes, the Ecca is categorized into three different geographical areas: the southern area, the western and northwestern area and the northeastern area. Six of the sixteen geological formations, namely the Prince Albert, Whitehill, Collingham, Ripon, Fort Brown, Waterford and Koonap Formations are present in the study area and are best exposed in road cuttings. For purposes of comparison, the underlying Witteberg Group, the Dwyka (which has Formation status here), and the overlying Koonap Formation of the Beaufort Group, are included in the study. This study is motivated by the relatively little information that is available on the heavy minerals of the Ecca Group, and that research of this nature had not been undertaken in the study area before. Another contributing motivation was to determine whether heavy mineral assemblages could be used to identify formations of the Ecca Group and for correlating between different localities in accordance with studies done elsewhere. Additionally, diagnostic heavy mineral assemblages could aid with stratigraphic selection of future boreholes in the Ecca Group. Heavy minerals are natural provenance tracers because of their stable nature and hydrodynamic behaviour. They are both non-opaque and opaque, with apatite, epidote, garnet, rutile, staurolite, tourmaline and zircon being good examples of non-opaque grains while ilmenite and magnetite are the most common opaques. Heavies are either derived from stable minor accessory minerals or from abundant but unstable mafic components of the host rock. They are very useful in interpreting the provenance due to the fact that some minerals are diagnostic of certain source rocks. However, sediments are exposed to several factors (conditions) such as weathering, erosion, breakage due to abrasion, mixing and recycling during transportation from the source to the depositional area. This implies that there are parameters other than the parent lithology that determine their final composition.

The study takes place in the Dwarsrivier area which lies on the border between Mpumalanga and Limpopo, to the North-West of Lydenberg, at an exposed road cutting. Within the road cutting, there is a unique portion of exposed rock which is light in colour and identified as a calc-silicate. The calc-silicate material is present as a package of rock and is surrounded top and bottom by pyroxenite. The surrounding rock belongs to the Bushveld Igneous Complex (BIC), which is the largest known layered intrusion on the planet and is host to numerous mines. The sample area is within the Critical Zone of the BIC and the host rock consists of pyroxenite which is crystalline and mafic. The calc-silicate package originates from the Pretoria Group sediments, which hosts the BIC, and has undergone varying degrees of metamorphism and mineralisation. The metamorphism formed and allowed for the preservation of two rare minerals, namely wüstite and chlorospinel. Numerous tests were performed on the samples, including SEM point scans to identify these rare minerals and to better understand how the calc-silicate package was preserved in the BIC. A model was created to explain the occurrence of the calc-silicate slab and surrounding features. The previous model involved the slab rising up through the BIC, but the proposed model in this thesis is that the calc-silicate was part of the roof rock which then delaminated, and subducting into the ductile magma of the BIC.<br>Dissertation (MSc)--University of Pretoria, 2019.<br>Geology<br>MSc<br>Unrestricted

The Lower Devonian Voorstehoek Formation is a fossil-rich, siliciclastic unit (Ceres Subgroup, Bokkeveld Group, Cape Supergroup) in South Africa. This Emsian unit contains a highly endemic benthic fossil biota characteristic of the cool to cold water Malvinokaffric Realm of southwestern Gondwana. The palaeontological and sedimentological investigations of the Voorstehoek Formation suggest that deposition took place in a shallow marine environment within the storm influenced, proximal part of an offshore transition zone. A relatively diverse, ophiuroid–stylophoran assemblage, well-preserved in the Karbonaatjies obrution bed, was excavated at the study site in the Hex River Pass, Western Cape. In this study the taphonomy, taxonomy and the palaeoautecology of Palaeozoic ophiuroids and stylophorans was investigated using micro CT scans. Over 60 samples were scanned, manually segmented and stitched together to create a virtual 3D model of a portion of the Karbonaatjies obrution bed. This method allowed for the determination of the degree of fossil articulation, fossil orientation and faunal counts, without damaging the delicate echinoderm fossils. Furthermore, the ability to digitally analyse the fossil-rich bed has revealed an echinoderm assemblage composed of over 700 articulated ophiuroids dominated by a proposed new genus and species Gamiroaster tempestatis, over 145 articulated mitrate stylophorans Paranacystis cf. petrii Caster, 1954 and eight Placocystella africana (Reed, 1925). Taphonomic analysis of this ophiuroid–stylophoran assemblage indicates this obrution deposit formed due to rapid burial that smothered a potentially gregarious community during a single storm event. Additionally, the admixture of skeletal debris and intact echinoderms present in the Karbonaatjies obrution bed reflects a complex history with significant time-averaging. This unique assemblage provides a taphonomic window into the marine ecosystems of the Early Devonian, including the structure of an unusual, echinoderm-dominated benthic community that forms part of a much wider fossil biota from the Falkland Islands and Precordillera of Argentina, which formed part of SW Gondwana.

Thesis (MSc (Earth Sciences))—University of Stellenbosch, 2005.<br>The integration of whole-rock chemistry, heavy mineral chemistry, detrital zircon morphology and age dating has enabled high-resolution characterization of the Permian Laingsburg and Tanqua submarine fan provenance in the Karoo Basin, upper Ecca Group, South Africa. Geochemically, the Laingsburg and Tanqua sandstones are classified as greywacke and litharenite. The chemical index of alteration values for these sandstones suggest low to moderately weathered sources and a relatively cold climate. Abundant angular clastic grains and lithic fragments as well as the predominance of pristine zircons indicate a near provenance and a first cycle derivation. The investigated sandstones originated from a continental island arc and an active continental margin. The source is dominantly intermediate to felsic and includes tonalites, granodiorites, and adamellites or their volcanic equivalents.

The research examines the sedimentary environments and provenance of the Balfour Formation of the Beaufort Group (Karoo Supergroup) in the Eastern Cape Province, South Africa. This Formation occurs in the southeastern part of the Karoo Basin. It consists of sedimentary rocks, which are an alternating siltstone, shale and mudstone succession with subordinate interbedded sandstone and subsequently intruded by Karoo dolerite in the form of sills and dykes. ithostratigraphically, the Balfour Formation is subdivided into five units namely, from the base to the top, the Oudeberg, Daggaboersnek, Barberskrans, Elandsberg and Palingkloof Members. The Balfour Formation is overlain by the Katberg Formation. This study involved field investigations in the vicinity of the towns of Bedford and Adelaide with integrated stratigraphical, sedimentological and petrological studies. A geological map was constructed after field investigations. Lithofacies of the Balfour Formation that were studied are characterised by sandstone facies (Sh, Sm, St, Sr, Sp) and fine-grained sediments (Fl or Fsm) which reflect point-bar, cut-bank, channel and floodplain deposits. Lithologically, the Oudeberg Member consists of sandstone of which some units are internally massive alternating with thin laminated siltstone and mudstone. The Daggaboersnek Member is characterised by regular, generally non-lenticular, overall stratification, in the Barberkrans Member consists of sandstone lithosomes, while the Elandsberg Member is an argillaceous unit, similar to the Daggaboersnek Member. The Palingkloof Member is composed predominantly of red mudstone that can be used to distinguish the Balfour Formation from the overlying Katberg Formation, which consists predominantly of sandstone. The stratigraphic sequence displays two fining upward megacycles of sedimentary deposits with change in the sediment supply pattern from low-sinuosity to high-sinuosity river systems which reflect both braid and meandering deposits, respectively. Sedimentary structures in the sandstone units and the provenance of the Balfour Formation indicate that these deposits were produced by rivers flowing from the southeast with minor drift towards the northwest. According to the composition of the sediments and their sequence of deposition the Formation represents a fluvial environment. Mineralogical and grain size data from the sandstones of the various members of the Balfour Formation indicate the same source area of granitic, metamorphic and older sedimentary rocks and show no significant petrographic differences. The petrographic and geochemical investigations confirmed the sandstone to be feldspathic litharenite and ultralithofeldspathic sandstone. The palaeocurrent investigation indicates the main provenance to have been situated to the southeast of the Karoo basin. Heavy-mineral concentrations within the sandstones also give an indication that the source had a transitional arc plate tectonic setting.

In the recent years, the shale gas discourse has become central to discussions about future energy supply in South Africa. In particular, the Permian black shales of the Lower Ecca Group formations in the Karoo Basin are considered potential source rocks for shale gas. The research presented in this thesis advances the understanding of the shale gas potential of mainly the Prince Albert, Whitehill and Tierberg/Collingham Formations. These shale sequences were sampled from eight deep boreholes spread across the main Karoo Basin and geochemically analysed at the GFZ - Helmholtz Centre Potsdam, Germany. Three key questions guided the study, these are: (i) what is the lithology of the sequence; (ii) where in the basin do the shale sequences attain maximum thickness at optimum depth i.e. beneath 1000-1500m; and (iii) and their shale characteristics. To evaluate these, borehole core logging, petrology and organic geochemistry were used extensively. Petrology involved the use of thin section, scanned electron and transmission electron microscopy for mineralogy as well as the identification of sedimentary features, organic matter and nano-scale porosity. These were coupled with standard organic geochemistry techniques such as Rock Eval. analysis, open pyrolysis gas chromatography and thermovaporisation to quantify the free gas, total organic carbon (TOC), present-day gas generative potential and kerogen type. The results show that the Whitehill Formation, away from the CFB and not intruded by dolerite, has the most potential for shale gas. Microscopic studies of this pyritic black shale reveal the occurrence of porous amorphous matter, indicating thermal maturity within the gas generation zone (i.e. > 1.1 percent Ro, 120ºC). The TOC content is consistently high within the Whitehill (exceeding industry requirement of 2 percent), attaining maximum of 7.3 percent. The highest yields of free and desorbed gas, especially methane, were emitted within this formation (S1 and nC1 peaks); mostly within its dolomitic units. In addition, dissolution porosity within dolomite units of the Whitehill Formation was identified as the predominant type of porosity. Thus, it is deduced that the dolomitic units of Whitehill Formation potentially contain the greatest volumes of free gas. HI values attain maximum of 25 mg HC/g TOC, whereas the OI values 26 mg CO2/g TOC. Such low HI and OI values are typically attributed to the dominance of Type IV kerogen, and consistent with overmaturity. Open pyrolysis (GC) show the main the chemical compound of the organic matter to be m-p-xylene, consistent with a mix of Type III, Type I/II and Type IV kerogen. Lithologically, the Whitehill Formation is composed of ~ 35 quartz, 13 percent feldspar, 26 percent illite and ~ 23 percent dolomite with variable amounts of pyrite. The dominance of quartz is directly proportional to the brittleness of the rock. Thus it can be deduced that the Whitehill Formation is relatively brittle and therefore fraccable. Burial trends indicate increasing depth (from ground level) to the top of the Whitehill Formation towards the south and south-eastern portion of the basin. It is in the southern region where thicknesses of this black shale exceeding 50m occur at depths more than 1500m; 1000m beneath fresh water aquifers. It therefore concluded that Whitehill Formation in the southern portion of Karoo Basin, but away from the thermo-tectonic overprint of the Cape Orogeny, is the most probable shale gas reservoir in South Africa.

The Ecca Group of Karoo Supergroup is a sedimentary rock sequence that deposited between the Late Carboniferous (Dwyka Group) and the Late Permian-Middle Triassic (Beaufort Group). The Ecca Group investigated in this study is situated in the Eastern Cape Province of South Africa and it comprises mainly of shales, mudstones, siltstones and sandstones. The Ecca Group sequence contains considerable carbon content and suitable thickness to make it an ideal target for shale gas exploration. Previous studies put more emphasis on the geology and stratigraphy of the Ecca Group, this study revised the stratigraphy, and put new insight on the petrography, depositional processes, sedimentary facies, provenance, paleoweathering, tectonic setting, subsidence rates and history, electrical resistivity, source rock characteristics and diagenesis of the potentially feasible sandstone and mudrock reservoir rocks of the Ecca Group. Based on the lithological features, sedimentary structures and facies characteristics, the stratigraphy of the Prince Albert, Whitehill, Collingham and Fort Brown Formations of the Ecca Group is now subdivided into two informal members each, i.e. Lower Member and Upper Member. Furthermore, the Ripon Formation is now subdivided into three informal members. Each member has been asigned a lithological name. The grain size parameters show that most of the Ecca Group sandstones are very fine to fine grained, poorly to moderately well sorted, mostly near-symmetrical and mesokurtic in grain-size distribution. The linear discriminant function analysis is dominantly indicative of turbidity current deposits under deep marine environment for Prince Albert, Whitehill and Collingham Formations, shallow marine environment for Ripon Formation, while the Fort Brown Formation is lacustrine-deltaic deposits. Modal composition analysis and petrography studies revealed that the detrital components of the sandstones are dominated by monocrystalline quartz, feldspar and lithic fragments. The sandstones are compositionally and texturally immature and can be classified as feldspathic wacke and lithic wacke. The provenance analysis revealed plutonic and metamorphic terrains as the main source rocks with minor debris derived from recycled sedimentary rocks. The detrital modal compositions of these sandstones are related to back arc to island and continental margin of tectonic setting. Based on the detailed sedimentological analyses of outcrop and borehole data, fourteen lithofacies were identified and seven facies associations (FAs) were recognised. The facies associations are: FA 1: Shale and mudstones intercalated with siltstones, FA 2: Carbonaceous shale, mudstone with subordinate chert and sandstone, FA 3: Mudstones rhythmite with thin bedded mudstone and lenticular siltstone, FA 4: Greyish medium bedded sandstone intercalated with laminated mudstone, FA 5: Dark-grey medium to thick bedded mudstone and siltstone, FA 6: Thin to medium bedded sandstone alternated with thin bedded carbonaceous mudstone, and FA 7: Varved mudstone rhythmite intercalated with siltstone and minor sandstone. Sedimentological characteristics of the identified facies associations indicate four deposition environments, namely, deep marine basin, turbidite, shallow marine and lacustrine environments, which constitute a gradually regression sequence as a result of sea-level dropping and shallowing of the basin during the developmental processes. Geochemical analysis of the Ecca mudrocks and sandstones revealed that the rocks are of quartzose sedimentary provenance, suggesting that they were derived from a cratonic interior or recycled orogen. The petrography and geochemistry of the sandstones indicated that the source areas are composed of plutonic and metamorphic rocks with a minor component from sedimentary rocks. The geochemical diagrams and indices of weathering suggested that the granitic source rocks underwent moderate to high degree of chemical weathering. The tectonic setting discrimination diagrams support passive continental margin setting of the provenance.

A traverse through the Balfour Formation was chosen in the area around the towns of Fort Beaufort and Alice in the Eastern Cape Province. The main objectives of the study were to map the lithological variations within the Balfour Formation and to distinguish it from the underlying Middleton Formation and the overlying Katberg Formation. A combined desktop, field and laboratory approach was used in this study. Aerial photographs, satellite images and digital topographical maps formed the basis of the desktop work. After desktop mapping, a number of field traverses were measured through the study area. Sedimentary structures were observed, photomosaics were done, stratigraphic sections were measured and samples were collected for thin sectioning, heavy mineral separation and major, trace and REE analysis. Sedimentological development of the Balfour Formation has been outlined in relation to its provenance during the Late Permian. Lithological variation of the Balfour Formation is characterised by alternating sandstone-dominated and mudstone-dominated members. Arenaceous Oudeberg and Barberskrans Members are contain facies ranging from intraformational conglomerates (Gmm), massive sandstones (Sm & Ss), horizontally laminated sandstones (Sh), planar and trough cross-bedded sandstones (Sp, Sl & St), trough cross-laminated sandstones (Sr) and fine-grained sediments (Fm & Fl), whereas the mudstone dominated members are characterised by the facies Fm and Fl. Lithofacies together with bedforms observed in the Balfour Formation were used in architecturalelement analysis. Sandstone–rich members are dominated by channel fill elements such as LS, DA, SB, LA and CH, whereas the fine-grained component consists of mainly, FF iii element. The mudstone-dominated members contain FF, CS and LV elements, with LA, SB and CH in the subordinate sandstones. Petrography, geochemistry and palaeocurrent analysis indicated that the source of the Balfour Formation was to the south-east and the rocks had a transitional/dissected magmatic arc signature. This led to the postulation of the Karoo Basin to have developed in a retro-arc foreland basin where there was supralithospheric loading in the Cape Fold Belt due to a compressional regime initiated by the subduction of Palaeo-Pacific plate underneath the Gondwana plate. The tectonic loading was episodic with eight major paroxysms affecting the Karoo Supergroup. The Balfour Formation coincides with the fourth paroxysm, this paroxysm in turn consists of two third-order paroxysm that initiated the deposition of the Oudeberg and Barberskrans Members in low sinuosity streams. Each paroxysm was followed by a period of quiescence and these resulted in the deposition of the Daggaboersnek, Elandsberg and Palingkloof Members in meandering streams. Depositional environments were determined mainly from the sedimentary structures and 3D architecture of the rock types. Sandstone rich members were formed by seasonal and ephemeral high energy low sinuous streams whereas the fine-grained rich members were formed by ephemeral meandering streams. Palaeoclimates have been equated to the present temperate climates; they were semi-arid becoming arid towards the top of the Balfour Formation. This has been determined geochemistry (CIA), sedimentary structures and other rock properties like colour.

The Vanrhynsdorp Group is a mainly fluvio-marine siliclastic succession that outcrops in the northwestern part of South Africa. The critical Precambrian-Cambrian boundary falls within the group, however the depositional environments across the boundary, its exact stratigraphic position and nature are unresolved. The group was deposited in the Vanrhynsdorp Basin, which has been shown to be the southernmost extension of the Nama Foreland Basin. Consequently, the Vanrhynsdorp Group has been correlated with the world-famous Nama Group, which features diverse Ediacaran-Cambrian fossils. To date, no body fossils have been discovered in the Vanrhynsdorp Group. Through U-Pb dating of detrital zircons using LA-ICP-MS, radiometric ages for the middle part of the Vanrhynsdorp Group (Besonderheid Formation) were obtained in a preliminary study of this project. The radiometric data, yielding a maximum depositional age of 524 to 528 Ma from the youngest zircon grain population, indicated that the Precambrian-Cambrian boundary is stratigraphically lower in the group than it was thought before. To further constrain the age of the lower Vanrhynsdorp Group, and by extension the position of the Precambrian-Cambrian boundary, several detrital zircon samples were processed for age determination from the succession in this study. In addition, using sedimentary facies analysis, the lateral and vertical facies variation in this lower part of the group were (re)documented in order to refine the palaeoenvironmental setting. The current results suggest a dominantly shallow marine, partly storm-dominated depositional environment for the lowermost units as opposed to the previous interpretations of dominantly alluvial settings. Because of the global importance of the Ediacaran-Cambrian transition for diversification of marine biota in the Cambrian, addressing these palaeoenvironmental inconsistencies is the vital outcome of this study. By integrating our sedimentological and geochronological results, the project presents an improved understanding of the depositional history of the Vanrhynsdorp Group during the critical Ediacaran-Cambrian transition.

The continental red bed succession of the main Karoo Basin in South Africa and Lesotho, the Elliot Formation (Stormberg Group, Karoo Supergroup), is a significant stratigraphic unit for the regional and global understanding of the Late Triassic - Early Jurassic evolution of terrestrial vertebrate faunas, however, the temporal resolution of its biostratigraphy is inadequate for detailed regional and global correlations. The main aim of this dissertation is to build a more comprehensive chronostratigraphic framework of the Late Triassic - Early Jurassic Elliot Formation by combining and constraining its biostratigraphy with new results obtained using magnetostratigraphic techniques. This dissertation presents magnetostratigraphic data from ten measured stratigraphic sections in the Elliot Formation across the main Karoo Basin in South Africa and Lesotho.

Thesis (PhD)--University of Stellenbosch, 2004.<br>ENGLISH ABSTRACT: Foreland basins commonly fill with sediment derived from the adjacent fold/thrust belt, providing a relatively simple source-to-basin configuration. However, that is not true for the early southwestern Karoo Basin, since the composition of the Ecca Group sedimentary rocks do not match the composition of the adjacent fold/thrust belt. The southwestern Karoo Basin is bordered to the west and south by the Cape Fold Belt (CFB) and provides the opportunity to study the linkage between its early structural evolution and deposition in the two spatially and temporally distinct Tanqua and Laingsburg depocentres. The CFB was formed when the early Palaeozoic passive continental margin, which formed a large section of the southern edge of Gondwana, evolved into an active convergent margin during the late Palaeozoic. Orogenesis resulted in a northwest-trending Cedarberg branch and an eastwest-trending Swartberg branch. The oroclinal bend between the two branches includes large-scale northeast-trending syntaxis structures, such as the Hex River and Baviaanshoek anticlinoria, which influenced the sedimentation path into the basin. Spectral gamma ray (SGR), mineralogical and geochemical studies of exposed rocks from the Tanqua and Laingsburg depocentres indicate a near uniform provenance for both, dominated by granitic and metamorphic material derived from a provenance seemingly far beyond the CFB. SGR data, combined with lithology, show that regional stratigraphic correlation is possible in the Skoorsteenberg, Kookfontein and Waterford Formations in the Tanqua depocentre. The same is true for the Laingsburg and Fort Brown Formations in the Laingsburg depocentre. There are no major changes in the SGR data set between the successive sandstone or shale units that could imply different origin, and no distinct signals in the SGR pattern of the shale intervals that could potentially correspond to maximum flooding surfaces. The Tanqua and Laingsburg depocentre sandstones are very fine- to lower mediumgrained, tightly packed, poorly to well sorted, and have undergone mechanical compaction and pressure solution. The mineralogical composition and texture of these sandstones suggest that they have undergone high-grade diagenesis to low-grade regional burial metamorphism to the lower greenschist facies (250 ± 50ºC; ~2 kbars). They are mineralogically and geochemically classified as lithic arenites and greywackes, and the Tanqua depocentre sandstones are slightly more mature than the Laingsburg depocentresandstones. REE patterns for the Tanqua and Laingsburg depocentre sandstones are similar, suggesting that both form part of the same evolutionary pattern and that the sediments have one common origin, i.e. a provenance predominantly composed of granitic material. Homogenous εNd-values for all sandstone samples of around –5 at the time of deposition indicate that there is little or no variation in provenance between the Tanqua and Laingsburg depocentre sediments. TCHUR model ages of 0.70 to 0.95 Ga, and TDM model ages of 1.19 to 1.49 Ga, resulted from a mixture of Archaean and Proterozoic material in unknown proportions. The most likely source terrane is thought to be the North Patagonian Massif. The latter show Nd isotopic compositions corresponding to an average εNd-value of -5 at 265 Ma.<br>AFRIKAANSE OPSOMMING: Voorlandkomme word oor die algemeen gevul met sediment afkomstig van die aanliggende plooigordel, wat lei tot ‘n redelik eenvoudige brongebied-tot-afsettingskom konfigurasie. Dit is egter nie van toepassing vir die vroeë suidwestelike Karookom nie, aangesien die samestelling van die Ecca Groep sedimentêre gesteentes nie ooreenstem met die samestelling van die aanliggende plooigordel nie. Die suidwestelike Karookom word aan die weste en suide begrens deur die Kaapse Plooigordel en bied die geleentheid om die verwantskap tussen die vroeë strukturele evolusie en afsetting in die twee ruimtelik en temporeel afsonderlike Tankwa en Laingsburg subkomme te bestudeer. Die Kaapse Plooigordel het gevorm toe die vroeë Palaeosoïkum kontinentale grens, wat ‘n groot deel van die suidelike grens van Gondwana was, ontwikkel het tot ‘n aktiewe konvergerende grens gedurende die laat Palaeosoïkum. Orogenese het gelei tot die vorming van ‘n noordwes-strekkende Sederberg tak en ‘n ooswes-strekkende Swartberg tak. Die oroklinale buig tussen die twee takke sluit grootskaalse noordoosstrekkende sintaksis strukture in, soos die Hex Rivier en Baviaanshoek antiklinoria, wat die sedimentasie rigtings na die kom beïnvloed het. Spektrale gammastraal (SGR), mineralogiese en geochemiese studies op die dagsome van die Tankwa en Laingsburg subkomme dui ‘n byna identiese brongebied aan vir beide, oorheers deur granitiese en metamorfe materiaal vanaf ‘n brongebied oënskynlik vêr vanaf die Kaapse Plooigordel. SGR data, gekombineer met litologie, dui aan dat dit moontlik is om regionale stratigrafiese korrelasies in the Skoorsteenberg, Kookfontein en Waterford Formasies in die Tankwa subkom te maak. Dieselfde geld vir die Laingsburg en Fort Brown Formasies in die Laingsburg subkom. Daar is geen groot veranderinge, wat ‘n verskil in oorsprong kan aandui, in the SGR datastel tussen die opeenvolgende sandsteen of skalie eenhede nie, en ook geenuitstaande tekens in the SGR patroon van die skalie-intervalle wat moontlik kan ooreenstem met ‘n maksimum vloedingsvlak nie. Die Tankwa en Laingsburg subkom sandsteenlae is baie fyn- tot laervlak mediumkorrelrig, dig gekompakteer, swak tot goed gesorteer, en het meganiese kompaksie en drukoplossing ondergaan. Die mineralogiese samestelling en tekstuur van hierdie sandsteenlae dui daarop dat hulle hoë-graadse diagenese tot lae-graadse regionale begrawingsmetamorfose tot laervlak groenskis fasies (250 ± 50ºC; ~2 kbars) ondergaan het. Hulle word mineralogies en geochemies geklassifiseer as litiese areniete en grouwakke. Die Tankwa subkom sandsteenlae is effens meer volwasse as die Laingsburg subkom sandsteenlae. Die lantanietgroep patroon vir die Tanqua en Laingsburg sandsteenlae is eenders, wat aandui dat beide deel gevorm het van dieselfde evolusionêre ontwikkeling en dat die sedimente een gesamentlike oorsprong gehad het, naamlik ‘n brongebied bestaande hoofsaaklik uit granitiese materiaal. Homogene εNd-waardes van ongeveer –5 by tye van afsetting vir al die sandsteen monsters dui daarop dat daar min of geen verandering in brongebied vir die Tankwa en Laingsburg subkom sedimente was nie. TCHUR model ouderdomme van 0.70 tot 0.95 Ga, en TDM model ouderdomme van 1.19 tot 1.49 Ga, is afkomstig van ‘n mengsel van Argeïese en Proterosoïese materiaal in onbekende hoeveelhede. Die mees waarskynlike brongebied is die Noord Patagoniese Gebergtes. Dit wys Nd isotopiese samestellings wat ooreenstem met ‘n gemiddelde εNd-waarde van –5 by 265 Ma.

The Karoo Basin of South Africa holds an estimated 906 billion to 11 trillion cubic meters of unconventional shale gas within the shales of the Whitehill and Collingham formations of the Ecca Group. Evaluation of this potential resource has been limited due to the lack of exploration and a scarcity of existing drill core data. In order to circumnavigate this problem this study was undertaken to evaluate the potential target horizons exposed in outcrops along the southern portion of the Karoo Basin, north of Grahamstown in the Eastern Cape Province. Detailed field logging was done on the exposed Whitehill and Collingham formations as well as a possible conventional sandstone (turbidite) reservoir, the Ripon Formation, along road cuttings of the Ecca Pass. Palaeocurrent data, jointing directions and fossil material were also documented. Samples were analysed for mineralogy, porosity, permeability, and total organic carbon content (TOC). The extensively weathered black shales of the Whitehill Formation contain a maximum TOC value of 0.9% and the Collingham Formation shales contain a maximum TOC value of 0.6%. The organic lithic arkose sandstones of the Ripon Formation are classified as ‘tight rock’ with an average porosity of 1% and an average permeability of 0.05 mD. The Whitehill Formation in the southern portion of the Karoo Basin has experienced organic matter loss due to low grade metamorphism as well as burial to extreme depths, thus reducing shale gas potential. The Ripon Formation is an unsuitable conventional reservoir along the southern basin boundary due to extensive cementation and filling of pore spaces.

Thesis (MSc)--Stellenbosch University, 2005.<br>ENGLISH ABSTRACT: Fan System 5 forms the uppermost submarine fan system of the Permian-age Tanqua Fan Complex (Ecca Group) of the southwestern Karoo Basin. It is the most widespread system and represents the final phase of fan deposition in the Tanqua sub-basin. Depositional characteristics differ markedly from the rest of the fan systems, mainly because it lacks sedimentary features indicative of a single point source basin floor fan. The entire system consists of six different stages of fan growth and development in the lower slope settings. A hypothetical model was composed for Fan System 5 to understand the spatial/temporal distribution of reservoir and seal facies in slope turbidite settings. The facies vary from massive amalgamated sandstone beds to thin-bedded, ripple cross-laminated sand and siltstone beds. A thick shale unit identified as a regional marker layer overlies Fan System 5. lts base is defined by the presence of a regionally developed 20 cm thick hemipelagic shale unit. Six sand-rich units with channel-complexes are present in the Klein Hangklip, Groot Hangklip, Kalkgat, Tongberg, Skoorsteenberg and Blauwkop localities. The facies characteristics in the southernmost outcrops of Fan System 5 (Groot Hangklip, Tongberg and Kalkgat) reflect deposition in a lower slope setting where local structural control seems to have played a major role in the distribution and regional development of channel-fill and overbank depositional elements. The channel-fills are arranged in vertical to off-set stacking patterns and are comprised of massive, amalgamated [me to very fine-grained sandstone units up to 30 m in thickness. They are separated by thinner sandstone/siltstone units of varying thickness. The channelization displayed by the more proximal outcrops are interpreted to represent an upper fan, deposited in a lower- to mid-slope setting. In contrast to the channel-fill deposits at Skoorsteenberg, Klein Hangklip and Groot Hangklip, ripple cross-laminated overbank deposits, associated with smaller channel-fill units, predominate in the northeastern and eastern parts of the outcrop area. Massive- and thinbedded frontal sheet sandstones constitute the down-dip extensions to the most northern outcrops of Fan System 5. Highly erosive, stacked base-of-slope channel complexes, seemingly controlled by subtle early structural features, were able to construct significant thicknesses of regionally well-developed overbank deposits, marginal to the channel complexes. These facies changes occur over relatively short distances, which hold significant implications for the prediction of and the heterogeneity of reservoir facies in slope settings. Gradients are much steeper in the lower slope to mid-slope area than on the proximal basin floor. The occurrence of soft-sediment deformation in the overbank and upper parts of the channel-fill deposits supports a slope origin. Weakly developed wave-ripple marks in the uppermost layers of Fan System 5 further indicate that water depths approached wave base prior to deposition of the upper markerbed shales. Paleotransport for Fan System 5 was towards the north, northeast and east. The palaeocurrent directions of the channel-fill complexes in Klein- and Groot Hangklip seem to roughly correspond to the structural trend of synclinal depressions in this area. However, the effect and influences of basin floor topography and structural features on deposition were determined to be minimal on the regional development and local facies control of the fan.<br>AFRIKAANSE OPSOMMING: Waaiersisteem 5 vorm die laaste submarine waaiersisteem van die Perm-ouderdom Tankwa Waaierkompleks (Ecca Groep) in die suidwestelike Karoo-kom. Dit vorm die mees wydverspreide sisteem en verteenwoordig ook die fmale fase van waaierafsetting in die Tankwa sub-kom. Afsettingseienskappe verskil aansienlik van die onderliggende waaiersisteme, omdat kenmerkende sedimentêre eienskappe van 'n enkele toevoer bron ontbreek. Die hele sisteem bestaan uit ses verskillende periodes van waaiergroei en ontwikkeling in die laer kornhelling omgewmgs. 'n Voorspellingsmodel is opgestel vir Waaiersisteem 5 om die ruimtelike/temporele verspreiding van die reservoir en seël fasies in kornhelling turbidiet omgewings te kan verstaan. Hierdie fasies varieer van massiewe, geamalgameerde sandsteen tot dun gelaagde riffel- lamineerde sand- en sliksteenlae. 'n Dik regionale skalie eenheid oorlê Waaiersisteem 5 en vorm die boonste merkerlaag. Die basis word onderlê deur 'n 20 cm dik regionaalontwikkelde hemipelagiese skalie laag wat die onderste merkerlaag vorm. Ses sandige eenhede met geassosieerde kanaalkomplekse is onderskeidelik teenwoordig in: Klein Hangklip, Groot Hangklip, Kalkgat, Tongberg, Skoorsteenberg en Blauwkop omgewings. Die fasies-eienskappe van die mees suidelike dagsome van Waaiersisteem 5 (Tongberg, Groot Hangklip en Kalkgat) toon afsetting in 'n laer kornhelling omgewing, waar plaaslike tektoniese effekte moontlik 'n groot rol gespeel het in die verspreiding en regionale ontwikkeling van die kanaalvulsels en geassosieerde oewerwal-afsettings. Die gestapelde, wegstand kanaalvulsels-afsettings bestaan uit massiewe, geamalgameerde fyn tot baie fynkorrelrige sandsteen eenhede, wat diktes tot ongeveer 30 m kan bereik. Dit word van mekaar geskei deur dun sandsteenlsliksteen eenhede van afwisselende diktes. Die kanaal komplekse in die mees proksimale dagsome word interpreteer as 'n bo-waaier, wat afgeset is in 'n laer- tot middel kornhelling omgewmg. In teenstelling met die kanaalvulsels in die Skoorsteenberg, Klein Hangklip en Groot Hangklip omgewings, domineer riffel kruisgelamineerde oewerwal-afsettings, geassoseer met klein kanaalvulsels, die noordoostelike en oostelike dagsome van Waaiersisteem 5. Massiewe en dungelaagde frontale plaat sandstene, kom voor in die distale helling-omgewings in die mees noordelike dagsome van Waaiersisteem 5. Hoogs eroderende, gestapelde kanaalkomplekse, aan die basis van die komhelling wat moontlik beheer is deur vroeë komvloer topografie, was die oorsaak vir regionaal goed-ontwikkelde oewerwalafsettings. Hierdie fasies-verandering vind plaas oor 'n baie kort afstand wat betekenisvolle gevolge inhou vir die voorspelling van heterogeniteit van petroleum reservoir fasies in komhelling afsetting-omgewings. Die gradiënt vir die laer komhelling tot mid-komhelling omgewings is baie steiler as die distale komvloer omgewings. Die voorkoms van sagte-sediment deformasies in die oewerwal en boliggende dele van die kanaalvulsels weerspeël 'n moontlike komhelling omgewing. Swakontwikkelde golfriffelmerke in die boonste lae van Waaiersisteem 5 dui 'n waterdiepte aan wat nabyaan golf-basis is, voordat dit deur diepmariene skalies oorlê word. Paleovloeirigtings vir Waaiersisteem 5 was in 'n noord, noordoostelike en oostelike rigting. Die paleovloeirigting vir die Klein- en Groot Hangklip kanaalkomplekse stem min of meer ooreen met die strukturele grein van die sinklinale laagtes in die omgewing. Die effek en beheer van komvloer topografie en ander strukturele faktore op afsetting was minimaalop die regionale ontwikkeling en plaaslike fasies verspreiding van die waaier.

The Permo-Triassic lower Beaufort Group fluvial deposits extend over 100s of kilometres within the Karoo Basin, South Africa. A detailed study of the depositional architecture and stacking patterns of sand bodies within a 900 m thick succession has enabled interpretation of the controls on ancient river channel and overbank processes. Facies include very fine- to medium-grained sandstone, intra-formational conglomerate, mudstone and palaeosols. Channel-belts are dominated by upper flow regime structures, consistent with a flashy to ephemeral fluvial system. The overbank deposits comprise splays interbedded with purple, green and grey mudstone; these floodplain colour changes signify water table fluctuations. A hierarchy of channel-related elements has been established that recognises beds, bedsets, storeys, channel-belts, complexes and complex sets. Each channel-belt may be single- or multi-storey, whereby one storey represents the complete cut and fill cycle of a single migrating river, comprising bar accretion elements and channel-abandonment fill. The abandonment fill elements often consist of heterolithic plugs of climbing ripple-laminated very fine-grained sandstone, or interbedded claystone with siltstone. The Beaufort channel-belts preserve either lateral- or downstream-accretion patterns, or a combination. Each belt has either a lenticular or tabular geometry, recognisable by an erosional base overlain by intra-formational conglomerate lag and barform deposits. Genetically related channel-belts cluster to form complexes, of which two broad styles have been identified: Type A) laterally and vertically stacked channel-belts, and Type B) sub-vertically stacked channel-belts. There is evidence of localised clustering of sub-vertically stacked channel-belts adjacent to extensive overbank mudstone deposits. The apparent lack of a well-defined ‘container’ surface with mappable margins, suggests that this stacked channel-belt architecture represents an avulsion complex rather than a palaeovalley-fill. The lateral and stratigraphic variability in fluvial-overbank architecture is interpreted as the interplay of several controls. Allogenic forcing factors include, tectonic subsidence that influences accommodation, sediment supply, and high frequency climate cycles associated with the flashy discharge regime and expressed in the mudrock colour changes and distribution of palaeosols. The depositional river style, variability in channel-belt stacking patterns and compensational stacking of some channel-belt/splay complexes is interpreted to be the result of autogenic channel avulsion, supported by an absence of significant erosion. The relative merits of basin-axial trunk river and distributive fluvial system (DFS) models are assessed from detailed architectural and stratigraphic outcrop studies.

>Magister Scientiae - MSc<br>The Proterozoic Namaqua-Natal Province comprises highly deformed rocks of medium to high grade metamorphism and is bordering the Archean Kaapvaal Craton to the west, south and east in South Africa. The sector to the west of the Craton, namely the Namaqua Sector, is structurally complex and subdivided from west to east into the Bushmanland Subprovince, the Kakamas and Areachap terranes of the Gordonia Subprovince and the Kheis Subprovince. The prominent Neusberg Mountain Range, with exposures to the north and south of the Orange River in the Kakamas Terrane constitutes evidence of crustal shortening as a result of continental collision of the Namaqua Sector block with the Kaapvaal Craton during the Namaquan Orogeny. The Mesoproterozoic Korannaland Group in the Kakamas Terrane is affected by faulting, folding and shearing.

The vegetation supported by the Witteberg and Dwyka Groups south of Worcester is a diverse mosaic of fynbos-, renosterveld- and succulent karoo vegetation units sustained by a winter-rainfall pattern. Elytropappus rhinocerotis (renosterbos) dominated plant communities are found on finer grained soils derived from the various mudrock-dominated formations of the Witteberg Group, a Passerina truncata (gonnabos) dominated shrubland with large Protea shrubs and / or small Protea trees where the substrate is largely influenced by the sandstone-dominated formations of the Witteberg Group, a grass dominated Capeochloa arundinacea (Olifantgras) shrubland where both mudrock-dominated and sandstone-dominated formations influence the substrate as a result of folding, a karoo Hirpicium integrifolium (Haarbossie) dominated shrubland where succulents are in abundance on the Dwyka tillite, and a distinct Thamnochortus bachmannii restio-dominated sandveld in areas where deep aeolian sand had accumulated. The differences in vegetation communities are mainly based on geology with consequent soil characters and degree of rockiness, as well as topography, moisture availability and the water holding capacity of the soil. Although slope, aspect and elevation can sometimes be associated with specific plant communities, geology, soil pH and rock cover are the principal elements responsible for shaping the vegetation mosaic. Rather than a broad ecotone, the vegetation of the study area is understood as a complex mosaic mountain vegetation entity.<br>Environmental Sciences<br>Ph. D. (Environmental Sciences)

A Dissertation Submitted to the Faculty of Science; University of the Witwatersrand, Johannesburg; for the Degree of Doctor of Philosophy<br>A volcanological study of the Onverwacht Group in the southwestern part of the Archaean (-3.5 - 3.2 Ga) Barberton greenstone belt (BGB), South Africa, shows that volcanic extrusion rates of the Komati and Hooggenoeg Formations must have been high to have maintained the degree of submarine sheet flooding that is evident. It is concluded that the volcanic attributes of the Komati and Hooggenoeg Formations are not typical of MOR crust, as has been claimed, but rather closely resemble those of modern oceanic plateaus. The shear-zone-bound basal contact of the Komati Formation suggests that the top of the ancient oceanic plateau was allochthonously emplaced and delaminated from its basal (intrusive) part. (Abbreviation abstract)<br>AC2017

M.Sc.<br>Known outcrops of the supracrustal Mesoarchean Mozaan Group of the Pongola Supergroup occur in north-eastern Kwazulu-Natal and southern Mpumalanga in South Africa, and southern Swaziland. Outcrops of the Mozaan succession in Swaziland are preserved in the Ntungulu-Mahlangatsha and Kubuta-Mooihoek areas. The succession is composed of polymictic conglomerate, poorly sorted scour based quartzite, orthoquartzite, shale, iron-formation, polymictic diamictite and lava. In the Kubuta- Mooihoek area a 3000m thick succession is preserved and correlates almost bed for bed with that in the Hartland area in South Africa. The succession is preserved from the Dipka member of the Sinqeni Formation at the base to the Tobolsk lava at the top. The depositional environment ranges essentially between fluvial and marine with two distinct glaciogenic diamictite units and one unit of lava near the top of the succession. Seven unconformity bounded sequences are recognised in the succession and from these a relative sea-level curve could be constructed. Trace element geochemistry of the shale reveals that the source area was predominantly felsic with a mafic component probably derived from the uplifted pre-Pongola granitoids and Nsuze Group. The petrography of the quartzite in the succession suggests a change in provenance from a low-lying deeply weathered to uplifted moderately weathered source area higher up in the stratigraphy. Part of the tectonic uplift may have been associated with isostatic rebound related to melting of continental glaciers. The Tobolsk lava is a continental flood basalt also possibly related to a tectonic uplift event. There are indications of sediment recycling in the upper part of the succession where conglomerates are predominantly composed of chert clasts A pretectonic quartz porphyry sill, folded with the strata, provides an upper age limit of 2837±5 Ma for the deposition of the Mozaan Group. The Mooihoek granite (2824±6 Ma) that intrudes and deforms the synclinal structure along its eastern flank, provides an upper age limit of the folding event. This suggests that the deformation of the Mozaan succession took place in the intervening 13 Ma period between 2824 and 2837 Ma ago.

The fluvio-lacustrine rocks of the Beaufort Group, South Africa have long been known for their tetrapod fossil record, which is the richest and most complete Middle Permian to Middle Triassic record for any terrestrial sequence in the world. The abundance of fossil material has enabled the Beaufort Group to be biostratigraphically subdivided into between 8 and 10 tetrapod assemblage zones, of which the lowest three (Eodicynodon, Tapinocephalus and Pristerognathus) are attributed to the Middle Permian. These lower assemblage zones record the earliest therapsiddominated faunas and, because they were recorded during a largely uninterrupted period of deposition, make the Beaufort Group the only place in the world where biodiversity change through the terrestrial Middle Permian can be effectively studied. In the last two decades, much interest has focused on an extinction of marine invertebrates at or close to the end of the Middle Permian (Guadalupian epoch), but the existence of a concurrent extinction in the terrestrial realm is contentious. The Beaufort Group is already well known to record the Permo-Triassic Mass Extinction but it also records an earlier extinction at the top of the Tapinocephalus Assemblage Zone (AZ). This extinction is very poorly understood but recent radiometric dates for many Permian assemblage zones of the Beaufort Group have confirmed a Middle Permian age for Eodicynodon, Tapinocephalus and Pristerognathus assemblage zones and suggest that the end-Tapinocephalus AZ extinction may coincide with the marine extinctions. A recently produced GIS database that accommodates all Beaufort Group fossil material curated in South Africa formed the basis on which the stratigraphic range of individual specimens was calculated. To put the fossil localities in a stratigraphic context, lithostratigraphic information was retrieved from the literature and extensive fieldwork was conducted, which measured stratigraphic sections in key areas and traced the surface outcrop of lithostratigraphic units. In order to compensate for lateral variations in lithostratigraphy, the basin was split into sectors, each represented by a stratigraphic section. The stratigraphic ranges of fossil specimens and, subsequently, of genera and families could then be calculated and a workable biostratigraphic subdivision of the Middle Permian Beaufort Group proposed. The Abrahamskraal Formation, which forms the majority of the Middle Permian Beaufort sequence, can be divided into six lithostratigraphic members based on the occurrence of sandstone ‘packages’. These members were traced laterally across the Basin and their correspondence with fining-upwards cycles was refined and correlated with the newly defined biostratigraphic units. This refined two-pronged stratigraphic subdivision allowed the recognition of a waning period of subsidence in the proximal sector of the Karoo Basin during the Middle Permian. Stratigraphic ranges of individual genera were found to be far more heterogeneous than previously recognised. Dicynodont genera are useful biostratigraphic indicators due to their relative abundance and well-defined stratigraphic ranges, while dinocephalians and pareiasaurs are clustered in the upper part of the Abrahamskraal Formation. The stratigraphic range of Eodicynodon extends further up in the Abrahamskraal Formation than was previously recognised. The Tapinocephalus AZ is restricted to approximately the upper fifth of the Abrahamskraal Formation and is characterised by advanced tapinocephalid dinocephalians and the pareiasaur Bradysaurus. Between these two biozones is a stratigraphic interval dubbed the mid- Abrahamskraal Formation Transition Zone, where both Eodicynodon and advanced tapinocephalids coexisted. A 75 % loss of generic diversity occurred between the upper Tapinocephalus AZ and the base of the Pristerognathus AZ, which corresponds to a stratigraphic interval between the mid-Karelskraal Member of the Abrahamskraal Formation and the mid- Poortjie Member of the Teekloof Formation. Several taxa that survive the end- Tapinocephalus AZ extinction, and are relatively common in the overlying Pristerognathus AZ (scylacosaurid therocephalians, the dicynodont genus Eosimops and the parareptile Eunotosaurus), all became extinct in the upper Poortjie Member at a time when generic originations are increasing. This suggests a second wave of extinctions in a similar fashion to that recorded at the Permo-Triassic boundary.

The Mesoproterozoic Bushmanland Subprovince of northwestern South Africa forms the western continuation of the transcontinental Namaqua-Natal Metamorphic Province, a crustal domain affected by the 1020-1220 Ma Namaquan Orogeny. Cross-cut by several large faults, the Bushmanland Subprovince can be subdivided into a southern Garies Terrain and northern Aggeneys Terrain. The supracrustal rocks of the Aggeneys Terrain (i.e. Bushmanland Group), comprise a thin (<1 km thick) metavolcano-sedimentary succession composed of a very consistent, shallow marine duplex of sandstone-shale to chemogenic metasedimentary and metavolcanic rocks that have undergone multiple phases of deformation and metamorphism. Since the discovery of the Broken Hill-type (BHT) mineralization in the Aggeneys-Gamsberg district (~440 Mt, 5.2% Cu+Zn+Pb) in the early 1970’s, controversy has persisted regarding the stratigraphy of the Bushmanland Group, its lateral correlation throughout the Aggeneys Terrain, environment and age of deposition, as well as classification and origin of its base-metal sulfide ± barite deposits. For these reasons, the present study primarily focuses on two aims, namely: (1) regionally based comprehensive lithostratigraphic, geochemical and geochronologic analysis of the Bushmanland Group to be used in the construction of a basin model; and (2) petrographic and geochemical analyses of Fe-Mn-rich rocks and barites to determine if they are related to base-metal mineralization and if so, to what extent. New lithostratigraphic data for the Bushmanland Group indicate that it can be subdivided into two subgroups and thirteen formations that are directly correlatable throughout the terrain as well as similar supracrustal successions in neighboring portions of the Namaqua Metamorphic Province. The base of the Bushmanland Group (Wortel Subgroup) comprises a thin (250-350 m thick) sequence of interbedded upward-coarsening psammo-pelitic schists and mature quartzite (i.e. meta-orthoquartzites) of the Namies Schist Fm., Pella Quartzite Fm., Bloemhoek Fm. and laterally equivalent Kangnas Fm. In contrast, the metasedimentary rocks of the unconformably overlying Kouboom Subgroup can be separated into facies terrains divided by the Pofadder-Tantalite Valley Shear Zone (PTV Shear Zone). West of the PTV Shear Zone the Kouboom Subgroup is characterized by a thin (205-225 m thick) succession of interbedded mature quartzites and pelitic schists. East of PTV Shear Zone the Kouboom Subgroup encompasses a thick (~1250 m thick) succession of calc-silicate rocks hosted by biotite to calc-silicate-rich schists and metagreywackes. The Koeris Fm., a variably thick (0-650 m) succession of psammitic schists, metaconglomerates and ortho-amphibolites unconformably overlies the Kouboom Subgroup. Geochemical provenance and detrital zircon core populations of the Wortel Subgroup suggest the metasedimentary rocks were derived from the Paleoproterozoic continental island arc rocks of the Vioolsdrift Intrusive Suite and Gladkop Suite, as well as an unidentified sedimentary/metasedimentary succession. Deposition took place in a passive continental margin environment between 1140 to 1650 Ma. In contrast, the unconformably overlying Kouboom Subgroup is characterized by larger plutonic derived zircons of the basement rocks to the Orange River Group, suggesting deposition in a tectonically active environment marked by repeated periods of tectonic uplift. In addition, new age constraints reveal that deposition in the upper part of the Kouboom Subgroup (possibly upper part of the Gams Fm.) was synchronous with emplacement of the Little Namaqualand Suite (~1190 Ma) into the lower portions, i.e. Wortel Subgroup, of the Bushmanland Group. The geochemical attributes and detrital zircon populations of metagreywackes from the Driekop Fm. suggest they were eroded from the newly exposed, i.e. fresh to poorly weathered, intrusions of the Little Namaqualand Suite, indicating a renewed period of tectonic uplift. Lastly, unlike the other lithologic units of the Bushmanland Group, the Koeris Fm. exhibits four detrital zircon age populations at 1125-1325, 1605-1695, 1730-1910 and 1935-2075 Ma. The older sub-populations indicate sediment derivation from various units of the Richtersveld Subprovince and Steinkopf Domain, while the younger sub-populations suggest derivation from various units in the Rehoboth Inlier of Namibia and the Gordonia Terrain to the east. The provenance signature of the younger subpopulation implies that deposition of the Koeris Fm. occurred after continental collision between the Rehoboth Inlier-Kaapvaal Craton and the Namaqua Metamorphic Province. With regards to the base-metal deposits of the Aggeneys-Gamsberg district, petrographic and geochemical analysis of the Bushmanland Group Fe-Mn-rich rocks suggests that they can be subdivided into several types: (1) primary Fe-Mn-rich metasedimentary rocks; (2) magnetite-amphibole-rich Fe-Mn-rich rocks; (3) coticules; and (4) epigenetic Fe-Mn-rich rocks. Primary Fe-Mn-rich metasedimentary rocks occur throughout the western and central portions of the study area and appear to have been formed through the deposition of Fe-Mn-rich hydrogenous precipitates in areas of localized sediment starvation. However, as illustrated by the primary Fe-Mn-rich metasedimentary rocks of the Lemoenpoort prospect, a syn-diagenetic, hot (>250°C), metalliferous hydrothermal fluids infiltrated and altered these hydrogenous Fe-Mnrich metasedimentary rocks, resulting in the deposition of base-metal sulfides, formation of magnetite-amphibolite-rich Fe-Mn-rich rocks, as well as hydrothermal alteration of the siliciclastic wall rocks to form coticules. The spatial restriction of epigenetic Fe-Mn-rich rocks to shear zones, high Fe2O3 T (ca. 65 wt %), low ΣREE (ca. 13 ppm), presence of recrystallized quartz crystals, elevated concentration of Cu in some occurrences and general similarities with some hydrothermal iron/iron-oxide copper-gold (IOCG) deposits, suggests that the epigenetic Fe-Mn-rich rocks may have formed during prograde metamorphism. Low concentrations of SrO (0.5 ± 0.2 wt %), highly radiogenic Sr/ Sr ratios (0.7164 ± 0.0028), elevated δ S (27.3 ± 4.9 ‰) and δ O (7.7 ± 3.1 ‰) values in the barites, as compared to contemporaneous Mesoproterozoic seawater, suggests precipitation of stratiform and stratabound barite layers in the Bushmanland Group occurred through mixing of an evolved continental crustal source and contemporaneous seawater sulfate, 87 86 34 18 modified by bacterial sulfate reduction. Most importantly, δ O values suggest possible minimum temperatures of formation ranging from 18 <150°C for the Gamsberg deposit to >250°C for occurrences in the Aggeneys area. These obvious differences in temperature of formation are in good agreement with the Cu-rich, Ba-poor nature of the sulfide mineralization characteristic of the Aggeneys deposits versus the Cu-poor, Ba-rich character of the Gamsberg deposit. In conjunction with this, the isotopic and petrographic arguments favor a sub-seafloor replacement model for the stratabound barite occurrences of the Aggeneys deposits, while at Gamsberg, deposition at the sediment-water interface as a true sedimentary exhalite appears more acceptable. Data obtained in the present study, combined with the results of previous investigations can be used to develop a comprehensive model for the geological evolution of the Aggeneys Terrain and Namaqua Metamorphic Province. The tectono-sedimentary evolution of the Aggeneys Terrain and Namaqua Metamorphic Province is marked by two important tectonic events separated by an episode of tectonic quiescence. Extrusion and deposition of the metavolcano-sedimentary rocks of the Orange River Group at 1908 Ma marks the start of the Orange River Orogeny. vii Prior to emplacement of the Vioolsdrift Intrusive Suite, the Orange River Group appears to have undergone a period of folding and low-grade metamorphism [D1/M1] that was subsequently followed by emplacement of the Main Phase Vioolsdrift Intrusive Suite roughly dated at 1890 Ma. Rapidly following emplacement of these intrusions, the lower crustal rocks of the Richtersveld Subprovince underwent a second, higher, amphibolite-facies metamorphic event [M1B] from 1870-1840 Ma. This event may have resulted in lower crustal melting and emplacement of the Gladkop Suite into an unknown package of metasediments or metasedimentary rocks south of the present day Orange River at roughly 1820 Ma. The Gladkop Suite was subsequently subjected to high-grade metamorphism at 1800 Ma. The Orange River Orogeny was terminated by emplacement of the Late Phase Vioolsdrift Intrusive Suite at approximately 1765 Ma and later northward-directed thrusting. Following termination of the Orange River Orogeny, deposition of the Bushmanland Group began in a tectonically stable environment marked by punctuated periods of tectonic activity that lasted until emplacement of the Little Namaqualand Suite at 1190 Ma. The detrital zircon populations of the Pella Quartzite Fm. and Koeris Fm. support (a) regional correlation of these stratigraphic units throughout the study area, (b) confirms sediment derivation from various local source terrains and (c) suggests a maximum depositional age of 1650 Ma. Furthermore, new age constraints reveal initiation of the O’okiepian Episode (Namaquan Orogeny), characterized by regional-scale mid- to high-grade contact metamorphism, was synchronous with emplacement of the Little Namaqualand Suite and deposition of the upper Kouboom Subgroup. Furthermore, the detrital zircon populations for the Driekop Fm. (upper Kouboom Subgroup) contain a large population of 1190 Ma (i.e. O’okiepian-age) detrital cores, suggesting a renewed period of tectonic uplift. Analogously, age constraints for the Koeris Fm. indicate a maximum depositional age of 1130 Ma, as well as derivation from a number of local and exotic source terrains indicating that deposition of the Koeris Fm. must have occurred in response to continental collision between the Rehoboth Inlier-Kaapvaal Craton and the Namaqua Metamorphic Province. Furthermore, these new age constraints also constrain the timing of D2-D3 deformation to between 1130-1080 Ma and regional peak metamorphism to 1020- 1040 Ma.<br>Prof. N.J. Beukes Prof. J. Gutzmer

M.Sc.<br>The sedimentary succession of the Paleoproterozoic Pretoria Group is very important for understanding Earth’s ancient history. It represents a time of extreme environmental changes on Earth, from global ice-ages to hot-houses. However, the genetic stratigraphy of the succession is poorly understood so that the stratigraphic relationships between the events remain uncertain. This dissertation provides a genetic stratigraphic model of the succession by utilising an integrated sedimentological and geochemical approach which culminates in a new sequence stratigraphic subdivision of the Pretoria Group. The study focuses on the Potchefstroom area in the western part of the Transvaal depository. The Pretoria Group commences with the Rooihoogte Formation which overlies the Chuniespoort Group with erosional contact. New stratigraphic data indicates that the Rooihoogte Formation is a correlative of the Duitschland Formation in the eastern Transvaal. The succession was deposited in a foreland basin. An important new finding is that a diamictite at the base of the formation contains striated and bull-nosed pebbles and is of glacial origin. The discordantly overlying Timeball Hill Formation is composed of a coarsening upward carbonaceous shale – hematite oolite-bearing quartzite unit overlain by a second carbonaceous shale, capped by a second glacial diamictite (the well known Rietfonteindam diamictite). The oolitic ironstones in the quartzites suggest that they formed in a warm oxidizing environment. The shales display mature chemical indices of alteration which supports this theory. ä13Corganic values increase from –35‰ to –24‰ from the bottom to the top of the Timeball Hill Formation indicating net carbon burial, which translate to a decrease in atmospheric CO2 and colder climates as deposition evolved. In turn this can be linked to the presence of the glacial Rietfonteindam diamictite in the upper part of the Timeball Hill Formation. The Rietfonteindam diamictite is overlain by conglomerate, quartzite and shale of the Boshoek Formation, which were deposited as an upwards fining transgressive sedimentary unit following on post-glacial eustatic sea-level rise. It is in turn overlain by the 2.22Ga. Hekpoort basalt. This basalt is metasomatically altered, but has remained virtually unaffected by regional metamorphism, as shown by detailed SEM petrographic analyses. Excellent examples of zeolite- filled amygdales are preserved in the lavas. The Hekpoort lavas are overlain by fluvial red beds of the Dwaalheuwel Formation. A lateritic paleosol (Hekpoort paleosol) is developed below the red bed succession. The red beds are overlain with sharp gradational contact by the carbonaceous shelf mudstone of the Strubenskop Formation which grades up into the shallow marine Daspoort quartzite. The Silverton Formation, mainly composed of carbonaceous shale, overlies the Daspoort Formation with sharp gradational contact and grades upwards into shallow marine Magaliesberg quartzite. ä13Corganic values decrease from –25‰ to –29‰, from middle to top of the Silverton Formation, most probably indicating carbon input into the atmosphere and therefore rising atmospheric temperature. The Machadodorp lava, which was previously thought to be restricted to the eastern part of the Transvaal basin, was found to be present in the Potchefstroom area as well. Five unconformity-bounded sequences are present in the succession. Estimates are that they were deposited in time intervals of 60m.y. each.

M.Sc.<br>The Lower Devonian Bokkeveld Group is the Middle unit of the tripartite Cape Supergroup, which outcrops along the western, southern and eastern coastline of South Africa. A well-established sedimentary and stratigraphic understanding of the Bokkeveld Group allowed for geochemical and geochronological investigation in order to gain insight into the provenance characteristics, as well as the paleotectonic environment of the provenance areas. In order to observe any changes within the Bokkeveld Basin, complete profiles for geochemical investigation were sampled in the western, southern and eastern parts of the basin, and compared. Major and trace element patterns suggest that the western part of the basin received detrital input from felsic, magmatically evolved, and possibly alkaline sources, and that the sediment was highly recycled before deposition. Furthermore, the geochemistry suggests that the western part of the basin experienced “passive margin” type sedimentation. The geochemistry of the southern basin, in contrast, suggests input from less evolved, non-alkaline sources, and predicts sedimentation under “active margin” conditions for the lower part of the group. The eastern basin is geochemically intermediate between the western and southern basins. Zircon populations for the three parts of the basin further suggest that sources of different ages fed the three parts of the basin. The zircon population of the western basin suggests that the Namaqua Natal Belt (Mesoproterozoic) and Neoproterozoic cover successions were the major source of detritus, with only minor input from Paleozoic sources. The eastern basin also appears to have sourced mainly Namaquan aged material as well as Neoproterozoic material, with no Paleozoic input. The southern basin has a remarkably different zircon population, with the majority of grains being Paleozoic in age, and only a few Neoproterozoic and Mesoproterozoic grains. Furthermore, many of the grains are younger than any known source-rocks on the Kalahari Craton, and thus allude to input from an extra-Kalahari source into the southern part of the basin. The youngest grain from the southern basin overlaps with the established depositional age of the Bokkeveld Group, suggesting some syn-depositional or briefly pre-depositional magmatic activity in the source area(s) of the southern basin, as predicted by the geochemistry. The complete lack of zircon ages older than the Namaqua Natal Belt (Mesoproterozoic), would suggest that the Archean to Paleoproterozoic inner part of the Kalahari Craton, the Kaapvaal Craton, was not sourced by the Bokkeveld Group. This is most likely due to the Namaqua Natal Belt having served as a large east-west trending morphological divide during Bokkeveld deposition, preventing transport of detritus from the craton interior. Remarkably, this would suggest that the Namaqua Natal Mountain Range must have survived erosion and persisted as a morphological boundary for ca. 600 Ma to serve as the major source of detritus for the Bokkeveld Group. Even an extensive, craton-fringing sedimentary cover-succession such as the Bokkeveld Group, may thus not provide a “detrital fingerprint” of the craton interior, and paleogeographical implications must be taken into consideration during provenance studies. Paleocurrent directions for the Bokkeveld Group indicate a west to east transport direction in the southern part of the basin, and as such, a western, extra-Kalahari source, most likely the Rio de La Plata Craton and surrounds, is expected to have been the source of both the young Paleozoic zircons, as well as undifferentiated material as revealed in the geochemistry.

The Platreef occurs at the base of the Northern Limb of the Bushveld Complex and is variably mineralised with PGE, Cu, and Ni. The Platreef varies in thickness from a few meters to a few hundred meters and rests on progressively older sediments of the Transvaal Supergroup and Archaean granite basement northwards. Recent studies have highlighted the importance of magmatic processes, contamination of the magma by footwall rocks and syn- and post metasomatic fluid activity on the observed mineralisation. Along the Platreef strike, the PGE grade profiles are generally top-loaded from Overysel to Tweefontein North and more variable and bottom loaded from Tweefontein Hill southwards emphasizing the importance of the change in mineralisation style at Tweefontein in relation to the whole Platreef. This study presents the first significant PGM data on the Tweefontein farm, including ten boreholes along strike, providing insight into the distinctly different PGE mineralisation styles observed. Samples were selected based on assay data, varying rock types, stratigraphic position and proximity to geological features. The selected samples were investigated using petrography, geochemistry and the automated SEM techniques of QEMSCAN and MLA. Over 9000 PGM were analysed forming one of the most comprehensive PGM studies on the Platreef to date. The lowermost footwall intersected along the Tweefontein strike is banded ironstone of the Penge Formation. This is overlain by a metasedimentary footwall package, of variable thickness, derived from the shales and dolomites of the Duitschland Formation. Iron-rich, recrystallised, noritic sills occur at the base of the Platreef and are thought to represent sills which intruded prior to the emplacement of the Platreef. A pre- and possibly syn-Bushveld structural control resulted in irregular floor topography defined by a topographic footwall high in the central Tweefontein area and topographic depressions at Tweefontein North and Tweefontein Hill. The depression areas at Tweefontein are similar to the footwall basins at Turfspruit to the south, in which the Platreef is more lithologically complex compared to the footwall high areas. The footwall basins at Tweefontein and Turfspruit contain basal massive and submassive sulphides, which may not necessarily carry significant PGE grade. The Platreef lithologies at Tweefontein are composed of pyroxenites and norites with minor harzburgitic lithologies and contain numerous cross-cutting granitic veins. Xenoliths/interlayers of metamorphosed Duitschland lithologies occur primarily near the base of the Platreef, but also in the middle and upper Platreef sequence reflecting roof pendants. Unlike the Platreef on the farms adjacent to Tweefontein, the Platreef and footwall lithologies are relatively unaltered, but localised serpentinisation and chloritisation occur within harzburgitic lithologies and metasedimentary interlayers. Based on the stratigraphy and geochemical characteristics, the Platreef at Tweefontein can be subdivided into the upper and lower Platreef. The upper Platreef subdivision occurs in the top 20-40 m of the sequence and is defined by higher Mg#, Cr, Cr (ppm)/MgO and Pt/Pd values compared to the lower Platreef. In addition, the majority of the grade and base metal sulphide (BMS) content is enriched in the upper versus the lower Platreef, particularly for the northern and central parts of Tweefontein. The upper and lower Platreef may have been derived from different magma sources based on the “R Factor” concept proposed by Campbell and Naldrett in 1979 whereby the abundance of the PGE relative to the BMS content is linked to the proportion of magma with which the sulphide ore equilibrated (Naldrett, 2005b). Previous detailed geochemical studies from Tweefontein Hill southwards highlighted compositional breaks in the Platreef sequence thought to represent distinct sill-like intrusions (Hutchinson and Kinnaird, 2005; Kinnaird, 2005; Manyeruke et al., 2005; Nyama et al., 2006). They reported a more primitive sill at the top of the Platreef, which correlates to the upper Platreef at Tweefontein. The lower Platreef is therefore likely to represent a different sill intrusion. A relatively homogenous pyroxenitic package characterises the upper Platreef, although a more heterogeneous package is observed close to and at Tweefontein Hill. At Tweefontein North, the base of the upper Platreef is often marked by a chromitiferous package comprising a pegmatoidal feldspathic pyroxenite unit, up to 6 m thick, capped by a chromitite layer. Due to similar stratigraphy and high PGE grades, this distinct horizon has been compared to the Merensky Reef found elsewhere in the Bushveld Complex. The predominant base metal sulphides (BMS) in the Platreef at Tweefontein are pyrrhotite, pentlandite, chalcopyrite with minor pyrite aligned with that found elsewhere along the Platreef strike. There is an increase in BMS content, primarily pyrrhotite, towards the base of the Platreef with massive and submassive sulphide development near the base and in the footwall, particularly at Tweefontein Hill. Sulphur isotopes and detailed mineralogical studies at Turfspruit have shown that the addition of S, As and Sb into the magma from the Duitschland footwall triggered the development of a PGE-poor sulphide liquid which was then able to mix, modify and dilute the magmatic sulphides (Hutchinson and McDonald, 2008). Due to the similarity in footwall between Turfspruit and Tweefontein, these proposed processes help to explain the increase in BMS towards the base and the development of basal massive and submassive sulphides, which are not necessarily associated with significant PGE grade. At Tweefontein North, the processes dominating the top-loaded PGE mineralisation were primarily magmatic. The PGM assemblage, hosted by base metal sulphides and magmatic silicates, is dominated by Pt-and Pd-bismuthides and -tellurides with minor PGE-sulphides and Pt-arsenides. PGE-sulphides occur in the Platreef where the chromitiferous horizon is developed, which may indicate an environment low in volatile activity and one of the most primary mineralisation styles along the Platreef strike. The footwall high, which separates the depressions at Tweefontein North and Tweefontein Hill may have kept the Platreef at Tweefontein North relatively protected from additional processes affecting Tweefontein Hill. In contrast, assimilation of the Duitschland footwall is thought to play a key role in the development of the variable but predominantly bottom-loaded PGE mineralisation at Tweefontein Hill. The PGM assemblage is Pd-dominant characterised by Sb-, As- and Bi-bearing PGM, reflecting the incorporation of Sb, As and Bi from the Duitschland footwall. The association of the PGE mineralisation with the extensive basal sulphide development implies that the mineralisation at Tweefontein Hill probably occurred due to the gravitational settling of a sulphide liquid containing a mix of sedimentary and PGE-hosting magmatic components. Due to a significant PGM-BMS association in the mineralised footwall and metasedimentary interlayers/xenoliths, a downward migrating sulphide melt is believed to be the main mechanism responsible for the redistribution of PGE, predominantly Pd, into the mineralised metasedimentary lithologies. Finally, the Platreef and footwall lithologies may be locally modified by late-stage felsic and hydrothermal fluids to form bismuthide- and arsenide-dominant PGM assemblages, primarily hosted in quartz and serpentine respectively. This study shows the PGM and sulphide mineralisation at Tweefontein to be multifaceted, involving magmatic processes, assimilation of the Duitchland footwall into the Platreef magma and late-stage hydrothermal and felsic fluid activity. Footwall composition and irregular floor topography, resulting in depression areas at Tweefontein North and Tweefontein Hill, are believed to play a key role in what processes become significant along the Tweefontein strike. This research represents a significant contribution to the understanding of the distinctly different PGE mineralisation styles at Tweefontein and allows for a complete comparison of the Platreef PGE mineralisation from Overysel to Turfspruit.

At present the Karoo Basin covers approximately 20 000 km2. It is a large intracratonic basin which, from Carboniferous to Jurassic times, was infilled with a succession of sediments ranging from glacial deposits to those deposited in warm, equable conditions. The Beaufort Group forms part of this succession, and was deposited in a terrestrial, river dominated environment. The dominant lithologies exposed in the Estcourt region in the KwaZulu-Natal Midlands belong to the lower and middle Beaufort divided by the PermoTriassic boundary. The Permo-Triassic palaeoenvironment in this region is reconstructed using sedimentary profiles combined with the study of the fossil remains discovered in the area, including plant, body, and trace fossils. The lower Beaufort sediments in this region belong to the Estcourt Formation, and the Middle Beaufort sediments to the Belmont Formation. The Estcourt Formation is dominated by a succession of alternating sandstones, siltstones and mudstones, which are interpreted as representing sediments deposited in a fluvial-floodplain environment, which can be divided into two sub-environments. The first is dominated by sediments that were deposited by meandering rivers on a semi-arid floodplain, and the second sub-environment is represented by those sediments deposited in lacustrine environments. Both of these subenvironments are closely linked and alternate in the rock record indicating many episodes of transgressive-regressive lacustrine episodes. The Estcourt Formation can be closely correlated with the lower Beaufort sediments mapped in other regions of the Karoo Basin, indicating similar climatic and environmental controls throughout the Karoo Basin of southern Africa. The Estcourt Formation also contains a wide variety of body and trace fossils. The PermoTriassic boundary can be traced along the western border of Estcourt by using the distribution pattern of the two mammal-like reptiles Dicynodon and Lystrosaurus. There is evidence of an overlap in the distribution between these to mammal-like reptiles, which together with palaeoflora evidence, indicates that Lystrosaurus evolved during the Late Permian and not Early Triassic as previously thought. The first Triassic sediments are represented in the Estcourt region by a series of maroon shales which can be correlated with the Palingkloof Member.<br>Thesis (M.Sc.)-University of Natal, 1997.

M.Sc. (Geology)<br>The Witwatersrand Supergroup is host to a number of auriferous and uraniferous conglomeratic reefs, which have been extensively exploited along the Witwatersrand Basin margins. The current study investigates the Vaal Reef, in the Klerksdorp gold field with particular focus on conducting a geometallurgical characterization of the ore which may ultimately enhance the recovery of gold and uranium and our understanding of how the ore responds to processing. Six samples were collected from AngloGold Ashanti’s Moab Khotsong mine and prepared for a chemical and mineralogical deportment study. These samples were milled and crushed down to 80% passing -75μm and processed for head chemistry assays, grading analysis as well as heavy liquid separation analysis as part of the chemical deportment. The samples were also submitted for gold cyanide, acid uranium and diagnostic leach tests.....

M.Sc.<br>The evolution of oxygen in the Earth's atmosphere during the early Precambrian has been a subject of debate for many years. Two fundamental models oppose another. The one by Cloud, Holland and co-workers suggests that the atmosphere was essentially anoxic until about 2.2Ga and then became highly oxygenated due to a sudden rise in oxygen levels. The, other advocated by Dimroth, Kimberley and Ohmoto suggests that the atmosphere was oxygenated as early as 3.5Ga. The most crucial assumption for the Cloud-Holland model for the evolution of atmospheric oxygen is that the 2.2-2.3Ga Hekpoort paleosol formed under reducing atmospheric conditions. However, regional field, drill core, petrographic and geochemical investigations of the Hekpoort paleosol during this study clearly show that the Hekpoort paleosol in fact represents an oxidised lateritic weathering profile. In addition, the Hekpoort paleosol correlates well to the oxidised saprolites below the Gamagara/Mapedi erosion surface in the Northern Cape Province. The basis for theassumption by Holland and co-workers that a dramatic rise in atmospheric oxygen levels took place at 2.2Ga thus falls away. During this study extensive red beds, belonging to the Dwaal Heuvel Formation were discovered directly above the Hekpoort paleosol in the Pretoria Group in Botswana and the western Transvaal area. The red beds show two stages of development, firstly fluvial and then deltaic. The red beds are correlated with the Gamagara/Mapedi red beds in Griqualand West. Apart from this evidence for highly oxygenated conditions immediately above the Hekpoort/Ongeluk lavas, hematitic ferricrete, pisolitic mudclast conglomerate and hematitic oolitic ironstones were also found in the Timeball Hill Formation underlying the Hekpoort lava. Oolitic ironstones are developed over an area of more than 100 000 km2. Several different types of oolites are developed within the oolitic ironstone which contains up to 73wt% Fe203. The ferricrete and hematitic pisolitic mudclast conglomerate contain oncolites. These ferricretes, pisolitic mudclast conglomerate and oolitic ironstones suggest that the atmosphere was already highly oxidising between 2.4 and 2.45Ga, prior to deposition of the Hekpoort lava. Pretoria Group rocks that were deposited in close contact with the atmosphere show no evidence for an anoxic atmosphere. It is suggested that atmospheric oxygen levels may have fluctuated through time but at the same time increased in a steplike manner during deposition of the Transvaal Supergroup. However, at this moment in time we do not have enough information available to develop a quantitative model for the evolution of atmospheric oxygen. New age data available on the Hekpoort/Ongeluk lava unit indicate that it may be 2.395Ga old i.e. some 200Ma older than thought earlier. Thus, the atmosphere could have been highly oxygenated in very early Paleoproterozoic times. Uraninite, pyrite and siderite present in older Archean sedimentary rocks do, however, argue for more reducing atmospheric conditions at that time. Both the Cloud-Holland and Dimroth-Ohmoto models of atmospheric oxygen development are therefore in need of revision.