Journal articles on the topic 'Geosorbents'

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1

Luthy, Richard G., George R. Aiken, Mark L. Brusseau, Scott D. Cunningham, Philip M. Gschwend, Joseph J. Pignatello, Martin Reinhard, Samuel J. Traina, Walter J. Weber, and John C. Westall. "Sequestration of Hydrophobic Organic Contaminants by Geosorbents." Environmental Science & Technology 31, no. 12 (December 1997): 3341–47. http://dx.doi.org/10.1021/es970512m.

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2

Bouchard, Dermont C. "Sorption of vinclozolin and atrazine on four geosorbents." Pesticide Science 55, no. 11 (October 15, 1999): 1095–102. http://dx.doi.org/10.1002/(sici)1096-9063(199911)55:11<1095::aid-ps61>3.0.co;2-7.

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3

Cheng, Hefa, and Martin Reinhard. "Measuring Hydrophobic Micropore Volumes in Geosorbents from Trichloroethylene Desorption Data." Environmental Science & Technology 40, no. 11 (June 2006): 3595–602. http://dx.doi.org/10.1021/es0522581.

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4

Mechlińska, Agata, Monika Gdaniec-Pietryka, Lidia Wolska, and Jacek Namieśnik. "Evolution of models for sorption of PAHs and PCBs on geosorbents." TrAC Trends in Analytical Chemistry 28, no. 4 (April 2009): 466–82. http://dx.doi.org/10.1016/j.trac.2009.01.005.

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5

Leovac, Anita, Ekaterina Vasyukova, Ivana Ivančev-Tumbas, Wolfgang Uhl, Marijana Kragulj, Jelena Tričković, Đurđa Kerkez, and Božo Dalmacija. "Sorption of atrazine, alachlor and trifluralin from water onto different geosorbents." RSC Advances 5, no. 11 (2015): 8122–33. http://dx.doi.org/10.1039/c4ra03886j.

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The sorption behavior of the herbicides atrazine, alachlor and trifluralin on two modified organoclays, one model sediment, and one natural sediment in three water matrices (synthetic water, natural groundwater and surface water) was investigated.
6

An, Xianjin, Baohua Xiao, Xinyue Di, Hui Dong, and Haiming Tang. "Research progress on aging of organic pollutants in geosorbents: a review." Acta Geochimica 36, no. 1 (November 1, 2016): 27–43. http://dx.doi.org/10.1007/s11631-016-0129-z.

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7

Sander, Michael, and Joseph J. Pignatello. "SORPTION IRREVERSIBILITY OF 1,4-DICHLOROBENZENE IN TWO NATURAL ORGANIC MATTER–RICH GEOSORBENTS." Environmental Toxicology and Chemistry 28, no. 3 (2009): 447. http://dx.doi.org/10.1897/08-128.1.

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8

Gillette, J. Seb, Richard G. Luthy, Simon J. Clemett, and Richard N. Zare. "Direct Observation of Polycyclic Aromatic Hydrocarbons on Geosorbents at the Subparticle Scale." Environmental Science & Technology 33, no. 8 (April 1999): 1185–92. http://dx.doi.org/10.1021/es980838a.

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9

Selig, Hildegarde, T. Michael Keinath, and Walter J. Weber. "Sorption and Manganese-Induced Oxidative Coupling of Hydroxylated Aromatic Compounds by Natural Geosorbents." Environmental Science & Technology 37, no. 18 (September 2003): 4122–27. http://dx.doi.org/10.1021/es020999l.

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10

Cornelissen, Gerard, Gijs D. Breedveld, Stavros Kalaitzidis, Kimon Christanis, Anne Kibsgaard, and Amy M. P. Oen. "Strong Sorption of Native PAHs to Pyrogenic and Unburned Carbonaceous Geosorbents in Sediments." Environmental Science & Technology 40, no. 4 (February 2006): 1197–203. http://dx.doi.org/10.1021/es0520722.

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11

Hale, Sarah E., Satoshi Endo, Hans Peter H. Arp, Andrew R. Zimmerman, and Gerard Cornelissen. "Sorption of the monoterpenes α-pinene and limonene to carbonaceous geosorbents including biochar." Chemosphere 119 (January 2015): 881–88. http://dx.doi.org/10.1016/j.chemosphere.2014.08.052.

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12

Yang, Yi, Bertrand Ligouis, Carmen Pies, Christine Achten, and Thilo Hofmann. "Identification of carbonaceous geosorbents for PAHs by organic petrography in river floodplain soils." Chemosphere 71, no. 11 (May 2008): 2158–67. http://dx.doi.org/10.1016/j.chemosphere.2008.01.010.

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13

Rahman, Md Mokhlesur, and Eckhard Worch. "Nonequilibrium sorption of phenols onto geosorbents: The impact of pH on intraparticle mass transfer." Chemosphere 61, no. 10 (December 2005): 1419–26. http://dx.doi.org/10.1016/j.chemosphere.2005.04.085.

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14

Breus, Irina P., Artem A. Mishchenko, Konstantin A. Potashev, and Vladimir A. Breus. "Description of organic compound vapor-phase sorption by geosorbents: Adequacy of the isotherm approximation." Colloids and Surfaces A: Physicochemical and Engineering Aspects 276, no. 1-3 (March 2006): 122–33. http://dx.doi.org/10.1016/j.colsurfa.2005.10.029.

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15

Kuo, Dave T. F., John B. Vander Sande, and Philip M. Gschwend. "Characterization of black carbon in geosorbents at the nanometer scale by STEM–EDX elemental mapping." Organic Geochemistry 56 (March 2013): 81–93. http://dx.doi.org/10.1016/j.orggeochem.2012.12.012.

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16

Zhang, Jing, Jean-Marie Séquaris, Hans-Dieter Narres, Harry Vereecken, and Erwin Klumpp. "Pyrene and Phenanthrene Sorption to Model and Natural Geosorbents in Single- and Binary-Solute Systems." Environmental Science & Technology 44, no. 21 (November 2010): 8102–7. http://dx.doi.org/10.1021/es1010847.

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17

Rahman, Mokhlesur, Fariba Amiri, and Eckhard Worch. "Application of the mass transfer model for describing nonequilibrium transport of HOCs through natural geosorbents." Water Research 37, no. 19 (November 2003): 4673–84. http://dx.doi.org/10.1016/s0043-1354(03)00430-5.

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18

Fuks, S. L., S. V. Devyaterikova, and S. V. Khitrin. "Possibilities of Using Fly Ash with Other Industrial Waste to Obtain Geosorbents and Composite Materials." IOP Conference Series: Earth and Environmental Science 459 (April 15, 2020): 022006. http://dx.doi.org/10.1088/1755-1315/459/2/022006.

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19

Fuks, S. L., S. V. Devyaterikova, and S. V. Khitrin. "Possibilities of Using Fly Ash with Other Industrial Waste to Obtain Geosorbents and Composite Materials." IOP Conference Series: Earth and Environmental Science 459 (April 15, 2020): 022009. http://dx.doi.org/10.1088/1755-1315/459/2/022009.

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20

Huang, Qingguo, Hildegarde Selig, and Walter J. Weber. "Peroxidase-Catalyzed Oxidative Coupling of Phenols in the Presence of Geosorbents: Rates of Non-extractable Product Formation." Environmental Science & Technology 36, no. 4 (February 2002): 596–602. http://dx.doi.org/10.1021/es010512t.

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21

Meyer, Wiebke, Sandra Kons, and Christine Achten. "Impact of reference geosorbents on oral bioaccessibility of PAH in a human in vitro digestive tract model." Environmental Science and Pollution Research 22, no. 7 (November 14, 2014): 5164–70. http://dx.doi.org/10.1007/s11356-014-3804-9.

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22

Xu, Xiaoyang, Hongwen Sun, and Myrna J. Simpson. "Concentration- and time-dependent sorption and desorption behavior of phenanthrene to geosorbents with varying organic matter composition." Chemosphere 79, no. 8 (May 2010): 772–78. http://dx.doi.org/10.1016/j.chemosphere.2010.03.027.

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23

Tremblay, Luc, Scott D. Kohl, James A. Rice, and Jean-Pierre Gagné. "Effects of lipids on the sorption of hydrophobic organic compounds on geosorbents: a case study using phenanthrene." Chemosphere 58, no. 11 (March 2005): 1609–20. http://dx.doi.org/10.1016/j.chemosphere.2004.11.073.

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24

Wang, Lei, Ying Xin, Zunlong Zhou, Xiaoyang Xu, and Hongwen Sun. "Impact of organic matter properties on sorption domains of phenanthrene on chemically modified geosorbents and synthesized charcoals." Journal of Hazardous Materials 244-245 (January 2013): 268–75. http://dx.doi.org/10.1016/j.jhazmat.2012.11.041.

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25

Sánchez-Jiménez, N., M. T. Sevilla, J. Cuevas, M. Rodríguez, and J. R. Procopio. "Interaction of organic contaminants with natural clay type geosorbents: Potential use as geologic barrier in urban landfill." Journal of Environmental Management 95 (March 2012): S182—S187. http://dx.doi.org/10.1016/j.jenvman.2011.02.011.

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26

Endo, Satoshi, Peter Grathwohl, Stefan B. Haderlein, and Torsten C. Schmidt. "Characterization of Sorbent Properties of Soil Organic Matter and Carbonaceous Geosorbents Usingn-Alkanes and Cycloalkanes as Molecular Probes." Environmental Science & Technology 43, no. 2 (January 15, 2009): 393–400. http://dx.doi.org/10.1021/es802277n.

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27

Rimola, Albert, Bartolomeo Civalleri, and Piero Ugliengo. "Physisorption of aromatic organic contaminants at the surface of hydrophobic/hydrophilic silica geosorbents: a B3LYP-D modeling study." Physical Chemistry Chemical Physics 12, no. 24 (2010): 6357. http://dx.doi.org/10.1039/c000009d.

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28

Aitken, Michael D. "Comment on “Peroxidase-Catalyzed Oxidative Coupling of Phenols in the Presence of Geosorbents: Rates of Non-extractable Product Formation”." Environmental Science & Technology 36, no. 19 (October 2002): 4197–98. http://dx.doi.org/10.1021/es020671s.

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29

Cowen, Scott, Megha Duggal, Tuan Hoang, and Hind A. Al-Abadleh. "Vibrational spectroscopic characterization of some environmentally important organoarsenicals — A guide for understanding the nature of their surface complexes." Canadian Journal of Chemistry 86, no. 10 (October 1, 2008): 942–50. http://dx.doi.org/10.1139/v08-102.

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Organoarsenicals are found in the environment from the biomethylation of inorganic arsenic compounds and from anthropogenic sources. It is clear that organoarsenicals pose a health and an environmental risk due to their potential cycling to the most toxic forms of arsenic as a result of redox activity in soils and natural waters. The environmental fate of arsenic compounds depends to a large extent on the surface interactions with geosorbents, mainly minerals and organic matter. Hence, elucidating the nature of surface complexes is important in understanding binding mechanisms and thermodynamics. In this paper, we report the vibrational spectra of a number of organoarsenicals in the aqueous and solid phases using attenuated total internal reflectance Fourier transform infrared (ATR-FTIR), transmission FTIR, and Raman spectroscopies. Analysis of the aqueous phase spectra revealed that for completely deprotonated anions, increasing the organic substituents on the AsOx moiety results in increasing the frequency of v(AsOx), whereas the opposite trend is observed for completely protonated molecules. Analysis of solid phase spectra showed that incorporation of water molecules in the crystalline structure and extensive hydrogen bonding with neighboring molecules significantly affect As–O bond lengths and hence frequencies of v(AsOx). Results are discussed in the context of identifying geometry of organoarsenicals surface complexes in situ using the ATR-FTIR technique.Key words: ATR-FTIR, organoarsenicals; oxyanion adsorption, arsenate, in situ spectroscopy.
30

Huang, Qingguo, Hildegarde Selig, and Walter J. Weber. "Response to Comment on “Peroxidase-Catalyzed Oxidative Coupling of Phenols in the Presence of Geosorbents: Rates of Non-extractable Product Formation”." Environmental Science & Technology 36, no. 19 (October 2002): 4199–200. http://dx.doi.org/10.1021/es020817n.

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31

Young, Katherine D., and Eugene J. LeBoeuf. "Development of a glass ampoule system for evaluation of long-term sorption/desorption behavior of vapor phase volatile organic compounds in geosorbents." Analyst 126, no. 10 (2001): 1816–19. http://dx.doi.org/10.1039/b104638c.

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32

Tremblay, Luc, Scott D. Kohl, James A. Rice, and Jean-Pierre Gagné. "Erratum to “Effects of lipids on the sorption of hydrophobic organic compounds on geosorbents: a case study using phenanthrene” [Chemosphere 58 (2005) 1609–1620]." Chemosphere 60, no. 1 (June 2005): 147. http://dx.doi.org/10.1016/j.chemosphere.2005.02.006.

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33

Sabur, Md Abdus, and Hind A. Al-Abadleh. "Surface interactions of monomethylarsonic acid with hematite nanoparticles studied using ATR-FTIR: adsorption and desorption kinetics." Canadian Journal of Chemistry 93, no. 11 (November 2015): 1297–304. http://dx.doi.org/10.1139/cjc-2015-0350.

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Monomethylarsonic acid (MMA) is an organoarsenical compound which, along with dimethylarsinic acid (DMA), poses health and environmental concerns. Little is known about the surface chemistry of MMA at the molecular level with materials relevant to geochemical environments and industrial sectors. We report the structure of MMA surface complexes and the adsorption/desorption kinetics of MMA to and from hematite as a model for reactive iron-containing materials commonly found in geosorbents and arsenic-removal technologies. Attenuated total internal reflectance Fourier transform infrared (ATR-FTIR) spectroscopy was used to study the surface interactions at the molecular level. Spectra of adsorbed MMA (MMA(ads)) were collected as a function of time and aqueous-phase concentration. Values for the apparent rates of adsorption and desorption were extracted from experimental data at pH 7 as a function of spectral components during the initial times of surface interactions (0–5 min). Results showed that MMA adsorbs on hematite nanoparticles with rates 1.3 to 1.6 times slower than arsenate. The desorption of MMA(ads) by hydrogen phosphate from hematite surfaces is 2× faster than arsenate, and proceeds with an overall nonunity order, suggesting the existence of more than one type of surface complex at equilibrium. Also, hydrogen phosphate leads to the desorption of about 67% of MMA(ads) compared with 26% of surface arsenate. Adsorption kinetics for aqueous hydrogen phosphate were also investigated in the absence and presence of surface arsenic and followed this order: fresh hematite > MMA/hematite ≥ iAs(V)/hematite. From this study, it can be inferred that, on average, the presence of the methyl group in MMA results in weaker surface interactions with hematite relative to arsenate under neutral pH because of the simultaneous formation of mono- and bidentate MMA complexes compared with predominantly bidentate complexes for arsenate.
34

Xie, Mengxing, Dan Lv, Xin Shi, Yuqiu Wan, Wei Chen, Jingdong Mao, and Dongqiang Zhu. "Sorption of monoaromatic compounds to heated and unheated coals, humic acid, and biochar: Implication for using combustion method to quantify sorption contribution of carbonaceous geosorbents in soil." Applied Geochemistry 35 (August 2013): 289–96. http://dx.doi.org/10.1016/j.apgeochem.2013.05.003.

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35

Hiller, E., M. Khun, L. Zemanová, Ľ. Jurkovič, and M. Bartaľ. "Laboratory study of retention and release of weak acid herbicide MCPA by soils and sediments and leaching potential of MCPA." Plant, Soil and Environment 52, No. 12 (November 19, 2011): 550–58. http://dx.doi.org/10.17221/3546-pse.

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MCPA sorption and desorption in five surface soils (denoted as A1-5), three bottom sediments (S1-3), two river sediments (L1-2) and one subsurface soil (SS) at two initial concentrations in aqueous solution &ndash; C<sub>0</sub> = 0.5 and 10&nbsp;mg/l were studied. No significant effect of the initial concentration on MCPA equilibrium distribution between soil/sediment and aqueous solution was observed. The difference between distribution coefficient K<sub>D</sub> at C<sub>0</sub> = 0.5&nbsp;mg/l and K<sub>D</sub> at C<sub>0</sub> = 10 mg/l was found only in the case of one bottom sediment (S2). A simple regression analysis between K<sub>D</sub> at C<sub>0</sub> = 0.5 and 10 mg/l and soil/sediment properties indicated that the most important property which determined the variation in MCPA sorption is organic carbon (r = 0.886*** and r = 0.926***, respectively). Similarly, desorption of MCPA was inversely proportional to organic carbon content of the soils and sediments used (r = &ndash;0.862* and r = &ndash;0.842**). These observations showed that MCPA sorption and desorption in soils and sediments were primarily controlled by organic components of the geosorbents used. Overall, the percentage of MCPA sorption in soils and sediments was low (P<sub>sorp</sub> &asymp; 3&ndash;53%; K<sub>D</sub> = 0.077&ndash;2.827 l/kg) and the percentage of MCPA desorbed was relatively high (P<sub>des</sub> &asymp; 11&ndash;70%), especially in the soils and sediments with lower organic carbon content. The experimental results and calculated values of groundwater ubiquity score GUS and relative leaching potential index RLPI imply that MCPA is very mobile in all the surface soils and has a potential to contaminate groundwater.
36

Thiebault, T., M. Boussafir, L. Le Forestier, C. Le Milbeau, L. Monnin, and R. Guégan. "Competitive adsorption of a pool of pharmaceuticals onto a raw clay mineral." RSC Advances 6, no. 69 (2016): 65257–65. http://dx.doi.org/10.1039/c6ra10655b.

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The removal of a Pharmaceutically Active Compound (PhAC) pool using a well referenced clay mineral from Wyoming (SWy-2) as a geosorbent was studied for a better understanding of the environmental fate.
37

Kragulj, Marijana, Jelena Trickovic, Bozo Dalmacija, Ivana Ivancev-Tumbas, Anita Leovac, Jelena Molnar, and Dejan Krcmar. "Sorption of benzothiazoles onto sandy aquifer material under equilibrium and nonequlibrium conditions." Journal of the Serbian Chemical Society 79, no. 1 (2014): 89–100. http://dx.doi.org/10.2298/jsc130115063k.

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In this study, the sorption behaviour of 1,3-benzothiazole (BT) and 2-(methylthio)benzothiazole (MTBT) was investigated on Danube geosorbent under equilibrium and nonequilibrium conditions. All sorption isotherms fitted well with the Freundlich model (R2=0.932-0.993). The results showed that organic matter of the Danube geosorbent has a higher sorption affinity for the more hydrophobic MTBT compared to BT. However, sorption-desorption experiments showed that MTBT was more easily desorbed than BT molecules, which indicates the importance of absorption relative to adsorption in the overall sorption mechanism of MTBT. In general, molecules of BT and MTBT were more easily desorbed in the lower concentration range, which resulted in an increase in the hysteresis indices with increasing concentrations. Column experiments revealed that retention of the investigated compounds on the aquifer material followed the compound?s hydrophobicity. BT showed a lower retention, in accordance with its lower sorption affinity obtained in the static experiments, while MTBT showed a greater sorption affinity, and thus had a longer retention time on the column. Thus during transport BT represent greater risk for groundwaters than MTBT. These results have increased our understanding of benzothiazoles sorption and desorption process which represent one of the most important factors which influence the behaviour of organic compounds in the environment.
38

Ehlers, George A. C., and Andreas P. Loibner. "Linking organic pollutant (bio)availability with geosorbent properties and biomimetic methodology: A review of geosorbent characterisation and (bio)availability prediction." Environmental Pollution 141, no. 3 (June 2006): 494–512. http://dx.doi.org/10.1016/j.envpol.2005.08.063.

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39

Weber, W. "Contaminant interactions with geosorbent organic matter: insights drawn from polymer sciences." Water Research 35, no. 4 (March 2001): 853–68. http://dx.doi.org/10.1016/s0043-1354(00)00339-0.

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40

Dong, Hui, and Baohua Xiao. "Effects of geosorbent and solution properties on sorption and desorption of PAHs." Acta Geochimica 40, no. 2 (January 15, 2021): 212–24. http://dx.doi.org/10.1007/s11631-021-00450-w.

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41

Weber, Walter J., Weilin Huang, and Eugene J. LeBoeuf. "Geosorbent organic matter and its relationship to the binding and sequestration of organic contaminants." Colloids and Surfaces A: Physicochemical and Engineering Aspects 151, no. 1-2 (June 1999): 167–79. http://dx.doi.org/10.1016/s0927-7757(98)00820-6.

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42

Werth, Charles J., and Martin Reinhard. "Counter-Diffusion of Isotopically Labeled Trichloroethylene in Silica Gel and Geosorbent Micropores: Column Results." Environmental Science & Technology 33, no. 5 (March 1999): 730–36. http://dx.doi.org/10.1021/es9800378.

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43

McMillan, Scott A., and Charles J. Werth. "Counter-Diffusion of Isotopically Labeled Trichloroethylene in Silica Gel and Geosorbent Micropores: Model Development." Environmental Science & Technology 33, no. 13 (July 1999): 2178–85. http://dx.doi.org/10.1021/es980811r.

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44

Wang, Peng, and Arturo Keller. "Adsorption of hydrophobic organic compounds onto a hydrophobic carbonaceous geosorbent in the presence of surfactants." Environmental Toxicology and Chemistry preprint, no. 2008 (2007): 1. http://dx.doi.org/10.1897/07-568.

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45

Wang, Peng, and Arturo A. Keller. "ADSORPTION OF HYDROPHOBIC ORGANIC COMPOUNDS ONTO A HYDROPHOBIC CARBONACEOUS GEOSORBENT IN THE PRESENCE OF SURFACTANTS." Environmental Toxicology and Chemistry 27, no. 6 (2008): 1237. http://dx.doi.org/10.1897/07-568.1.

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46

Fux, S. L., S. V. Devyaterikova, and T. A. Musikhina. "Geosorbent Based on the Combination of Kuznetsk-Basin Coal Fly Ssh With Various Kinds of Lignin." IOP Conference Series: Earth and Environmental Science 272 (June 21, 2019): 022053. http://dx.doi.org/10.1088/1755-1315/272/2/022053.

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47

Mira Anuar, Nurasiah, and Chee-Ming Chan. "Adsorption of Escherichia coli from landfill leachate using Dredged marine soils as Geosorbent: The influence of temperature." Materials Today: Proceedings 31 (2020): 278–81. http://dx.doi.org/10.1016/j.matpr.2020.06.007.

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48

Jeong, Sangjo, and Charles J. Werth. "Evaluation of Methods To Obtain Geosorbent Fractions Enriched in Carbonaceous Materials That Affect Hydrophobic Organic Chemical Sorption." Environmental Science & Technology 39, no. 9 (May 2005): 3279–88. http://dx.doi.org/10.1021/es0491836.

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49

JU, D., and T. YOUNG. "The influence of the rigidity of geosorbent organic matter on non-ideal sorption behaviors of chlorinated benzenes." Water Research 39, no. 12 (July 2005): 2599–610. http://dx.doi.org/10.1016/j.watres.2005.04.058.

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50

Akar, Sibel Tunali, Sevcin Aslan, and Tamer Akar. "Conversion of natural mineral to effective geosorbent by coating MnO 2 and its application potential for dye contaminated wastewaters." Journal of Cleaner Production 189 (July 2018): 887–97. http://dx.doi.org/10.1016/j.jclepro.2018.04.063.

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