Academic literature on the topic 'Glass corrosion'

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Journal articles on the topic "Glass corrosion"

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Espinoza Vazquez, Araceli, Andres Soriano Carranza, Ignacio A. Figueroa Vargas, and Francisco Rodriguez. "Effect of the pH on the Corrosion Behaviour for a Ni59.5 Nb40.5 Binary Metallic Glass." ECS Transactions 106, no. 1 (January 31, 2022): 63–70. http://dx.doi.org/10.1149/10601.0063ecst.

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Ni-Nb binary metallic glass was synthesized by the melt spinning technique with a tangential wheel rotation speed during cooling of 6 m/s obtaining a glassy matrix which was characterized by X-ray diffraction (XRD). Electrochemical properties were determined by electrochemical impedance spectroscopy (EIS). The results show that this metallic glass is very resistant to corrosion, being better when exposed to corrosive media with pH = 0 and 7 in chloride ions presence. However, at pH = 14 the passive film is not homogeneous, and the corrosion rate increases with respect to the other systems.
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Weaver, Jamie L., Joelle Reiser, Owen K. Neill, John S. McCloy, and Nathalie A. Wall. "A Sampling Method for Semi-Quantitative and Quantitative Electron Microprobe Analysis of Glass Surfaces." MRS Proceedings 1744 (2015): 101–6. http://dx.doi.org/10.1557/opl.2015.496.

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ABSTRACTThe determination of the long-term stability and corrosion of vitrified nuclear waste is an important aspect of research for the U.S. Department of Energy (DOE). It is necessary to understand the rate and mechanisms of Nuclear Waste Glass (NWG) corrosion to determine whether or not the glassy matrix will be able to retain radionuclides for the required repository performance time period. Glass corrosion and the rate of glass corrosions is determined by both chemical and microscopy. Electron Microprobe Analysis (EPMA) is a common and powerful method utilized in the examination of the chemographic difference between corroded and uncorroded NGWs. In this work, two forms of quantitative and semi-quantitative EPMA methods are defined by optimizing the instruments counting statistics against a standard glass and NIST minerals that have compositions similar to the glasses under examination. Data collected on both the planar and cross-sectioned surfaces of an unaltered simulated NWG by Standard based Wavelength Dispersive Spectroscopy (WDS) was found to be comparable to the theoretical composition of the glass. Conventional standardless Energy Dispersive Spectroscopy (EDS) data collected on the same surfaces was not comparable. However, standard-based EDS analysis is shown to be able to discriminate between unaltered and corroded glass surfaces.
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Kim, Hwan Sik, Yoo Taek Kim, Gi Gang Lee, Jung Hwan Kim, and Seung Gu Kang. "Corrosion of Silicate Glasses and Glass-Ceramics Containing EAF Dust in Acidic Solution." Solid State Phenomena 124-126 (June 2007): 1585–88. http://dx.doi.org/10.4028/www.scientific.net/ssp.124-126.1585.

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The corrosion behavior of glass and glass-ceramics fabricated with silicate glass frit mixed with 50~70 wt% EAF dust in the acidic solution was analyzed by both heavy metal leaching test and microstructural observation. The crystallization temperature, Tc of glassy specimens was around 850 measured by DTA and the heat treatment temperature to crystallize a glassy specimen was selected as 950 / 1 hr. The spinel crystal peaks were found in XRD analysis for the glass containing dust > 60 wt%. For the glass-ceramics, however, the spinel peaks in a specimen containing dust > 50 wt% was found with weak willemite peaks. The glass and glass-ceramic specimens showed the first stage of corroding reaction according to Clark models in acidic solution. The glass-ceramic specimens showed much lower a heavy metal leaching concentration than that of glass specimens in the corrosion test in acidic solution of pH=2.95. Especially, the glass-ceramics containing dust 60 wt% showed a heavy metal leaching concentration of 66 % Pb, 60 % Zn and 98 % Fe lower than that of glass specimens due to crystal phases formed, thermodynamically more stable than a glass network structure. From the leaching test that more Zn ion leached out than Fe ion, the spinel crystal phase [ZnFe2O4] showed better corrosion resistant in the acidic solution than the willemite [Zn2SiO4].
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Chen, Ken, Jiewei Lin, Wenfang Li, Wen Zhu, Kang Li, Aihua Yi, Shaodong Hu, Minghui Chen, and Fuhui Wang. "Improved Oxidation and Hot Corrosion Resistance of 1Cr11Ni2W2MoV Stainless Steel at 650 °C by a Novel Glass-Ceramic Coating." Crystals 11, no. 10 (October 8, 2021): 1213. http://dx.doi.org/10.3390/cryst11101213.

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A novel glass-ceramic coating was applied onto the 1Cr11Ni2W2MoV stainless steel. The oxidation and corrosion behaviors of coated and uncoated steels were comparatively investigated in air and in the presence of NaCl + Na2SO4 eutectic deposits at 650 °C, respectively. Protective scales formed on the surface of stainless steel prevented the severe oxidation of the alloy. Catastrophic hot corrosion occurred on the steel when a salt film was attached, producing loose iron oxide layers and internal corrosion zone. The glass-ceramic coating acted as a barrier that effectively hindered the invasion of corrosive species during the oxidation and hot corrosion tests.
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Yue, Li Jie, Jin Sheng Han, and Kun Xie. "The Microalloying Effects in Cu-Based Bulk Metallic Glasses." Materials Science Forum 688 (June 2011): 407–12. http://dx.doi.org/10.4028/www.scientific.net/msf.688.407.

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The glassy alloy rods of Cu50Zr43Al7, (Cu50Zr43Al7)100-xYx(x=2,5) and (Cu50Zr43Al7)100-xAgx(x=6,7) with diameters of 3.0 mm were prepared by copper mold suction casting method. The influence of adding Ag and Y to Cu50Zr43Al7 metallic glass on glass formation ability (GFA) and thermal stability was studied by means of X-ray diffraction analysis (XRD) and differential scanning calorimetry (DSC). The results show that Ag and Y appropriate micro-addition enhance the glass formation ability and thermal stability of the Cu-Zr-Al metallic glass. The effect of Ag is better than that of Y. The addition of Ag causes a increase of the reduced glass transition temperature (Trg) of (Cu50Zr43Al7)100-xAgx alloy from 0.618 at 0 at.% Ag to 0.628 at 7 at.% Ag. The width of the supercooled liquid region of Cu43Zr43Al7Ag7 glassy alloy increases about 25K compared with that of Cu50Zr43Al7, and the γ value of Cu43Zr43Al7Ag7 reaches 0.433. The electrochemical corrosion behaviors of Cu50Zr43Al7, (Cu50Zr43Al7)100-xYx(x=2,5) and (Cu50Zr43Al7)100-xAgx(x=6,7) metallic glasses in 3.5% NaCl solution were investigated by potentiodynamic polarization method. It is found that corrosion resistance of all amorphous alloys is better than that of the corresponding crystalline alloys. The Ag and Y micro-addition improve corrosion resistance of Cu50Zr43Al7 metallic glass. The corrosion current density of Cu43Zr43Al7Ag7 metallic glass decreases 1~2 orders of magnitude compared with that of Cu50Zr43Al7.
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Orhon, Melek, İlkay Sökmen, and Gülçin Albayrak. "Dishwasher Corrosion of Glasses." Advanced Materials Research 39-40 (April 2008): 317–22. http://dx.doi.org/10.4028/www.scientific.net/amr.39-40.317.

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Dishwasher resistance of glass articles is one of the most important quality criteria for glass tableware manufacturer. Dishwasher corrosion of glass and the resulting formation of unacceptable appearance limits the lifetime of glass tableware in private households and even more in professional catering business where constant replacement of glass tableware is a considerable cost factor. Usually glasses undergo through some reactions in an atmospheric corrosion process, which is known as “weathering” or “warehouse effect”. This phenomenon is found to trigger the formation of defects during dishwashing and, visible defects such as cloudiness and iridescence are formed on the glass surface after certain dishwasher cycles depending upon the degree of the atmospheric corrosion that has already been formed on the surface prior to washing. Consequently atmospheric corrosion resistance is an important parameter for dishwasher resistance. The present paper comprehensively investigates the glass corrosion behavior during dishwashing and the effect of glass composition on improved dishwasher resistance by rendering the glass less prone to atmospheric corrosion even under severe conditions.
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Ma, Haoran, and Roland Bennewitz. "Relationship between corrosion and nanoscale friction on a metallic glass." Beilstein Journal of Nanotechnology 13 (February 18, 2022): 236–44. http://dx.doi.org/10.3762/bjnano.13.18.

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Metallic glasses are promising materials for microdevices, although corrosion and friction limit their effectiveness and durability. We investigated nanoscale friction on a metallic glass in corrosive solutions after different periods of immersion time using atomic force microscopy to elucidate the influence of corrosion on nanoscale friction. The evolution of friction upon repeated scanning cycles on the corroded surfaces reveals a bilayer surface oxide film, of which the outer layer is removed by the scanning tip. The measurement of friction and adhesion allows one to compare the physicochemical processes of surface dissolution at the interface of the two layers. The findings contribute to the understanding of mechanical contacts with metallic glasses under corrosive conditions by exploring the interrelation of microscopic corrosion mechanisms and nanoscale friction.
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Wang, Yong Sheng, Ming Jen Tan, and Anders W. E. Jarfors. "Corrosion Behavior and Surface Analysis of Melt-Spun Mg-Based Metallic Glass in Physiological Saline Solution." Materials Science Forum 706-709 (January 2012): 606–11. http://dx.doi.org/10.4028/www.scientific.net/msf.706-709.606.

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The developed Mg-based metallic glass shows great potential as implants in biomedical applications instead of crystalline Mg alloys, which may possesses acceptable corrosion properties. In this study, corrosion behaviors of melt-spun amorphous Mg67Zn28Ca5 ribbons were investigated in physiological saline solution. Electrochemical testing and hydrogen evolution rate indicated that the glassy ribbons obtained at lower wheel speed were more noble with smaller corrosion current, and possessed a comparatively lower corrosion rate in physiological saline solution. Surface morphology analysis revealed that glassy Mg67Zn28Ca5 ribbons exhibited a strong susceptibility to localized pitting corrosion. A Zn-rich passive layer was formed on the surfaces of the glassy ribbons, indicating that Zn was an effective alloying element to enhance the corrosion resistance of amorphous Mg67Zn28Ca5 alloys.
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Rodriguez, Ernesto L. "Corrosion of glass fibres." Journal of Materials Science Letters 6, no. 6 (June 1987): 718–20. http://dx.doi.org/10.1007/bf01770937.

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Dunkl, Michael. "Boundary Layers Refractory/Glass Melt and Glass Defects." Advanced Materials Research 39-40 (April 2008): 601–6. http://dx.doi.org/10.4028/www.scientific.net/amr.39-40.601.

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In this paper the formation of boundary layers and their behaviour regarding corrosion and glass defect potential of different refractory/glass melt combinations will be discussed. The reaction between refractories and glass melts is determined by the diffusion of the different ions from the glass melt into the refractory material and vice versa. The connected solution reactions lead to the formation of a saturation boundary layer, which influences the corrosion behaviour and the glass defect potential. The behaviour of the boundary layers of various refractory/glass melt types are partly complete different. On the one side there are refractory/glass melt combinations which form a relative thick reaction layer, on the other side there are refractory/glass melt combinations with very thin boundary layers. Thick reaction layers affect in the most cases like a protection layer with a good corrosion resistance, but there can be a relative high glass defect potential at operation changes. Thin reaction layers have for the most cases a low glass defect potential, but partly a higher corrosion rate.
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Dissertations / Theses on the topic "Glass corrosion"

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de, Carvalho Joana Nunes. "The Corrosion of Float Glass." Thesis, University of Surrey, 2010. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.518719.

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Saewong, Pakamard. "Erosion of glass and glass-ceramic matrix composites." Thesis, Imperial College London, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.300838.

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Lenting, Christoph [Verfasser]. "Glass corrosion : Towards a Unifying Mechanistic Model / Christoph Lenting." Bonn : Universitäts- und Landesbibliothek Bonn, 2019. http://d-nb.info/1201727863/34.

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Lynch, Matthew Earl. "The Effect of Microwaves on Aqueous Corrosion of Glass." Thesis, Virginia Tech, 2003. http://hdl.handle.net/10919/34187.

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Glass corrodes in aqueous environments. The corrosion process is well-understood for many circumstances involving long periods of time at room temperature as well as processes that involve conventional heating, but the effect of microwave energy on glass corrosion has never been fully investigated. It was suspected that microwaves may alter or accelerate the aqueous corrosion processes that occur in glass which contribute to migration into foods or other materials. Lithium disilicate (Li2O-2SiO2) and commercial soda-lime glass were corroded using both conventional and microwave heating in this study. The results did not clearly show substantial differences in corrosion under the test conditions, but leave open the possibility of an altered mechanism in some circumstances. These findings suggest the need for testing at a lower microwave frequency, specifically 2.45 GHz.
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Lynch, Matthew. "The Effect of Microwaves on Aqueous Corrosion of Glass." Thesis, Virginia Tech, 2006. http://hdl.handle.net/10919/34187.

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Glass corrodes in aqueous environments. The corrosion process is well-understood for many circumstances involving long periods of time at room temperature as well as processes that involve conventional heating, but the effect of microwave energy on glass corrosion has never been fully investigated. It was suspected that microwaves may alter or accelerate the aqueous corrosion processes that occur in glass which contribute to migration into foods or other materials. Lithium disilicate (Li2O-2SiO2) and commercial soda-lime glass were corroded using both conventional and microwave heating in this study. The results did not clearly show substantial differences in corrosion under the test conditions, but leave open the possibility of an altered mechanism in some circumstances. These findings suggest the need for testing at a lower microwave frequency, specifically 2.45 GHz.
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Sundaram, S. K. "Corrosion and electrochemical protection of molybdenum and molybdenum disilicide in molten silicate glass environments." Diss., Georgia Institute of Technology, 1994. http://hdl.handle.net/1853/18906.

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Li, Chunling. "Al-Co-Ce glass forming alloys and their corrosion behaviour." Thesis, University of Nottingham, 2014. http://eprints.nottingham.ac.uk/14473/.

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There is growing interest in Al-TM (transition metal)-RE (rare earth) amorphous alloys because of the combination of their good mechanical properties and corrosion resistance. However, the high critical cooling rate required to form the amorphous structure leads to difficulties in generating bulk amorphous material. Therefore, there has been greater interest in producing amorphous Al-TM-RE alloys as surface layers. In this study, wedge mould casting, laser surface melting (LSM) and large area electron beam (LAEB) surface melting were used to fabricate Al Co-Ce alloys in both crystalline and amorphous form. An eutectic Al 33Cu (wt.%) alloy was also used to quantify the solidification conditions based on the well-known relationship. The microstructures formed by different processes were investigated by scanning electron microscopy, energy dispersive X-ray spectroscopy, image analysis and X ray and glancing angle X-ray diffraction. In particular, LAEB surface melting was found to be able to provide a sufficiently high solidification velocity for the generation of an amorphous layer on the remelted surface of bulk crystalline Al Co-Ce alloys. Experimental results show that the LAEB treatment can remelt, homogenise the multiphase crystalline starting material and generate a predominantly amorphous layer, although it also caused cracking of the treated layer. However, the cracking was largely reduced in the laser refined starting microstructure. Laser microstructural refinement also improved the homogenisation and amorphisation generated by the subsequent LAEB treatment. The temperature field of multi-pulse LAEB irradiated Al-Co-Ce and Al-Cu alloys was numerically simulated through a finite difference method. The simulation results were generally consistent with the experimental results. The corrosion behaviour of Al-Co-Ce alloys with different microstructures was studied through potentiodynamic polarisation tests. Al-Co-Ce amorphous layer exhibited an enhanced corrosion resistance compared to the crystalline counterpart, although cracking in the amorphous layer greatly influenced the effectiveness of the amorphous layer protecting the substrate.
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Zhang, Li [Verfasser]. "Exploring float glass powder as corrosion resistant glass coating applied to concrete by flame spraying / Li Zhang." Aachen : Hochschulbibliothek der Rheinisch-Westfälischen Technischen Hochschule Aachen, 2014. http://d-nb.info/1054632707/34.

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Farn, Sharon. "Thermochemical corrosion of alumina-zirconia-silica refractories for glass furnace regenerators." Thesis, Keele University, 2004. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.522676.

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McMillan, Alan Robert. "Environmental degradation of glass reinforced polyesters in the wastewater treatment industry." Thesis, University of Nottingham, 1997. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.362912.

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Books on the topic "Glass corrosion"

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A, Pecoraro George, Marra James C, Wenzel John T, American Ceramic Society Meeting, and American Ceramic Society Meeting, eds. Corrosion of materials by molten glass. Westerville, Ohio: American Ceramic Society, 1996.

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C, Cunnane J., Bates John K, and United States. Dept. of Energy. High-Level Waste Division, eds. High-level waste borosilicate glass: A compendium of corrosion characteristics. [Washington, D.C.?]: U.S. Dept. of Energy, Office of Waste Management, Office of Eastern Waste Management Operations, High-Level Waste Division, 1994.

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C, Cunnane J., Bates John K, and United States. Dept. of Energy. High-level Waste Division., eds. High-level waste borosilicate glass: A compendium of corrosion characteristics. [United States]: U.S. Dept. of Energy, Office of Waste Management, Office of Eastern Waste Management Operations, High-Level Waste Division, 1994.

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C, Cunnane J., Bates John K, and United States. Dept. of Energy. High-level Waste Division., eds. High-level waste borosilicate glass: A compendium of corrosion characteristics. [Washington, D.C.?]: U.S. Dept. of Energy, Office of Waste Management, Office of Eastern Waste Management Operations, High-Level Waste Division, 1994.

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C, Cunnane J., Bates John K, and United States. Dept. of Energy. High-Level Waste Division., eds. High-level waste borosilicate glass: A compendium of corrosion characteristics. [Washington, D.C.?]: U.S. Dept. of Energy, Office of Waste Management, Office of Eastern Waste Management Operations, High-Level Waste Division, 1994.

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C, Cunnane J., Bates John K, and United States. Dept. of Energy. High-Level Waste Division, eds. High-level waste borosilicate glass: A compendium of corrosion characteristics. [Washington, D.C.?]: U.S. Dept. of Energy, Office of Waste Management, Office of Eastern Waste Management Operations, High-Level Waste Division, 1994.

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C, Cunnane J., Bates John K, and United States. Dept. of Energy. High-level Waste Division., eds. High-level waste borosilicate glass: A compendium of corrosion characteristics. [Washington, D.C.?]: U.S. Dept. of Energy, Office of Waste Management, Office of Eastern Waste Management Operations, High-Level Waste Division, 1994.

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Engineers, Society of Automotive, and SAE World Congress (2007 : Detroit, Mich.), eds. Body engineering and design, glass applications, corrosion prevention and design tools. Warrendale, PA: Society of Automotive Engineers, 2007.

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E, Clark David, and Zoitos Bruce K, eds. Corrosion of glass, ceramics, and ceramic superconductors: Principles, testing, characterization, and applications. Park Ridge, N.J: Noyes, 1992.

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Byers, C. D. A study of natural glass analogues as applied to alteration of nuclear waste glass. Argonne, Ill: Argonne National Laboratory, Chemical Technology Division, 1987.

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Book chapters on the topic "Glass corrosion"

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Hench, L. L. "Glass Corrosion." In Glass … Current Issues, 551–54. Dordrecht: Springer Netherlands, 1985. http://dx.doi.org/10.1007/978-94-009-5107-5_44.

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Grambow, B. "Corrosion of Glass." In Uhlig's Corrosion Handbook, 399–419. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2011. http://dx.doi.org/10.1002/9780470872864.ch29.

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Gy, R. "Stress Corrosion of Glass." In Physical Aspects of Fracture, 305–20. Dordrecht: Springer Netherlands, 2001. http://dx.doi.org/10.1007/978-94-010-0656-9_22.

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Weissmann, R., and R. Drewello. "Attack on Glass." In Microbially Influenced Corrosion of Materials, 339–52. Berlin, Heidelberg: Springer Berlin Heidelberg, 1996. http://dx.doi.org/10.1007/978-3-642-80017-7_24.

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Hull, D. "Stress Corrosion of Glass Reinforced Composites." In Glass … Current Issues, 595–96. Dordrecht: Springer Netherlands, 1985. http://dx.doi.org/10.1007/978-94-009-5107-5_50.

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Michalske, Terry A. "Fractography of Stress Corrosion Cracking in Glass." In Fractography of Glass, 111–42. Boston, MA: Springer US, 1994. http://dx.doi.org/10.1007/978-1-4899-1325-8_4.

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Kaiser, J. P., S. Trümpler, and P. Raschle. "Fungal Growth on Medieval Glass Paintings." In Microbially Influenced Corrosion of Materials, 353–57. Berlin, Heidelberg: Springer Berlin Heidelberg, 1996. http://dx.doi.org/10.1007/978-3-642-80017-7_25.

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Heimerl, Wilfried, Friedrich G. K. Baucke, Peter Brix, and Reinhard Conradt. "Chemical Resistance and Corrosion, and Ion Release." In Analysis of the Composition and Structure of Glass and Glass Ceramics, 399–450. Berlin, Heidelberg: Springer Berlin Heidelberg, 1999. http://dx.doi.org/10.1007/978-3-662-03746-1_5.

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Paskocimas, C. A., E. R. Leite, E. Longo, W. Kobayashi, M. Zorrozua, and J. A. Varela. "Determination of Corrosion Factors in Glass Furnaces." In A Collection of Papers Presented at the 58th Conference on Glass Problems: Ceramic Engineering and Science Proceedings, Volume 19, Issue 1, 75–88. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2008. http://dx.doi.org/10.1002/9780470294468.ch6.

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Winder, SM, and KR Selkregg. "Corrosion of Refractories in Glass-Melting Application." In Ceramic Transactions Series, 195–221. 735 Ceramic Place, Westerville, Ohio 43081: The American Ceramic Society, 2012. http://dx.doi.org/10.1002/9781118370940.ch10.

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Conference papers on the topic "Glass corrosion"

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Zhou, You, Jiuwang Wang, Yun Wang, Yang Fu, Ran Zhao, and Peng Jiao. "Study on corrosion of optical glass." In AI in Optics and Photonics, edited by Jun Tanida, Yadong Jiang, Dong Liu, John Greivenkamp, HaiMei Gong, and Jin Lu. SPIE, 2019. http://dx.doi.org/10.1117/12.2547469.

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Pyszel, Richard. "Effects of Fretting Corrosion on Lift Glass." In SAE 2011 World Congress & Exhibition. 400 Commonwealth Drive, Warrendale, PA, United States: SAE International, 2011. http://dx.doi.org/10.4271/2011-01-1434.

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Kuznetsova, Marta, and Iryna Lutsyuk. "Corrosion Resistant Two-Layer Glass-Ceramic Coating." In Chemical technology and engineering. Lviv Polytechnic National University, 2019. http://dx.doi.org/10.23939/cte2019.01.178.

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Lemmens, Karel, Marc Aertsens, Véra Pirlet, Hélène Serra, Elie Valcke, Pierre De Cannière, and Pierre Van Iseghem. "Measurement of Glass Corrosion in Boom Clay Disposal Conditions." In ASME 2001 8th International Conference on Radioactive Waste Management and Environmental Remediation. American Society of Mechanical Engineers, 2001. http://dx.doi.org/10.1115/icem2001-1286.

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Abstract To estimate the life-time of vitrified high level waste (HLW-glass) in geological disposal conditions in Boom Clay, the dissolution behaviour of waste glass has been studied in experiments in surface laboratories and in the HADES underground research facility of SCK•CEN since the 1980’s. The programme consists mainly of dissolution tests. The purpose of these tests is to understand the basic glass dissolution mechanisms, and to demonstrate realistic long-term dissolution rates. The main experimental variables are glass composition, environmental materials, temperature, and test duration. The studied glasses are the COGEMA glass R7T7, and the PAMELA glasses with SM539, SM527 and SM513 glass frit. The environmental materials comprise Boom Clay, metallic corrosion products and engineered barrier materials. Dissolution tests have been performed at temperatures from 40 to 190°C, for test durations from days to several years. The tests are performed with inactive glasses, which can be doped with radionuclides of interest. Because of the importance of silica sorption by the environmental materials, the dissolution test programme was extended with silica diffusion- and sorption tests in Boom Clay and FoCa clay. The interpretation of the experimental results is supported by geochemical and kinetic modeling. In the area of kinetic modeling, both analytical and Monte Carlo codes are applied. The dissolution tests have demonstrated that, although the presence of Boom Clay initially increases the glass dissolution rate, the long-term dissolution rate decreases for diluted clay / clay water slurries. This decrease has not yet been demonstrated for the R7T7 glass in compact Boom Clay, but is expected to occur here also on the long term. The dissolution rate decreases faster after sufficient addition of glass powder to the medium. This was tested in experiments with the R7T7 glass at relatively high clay concentration (2000 g of humid Boom Clay per liter clay water, this is about half the solid/liquid ratio of compact Boom Clay), at 40 and 90°C. Linear interpolation of the long-term mass losses resulted in dissolution rates of ∼ 0.01 g.m−2.day−1. The statistical uncertainties on the dissolution test results did not allow to demonstrate smaller rates. The minimum statistically significant dissolution rate depends on the test conditions. Therefore, the present SCK•CEN programme includes dissolution tests at long-term near-field conditions (this is at 30°C, with compact Boom Clay and FoCa clay), which are considered more representee for the long-term situation. In view of the uncertainties on the experimental long-term dissolution rates and on the long-term dissolution mechanisms, rates smaller than 0.01 g.m−2.day1 (about 1 μ/year) should not be used as best estimate in the present performance assessment studies for disposal in Boom Clay. A constant dissolution rate of 0.01 g.m−2.day−1 would correspond to a dissolution time for a R7T7 glass package of approximately 150 000 years. The minimum dissolution time is of the order of 104 years.
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Xu, Jin-Sha, Chen-Huai Tang, Yi Chen, Fa-Cai Ren, Jun Si, Ju Ding, Pu-Gen Zhang, Yu-Qing Yang, Yan-Nan Du, and Shou-Peng Han. "Effect of Glaze Composition on the Corrosion Resistance of Glass Lining of Glass-Lined Pressure Vessels." In ASME 2020 Pressure Vessels & Piping Conference. American Society of Mechanical Engineers, 2020. http://dx.doi.org/10.1115/pvp2020-21153.

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Abstract Glass-lined pressure vessels are widely used in various corrosion conditions because of their excellent corrosion resistance. Under the same firing process condition, the corrosion-resistant properties of glass-lined vessels are largely dependent upon the glaze composition. In this paper, three kinds of glazes were selected to study the corrosion resistance to acid and alkali of the glass lining. Based on the glaze composition analysis, the corrosion quantity and the micromorphology observations of the corroded surfaces, the effect of glaze composition on the corrosion resistance to acid and alkali of glass lining was discussed. The results showed that the corrosion resistance of glass lining was mainly to the content of SiO2 and the continuity level of [SiO4] skeleton in glass network structure. The higher continuity level of [SiO4] skeleton led to the better physicochemical properties of the glass lining. The addition of the acid resistant oxide TiO2 improved the acid resistance of glass lining. The proper addition of ZrO2 improved the corrosion resistance to acid and alkali. There were two reasons, one of which was that the joining of Zr4+ into the glass network improved the structural integrity, and the other was that the reaction of Zr4+ with OH− produced Zr(OH)4 on the glass lining occurred and formed a shielding lining against alkali when glass lining was in the alkaline condition.
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6

Duparré, Angela, Horst Truckenbrodt, and Friedrich Scheerer. "Surace Corrosion of Thin Film Optical Components." In Optical Interference Coatings. Washington, D.C.: Optica Publishing Group, 1995. http://dx.doi.org/10.1364/oic.1995.wa6.

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Thin film optical components on glass substrates, though designed for application in high quality optical instruments such as microscopes, binoculars, and cameras, have been found to reveal pronounced degradation effects as a result of surface corrosion on the classes. Starting with substrate roughness and defects due to the polishing process, subsequent cleaning procedures and storage of the samples under normal environmental conditions (in particular exposure to humidity) cause further development of the existing as well as the emergence of new morphological defects on the glass surfaces. After covering the substrates with optical coatings, the corrosion process is ongoing, and it is often only after a certain time of exposure to the environment that these effects become actually obvious. This, of course, gives rise to severe shortcomings regarding the overall quality of the final optical component.
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7

Cai, Meng, Longfei Zhang, Feng Guan, Wenkai Zhao, Long Zhang, and Yiguang Jiang. "Study on corrosion process and mechanism of fluoride laser glass fiber." In Optoelectronic Devices and Integration, edited by Buwen Cheng, Jin Guo, and Sen Qian. SPIE, 2023. http://dx.doi.org/10.1117/12.2646324.

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8

Bacon, Diana H., Michael I. Ojovan, B. Peter McGrail, Natalie V. Ojovan, and Irene V. Startsceva. "Vitrified Waste Corrosion Rates From Field Experiment and Reactive Transport Modeling." In ASME 2003 9th International Conference on Radioactive Waste Management and Environmental Remediation. ASMEDC, 2003. http://dx.doi.org/10.1115/icem2003-4509.

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The Hanford Site in southeastern Washington State has been used extensively by the U.S. Department of Energy (DOE) to produce nuclear materials for the U.S. strategic defense arsenal. A large inventory of radioactive and mixed waste has accumulated in 177 buried single- and double-shell tanks. Liquid waste recovered from the tanks will be pre-treated to separate the low activity fraction from the high-level and transuranic wastes. The low-activity waste (LAW) will be immobilized in glass and placed in a near-surface disposal system on the Hanford Site. Vitrifying the LAW will generate over 160,000 m3 of glass. Before the immobilized low-activity waste (ILAW) can be disposed, DOE must approve a performance assessment (PA), which is a document that describes the long-term impacts of the disposal facility on public health and environmental resources. A sound scientific basis for determining the long-term release rates of radionuclides from LAW glasses must be developed if the PA is to be accepted by regulators and stakeholders. To conduct this calculation, Pacific Northwest National Laboratory (PNNL) used a methodology in which the waste form release rate was calculated by modeling the basic physical and chemical processes that are known to control dissolution behavior using a reactive transport code, STORM [1]. This methodology was used instead of empirical extrapolations from laboratory “leaching” experiments commonly used in other PA or in the phenomenological approach of SIA “Radon” [2]. This methodology is preferred because the dissolution rate, and hence radionuclide release rate, from silicate glasses is not a static variable—a constant that can be derived independently of other variables in the system. Glass dissolution rate is a function of three variables (neglecting glass composition itself): temperature, pH, and composition of the fluid contacting the glass. SIA Radon has been running a field experiment for over 12 years to evaluate the behavior of a high sodium glass buried in a loamy soil. The radioactive waste glass (K-26) made from actual intermediate-level waste from the Kursk (RBMK) reactor was manufactured and placed in a shallow trench. The waste stream was 86 mass% NaNO3, very similar to the salt content expected for Hanford LAW. The final glass composition had a Na2O content of roughly 16 mass%, making it very relevant to the glass formulations being considered at Hanford. A joint US DOE-SIA Radon project was devised to validate the modeling approach used for the ILAW PA by modeling glass corrosion in the subsurface experimental facility [3]. This paper gives an estimate of glass corrosion and ion exchange rates for K-26 waste glass based on field measurements.
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Abbas, Naseem, Maryama Hammi, Siham Echihi, and Nida Zahra. "Inhibiting corrosion effect of Phosphate glass on mild steel in acid solution." In 2017 IEEE 3rd International Conference on Engineering Technologies and Social Sciences (ICETSS). IEEE, 2017. http://dx.doi.org/10.1109/icetss.2017.8324185.

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Sheikh, Shamim Ahmed, and Zahra Kharal. "Corrosion-resistant Reinforced Concrete Columns." In IABSE Conference, Kuala Lumpur 2018: Engineering the Developing World. Zurich, Switzerland: International Association for Bridge and Structural Engineering (IABSE), 2018. http://dx.doi.org/10.2749/kualalumpur.2018.0946.

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<p>To address this issue of corrosion of steel in reinforced concrete, large scale columns reinforced with glass fibre reinforced polymer (GFRP) bars were tested under simulated earthquake loads. In addition to the moment - curvature and shear - deflection responses, ductility factors, and work and energy dissipation parameters were used to evaluate column performance. Twenty-five columns with circular and square sections can be compared to investigate variables such as axial load level, amount and type of reinforcement, i.e. GFRP vs steel. GFRP-reinforced columns were found to behave with stable post-peak response and achieved high levels of deformability and energy dissipation. The optimum solution with respect to column strength, stiffness, ductility and energy dissipation, and corrosion resistance appears to be a hybrid column with steel longitudinal bars and GFRP transverse reinforcement.</p>
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Reports on the topic "Glass corrosion"

1

Va'vra, Jaroslav. Corrosion of Glass Windows in DIRC PMTs. Office of Scientific and Technical Information (OSTI), July 2001. http://dx.doi.org/10.2172/787189.

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2

Abrajano, T. A. Jr, W. L. Ebert, and J. S. Luo. Natural analogues of nuclear waste glass corrosion. Office of Scientific and Technical Information (OSTI), January 1999. http://dx.doi.org/10.2172/12000.

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3

Ebert, W. L., and J. K. Bates. Long-term corrosion behavior of environmental assessment glass. Office of Scientific and Technical Information (OSTI), April 1996. http://dx.doi.org/10.2172/215838.

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4

Bourcier, W. L. Waste glass corrosion modeling: Comparison with experimental results. Office of Scientific and Technical Information (OSTI), November 1993. http://dx.doi.org/10.2172/142480.

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Steefel, Carl. Micro-Continuum Modeling of Nuclear Waste Glass Corrosion. Office of Scientific and Technical Information (OSTI), August 2014. http://dx.doi.org/10.2172/1150012.

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Steefel, Carl. Preliminary Simulation of the Corrosion Rate of Archaeological Glass. Office of Scientific and Technical Information (OSTI), January 2014. http://dx.doi.org/10.2172/1131033.

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7

Crawford, Charles L. Letter report on PCT/Monolith glass ceramic corrosion tests. Office of Scientific and Technical Information (OSTI), September 2015. http://dx.doi.org/10.2172/1221777.

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8

Ebert, W. L. The effects of the glass surface area/solution volume ratio on glass corrosion: A critical review. Office of Scientific and Technical Information (OSTI), March 1995. http://dx.doi.org/10.2172/67461.

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Author, Not Given. Accelerating High-Level Waste Glass Corrosion Research with Big Data. Office of Scientific and Technical Information (OSTI), September 2018. http://dx.doi.org/10.2172/1469277.

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Tang, Ming. Characterization and corrosion behavior test of glass ceramic waste form. Office of Scientific and Technical Information (OSTI), October 2015. http://dx.doi.org/10.2172/1237486.

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