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1

Schulz, Stephan, Andreas Kuczkowski, Daniella Schuchmann, Ulrich Flörke, and Martin Nieger. "Group 13−Group 13 Donor−Acceptor Complexes." Organometallics 25, no. 22 (2006): 5487–91. http://dx.doi.org/10.1021/om0606946.

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2

Atwood, David A. "Cationic group 13 complexes." Coordination Chemistry Reviews 176, no. 1 (1998): 407–30. http://dx.doi.org/10.1016/s0010-8545(98)00127-1.

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3

Ong, Christopher M., and Douglas W. Stephan. "1,2-Cyclopentadienyl Diimine−Group 13 Complexes." Inorganic Chemistry 38, no. 22 (1999): 5189–91. http://dx.doi.org/10.1021/ic9903782.

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4

Atwood, David A. "ChemInform Abstract: Cationic Group 13 Complexes." ChemInform 30, no. 12 (2010): no. http://dx.doi.org/10.1002/chin.199912269.

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5

Jaśkowska, Eliza, Iwona Justyniak, Michał K. Cyrański, et al. "Benzoxaborolate ligands in group 13 metal complexes." Journal of Organometallic Chemistry 732 (May 2013): 8–14. http://dx.doi.org/10.1016/j.jorganchem.2013.01.023.

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6

Atwood, David A., Alan H. Cowley, Rodney D. Schluter, Marcus R. Bond, and Carl J. Carrano. "Intramolecularly Base-Stabilized Group 13 Aryloxide Complexes." Inorganic Chemistry 34, no. 8 (1995): 2186–89. http://dx.doi.org/10.1021/ic00112a034.

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7

Nabeshima, Tatsuya, Yusuke Chiba, Takashi Nakamura, and Ryota Matsuoka. "Synthesis and Functions of Oligomeric and Multidentate Dipyrrin Derivatives and their Complexes." Synlett 31, no. 17 (2020): 1663–80. http://dx.doi.org/10.1055/s-0040-1707155.

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The dipyrrin–metal complexes and especially the boron complex 4,4-difluoro-4-bora-3a,4a-diaza-s-indacene (BODIPY) have recently attracted considerable attention because of their interesting properties and possible applications. We have developed two unique and useful ways to extend versatility and usefulness of the dipyrrin complexes. The first one is the linear and macrocyclic oligomerization of the BODIPY units. These arrangements of the B–F moieties of the oligomerized BODIPY units provide sophisticated functions, such as unique recognition ability toward cationic guest, associated with cha
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8

Linton, David J., Paul Schooler, and Andrew E. H. Wheatley. "Group 12 and heavier Group 13 alkali metal 'ate complexes." Coordination Chemistry Reviews 223, no. 1 (2001): 53–115. http://dx.doi.org/10.1016/s0010-8545(01)00379-4.

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9

Goswami, Bhupendra, Ravi Yadav, Christoph Schoo, and Peter W. Roesky. "Neutral and cationic enantiopure group 13 iminophosphonamide complexes." Dalton Transactions 49, no. 3 (2020): 675–81. http://dx.doi.org/10.1039/c9dt04082j.

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10

Muñoz-Hernández, Miguel-Angel, Michael S. Hill, and D. A. Atwood. "Syntheses and reactions of tetrazole-group 13 complexes." Polyhedron 17, no. 13-14 (1998): 2237–42. http://dx.doi.org/10.1016/s0277-5387(98)00057-6.

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11

Wei, Pingrong, and David A. Atwood. "Syntheses and reactions of Saltren–Group 13 complexes." Journal of Organometallic Chemistry 563, no. 1-2 (1998): 87–93. http://dx.doi.org/10.1016/s0022-328x(98)00544-0.

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12

Lugo née Gushwa, Audra F., and Anne F. Richards. "Ketiminate-Supported LiCl Cages and Group 13 Complexes." European Journal of Inorganic Chemistry 2010, no. 13 (2010): 2025–35. http://dx.doi.org/10.1002/ejic.201000123.

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13

Gálvez-Ruiz, Juan Carlos, Carlos Guadarrama-Pérez, Heinrich Nöth, and Angelina Flores-Parra. "Group 13 Complexes of 5-Methyl-1,3,5-dithiazinane." European Journal of Inorganic Chemistry 2004, no. 3 (2004): 601–11. http://dx.doi.org/10.1002/ejic.200300385.

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14

Kuchta, Matthew C., and Gerard Parkin. "Terminal chalcogenido complexes of Group 13 and 14 elements." Coordination Chemistry Reviews 176, no. 1 (1998): 323–72. http://dx.doi.org/10.1016/s0010-8545(98)00123-4.

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15

Thoi, Van S., Jay R. Stork, Douglas Magde, and Seth M. Cohen. "Luminescent Dipyrrinato Complexes of Trivalent Group 13 Metal Ions." Inorganic Chemistry 45, no. 26 (2006): 10688–97. http://dx.doi.org/10.1021/ic061581h.

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16

Ong, Christopher M., Peggy McKarns, and Douglas W. Stephan. "Neutral and Cationic Group 13 Phosphinimine and Phosphinimide Complexes." Organometallics 18, no. 20 (1999): 4197–204. http://dx.doi.org/10.1021/om9904044.

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17

Vollmer, Matthew V., Jing Xie, Ryan C. Cammarota, et al. "Formal Nickelate(−I) Complexes Supported by Group 13 Ions." Angewandte Chemie 130, no. 26 (2018): 7941–45. http://dx.doi.org/10.1002/ange.201803356.

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18

Vollmer, Matthew V., Jing Xie, Ryan C. Cammarota, et al. "Formal Nickelate(−I) Complexes Supported by Group 13 Ions." Angewandte Chemie International Edition 57, no. 26 (2018): 7815–19. http://dx.doi.org/10.1002/anie.201803356.

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19

Beament, James, Mary F. Mahon, Antoine Buchard, and Matthew D. Jones. "Salan group 13 complexes – structural study and lactide polymerisation." New J. Chem. 41, no. 5 (2017): 2198–203. http://dx.doi.org/10.1039/c6nj03844a.

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20

Fischer, Roland A., Thomas Priermeier, and Wolfgang Scherer. "Organo Group 13 metal complexes of d-block elements." Journal of Organometallic Chemistry 459, no. 1-2 (1993): 65–71. http://dx.doi.org/10.1016/0022-328x(93)86056-n.

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21

Linton, David J., Paul Schooler, and Andrew E. H. Wheatley. "ChemInform Abstract: Group 12 and Heavier Group 13 Alkali Metal ′Ate Complexes." ChemInform 32, no. 51 (2010): no. http://dx.doi.org/10.1002/chin.200151247.

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22

Swidan, Ala'aeddeen, and Charles L. B. Macdonald. "Polyether complexes of groups 13 and 14." Chemical Society Reviews 45, no. 14 (2016): 3883–915. http://dx.doi.org/10.1039/c5cs00934k.

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23

Li, Shenggang, Gretchen K. Rothschopf, Bradford R. Sohnlein, and Dong-Sheng Yang. "Ionization and Dissociation Energies of Group 13 Metal Complexes with Group 15 Hydrides." Journal of Physical Chemistry A 106, no. 30 (2002): 6941–44. http://dx.doi.org/10.1021/jp0206471.

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24

Atwood, D. "Salan complexes of the group 12, 13 and 14 elements." Coordination Chemistry Reviews 165, no. 1 (1997): 267–96. http://dx.doi.org/10.1016/s0010-8545(97)00017-9.

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25

Atwood, David A. "Salan complexes of the group 12, 13 and 14 elements." Coordination Chemistry Reviews 165 (October 1997): 267–96. http://dx.doi.org/10.1016/s0010-8545(97)90159-4.

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26

Leiner, Eva, and Manfred Scheer. "Cp* - Migration – an Approach to Novel Group 13 Element Complexes." Phosphorus, Sulfur, and Silicon and the Related Elements 169, no. 1 (2001): 165–68. http://dx.doi.org/10.1080/10426500108546616.

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27

Atwood, David, and Jolin Jegier. "Factors affecting cation formation in group 13 alkyl halide complexes." Chemical Communications, no. 13 (1996): 1507. http://dx.doi.org/10.1039/cc9960001507.

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28

Leiner, Eva, and Manfred Scheer. "A Synthetic Approach to Novel Group 13/15 Element Complexes†." Organometallics 21, no. 21 (2002): 4448–53. http://dx.doi.org/10.1021/om020473+.

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29

Ho, Luong Phong, Lisa Anders, and Matthias Tamm. "Group 13 Element Trihalide Complexes of Anionic N‐Heterocyclic Carbenes." Chemistry – An Asian Journal 15, no. 6 (2020): 845–51. http://dx.doi.org/10.1002/asia.201901774.

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30

Fleischmann, Martin, Stefan Welsch, Hannes Krauss, et al. "Complexes of Monocationic Group 13 Elements with Pentaphospha- and Pentaarsaferrocene." Chemistry - A European Journal 20, no. 13 (2014): 3759–68. http://dx.doi.org/10.1002/chem.201304466.

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31

Lewiński, Janusz, Janusz Zachara, Iwona Justyniak, and Maciej Dranka. "Hydrogen-bond supramolecular structure of group 13 Schiff base complexes." Coordination Chemistry Reviews 249, no. 11-12 (2005): 1185–99. http://dx.doi.org/10.1016/j.ccr.2004.11.013.

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32

Schorn, W., D. Grosse-Hagenbrock, B. Oelkers, and J. Sundermeyer. "Formazanido complexes of heavier group 13 elements aluminium, gallium, and indium." Dalton Transactions 45, no. 3 (2016): 1201–7. http://dx.doi.org/10.1039/c5dt03906a.

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33

Dange, Deepak, Christian P. Sindlinger, Simon Aldridge, and Cameron Jones. "Boryl substituted group 13 metallylenes: complexes with an iron carbonyl fragment." Chemical Communications 53, no. 1 (2017): 149–52. http://dx.doi.org/10.1039/c6cc08449d.

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The first examples of boryl substituted aluminylene and gallylene complexes (see picture, DAB = {(C<sub>6</sub>H<sub>3</sub>Pr<sup>i</sup><sub>2</sub>-2,6)NCH}<sub>2</sub>) have been prepared by reduction of boryl-group 13 dihalide compounds with K<sub>2</sub>[Fe(CO)<sub>4</sub>].
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34

Vasko, Petra, Virva Kinnunen, Jani O. Moilanen, et al. "Group 13 complexes of dipyridylmethane, a forgotten ligand in coordination chemistry." Dalton Transactions 44, no. 41 (2015): 18247–59. http://dx.doi.org/10.1039/c5dt02830b.

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A comprehensive study of the coordination properties of dipyridylmethane (dpma) was performed. The preparation of metal complexes of the type [(dpma)<sub>2</sub>MCl<sub>2</sub>]<sup>+</sup>, [(dpma)MCl<sub>2</sub>]<sup>+</sup>, (M = Al, Ga), (dpma)InCl<sub>3</sub> and (dpma)(BCl<sub>3</sub>)<sub>2</sub> is described along with their characterization.
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35

Hinchliffe, Alan, Francis S. Mair, Eric J. L. McInnes, Robin G. Pritchard, and John E. Warren. "Light group 13 chloride diazadiene complexes: consequences of varying substituent bulk." Dalton Trans., no. 2 (2008): 222–33. http://dx.doi.org/10.1039/b712911d.

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36

Pan, Sudip, Sai Manoj, and Gernot Frenking. "Quadruple bonding of bare group-13 atoms in transition metal complexes." Dalton Transactions 49, no. 42 (2020): 14815–25. http://dx.doi.org/10.1039/d0dt02773a.

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Bonding analysis shows that E–TM(CO)<sub>3</sub><sup>q</sup> bonds possess four bonding components: one strong electron-sharing σ bond E–TM(CO)<sub>3</sub><sup>q</sup>, two π backdonations E⇇TM(CO)<sub>3</sub><sup>q</sup> and one weak σ donation E→TM(CO)<sub>3</sub><sup>q</sup>.
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37

Baker, Robert J., Marcus L. Cole, Cameron Jones, and Mary F. Mahon. "Bidentate N-heterocyclic carbene complexes of Group 13 trihydrides and trihalides." Journal of the Chemical Society, Dalton Transactions, no. 9 (April 5, 2002): 1992–96. http://dx.doi.org/10.1039/b200500j.

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38

Li, Xiao-Wang, Jianrui Su, and Gregory H. Robinson. "Syntheses and molecular structure of organo-group 13 metal carbene complexes." Chemical Communications, no. 23 (1996): 2683. http://dx.doi.org/10.1039/cc9960002683.

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39

Hill, Michael S., Peter B. Hitchcock, and Sophia M. A. Karagouni. "Group 1 and 13 complexes of aryl-substituted bis(phosphinimino)methyls." Journal of Organometallic Chemistry 689, no. 4 (2004): 722–30. http://dx.doi.org/10.1016/j.jorganchem.2003.11.030.

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40

Baker, Robert J., Markus Brym, Cameron Jones, and Mark Waugh. "9-Triptycenyl complexes of group 13 and 15 halides and hydrides." Journal of Organometallic Chemistry 689, no. 4 (2004): 781–90. http://dx.doi.org/10.1016/j.jorganchem.2003.12.014.

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41

Prabusankar, Ganesan, Sandra Gonzalez-Gallardo, Adinarayana Doddi, Christian Gemel, Manuela Winter, and Roland A. Fischer. "Linear Coinage Metal Complexes Stabilized by a Group 13 Metalloid Ligand." European Journal of Inorganic Chemistry 2010, no. 28 (2010): 4415–18. http://dx.doi.org/10.1002/ejic.201000616.

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42

Ganesamoorthy, Chelladurai, Dieter Bläser, Christoph Wölper, and Stephan Schulz. "Temperature-Dependent Electron Shuffle in Molecular Group 13/15 Intermetallic Complexes." Angewandte Chemie 126, no. 43 (2014): 11771–75. http://dx.doi.org/10.1002/ange.201406304.

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43

Cole, Marcus L., Cameron Jones, Peter C. Junk, Marc Kloth, and Andreas Stasch. "Synthesis and Characterization of Thermally Robust Amidinato Group 13 Hydride Complexes." Chemistry - A European Journal 11, no. 15 (2005): 4482–91. http://dx.doi.org/10.1002/chem.200500278.

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44

Frąckiewicz, Kinga, Marian Czerwiński, and Sławomir Siekierski. "Secondary Periodicity in the Tetrahalogeno Complexes of the Group 13 Elements." European Journal of Inorganic Chemistry 2005, no. 19 (2005): 3850–56. http://dx.doi.org/10.1002/ejic.200500257.

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45

Maar, Ryan R., and Joe B. Gilroy. "Group 13 Complexes of Chelating N2O2n−Ligands as Hybrid Molecular Materials." Chemistry - A European Journal 24, no. 48 (2018): 12449–57. http://dx.doi.org/10.1002/chem.201800354.

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46

Kuchta, Matthew C., and Gerard Parkin. "ChemInform Abstract: Terminal Chalcogenido Complexes of Group 13 and 14 Elements." ChemInform 30, no. 11 (2010): no. http://dx.doi.org/10.1002/chin.199911302.

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47

Ganesamoorthy, Chelladurai, Dieter Bläser, Christoph Wölper, and Stephan Schulz. "Temperature-Dependent Electron Shuffle in Molecular Group 13/15 Intermetallic Complexes." Angewandte Chemie International Edition 53, no. 43 (2014): 11587–91. http://dx.doi.org/10.1002/anie.201406304.

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48

Wu, Melissa M., Arran M. Gill, Lu Yunpeng, et al. "Aryl-NHC-group 13 trimethyl complexes: structural, stability and bonding insights." Dalton Transactions 46, no. 3 (2017): 854–64. http://dx.doi.org/10.1039/c6dt04448d.

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Treatment of aromatic N-substituted N-heterocyclic carbenes (NHCs) with trimethylgallium and -indium yielded the new Lewis acid–base adducts (as shown in the Figure). The steric and electronic factors affecting the stability of these complexes were quantified using percent buried volume, topographic steric maps and theoretical studies.
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49

Ioannou, Panayiotis V. "Dimethylphosphinato and dimethylarsinato complexes of group 13 metals and their chemistry." Monatshefte für Chemie - Chemical Monthly 144, no. 6 (2013): 793–802. http://dx.doi.org/10.1007/s00706-013-0935-5.

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50

Mazumder, Lakhya J., Amlan J. Kalita, Shahnaz S. Rohman, et al. "Unsupported Donor–Acceptor Complexes of Noble Gases with Group 13 Elements." ACS Omega 6, no. 12 (2021): 8656–61. http://dx.doi.org/10.1021/acsomega.1c00543.

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