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1

Webster, Owen W., and D. Y. Sogah. "Group transfer polymerization." Kobunshi 36, no. 11 (1987): 808–11. http://dx.doi.org/10.1295/kobunshi.36.808.

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2

BLEDZKI, ANDRZEJ K. "Group - transfer polymerization." Polimery 30, no. 08 (1985): 293–95. http://dx.doi.org/10.14314/polimery.1985.293.

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3

Chen, Yougen, and Toyoji Kakuchi. "Organocatalyzed Group Transfer Polymerization." Chemical Record 16, no. 4 (2016): 2161–83. http://dx.doi.org/10.1002/tcr.201600034.

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4

Hertler, Walter R. "Chain transfer in group-transfer polymerization." Macromolecules 20, no. 12 (1987): 2976–82. http://dx.doi.org/10.1021/ma00178a004.

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5

Sogah, Dotsevi Y., Walter R. Hertler, Owen W. Webster, and Gordon M. Cohen. "Group transfer polymerization - polymerization of acrylic monomers." Macromolecules 20, no. 7 (1987): 1473–88. http://dx.doi.org/10.1021/ma00173a006.

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6

Brittain, William J., and Ira B. Dicker. "Termination in group-transfer polymerization." Macromolecules 22, no. 3 (1989): 1054–57. http://dx.doi.org/10.1021/ma00193a010.

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7

Brittain, William J. "A Review of Group-Transfer Polymerization." Rubber Chemistry and Technology 65, no. 3 (1992): 580–600. http://dx.doi.org/10.5254/1.3538630.

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Abstract Group-transfer polymerization is a very useful synthetic method for the preparation of acrylic ester polymers. This living polymerization process works well at room temperature and can be used to prepare a wide variety of complex polymer structures. Mechanistic work suggests that GTP is a form of anionic polymerization where propagation occurs via a small concentration of enolate anions which are in equilibrium with dormant silyl ketene acetal chain ends. GTP will find the most use in specialty applications including dispersants, toners, photoresists, and rheology control agents.
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8

Ute, Koichi, Toshiyuki Tarao, and Koichi Hatada. "Group Transfer Polymerization of Methyl Crotonate." Polymer Journal 29, no. 11 (1997): 957–58. http://dx.doi.org/10.1295/polymj.29.957.

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9

Bywater, Stanley. "Group transfer polymerization - A critical overview." Makromolekulare Chemie. Macromolecular Symposia 67, no. 1 (1993): 339–50. http://dx.doi.org/10.1002/masy.19930670127.

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10

Quirk, Roderic P., Jie Ren, and Gregory Bidinger. "Mechanistic aspects of group transfer polymerization." Makromolekulare Chemie. Macromolecular Symposia 67, no. 1 (1993): 351–63. http://dx.doi.org/10.1002/masy.19930670128.

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11

Brittain, William J., and Ira B. Dicker. "Termination processes in group transfer polymerization." Makromolekulare Chemie. Macromolecular Symposia 67, no. 1 (1993): 373–86. http://dx.doi.org/10.1002/masy.19930670130.

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12

Sogah, Dotsevi Y. "Functional Polymers by Group Transfer Polymerization." Kobunshi 41, no. 2 (1992): 90–93. http://dx.doi.org/10.1295/kobunshi.41.90.

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13

Kassi, Eleni, Michalis S. Constantinou, and Costas S. Patrickios. "Group transfer polymerization of biobased monomers." European Polymer Journal 49, no. 4 (2013): 761–67. http://dx.doi.org/10.1016/j.eurpolymj.2012.11.012.

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14

Chen, Yougen, and Yuansheng Ding. "Recent Progress of Organocatalyzed Group Transfer Polymerization." Acta Chimica Sinica 78, no. 8 (2020): 733. http://dx.doi.org/10.6023/a20040115.

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15

Hertler, W. R., D. Y. Sogah, and F. P. Boettcher. "Group-transfer polymerization on a polymeric support." Macromolecules 23, no. 5 (1990): 1264–68. http://dx.doi.org/10.1021/ma00207a007.

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16

Collins, Scott, and David G. Ward. "Group-transfer polymerization using cationic zirconocene compounds." Journal of the American Chemical Society 114, no. 13 (1992): 5460–62. http://dx.doi.org/10.1021/ja00039a088.

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17

Saito, Atsushi, and David A. Tirrell. "Group Transfer Polymerization of N-Substituted Maleimides." Polymer Journal 26, no. 2 (1994): 169–77. http://dx.doi.org/10.1295/polymj.26.169.

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18

Hertler, Walter R. "Group-transfer polymerization: Recent advances and applications." Macromolecular Symposia 88, no. 1 (1994): 55–69. http://dx.doi.org/10.1002/masy.19940880106.

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19

Fuchise, Keita, Yougen Chen, Toshifumi Satoh, and Toyoji Kakuchi. "Recent progress in organocatalytic group transfer polymerization." Polymer Chemistry 4, no. 16 (2013): 4278. http://dx.doi.org/10.1039/c3py00278k.

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20

Boettcher, F. Peter. "Controlled polymerization of silyl vinyl ethers by aldol group transfer polymerization." Makromolekulare Chemie. Macromolecular Symposia 13-14, no. 1 (1988): 193–202. http://dx.doi.org/10.1002/masy.19880130115.

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21

Quirk, Roderic P., and Jie Ren. "Mechanistic studies of group transfer polymerization. Silyl group exchange studies." Macromolecules 25, no. 24 (1992): 6612–20. http://dx.doi.org/10.1021/ma00050a034.

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22

Simon, Peter F. W., and Axel H. E. Müller. "Kinetic Investigation of Self-Condensing Group Transfer Polymerization." Macromolecules 37, no. 20 (2004): 7548–58. http://dx.doi.org/10.1021/ma0358834.

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23

Xiong, Silei, D. Keith Steelman, Grigori A. Medvedev, W. Nicholas Delgass, Mahdi M. Abu-Omar, and James M. Caruthers. "Selective Degenerative Benzyl Group Transfer in Olefin Polymerization." ACS Catalysis 4, no. 4 (2014): 1162–70. http://dx.doi.org/10.1021/cs500021g.

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24

Müller, Axel H. E. "Group transfer and anionic polymerization: A critical comparison." Makromolekulare Chemie. Macromolecular Symposia 32, no. 1 (1990): 87–104. http://dx.doi.org/10.1002/masy.19900320109.

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25

Webster, Owen W. "The discovery and commercialization of group transfer polymerization." Journal of Polymer Science Part A: Polymer Chemistry 38, no. 16 (2000): 2855–60. http://dx.doi.org/10.1002/1099-0518(20000815)38:16<2855::aid-pola10>3.0.co;2-s.

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26

Simon, Peter F. W., Wolfgang Radke, and Axel H. E. Müller. "Hyperbranched methacrylates by self-condensing group transfer polymerization." Macromolecular Rapid Communications 18, no. 9 (1997): 865–73. http://dx.doi.org/10.1002/marc.1997.030180915.

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27

Hirabayashi, Tadamichi, Tetsukazu Itoh, and Kenji Yokota. "Group Transfer and Cationic Polymerization of 1-Butadienyloxytrimethylsilane." Polymer Journal 20, no. 11 (1988): 1041–48. http://dx.doi.org/10.1295/polymj.20.1041.

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28

Rathnayake, Hemali P., and Todd Emrick. "Grafting-from Nanoparticles Using Aldol Group Transfer Polymerization." Macromolecules 41, no. 9 (2008): 2969–71. http://dx.doi.org/10.1021/ma800571c.

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29

Simon, Peter F. W., and Axel H. E. Müller. "Kinetic Investigations of Self-Condensing Group Transfer Polymerization." Macromolecular Symposia 240, no. 1 (2006): 83–92. http://dx.doi.org/10.1002/masy.200650811.

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30

Kawakami, Susumu, Atsushi Kameyama, Mitsuhiro Miyata, and Tadatomi Nishikubo. "Center-Propagating Type Polymerization of Thiirane Using an Acyl-Group Transfer Polymerization." Polymer Journal 29, no. 6 (1997): 550–52. http://dx.doi.org/10.1295/polymj.29.550.

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31

Theis, Alexander, Martina H. Stenzel, Thomas P. Davis, Michelle L. Coote, and Christopher Barner-Kowollik. "A Synthetic Approach to a Novel Class of Fluorine-Bearing Reversible Addition - Fragmentation Chain Transfer (RAFT) Agents: F-RAFT." Australian Journal of Chemistry 58, no. 6 (2005): 437. http://dx.doi.org/10.1071/ch05069.

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A synthetic route is described to a novel class of reversible addition–fragmentation chain transfer (RAFT) agents bearing a fluorine Z-group. Such F-RAFT agents are theoretically predicted to allow living free radical polymerization of various monomers without affecting the rate of polymerization, and should also facilitate the construction of block copolymers from monomers with disparate reactivity. The class of F-RAFT agents is exemplified by the example of benzyl fluoro dithioformate (BFDF) in styrene free-radical polymerizations and the process is shown to induce living polymerization.
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32

Hertler, Walter R., T. V. RajanBabu, Derick W. Ovenall, Gade S. Reddy, and Dotsevi Y. Sogah. "Group transfer polymerization with polyunsaturated esters and silyl polyenolates." Journal of the American Chemical Society 110, no. 17 (1988): 5841–53. http://dx.doi.org/10.1021/ja00225a040.

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33

Dicker, Ira B., Gordon M. Cohen, William B. Farnham, Walter R. Hertler, Evan D. Laganis, and Dotsevi Y. Sogah. "Oxyanions catalyze group-transfer polymerization to give living polymers." Macromolecules 23, no. 18 (1990): 4034–41. http://dx.doi.org/10.1021/ma00220a002.

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34

Sato, Tsuneyuki, Kazuhiro Miki, and Makiko Seno. "Radical Group-Transfer Polymerization of 2-Thiocyanatoethyl Vinyl Ether." Macromolecules 32, no. 13 (1999): 4166–72. http://dx.doi.org/10.1021/ma9819283.

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35

Vamvakaki, Maria, Edna N. Yamasaki, Stella C. Hadjiyannakou, and Costas S. Patrickios. "Characterization of hydrophilic networks synthesized by group transfer polymerization." Macromolecular Symposia 171, no. 1 (2001): 209–24. http://dx.doi.org/10.1002/1521-3900(200106)171:1<209::aid-masy209>3.0.co;2-u.

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36

Salzinger, Stephan, and Bernhard Rieger. "Rare Earth Metal-Mediated Group Transfer Polymerization of Vinylphosphonates." Macromolecular Rapid Communications 33, no. 16 (2012): 1327–45. http://dx.doi.org/10.1002/marc.201200278.

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37

Mueller, Axel H. E. "Kinetic Discrimination between Various Mechanisms in Group-Transfer Polymerization." Macromolecules 27, no. 7 (1994): 1685–90. http://dx.doi.org/10.1021/ma00085a004.

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38

Jenkins, A. D. "Enolate ions and the initiation of “group-transfer” polymerization." European Polymer Journal 27, no. 7 (1991): 649. http://dx.doi.org/10.1016/0014-3057(91)90150-m.

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39

Ute, Koichi, Toshiyuki Tarao, and Tatsuki Kitayama. "Enhanced Stereocontrol in Disyndiotactic-specific Group Transfer Polymerization of Methyl Crotonate—Stereochemical Evidence of Group Transfer." Polymer Journal 37, no. 8 (2005): 578–83. http://dx.doi.org/10.1295/polymj.37.578.

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40

Moad, Catherine L., and Graeme Moad. "Fundamentals of reversible addition–fragmentation chain transfer (RAFT)." Chemistry Teacher International 3, no. 2 (2020): 3–17. http://dx.doi.org/10.1515/cti-2020-0026.

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Abstract Radical polymerization is transformed into what is known as reversible addition–fragmentation chain transfer (RAFT) polymerization by the addition of a RAFT agent. RAFT polymerization enables the preparation of polymers with predictable molar mass, narrow chain length distribution, high end-group integrity and provides the ability to construct macromolecules with the intricate architectures and composition demanded by modern applications in medicine, electronics and nanotechnology. This paper provides a background to understanding the mechanism of RAFT polymerization and how this tech
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41

Sakamoto, Kenkichi, Takuji Aimiya, and Mitsuo Kira. "Preparation of Hyperbranched Polymethacrylates by Self-Condensing Group Transfer Polymerization." Chemistry Letters 26, no. 12 (1997): 1245–46. http://dx.doi.org/10.1246/cl.1997.1245.

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42

Krupers, Maarten J., and Martin Möller. "Synthesis and characterization of semifluorinated polymers via group transfer polymerization." Journal of Fluorine Chemistry 82, no. 2 (1997): 119–24. http://dx.doi.org/10.1016/s0022-1139(96)03569-5.

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43

Adams, Friederike, Martin R. Machat, Peter T. Altenbuchner, et al. "Toolbox of Nonmetallocene Lanthanides: Multifunctional Catalysts in Group-Transfer Polymerization." Inorganic Chemistry 56, no. 16 (2017): 9754–64. http://dx.doi.org/10.1021/acs.inorgchem.7b01261.

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44

Takenaka, Yasumasa, and Hideki Abe. "Group-Transfer Polymerization of Various Crotonates Using Organic Acid Catalysts." Macromolecules 52, no. 11 (2019): 4052–58. http://dx.doi.org/10.1021/acs.macromol.9b00272.

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45

Kim, Yang Bae, Weon Jung Choi, Byung Seok Choi, and Sam Kwon Choi. "Cyclopolymerization of 2,6-dicarbomethoxy-1,6-heptadiene by group-transfer polymerization." Macromolecules 24, no. 18 (1991): 5006–8. http://dx.doi.org/10.1021/ma00018a005.

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46

Sumi, Hiroshi, Atsushi Suzuki, Tadamichi Hirabayashi, Yoshihito Inai, and Kenji Yokota. "Kinetic Study on the Group Transfer Polymerization of 1-Butadienyloxytrimethylsilane." Polymer Journal 26, no. 6 (1994): 705–14. http://dx.doi.org/10.1295/polymj.26.705.

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47

Shimano, Yasuo, Kumiko Sato, and Shiro Kobayashi. "Group Transfer Polymerization of Methacryl-Type Poly(2-oxazoline) Macromonomers." Polymer Journal 31, no. 5 (1999): 458–63. http://dx.doi.org/10.1295/polymj.31.458.

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48

Hertler, Walter R. "Vinylphosphonic esters as end-capping agents in group transfer polymerization." Journal of Polymer Science Part A: Polymer Chemistry 29, no. 6 (1991): 869–73. http://dx.doi.org/10.1002/pola.1991.080290611.

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49

Webster, Owen W. "Molecular architecture control in acrylic polymers by group transfer polymerization." Makromolekulare Chemie. Macromolecular Symposia 53, no. 1 (1992): 307–15. http://dx.doi.org/10.1002/masy.19920530128.

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50

Webster, Owen W. "Molecular architecture control in acrylic polymers by group transfer polymerization." Makromolekulare Chemie. Macromolecular Symposia 70-71, no. 1 (1993): 75–81. http://dx.doi.org/10.1002/masy.19930700111.

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