Academic literature on the topic 'Group transfer reactions'

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Journal articles on the topic "Group transfer reactions"

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Schafer, Andrew G., and Simon B. Blakey. "Ir-Catalyzed enantioselective group transfer reactions." Chemical Society Reviews 44, no. 17 (2015): 5969–80. http://dx.doi.org/10.1039/c5cs00354g.

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Pandey, Ganesh, K. S. S. P. Rao, and K. V. Nageshwar Rao. "PhSeSiR3-Catalyzed Group Transfer Radical Reactions." Journal of Organic Chemistry 65, no. 14 (2000): 4309–14. http://dx.doi.org/10.1021/jo000128z.

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Yamago, Shigeru. "Novel Group-Transfer Radical Reactions with Organotelluriums." Synlett 2004, no. 11 (2004): 1875–90. http://dx.doi.org/10.1055/s-2004-830883.

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Karnik, A. V., and J. P. Rane. "ChemInform Abstract: Group Transfer Reactions Using Benzimidazolides." ChemInform 30, no. 19 (2010): no. http://dx.doi.org/10.1002/chin.199919073.

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Kook Sohn, Chang, Eun Kyung Ma, Chang Kon Kim, Hai Whang Lee, and Ikchoon Lee. "Theoretical studies on thiocarbonyl group transfer reactions." New Journal of Chemistry 25, no. 6 (2001): 859–63. http://dx.doi.org/10.1039/b010202o.

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E. Forbes, Judith, Catherine Tailhan, and Samir Z. Zard. "Dithiocarbonate group transfer in radical chain reactions." Tetrahedron Letters 31, no. 18 (1990): 2565–68. http://dx.doi.org/10.1016/0040-4039(90)80126-7.

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Chow, Toby Wai-Shan, Guo-Qiang Chen, Yungen Liu, Cong-Ying Zhou, and Chi-Ming Che. "Practical iron-catalyzed atom/group transfer and insertion reactions." Pure and Applied Chemistry 84, no. 8 (2012): 1685–704. http://dx.doi.org/10.1351/pac-con-11-11-08.

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Iron-catalyzed reactions are receiving a surge of interest owing to the natural abundance and biocompatibility of Fe and the urge to develop practically useful sustainable catalysis for fine chemical industries. This article is a brief account of our studies on the C–O and C–N bond formation reactions catalyzed by Fe complexes supported by oligopyridine, macrocyclic tetraaza, and fluorinated porphyrin ligands. The working principle is the in situ generation of reactive Fe=O and Fe=NR intermediates supported by these oxidatively robust N-donor ligands for oxygen atom/nitrogen group transfer and
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Fernández, Israel, Miguel A. Sierra, and Fernando P. Cossío. "In-Plane Aromaticity in Double Group Transfer Reactions." Journal of Organic Chemistry 72, no. 4 (2007): 1488–91. http://dx.doi.org/10.1021/jo062310r.

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Kalek, Marcin, Manoj Ghosh, and Adam Rajkiewicz. "Organocatalytic Group Transfer Reactions with Hypervalent Iodine­ Reagents." Synthesis 51, no. 02 (2018): 359–70. http://dx.doi.org/10.1055/s-0037-1609639.

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In recent years, a plethora of synthetic methods that employ hypervalent iodine compounds donating an atom or a group of atoms to an acceptor molecule have been developed. Several of these transformations utilize organocatalysis, which complements well the economic and environmental advantages offered by iodine reagents. This short review provides a systematic survey of the organocatalytic approaches that have been used to promote group transfer from hypervalent iodine species. It covers both the reactions in which an organocatalyst is applied to activate the acceptor, as well as those that ex
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Pandey, Ganesh, K. S. S. P. Rao, and K. V. Nageshwar Rao. "ChemInform Abstract: PhSeSiR3-Catalyzed Group Transfer Radical Reactions." ChemInform 31, no. 46 (2010): no. http://dx.doi.org/10.1002/chin.200046186.

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Dissertations / Theses on the topic "Group transfer reactions"

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Ruppel, Joshua V. "Cobalt(II)-Catalyzed Atom/Group Transfer Reactions: Stereoselective Carbene and Nitrene Transfer Reactions." Scholar Commons, 2008. https://scholarcommons.usf.edu/etd/484.

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Metalloporphyrins have been shown to catalyze many fundamental and practically important chemical transformations, some of which represent the first demonstrations of these catalytic processes. The most notable examples include an assortment of atom/group transfer reactions, such as oxene, nitrene, and carbene transfers. Atom/group transfer reactions allow for the direct conversion of abundant and inexpensive alkenes and alkanes into value-added functional molecules. Previous reports from our group have shown that cobalt-porphyrin based carbene and nitrene transfer reactions are some of the mo
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Luthra, A. K. "Some studies of acyl-group transfer reactions." Thesis, University of Kent, 1985. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.332147.

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Basaif, Salem Ahmad. "Organic reactions in aqueous solution : studies of acyl group transfer." Thesis, University of Kent, 1989. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.328061.

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Zheng, Baofu. "Lewis acid-catalyzed asymmetric atom and group transfer radical cyclization reactions." Click to view the E-thesis via HKUTO, 2005. http://sunzi.lib.hku.hk/hkuto/record/B3625812X.

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Zheng, Baofu, and 鄭保富. "Lewis acid-catalyzed asymmetric atom and group transfer radical cyclization reactions." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2005. http://hub.hku.hk/bib/B3625812X.

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Dowling, Mary J. "Prototropic processes and group transfer reactions in X=Y-ZH systems." Thesis, Queen's University Belfast, 1990. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.335337.

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Soper, Jake D. "Reactions at nitrogenous ligands on oxidizing group 8 metal centers /." Thesis, Connect to this title online; UW restricted, 2003. http://hdl.handle.net/1773/8589.

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Averesch, Kai Florian Gustav. "Novel Cationic Sulfur Reagents and their Application in Electrophilic Group-Transfer Reactions." Doctoral thesis, Niedersächsische Staats- und Universitätsbibliothek Göttingen, 2019. http://hdl.handle.net/21.11130/00-1735-0000-0005-13C9-3.

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Ericsson, Cecilia. "Synthesis of Tetrahydrofuran and Pyrrolidine Derivatives Utilising Radical Reactions : Organochalcogenides in Reductive, Carbonylative and Group-Transfer Cyclisation." Doctoral thesis, Uppsala : Acta Universitatis Upsaliensis : Univ.-bibl. [distributör], 2004. http://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-4018.

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Fields, Kimberly Bliss. "The Design and Synthesis of Functionalized Porphyrins and Their Applications in Group Transfer Reactions, Medicine, and Materials." Scholar Commons, 2010. http://scholarcommons.usf.edu/etd/3461.

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Porphyrins and their analogs are a class of chemically and biologically important compounds that have found a variety of applications in different fields such as catalysis, medicine, and materials. The physical, chemical, and biological dependence of the peripheral substituents of porphyrins on their properties has prompted great effort towards the synthesis of new porphyrins with different electronic, steric, and conformational environments. To this end, porphyrins have been prepared using a modular approach from bromo- and triflate synthons. These synthons underwent palladium-catalyzed cross
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Books on the topic "Group transfer reactions"

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Wissing, Elmo. Group-transfer reactions of diorganozinc and triorganoaluminium reagents with 1,4-diaza-1,3-butadienes ...: Proefschrift ter verkrijging van de graad van doctor ... 1992. [Rijksuniversiteit te Utrecht?], 1993.

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(Editor), Andreas Holzenburg, and Nigel S. Scrutton (Editor), eds. Enzyme-Catalyzed Electron and Radical Transfer (Subcellular Biochemistry Volume 35). Springer, 2000.

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Book chapters on the topic "Group transfer reactions"

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Dinda, Biswanath. "Group Transfer Reactions." In Lecture Notes in Chemistry. Springer International Publishing, 2016. http://dx.doi.org/10.1007/978-3-319-45934-9_5.

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Hatakeyama, Kazuyuki, Yasuo Nemoto, Kunihiro Ueda, and Osamu Hayaishi. "Poly(ADP-Ribose) Glycohydrolase and ADP-Ribosyl Group Turnover." In ADP-Ribose Transfer Reactions. Springer US, 1989. http://dx.doi.org/10.1007/978-1-4615-8507-7_8.

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Stanbury, David M. "Nuclear Factors in Main-Group Electron Transfer Reactions." In Advances in Chemistry. American Chemical Society, 1997. http://dx.doi.org/10.1021/ba-1997-0253.ch010.

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Kaim, Wolfgang. "Thermal and light induced electron transfer reactions of main group metal hydrides and organometallics." In Electron Transfer I. Springer Berlin Heidelberg, 1994. http://dx.doi.org/10.1007/3-540-57565-0_77.

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Choi, Junghoon, Jongsung Yoem, Jongha Lee, Taekee Hong, and Jinsoon Cha. "Alkyl Transfer Reactions of Trialkylborane to the Carbonyl Groups by Electrochemical Method." In Novel Trends in Electroorganic Synthesis. Springer Japan, 1998. http://dx.doi.org/10.1007/978-4-431-65924-2_102.

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Hienerwadel, R., M. Paddock, M. Okamura, E. Nabedryk, J. Breton, and W. Mäntele. "Coupling of Proton Transfer to Electron Transfer in Photosynthetic Reaction Centers: Time-Resolved IR Signals from Carboxyl Group Protonation upon Reduction of QB." In Fifth International Conference on the Spectroscopy of Biological Molecules. Springer Netherlands, 1993. http://dx.doi.org/10.1007/978-94-011-1934-4_116.

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Mandal, Dipak K. "Group Transfer Reactions." In Pericyclic Chemistry. Elsevier, 2018. http://dx.doi.org/10.1016/b978-0-12-814958-4.00010-6.

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Griesbeck, A. G., and E. Zimmermann. "Diazo Group Transfer Reactions." In Quinones and Heteroatom Analogues. Georg Thieme Verlag KG, 2006. http://dx.doi.org/10.1055/sos-sd-028-00783.

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Kumar, Sunil, Vinod Kumar, and S. P. Singh. "Group Transfer, Elimination, and Related Reactions." In Pericyclic Reactions. Elsevier, 2016. http://dx.doi.org/10.1016/b978-0-12-803640-2.00006-3.

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"Group Transfer Reactions: Hydrolysis, Amination, Phosphorylation." In Organic Chemistry of Enzyme-Catalyzed Reactions. Elsevier, 2002. http://dx.doi.org/10.1016/b978-0-08-051336-2.50007-3.

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Conference papers on the topic "Group transfer reactions"

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Kockmann, Norbert, and Dominique M. Roberge. "Liquid-Liquid Test Reactions to Characterize 2-Phase-Mixing in Microchannels." In ASME 2011 9th International Conference on Nanochannels, Microchannels, and Minichannels. ASMEDC, 2011. http://dx.doi.org/10.1115/icnmm2011-58157.

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Multiphase flow is often found in chemical engineering, food processing, or analytics. First contacting and droplet generation as well as coalescence and re-dispersion have high importance for the flow characteristics. In all processes, the channel geometry, fluid properties, and flow velocity determine the flow regime, droplet size, and interfacial area. The hydrolysis of alkyl acetates in organic phase with sodium hydroxide NaOH in the aqueous phase is investigated as flexible test reaction for mass transfer and interfacial area. For right design of the characteristic time for mass transfer,
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Kaneko, H., Y. Naganuma, S. Taku, K. Ouchi, N. Hasegawa, and Y. Tamaura. "Solar H2 Production From a Two-Step Water Splitting Process With Metal (Fe, Ni) Doped Ceria." In ASME 2008 2nd International Conference on Energy Sustainability collocated with the Heat Transfer, Fluids Engineering, and 3rd Energy Nanotechnology Conferences. ASMEDC, 2008. http://dx.doi.org/10.1115/es2008-54281.

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Solar H2 production by the two-step water splitting process with thermochemical reaction has been proposed to convert solar energy into chemical energy. We succeeded in repeating the cyclic two-step water splitting process composed of the O2-releasing and H2-generation reactions with metal (Fe, Ni) doped ceria. The metal doped ceria with low content of metal ion (Fe3+, Ni2+) formed a solid solution with fluorite-type structure between ceria (CeO2) and metal oxide (Fe2O3, NiO). The empirical formula of the solid solution was Ce1-αMαO2−δ (M = Fe, Ni), and it was assumed that the high reactivity
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Chang, S. L., C. Q. Zhou, and B. Golchert. "A Simulation Approach for Bubble Flow in a Glass Melter." In ASME 2002 International Mechanical Engineering Congress and Exposition. ASMEDC, 2002. http://dx.doi.org/10.1115/imece2002-33494.

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Combustion heat is used in glass furnaces to melt sand and cullet (scrap glass) into liquid glass to make products. The glass flow in a melter consists of solid particles of sand/cullet, liquid glass, and bubbles. Bubbles formed in the melting processes due to the glass reactions have strong impacts on glass quality and furnace efficiency. Smaller bubbles entrained in the liquid flow degrade the glass quality. Larger bubbles rise to the top of the melter and form a foam layer that impedes the radiation heat transfer from the combustion space and lowers the furnace efficiency. An Eulerian appro
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Al-Raqom, Fotouh, and James F. Klausner. "Fluidized Bed Kinetics for Hydrogen Production Through Steam Iron Oxidation." In ASME 2013 7th International Conference on Energy Sustainability collocated with the ASME 2013 Heat Transfer Summer Conference and the ASME 2013 11th International Conference on Fuel Cell Science, Engineering and Technology. American Society of Mechanical Engineers, 2013. http://dx.doi.org/10.1115/es2013-18156.

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Kinetic analysis is essential for chemical reactor modeling. This study proposes a methodology to use available kinetic analysis methodologies, including conventional (modelistic) graphical representation, isoconversional (model free), models based on first principles and reduced time scale analysis (Sharp and Hancock procedure) to predict the kinetics of an investigated reaction. Even though these methods have some limitations, a methodology comprised of combining their results can help in determining the kinetic parameters for reaction. The isoconversional approach can be used to determine t
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Huang, Wei, and Wilson K. S. Chiu. "A Mass Transport Model for CVD Coating of Optical Fibers." In ASME 2003 International Mechanical Engineering Congress and Exposition. ASMEDC, 2003. http://dx.doi.org/10.1115/imece2003-43414.

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Carbon coated optical fibers are produced by the chemical vapor deposition process which includes multi-species mass transport with chemical reactions. A proper numerical model of this process will help elucidate the basic mechanisms and optimize the process to improve coating quality. A heat transfer model has been developed in our research group. We are now developing an applicable chemical kinetics model to include mass transport with gas phase and surface reactions. Several different chemical reactor models have been tried, including a continuous-stirred tank reactor (CSTR) model, a plug f
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Li, Yunan, Timothy I. Anderson, and Anthony R. Kovscek. "Ignition Forecast Based on Chemical Kinetics and Uncertainty Quantification." In SPE Western Regional Meeting. SPE, 2021. http://dx.doi.org/10.2118/200874-ms.

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Abstract The description of chemical kinetics is very import to the simulation of reactive transport for enhanced oil recovery (EOR). Characterizing petroleum ignition is especially important for simulation and prediction of In-Situ Combustion (ISC). In order to model crude oil oxidation reactions accurately, an experimental workflow is introduced to obtain kinetic parameters for ISC chemical reaction models. An optimization algorithm assists to match the reaction model parameters to the experimental results, and this validated model is used to predict ignition of crude oil in porous media. Ap
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Ho, Son H., Muhammad M. Rahman, and Aydin K. Sunol. "Prediction of Temperature Distribution in a Food Self-Heating System." In 2010 14th International Heat Transfer Conference. ASMEDC, 2010. http://dx.doi.org/10.1115/ihtc14-23394.

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This paper presents a numerical modeling and simulation of heat transfer in a food self-heating unit for group meals. A model of a water-activated heater based on an exothermic reaction was developed. The resulting governing equations of heat conduction and chemical reaction were solved for an analytical approximate solution, to which experimental data found from literature were compared and curve fitted. Then a model of a complete food-heating unit, which includes a stack of four sets of food tray, heating tray, and heater sandwiched between them, as well as the cardboard container, was devel
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Wibel, Wolf, and Peter Ehrhard. "Experiments on the Laminar/Turbulent Transition of Liquid Flows in Rectangular Micro Channels." In ASME 2007 5th International Conference on Nanochannels, Microchannels, and Minichannels. ASMEDC, 2007. http://dx.doi.org/10.1115/icnmm2007-30037.

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The advances of micro-fabrication techniques allow for the manufacturing of micro heat exchangers or micro reactors. These micro devices are characterized by a large surface-to-volume ratio and, hence, allow for the transfer of large heat fluxes or offer large catalytic surfaces for reactions. The design and optimization of such micro devices heavily relies on correlations for pressure drop and heat transfer, as well as on information on the laminar/turbulent transition. As these questions are still discussed controversially in literature, a careful investigation appears highly desirable. We c
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Duarte, Leonardo José, and Roy Edward Bruns. "Infrared intensities of imaginary frequencies: Gas-Phase SN2 Transition States." In VIII Simpósio de Estrutura Eletrônica e Dinâmica Molecular. Universidade de Brasília, 2020. http://dx.doi.org/10.21826/viiiseedmol202032.

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The gas phase SN2 reaction transition state structures for nine [XCZ_3 Y]^- systems, where X,Y=H,F,Cl and Z = H,F were optimized and their normal modes of vibrations were determined at the QCISD/aug-cc-pVTZ level of theory. Using Quantum Theory of Atoms in Molecules (QTAIM), the atomic charges and atomic dipoles were obtained and used to calculate the Charge – Charge Transfer – Dipolar Polarization (CCTDP) contributions to the imaginary normal mode intensity of transition states. The results show that the imaginary bands are strong, ranging from 1217 to 16086 〖km∙mol〗^(-1), much higher than oc
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Ravishankar, Mahesh, Sandip Mazumder, and Ankan Kumar. "Finite-Volume Solution of the P3 Equations of Radiative Transfer and Coupling to Reacting Flow Calculations." In ASME 2009 Heat Transfer Summer Conference collocated with the InterPACK09 and 3rd Energy Sustainability Conferences. ASMEDC, 2009. http://dx.doi.org/10.1115/ht2009-88014.

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The method of spherical harmonics (or PN) is a popular method for approximate solution of the radiative transfer equation (RTE) in participating media. A rigorous conservative finite-volume (FV) procedure is presented for discretization of the P3 equations of radiative transfer in two-dimensional geometry—a set of four coupled second-order partial differential equations. The FV procedure, presented here, is applicable to any arbitrary unstructured mesh topology. The resulting coupled set of discrete algebraic equations are solved implicitly using a coupled solver that involves decomposition of
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Reports on the topic "Group transfer reactions"

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Atwood, J. D. Group transfer and electron transfer reactions of organometallic complexes. Office of Scientific and Technical Information (OSTI), 1994. http://dx.doi.org/10.2172/10105478.

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Mindiola, Daniel J. Synthesis and Exploratory Catalysis of 3d Metals: Group-Transfer Reactions, and the Activation and Functionalization of Small Molecules Including Greenhouse Gases. Office of Scientific and Technical Information (OSTI), 2014. http://dx.doi.org/10.2172/1130753.

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Mindiola, Daniel. Synthesis and Exploratory Catalysis of 3d Metals: Atom and Group-Transfer Reactions and the Activation and Functionalization of Small Molecules Including Greenhouse Gases. Office of Scientific and Technical Information (OSTI), 2020. http://dx.doi.org/10.2172/1843640.

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Lampland, Nicole Lynn. Beyond alkyl transfer: Synthesis of main group metal (Mg, Ca, Zn) silyl and tris(oxazolinyl)borato complexes and their stoichiometric and catalytic reactions with borane Lewis acids and carbonyls. Office of Scientific and Technical Information (OSTI), 2015. http://dx.doi.org/10.2172/1417988.

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Hansen, Peter J., and Zvi Roth. Use of Oocyte and Embryo Survival Factors to Enhance Fertility of Heat-stressed Dairy Cattle. United States Department of Agriculture, 2011. http://dx.doi.org/10.32747/2011.7697105.bard.

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The overall goal was to identify survival factors that can improve pregnancy success following insemination or embryo transfer in lactating dairy cows exposed to heat stress. First, we demonstrated that oocytes are actually damaged by elevated temperature in the summer. Then we tested two thermoprotective molecules for their effect on oocyte damage caused by heat shock. One molecule, ceramide was not thermoprptective. Another, insulin-like growth factor-1 (IGF) reduced the effects of heat shock on oocyte apoptosis and oocyte cleavage when added during maturation. We also used lactating cows ex
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Ohad, Itzhak, and Himadri Pakrasi. Role of Cytochrome B559 in Photoinhibition. United States Department of Agriculture, 1995. http://dx.doi.org/10.32747/1995.7613031.bard.

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The aim of this research project was to obtain information on the role of the cytochrome b559 in the function of Photosystem-II (PSII) with special emphasis on the light induced photo inactivation of PSII and turnover of the photochemical reaction center II protein subunit RCII-D1. The major goals of this project were: 1) Isolation and sequencing of the Chlamydomonas chloroplast psbE and psbF genes encoding the cytochrome b559 a and b subunits respectively; 2) Generation of site directed mutants and testing the effect of such mutation on the function of PSII under various light conditions; 3)
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[Group transfer and electron transfer reactions of organometallic complexes]: Summary of research accomplished in 1993. Office of Scientific and Technical Information (OSTI), 1993. http://dx.doi.org/10.2172/10113614.

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