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Dissertations / Theses on the topic 'Group viii metal complexes'

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Published: 4 June 2021

Last updated: 17 February 2022

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1

Leese, Troy Adrian. "Polypyridine complexes of group VIII metals." Thesis, University of Cambridge, 1989. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.316723.

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2

France, Marcia Beth Grubbs Robert H. "Olefin metathesis with group VIII transition metal complexes : mechanism, reactivity, and catalyst development /." Diss., Pasadena, Calif. : California Institute of Technology, 1995. http://resolver.caltech.edu/CaltechETD:etd-10122005-083645.

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3

Green, Lisa Marie. "Synthesis, characterization and reactivity of platinum(0)-tetraphosphion complexes and group VIII metal phosphine complexes coordinated to alkoxide and hydroxide ligands /." The Ohio State University, 1987. http://rave.ohiolink.edu/etdc/view?acc_num=osu1487331541709992.

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4

Soules, Régis. "Proprietes cooperatives de complexes polymetalliques des ligands squarate et thiosquarate." Toulouse 3, 1987. http://www.theses.fr/1987TOU30178.

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Etude de l'emploi d'un coordinat assembleur qui puisse par coordination avec le centre metallique utilise (metaux de transition du groupe viii) aboutir a un agencement a une dimension des motifs moleculaires par empilement d'entites monomeres ou par formation de chaines. Par utilisation du coordinat squarate sous ses formes oxygenees et soufrees, obtention d'un certain nombre de complexes de pt, pd, ni et cu repondant aux criteres fixes. Etude des structures de ces composes, de leurs proprietes physiques et de la relation structure-propriete. La nature du coordinat comme le caractere specifiqu

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5

Pounds, Thomas John. "Redox group-functionalised diphosphine complexes." Thesis, University of Liverpool, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.367302.

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6

Jones, A. G. "Synthetic, structural and catalytic studies of metal carbonyl clusters of Group VIII." Thesis, University of Southampton, 1986. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.374567.

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7

Gash, Rosslyn Clare. "Metal haloalkyl in complexes in catalysis." Thesis, University of St Andrews, 1993. http://hdl.handle.net/10023/14706.

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In this thesis, the preparation of a number of halomethyl complexes of rhodium, platinum, and palladium is described. Complexes of the type trans-[Rh(CH2X)X(P4)]+ (X = Cl, Br, I, P = PMe3, dmpe) were found to be unstable, decomposing in situ to give a mixtures of dihalo, trihalo, and phosphine ylide species. Platinum and palladium species of the type trans-M(CH2X)X(PEt3)2 (X = Cl, I, M = Pt, Pd), which were formed by the reaction between M(PEt3)3 CH2XY were also unstable. In the case of platinum, phosphine ylide species were isolated from reaction mixtures, whilst the palladium halomethyl spec

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8

Harding, David James. "Redox-active group 6 transition metal alkyne complexes." Thesis, University of Bristol, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.324328.

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9

Bell, Michael Niall. "Organometallic platinum group metal complexes incorporating macrocyclic ligands." Thesis, University of Edinburgh, 1987. http://hdl.handle.net/1842/13895.

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10

Mayo, Elizabeth Idonia Barton Jacqueline K. "Kinetics and thermodynamics of dye (group VIII metal)-sensitized nanocrystalline titanium dioxide photoelectrodes /." Diss., Pasadena, Calif. : California Institute of Technology, 2004. http://resolver.caltech.edu/CaltechETD:etd-06042004-153530.

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11

Jefferis, Jesse Mark. "The preparation and reactivity of group 5 indenyl complexes." Virtual Press, 1995. http://liblink.bsu.edu/uhtbin/catkey/958792.

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The preparation of tri-n-butylstannylindene, has led to new synthetic routes to obtaining indenyl metal complexes of the Group V metal halides. Also, the fluxional behavior of tri-n-butylstannylindene has been studied by variable temperature 1H NMR spectroscopy.The interaction of the Group V metal halides with tri-n-butylstannylindene has led to the isolation and characterization of [(q5-C9H7)2TaC12] [TaC16] and [('q5-C9H7)2NbC12] [NbCl6]. Subsequent Lewis base chemistry has produced (T15-C9H7)TaC14(PMe3). The crystal structures of [(r15-C9H7)2TaCl2] [TaC16] and (15-C9H7)TaC14(PMe3) have been

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12

Baxter, Paul N. W. "Substituted #alpha#-diimine complexes of group VI metal carbonyls." Thesis, University of Kent, 1990. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.279680.

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13

Boonyuen, Supakorn. "The redox chemistry of Group 6 metal alkyne complexes." Thesis, University of Bristol, 2005. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.420906.

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14

Riddlestone, Ian Martin. "Synthesis and reactivity of transition metal-group 13 complexes." Thesis, University of Oxford, 2013. http://ora.ox.ac.uk/objects/uuid:f253a2a5-cc6e-4978-86d9-5f3064dadc1b.

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The synthesis and reactivity of a number of mixed transition metal-aluminium and σ-alane complexes are detailed in this thesis. Chapter III reports on the formation and structural characterisation of N,N'-chelated aluminium dihalide precursors featuring amidinate and guanidinate substituents. These precursors of the type RC(R'N)<sub>2</sub>AlX<sub>2</sub> (R = <sup>i</sup>Pr<sub>2</sub>N or Ph; R' = Cy or <sup>i</sup>Pr or Dipp; X = hal), readily react with Na[CpFe(CO)<sub>2</sub>] via salt elimination to form the corresponding mixed iron-aluminium complexes CpFe(CO)2[(X)Al(NR')2CR] which have

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15

Pierssens, Luc Jean-Marie. "Aspects of subvalent group 14 metal chemistry." Thesis, University of Sussex, 1997. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.360491.

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16

Coles, Martyn Paul. "Transition metal imido complexes : synthesis and applications to polymerisation catalysis." Thesis, Durham University, 1995. http://etheses.dur.ac.uk/5215/.

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This thesis describes studies into Group 5 and Group 6 transition metal imido complexes, with particular emphasis on the development of complexes which can be applied to catalytic processes. Chapter 1 highlights the electronic and structural aspects of the imido and alkylidene ligands. The isolobal analogy between Group 4 bent metallocene. Group 5 half-sandwich imido and Group 6 bis(imido) metal fragments is outlined. In addition, Ziegler-Natta type a-olefin polymerisation and Ring Opening Metathesis Polymerisation (ROMP) are briefly reviewed. Chapter 2 describes initial screening of half-sand

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17

Hopkins, A. D. "Group 15/alkali metal complexes and applications to photoemissive materials." Thesis, University of Cambridge, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.604223.

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The research presented in this thesis falls into four related areas. The synthetic approach used in all studies was the stepwise deprotonation of primary amines and phosphines with Group 15 dimethylamido reagents to produce heterobimetallic Group 15/alkali metal complexes. The principal aim was to examine the decomposition of these species, potentially into photoemission alkali metal antimonate layers. After an initial introduction (Chapter 1) detailing previous methods of synthesis of imido heterobimetallic complexes and photodiode materials, there follows an experimental section (Chapter 2)

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18

Hart, I. J. "Synthesis and reactions of some Group 6 metal alkylidyne complexes." Thesis, University of Bristol, 1988. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.233743.

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19

Llewellyn, Susan Clare. "Early main group and mixed-metal complexes of multifunctional amines." Thesis, University of Cambridge, 1994. https://www.repository.cam.ac.uk/handle/1810/272755.

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20

Cragg-Hine, Ian. "Early main group metal complexes of multi-functional organic molecules." Thesis, University of Cambridge, 1995. https://www.repository.cam.ac.uk/handle/1810/271932.

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21

Blackburn, Octavia Ann. "Synthesis of group 10 metal complexes for potential electronic applications." Thesis, University of Manchester, 2011. https://www.research.manchester.ac.uk/portal/en/theses/synthesis-of-group-10-metal-complexes-for-potential-electronic-applications(144ae5b9-9bdd-4e74-85d8-24995e3aa50e).html.

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The unique properties of dichroic dyes allow a guest-host display to be fabricated whereby an image is formed by liquid crystal (LC)-assisted orientational changes of the dyes upon application of an electric field. This technology is currently of interest for use in electronic paper, which aims to provide the consumer with the advantages of electronic media whilst enjoying portable paper-like images. Essential to this approach is the availability of chromophores with especially high dichroic ratios (DRs). This thesis concerns the relatively unprecedented use of metal ions in constructing new d

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22

Scheibel, Markus. "Metal-Nitrogen Multiple Bonds with Square-Planar Group 9 Transition Metal PNP Pincer Complexes." Doctoral thesis, Niedersächsische Staats- und Universitätsbibliothek Göttingen, 2014. http://hdl.handle.net/11858/00-1735-0000-0023-9944-4.

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23

Clode, Kirsten Everald. "Mono-and dimetallic #PI# - complexes of the group VI metals." Thesis, University of Nottingham, 1989. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.329849.

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24

Jolly, B. S. "Sterically hindered organic complexes of the heavier group 14 elements." Thesis, University of Sussex, 1987. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.383558.

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25

Du, Guodong. "Group 4 Metalloporphyrin diolato Complexes and Catalytic Application of Metalloporphyrins and Related Transition Metal Complexes." Washington, D.C. : Oak Ridge, Tenn. : United States. Dept. of Energy. Office of Science ; distributed by the Office of Scientific and Technical Information, U.S. Dept. of Energy, 2004. http://www.osti.gov/servlets/purl/835301-irsXCw/webviewable/.

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26

Burger, M. R. (Marga Retha). "Condensed phase properties of platinum group metal complexes from computational simulations." Thesis, Stellenbosch : University of Stellenbosch, 2004. http://hdl.handle.net/10019.1/16263.

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Thesis (MSc)--University of Stellenbosch, 2004<br>ENGLISH ABSTRACT: A variety of computational techniques are used to calculate structural, thermodynamic and transport properties of two specific Platinum Group Metal (PGM) complex systems. The first system consists of a PGM complex ([PdCl4]2-; [PtCl4]2-; [PtCl6]2- or [RhCl6]3-) with sodium counter-ions in a water solution at 30ºC and at a concentration of 0.106 mol/dm3. The second system under consideration is that of a PGM complex ([PdCl4]2-; [PtCl4]2-; [PtCl6]2- or [RhCl6]3-) with sodium counter-ions in a water solution in the presence o

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27

Ghaffar, Tallit. "Synthesis, structure and catalytic activity of some platinum group metal complexes." Thesis, King's College London (University of London), 1995. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.281709.

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28

Nettles, Shawn M. "Synthesis and characterization of electrophilic group 4 metal complexes of benzynes." Morgantown, W. Va. : [West Virginia University Libraries], 1998. http://etd.wvu.edu/templates/showETD.cfm?recnum=175.

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Thesis (M.S.)--West Virginia University, 1998.<br>Title from document title page. Document formatted into pages; contains vii, 69 p. : ill. Vita. Includes abstract. Includes bibliographical references (p. 62-64).

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29

Bunker, Janet Constance. "The effects of some platinum group metal complexes on bacterial growth." Thesis, Royal Holloway, University of London, 1985. http://repository.royalholloway.ac.uk/items/a0148261-1454-40d1-94dc-bf2b46c26c71/1/.

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Experimental conditions were established which gave reproducible power-time and biomass-time traces for Klebsiella aerogenes growing in glucose-limited medium and Staphylococcus aureus 13137, Ps47 and Pseudomonas aeruginosa in nutrient broth. Aeration of the cultures was critical in determining the shape and reproducibility of the power-time traces. High oxygen tensions caused a reduction in the final biomass value and an increase in waste heat production in nutrient broth. Biomass production occured without any accompanying heat production and vice versa in nutrient broth. The reproducible po

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30

Fujita, Kenichi. "Synthesis, Structure, and Reactivity of Novel Group 8 Transition Metal Complexes." Kyoto University, 1997. http://hdl.handle.net/2433/202318.

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Kyoto University (京都大学)<br>0048<br>新制・課程博士<br>博士(工学)<br>甲第6878号<br>工博第1629号<br>新制||工||1070(附属図書館)<br>15965<br>UT51-97-H262<br>京都大学大学院工学研究科物質エネルギー化学専攻<br>(主査)教授光藤武明, 教授植村榮, 教授玉尾皓平<br>学位規則第4条第1項該当

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31

McAslan, Ewan Blyth. "Synthetic, structural and spectroscopic studies on some platinum group metal complexes." Thesis, University of Edinburgh, 1986. http://hdl.handle.net/1842/28560.

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32

Genge, Anthony Richard John. "Mono- and bi-dentate group 15 and 16 ligand complexes of main group metal halides." Thesis, University of Southampton, 1999. https://eprints.soton.ac.uk/393598/.

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33

Le, Roux Adele. "Hard-hard and soft-soft coordination in complexes of Group 6 and Group 10 & 11 metals respectively." Thesis, Link to the online version, 2008. http://hdl.handle.net/10019/868.

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34

Jones, Simon C. "Metal-metal coupling in bi- and multimetallic systems : organometallic pentalene and group 14-bridged cyclopentadienyl complexes of transition metals." Thesis, University of Oxford, 2003. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.270635.

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35

Kristofzski, John Gregory. "Ionization-structure relationships of thin film and gas phase group VI metal-metal quadruple-bonded complexes." Diss., The University of Arizona, 1988. http://hdl.handle.net/10150/184384.

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Principles involving the electronic structure of group VI metal-metal multiple bonded complexes are examined in order to provide insights into the intramolecular and intermolecular interactions of these systems. Examination of chromium, molybdenum and tungsten tetracarboxylate thin films by ultraviolet photoelectron spectroscopy has provided the first experimental evidence for the location of the σ ionization in dimolybdenum tetracarboxylate quadruple bonded complexes. These compounds have significant intermolecular interactions as thin films which destabilizes ionization of the valence σ stat

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36

Wicks, Joseph Leslie Michael. "Routes to mixed metal compounds of the platinum group : metal σ-acetylide complexes and platinum clusters". Thesis, University of Cambridge, 2002. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.620495.

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37

Parkin, Christopher James. "The structure and co-ordination chemistry of group 2 metal salicylate complexes." Thesis, University of Hull, 2005. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.417162.

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38

Hawkes, Kirsty June. "Group 9 and 10 transition metal n-heterocyclic carbene complexes in catalysis." Thesis, Cardiff University, 2006. http://orca.cf.ac.uk/56061/.

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This thesis describes the theoretical and experimental study of group 9 and 10 transition metal N-heterocyclic carbene complexes in catalytic reactions. In order to overcome decomposition reactions discovered in the use of carbene complexes for carbon monoxide/ethylene copolymerisation, chelating thiazolium salts were prepared for the synthesis of corresponding palladium complexes. Complex formation proved difficult and experimental attempts to overcome possible side reactions caused by reactant-metal interactions were unsuccessful. Theoretical studies indicated a sulfur-palladium interaction

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39

Bartlett, Ian Mark. "The redox activiation of alkyne ligands in group 6 transition metal complexes." Thesis, University of Bristol, 1997. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.390376.

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40

Burgoyne, Andrew R. "Development, synthesis and anticancer evaluation of trinuclear Platinum Group Metal organometallic complexes." Doctoral thesis, University of Cape Town, 2016. http://hdl.handle.net/11427/20303.

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Over the past few decades metals in medicine have played to play a significant role, especially after the discovery of the anticancer properties of cisplatin. However, acquired and intrinsic resistance, toxicity and a host of side-effects have encouraged the research for new metal based anticancer agents. Organometallic complexes have proved to be successful anticancer agents and several have commenced clinical trials. The aim of this study was to prepare and characterize trinuclear platinum group organometallic complexes and investigate their in vitro activity. The first series of ester conta

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41

李富華 and Fu-wa Lee. "Syntheses, structures and reactivity of the group 6 and 7 metal complexes containing chelating nitrogen donor ligands and metal-ligandmultiple bonds." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 1997. http://hub.hku.hk/bib/B29872911.

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42

Heydenrych, Greta. "New amino- and titanoxycarbene complexes of group 6 metals." Thesis, Stellenbosch : Stellenbosch University, 2001. http://hdl.handle.net/10019.1/52355.

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43

Lee, Fu-wa. "Syntheses, structures and reactivity of the group 6 and 7 metal complexes containing chelating nitrogen donor ligands and metal-ligand multiple bonds /." Hong Kong : University of Hong Kong, 1997. http://sunzi.lib.hku.hk/hkuto/record.jsp?B21020255.

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44

Sadler, Mark. "Main group selenium chemistry and a series of hydrophobic bispidone-transition metal complexes." Thesis, University of Manchester, 2009. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.515118.

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This thesis encompasses two distinct areas of chemistry. The first part involves the synthesis and characterisation of phenylselenium(II) halides and pseudohalides and their further reactions with tertiary phosphines. The molecular structures of phenylselenium(II) chloride and thiocyanide are reported along with a large series of reactions involving phenylselenium(lI) chloride with tertiary phosphines. In addition to an extensive study of the products in solution using multinuclear NMR, suitable crystals were characterised using X-ray crystallography, yielding three novel crystal structures, t

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45

Coombs, Natalie D. "Synthesis of low-coordinate transition metal complexes of the heavier group 13 elements." Thesis, Cardiff University, 2008. http://orca.cf.ac.uk/54759/.

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This thesis describes the synthesis, structural and reaction chemistry of a number of novel gallium and indium containing species, including metal complexes featuring previously unreported gallium and indium ligand systems. The synthesis, spectroscopic and structural characterisation of the asymmetric haloindyl (n5-C5R5)Fe(CO)2In(Mes*)Br (R = H, Me) and halogallyl Cp*Fe(CO)2Ga(Mes)I complexes are reported herein, with Cp*Fe(CO)2ln(Mes*)Br representing the first example of structurally characterised asymmetric bromoindyl complex. Cp*Fe(CO)2In(Mes*)Br is a versatile substrate for the synthesis o

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46

Tompkin, Peter Kenneth. "The synthesis and reactivity of transition metal complexes containing naked Group 15 ligands." Thesis, University of Cambridge, 1997. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.627348.

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47

Rothenberger, Alexander. "Studies of main group metal complexes containing new phosphorus and nitrogen functionalised ligands." Thesis, University of Cambridge, 2002. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.620442.

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48

Palmer, Julie Sharon. "Aspects of ligand design and aggregation in main group and transition metal complexes." Thesis, University of Cambridge, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.624463.

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49

Hafeez, Muhammad [Verfasser]. "Novel Group 4 Metal Amido Complexes - syntheses, reactivity and olefin polymerization catalysis / Muhammad Hafeez." Bayreuth : Universität Bayreuth, 2012. http://d-nb.info/1059413191/34.

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50

Poplaukhin, Pavel V. "Ytterbium(II) - group 6, 7 transition metal carbonyl complexes systematic synthesis and structural characterization /." Columbus, Ohio : Ohio State University, 2006. http://rave.ohiolink.edu/etdc/view?acc%5Fnum=osu1154373668.

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