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Dissertations / Theses on the topic 'Guest inclusion complexes'

Author: Grafiati

Published: 18 May 2024

Last updated: 31 July 2025

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1

Bezuidenhout, Charl Xavier. "Polar ordering of guest molecules in host-guest inclusion complexes." Thesis, Stellenbosch : Stellenbosch University, 2011. http://hdl.handle.net/10019.1/18107.

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Thesis (MSc)--Stellenbosch University, 2011.<br>ENGLISH ABSTRACT: 2,7-dimethylocta-3,5-diyne-2,7-diol forms inclusion complexes with various guests molecules, where the guest molecules are polar-ordered. A Cambridge Structural Database (CSD) search revealed ten inclusion complexes where the guest molecules were polar-ordered. Using Density Functional Theory (DFT) computational methods (in the absence of the host), we evaluated the intra-channel and lateral guest-guest interactions between the guest molecules. Two polar-ordered inclusion complexes ((1,4,7-cyclohexane-1,2,4,5,7,8-hexaoxonane)·C

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2

Roy, Aditi. "Study to explore molecular inclusion complexes of cyclic hosts with vital guests in various environments." Thesis, University of North Bengal, 2018. http://ir.nbu.ac.in/handle/123456789/2633.

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3

O'Brien, Mark. "Spectroscopic Studies of Inclusion Host-Guest Complexes Between Cyclophane Corrals and Polcyclic Aromatic Hydrocarbons." TopSCHOLAR®, 2005. http://digitalcommons.wku.edu/theses/470.

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Cyclophanes are macromolecules that are known to effectively bind with molecules to form host-guest complexes. Several cyclophane molecules, referred to as corrals (1-6) by their founders, have been synthesized. The characterization of these compounds and their complexes has been investigated using combined spectroscopic and theoretical methods. Hostguest interactions of cyclophane-anthracene (C-A), cyclophane-9-fluorenone (C-F) and cyclophane-pyrene (C-P) complex systems in dichloromethane are presented in this thesis. The stability constants, log Ka, for the C-A, C-F and C-P complexes are de

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4

Hulushe, Siyabonga Theophillus. "Guest inclusion behaviour of zirconium(IV)- based polycarboxylate complexes: a study of metal-organic frameworks." Thesis, Rhodes University, 2018. http://hdl.handle.net/10962/63710.

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5

Mondal, Jaygopal. "Solvation consequences of different aqueous media on some biologically active compounds: a physico-chemical study." Thesis, University of North Bengal, 2021. http://ir.nbu.ac.in/handle/123456789/4751.

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6

Kundu, Mitali. "Exploration of inclusion complexes between host and guest molecules and solvation effect of some vital molecules in various environments." Thesis, University of North Bengal, 2017. http://ir.nbu.ac.in/handle/123456789/2689.

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7

Roy, Niloy. "Synthesis, characterization and innovative applications of inclusion complexes and nanocomposites of some biologically potent molecules." Thesis, University of North Bengal, 2022. http://ir.nbu.ac.in/handle/123456789/4754.

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8

Barman, Siti. "Investigation on solvation behaviour and host guest inclusion complexes of some significant molecules with diverse cyclic compounds." Thesis, University of North Bengal, 2017. http://ir.nbu.ac.in/handle/123456789/2588.

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9

Rahaman, Habibur. "Diverse Interactions of Some Significant Compounds Prevailing in Different Solvent Systems with the Manifestation of Solvation Consequence by Physicochemical Investigations." Thesis, University of North Bengal, 2019. http://ir.nbu.ac.in/handle/123456789/2814.

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10

Groom, Jazerie J. "Evaluation of Apparent Formation Constants of Host-Guest Inclusion Complexes of Solutes with Soluble Calixarenes Using High Performance Liquid Chromatography." Youngstown State University / OhioLINK, 2013. http://rave.ohiolink.edu/etdc/view?acc_num=ysu1389273191.

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11

Saha, Binoy Chandra. "Host guest inclusion complexes and thermodynamic properties of some imperative molecules with the manifestation of diverse interections by physiochemical investigation." Thesis, University of North Bengal, 2020. http://ir.nbu.ac.in/handle/123456789/3966.

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12

Nikolaou, Panayiotis. "SPECTROSCOPIC STUDIES OF NUCLEAR SPINS POLARIZED VIA SPIN EXCHANGE OPTICAL PUMPING AND DYNAMIC COUPLING IN CRYPTOPHANE HOST-GUEST COMPLEXES." OpenSIUC, 2010. https://opensiuc.lib.siu.edu/dissertations/185.

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NMR is a powerful analytical spectroscopic tool used to perform detailed studies of structure and dynamics of molecules in solution. However, despite NMR's excellent spectral sensitivity, most NMR methods suffer from low detection sensitivity. This low detection sensitivity results largely from extremely small (Boltzmann) nuclear spin polarization at thermal equilibrium--in even the strongest of magnets. This dissertation focuses on selected research areas that maybe used to combat the limitations presented by NMR and measure weak spectral responses with atomic-scale precision. In particular,

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13

Takacs, Zoltan. "Chloromethane Complexation by Cryptophanes : Host-Guest Chemistry Investigated by NMR and Quantum Chemical Calculations." Doctoral thesis, Stockholms universitet, Institutionen för material- och miljökemi (MMK), 2012. http://urn.kb.se/resolve?urn=urn:nbn:se:su:diva-81472.

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Host–guest complexes are widely investigated because of their importance in many industrial applications. The investigation of their physico–chemical properties helps understanding the inclusion phenomenon. The hosts investigated in this work are cryptophane molecules possessing a hydrophobic cavity. They can encapsulate small organic guests such as halo–methanes (CH2Cl2, CHCl3). The encapsulation process was investigated from both the guest and the host point of view. With the help of Nuclear Magnetic Resonance (NMR), the kinetics of complex formation was determined. The information was furth

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14

Escobar, González Luis. "Molecular containers based on aryl-extended calix[4]Pyrroles." Doctoral thesis, Universitat Rovira i Virgili, 2019. http://hdl.handle.net/10803/668442.

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Aquesta Tesi s'ocupa del disseny i síntesi de receptors còncaus que posseeixen cavitats hidrofíliques: receptors covalents, caixes metàl·liques i càpsules no covalents. Per a la seva construcció, triem la bastida de calix[4]pirrol aril-estès (C[4]P-AE), que proporciona una cavitat aromàtica profunda tancada en un extrem per un lloc d'unió polar i oberta a l'extrem oposat. També investiguem les propietats de reconeixement dels receptors sintetitzats en dissolvents orgànics així com en aigua. Específicament, descrivim un mètode sintètic per l'allargament de la cavitat de C[4]P-AEs que condueix a

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15

Saha, Subhadeep. "Study to explore the formation of host - guest inclusion complexes of cyclodextrins with biologically active moleculars and crown ethers with ionic liquids by spectroscopic and physicochemical techniques." Thesis, University of North Bengal, 2018. http://ir.nbu.ac.in/handle/123456789/2648.

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16

Silva, Cassio Pacheco da. "Complexos de inclusão de antocianinas e análogos sintéticos de antocianinas." Universidade de São Paulo, 2015. http://www.teses.usp.br/teses/disponiveis/46/46136/tde-17122015-094757/.

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As antocianinas compreendem o maior conjunto de pigmentos naturais do Reino Vegetal. São caracterizadas pelas colorações vermelha, roxa e azul de uma variedade de flores, frutas e folhas. A sua estabilidade é influenciada por diversos fatores como o pH local do meio, temperatura, luz ou copigmentos. A inclusão das antocianinas e análogos sintéticos, os sais de flavílio, dentro da cavidade da cucurbit[7]uril (CB[7]), sistema hóspede-hospedeiro, foi estudada a partir da espectroscopia de fluorescência. As antocianinas sintéticas utilizadas foram o cloreto de 7-hidroxi-4-metilflavílio (HMF) e o c

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17

Pais, Joana Margarida Mosquito. "Cyclodextrins inclusion to stabilise multicomponent guests of plant origin." Master's thesis, Universidade de Aveiro, 2017. http://hdl.handle.net/10773/22418.

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Mestrado em Bioquímica - Bioquímica Alimentar<br>A inclusão em ciclodextrinas (CDs) de hóspedes multi-componente, tais como óleos essenciais e extratos de plantas, é um tema atual e útil para uma série de aplicações nas indústrias alimentar, cosmética e farmacêutica. No presente trabalho foram estudados dois destes sistemas, tendo por hóspedes o óleo essencial de Cistus ladanifer e uma mistura de gingerois extraídos de rizoma fresco de gengibre. A composição do óleo essencial de C. ladanifer foi estudada por GC-MS, tendo-se identificado 94,3% dos seus componentes e determinado a massa molecul

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18

Daver, Henrik. "Quantum Chemical Modeling of Phosphoesterase Mimics and Chemistry in Confined Spaces." Doctoral thesis, Stockholms universitet, Institutionen för organisk kemi, 2017. http://urn.kb.se/resolve?urn=urn:nbn:se:su:diva-148259.

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In this thesis, density functional theory is employed in the study of two kinds of systems that can be considered to be biomimetic in their own ways. First, three binuclear metal complexes, synthesized by the group of Prof. Ebbe Nordlander, have been investigated. The complexes are designed to resemble the active sites of phosphatase enzymes and have been examined in complexes where either two Zn(II) ions or one Fe(III) and one Mn(II) ion are bound. These dinuclear compounds were studied as catalysts for the hydrolysis of bis(2,4-dinitrophenyl) phosphate and the transesterification of 2-hydrox

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19

Wang, Ruibing. "Cucurbit[n]uril host-guest complexes: the effects of inclusion on the chemical reactivity and spectroscopic properties of aromatic guest molecules." Thesis, 2007. http://hdl.handle.net/1974/502.

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This thesis deals primarily with supramolecular chemistry based on cucurbit[n]uril (CB[n], n = 7 and 8) host molecules. The research has been focused on the synthesis and characterization of host-guest complexes CB[n] with aromatic guest molecules, and the study of the effects of the host-guest complexation on the chemical reactivity and spectroscopic properties of the included guests, such as their photoreactivity and their UV-visible absorption and emission properties, in aqueous solution. The [4+4] photodimerization of protonated 2-aminopyridine (APH+) occurs stereoselectively to give the

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20

Cova, Tânia Firmino Guerra Guerreiro. "Simulation of Supramolecular Systems for Drug Delivery Based on Inclusion Complexes." Doctoral thesis, 2018. http://hdl.handle.net/10316/87642.

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Tese de Doutoramento em Química, no ramo de Química Macromolecular, apresentada ao Departamento de Química da Faculdade de Ciências e Tecnologia da Universidade de Coimbra<br>The accurate description of the interaction patterns, energetics and binding affinities of host-guest systems by means of molecular dynamics (MD) and free-energy calculations have gained increasing interest in pharmaceutical technology and drug delivery applications. In spite of its importance, many conceptual and practical aspects are still under intense scrutiny, particularly those related to the molecular origin, stren

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21

Campos, Joana Marques de. "Internship and Monograph reports entitled ”Application of cyclodextrins for the development of parenteral formulations"." Master's thesis, 2020. http://hdl.handle.net/10316/92965.

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Relatório de Estágio do Mestrado Integrado em Ciências Farmacêuticas apresentado à Faculdade de Farmácia<br>Parenteral formulations are indispensable in clinical practice, and often consist of the only option to administer drugs not able to be administrated through other routes, such as proteins and certain anticancer drugs, which are indispensable to treat some of the most prevailing chronic diseases worldwide, as diabetes and cancer. Additionally, parenteral formulations play a relevant role in emergency care since they are the only ones which provide an immediate action of the drug upon adm

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22

Popr, Martin. "Syntéza cyklodextrinových derivátů pro praktické aplikace." Doctoral thesis, 2017. http://www.nusl.cz/ntk/nusl-267013.

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Synthesis of cyclodextrin derivatives for practical applications Abstract The first part of this PhD thesis is focused on the synthesis of a series of monosubstituted tetraalkylammonium cyclodextrin (CD) derivatives. The emphasis was placed on the possible applicability of the synthetic process to multigram or even industrial scale. Monotosylation of the native cyclodextrins (-, -, -) on the primary side of the macrocycle afforded the starting materials. Derivatives with one cationic group were prepared by the reaction with aqueous trimethylamine. The reaction of the mono-Ts-CD with neat N,

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