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1

Sagara, H. M., S. A. Schliebe, and M. C. Kong. "Pyrotechnic Residues in Gunshot Residue Analysis." Proceedings, annual meeting, Electron Microscopy Society of America 43 (August 1985): 128–29. http://dx.doi.org/10.1017/s0424820100117649.

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Particle analysis by scanning electron microscopy with energy-dispersive x- ray analysis is one of the current methods used in crime laboratories to aid law enforcement in identifying individuals who have recently fired or handled a firearm. During the discharge of a firearm, the high pressure caused by the detonation of the cartridge materials forces a portion of the generated gases through leaks in the firing mechanism of the weapon. These gases contain residues of smokeless powder, primer mixture, and contributions from the projectile itself. The condensation of these hot gases form discrete, micrometer-sized particles, which can be collected, along with dry skin cells, salts, and other hand debris, from the hands of a shooter by a simple adhesive lift technique. The examination of the carbon-coated adhesive lifts consist of time consuming systematic searches for high contrast particles of spherical morphology with the characteristic elemental composition of antimony, barium and lead. A detailed list of the elemental compositions which match the criteria for gunshot residue are discussed in the Aerospace report.
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2

Thornton, John I. "Close Proximity Gunshot Residues." Journal of Forensic Sciences 31, no. 2 (April 1, 1986): 12310J. http://dx.doi.org/10.1520/jfs12310j.

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3

Takic, Milos. "Forensic exspertise of gunshot residues." Bezbednost, Beograd 58, no. 1 (2016): 167–84. http://dx.doi.org/10.5937/bezbednost1601167t.

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4

Taudte, Regina Verena, Alison Beavis, Lucas Blanes, Nerida Cole, Philip Doble, and Claude Roux. "Detection of Gunshot Residues Using Mass Spectrometry." BioMed Research International 2014 (2014): 1–16. http://dx.doi.org/10.1155/2014/965403.

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In recent years, forensic scientists have become increasingly interested in the detection and interpretation of organic gunshot residues (OGSR) due to the increasing use of lead- and heavy metal-free ammunition. This has also been prompted by the identification of gunshot residue- (GSR-) like particles in environmental and occupational samples. Various techniques have been investigated for their ability to detect OGSR. Mass spectrometry (MS) coupled to a chromatographic system is a powerful tool due to its high selectivity and sensitivity. Further, modern MS instruments can detect and identify a number of explosives and additives which may require different ionization techniques. Finally, MS has been applied to the analysis of both OGSR and inorganic gunshot residue (IGSR), although the “gold standard” for analysis is scanning electron microscopy with energy dispersive X-ray microscopy (SEM-EDX). This review presents an overview of the technical attributes of currently available MS and ionization techniques and their reported applications to GSR analysis.
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5

Lonsdale, Wade, Magdalena Wajrak, and S. Ridgway. "Onsite Measurement of Lead in Gunshot Residues Using Linear Sweep Voltammetry." Modern Environmental Science and Engineering 1, no. 4 (December 20, 2015): 192–95. http://dx.doi.org/10.15341/mese(2333-2581)/04.01.2015/005.

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6

Arai, Hiroyuki, and Jun Nakamura. "Identification of Smokeless Powder Gunshot Residues." Japanese journal of science and technology for identification 1, no. 1 (1996): 53–55. http://dx.doi.org/10.3408/jasti.1.53.

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7

Duarte, A., L. M. Silva, C. T. de Souza, E. M. Stori, L. A. Boufleur, L. Amaral, and J. F. Dias. "Elemental quantification of large gunshot residues." Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms 348 (April 2015): 170–73. http://dx.doi.org/10.1016/j.nimb.2014.11.116.

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8

Üner, H. B., and A. Özaslan. "Gunshot residues of blank firing pistols." Trace Elements and Electrolytes 22, no. 10 (October 1, 2005): 268–71. http://dx.doi.org/10.5414/tep22268.

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9

Stich, Susanne, Delphine Bard, Leo Gros, H. Walter Wenz, Jack Yarwood, and Ken Williams. "Raman microscopic identification of gunshot residues." Journal of Raman Spectroscopy 29, no. 9 (September 1998): 787–90. http://dx.doi.org/10.1002/(sici)1097-4555(199809)29:9<787::aid-jrs301>3.0.co;2-h.

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10

Lindström, Anne-Christine, Noelyn Hung, Warwick Duncan, and Jules Kieser. "Detection of gunshot residues (GSR) on a self-inflicted gunshot wound." Pathology 46, no. 3 (April 2014): 260–63. http://dx.doi.org/10.1097/pat.0000000000000083.

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11

Stein, K. M., M. L. Bahner, J. Merkel, S. Ain, and R. Mattern. "Detection of gunshot residues in routine CTs." International Journal of Legal Medicine 114, no. 1-2 (December 11, 2000): 15–18. http://dx.doi.org/10.1007/s004149900124.

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12

Gallidabino, Matteo D., Leon P. Barron, Céline Weyermann, and Francesco S. Romolo. "Quantitative profile–profile relationship (QPPR) modelling: a novel machine learning approach to predict and associate chemical characteristics of unspent ammunition from gunshot residue (GSR)." Analyst 144, no. 4 (2019): 1128–39. http://dx.doi.org/10.1039/c8an01841c.

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13

Zeng, Jianbo, Ji Qi, Fuquan Bai, Jorn Chi Chung Yu, and Wei-Chuan Shih. "Analysis of ethyl and methyl centralite vibrational spectra for mapping organic gunshot residues." Analyst 139, no. 17 (2014): 4270–78. http://dx.doi.org/10.1039/c4an00657g.

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14

Fambro, Lashaundra A., Ethan T. Miller, Deidre D. Vandenbos, and Christopher R. Dockery. "Characterization of lead-free gunshot residue analogs." Analytical Methods 8, no. 15 (2016): 3132–39. http://dx.doi.org/10.1039/c6ay00725b.

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15

Zuy, Yelyzaveta, Samantha O. Sweck, Christopher R. Dockery, and Gretchen E. Potts. "HPLC detection of organic gunshot residues collected with silicone wristbands." Analytical Methods 12, no. 1 (2020): 85–90. http://dx.doi.org/10.1039/c9ay02305d.

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16

Polnparkh, Ussada-yooth, Dr Narong Chimpalee, and Kosin Hintoa. "Comparison of Particles of Occupation Origins Residues and Lead-free Gunshot Residues." Khon Kaen University Journal (Graduate Studies) 12, no. 1 (January 1, 2012): 34–45. http://dx.doi.org/10.5481/kkujgs.2012.12.1.4.

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17

Jeon, Chung-Hyun. "Review: Identification and Analysis of Organic Gunshot Residues." Korean Academy of Scientific Criminal Investigation 10, no. 4 (December 20, 2016): 253–95. http://dx.doi.org/10.20297/jsci.2016.10.4.253.

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18

MacCrehan, William A., Malinda J. Layman, and Janelle D. Secl. "Hair combing to collect organic gunshot residues (OGSR)." Forensic Science International 135, no. 2 (August 2003): 167–73. http://dx.doi.org/10.1016/s0379-0738(03)00207-x.

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19

Salles, Maiara O., Juliana Naozuka, and Mauro Bertotti. "A forensic study: Lead determination in gunshot residues." Microchemical Journal 101 (March 2012): 49–53. http://dx.doi.org/10.1016/j.microc.2011.10.004.

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20

Gassner, Anne-Laure, and Céline Weyermann. "Prevalence of organic gunshot residues in police vehicles." Science & Justice 60, no. 2 (March 2020): 136–44. http://dx.doi.org/10.1016/j.scijus.2019.09.009.

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21

Szynkowska, Małgorzata Iwona, Andrzej Parczewski, Katarzyna Szajdak, and Jacek Rogowski. "Examination of gunshot residues transfer using ToF-SIMS." Surface and Interface Analysis 45, no. 1 (August 29, 2012): 596–600. http://dx.doi.org/10.1002/sia.5142.

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22

Melo, Lis G. A., Andrea Martiny, and André L. Pinto. "Nano characterization of gunshot residues from Brazilian ammunition." Forensic Science International 240 (July 2014): 69–79. http://dx.doi.org/10.1016/j.forsciint.2014.04.010.

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23

Pelizza, P., E. Saligari, and M. Signori. "Gunshot residues determination on entrance and exit orifices." Journal of Clinical Forensic Medicine 2 (March 1995): 23. http://dx.doi.org/10.1016/1353-1131(95)90167-1.

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24

Meng, Hsien-hui, and Brian Caddy. "Fluorescence Detection of Ethyl Centralite in Gunshot Residues." Journal of Forensic Sciences 39, no. 5 (September 1, 1994): 13707J. http://dx.doi.org/10.1520/jfs13707j.

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25

Prasertying, Paithoon, Nanthatchaphon Jantawong, Thitaporn Sonsa-ard, Thinnapong Wongpakdee, Nuttamon Khoonrueng, Supatana Buking, and Duangjai Nacapricha. "Gold leaf electrochemical sensors: applications and nanostructure modification." Analyst 146, no. 5 (2021): 1579–89. http://dx.doi.org/10.1039/d0an02455d.

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26

Argente-García, Ana, Lusine Hakobyan, Carmen Guillem, and Pilar Campíns-Falcó. "Estimating Diphenylamine in Gunshot Residues from a New Tool for Identifying both Inorganic and Organic Residues in the Same Sample." Separations 6, no. 1 (March 19, 2019): 16. http://dx.doi.org/10.3390/separations6010016.

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A method involving the collection and determination of organic and inorganic gunshot residues on hands using on-line in-tube solid-phase microextraction (IT-SPME) coupled to miniaturized capillary liquid chromatography with diode array detection (CapLC-DAD) and scanning electron microscopy coupled to energy dispersion X-ray (SEM-EDX), respectively, for quantifying both residues was developed. The best extraction efficiency for diphenylamine (DPA) as the main target among organic residues was achieved by using a dry cotton swab followed by vortex-assisted extraction with water, which permits preservation of inorganic residues. Factors such as the nature and length of the IT-SPME extractive phase and volume of the sample processed were investigated and optimized to achieve high sensitivity: 90 cm of TRB-35 (35% diphenyl, 65% polydimethylsiloxane) capillary column and 1.8 mL of the processed sample were selected for the IT-SPME. Satisfactory limit of detection of the method for analysis of DPA deposited on shooters’ hands (0.3 ng) and precision (intra-day relative standard deviation, 9%) were obtained. The utility of the described approach was tested by analyzing several samples of shooters’ hands. Diphenylamine was found in 81% of the samples analyzed. Inorganic gunshot residues analyzed by SEM-EDX were also studied in cotton swab and lift tape kit samplers. Optical microscopy was used to see the inorganic gunshot residues in the cotton swab samplers. The lift tape kits provided lesser sensitivity for DPA than dry cotton swabs—around fourteen times. The possibility of environmental and occupational sources could be eliminated when DPA was found together with inorganic residues. Then, the presence of inorganic and organic residues in a given sample could be used as evidence in judicial proceedings in the forensic field.
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27

Silva, Maria José, Juliana Cortez, Celio Pasquini, Ricardo S. Honorato, Ana Paula S. Paim, and Maria Fernanda Pimentel. "Gunshot residues: screening analysis by laser-induced breakdown spectroscopy." Journal of the Brazilian Chemical Society 20, no. 10 (2009): 1887–94. http://dx.doi.org/10.1590/s0103-50532009001000017.

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28

Weber, I. T., A. J. G. Melo, M. A. M. Lucena, E. F. Consoli, M. O. Rodrigues, G. F. de Sá, A. O. Maldaner, M. Talhavini, and S. Alves. "Use of luminescent gunshot residues markers in forensic context." Forensic Science International 244 (November 2014): 276–84. http://dx.doi.org/10.1016/j.forsciint.2014.09.001.

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29

Gassner, Anne-Laure, Cristina Ribeiro, Joanna Kobylinska, Arie Zeichner, and Céline Weyermann. "Organic gunshot residues: Observations about sampling and transfer mechanisms." Forensic Science International 266 (September 2016): 369–78. http://dx.doi.org/10.1016/j.forsciint.2016.06.029.

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30

Ditrich, Hans. "Distribution of gunshot residues – The influence of weapon type." Forensic Science International 220, no. 1-3 (July 2012): 85–90. http://dx.doi.org/10.1016/j.forsciint.2012.01.034.

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31

Sarraguça, Jorge M. G., Catarina Lima, Filipe Machado, João A. Lopes, Agostinho Almeida, Luís Fernandes, Teresa Magalhães, and Agostinho Santos. "A FT-NIR spectroscopy methodology to estimate firing distance based on the direct analysis of the bullet impact surface." Analyst 141, no. 14 (2016): 4410–16. http://dx.doi.org/10.1039/c6an00247a.

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32

Unceta, Nora, Nagore Grijalba, Sandra Benito, Zuriñe Abrego, Alicia Sánchez, Mª Aránzazu Goicolea, Alberto Gomez, Asier Vallejo, and Ramón J. Barrio. "Tiro-aztarnen identifikazioa, auzitegi-laborategien erronka." EKAIA Euskal Herriko Unibertsitateko Zientzi eta Teknologi Aldizkaria, no. 28 (December 9, 2015): 105–23. http://dx.doi.org/10.1387/ekaia.14556.

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Azken urteotan, su-armen erabilera nabarmen handitu da gure gizartean eta horrek tiro egin ondoren sortutako partikulen analisirako metodologia berriak garatzea ekarri du. Krimen agertokian tiro-aztarnak (gunshot residue, GSR) osatzen dituzten konposatuen detekzio eta identifikazioak su-armen erabileraren ebidentzia fidagarria eskaintzen du. Tiro-aztarnak erretako eta erre gabeko partikulen multzoa da, munizioa erretzen denean sortutakoak eta su-armak berak, jaurtigaiak eta kartutxoak askatutako konposatuez osatuak. Tiro egin ostean, partikulak tiroa gertatu den tokiaren inguruan jalkitzen dira baina, batez ere, tiratzailearen gorputzean (eskuak, sudurra eta ilea) eta arropetan. Gaur egun, GSR partikulen ohiko analisia konposatu ez-organikoen identifikazioan oinarritzen da. Konposatu organikoen azterketak (organic gunshot residues, OGSR) lagin baten froga-balioa indartu dezake. Hala ere, gutxi dira OGSR-en dudarik gabeko identifikaziorako guztiz sentikorrak diren metodoak. Lan honetan beraz, tiro-aztarnen laginketa eta analisirako teknika aipagarrienak laburbildu eta berrikusten dira.
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33

Vander Pyl, Courtney, Claudia Martinez-Lopez, Korina Menking Hoggatt, and Tatiana Trejos. "Analysis of primer gunshot residue particles by laser induced breakdown spectroscopy and laser ablation inductively coupled plasma mass spectrometry." Analyst 146, no. 17 (2021): 5389–402. http://dx.doi.org/10.1039/d1an00689d.

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LIBS and LAICPMS microchemical mapping for rapid detection of gunshot residues is reported for a large dataset of pGSR authentic items and microparticle standards, with accurate differentiation between shooter and non-shooter profiles (>88%).
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34

Feeney, William, Korina Menking-Hoggatt, Courtney Vander Pyl, Colby E. Ott, Suzanne Bell, Luis Arroyo, and Tatiana Trejos. "Detection of organic and inorganic gunshot residues from hands using complexing agents and LC-MS/MS." Analytical Methods 13, no. 27 (2021): 3024–39. http://dx.doi.org/10.1039/d1ay00778e.

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35

Tuğcu, Harun, Coşkun Yorulmaz, Görgün Bayraktaroğlu, Hüseyin Bülent Üner, Yıldırım Karslioğlu, Sermet Koç, Mustafa Özer Ulukan, and Bülent Celasun. "Determination of Gunshot Residues with Image Analysis: An Experimental Study." Military Medicine 170, no. 9 (September 2005): 802–5. http://dx.doi.org/10.7205/milmed.170.9.802.

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36

Hellmiss, Guenter, Wolfgang Lichtenberg, and Manfred Weiss. "Investigation of Gunshot Residues by Means of Auger Electron Spectroscopy." Journal of Forensic Sciences 32, no. 3 (May 1, 1987): 12381J. http://dx.doi.org/10.1520/jfs12381j.

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37

Maitre, Matthieu, Scott Chadwick, K. Paul Kirkbride, Anne-Laure Gassner, Céline Weyermann, Alison Beavis, and Claude Roux. "An investigation on the secondary transfer of organic gunshot residues." Science & Justice 59, no. 3 (May 2019): 248–55. http://dx.doi.org/10.1016/j.scijus.2019.01.007.

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38

Andrasko, J., and S. Pettersson. "A simple method for collection of gunshot residues from clothing." Journal of the Forensic Science Society 31, no. 3 (July 1991): 321–30. http://dx.doi.org/10.1016/s0015-7368(91)73164-2.

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39

Salles, Maiara O., Mauro Bertotti, and Thiago R. L. C. Paixão. "Use of a gold microelectrode for discrimination of gunshot residues." Sensors and Actuators B: Chemical 166-167 (May 2012): 848–52. http://dx.doi.org/10.1016/j.snb.2012.02.097.

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40

Taborelli, Anna, Daniele Gibelli, Agostino Rizzi, Salvatore Andreola, Alberto Brandone, and Cristina Cattaneo. "Gunshot Residues on Dry Bone After Decomposition-A Pilot Study." Journal of Forensic Sciences 57, no. 5 (April 3, 2012): 1281–84. http://dx.doi.org/10.1111/j.1556-4029.2012.02119.x.

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41

Nag, N. K., and P. Sinha. "A note on assessability of firing distance from gunshot residues." Forensic Science International 56, no. 1 (September 1992): 1–17. http://dx.doi.org/10.1016/0379-0738(92)90140-r.

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42

Redouté Minzière, Virginie, Denis Werner, Daniela Schneider, Manuela Manganelli, Balthasar Jung, Céline Weyermann, and Anne‐Laure Gassner. "Combined Collection and Analysis of Inorganic and Organic Gunshot Residues." Journal of Forensic Sciences 65, no. 4 (March 17, 2020): 1102–13. http://dx.doi.org/10.1111/1556-4029.14314.

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43

Maitre, Matthieu, Mark Horder, K. Paul Kirkbride, Anne-Laure Gassner, Céline Weyermann, Claude Roux, and Alison Beavis. "A forensic investigation on the persistence of organic gunshot residues." Forensic Science International 292 (November 2018): 1–10. http://dx.doi.org/10.1016/j.forsciint.2018.08.036.

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44

Hofstetter, Carmen, Matthieu Maitre, Alison Beavis, Claude P. Roux, Céline Weyermann, and Anne-Laure Gassner. "A study of transfer and prevalence of organic gunshot residues." Forensic Science International 277 (August 2017): 241–51. http://dx.doi.org/10.1016/j.forsciint.2017.06.013.

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45

Aksoy, Cagdas. "Determination of Antimony in Gunshot Residues Using GFAAS and SEM/EDX." Atomic Spectroscopy 34, no. 5 (October 5, 2013): 170–74. http://dx.doi.org/10.46770/as.2013.05.003.

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46

Polovková, Júlia, Miroslav Šimonič, and Igor Szegényi. "Study of gunshot residues from Sintox® ammunition containing marking substances." Egyptian Journal of Forensic Sciences 5, no. 4 (December 2015): 174–79. http://dx.doi.org/10.1016/j.ejfs.2014.09.003.

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47

Wheals, B. B., and M. J. Ellison. "Hydrolysis studies on nitrocelluloses, nitroglycerine and gunshot residues using anion chromatography." Forensic Science International 41, no. 1-2 (April 1989): 147–62. http://dx.doi.org/10.1016/0379-0738(89)90246-6.

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48

Brandone, A., F. De Ferrari, P. Pelizza, and M. Signori. "The labelling of gunpowder: An approach to improve gunshot residues determination." Forensic Science International 47, no. 3 (October 1990): 289–95. http://dx.doi.org/10.1016/0379-0738(90)90298-d.

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49

Bernal Morales, Ernesto, and Alma L. Revilla Vázquez. "Simultaneous determination of inorganic and organic gunshot residues by capillary electrophoresis." Journal of Chromatography A 1061, no. 2 (December 2004): 225–33. http://dx.doi.org/10.1016/j.chroma.2004.10.083.

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50

Nunziata, Felice, and Matteo Donghi. "On the formation of Basu's Type III (peeled orange) gunshot residues." Defence Technology 15, no. 1 (February 2019): 23–26. http://dx.doi.org/10.1016/j.dt.2018.09.002.

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