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Journal articles on the topic 'Halide derivative'

Author: Grafiati

Published: 5 June 2025

Last updated: 1 August 2025

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1

Brian, Ptoton Mnangat, and Peter Musau. "Synthesis, Reactivity and Stability of Aryl Halide Protecting Groups towards Di-Substituted Pyridines." Indonesian Journal of Chemistry 16, no. 1 (2018): 53. http://dx.doi.org/10.22146/ijc.21177.

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This paper reports the synthesis and reactivity of different Benzyl derivative protecting groups. The synthesis and stability of Benzyl halides, 4-methoxybenzyl halides, 3,5-dimethoxybenzyl halides, 3,4-dimethoxybenzyl halides, 3,4,5-trimethoxybenzyl halide protecting groups and their reactivity towards nitrogen atom of a di-substituted pyridine ring in formation of pyridinium salts is also reported.

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2

Ibrahim, Hassan K., Sayed H. El-Tamany, Reda F. El-Shaarawy, and Ibrahim M. El-Deen. "Synthesis and investigation of mass spectra of some novel benzimidazole derivatives." Macedonian Journal of Chemistry and Chemical Engineering 27, no. 1 (2008): 65. http://dx.doi.org/10.20450/mjcce.2008.248.

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2-Substituted benzimidazoles (3) and (4a-c) were prepared via condensation of ethyl 2-thionyl-pyruvate (1) and hydrazidoyl derivatives (2a-c) with o-phenylene diamine in acetic acid. Acetylation of compound (4a) with acetic anhydride yielded the corresponding N-acetyl derivative (5). Treatment of compound 4b with hydrazine hydrate gave the corresponding hydrazino derivative (6). Reaction of 2-[(2-thionyl)acetyl)] benzimidazole (3) with hydrazine hydrate gave the pyrazolyl derivative (7) and hydrazino derivative (8). Alkylation of compound 3 with alkyl halide gave the corresponding 2,3-disubsti

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3

Demirdogen, Ruken Esra, Tuncay Yeşilkaynak, Tetyana Tishakova, and Fatih Mehmet Emen. "Antibacterial Cellulose Acetate Microfibers Containing Pyridine Derivative Complexes." Chemistry & Chemical Technology 15, no. 2 (2021): 217–25. http://dx.doi.org/10.23939/chcht15.02.217.

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Pyridine (L1) and 2,4-dimethylpyridine (L2) halide complexes of the type of [ML2X2] were prepared and characterized via FT-IR and 1H NMR. The CA microfibers containing complexes were electrospun and investigated via FT-IR. The morphologies of the microfibers were investigated via FE-SEM. Antibacterial activities of the complexes and the fibers were investigated.

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4

Masahara, Shingo, Hiromichi Yokoyama, Yuji Suzaki, and Tomohito Ide. "Convenient synthesis of copper(i) halide quasi-one-dimensional coordination polymers: their structures and solid-state luminescent properties." Dalton Transactions 50, no. 25 (2021): 8889–98. http://dx.doi.org/10.1039/d1dt01571k.

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5

Corinti, Davide, Barbara Gregori, Leonardo Guidoni, et al. "Complexation of halide ions to tyrosine: role of non-covalent interactions evidenced by IRMPD spectroscopy." Physical Chemistry Chemical Physics 20, no. 6 (2018): 4429–41. http://dx.doi.org/10.1039/c7cp06657k.

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6

Creste, Geordie, Sihem Groni, Claire Fave, Mathieu Branca, and Bernd Schöllhorn. "Comparative study of non-covalent interactions between cationic N-phenylviologens and halides by electrochemistry and NMR: the halogen bonding effect." Faraday Discussions 203 (2017): 301–13. http://dx.doi.org/10.1039/c7fd00082k.

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Five N-phenylviologen (PV<sup>2+</sup>) derivatives have been synthesized and their electrochemical behavior in the presence of halide anions has been studied. Further investigations were carried out by <sup>1</sup>H and <sup>19</sup>F NMR spectroscopy at different chloride concentrations. This is the first time a systematic study combines cyclic voltammetry and NMR spectroscopy in order to analyse the contribution of halogen bonding among the various non-covalent interactions between iodinated N-phenylviologens. The results show strong evidence for a significant “halogen bonding effect” in th

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7

Pan, Qiu-Yue, Meng-En Sun, Chong Zhang, et al. "A multi-responsive indium-viologen hybrid with ultrafast-response photochromism and electrochromism." Chemical Communications 57, no. 86 (2021): 11394–97. http://dx.doi.org/10.1039/d1cc05070b.

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8

Hisaeda, Yoshio, Keishiro Tahara, Hisashi Shimakoshi, and Takahiro Masuko. "Bioinspired catalytic reactions with vitamin B12 derivative and photosensitizers." Pure and Applied Chemistry 85, no. 7 (2013): 1415–26. http://dx.doi.org/10.1351/pac-con-12-10-05.

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As part of a study directed toward design of good catalytic systems based upon a hydrophobic vitamin B12, heptamethyl cobyrinate perchlorate, we describe the preparation of various nanomaterials using the vitamin B12 derivative and photosensitizers. Examples include vitamin B12-hyperbranched polymers (HBPs), human serum albumin (HSA) containing vitamin B12 derivatives, a vitamin B12-titanium dioxide hybrid catalyst, a vitamin B12-Ru complex combined system, and a vitamin B12-rose bengal combined system. These bioinspired materials have the potential as catalytic systems for the degradation of

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9

Lédée, Ferdinand, Pierre Audebert, Gaëlle Trippé-Allard, et al. "Tetrazine molecules as an efficient electronic diversion channel in 2D organic–inorganic perovskites." Materials Horizons 8, no. 5 (2021): 1547–60. http://dx.doi.org/10.1039/d0mh01904f.

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Taking advantage of an innovative design concept, we present the synthesis of two novel two-dimensional (2D) hybrid organic–inorganic halide perovskites incorporating for the first time 100% of a photoactive tetrazine derivative as the organic component.

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10

Yao, Li, Guangda Niu, Lixiao Yin, et al. "Bismuth halide perovskite derivatives for direct X-ray detection." Journal of Materials Chemistry C 8, no. 4 (2020): 1239–43. http://dx.doi.org/10.1039/c9tc06313g.

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11

Sari, Asdani Muatika, Ani Suryani, Puspa Dewi Lotulung, and Silvester Tursiloadi. "Preparation of Alkyl Halide as Intermediate Compound in Synthesis Cationic Surfactant Alkyl Trimethyl Ammonium Chloride." Jurnal Kimia Terapan Indonesia 19, no. 1 (2017): 25–28. http://dx.doi.org/10.14203/jkti.v19i1.327.

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Cationic surfactant alkyl trimethyl ammonium chloride was synthesized by quartenerisation of tertiary amines. Materials used in quartenerization are tertiary amine and alkyl halide. Alkyl halide is a hydrocarbon derivative in which one or more hydrogen is replaced with halogen. In this research, thionyl chloride is used as a reactant . Thionyl chloride (SOCl2) is often used because it is easier to make, the yield is greater and byproducts are volatile. Alkyl halide is synthesized from the reaction of hexadecyl alcohol with thionyl chloride (SOCl2) at a temperature of 80 C for 24 hours in a ref

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12

Tan, Xiaoyan, Peter W. Stephens, Mylène Hendrickx, et al. "Tetragonal Cs1.17In0.81Cl3: A Charge-Ordered Indium Halide Perovskite Derivative." Chemistry of Materials 31, no. 6 (2019): 1981–89. http://dx.doi.org/10.1021/acs.chemmater.8b04771.

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13

Ozerova, Victoria V., Ivan S. Zhidkov, Aleksandra Boldyreva, et al. "Spectacular Enhancement of the Thermal and Photochemical Stability of MAPbI3 Perovskite Films Using Functionalized Tetraazaadamantane as a Molecular Modifier." Energies 14, no. 3 (2021): 669. http://dx.doi.org/10.3390/en14030669.

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Perovskite solar cells represent a highly promising third-generation photovoltaic technology. However, their practical implementation is hindered by low device operational stability, mostly related to facile degradation of the absorber materials under exposure to light and elevated temperatures. Improving the intrinsic stability of complex lead halides is a big scientific challenge, which might be addressed using various “molecular modifiers”. These modifiers are usually represented by some additives undergoing strong interactions with the perovskite absorber material, resulting in enhanced so

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14

Toumi, Selma, Madiha Melha Yahoum, Sonia Lefnaoui, et al. "Development of New Alkylated Carrageenan Derivatives: Physicochemical, Rheological, and Emulsification Properties Assessment." Sustainability 15, no. 8 (2023): 6473. http://dx.doi.org/10.3390/su15086473.

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In this research, amphiphilic derivatives of kappa carrageenan (KC) were synthesized by hydrophobic modification with an alkyl halide (1-Octyl chloride). Three hydrophobic polymers with different degrees of substitution (DS) were obtained by the Williamson etherification reaction in an alkaline medium. The effect of the molar ratio (R = reagent/polymer) on the DS was investigated at different ratios (1, 2, and 3). The KC derivatives (KCRs) were characterized by different techniques such as FT-IR, 1H-NMR, X-ray Diffraction, Scanning electron microscopy, and a rheological assessment. The FT-IR a

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15

Batema, Guido D., Ties J. Korstanje, Gabriela Guillena, et al. "Replacing the Z-phenyl Ring in Tamoxifen® with a para-Connected NCN Pincer-Pt-Cl Grouping by Post-Modification." Molecules 26, no. 7 (2021): 1888. http://dx.doi.org/10.3390/molecules26071888.

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Post-modification of a series of NCN-pincer platinum(II) complexes [PtX(NCN-R-4)] (NCN = [C6H2(CH2NMe2)2-2,6]–, R = C(O)H, C(O)Me and C(O)Et), X = Cl– or Br–) at the para-position using the McMurry reaction was studied. The synthetic route towards two new [PtCl(NCN-R-4)] (R = C(O)Me and C(O)Et) complexes used above is likewise described. The utility and limitations of the McMurry reaction involving these pincer complexes was systematically evaluated. The predicted “homo-coupling” reaction of [PtBr(NCN-C(O)H-4)] led to the unexpected formation of 3,3′,5,5′-tetra[(dimethylamino)methyl]-4,4′-bis(

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16

Xavier, Tania, Sylvie Condon, Christophe Pichon, Erwan Le Gall, and Marc Presset. "Preparation of mono-substituted malonic acid half oxyesters (SMAHOs)." Beilstein Journal of Organic Chemistry 17 (August 18, 2021): 2085–94. http://dx.doi.org/10.3762/bjoc.17.135.

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The use of mono-substituted malonic acid half oxyesters (SMAHOs) has been hampered by the sporadic references describing their preparation. An evaluation of different approaches has been achieved, allowing to define the best strategies to introduce diversity on both the malonic position and the ester function. A classical alkylation step of a malonate by an alkyl halide followed by a monosaponification gave access to reagents bearing different substituents at the malonic position, including functionalized derivatives. On the other hand, the development of a monoesterification step of a substit

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17

Hassan, Sidra, Agnieszka Jackowska, and Dorota Gryko. "Truncated vitamin B12 derivative with the phosphate group retained." Journal of Porphyrins and Phthalocyanines 23, no. 04n05 (2019): 554–60. http://dx.doi.org/10.1142/s1088424619500421.

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Cobyric acid and cobinamide are valuable building blocks for the synthesis of artificial cobalamins modified at the nucleotide loop. However, truncated vitamin B[Formula: see text] derivatives are devoid of the phosphate group. We have found that 2-iodoxy benzoic acid-mediated phosphorolysis leads to the cleavage of only one of the phosphodiester bond giving a vitamin B[Formula: see text] analogue with the phosphate moiety preserved. Subsequent alkylation with an organic halide establishes its role as a precursor for the synthesis of vitamin B[Formula: see text] mimics modified at the nucleoti

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18

Shahad Muhammad and Ahmed Ahmed. "Synthesis, characterization and photostability study of triazole derivatives." GSC Advanced Research and Reviews 9, no. 2 (2021): 066–72. http://dx.doi.org/10.30574/gscarr.2021.9.2.0251.

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heterocyclic derivative contain triazole ring was synthesized and characterized the product and their structures by infrared spectroscopy, 1H-NMR, 13C-NMR and instrumental techniques. Compound (4) was synthesized by reacting of Schiff base (3) with an three moles of alkyl halide (p-phenyl phenacyl bromide). Final product played an important role in photostabilizer of polymer (PS), and showed the activity as a photostabilizer when exposed to UV light (300 hours).

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19

Phaphon, Kanlaya, Sumrit Wacharasindhu, and Amorn Petsom. "Preparation of PEG-rosin derivative for water soluble rosin flux." Soldering & Surface Mount Technology 28, no. 4 (2016): 188–200. http://dx.doi.org/10.1108/ssmt-08-2015-0025.

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Purpose This study aims to synthesize polyethylene glycol (PEG)-rosin derivatives from rosin and PEG for the production of solid soldering fluxes. The PEG-rosin derivatives would be water soluble, and the resulting solid soldering fluxes would have reasonable wetting ability when combined with a low-halide-content activator. Design/methodology/approach This paper presents a synthetic process for PEG-rosin derivatives. The reaction conditions (including catalyst type, catalyst concentration, reaction temperature and PEG type) were optimized for the synthesis of PEG-rosin derivatives. The chemic

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20

Srivastava, Abhay P. "Compare Halide Melting Curves using the Equation of State and Lindemann's Law for a Comprehensive Analysis." International Scientific Journal of Engineering and Management 04, no. 06 (2025): 1–9. https://doi.org/10.55041/isjem04566.

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Abstract: The primary objective of this work is to accurately predict the equation of state necessary for calculating the pressure-dependent melting curves of alkali halides. In this study, we assert a distinct model for the melting curve utilizing the Murnaghan, Singh and Kao, Shanker, and Usual-Tait equations of state. Our developed model, rigorously tested and compared with Lindemann's model, defines the relationship among pressure, bulk modulus, pressure derivative of bulk modulus, and volume compression. Our findings unequivocally demonstrate that a substantial increase in melting tempera

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21

Shahad, Muhammad, and Ahmed Ahmed. "Synthesis, characterization and photostability study of triazole derivatives." GSC Advanced Research and Reviews 9, no. 2 (2021): 066–72. https://doi.org/10.5281/zenodo.5763560.

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heterocyclic derivative contain triazole ring was synthesized and characterized the product and their structures by infrared spectroscopy, <sup>1</sup>H-NMR, <sup>13</sup>C-NMR and instrumental techniques. Compound (4) was synthesized by reacting of Schiff base (3) with an three moles of alkyl halide (<em>p</em>-phenyl phenacyl bromide). Final product played an important role in photostabilizer of polymer (PS), and showed the activity as a photostabilizer when exposed to UV light (300 hours).

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22

Nakano, Yutaka, Tomoyoshi Tsuchiya, Kimihiro Hirose, and Kingo Chida. "Occupational Asthma Caused by Pyrazolone Derivative Used in Silver Halide Photographic Paper." Chest 118, no. 1 (2000): 246–48. http://dx.doi.org/10.1378/chest.118.1.246.

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23

Bobokhidze, Lia. "NOVEL SYNTHETIC INVESTIGATION IN THE FIELD OF INDOLO[2,3-B]QUINOXALINE RING CONTAINING TETRACYCLIC AND PENTACYCLIC HETEROCYCLES." New Materials, Compounds and Applications 8, no. 1 (2024): 13–23. http://dx.doi.org/10.62476/nmca8113.

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A series of seven new indolo[2,3-b]quinoxaline ring containing compounds were efficiently synthesized in three different pathways. In the first case, the relevant pentacyclic systems (3,4) were received by the condensation reaction between 7-acetyl-1,5,6,7-tetrahydropyrrolo[3,2-f]indole-2,3-dione and o-phenylenediamine in glacial acetic acid. In the second case, tetracyclic indolo[2,3-b]qui-no¬xa¬li¬ne derivatives (7, 8a-d) were synthesised by a one-pot approach using Pd-catalyzed Sonogashira-hagihara C-C cross-coupling reaction between various terminal acetylenes and 9-iodo-6H-indo¬lo¬[2,3-b]

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24

Jicsinszky, Laszlo, Marina Caporaso, Katia Martina, Emanuela Calcio Gaudino, and Giancarlo Cravotto. "Efficient mechanochemical synthesis of regioselective persubstituted cyclodextrins." Beilstein Journal of Organic Chemistry 12 (November 10, 2016): 2364–71. http://dx.doi.org/10.3762/bjoc.12.230.

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A number of per-6-substituted cyclodextrin derivative syntheses have been effectively carried out in a planetary ball mill under solvent-free conditions. The preparation of Bridion® and important per-6-amino/thiocyclodextrin intermediates without polar aprotic solvents, a source of byproducts and persistent impurities, could be performed. Isolation and purification processes could also be simplified. Considerably lower alkylthiol/halide ratio were necessary to reach the complete reaction in comparison with thiourea or azide reactions. While the presented mechanochemical syntheses were carried

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25

Jandl, C., S. Stegbauer та A. Pöthig. "A halide-free pyridinium-substituted η3-cycloheptatrienide–Pd complex". Acta Crystallographica Section C Structural Chemistry 73, № 9 (2017): 754–59. http://dx.doi.org/10.1107/s2053229617012244.

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We report the synthesis and characterization of a novel 4-(dimethylamino)pyridinium-substituted η3-cycloheptatrienide–Pd complex which is free of halide ligands. Diacetonitrile{η3-[4-(dimethylamino)pyridinium-1-yl]cycloheptatrienido}palladium(II) bis(tetrafluoroborate), [Pd(C2H3N)2(C14H16N2)](BF4)2, was prepared by the exchange of two bromide ligands for noncoordinating anions, which results in the empty coordination sites being occupied by acetonitrile ligands. As described previously, exchange of only one bromide leads to a dimeric complex, di-μ-bromido-bis({η3-[4-(dimethylamino)pyridinium-1

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26

Thiounn, Timmy, Moira K. Lauer, Menisha S. Karunarathna, Andrew G. Tennyson, and Rhett C. Smith. "Copolymerization of a Bisphenol a Derivative and Elemental Sulfur by the RASP Process." Sustainable Chemistry 1, no. 2 (2020): 183–97. http://dx.doi.org/10.3390/suschem1020013.

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Fossil fuel refining produces over 70 Mt of excess sulfur annually from for which there is currently no practical use. Recently, methods to convert waste sulfur to recyclable and biodegradable polymers have been delineated. In this report, a commercial bisphenol A (BPA) derivative, 2,2′,5,5′-tetrabromo(bisphenol A) (Br4BPA), is explored as a potential organic monomer for copolymerization with elemental sulfur by RASP (radical-induced aryl halide-sulfur polymerization). Resultant copolymers, BASx (x = wt% sulfur in the monomer feed, screened for values of 80, 85, 90, and 95) were characterized

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27

Sukhikh, Taisiya S., Dmitry S. Kolybalov, Ekaterina K. Pylova, and Sergey N. Konchenko. "Luminescent Zn Halide Complexes with 2-(2-Aminophenyl)benzothiazole Derivatives." Inorganics 10, no. 9 (2022): 138. http://dx.doi.org/10.3390/inorganics10090138.

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We report a comparative study of coordination behaviour of 2-(2-aminophenyl)benzothiazole (NH2-pbt) and its phosphorus-containing derivative, α-aminophosphine oxide (PCNH-pbt), towards zinc halides. The corresponding coordination compounds [Zn(L)2Hal2] (L = PCNH-pbt, Hal = Cl, 1 and Hal = Br, 2) and [Zn(L’)Hal2] (L’ = NH2-pbt, Hal = Cl, 3 and Hal = Br, 4) were obtained as single phases. As evidenced by single-crystal X-ray diffraction analysis, L’ ligand coordinates to Zn in a chelate manner via two N atoms. Despite a similar coordination mode in complexes 3 and 4, the spatial geometry of the

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28

Kuruca, Serap Erdem, Nilgun Karali, Beyza Cetin, Sabriye Karadenizli, and Zeynep Karakas. "The Antileukemic Potential of New Derivatives of 5-Fluoro-1H-Indole-2,3-Dione-3-Thiosemicarbazone on in Vitro Cell Lines." Blood 112, no. 11 (2008): 5055. http://dx.doi.org/10.1182/blood.v112.11.5055.5055.

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Abstract 1H-Indole-2,3-dione (isatin) is an endogenous compound identified in many organisms, possesses a wide range of biological activities. Biological properties of isatin include a range of actions in brain and offer protection against certain types of infections. This molecule has a versatile moiety that displays diverse biological activities, including anticancer activity. The discovery of numerous biologically active 3-substituted 2-indolinones led in the past decade to extensive synthesis of related compounds and as a result, anticancer agents were developed. In particular, among the 5

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29

Wang, Zihan, Qingjuan Dan, Ruo-Yu Zhao, Rang-Dong Xu, Guang-Ning Liu, and Cuncheng Li. "Optical properties of two bismuth(III) halide hybrids with pyridyl sulfide derivative counter cations." Inorganic Chemistry Communications 111 (January 2020): 107632. http://dx.doi.org/10.1016/j.inoche.2019.107632.

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30

Zhang, Feng, Tianye Zhou, Guogang Liu, Jianbing Shi, Haizheng Zhong, and Yuping Dong. "Tetraphenylethylene derivative capped CH3NH3PbBr3 nanocrystals: AIE-activated assembly into superstructures." Faraday Discussions 196 (2017): 91–99. http://dx.doi.org/10.1039/c6fd00167j.

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The surfaces of semiconductor nanocrystals have been known to be a very important factor in determining their optical properties. The introduction of functionalized ligands can further enhance the interactions between nanocrystals, which is beneficial for the assembly of nanocrystals. In a previous report, we developed a ligand-assisted reprecipitation method to fabricate organometal halide perovskite nanocrystals capped with octylamine and oleic acid. Here, a TPE derivative 3-(4-(1,2,2-triphenylvinyl)phenoxy)propan-1-amine, which shows a typical aggregation induced emission feature, is applie

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31

Venkatachalam, Taracad K., Paul V. Bernhardt, Gregory K. Pierens, Damion H. R. Stimson, Rajiv Bhalla, and David C. Reutens. "Synthesis and Characterisation of Indium(III) Bis-Thiosemicarbazone Complexes: 18F Incorporation for PET Imaging." Australian Journal of Chemistry 72, no. 5 (2019): 383. http://dx.doi.org/10.1071/ch18559.

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Several structurally related indium chlorido complexes of bis-thiosemicarbazones were prepared, starting from the appropriately substituted bis-thiosemicarbazones, using sodium methoxide in methanol. Detailed NMR studies were conducted to assign the structure including COSY, HSQC, and HMBC techniques. The structures of all indium complexes were solved using single crystal X-ray diffraction. The chlorido ligand was present at the apex of the square pyramidal coordination sphere in all indium complexes. In some complexes, an intermolecular hydrogen bond was present between the chlorine atom and

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32

Kotora, Martin, Yoshinori Noguchi, and Tamotsu Takahashi. "Reactions of Zirconacyclopentadienes with Propargyl Halides Leading to (Buta-2,3-dien-1-yl)benzenes." Collection of Czechoslovak Chemical Communications 64, no. 7 (1999): 1119–24. http://dx.doi.org/10.1135/cccc19991119.

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The reaction of 1,1-bis(η5-cyclopentadienyl)-1-zirconacyclopenta-2,4-dienes with propargyl halides in the presence of a catalytic or a stoichiometric amount of CuCl afforded benzene derivatives. This reaction involves SN2' type of attack of organocopper intermediate to propargyl halide followed by intramolecular carbometallation, and coupling with the second molecule of propargyl halide.

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33

Franco, Mario, Raquel Sainz, Al Mokhtar lamsabhi, Cristina Díaz, Mariola Tortosa, and Belén M. Cid. "Evaluation of the role of graphene-based Cu(I) catalysts in borylation reactions." Catal. Sci. Technol. 11 (March 17, 2021): 3501. https://doi.org/10.1039/d1cy00104c.

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Carbon-supported catalysts have been considered as macromolecular ligands which modulate the activity of the metallic catalytic center. Understanding the properties and the factors that control the interactions between the metal and support allows a fine tuning of the catalyzed processes. Although huge effort has been devoted to comprehending binding energies and charge transfer for single atom noble metals, the interaction of graphenic surfaces with cheap and versatile Cu(I) salts has been scarcely studied. A methodical experimental and theoretical analysis of different carbon-based Cu(I) mat

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34

Chatterjee, Soumyo, Julia Payne, John T. S. Irvine, and Amlan J. Pal. "Bandgap bowing in a zero-dimensional hybrid halide perovskite derivative: spin–orbit coupling versus lattice strain." Journal of Materials Chemistry A 8, no. 8 (2020): 4416–27. http://dx.doi.org/10.1039/c9ta12263j.

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35

Kianfar, Elham, Uwe Monkowius, Engelbert Portenkirchner, and Günther Knör. "Synthesis and Characterization of Novel Re(BIAN)(CO)3Cl Derivatives Including the First Example of a Water-soluble Tricarbonyl Rhenium(I) Complex with Bis(imino)acenaphthene Ligands." Zeitschrift für Naturforschung B 69, no. 6 (2014): 691–98. http://dx.doi.org/10.5560/znb.2014-4016.

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A series of rhenium(I) carbonyl chloride complexes carrying bis(imino)acenaphthene (BIAN) molecules as p-acceptor ligands was prepared and characterized by various spectroscopic techniques. Among the novel compounds described, the remarkable example of a deeply colored water-soluble rhenium carbonyl derivative is presented. The crystal structures of this family of BIAN compounds are also reported, which confirm the position of the chloro ligand at the tricarbonyl rhenium(I) center. In the case of BIAN ligands carrying bulky substituents in the ortho-position of the arylimino subunits, evidence

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36

Pai, Sung Jin, and Sang Soo Han. "SE2 reaction in noncarbon system: Metal-halide catalysis for dehydrogenation of ammonia borane." Proceedings of the National Academy of Sciences 114, no. 52 (2017): 13625–30. http://dx.doi.org/10.1073/pnas.1712137115.

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An electrophilic substitution (SE) reaction of BN isosteres has been investigated for the dehydrogenation of ammonia borane (AB) by metal chlorides (MCl2) using various ab initio calculations. In contrast to the typical SE reaction occurring at the carbon atom, the nitrogen atom in AB serves as the reaction center for the SE reaction with the boron moiety as the leaving group when the MCl2 approaches the AB. The SE2 backside reaction is favored as a trigger step for the dehydrogenation of AB by the MCl2. The SE2 reaction is found for 3d-transition-metal chlorides (e.g., FeCl2, CoCl2, NiCl2, Cu

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37

Heeney, Martin J., Shaya A. Al-Raqa, Aurélien Auger, et al. "Routes to some 3,6-disubstituted phthalonitriles and examples of phthalocyanines derived therefrom: An overview." Journal of Porphyrins and Phthalocyanines 17, no. 08n09 (2013): 649–64. http://dx.doi.org/10.1142/s108842461330005x.

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The paper reviews a selection of synthetic pathways that provide access to 3,6-disubstituted phthalonitriles, precursors for the synthesis of 1,4,8,11,15,18,22,25-octasubstituted phthalocyanine derivatives. Early routes using Diels–Alder reactions for the synthesis of 3,6-dialkyl, 3,6-dialkoxymethyl, 3,6-dialkenyl and 3,6-diphenylphthalonitriles are appraised. However, the emphasis of the review focuses on the scope and applications of 2,3-dicyanohydroquinone as a starting material for obtaining 3,6-disubstituted phthalonitriles. The earliest example of the use of 2,3-dicyanohydroquinone conce

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Taufique, M. F. N., Samrat Choudhury, and Soumik Banerjee. "Energetics of Solvent-Based Deposition of Fullerene Derivative on the Inorganic–Organic Hybrid Lead Halide Perovskite Surface." Journal of Physical Chemistry C 123, no. 36 (2019): 22368–76. http://dx.doi.org/10.1021/acs.jpcc.9b06093.

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Takagi, Tomohiro, Akitaka Hoshino, Hideki Miyaji, Kunihide Izumi, and Ryohei Kokawa. "Formation Mechanism of Incommensurate Epitaxial Crystals of Chloroiron(III) Derivative of Tetraphenylporphine on Alkali–Halide (001) Surfaces." Japanese Journal of Applied Physics 40, Part 1, No. 12 (2001): 6929–35. http://dx.doi.org/10.1143/jjap.40.6929.

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Lim, Suh-Ciuan, Hsuan-Peng Lin, Wei-Lun Tsai, Hao-Wu Lin, Yao-Tsung Hsu, and Hsing-Yu Tuan. "Binary halide, ternary perovskite-like, and perovskite-derivative nanostructures: hot injection synthesis and optical and photocatalytic properties." Nanoscale 9, no. 11 (2017): 3747–51. http://dx.doi.org/10.1039/c6nr06740a.

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Sundgren, Andreas, Martina Lahmann та Stefan Oscarson. "Synthesis of 6-PEtN-α-D-GalpNAc-(1–>6)-β-D-Galp-(1–>4)-β-D-GlcpNAc-(1–>3)-β-D-Galp-(1–>4)-β-D-Glcp, a Haemophilus influenzae lipopolysacharide structure, and biotin and protein conjugates thereof". Beilstein Journal of Organic Chemistry 6 (26 липня 2010): 704–8. http://dx.doi.org/10.3762/bjoc.6.80.

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Background: In bacteria with truncated lipopolysaccharide structures, i.e., lacking the O-antigen polysaccharide part, core structures are exposed to the immune system upon infection and thus their use as carbohydrate surface antigens in glycoconjugate vaccines can be considered and investigated. One such suggested structure from Haemophilus influenzae LPS is the phosphorylated pentasaccharide 6-PEtN-α-D-GalpNAc-(1→6)-β-D-Galp-(1→4)-β-D-GlcpNAc-(1→3)-β-D-Galp-(1→4)-β-D-Glcp. Results: Starting from a spacer-containing lactose derivative a suitably protected lacto-N-neotetraose tetrasaccharide s

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Curran, Danielle, Helge Müller-Bunz, Sofia I. Bär, Rainer Schobert, Xiangming Zhu, and Matthias Tacke. "Novel Anticancer NHC*-Gold(I) Complexes Inspired by Lepidiline A." Molecules 25, no. 15 (2020): 3474. http://dx.doi.org/10.3390/molecules25153474.

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N-Heterocyclic carbene gold(I) complexes derived from 1,3-dibenzyl-4,5-diphenylimidazol-2-ylidene (NHC*) represent a promising class of anticancer drugs. Complexes of the type NHC*-Au-L (L = Br−, I−, C≡C-R) and [NHC*-Au-L]+ (L = NHC*, PPh3) have been synthesised. The X-ray crystal structures of all gold(I) complexes are presented; aurophilic interactions were observed in five of the complexes. The anticancer activity was assessed via MTT (3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide)-based proliferation assays against the human colon carcinoma cell line HCT-116wt and the multid

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Alam, Ryan M., and John J. Keating. "Regioselective N-alkylation of the 1H-indazole scaffold; ring substituent and N-alkylating reagent effects on regioisomeric distribution." Beilstein Journal of Organic Chemistry 17 (August 2, 2021): 1939–51. http://dx.doi.org/10.3762/bjoc.17.127.

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The indazole scaffold represents a promising pharmacophore, commonly incorporated in a variety of therapeutic drugs. Although indazole-containing drugs are frequently marketed as the corresponding N-alkyl 1H- or 2H-indazole derivative, the efficient synthesis and isolation of the desired N-1 or N-2 alkylindazole regioisomer can often be challenging and adversely affect product yield. Thus, as part of a broader study focusing on the synthesis of bioactive indazole derivatives, we aimed to develop a regioselective protocol for the synthesis of N-1 alkylindazoles. Initial screening of various con

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Shestimerova, Tatiana A., Nikita A. Golubev, Mikhail A. Bykov, et al. "Molecular and Supramolecular Structures of Triiodides and Polyiodobismuthates of Phenylenediammonium and Its N,N-dimethyl Derivative." Molecules 26, no. 18 (2021): 5712. http://dx.doi.org/10.3390/molecules26185712.

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Despite remarkable progress in photoconversion efficiency, the toxicity of lead-based hybrid perovskites remains an important issue hindering their applications in consumer optoelectronic devices, such as solar cells, LED displays, and photodetectors. For that reason, lead-free metal halide complexes have attracted great attention as alternative optoelectronic materials. In this work, we demonstrate that reactions of two aromatic diamines with iodine in hydroiodic acid produced phenylenediammonium (PDA) and N,N-dimethyl-phenylenediammonium (DMPDA) triiodides, PDA(I3)2⋅2H2O and DMPDA(I3)I, resp

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Yoon, Woo-Jun, Scott B. Orlove, Robert L. Olmon, and Paul R. Berger. "Enhanced Emission Using Thin Li-Halide Cathodic Interlayers for Improved Injection into Poly(p-phenylene vinylene) Derivative PLEDs." Electrochemical and Solid-State Letters 11, no. 10 (2008): J76. http://dx.doi.org/10.1149/1.2961823.

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Nhari, Laila M., Elham N. Bifari, Aisha R. Al-Marhabi, et al. "Synthesis of Novel Key Chromophoric Intermediates via C-C Coupling Reactions." Catalysts 12, no. 10 (2022): 1292. http://dx.doi.org/10.3390/catal12101292.

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The fundamentals of Pd-catalyzed Csp2−Csp2 Miyaura borylation, Suzuki cross-coupling, and Stille cross-coupling reactions for a variety of borylated precursors based on phenothiazine (PTZ), phenoxazine (POZ), carbazole (Cz), and quinoxaline (QX) units have been explored. Three palladium-based catalysts were chosen for this study: Pd(PPh3)4, Pd(PPh3)2Cl2, and Pd(dppf)Cl2, applying different reaction conditions. Around 16 desired chromophores were successfully designed and synthesized using C-C cross-coupling reactions in moderate to excellent yields, including PTZ, POZ, and Cz units coupled wit

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Shichijo, Keita, Yoshio Hisaeda та Hisashi Shimakoshi. "Synthesis and Electrochemical Investigation of π Expanded Vitamin B₁₂ Derivative, Pyrocobester". ECS Meeting Abstracts MA2022-01, № 14 (2022): 967. http://dx.doi.org/10.1149/ma2022-0114967mtgabs.

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Vitamin B12 is a unique metal complex which has the cobalt ion and the corrin as a centered metal and a ligand, respectively. The Co(I) state of the vitamin B12 reacts alkyl halide to form alkylated complex by the SN2 type reaction and proceed the several catalytic reactions via alkyl radicals formed by homolysis of the cobalt-carbon bond.[1] Based on these properties of the vitamin B12, many B12-inspired reactions have been developed.[2] In general, many researchers have used the cobyrinate complex (1) as the B12 derivatives. Here, we report the synthesis and characterization of the Co(II) st

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Junghare, Nilesh, Pravin Kadam, Jotiram Chavan, Minakshi Patil, and Gurunath Chougale. "A Highly Efficient, Catalyst-Free Synthesis of S-Alkyl/aryl Dithiocarbamate Derivatives under Green Conditions and Evaluation of their Biological Activity." Asian Journal of Chemistry 35, no. 11 (2023): 2703–7. http://dx.doi.org/10.14233/ajchem.2023.28324.

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An efficient, feasible, transition metal catalyst-free and environmental friendly approach for the synthesis of dithiocarbamate in an ethanol-water solvent combination at room temperature has been established. Alkyl/aryl halide, carbon disulfide and secondary amine were condensed in one pot to produce a range of dithiocarbamate derivatives. Based on the results, the yields were higher when aliphatic amine reacted with benzyl halides as compared to alkyl halides. This method has the advantage of using no hazardous solvents. Other benefits of this method include producing compounds with a good y

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Río, Ignacio del, Robert A. Gossage, Milja S. Hannu, Martin Lutz, Anthony L. Spek та Gerard van Koten. "Synthesis and characterization of two new "pincer" complexes of zinc(II). The X-ray crystal structures of the five coordinate complexes [ZnCl2{η3-NN'N-2,6-(R2NCH2)2C5H3N}] (R = n-Bu or Me)". Canadian Journal of Chemistry 78, № 12 (2000): 1620–26. http://dx.doi.org/10.1139/v00-145.

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The potentially terdentate NN'N donor ligand 2,6-bis[di-(n-butyl)aminomethyl]pyridine (1) does not form a stable, isolable Ru complex using any standard Ru starting materials. This is in contrast to the dimethylamino derivative 2. In the presence of Zn metal as a reducing agent, the treatment of hydrated ruthenium trichloride with 2 leads instead to the isolation of a diamagnetic Zn(II) complex (3) of general formula [ZnCl2(1)]. Analysis of 3 (NMR, X-ray) reveals the complex to be a mononuclear Zn halide compound containing ligand 1 in an η3-NN'N bonding motif. The Zn atom is found to be five-

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Kassa, M. D., N. G. Debelo, and M. M. Woldemariam. "Computational study of structural, elastic, electronic, phonon dispersion relation and thermodynamic properties of orthorhombic CaZrS3 for optoelectronic applications." Condensed Matter Physics 26, no. 2 (2023): 23701. http://dx.doi.org/10.5488/cmp.26.23701.

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Chalcogenide perovskites offer superior thermal and aqueous stability as well as a benign elemental composition compared to organic halide perovskites for optoelectronic applications. In this study, the structural, electrical, elastic, phonon dispersion, and thermodynamic features of the orthorhombic phase of chalcogenide perovskite CaZrS3 (space group Pnma) were examined by first principles calculations utilizing the plane wave pseudopotentials (PW-PPs) in generalized gradient approximations (GGA). The ground state properties such as lattice parameters, unit cell volume, bulk modulus, and its

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