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Journal articles on the topic 'Halogenated alkyls'

Author: Grafiati

Published: 7 June 2025

Last updated: 2 August 2025

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1

Coulibali, Siomenan, Souleymane Coulibaly, Patrick-Armand Achi, Kouassi Yves Guillaume Sissouma Drissa Molou, and Ané Adjou. "Synthesis of New Thiazolopyrimidines and 2-Alkylthiopyrimidines Derivatives." Pharmaceutical and Chemical Journal 9, no. 1 (2022): 5–10. https://doi.org/10.5281/zenodo.13970008.

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In this work, we reported the synthesis of derivative’s 2-thiopyrimidine substituted on the positions -1 and -2 by the alkyl groups. The bicyclic scaffold (<strong>6a</strong> and <strong>6b</strong>) were obtained via condensation of 2-thiopyrimidines (<strong>4a</strong> and <strong>4b</strong>) with dihalogenated ethane <strong>5</strong> in the presence of potassium carbonate<strong>.</strong> We got the 2-thioalkylpyrimidine derivatives (<strong>8a</strong>-<strong>f</strong>) with the same workup, condensing halogenated alkyls <strong>7</strong> with 2-thiopyrimidines (<strong>4a</

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2

Nomura, Kotohiro, Itsuki Izawa, Mahaharu Kuboki, Kensuke Inoue, Hirotaka Aoki, and Ken Tsutsumi. "Solution XAS Analysis for Reactions of Phenoxide-Modified (Arylimido)vanadium(V) Dichloride and (Oxo)vanadium(V) Complexes with Al Alkyls: Effect of Al Cocatalyst in Ethylene (Co)polymerization." Catalysts 12, no. 2 (2022): 198. http://dx.doi.org/10.3390/catal12020198.

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V K-edge XANES (XANES = X-ray Absorption Near Edge Structure) spectra of the reaction solution of V(NAr)Cl2(OAr) (1, Ar = 2,6-Me2C6H3) with halogenated Al alkyls (Me2AlCl, Et2AlCl, EtAlCl2, 50 equiv) in toluene showed low energy shifts (2.6–3.6 eV on the basis of inflection point in the photon energy) in the edge absorption accompanying slight shift to low photon energy in the pre-edge peak (λmax values); a similar spectrum was observed when the reaction of 1 with Me2AlCl was conducted in n-hexane. These results strongly suggest a formation of similar vanadium(III) species irrespective of kind

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3

Igarashi, Atsushi, Wenjuan Zhang, Wen-Hua Sun, and Kotohiro Nomura. "Ethylene Polymerization Using (Imino)vanadium(V) Dichloride Complexes Containing (Anilido)methyl-pyridine, -quinoline Ligands–Halogenated Al Alkyls Catalyst Systems." Catalysts 3, no. 1 (2013): 148–56. http://dx.doi.org/10.3390/catal3010148.

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4

Liu, Yan, Huayou Hu, Junyu Zhou, Wenhui Wang, Youliang He, and Chao Wang. "Application of primary halogenated hydrocarbons for the synthesis of 3-aryl and 3-alkyl indolizines." Organic & Biomolecular Chemistry 15, no. 23 (2017): 5016–24. http://dx.doi.org/10.1039/c7ob00980a.

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A transition-metal-free synthetic route to 3-aryl and 3-alkyl indolizines from electron-deficient alkenes, pyridines and primary halogenated hydrocarbons is reported for the first time using a tandem reaction.

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5

Ai, Youhong, Yangyang Zhan, Dongbo Cai та Shouwen Chen. "A Convenient and Highly Efficient Strategy for Esterification of Poly (γ-Glutamic Acid) with Alkyl Halides at Room Temperature". Polymers 17, № 1 (2024): 10. https://doi.org/10.3390/polym17010010.

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The presented work discusses the highly efficient esterification of poly (γ-glutamic acid) (γ-PGA) with alkyl halides at room temperature. The esterification reaction was completed within 3 h, and the prepared γ-PGA esters were obtained with excellent yields (98.6%) when 1,1,3,3-tetramethylguanidine (TMG) was used as a promoter. The influence of the amount of TMG, solvent, reaction conditions, and alkyl halides on the esterification reaction was examined. It was found that polar aprotic solvents, such as N-Methylpyrrolidone (NMP) and 1,3-Dimethyl-2-imidazolidinone (DMI), were favorable for the

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6

Dong, Zhi-Bing, Jin-Quan Chen, and Jia Guo. "Three-Component Synthesis of 2-Alkylthiobenzoazoles in Aqueous Media." Synthesis 52, no. 13 (2020): 1927–33. http://dx.doi.org/10.1055/s-0039-1690854.

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A highly efficient three-component protocol for the synthesis of the 2-alkylthiobenzoazoles is described. Tetramethylthiuram disulfide (TMTD) cyclized with o-aminothiophenols, generating the intermediate 2-mercaptobenzothiazoles, and the successive C–S coupling with halogenated alkanes afforded a series of 2-alkyl-substituted thiobenzothiazoles smoothly in a one-pot process. This procedure could also be utilized for the preparation of 2-alkyl-substituted thiobenzoxazoles and 2-alkyl-substituted thiobenzimidazoles. Inexpensive and easily available starting materials, metal catalyst-free, broad

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7

Matyugina, Elena S., Evgeniya B. Logashenko, Marina A. Zenkova, Sergey N. Kochetkov, and Anastasia L. Khandazhinskaya. "5′-Norcarbocyclic analogues of furano[2,3-d]pyrimidine nucleosides." Heterocyclic Communications 21, no. 5 (2015): 259–62. http://dx.doi.org/10.1515/hc-2015-0160.

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Abstract5′-Norcarbocyclic analogues of furano[2,3-d]pyrimidine nucleosides as well as 5-bromo and 5-iodouracil derivatives were synthesized to evaluate their potential antitumor activity. The halogenated derivatives display no cytotoxicity with respect to all tested cells: KB-3-1 (human epidermoid carcinoma), HeLa (human cervical epithelioid carcinoma), HuTu-80 (human duodenal cancer), B16 (mouse melanoma), and MDCK (normal epithelial). The cytotoxicity of the non-halogenated furano[2,3-d]pyrimidine derivatives increases with the lengthening of the alkyl chain of the substituent from 45 to 60

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8

Lee, Hing-Biu, M. Lewina Svoboda, Thomas E. Peart, and Shirley Anne Smyth. "Optimization of a microwave-assisted extraction procedure for the determination of selected alkyl, aryl, and halogenated phenols in sewage sludge and biosolids." Water Quality Research Journal 51, no. 4 (2016): 344–56. http://dx.doi.org/10.2166/wqrjc.2016.002.

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A microwave-assisted extraction method for the determination of 15 alkyl, aryl, and halogenated phenols in sewage sludge and biosolids samples was developed and optimized. The effects of solvent, temperature, time, moisture content, acid, and number of extractions on the recovery of phenols were evaluated. Results indicated that extraction solvent had the greatest impact on the recovery of all phenols while pH had the largest effect on recovery of hexachlorophene and pentachlorophenol. Wet sludge samples were extracted with acetone-hexane mixture in the presence of glacial acetic acid. The ext

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9

Ding, Xu, Geng Zhu, Jian-Ning Guan та Guo-Zhi Han. "Selective Reduction of Nitro Group in Aryl Halides Catalyzed by Silver Nanoparticles Modified with β-CD". Journal of Nanoscience and Nanotechnology 18, № 12 (2018): 8201–6. http://dx.doi.org/10.1166/jnn.2018.16406.

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In this paper, we first report the selective reduction of nitro group in aryl halides catalyzed by silver nanoparticles modified with β-CD. Taking advantage of hydrophobic lumen and donor–acceptor behavior of β-CD, the halogenated alkyl groups on the aromatic ring can be enveloped in the inner cavity that thereby inhibits the reduction of the halogen. For validating the mechanism proposed by us, different silver nanoparticles were applied in parallel experiments. In our experiments, UV-vis spectra and NMR spectra were used to characterize the selectivity. This strategy represents an outstandin

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10

Cao, Guo Min, Fang Hong, Mei Sheng, Xiao Dan Shuai, and Lin Hu. "Research on the Reutilization Technology of the Brine from Vinylidene Chloride Synthesis." Advanced Materials Research 610-613 (December 2012): 2242–45. http://dx.doi.org/10.4028/www.scientific.net/amr.610-613.2242.

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The brine from vinylidene chloride (VDC) synthesis contains high concentration of sodium chloride and halogenated hydrocarbons which are all volatile organic chemicals (VOCs). Based on the contaminations’ characteristics in the brine, an air-stripping process was firstly applied for removing most of the halogenated hydrocarbons in the brine, and then the H2O2/UV oxidation process was used for polishing treatment so that the treated brine could be reused as a raw material for a chloro-alkali process. The results showed the residual TOC after air-stripping could be effectively removed by H2O2/UV

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11

Krost, Kenneth J. "Analysis of Selected Chemical Groups by Liquid Chromatography/Mass Spectrometry." Applied Spectroscopy 47, no. 6 (1993): 821–29. http://dx.doi.org/10.1366/0003702934066983.

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The use of a moving-belt liquid chromatography/mass spectrometry interface for identifying selected members of various chemical classes has been investigated. Among the chemical groups examined with this system were benzidines, nitrosoamines, anilines, nitroaromatics, dinitroaromatics, hydrazines, amides, phenylenediamines, organophosphites, acrylates, pyridines, phthalates, nitrophenols, halogenated triazines, pesticides, halogenated pyridines, and alkyl tins. Selective ion monitoring was used for detection in all cases, in view of the lack of sensitivity in the full-scan mode. The lower limi

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12

Hurtová, Martina, David Biedermann, Zuzana Osifová, Josef Cvačka, Kateřina Valentová, and Vladimír Křen. "Preparation of Synthetic and Natural Derivatives of Flavonoids Using Suzuki–Miyaura Cross-Coupling Reaction." Molecules 27, no. 3 (2022): 967. http://dx.doi.org/10.3390/molecules27030967.

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Herein, we report the use of the Suzuki–Miyaura cross-coupling reaction for the preparation of a library of synthetic derivatives of flavonoids for biological activity assays. We have investigated the reactivity of halogenated flavonoids with aryl boronates and with boronyl flavonoids. This reaction was used to prepare new synthetic derivatives of flavonoids substituted at C-8 with aryl, heteroaryl, alkyl, and boronate substituents. The formation of flavonoid boronate enabled a cross-coupling reaction with halogenated flavones yielding biflavonoids connected at C-8. This method was used for th

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13

Li, Kangcong, Yan Gao, Xiuqin Li, Yan Zhang, Benfeng Zhu, and Qinghe Zhang. "Fragmentation Pathway of Organophosphorus Flame Retardants by Liquid Chromatography–Orbitrap-Based High-Resolution Mass Spectrometry." Molecules 29, no. 3 (2024): 680. http://dx.doi.org/10.3390/molecules29030680.

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Organophosphorus flame retardants (OPFRs) have been widely used in polymeric materials owing to their flame retardant and plasticizing effects. Investigating the fragmentation pathway of OPFRs is of great necessity for further discovering and identifying novel pollutants using orbitrap-based high-resolution mass spectrometry (HRMS). A total of 25 OPFRs, including alkyl, halogenated, and aromatic types, were analyzed in this study. The fragmentation pathways of the OPFRs were investigated using orbitrap-based HRMS with high-energy collision dissociation (HCD) in positive mode. The major fragmen

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14

Holman, Robert W., Jennifer Davis, Amy Walstrom та ін. "An Investigation of Gaseous α-Halogenated Carbocations and Isomeric Halonium, Halenium, and Allylhalonium Ions". Australian Journal of Chemistry 56, № 5 (2003): 437. http://dx.doi.org/10.1071/ch02264.

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We investigated with tandem mass spectrometric methods (MS/MS) the nature and extent of stabilization of gas-phase alkyl, vinyl and 2-allyl carbenium ions caused by halogen participation of neighboring chlorine and bromine atoms. The extent of halogen atom stabilization is greatest for alkyl ions, followed closely by that for vinyl ions, and is significantly less for the 2-halosubstituted allyl ions. The data is consistent with bridged halonium ion formation in alkyl systems and bridged halenium ion formation in vinyl systems. Our results for the 2-chloro allyl system are in accord with an ear

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15

Jenne, Carsten, and Christoph Kirsch. "Alkoxy substituted halogenated closo-dodecaborates as anions for ionic liquids." Dalton Transactions 44, no. 29 (2015): 13119–24. http://dx.doi.org/10.1039/c5dt01633a.

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Alkoxy substituted halogenated closo-dodecaborate anions [B<sub>12</sub>X<sub>11</sub>OR]<sup>2−</sup> (X = Cl, Br; R = alkyl) have been synthesized and fully characterized. Thermal analyses were carried out to reveal their properties for possible applications in ionic liquids. The new salt [C<sub>6</sub>mim]<sub>2</sub>[B<sub>12</sub>Cl<sub>11</sub>O-propyl] is an elusive example of an ionic liquid containing a doubly charged anion.

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16

Vivas-Reyes, Ricardo, and Andersson Arias. "Evaluation of group electronegativities and hardness (softness) of group 14 elements and containing functional groups through density functional theory and correlation with NMR spectra data." Ecletica Quimica 33, no. 3 (2008): 69–76. http://dx.doi.org/10.26850/1678-4618eqj.v33.3.2008.p69-76.

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Quantum Chemical calculations for group 14 elements of Periodic Table (C, Si, Ge, Sn, Pb) and their functional groups have been carried out using Density Functional Theory (DFT) based reactivity descriptors such as group electronegativities, hardness and softness. DFT calculations were performed for a large series of tetracoordinated Sn compounds of the CH3SnRR’X type, where X is a halogen and R and R’ are alkyl, halogenated alkyl, alkoxy, or alkyl thio groups. The results were interpreted in terms of calculated electronegativity and hardness of the SnRR’X groups, applying a methodology previo

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17

Wang, Hong-Mei, Tian-Shuai Wang, Sheng-Jie He, Zong-Yun Chen, and Yang-Gen Hu. "An efficient synthesis of 3-alkyl-2-diversity-substituted benzofuro[3,2-d]pyrimidin-4(3H)-one derivatives." Journal of Chemical Research 43, no. 5-6 (2019): 201–4. http://dx.doi.org/10.1177/1747519819858734.

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Benzofuro[3,2- d]pyrimidine derivatives are prepared using aza-Wittig reactions of iminophosphoranes with n-butyl isocyanate at 40–50 °C to give carbodiimide intermediates, which are reacted with nitrogen-oxygen-containing nucleophiles to give 3-alkyl-2-amino (aryloxy/alkoxy)-benzofuro[3,2- d]pyrimidin-4(3 H)-ones in satisfactory yields in the presence of a catalytic amount of sodium ethoxide or K2CO3. The iminophosphorane also reacts directly with excess carbon disulfide, followed by n-propylamine; further reaction with alkyl halides or halogenated aliphatic esters in the presence of anhydrou

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18

Joshi, Om Prakash, Ankit Kumar Dash, Ramalingam Thirumoorthi, and Chandrakanta Dash. "Iron-Catalyzed Annulation of 2-Aminobenzaldehydes with Iodonium Ylides: A Mild and General Route for the Synthesis of Acridinone Derivatives." Asian Journal of Chemistry 36, no. 6 (2024): 1423–28. http://dx.doi.org/10.14233/ajchem.2024.31565.

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An inexpensive iron-catalyzed annulation of 2-aminobenzaldehydes with iodonium ylides for the synthesis of acridinone derivatives was reported. A library of biologically relevant 3,4-dihydropyridine-1-one scaffold was synthesized by the reaction of corresponding 2-amino benzaldehyde and iodonium ylides under mild reaction conditions in a green solvent. The reaction tolerates various alkyl, aryl and halogenated substrates and affords the desired product in moderate to good yields. The reported reaction has an inexpensive catalytic system, mild reaction conditions, easily accessible substrates a

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19

Wooster, R., L. Sutherland, T. Ebner, D. Clarke, O. Da Cruz e Silva, and B. Burchell. "Cloning and stable expression of a new member of the human liver phenol/bilirubin: UDP-glucuronosyltransferase cDNA family." Biochemical Journal 278, no. 2 (1991): 465–69. http://dx.doi.org/10.1042/bj2780465.

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A new human liver UDP-glucuronosyltransferase (HlugP4) has been cloned and expressed in cell culture. The expressed enzyme has a molecular mass of 56 kDa and preferentially catalysed the glucuronidation of halogenated and bulky alkyl phenols. The C-terminal half of the sequence (246 amino acids) is 96% identical with the same portion of HlugP1, whereas the N-terminal half of the deduced protein sequences are only 38% identical. These results suggest that the two isoenzymes may be derived from the same gene by differential splicing of the gene product.

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20

BOGDAL, DARIUSZ, VALERIY YASHCHUK, JAN PIELICHOWSKI, et al. "Spectral investigation of alkyl polymethacrylates with halogenated carbazolyl pendant groups." Polimery 47, no. 04 (2002): 279–81. http://dx.doi.org/10.14314/polimery.2002.279.

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21

Lee, Taeho, Sora Oh, Shafket Rasool, et al. "Non-halogenated solvent-processed ternary-blend solar cells via alkyl-side-chain engineering of a non-fullerene acceptor and their application in large-area devices." Journal of Materials Chemistry A 8, no. 20 (2020): 10318–30. http://dx.doi.org/10.1039/d0ta00947d.

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Ternary-blend organic solar cells based on a novel asymmetric non-fullerene acceptor (T2-OEHRH) processed from a non-halogenated solvent exhibit impressive PCEs of 12.10% and 9.32% in small- and large-area devices, respectively.

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22

Pomarico, Giuseppe, Manuela Stefanelli, Sara Nardis та ін. "Synthesis and functionalization of β-alkyl-meso-triarylcorroles". Journal of Porphyrins and Phthalocyanines 19, № 07 (2015): 865–73. http://dx.doi.org/10.1142/s1088424615500613.

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After the definition of efficient synthetic routes for the preparation of triarylcorroles, the functionalization of these macrocycles is becoming a necessary and challenging field of research. One important synthetic step is the introduction of substituents able to influence the electronic distribution in the macrocyclic ring. A valuable target would be a corrole macrocycle with some β-pyrrole positions occupied by methyl groups, while exploiting other positions to introduce electron-withdrawing substituents. To explore the scope of this approach, we investigated the bromination and the nitrat

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23

Das, Siva Prasad, Rakesh Ganguly, Yongxin Li, and Han Sen Soo. "Nucleophilic reactivity and electrocatalytic reduction of halogenated organic compounds by nickel o-phenylenedioxamidate complexes." Dalton Transactions 45, no. 34 (2016): 13556–64. http://dx.doi.org/10.1039/c6dt02349e.

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Nickel(ii)-ate complexes supported by o-phenylenebis(N-methyloxamide) reacted with alkyl halides to form new imidate tautomers which were characterized by X-ray crystallography and FT-IR spectroscopy, and used for electroreduction of chloroform.

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24

Liu, Huiyan, Zhuye Liang, Qun Qian, and Kunhua Lin. "Nickel-Catalyzed Reductive Alkylation of Halogenated Pyridines with Secondary Alkyl Bromides." Synthetic Communications 44, no. 20 (2014): 2999–3007. http://dx.doi.org/10.1080/00397911.2014.924141.

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25

Blazso, Marianne, and Janos Bozi. "Catalytic Conversion of Thermal Decomposition Products of Halogen Containing Polymers Studied by Pyrolysis-GC-MS." Current Analytical Chemistry 7, no. 2 (2011): 110–16. http://dx.doi.org/10.2174/157341111794815039.

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Feedstock recycling of plastics wastes by pyrolysis is adequate for obtaining valuable oil. However, thermal decomposition products of the halogen containing components of the plastics are contaminating the pyrolysis oil. In this work, pyrolysis-gas chromatography-mass spectrometry combined with online catalytic conversion has been applied to study the activity of Na-zeolite catalysts for dehalogenation of chloro- and bromo-hydrocarbons in pyrolysis oil of poly(vinylbenzyl chloride), polychloroprene, polychlorostyrene and polybromostyrene. GC-MS analysis of the products helped to recognize cat

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26

van Beerendonk, G. J. M., S. D. Nelson, and J. H. N. Meerman. "Metabolism and Genotoxicity of the Halogenated Alkyl Compound Tris(2,3-Dibromopropyl)phosphate." Human & Experimental Toxicology 13, no. 12 (1994): 861–65. http://dx.doi.org/10.1177/096032719401301208.

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1 The genotoxicity of the flame retardant tris(2,3-dibromopropyl)phosphate (Tris-BP) was studied in vivo. Results showed that Tris-BP was highly clasfogenic, but it could only initiate a low number of preneoplastic foci in the rat liver in vivo. In Drosophila, Tris-BP could be classified as a cross-linking agent, because it was more clastogenic than mutagenic. The use of completely deuterated Tris-BP as a metabolic probe revealed that cytochrome P450 and most likely the formation of 2-bromoacrolein (2BA) from Tris-BP is important for the observed genotoxic effects. 2 In contrast to the high mu

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27

Liu, Yingshuai, Guozhu Sheng, Baohong Liu, Ruofei Yin, Yaoyao Du, and Bin Li. "Design, synthesis, and biological activity of novel halogenated sulfite compounds." PLOS One 20, no. 7 (2025): e0327587. https://doi.org/10.1371/journal.pone.0327587.

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The acaricide propargite has been widely used for over 50 years without significant resistance issues. Addressing to the propargite defects of poor crop safety, thirty-six novel halogenated propargite analogues were designed, synthesized, and characterized using 1H NMR, 13C NMR spectroscopy, and HRMS. All target compounds were screened for activity against adult Tetranychus cinnabarinus (spider mites) and Myzus persicae (aphids). Two compounds exhibiting higher insecticidal activity were further evaluated for crop safety on cowpea seedlings. Structural modifications, such as replacing the tert

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28

Al-Sodies, Salsabeel, Nadjet Rezki, Fawzia Faleh Albelwi, et al. "Novel Dipyridinium Lipophile-Based Ionic Liquids Tethering Hydrazone Linkage: Design, Synthesis and Antitumorigenic Study." International Journal of Molecular Sciences 22, no. 19 (2021): 10487. http://dx.doi.org/10.3390/ijms221910487.

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Novel dicationic pyridinium ionic liquids tethering amphiphilic long alkyl side chains and fluorinated counter anions have been successfully synthesized by means of the quaternization of the dipyridinium hydrazone through its alkylation with different alkyl halides. The resulting halogenated di-ionic liquids underwent a metathesis reaction in order to incorporate some fluorinated counter anions in their structures. The structures of all the resulting di-ionic liquids were characterized by several spectroscopic experiments. The antitumorigenic activities of the investigated compounds were furth

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29

McGregor, Pamela A., David R. Allan, Simon Parsons, and Colin R. Pulham. "The low-temperature and high-pressure crystal structures of cyclobutanol (C4H7OH)." Acta Crystallographica Section B Structural Science 61, no. 4 (2005): 449–54. http://dx.doi.org/10.1107/s0108768105019191.

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The low-temperature and high-pressure crystal structures of cyclobutanol (C4H7OH) have been determined using single-crystal X-ray diffraction techniques. At temperatures below 220 K, cyclobutanol crystallizes in the Aba2 space group (Z′ = 2) and its crystal structure is composed of pseudo-threefold hydrogen-bonded molecular catemers [assigned as C_2^2(4) in graph-set notation], which lie parallel to the crystallographic a axis. At a pressure of 1.3 GPa, the crystal symmetry changes to Pna21 (Z′ = 1) and the molecular catemers [expressed as C(2) in graph-set notation] adopt a pseudo-twofold arr

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30

Ravindra, Patil, and Dabade Sapna. "A Review on Grignard Reagent." International Journal of Pharmaceutical Sciences and Medicine 8, no. 4 (2023): 132–42. http://dx.doi.org/10.47760/ijpsm.2023.v08i04.010.

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Grignard reagents are highly reactive organomagnesium halides formed by the reaction of magnesium metal with alkyl or alkenyl halides. They are very strong bases and react with acidic hydrogens such as alcohols, water and carboxylic acids. They are generally produced by reacting an aryl halide or an alkyl halide with magnesium. Grignard compounds are popular reagents in organic synthesis for creating new carbon-carbon bonds. For example, when reacted with another halogenated compound R'−X' in the presence of a suitable catalyst, they typically yield R−R' and the magnesium halide Mg-XX' as a by

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31

Derendorf, Janis, Mathias Keßler, Carsten Knapp, Monika Rühle, and Christoph Schulz. "Alkali metal-sulfur dioxide complexes stabilized by halogenated closo-dodecaborate anions." Dalton Transactions 39, no. 37 (2010): 8671. http://dx.doi.org/10.1039/c0dt00521e.

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32

Foley, Stephen R., Han Shen, Umair A. Qadeer, and Richard F. Jordan. "Generation and Insertion Reactivity of Cationic Palladium Complexes That Contain Halogenated Alkyl Ligands." Organometallics 23, no. 3 (2004): 600–609. http://dx.doi.org/10.1021/om034211z.

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33

Liu, Huiyan, Zhuye Liang, Qun Qian, and Kunhua Lin. "ChemInform Abstract: Nickel-Catalyzed Reductive Alkylation of Halogenated Pyridines with Secondary Alkyl Bromides." ChemInform 46, no. 8 (2015): no. http://dx.doi.org/10.1002/chin.201508222.

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34

Ke, Hui Min, Ri Peng Zhu, Jing Hong Ma, and Jing Hua Gong. "Preparation and Properties of Halogen-Free Flame Retardant Polyurethane for Superfine Fiber Leather." Materials Science Forum 993 (May 2020): 669–77. http://dx.doi.org/10.4028/www.scientific.net/msf.993.669.

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Polyurethane (PU) superfine fiber leathers have been widely used in people's life. However, the flammability brings potential risks to their application. Therefore, more and more attention has been paid to the flame retardant modification of PU leathers. In the 1980s, researchers found that some brominated flame retardants produced dioxins during combustion. In 2007, the EU began implementing the REACH regulation, which restricted the use of certain halogenated flame retardants, so a majority of studies focused on halogen-free flame retardant modification. In addition, the halogen-free flame r

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35

Netscher, Thomas, and Patrick Bohrer. "Towards Highly Activating Leaving Groups: Studies on the Preparation of Some Halogenated Alkyl Sulfonates." Molecules 7, no. 8 (2002): 601–17. http://dx.doi.org/10.3390/70800601.

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Węgłowska, Dorota, Michał Czerwiński, Przemysław Kula, Mateusz Mrukiewicz, Rafał Mazur, and Jakub Herman. "Fast-response halogenated 4-alkyl-4′′-cyano-p-terphenyls as dual frequency addressing nematics." Fluid Phase Equilibria 522 (November 2020): 112770. http://dx.doi.org/10.1016/j.fluid.2020.112770.

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37

Gueutin, Claire, та Doris Lexa. "Low temperature spectroelectrochemistry for the characterization of highly reduced σ-alkyl iron halogenated porphyrins". Electroanalysis 8, № 11 (1996): 1029–33. http://dx.doi.org/10.1002/elan.1140081110.

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Dumitrescu, Denisa, Sergiu Shova, Isabela C. Man, Mino R. Caira, Marcel Mirel Popa, and Florea Dumitrascu. "5-Iodo-1-Arylpyrazoles as Potential Benchmarks for Investigating the Tuning of the Halogen Bonding." Crystals 10, no. 12 (2020): 1149. http://dx.doi.org/10.3390/cryst10121149.

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5-Iodo-1-arylpyrazoles are interesting templates for investigating the halogen bond propensity in small molecules other than the already well-known halogenated molecules such as tetrafluorodiiodobenzene. Herein, we present six compounds with different substitution on the aryl ring attached at position 1 of the pyrazoles and investigate them in the solid state in order to elucidate the halogen bonding significance to the crystallographic landscape of such molecules. The substituents on the aryl ring are generally combinations of halogen atoms (Br, Cl) and various alkyl groups. Observed halogen

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Seetula, Jorma A. "Ab initio study of the transition states for determining the enthalpies of formation of alkyl and halogenated alkyl free radicals." Physical Chemistry Chemical Physics 2, no. 17 (2000): 3807–12. http://dx.doi.org/10.1039/b001350l.

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Tian, Peng, Zhi Gang Zhao, Yang Yang Song, Bo Meng, Tian Ling Qin, and Ting Ting Zhu. "Preparation and Characterization of N-Butyl Pyridine Nitrate." Applied Mechanics and Materials 295-298 (February 2013): 220–23. http://dx.doi.org/10.4028/www.scientific.net/amm.295-298.220.

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The halogenated hydrocarbon and pyridine are used in the synthesis of room temperature ionic liquid intermediates chlorinated N-butyl pyridine BPC. We use the double decomposition reaction of BPC and NaNO3in acetone for the synthesis of BP-NO3 ionic liquids. We use infrared spectrometer for the structSubscript texture characterization, it is proved that we have gotten BP-NO3room temperature ionic liquids. Solvent polarity and acidSubscript textalkali both will have a room temperature ionic liquid ultraviolet spectrum diagram happen displacement, so in the ionic liquid and other solvent mixed s

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Wang, Feng, and Delano P. Chong. "The Role of Exchange Energy in Modeling Core-Electron Binding Energies of Strongly Polar Bonds." Molecules 30, no. 13 (2025): 2887. https://doi.org/10.3390/molecules30132887.

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Accurate determination of carbon core-electron binding energies (C1s CEBEs) is crucial for X-ray photoelectron spectroscopy (XPS) assignments and predictive computational modeling. This study evaluates density functional theory (DFT)-based methods for calculating C1s core-electron binding energies (CEBEs), comparing three functionals—PW86x-PW91c (DFTpw), mPW1PW, and PBE50—across 68 C1s cases in small hydrocarbons and halogenated molecules (alkyl halides), using the delta self-consistent field ΔSCF (or ΔDFT) method developed by Chong et al. over the past decade. The PW86x-PW91c functional achie

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Feng, Xue Zhen, Zhuanquan Xiao, Li Zhang та ін. "Antifungal Activity of β-Pinene-Based Hydronopyl Quaternary Ammonium Salts Against Phytopathogenic Fungi". Natural Product Communications 15, № 8 (2020): 1934578X2094836. http://dx.doi.org/10.1177/1934578x20948365.

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β-Pinene can be used as a cheap source to synthesize a large number of high value-added derivatives. In this study, a series of β-pinene derivatives was prepared, and the antifungal activities of the compounds were assessed against phytopathogenic fungi. Eight N-alkyl hydronopyl diethyl ammonium halide salts were synthesized by the reaction of hydronopyl diethyl ammonium halide with 8 halogenated alkanes. The structures of the synthesized products were characterized by Fourier-transform infrared spectroscopy and nuclear magnetic resonance spectroscopy and mass spectrometry. The antifungal acti

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Bleckmann, P., U. Englich, U. Hermann, et al. "Synthesis and Reactivity of Novel Bis(stannyl)silanes." Zeitschrift für Naturforschung B 54, no. 9 (1999): 1188–96. http://dx.doi.org/10.1515/znb-1999-0916.

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Bis(stannyl)silanes of types R3Sn-SiR′2-SnR3 and R2(H)Sn-SiR′2-Sn(H)R2 with R′ being methyl, phenyl, iso-propyl or terf-butyl have been synthesized by treatment of difunctionalized diorganosilanes with alkali stannides (R = Me, tBu; R′= Me, iPr; 1 - 6, 8 ) or with triphenyltin chloride and magnesium (R = Ph; R′ = Me, iPh;Pr; 7, 9). Me3Sn-SitBu2-SnMe3 4, was halogenated using SnCl4, to yield the bis(chlorostannyl)silane 11. The reaction of bis(stannyl)diorganosilanes R3SnSiR′SnR3 with catalytic amounts of Pd(PPh3)4 resulted in unexpected rearrangements under formation of the silyldistannanes R3

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MINEGISHI, KENICHIRO, HIDEO KUREBAYASHI, SEIICHI NAMBARU, KAZUSHIGE MORIMOTO, TERUE TAKAHASHI, and TSUTOMU YAMAHA. "Comparative studies on absorption, distribution, and excretion of flame retardants halogenated alkyl phosphate in rats." Eisei kagaku 34, no. 2 (1988): 102–14. http://dx.doi.org/10.1248/jhs1956.34.102.

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Khilifi, Akila, Noureddine Raouafi, Issa Tapsoba, Khaled Boujlel, and Mohamed Lamine Benkhoud. "Reactivity of N-thioamido amidines with halogenated alkyl derivatives: synthesis of 4,5-disubstituted 2-alkylaminothiazoles." Journal of Sulfur Chemistry 29, no. 6 (2008): 593–605. http://dx.doi.org/10.1080/17415990802346002.

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SCOUTEN, WILLIAM H., RUSSELL RINES, A. H. L. MULDER, and REINHART LOY. "Chromophoric and Affinity Ligand-containing Halogenated N-Alkyl Pyridiniums as Activating Agents for Hydroxylic Matrices." Annals of the New York Academy of Sciences 542, no. 1 Enzyme Engine (1988): 204–9. http://dx.doi.org/10.1111/j.1749-6632.1988.tb25829.x.

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Ganter, Matthew J., Brian J. Landi, James J. Worman, Christopher M. Schauerman, Cory D. Cress, and Ryne P. Raffaelle. "Variation of single wall carbon nanotube dispersion properties with alkyl amide and halogenated aromatic solvents." Materials Chemistry and Physics 116, no. 1 (2009): 235–41. http://dx.doi.org/10.1016/j.matchemphys.2009.03.020.

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Siporska, A., and J. Szydłowski. "Phase behavior of ionic liquids 1-alkyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imides with halogenated benzenes." Journal of Chemical Thermodynamics 88 (September 2015): 22–29. http://dx.doi.org/10.1016/j.jct.2015.04.012.

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Bogdal, D., V. Yashchuk, J. Pielichowski, T. Ogul'Chansky, M. Warzala, and V. Kudrya. "Synthesis and spectral investigation of alkyl methacrylates with halogenated carbazolyl pendant groups for photonics applications." Journal of Applied Polymer Science 84, no. 9 (2002): 1650–56. http://dx.doi.org/10.1002/app.10469.

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Watanabe, Seiya, Georgia A. Pilkington, Anna Oleshkevych, et al. "Interfacial structuring of non-halogenated imidazolium ionic liquids at charged surfaces: effect of alkyl chain length." Physical Chemistry Chemical Physics 22, no. 16 (2020): 8450–60. http://dx.doi.org/10.1039/d0cp00360c.

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Control of the interfacial structures of ionic liquids (ILs) at charged interfaces is important to many of their applications, including in energy storage solutions, sensors and advanced lubrication technologies utilising electric fields.

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