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Dissertations / Theses on the topic 'Halogenated compound'

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Published: 4 June 2021

Last updated: 7 February 2022

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1

Rehfuss, Marc Y. "Characterization and phylogenetic analysis of a phenol and halogenated aromatic compound degrading microbial consortium /." Search for this dissertation online, 2004. http://wwwlib.umi.com/cr/ksu/main.

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2

Smith, Madelyn M. "Cometabolic Degradation of Halogenated Aliphatic Hydrocarbons by Aerobic Microorganisms Naturally Associated with Wetland Plant Roots." Wright State University / OhioLINK, 2012. http://rave.ohiolink.edu/etdc/view?acc_num=wright1341854406.

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3

Nijenhuis, Ivonne [Verfasser], R. Gary [Akademischer Betreuer] Sawers, G. [Akademischer Betreuer] Diekert, and Lollar B. [Akademischer Betreuer] Sherwood. "Characterisation of microbial transformation of halogenated organic contaminants using compound-specific stable isotope analysis / Ivonne Nijenhuis. Betreuer: R. Gary Sawers ; G. Diekert ; B. Sherwood Lollar." Halle, Saale : Universitäts- und Landesbibliothek Sachsen-Anhalt, 2016. http://d-nb.info/109078662X/34.

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4

Paschoalato, Cristina Filomêna Pereira Rosa. "Efeito da pré-oxidação, coagulação, filtração e pós-cloração na formação de subprodutos orgânicos halogenados em águas contendo substâncias húmicas." Universidade de São Paulo, 2005. http://www.teses.usp.br/teses/disponiveis/18/18138/tde-04022016-122828/.

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A presença de substâncias húmicas em águas destinadas ao abastecimento tem ocasionado diversos problemas, decorrentes da formação de subprodutos orgânicos halogenados, principalmente quando se emprega a pré-oxidação com cloro. Os compostos orgânicos halogenados, reconhecidamente carcinogênicos e que podem ser encontrados nas águas tratadas e distribuída à população, são: trialometanos, ácidos haloacéticos, haloaldeidos, halocetonas, halofenóis e halopicrinas. Nas estações de tratamento de água para abastecimento (ETAs), a utilização da etapa de pré-oxidação da água bruta com cloro contribui pa

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5

Connell, Richenda K. "Tropospheric degradation of halogenated compounds." Thesis, University of Oxford, 1995. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.320615.

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6

Huang, Jinqing, and 黃普卿. "A study of the reaction mechanisms and reactive intermediates involved in halogenated compounds : trichloroethylene oxide, halogenated benzophenones, and halogenated quinoline-based phototriggers." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2014. http://hdl.handle.net/10722/208036.

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UV/Vis absorption spectroscopy (UV/Vis), femtosecond transient absorption spectroscopy (fs-TA), nanosecond transient absorption spectroscopy (ns-TA), and nanosecond time-resolved resonance Raman spectroscopy (ns-TR3), as well as density functional theory (DFT) computations were employed to study the mechanisms and the intermediates in reactions of selected halogenated compounds, including trichloroethylene oxide (TCE oxide), halogenated benzophenones (4-FBP, 4-ClBP, 4-BrBP, 3-FBP, 33’-DFBP, 3-ClBP, 3-BrBP, 2-FBP, 2-ClBP, and 2-BrBP), and halogenated quinoline-based phototriggers (BHQ-OPh and B

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7

Greenacre, Caroline M. "Tropospheric chemistry of halogenated organic compounds." Thesis, University of Oxford, 2004. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.404120.

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8

Kinnison, David J. A. "Tropospheric chemistry of halogenated organic compounds." Thesis, University of Oxford, 1994. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.240663.

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9

Armfield, Susan J. "Microbial dehalogenation of halogenated aliphatic compounds." Thesis, University of Kent, 1990. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.253744.

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10

Allpress, James David. "Microbial transformation of halogenated organic compounds." Thesis, Manchester Metropolitan University, 1995. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.309883.

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11

Hoxworth, Scott. "DEGRADATION OF HALOGENATED ALIPHATIC COMPOUNDS IN SEQUENTIAL ANAEROBIC." Master's thesis, University of Central Florida, 2004. http://digital.library.ucf.edu/cdm/ref/collection/ETD/id/2803.

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The objective of this study was to utilize an alternating anaerobic/aerobic sequence to biologically transform perchloroethylene to non-hazardous end products such as ethylene, CO2 and H2 using a single microbial consortia in a methanogenic and/or a homoacetogenic environment followed by a aerobic methanotrophic environment. Reductive dechlorination of PCE and TCE to cDCE and VC in an anaerobic environment is typically carried out by methanogens, sulfidogens, or homoacetogens but often (e.g. in-situ) leads to an accumulation of daughter compounds (cDCE, VC) which are more toxic than their pare

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12

Al-Haddad, Ameera S. "Chromatographic and spectroscopic studies of halogenated aromatic compounds." Thesis, University of East Anglia, 1989. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.327872.

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13

Nagarajan, Jayasudha. "Metabolism of halogenated compounds by Rhodococcus UKMP-5M." Thesis, Imperial College London, 2014. http://hdl.handle.net/10044/1/34383.

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Members of the genus Rhodococcus are well known for their high metabolic capabilities to degrade wide range of organic compounds ranging from simple hydrocarbons to more recalcitrant compounds such as polychlorinated biphenyls. Their ability to display novel enzymatic capabilities for the transformation of many hazardous contaminants in the environment makes them a potential candidate for bioremediation. Rhodococcus UKMP-5M, an actinomycete isolated in Peninsular Malaysia shows great potential towards degradation of cyanide, hydrocarbons and phenolic compounds. In the present study, the capaci

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14

Lowe, Peter Richard. "Molecular detection and analysis of the diversity of bacterial dehalogenases." Thesis, University of Aberdeen, 2001. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.368833.

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The identification and isolation of bacteria capable of dehalogenating highly chlorinated aromatic compounds is currently a time consuming process, therefore the ability to predict the potential of a site to naturally remediate contamination is limited. This work has assessed a selection of modern molecular biological techniques to detect the presence of specific dehalogenase enzymes or the genes encoding them, as an indicator of a contaminated site's potential to perform remediation naturally. DNA and protein based detection strategies were tested in a variety of formats. DNA detection of deh

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15

Carss, Steven Andrew. "High-resolution NMR studies of solid halogenated organic compounds." Thesis, Durham University, 1995. http://etheses.dur.ac.uk/5208/.

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This thesis is a study of solid halogenated organic compounds by Nuclear Magnetic Resonance Spectroscopy (NMR) in an attempt to extract previously inaccessible information. The first part of the thesis is concerned with three fluorinated steroids, studied by observing (^1)H, (^13)C and (^19)F nuclei. A number of experimental techniques are employed to verify solution-state and solid-state spectral assignments, and spectral anomalies are discussed. Both proton-coupled and proton-decoupled (^19)F solid-state spectra, recorded using specially designed spectrometer hardware, are presented. The hug

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16

Mohran, Hossnia Saber. "Analytical and thermodynamic studies on some halogenated benzenoid compounds." Thesis, Royal Holloway, University of London, 1986. http://repository.royalholloway.ac.uk/items/6eed7444-a22e-47ac-bcc7-850e50d14fbb/1/.

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The bromination of 2-fluorophenol, 3-fluorophenol, 4-fluorophenol, 2-fluoroaniline, 3-fluoroaniline and 4-fluoroaniline was carried out inaqueous medium using an acidified mixture of potassium bromate andpotassium bromide as a source of bromine. The chlorination of thesecompounds was carried out using sulphuryl chloride as a chlorinatingagent in chloroform or diethyl ether. Anhydrous aluminium chloridewas used as a catalyst in the chlorination of the fluoroanilines. All the reaction products obtained were analyzed by fluorine-19 nuclear magnetic resonance spectroscopy (F n.m.r. spectroscopy),

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17

Misra, Ashutosh. "Kinetics and Thermochemistry of Halogenated Species." Thesis, University of North Texas, 1997. https://digital.library.unt.edu/ark:/67531/metadc278143/.

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18

Guan, Xiangguo. "The photochemistry of polyhalomethanes in water and the water-catalyzed dehalogenation reactions of selected isopolyhalomethanes, halogenated methanols and halogenated formaldehydes." Click to view the E-thesis via HKUTO, 2006. http://sunzi.lib.hku.hk/hkuto/record/B38718960.

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19

Guan, Xiangguo, and 官向國. "The photochemistry of polyhalomethanes in water and the water-catalyzed dehalogenation reactions of selected isopolyhalomethanes,halogenated methanols and halogenated formaldehydes." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2006. http://hub.hku.hk/bib/B38718960.

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20

Vienravi, Veerawan. "A new haloalkane dehalogenase in Pseudomonas sp. E4M." Thesis, University of Kent, 1993. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.335147.

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21

Thompson, Katherine C. "Aspects of the tropospheric chemistry of halogenated compounds and chlorine atoms." Thesis, University of Oxford, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.302490.

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22

O'Sullivan, Deborah Antoinette. "Temporal and spatial variability of halogenated compounds and other trace gases." Thesis, University of East Anglia, 2008. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.490606.

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Air samples. from four aircraft campaigns and two surface experiments covering a large geographical area over both hemispheres have been analysed using the technique of gas chromatography mass spectroscopy (GCMS). Around 40 trace gases have been detected and where possible quantified, including most of the CFC's, HCFC's, and halon's, HFC-134a, HFC-152a, HFC-365mfc, CCI4, CH3CCb, CH3Br, CH3CI, and a number of short lived halogenated compounds including CH31, CHBr3, CH2BrCI, and n-C3H7Br. From the data obtained it has been possible to investigate the spatial and temporal variability of halogenat

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23

Raimund, Stefan. "Sources and fluxes of volatile halogenated organic compounds in highly productive marine areas." Brest, 2010. http://www.theses.fr/2010BRES2022.

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Les Composés Halogénés Organiques Volatils (VHOC) sont des composès qui influencent largement la chimie atmosphérique et qui ont des sources naturelles et anthropiques. La production biogénique, les sources marines et les flux à l’interface air-mer de ces composés sont encore peu connues et ont fait l’objet de cette étude. Un système analytique et de nouveaux systèmes de prélèvement ont été développés. Lors d’un travail au laboratoire, il a été démontré que la communication plante-plante orchestre la formation des VHOC : une algue pré-traitée réagit moins intensément après réception d’un signa

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24

Baptista, Inês Isabel Rodrigues. "Biomolecular approach to the study of microbial dynamics during biodegradation of halogenated compounds." Thesis, Imperial College London, 2008. http://hdl.handle.net/10044/1/11498.

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25

Muftikian, Rosy. "Dehalogenation of halogenated aliphatic organic compounds in the presence of the bimetallic system palladized iron." Diss., The University of Arizona, 1997. http://hdl.handle.net/10150/288956.

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Saturated and unsaturated chlorinated aliphatic hydrocarbons containing one to three carbons are commonly used as industrial solvents. These solvents are often found as contaminants in groundwater through improper disposal and many of them are carcinogenic. Remediation of groundwater containing these chlorinated compounds is of obvious importance. Methods such as air stripping and carbon adsorption involve the physical transfer of these contaminants onto activated carbon, and that does not diminish their toxicity. Other methods such as U.V. irradiation in the presence of ozone, hydrogen peroxi

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26

Wevill, David John. "Atmospheric and marine measurements of volatile halogenated organic compounds in coastal and open ocean environments." Thesis, University of York, 2005. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.425413.

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27

Jaramillo-Fellin, Donna Marie. "Reactions of halogenated compounds on Pd(111) studied by LITD-FTMS, TPD, and FT-RAIRS /." For electronic version search Digital dissertations database. Restricted to UC campuses. Access is free to UC campus dissertations, 2002. http://uclibs.org/PID/11984.

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28

Wee, Hun Young. "Remedial extraction and catalytic hydrodehalogenation for treatment of soils contaminated by halogenated hydrophobic organic compounds." [College Station, Tex. : Texas A&M University, 2007. http://hdl.handle.net/1969.1/ETD-TAMU-1280.

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29

Palmer, Carl James. "A study of the distribution and origin of volatile halogenated organic compounds in troposphere and oceans." Thesis, University of York, 2006. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.432223.

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30

Brücher, Jörg. "The influence of sorption on transport of organic compounds in soil /." Uppsala : Swedish Univ. of Agricultural Sciences (Sveriges lantbruksuniv.), 1999. http://epsilon.slu.se/avh/1999/91-576-5481-6.pdf.

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31

Cherukuri, Laxmi Deepshika. "CATALYTIC GROWTH OF STRUCTURED CARBON via THE DECOMPOSITION OF HALOGENATED REACTANTS OVER SUPPORTED NICKEL." UKnowledge, 2007. http://uknowledge.uky.edu/gradschool_theses/459.

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The synthesis of highly ordered carbonaceous materials, including carbon nanofibers, has been the subject of a disparate and burgeoning literature over the past decade. Growth of carbon nanotubes via an atypical catalytic route, the decomposition of halogenated reactants as chlorobenzene (CB) over 10% (w/w) Ni/SiO2 is investigated. The C (carbon) yield and structural order are a function of reaction time and temperature. Greater degree of structural order and C yield is observed from CB relative to benzene, suggesting Cl/catalyst interaction(s) and metal site restructuring. Evaluation of the e

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32

Lou, Yaoyin. "Electrochemical processes as a pre-treatment step before biological treatment : Application to the removal of organo-halogenated compounds." Thesis, Rennes, Ecole nationale supérieure de chimie, 2019. http://www.theses.fr/2019ENCR0057.

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Le couplage d’un traitement électrochimique avec un procédé biologique est une alternative prometteuse pour la dégradation de composés organo-halogénés biorécalcitrants dans l’environnement. Les procédés d’électroréduction, connus pour couper sélectivement la liaison carbone-halogène, ont été mis en oeuvre afin de réduire la toxicité des molécules cibles et augmenter leur biodégradabilité avant une minéralisation totale des polluants par un traitement biologique. Pour améliorer le rendement de déchloration, la cathode préalablement nickelée a été modifiée par des nanoparticules d’argent car l’

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33

Sarathy, Vaishnavi. "Engineered remediation and natural attenuation of halogenated alkanes (carbon tetrachloride and 1,2,3-trichloropropane) : a study of contaminant reactivity and reductant morphology /." Full text open access at:, 2008. http://content.ohsu.edu/u?/etd,651.

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34

Stein, Erika Mattos. "Barcode e bioprospecção de metabólitos das algas marinhas Laurencia aldingensis, L. dendroidea e Laurenciella sp. (Ceramiales, Rhodophyta)." Universidade de São Paulo, 2016. http://www.teses.usp.br/teses/disponiveis/9/9141/tde-19102016-155122/.

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A natureza e diversidade das estruturas químicas com atividade farmacológica que se tem encontrado nos organismos marinhos justificam a busca por novos compostos que são de interesse nas mais diversas áreas de aplicação. As espécies de macroalgas vermelhas, em especial Laurencia spp., merecem destaque pela enorme variedade de terpenos e acetogeninas que produzem, sendo consideradas de grande potencial na produção de novos fármacos. O estudo de seus constituintes pode fornecer importantes subsídios para a quimiotaxonomia, ecologia química, caracterização das espécies e avaliação do potencial bi

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35

Kossoski, Fábris. "Dinâmica de íons temporários de biomoléculas halogenadas." Universidade de São Paulo, 2016. http://www.teses.usp.br/teses/disponiveis/43/43134/tde-08042016-142136/.

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Apresentamos resultados para o espectro de ânions e para a dinâmica vibracional induzida pela captura eletrônica, para uma série de moléculas halogenadas. Os estados do ânion foram caracterizados por meio de cálculos de espalhamento elástico realizados na aproximação de núcleos fixos, efetuados com o método multicanal de Schwinger com pseudopotenciais. Cálculos de dinâmica quântica do pacote de onda nuclear foram realizados a partir da propagação desse nas superfícies de energia potencial descritas na aproximação local. Foram alvo de estudo clorometano, cloroeteno, uracila, 5-fluorouracila, 5-

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36

Sandau, Courtney Douglas. "Analytical chemistry of hydroxylated metabolites of PCBs and other halogenated phenolic compounds in blood and their relationship to thyroid hormone and retinol homeostasis in humans and polar bears." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 2001. http://www.collectionscanada.ca/obj/s4/f2/dsk3/ftp04/NQ57637.pdf.

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37

Sandau, Courtney Douglas Carleton University Dissertation Chemistry. "Analytical chemistry of hydroxylated metabolites of PCBs and other halogenated phenolic compounds in blood and their relationship to thyroid hormone and retinol homeostasis in humans and polar bears." Ottawa, 2000.

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38

Fejfar, José Luiz. "Resolução cinética em reações de substituição nucleofílica mediadas por catalisadores por transferência de fase derivados da efedrina, cinchonidina e quinina." Universidade de São Paulo, 2001. http://www.teses.usp.br/teses/disponiveis/46/46135/tde-29112018-120557/.

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Neste trabalho foram estudadas reações de substituição nucleofílica alifática de seis substratos halogenados, na presença de sais quaternários de amônio quirais (catalisadores por transferência de fase), derivados de alcalóides naturais. O sistema usado durante os trabalhos foi o sólido-líquido, sendo utilizado o tolueno como solvente do substrato halogenado. Os eletrófilos escolhidos para este trabalho foram, em sua grande maioria, compostos halogenados na posição alfa à carbonila e o nucleófilo foi o fenilmercapteto de sódio. A estrutura do substratos, as condições de reação e o tipo de cata

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39

Lien, Hsing-Lung. "Nanoscale bimetallic particles for dehalogenation of halogenated aliphatic compounds /." Diss., 2000. http://gateway.proquest.com/openurl?url_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:dissertation&res_dat=xri:pqdiss&rft_dat=xri:pqdiss:9982868.

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40

Allen, Grant Richard. "Laser pyrolysis of selected halogenated compounds with W(CO)6." 2000. http://hdl.handle.net/2292/609.

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The pyrolysis of selected halogenated compounds in the absence and presence of W(CO)6 has been investigated using infrared laser powered homogeneous pyrolysis (IR LPHP). The chemistry of these compounds in the absence of W(CO)6 is dominated by the themes of dehydrohalogenation (where available) and C–X bond homolysis (where X = halogen). The pyrolysis of W(CO)6 in the gas phase at moderate temperatures leads to unsaturated W(CO)x species; these prove to be very effective and selective abstractors of Cl and Br atoms from the selected halogenated compounds. The subsequent chemistry is dominated

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41

Tang, Datong. "Chemistry of highly halogenated cyclopentadiene dimers and cages /." 2002. http://gateway.proquest.com/openurl?url_ver=Z39.88-2004&res_dat=xri:pqdiss&rft_val_fmt=info:ofi/fmt:kev:mtx:dissertation&rft_dat=xri:pqdiss:3039059.

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42

Taylor, Stephanie Michelle 1985. "Biosynthesis of coenzyme M and the catabolism of halogenated aromatic compounds." Thesis, 2012. http://hdl.handle.net/2152/28462.

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Methanogens, members of the domain Archaea, are unique in their ability to reduce carbon substrates to methane. Coenzyme M (CoM) is required in all methanogenic pathways. The biosynthesis of this coenzyme has been well studied in Class I Methanogens, but in Class II Methanogens, such as Methanosarcina acetivorans, little is known. The first step in the biosynthetic pathway might be catalyzed by cysteate synthase (CS), which converts phosphoserine to cysteate by the addition of sulfite. The 46 kDa enzyme was successfully purified from inclusion bodies and characterized. The identity of the p

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43

Powis, Melanie Lynn. "Modulation of Aryl Hydrocarbon Receptor-dependent Transcription by Halogenated Compounds and Pharmaceuticals." Thesis, 2011. http://hdl.handle.net/1807/29602.

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The aryl hydrocarbon receptor (AHR) mediates the toxic effects of halogenated aromatic hydrocarbons (HAHs), including 2,3,7,8-tetrachlorodibenzo-p-dioxin, 2,3,4,7,8-pentachlorodibenzofuran and 2,3,7,8-tetrachlorodibenzofuran. Y322 is believed to play a role in binding-independent activation of AHR by atypical inducers, such as omeprazole. I examined AHR-mediated regulation of and coactivator recruitment to CYP1A1, CYP1B1, HES1 and TiPARP in T-47D and HuH7 cells. All compounds induced expression of each gene in both cell lines, with some temporal differences between the HAHs and omeprazole.

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44

Sheu, Jong Rong, and 許中榮. "Quantitative-Structure Activity Relationship of Halogenated Aromatics and Toxic Organophosphorus Toxic Compounds." Thesis, 1994. http://ndltd.ncl.edu.tw/handle/35925665904189229376.

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45

Xu, Zhong-Rong, and 許中榮. "Quantitative-Structure Activity Relationship of Halogenated Aromatics and Toxic Organophosphorus Toxic Compounds." Thesis, 1994. http://ndltd.ncl.edu.tw/handle/23546659227774256979.

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46

Han, Tsung-Han, and 韓宗翰. "A Study of Auto-Ignition Temperatures for Halogenated Organic Compounds and Ion Liquids." Thesis, 2012. http://ndltd.ncl.edu.tw/handle/46617443543495533830.

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碩士<br>國立高雄第一科技大學<br>環境與安全衛生工程研究所<br>100<br>In recent years, a large quantity of flammable liquids are used in both petrochemical industries and high-tech industries, therefore recognition and understanding the hazardous characteristics of these flammable liquids are important issues for preventing the fire hazard or explosion hazard. Auto-ignition temperature (AIT) is one of the major attributes for assessing the flammability characteristics of a liquid. For example, National Fire Protection Association 70 code (NFPA 70), in Article 500.8, provides that “Class I equipment shall not have any ex

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47

Wu, Chia-Yan, and 吳佳燕. "Photodissociation of halogenated compounds monitored with step-scan time-resolved Fourier-transform infrared emission spectroscopy." Thesis, 2004. http://ndltd.ncl.edu.tw/handle/67012436840573852199.

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48

Olson, David Alan. "In-home formation of halogenated volatile organic compounds (VOCS) implications for human exposure and indoor air quality /." Thesis, 2002. http://wwwlib.umi.com/cr/utexas/fullcit?p3086783.

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49

Osorio, Amado Carmen H. "Experimental and Computational Study of Flame Inhibition Mechanisms of Halogenated Compounds in C1-C3 Alkanes Flames." Thesis, 2013. http://hdl.handle.net/1969.1/151187.

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After the restriction of different halogenated fire suppressants by the Montreal Protocol, there is an urgent need to identify environmentally friendlier alternatives. In particular, several efforts have been conducted to find substitutes of Halon 1301 (CF_(3)Br) which was considered the best in its class, not only because of its superior extinguishing performance, but also due to its relatively low toxicity. Different options have been proposed over the last decade. However, no single compound has been found to meet all of the exigent criteria. Further progress in this research requires fun

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50

Li, Chiahsien, and 李佳憲. "Simulation of the Formation Characteristics for Mercury and Halogenated Emerging Compounds in Fly Ashes by Using a Laboratory System." Thesis, 2011. http://ndltd.ncl.edu.tw/handle/91104190885216080787.

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碩士<br>國立屏東科技大學<br>環境工程與科學系所<br>99<br>Combustion of domestic products containing mercury and brominated flame retardants (BFRs) may lead to concurrent emission of mercury and brominated emerging contaminants. Especially, these brominated compounds were adsorbed onto the surface of fly ash particles. Experiments were conducted adding the organic and inorganic bromide sources with bag house fly ashes in a packed bed reactor under real flue gas conditions to simulate the filter cake zone. The results indicated that adding pentabromophenol into the fly ash has significantly enhancement for mercury

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