Academic literature on the topic 'Halogenatio Reactions'

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Journal articles on the topic "Halogenatio Reactions"

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Santos, Ricardo, Diana Pinto, Clara Magalhães, and Artur Silva. "Halogenated Flavones and Isoflavones: A State-of-Art on their Synthesis." Current Organic Synthesis 17, no. 6 (2020): 415–25. http://dx.doi.org/10.2174/1570179417666200530213737.

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Background: Flavonoid is a family of compounds present in the everyday consumption plants and fruits, contributing to a balanced diet and beneficial health effects. Being a scaffold for new drugs and presenting a wide range of applicability in the treatment of illnesses give them also an impact in medicine. Among the several types of flavonoids, flavone and isoflavone derivatives can be highlighted due to their prevalence in nature and biological activities already established. The standard synthetic route to obtain both halogenated flavones and isoflavones is through the use of already haloge
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Dai, Bin, Ping Liu, Jing He, Yueting Wei, Yijiao Feng, and Chuntian Li. "Halogenations of 3-Aryl-1H-pyrazol-5-amines." Synthesis 54, no. 07 (2021): 1793–802. http://dx.doi.org/10.1055/a-1684-0308.

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AbstractA direct C–H halogenation of 3-aryl-1H-pyrazol-5-amines using N-halogenosuccinimides (NXS; X = Br, I, Cl) in dimethyl sulfoxide at room temperature has been developed. This transformation provides an effective metal-free protocol for the synthesis of novel 4-halogenated pyrazole derivatives with moderate to excellent yields. The method utilizes NXS reagents as cheap and safe halogenating reagents under simple and mild reaction conditions, it has broad substrate scope, and can be used for gram-scale synthesis. The utility of this procedure is established by further transformations of th
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Hodin, Fredrik, Hans Borén, Anders Grimvall, and Susanne Karlsson. "Formation of Chlorophenols and Related Compounds in Natural and Technical Chlorination Processes." Water Science and Technology 24, no. 3-4 (1991): 403–10. http://dx.doi.org/10.2166/wst.1991.0496.

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Surface water was halogenated by the addition of: (i) chloroperoxidase, hydrogen peroxide and chloride; (ii) hydrogen peroxide and chloride or bromide; (iii) hypochlorite. Analysis of adsorbable organic halogen (AOX), halogenated phenols and purgeable organic compounds showed that reactions (i) and (ii) produced almost the same halogenated compounds. It was also shown that active chlorine occurred as an intermedi-ate in reaction (i). Reaction (ii) implied a marked halogenation only after the addition of bromide, and this reaction was enhanced by a low pH. Existing evidence that 2,4,6-trichloro
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Weidlich, Tomáš. "The Influence of Copper on Halogenation/Dehalogenation Reactions of Aromatic Compounds and Its Role in the Destruction of Polyhalogenated Aromatic Contaminants." Catalysts 11, no. 3 (2021): 378. http://dx.doi.org/10.3390/catal11030378.

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The effect of copper and its compounds on halogenation and dehalogenation of aromatic compounds will be discussed in the proposed article. Cu oxidized to appropriate halides is an effective halogenation catalyst not only for the synthesis of halogenated benzenes or their derivatives as desired organic fine chemicals, but is also an effective catalyst for the undesirable formation of thermodynamically stable and very toxic polychlorinated and polybrominated aromatic compounds such as polychlorinated biphenyls, dibenzo-p-dioxins and dibenzofurans accompanied incineration of waste contaminated wi
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Moqadam, Samira, and Mehdi Salami-Kalajahi. "Halogenated sunflower oil as a precursor for synthesis of polysulfide polymer." e-Polymers 16, no. 1 (2016): 33–39. http://dx.doi.org/10.1515/epoly-2015-0152.

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AbstractPolysulfide polymers usually are prepared by the reaction of different dihalide compounds with disodium polysulfides. In this field, dihalides are expensive and produced from halogenation of organic compounds by different methods with harsh conditions. To overcome this problem, in this work, sunflower oil as polyunsaturated oil was used as precursor to produce polyhalide compound. In this field, double bonds of oil were applied as functional groups to halogenate the sunflower via benzoyl peroxide-catalyzed reaction with hydrochloric acid. Also, Na2S3 was synthesized via the reaction be
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Nishikawa, Takuro, Emiko Miyahara, Masahisa Horiuchi, et al. "Myeloperoxidase-Derived Halogenative Stress, a Possible Cause of Benzene Leukemogenesis." Blood 118, no. 21 (2011): 4404. http://dx.doi.org/10.1182/blood.v118.21.4404.4404.

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Abstract Abstract 4404 Background: Benzene, widely used in the chemical industry, is known to be myelotoxic, and to cause acute myeloid leukemia in humans. Although the mechanism has not been elucidated, benzene toxicity is considered to occur only after metabolic activation. Myeloperoxidase (MPO) is synthesized and secreted by myeloid cells catalyzes the formation of hypochlorous acid (HOCl), a powerful oxidant derived from chloride ions and hydrogen peroxide (H2O2). HOCl plays key roles in host defense by oxidizing the cellular constituents of invading pathogens. At the same time, HOCl is al
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van Pee, Karl-Heinz. "Halogenating Enzymes for Selective Halogenation Reactions." Current Organic Chemistry 16, no. 21 (2012): 2583–97. http://dx.doi.org/10.2174/138527212804004607.

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Cantillo, David, and C. Oliver Kappe. "Halogenation of organic compounds using continuous flow and microreactor technology." Reaction Chemistry & Engineering 2, no. 1 (2017): 7–19. http://dx.doi.org/10.1039/c6re00186f.

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Walter, Antje, Lorenzo Caputi, Sarah O’Connor, Karl-Heinz van Pée, and Jutta Ludwig-Müller. "Chlorinated Auxins—How Does Arabidopsis Thaliana Deal with Them?" International Journal of Molecular Sciences 21, no. 7 (2020): 2567. http://dx.doi.org/10.3390/ijms21072567.

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Plant hormones have various functions in plants and play crucial roles in all developmental and differentiation stages. Auxins constitute one of the most important groups with the major representative indole-3-acetic acid (IAA). A halogenated derivate of IAA, 4-chloro-indole-3-acetic acid (4-Cl-IAA), has previously been identified in Pisum sativum and other legumes. While the enzymes responsible for the halogenation of compounds in bacteria and fungi are well studied, the metabolic pathways leading to the production of 4-Cl-IAA in plants, especially the halogenating reaction, are still unknown
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Morimoto, Koji, Toshifumi Dohi, and Yasuyuki Kita. "Metal-free Oxidative Cross-Coupling Reaction of Aromatic Compounds Containing Heteroatoms." Synlett 28, no. 14 (2017): 1680–94. http://dx.doi.org/10.1055/s-0036-1588455.

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The biaryl unit containing a heteroatom is a key structure in a large number of natural products and π-conjugated organic systems. The cross-couplings can provide powerful methods for the construction of biaryls and heterobiaryls; thus the development of a new coupling method has been intensively studied by synthetic chemists. Therefore, the oxidative biaryl coupling reaction of arenes containing a heteroatom is a significantly attractive, convenient, and straightforward route to the synthesis of biaryls due to its operational simplicity avoiding the preparation of the corresponding halogenate
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Dissertations / Theses on the topic "Halogenatio Reactions"

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Benmansour, Hadjar. "Palladium catalysed reactions of halogenated heterocycles." Thesis, Durham University, 2001. http://etheses.dur.ac.uk/4948/.

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1- The synthesis of unusually substituted halo-fluoroheterocycles has been achieved. 2,4,6-Tribromo-3,5-difluoropyridine and 4-bromo-2,3,5,6-tetrafluoropyridine were prepared from pentafluoropyridine, aluminium bromide and hydrogen bromide Reactions with lithium halides allowed the preparation of 4-iodo-2,3,5,6- tetrafluoropyridine, 4-iodo-2,6-dibromo-3,5-difluoropyridine, 4-iodo-2,3,5,6- tetrafluoropyridine and 4-chloro-2,6-dibromo-3,5-difluoropyridine.2- Reactions of 2,4,6-tribromo-3, 5-difluoropyridine with nucleophiles showed that selective substitution at the C-F centre can be achieved us
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Mashino, Michio. "Photoinduced Chemical Reaction of Halogenated Hydrocarbons." 京都大学 (Kyoto University), 2004. http://hdl.handle.net/2433/147629.

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Palau, Lluch Gerard. "alpha,beta-difunctionalization of alpha,beta-unsaturated carbonyl compounds through borylation reaction." Doctoral thesis, Universitat Rovira i Virgili, 2015. http://hdl.handle.net/10803/311620.

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Aquesta tesi presenta resultats referits a noves metodologies aplicades cap a la obtenció de productes alfa-funcionalitzats i beta-borilats, que no tenen precedents en la bibliografia, a partir de cetones alfa,beta-insaturatdes. Les funcionalitzacions estudiades han sigut utilitzant fluor, per obtenir alfa-fluoro beta-boryl cetones; halogens, per obtenir alfa-halo beta-boryl cetones (sent els halogens clor i brom); i finalment difuncionalitzar cetones alfa,beta-insaturades per obtenir alfa-aryl beta-boryl cetones, que tal i com es reporta a la tesi, han sigut els intermedis cap a la sintesi de
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Yeung, Chi-shun, and 楊智淳. "The experimental and AB initio studies of the photolysis of selected tribromo-compounds and the water assisted dehalogenation reactions of selected isotribromo-compounds." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2014. http://hdl.handle.net/10722/206479.

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The photochemistry of several tribromo-compounds, R−CBr3 (R = CH2OH, CH2OC(O)CF3, COOH) have been studied by utilizing nanosecond transient absorption (ns-TA) and femtosecond transient absorption spectroscopy. Femtosecond transient absorption experiments showed that isomer species R−CBr2−Br were formed after excitation of R−CBr3 within several picoseconds. The absorption band of the isomers R−CBr2−Br showed a strong solvent dependence upon changing the solvent from cyclohexane to acetonitrile. The absorption wavelength of the proposed isomer intermediates and the spectral shift in cyclohexane
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Minton, Mary Amanda. "Reactions of Halogenated Ethylenes on the alpha-Cr2O3 (1012) Surface." Diss., Virginia Tech, 2006. http://hdl.handle.net/10919/29014.

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The thermally induced reaction of halogenated ethylenes on the α-Cr<sub>2</sub>O<sub>3</sub> (10 2) single crystal surface results in the formation of gas phase hydrocarbons including acetylene, ethylene, butadiene, and dihydrogen, and deposition of surface chlorine adatoms. No surface carbon or combustion products are observed in any reactions indicating no thermally induced C-C bond cleavage occurs and surface lattice oxygen is not incorporated into surface intermediates. Thermal desorption spectroscopy indicates that in all halogenated ethylene reactions acetylene is the major product, r
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Huang, Jinqing, and 黃普卿. "A study of the reaction mechanisms and reactive intermediates involved in halogenated compounds : trichloroethylene oxide, halogenated benzophenones, and halogenated quinoline-based phototriggers." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2014. http://hdl.handle.net/10722/208036.

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UV/Vis absorption spectroscopy (UV/Vis), femtosecond transient absorption spectroscopy (fs-TA), nanosecond transient absorption spectroscopy (ns-TA), and nanosecond time-resolved resonance Raman spectroscopy (ns-TR3), as well as density functional theory (DFT) computations were employed to study the mechanisms and the intermediates in reactions of selected halogenated compounds, including trichloroethylene oxide (TCE oxide), halogenated benzophenones (4-FBP, 4-ClBP, 4-BrBP, 3-FBP, 33’-DFBP, 3-ClBP, 3-BrBP, 2-FBP, 2-ClBP, and 2-BrBP), and halogenated quinoline-based phototriggers (BHQ-OPh and B
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Vipond, Alison. "Laboratory studies of reactions of some halogenated species in the atmosphere." Thesis, University of Oxford, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.301791.

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Guan, Xiangguo. "The photochemistry of polyhalomethanes in water and the water-catalyzed dehalogenation reactions of selected isopolyhalomethanes, halogenated methanols and halogenated formaldehydes." Click to view the E-thesis via HKUTO, 2006. http://sunzi.lib.hku.hk/hkuto/record/B38718960.

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Guan, Xiangguo, and 官向國. "The photochemistry of polyhalomethanes in water and the water-catalyzed dehalogenation reactions of selected isopolyhalomethanes,halogenated methanols and halogenated formaldehydes." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2006. http://hub.hku.hk/bib/B38718960.

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Foley, Loraine Johanna. "Photochemically induced reactions between ozone and halogenated species : a matrix isolation study." Thesis, University College London (University of London), 2001. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.369260.

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Books on the topic "Halogenatio Reactions"

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Timonen, Raimo. Kinetics of the reactions of some polyatomic free radicals with Cl₂ and Br₂, and reactions of formyl radicals with O₂, NO₂, Cl₂, Br₂, and H atoms. Suomalainen Tiedeakatemia, 1988.

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Wolfe, N. Lee. Transformations of halogenated hydrocarbons: Hydrolysis and redox processes. U.S. Environmental Protection Agency, Environmental Research Laboratory, [1990], 1990.

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Wolfe, N. Lee. Transformations of halogenated hydrocarbons: Hydrolysis and redox processes. U.S. Environmental Protection Agency, Environmental Research Laboratory, [1990], 1990.

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Peverall, Robert. Negative ion and electron attachment reactions with a variety of halogenated compounds. University of Birmingham, 1995.

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Löfås, Stefan. Mechanistic and synthetic investigations of novel halogenation reactions of amidines and enamines with tetrahalomethanes. Uppsala University?, 1985.

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Blight, E. John. A study of the reactions of some halogenated ethanes on silica-supported copper. Brunel University, 1986.

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Carr, Sinéad. Kinetics and mechanisms of the reactions of chlorine atoms and hydroxyl radicals with a series of halogenated ketones and carboxylic acids. University College Dublin, 1996.

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Heine, Christopher L. Malignant Hyperthermia. Edited by Matthew D. McEvoy and Cory M. Furse. Oxford University Press, 2017. http://dx.doi.org/10.1093/med/9780190226459.003.0025.

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In this chapter we discuss the pathophysiology of malignant hyperthermia, identify those who are known to be susceptible to MH, delineate how best to prepare the operating for those patients, and provide step by step treatment recommendations for patients that develop MH. Malignant hyperthermia (MH) is a pharmacogenetic disease. When susceptible individuals are exposed to a triggering agent, a hypermetabolic response develops. Succinylcholine and halogenated, inhaled anesthetics are triggers of MH. The MH reaction is initiated by a rapid influx of calcium ions into the myoplasm that triggers u
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Book chapters on the topic "Halogenatio Reactions"

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Clark, J. H. "By Halogenation." In Inorganic Reactions and Methods. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470145180.ch42.

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Mews, R. "By Halogenation with Metal Halides." In Inorganic Reactions and Methods. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470145173.ch107.

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Mews, R. "By Halogenation with Nonmetal Halides." In Inorganic Reactions and Methods. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470145173.ch110.

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Mews, R. "From Halogenation by Hydrogen Halides." In Inorganic Reactions and Methods. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470145173.ch46.

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Mews, R. "From Halogenation by Oxidizing Halides." In Inorganic Reactions and Methods. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470145173.ch47.

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Mews, R. "From Halogenation by Organic Halides." In Inorganic Reactions and Methods. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470145173.ch51.

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Page, E. M. "By Halogenation by Aluminum Halides." In Inorganic Reactions and Methods. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470145180.ch121.

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Page, E. M., and D. A. Rice. "Halogenation of Substituted Metal Carbonyls." In Inorganic Reactions and Methods. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470145180.ch162.

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James, B. D. "By Halogenation of the Elements." In Inorganic Reactions and Methods. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470145180.ch2.

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Edwards, D. A. "By Halogenation of Metal Oxides." In Inorganic Reactions and Methods. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470145180.ch66.

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Conference papers on the topic "Halogenatio Reactions"

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Cheng, L., R. C. May, and K. M. Given. "A New Environmentally-Preferred Copper Corrosion Inhibitor." In CORROSION 1999. NACE International, 1999. https://doi.org/10.5006/c1999-99101.

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Abstract Copper and its alloys have excellent heat transfer properties and are widely used in industrial cooling water systems. A corrosion inhibitor, however, is needed to prevent equipment failures and to reduce the discharge of toxic copper compounds into the environment. Although azoles such as benzotriazole and tolyltriazole have been used to protect copper alloys from corrosion, they react with oxidizing halogens which are commonly used to control microbiological activity. Their reaction with chlorine, for example, produces species that are not protective to copper. The inhibitor films f
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Kao, W., J. P. Singh, F. Y. Yueh та R. L. Cook. "Study of the High Temperature Multiplex HCℓ CARS Spectrum". У Laser Applications to Chemical Analysis. Optica Publishing Group, 1992. http://dx.doi.org/10.1364/laca.1992.wc5.

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Coherent Anti-Stokes Raman Spectroscopy (CARS) is a laser based advanced combustion diagnostic technique and is being used to measure the temperature and major species concentration in a turbulent, harsh, high luminescence and reactive combustion environment.1 Recently, it has also been applied to a Coal Fired Flow Facility (CFFF), which is a unique practical combustion environment.2 Only a few CARS applications to chemical reaction have been reported. One of the important chemical reactions is a chlorination reaction. CH4 + Cℓ2 → CH3Cℓ + HCℓ. This is being used to manufacture the halogenated
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"Convenient and Efficient Suzuki Miyaura Coupling Reactions of Meso-Halogenated BODIPYs." In Chemical technology and engineering. Lviv Polytechnic National University, 2021. http://dx.doi.org/10.23939/cte2021.01.184.

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Aggour, Y. A., A. S. Al-Shihri, and M. R. Bazzt. "Recycling of vulcanized waste rubber through halogenations and amination chemical reactions." In SUSTAINABLE DEVELOPMENT 2009. WIT Press, 2009. http://dx.doi.org/10.2495/sdp090822.

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Rothschild, M., J. H. C. Sedlacek, and D. J. Ehrlich. "Laser Photochemical Etching of Molybdenum and Tungsten Thin Films by Surface Halogenation*." In Microphysics of Surfaces, Beams, and Adsorbates. Optica Publishing Group, 1987. http://dx.doi.org/10.1364/msba.1987.mb4.

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Laser direct writing techniques, employing rapidly scanned microchemical deposition and etching reactions, are of importance for advanced nonlithographic fabrication of microelectronics. One class of applications employs these techniques for fine-line in situ alteration of conducting films as a last step in fabrication. Of particular importance for these applications is laser-induced patterning of Mo and W, which are becoming widely used materials for metallization of both Si and GaAs microelectronic devices.
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Wu, Yiting, Weitong Xiao, Jingyang Chen, and Weiling Luan. "BODIPY as a Photosensitizer for Photodynamic Therapy: Mechanisms, Functionalization, and Future Prospects." In 6th International Conference on Structural Health Monitoring and Integrity Management, 8 - 10 November 2024, Zhengzhou. NDT.net, 2025. https://doi.org/10.58286/30976.

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Photodynamic therapy (PDT) has the advantages of strong targeting, few side effects, and little damage to normal tissues, which is considered as a high-quality new non-invasive treatment for cancer treatment. Photosensitizer (PSs), molecular oxygen and light are the three main components of PDT. Boron-dipyrromethene (BODIPY) is a widely used organic fluorescent dye, and its core structure is composed of a central boron atom (B) and two pyrrole rings connected by a methylene bridge. The eight active sites on the parent nucleus allow for a variety of functionalization modifications: positions 2,
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Salama, Tarek, та Saad Elmorsy. "Silicon Assisted Halogenation I: A Convenient Synthesis of β-chloroketones via Reaction of α,β-unsaturated ketones with Tetrachlorosilane-Phenol". У The 13th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2009. http://dx.doi.org/10.3390/ecsoc-13-00181.

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Lindvold, L. R. "Dyed gelatin film as a storage material for volume phase holograms." In OSA Annual Meeting. Optica Publishing Group, 1991. http://dx.doi.org/10.1364/oam.1991.tuh5.

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Dye-sensitized gelatin is a common recording material for volume holograms. The dye acts as a spectral sensitizer in light-sensitive materials such as silver halide, dichromated gelatin, and photopolymers, mostly used as volume phase recording media. The dye, however, can be used in a pure gelatin matrix also for real-time experiments, e.g., degenerate four-wave mixing facilitated by the cis-trans isomerization of the dye to record polarization-sensitive gratings. This paper describes some preliminary results concerning an observed photoinduced crosslinking effect of a dyed gelatin. The system
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Pranszke, B., P. Kierzkowski, A. Kowalski, and M. Menzinger. "Electronic energy partitioning in the reactions of metastable Mg*(3P) and Ca*(3P,1D) atoms with halogenated methanes CX 4 (X = F, Cl, Br)." In Jurata, Poland, edited by Jerzy Kwela, Ryszard Drozdowski, and Tomasz J. Wasowicz. SPIE, 2005. http://dx.doi.org/10.1117/12.629490.

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Reports on the topic "Halogenatio Reactions"

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Linteris, Gregory T., and Jeffrey A. Manion. xothermic Reaction of Halogenated Hydrocarbons: WORKSHOP PROCEEDINGS. National Institute of Standards and Technology, 2015. http://dx.doi.org/10.6028/nist.tn.1871.

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Lunsford, J. H. The Adsorption and Reactions of Halogenated Volatile Organic Compounds (VOCs) on Metal Oxides - Final Report. Office of Scientific and Technical Information (OSTI), 2000. http://dx.doi.org/10.2172/775042.

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Lunsford, J., D. W. Goodman, and J. F. Haw. The adsorption and reaction of halogenated volatile organic compounds (VOC's) on metal oxides. 1998 annual progress report. Office of Scientific and Technical Information (OSTI), 1998. http://dx.doi.org/10.2172/13641.

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Lunsford, J. H., J. F. Haw, and D. W. Goodman. The adsorption and reaction of halogenated volatile organic compounds (VOC's) on metal oxides. Annual progress report, September 1996--October 1997. Office of Scientific and Technical Information (OSTI), 1997. http://dx.doi.org/10.2172/13640.

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