Academic literature on the topic 'Halogens. Halides'

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Journal articles on the topic "Halogens. Halides"

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López-Duplá, Esperanza, Peter G. Jones, and Fabiola Vancea. "Secondary Bonding Interactionsi in Some Di- and Trihaloanilinium Halides." Zeitschrift für Naturforschung B 58, no. 1 (2003): 191–200. http://dx.doi.org/10.1515/znb-2003-0129.

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Abstract Six solvent-free structures of di- and trihaloanilinium halides are presented. All involve clearly defined hydrophilic regions built up from classical hydrogen bonding systems. The 2,4-dibromo-, 2,6- dichloro-, 2,4,6-trichloro- and 2,4,6-tribromoanilinium derivatives form ribbon structures involving annelated R24 (8) rings with NH2 donors (two hydrogens from the positively charged NH3 groups) and halide acceptors. The 2,5-dibromo- and 2,4,5-trichloro derivatives form layers with two types of ring, R24 (8) and R48 (16). All structures also involve other secondary interactions (C-H. . .
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Fang, Hong, and Puru Jena. "Super-ion inspired colorful hybrid perovskite solar cells." Journal of Materials Chemistry A 4, no. 13 (2016): 4728–37. http://dx.doi.org/10.1039/c5ta09646d.

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Hybrid perovskites viewed as super alkali halides with alkali and halogen ions replaced by super alkalis and super halogens, respectively. The basic properties of these materials are determined by the bonding ionicity and effective ionic radii of the super-ions. New colorful hybrid perovskites can be invented with super-ions as the building block.
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Skitchenko, Rostislav K., Dmitrii Usoltsev, Mayya Uspenskaya, Andrey V. Kajava, and Albert Guskov. "Census of halide-binding sites in protein structures." Bioinformatics 36, no. 10 (2020): 3064–71. http://dx.doi.org/10.1093/bioinformatics/btaa079.

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Abstract Motivation Halides are negatively charged ions of halogens, forming fluorides (F−), chlorides (Cl−), bromides (Br−) and iodides (I−). These anions are quite reactive and interact both specifically and non-specifically with proteins. Despite their ubiquitous presence and important roles in protein function, little is known about the preferences of halides binding to proteins. To address this problem, we performed the analysis of halide–protein interactions, based on the entries in the Protein Data Bank. Results We have compiled a pipeline for the quick analysis of halide-binding sites
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Poynder, Tiffany B., Dharmeshkumar P. Savaliya, Andrew Molino, David J. D. Wilson, and Jason L. Dutton. "Elimination of Ethene from 1,2-Diiodoethane Induced by N-Heterocyclic Carbene Halogen Bonding." Australian Journal of Chemistry 72, no. 8 (2019): 614. http://dx.doi.org/10.1071/ch19237.

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The attempted synthesis of N-heterocyclic carbene (NHC)-stabilised dicarbon (C2) fragments via nucleophilic substitution at 1,2-diiodoethane is reported. Rather than the expected SN2 pathway, clean elimination of ethene and formation of an iodoimidazolium cation was observed. The resistance towards nucleophilic substitution piqued interest, and subsequent investigation determined NHC-halogen bonding as the source. This is in contrast to reactions between NHCs and other alkyl halides, where substitution or elimination pathways are reported. A detailed theoretical study between these cases highl
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Saadat, Kayvan, and Hossein Tavakol. "An exceptional functionalization of doped fullerene observed via theoretical studies on the interactions of sulfur-doped fullerenes with halogens and halides." RSC Advances 5, no. 68 (2015): 55227–37. http://dx.doi.org/10.1039/c5ra08141f.

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Malkanduev, Yusuf A., Madina B. Begieva, Aneta A. Kokoeva, Muslim A. Mikitaev, Аblulakhat T. Dzhalilov, and Madzera K. Vindizheva. "Synthesis and Properties of Polymers Based on N-Vinyl-Pyrrolidone and Halogen-Containing Compounds of Acrylic Acids." Key Engineering Materials 869 (October 2020): 303–7. http://dx.doi.org/10.4028/www.scientific.net/kem.869.303.

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The paper presents the results of the copolymerization of α-halogens of acrylic acid and N-vinylpyrrolidone in the presence of a radical initiator. The copolymerization equations are presented and activity factors are calculated. IR spectra of the obtained copolymers confirm the amination reaction. The synthesized aminated polymers form intramuscular compounds with divalent metal halides at room temperature. The kinetics of the copolymerization reaction of these systems shows that the presence of a reactive halogen atom in the structure of the copolymer has a great influence on the formation a
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Klapötke, Thomas M., Burkhard Krumm, and Kurt Polborn. "The Reactivity of CF3C6F4OC6F4Li towards Halogens and Cyanogen Halides." Zeitschrift für anorganische und allgemeine Chemie 626, no. 10 (2000): 2047–52. http://dx.doi.org/10.1002/1521-3749(200010)626:10<2047::aid-zaac2047>3.0.co;2-h.

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ALTINTAS, BAHADIR. "STRUCTURAL AND ELECTRONIC PROPERTIES OF α-TiNX (X:F, Cl, Br, I): AN AB INITIO STUDY". Journal of Theoretical and Computational Chemistry 10, № 01 (2011): 65–74. http://dx.doi.org/10.1142/s0219633611006311.

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The electronic and lattice properties of α-TiNX (X:F, Cl, Br, I) were investigated from first principles. Ab initio calculations for geometry optimization, electronic band structure and zone-center phonon calculations have been carried out by using plane-wave pseudopotential method which is not examined before. From the electronic structure calculation, band gaps have been found as 1.23 eV, 0.955 eV, 0.897 eV for TiNF , TiNCl , TiNBr while there is no band gap for TiNI . This result can separate TiNI from other metal nitride halides which are semiconductor. Band structure calculations showed t
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Nienhuis, Emily, Muad Saleh, and John McCloy. "Structural Characterization of Ternary Salt Melts for Low Activity Waste Applications." MRS Advances 4, no. 17-18 (2019): 1045–56. http://dx.doi.org/10.1557/adv.2019.136.

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ABSTRACTReactions of alkali salts (nitrates, sulfates, carbonates, halides, borates) play a key role in the low temperature feed conversion occurring at the cold cap during processing of Hanford Low Activity Waste (LAW) glass melters. An alkali salt phase can sometimes form, and preferentially incorporate radionuclides of Cs, Cl, I, and Tc. During melting of the slurry feed, some of the feed components sequentially break down with increasing temperature to form gases (i.e., nitrates ➔ NOx, carbonates ➔ CO2, and boric acid ➔ H2O) or partially volatilize (halides). Sulfate, however, tends not to
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Detty, Michael R., Feng Zhou, and Alan E. Friedman. "Positive Halogens from Halides and Hydrogen Peroxide with Organotellurium Catalysts." Journal of the American Chemical Society 118, no. 2 (1996): 313–18. http://dx.doi.org/10.1021/ja953187g.

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Dissertations / Theses on the topic "Halogens. Halides"

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Awwadi, Firas Fandi. "A crystallographic and theoretical study of halogen---halogen and halogen---halide synthons." Online access for everyone, 2005. http://www.dissertations.wsu.edu/Dissertations/Summer2005/F%5FAwwadi%5F072705.pdf.

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Jackman, R. B. "Interfacial chemistry of metal carbonyls, metal halides and halogens : Surface studies with application to photon and electron enhanced processes on semiconductors." Thesis, University of Southampton, 1986. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.374568.

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Meerbach, Christian, Cong Wu, Steven C. Erwin, Zhiya Dang, Anatol Prudnikau, and Vladimir Lesnyak. "Halide-Assisted Synthesis of Cadmium Chalcogenide Nanoplatelets." American Chemical Association, 2019. https://tud.qucosa.de/id/qucosa%3A74323.

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Atomically flat colloidal semiconductor CdSe nanoplatelets (NPLs) with precisely controlled thickness possess a range of unique optoelectronic properties. Here, we study the growth of CdSe, CdTe, and CdS NPLs with the aim of synthesizing thicker NPLs in order to extend their optical activity further into the lower energy/larger wavelength range. We employ cadmium halides, which lead to faster reaction kinetics as confirmed by control experiments with cadmium hydroxide as a Cd-precursor. Addition of halides in all cases led to the formation of thicker NPL species, as compared with the correspon
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Torrey, Jason Robert. "Antimicrobial Properties Of Metal And Metal-Halide Nanoparticles And Their Potential Applications." Diss., The University of Arizona, 2014. http://hdl.handle.net/10150/338682.

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Heavy metals have been known to possess antimicrobial properties against bacterial, fungal, and viral pathogens. Silver and copper in particular have been used for millennia to control bacterial and fungal contamination. Metal nanoparticles (aggregations of metal atoms 1-200 nm in size) have recently become the subject of intensive study for their increased antimicrobial properties due to their increased surface area and localized release of metal ions when attached to pathogens. In the current studies, metal and metalhalide nanoparticles including silver (Ag), silver bromide (AgBr), silver io
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Attrell, Robert J. "A Solid-State 35Cl and 81Br NMR and Computational Study of Chlorine and Bromine Electric Field Gradient and Chemical Shift Tensors in Haloanilinium Halides." Thesis, Université d'Ottawa / University of Ottawa, 2012. http://hdl.handle.net/10393/20546.

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The results of a systematic 35Cl, 81Br, and 127I SSNMR spectroscopic study of a series of halogen-substituted anilinium halide salts are presented. Solid-state NMR of these nuclides, bromine-/81 and iodine-127 in particular, is not well established. Twenty-one compounds thought to exhibit halogen bonding were prepared based on modified literature procedures, and two crystal structures were solved. Experiments show that collection of SSNMR spectra of the anions is feasible, though ultrahigh magnetic fields (21.1 T) and variable offset data acquisition were found to be essential. Electric fi
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Ratcliffe, Shane. "Cocrystals of urea, complex chemistry of thioureas with group 15 halides and halogen adducts of tertiary phosphine selenides." Thesis, University of Manchester, 2010. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.706079.

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Balkenhohl, Moritz [Verfasser], and Paul [Akademischer Betreuer] Knochel. "Metalation and amination of N-heterocycles and the halogen/zinc exchange of aryl halides / Moritz Balkenhohl ; Betreuer: Paul Knochel." München : Universitätsbibliothek der Ludwig-Maximilians-Universität, 2019. http://d-nb.info/1211957128/34.

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Machover, Sarah B. "Understanding the Solvent-free Nucleophilic Substitution Reaction Performed in the High Speed Ball Mill (HSBM): Reactions of Secondary Alkyl Halides and Alkali Metal-Halogen Salts." University of Cincinnati / OhioLINK, 2011. http://rave.ohiolink.edu/etdc/view?acc_num=ucin1307043848.

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Claros, Casielles Miguel. "Development of Visible Light Photoredox Methodologies towards the Activation of Carbon-Halogen Bonds." Doctoral thesis, Universitat Rovira i Virgili, 2020. http://hdl.handle.net/10803/669435.

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Metodologies fotocatalítiques sota irradiació de llum visible han estat desenvolupades amb diversos substrats disponibles al mercat com ara els àcids carboxílics, trifluoroboratos alquílics de potassi, silicats alquílics d'amoni o èsters activats entre d'altres. Sota irradiació de llum, aquests precursors s'activen mitjançant processos de transferència d'un sol electró amb catalitzadors fotoexcitables (PC). Entre ells, els halurs orgànics són socis d'acoblament convenients en la fotocatàlisi, ja que experimenten una escissió de l'enllaç C-halogen catalitzada per diversos PC en presència d'un d
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Davis, Anthony Alan. "The structure and chemistry of InSb(001) and InP(001) : clean surface structure, halogen adsorption and layered halide growth by rotational epitaxy." Thesis, University of Nottingham, 1997. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.243492.

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Books on the topic "Halogens. Halides"

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Biochemistry of the elemental halogens and inorganic halides. Plenum Press, 1991.

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Kirk, Kenneth L. Biochemistry of the Elemental Halogens and Inorganic Halides. Springer US, 1991. http://dx.doi.org/10.1007/978-1-4684-5817-6.

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Wilson, John W. Analysis of the physical atomic forces between noble gas atoms, alkali ions, and halogen ions. National Aeronautics and Space Administration, Scientific and Technical Information Branch, 1986.

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Wilson, John W. Analysis of the physical atomic forces between noble gas atoms, alkali ions, and halogen ions. Langley Research Center, 1986.

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Neidig, H. A., and M. L. Gillette. Establishing the Relative Reactivity of Halogens and Halide Ions. Chemical Education Resources, 1998.

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Susan, A. Ph D. Johnson. Halides, Oxyhalides and Salts of Halogen Complexes of Titanium, Zirconium, Hafnium, Vanadium, Niobium and Tantalum. Elsevier Science Pub Co, 1989.

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Jiri, Hála, Johnson Susan A, Clever H. Lawrence, Oshiba Takashi, and Salomon Mark, eds. Halides, oxyhalides and salts of halogen complexes of titanium, zirconium, hafnium, vanadium, niobium and tantalum. Pergamon, 1989.

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Book chapters on the topic "Halogens. Halides"

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Anderson, G. K. "Reactions of Halogens and Hydrogen Halides." In Inorganic Reactions and Methods. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470145296.ch223.

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Kirk, Kenneth L. "The Halogens: Discovery, Occurrence, and Biochemistry of the Free Elements." In Biochemistry of the Elemental Halogens and Inorganic Halides. Springer US, 1991. http://dx.doi.org/10.1007/978-1-4684-5817-6_1.

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Kirk, Kenneth L. "Biochemistry of Inorganic Fluoride." In Biochemistry of the Elemental Halogens and Inorganic Halides. Springer US, 1991. http://dx.doi.org/10.1007/978-1-4684-5817-6_2.

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Kirk, Kenneth L. "Biochemistry of Inorganic Chloride." In Biochemistry of the Elemental Halogens and Inorganic Halides. Springer US, 1991. http://dx.doi.org/10.1007/978-1-4684-5817-6_3.

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Kirk, Kenneth L. "Biochemistry of Inorganic Bromide." In Biochemistry of the Elemental Halogens and Inorganic Halides. Springer US, 1991. http://dx.doi.org/10.1007/978-1-4684-5817-6_4.

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Kirk, Kenneth L. "Biochemistry of Inorganic Iodide." In Biochemistry of the Elemental Halogens and Inorganic Halides. Springer US, 1991. http://dx.doi.org/10.1007/978-1-4684-5817-6_5.

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Kirk, Kenneth L. "Iodotyrosine, Iodothyronines, and Thyroid Function." In Biochemistry of the Elemental Halogens and Inorganic Halides. Springer US, 1991. http://dx.doi.org/10.1007/978-1-4684-5817-6_6.

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Kirk, Kenneth L. "Biohalogenation." In Biochemistry of the Elemental Halogens and Inorganic Halides. Springer US, 1991. http://dx.doi.org/10.1007/978-1-4684-5817-6_7.

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Kirk, Kenneth L. "Persistent Polyhalogenated Compounds: Biochemistry, Toxicology, Medical Applications, and Associated Environmental Issues." In Biochemistry of the Elemental Halogens and Inorganic Halides. Springer US, 1991. http://dx.doi.org/10.1007/978-1-4684-5817-6_8.

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Kirk, Kenneth L. "Metabolism of Halogenated Compounds—Biodehalogenation." In Biochemistry of the Elemental Halogens and Inorganic Halides. Springer US, 1991. http://dx.doi.org/10.1007/978-1-4684-5817-6_9.

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Conference papers on the topic "Halogens. Halides"

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Peebles, Rebecca, Sean Peebles, Rachel Dorris, Cori Christenholz, and Ashley Anderton. "INFLUENCE OF HALOGEN VARIATION ON STRUCTURE AND INTERACTIONS IN VINYL HALIDE (H2C=CHX)…CO2 (X = F, Cl, Br) COMPLEXES." In 71st International Symposium on Molecular Spectroscopy. University of Illinois at Urbana-Champaign, 2016. http://dx.doi.org/10.15278/isms.2016.wc03.

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