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Relevant bibliographies by topics / Heck reaction

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Academic literature on the topic 'Heck reaction'

Author: Grafiati

Published: 4 June 2021

Last updated: 26 July 2025

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Journal articles on the topic "Heck reaction"

1

Kurandina, Daria, Padon Chuentragool, and Vladimir Gevorgyan. "Transition-Metal-Catalyzed Alkyl Heck-Type Reactions." Synthesis 51, no. 05 (2019): 985–1005. http://dx.doi.org/10.1055/s-0037-1611659.

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The Heck reaction is one of the most reliable and useful strategies for the construction of C–C bonds in organic synthesis. However, in contrast to the well-established aryl Heck reaction, the analogous reaction employing alkyl electrophiles is much less developed. Significant progress in this area was recently achieved by merging radical-mediated and transition-metal-catalyzed approaches. This review summarizes the advances in alkyl Heck-type reactions from its discovery early in the 1970s up until the end of 2018.1 Introduction2 Pd-Catalyzed Heck-Type Reactions2.1 Benzylic Electrophiles2.2 α

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Newman, Stephen, and Jaya Vandavasi. "A High-Throughput Approach to Discovery: Heck-Type Reactivity with Aldehydes." Synlett 29, no. 16 (2018): 2081–86. http://dx.doi.org/10.1055/s-0037-1610161.

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The classical Heck reaction is among the most powerful methods available for the construction of C–C bonds. Modification of this transformation to utilize diverse organohalide coupling partners has resulted in new reactions such as the silyl-Heck, aza-Heck, and boryl-Heck reactions. In contrast, modification of the olefin coupling partner is rare. For instance, use of the π-bond of an aldehyde instead of an alkene would provide ketones via a carbonyl-Heck process. This seemingly minor manipulation of the Heck reaction has proven surprisingly difficult to realize in practice. Through the use of

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3

Wall, Valerie M., Amihai Eisenstadt, David J. Ager, and Scott A. Laneman. "The Heck Reaction and Cinnamic Acid Synthesis by Heterogeneous Catalysis." Platinum Metals Review 43, no. 4 (1999): 138–45. http://dx.doi.org/10.1595/003214099x434138145.

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The Heck reaction for the construction of carbon-carbon bonds, using palladium catalysts, is one of the most valuable strategies in organic chemistry and appears frequently in the literature, usually as homogeneous catalysis. In this review the progress made to date with this reaction is examined, together with the most discussed aspects of the Heck reaction, including a description of its mechanism and the conditions required for success. Some limitations to the homogeneous reaction are mentioned with reasons for proceeding with heterogeneous catalysts, in particular with palladium/carbon. Ex

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Lee, Jin-Kyun, Rachel M. Williamson, Andrew B. Holmes, Edward J. Bush, and Ian F. McConvey. "A Study of the Heck Reaction in Non-Polar Hydrocarbon Solvents and in Supercritical Carbon Dioxide." Australian Journal of Chemistry 60, no. 8 (2007): 566. http://dx.doi.org/10.1071/ch07160.

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The effects of electronic and steric properties of phosphorus ligands on Heck reactions in supercritical CO2 and non-polar hydrocarbon solvents were studied. In Heck reactions between iodobenzene and butyl acrylate, higher yields were obtained with less electron-rich phosphine ligands. This trend was also observed with the electron-poor triphenyl phosphite. A range of sterically demanding phosphites were then investigated. Biphenyl-containing phosphites 8 and 13 were found to be highly effective. In the Heck reaction between the less-reactive bromobenzene and butyl acrylate, the bulky, electro

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Díaz-Ortiz, Ángel, Pilar Prieto, Abel de Cózar, Cristina Cebrián, Andrés Moreno, and Antonio de la Hoz. "Microwave-Controlled Preparation of Alkenyl-(1H)-1,2,4-triazoles: First Heck Reaction on a (1H)-1,2,4-Triazole Moiety." Australian Journal of Chemistry 62, no. 12 (2009): 1600. http://dx.doi.org/10.1071/ch09185.

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A new synthetic approach for the preparation of alkenyl-1,2,4-triazole derivatives based on microwave-induced C–C cross-coupling Heck reactions is described. To the best of our knowledge, this is the first application of the Heck reaction to a dihalogenated 1,2,4-triazole. This approach allows the introduction of a wide range of equivalent or different alkenyl substituents in the 5- and/or 3-positions, thus extending the possibilities for the preparation of these valuable derivatives. A similar microwave-induced synthetic procedure has also been applied to the Heck reaction of 4-vinyl-1,2,3-tr

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Shibasaki, Masakatsu, Erasmus M Vogl, and Takashi Ohshima. "Asymmetric Heck Reaction." Advanced Synthesis & Catalysis 346, no. 13-15 (2004): 1533–52. http://dx.doi.org/10.1002/adsc.200404203.

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Demidoff, Felipe, Fabrícia de Souza, and Chaquip Netto. "Synthesis of Stilbene-Quinone Hybrids through Heck Reactions in PEG-400." Synthesis 49, no. 23 (2017): 5217–23. http://dx.doi.org/10.1055/s-0036-1589095.

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Styrenes were coupled with 3-iodolawsone in PEG-400 at 90 °C, leading stereoselectively to (E)-stilbene-quinone hybrids through Heck reactions. The best reaction conditions were found to be the use of NaOH (3 equiv) and 10 mol% of palladium acetate at 90 °C for 15 minutes. The chemical yields of the Heck reactions using styrenes with electron-withdrawing groups (65–98%) were greater than styrenes bearing electron-donating groups (7–32%) on the aromatic ring. In particular, the chemical yields of Heck reactions involving nitrostyrenes were the best ones observed.

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Tietze, Lutz F., Lars P. Lücke, Felix Major, and Peter Müller. "Efficient Synthesis of an Enantiopure Thiasteroid by a Double Heck Reaction." Australian Journal of Chemistry 57, no. 7 (2004): 635. http://dx.doi.org/10.1071/ch04034.

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The thiaestrane 7 was synthesized by two sequential Heck reactions starting from the thiophene derivatives 8a–8c, which contain a (Z)-halogenovinyl group, and the enantiopure hydrindene 2a. The first intermolecular Pd-catalyzed reaction leads to 11a and 11b in a highly regio- and diastereoselective manner. A subsequent intramolecular Heck reaction catalyzed by the palladacycle 4 then gave the thiasteroid 7 with an unusual cis-junction of the rings B and C.

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de Vries, Johannes G. "The Heck reaction in the production of fine chemicals." Canadian Journal of Chemistry 79, no. 5-6 (2001): 1086–92. http://dx.doi.org/10.1139/v01-033.

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An overview is given of the use of the Heck reaction for the production of fine chemicals. Five commercial products have been identified that are produced on a scale in excess of 1 ton/year. The herbicide Prosulfuron(tm) is produced via a Matsuda reaction of 2-sulfonatobenzenediazonium on 3,3,3-trifluoropropene. The sunscreen agent 2-ethylhexyl p-methoxy-cinnamate has been produced on pilot scale using Pd/C as catalyst. Naproxen(tm) is produced via the Heck reaction of 2-bromo-6-methoxy-naphthalene on ethylene, followed by carbonylation of the product. Monomers for coatings are produced via a

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Srivastava, Vivek. "Synthesis and Characterization of Pd exchanged MMT Clay for Mizoroki-Heck Reaction." Open Chemistry 16, no. 1 (2018): 605–13. http://dx.doi.org/10.1515/chem-2018-0065.

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AbstractWe successfully synthesized Pd@MMT clay using a cation exchange process. We characterized all the synthesized Pd@MMT clays using sophisticated analytical techniques before testing them as a heterogeneous catalyst for the Mizoroki - Heck reaction (mono and double). The highest yield of the Mizoroki-Heck reaction product was recovered using thermally stable and highly reactive Pd@ MMT-1 clay catalyst in the functionalized ionic liquid reaction medium. We successfully isolated 2-aryl-vinyl phosphonates (mono-Mizoroki-Heck reaction product) and 2,2-diaryl-vinylphosphonates (double-Mizoroki

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Dissertations / Theses on the topic "Heck reaction"

1

McConville, Matthew. "New directions in the Heck reaction." Thesis, University of Liverpool, 2010. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.533986.

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Sellarajah, Shane. "Chiral additives in the asymmetric Heck reaction." Thesis, University of East Anglia, 2001. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.390653.

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McDermott, Michael Cory. "Asymmetric Heck reaction : conformational effects and enantioselectivity." Thesis, University of East Anglia, 2005. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.426670.

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Smith, Andrew. "The cationic Heck reaction : a computational study." Thesis, University of Warwick, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.369388.

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Bangar, P. G. "Visible light photocatalysis - a greener approach towards mizoroki-heck reaction & variables in mizoroki-heck reaction of mono & disubstituted olefins." Thesis(Ph.D.), CSIR-National Chemical Laboratory, Pune, 2018. http://dspace.ncl.res.in:8080/xmlui/handle/20.500.12252/4565.

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Nassar, Hardy Luma. "Tandem reactions using multi-task catalysts." Thesis, Bordeaux 1, 2011. http://www.theses.fr/2011BOR14317/document.

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Le développement d’une chimie propre et donc durable est un des challenges majeurs du 21ème siècle dans les pays industrialisés. Étant au cœur de nombreuses découvertes dans divers domaines scientifiques allant de la physique à la médecine, les sciences chimiques doivent jouer un rôle central pour résoudre un certain nombre de problèmes environnementaux auxquels nous devons faire face. Mon travail de thèse s’inscrit dans cette problématique par le développement de méthodologies de synthèse faisant intervenir plusieurs transformations dans le même réacteur. Nous avons notamment développé des sé

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Olofsson, Kristofer. "Regiocontrol in the Heck-reaction and fast fluorous chemistry." Doctoral thesis, Uppsala : Acta Universitatis Upsaliensis : Univ.-bibl. [distributör], 2001. http://publications.uu.se/theses/91-554-4883-6/.

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Gleasure, A. J. "Ruthenium and palladium catalysed cyclisation reactions." Thesis, Queen's University Belfast, 2002. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.246436.

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Lee, Jin Kyun. "Heck reaction and diaryl ether synthesis in supercritical carbon dioxide." Thesis, University of Cambridge, 2005. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.615277.

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Sumoreeah, Ravi Leckman. "Studies towards the total synthesis of galanthamine and the total synthesis of 2-Benzoyl-9-azabicyclo[4.2.1]non-2-ene : phenyl analogue of (#+-#)Anatoxin-a." Thesis, University of Sussex, 2002. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.289225.

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This thesisd escribess yntheticw ork carriedo ut on two separatep rojects. (i) Synthetics tudiest owardst he total synthesiso f galanthamine (ii) The total synthesis of 2-Benzoyl-9-azabicyclo[4.2.1 ]non-2-ene Galanthamine is an amaryllidaceae alkaloid processing a rigid tetracyclic structure with a fused dihydrobenzofuran onto a cyclohexenol and a bridging tertiary amine. 2-Benzoyl-9-azabicyclo[4.2.1]non-2-ene is an analogue of anatoxin-a, whereby the acetyl side chain has been substituted with a benzoyl group. Anatoxin-a itself possesses a 9-azabicyclo[4.2.1]nonane framework. Although structu

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Books on the topic "Heck reaction"

1

Oestreich, Martin, ed. The Mizoroki–Heck Reaction. John Wiley & Sons, Ltd, 2009. http://dx.doi.org/10.1002/9780470716076.

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Smith, Andrew. The cationic Heck reaction: A computational study. typescript, 2000.

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3

Wolfe, J. P. (James Philip), 1943- and Larhed Mats, eds. Science of synthesis: Cross coupling and Heck-type reactions. Georg Thieme Verlag KG, 2013.

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4

fakulteten, Uppsala universitet Farmaceutiska, and Uppsala universitet, eds. Regio-controlled and fast intermolecular heck reactions: Palladium-catalyzed coupling reactions with microwave heating. Acta Universitatis Upsaliensis, 1997.

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5

Oestreich, Martin. Mizoroki-Heck Reaction. Wiley & Sons, Incorporated, John, 2009.

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6

Oestreich, Martin. Mizoroki-Heck Reaction. Wiley & Sons, Limited, John, 2008.

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7

The Mizoroki-Heck reaction. Wiley, 2008.

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8

Catalyzed Mizoroki–Heck Reaction or C–H activation. MDPI, 2020. http://dx.doi.org/10.3390/books978-3-03928-139-8.

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9

Fang, Yuanqing. Palladium-catalysed Heck reaction and tandem cross coupling reactions for heterocycle synthesis. 2007.

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10

Fergus, Julie Anne. New reagents in asymmetric synthesis and studies on the Heck reaction. 1998.

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Book chapters on the topic "Heck reaction"

1

Li, Jie Jack. "Heck reaction." In Name Reactions. Springer Berlin Heidelberg, 2003. http://dx.doi.org/10.1007/978-3-662-05336-2_135.

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Li, Jie Jack. "Heck reaction." In Name Reactions. Springer International Publishing, 2014. http://dx.doi.org/10.1007/978-3-319-03979-4_129.

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Li, Jie Jack. "Heck reaction." In Name Reactions. Springer Berlin Heidelberg, 2002. http://dx.doi.org/10.1007/978-3-662-04835-1_126.

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Li, Jie Jack. "Heck reaction." In Name Reactions. Springer Berlin Heidelberg, 2009. http://dx.doi.org/10.1007/978-3-642-01053-8_121.

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Li, Jie Jack. "Heck Reaction." In Name Reactions. Springer International Publishing, 2021. http://dx.doi.org/10.1007/978-3-030-50865-4_64.

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Li, Jie Jack. "Heteroaryl Heck reaction." In Name Reactions. Springer Berlin Heidelberg, 2003. http://dx.doi.org/10.1007/978-3-662-05336-2_140.

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Gøgsig, Thomas Meyer. "Carbonylative Heck Reaction." In Springer Theses. Springer Berlin Heidelberg, 2012. http://dx.doi.org/10.1007/978-3-642-32099-6_7.

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Li, Jie Jack. "Heteroaryl Heck reaction." In Name Reactions. Springer Berlin Heidelberg, 2002. http://dx.doi.org/10.1007/978-3-662-04835-1_131.

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9

Geoghegan, Kimberly. "Regioselectivity in the Heck (Mizoroki-Heck) Reaction." In Selectivity in the Synthesis of Cyclic Sulfonamides. Springer International Publishing, 2014. http://dx.doi.org/10.1007/978-3-319-10338-9_2.

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10

Ozawa, Fumiyuki, Akihiko Kubo, and Tamio Hayashi. "Catalytic Asymmetric Heck Reaction." In ACS Symposium Series. American Chemical Society, 1993. http://dx.doi.org/10.1021/bk-1993-0517.ch006.

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Conference papers on the topic "Heck reaction"

1

Carmona, Rafaela C., and Carlos Roque D. Correia. "Asymmetric Arylation of Indenes via Heck-Matsuda Reaction." In 15th Brazilian Meeting on Organic Synthesis. Editora Edgard Blücher, 2013. http://dx.doi.org/10.5151/chempro-15bmos-bmos2013_201381992939.

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Santana, Victor, and Regina Buffon. "The Heck reaction applied to the synthesis of chlorambucil." In Congresso de Iniciação Científica UNICAMP. Universidade Estadual de Campinas, 2019. http://dx.doi.org/10.20396/revpibic2720192201.

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Schwalm, Cristiane S., Jailton Ferrari, and Carlos R. D. Correia. "Synthetic Studies Towards Arylpyrrole Derivatives via Heck- Matsuda Reaction." In 14th Brazilian Meeting on Organic Synthesis. Editora Edgard Blücher, 2013. http://dx.doi.org/10.5151/chempro-14bmos-r0019-1.

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Biajoli, André F. P., Francisco de Azambuja, and Carlos R. D. Correia. "Synthetic Studies Towards Combrestatin Analogues via Heck- Matsuda Reaction." In 14th Brazilian Meeting on Organic Synthesis. Editora Edgard Blücher, 2013. http://dx.doi.org/10.5151/chempro-14bmos-r0043-1.

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Silva, Allan Ribeiro da, Patrícia Prediger, and Carlos Roque Duarte Correia. "Construction of Diarylmethane Compounds. Synthesis of tolpropamine via Heck-Matsuda Reaction." In 15th Brazilian Meeting on Organic Synthesis. Editora Edgard Blücher, 2013. http://dx.doi.org/10.5151/chempro-15bmos-bmos2013_2013818131420.

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Sotomayor, Nuria, Ane Azcargorta, and Esther Lete. "Diastereoselective formation of tertiary stereocenters via Mizoroki-Heck reaction." In MOL2NET, International Conference on Multidisciplinary Sciences. MDPI, 2015. http://dx.doi.org/10.3390/mol2net-1-a008.

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Forni, J. A., A. F. P. Biajoli, E. T. da Penha, and C. R. D. Correia. "Expeditious syntheses of 3,4-dihydroisocoumarins and phthalides via a Heck-Matsuda reaction." In 14th Brazilian Meeting on Organic Synthesis. Editora Edgard Blücher, 2013. http://dx.doi.org/10.5151/chempro-14bmos-r0044-1.

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Frota, Carlise, Caio Costa Oliveira, and Carlos R. D. Correia. "Study on the intermolecular Enantioselective Heck-Matsuda reaction of acyclic olefin diol." In 15th Brazilian Meeting on Organic Synthesis. Editora Edgard Blücher, 2013. http://dx.doi.org/10.5151/chempro-15bmos-bmos2013_2013913204933.

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Rabbani, Mahboubeh, and Masoomeh Fazeli. "Synthesis of AlF₃ as a catalyst of Heck reaction." In The 23rd International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2019. http://dx.doi.org/10.3390/ecsoc-23-06655.

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Schwalm, Cristiane Storck, and Carlos Roque Duarte Correia. "Exploring the enantioselective Heck-Matsuda reaction with electron-rich endocyclic olefins – 2,3-dihydrofuran asymmetric arylation." In 15th Brazilian Meeting on Organic Synthesis. Editora Edgard Blücher, 2013. http://dx.doi.org/10.5151/chempro-15bmos-bmos2013_20139720518.

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