Academic literature on the topic 'Hemilabile phosphine ligands'

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Journal articles on the topic "Hemilabile phosphine ligands"

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Keim, Wilhelm, Heiko Maas, and Stefan Mecking. "Palladium Catalyzed Alternating Cooligomerization of Ethylene and Carbon Monoxide to Unsaturated Ketones." Zeitschrift für Naturforschung B 50, no. 3 (March 1, 1995): 430–38. http://dx.doi.org/10.1515/znb-1995-0318.

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Cationic palladium catalysts have been used to cooligomerize ethylene and carbon monoxide. At high ethylene/CO ratios (m /m = 10:1) in methylene chloride as a solvent, unsaturated alternating cooligomers of the general structure R[C(O)CH2CH2]mH ( m ≥ 1 ; R ≡CH2=CH-, CH2=CHCH2CH2- and CH3CH = CHCH2-) were obtained for the first time. Single component catalyst precursors [(allyl)Pd(P^X )]+Y- (P^X = Ph2P(CH2)nC(= O )OR, Ph2P(CH2)2P(=O)Ph2, Ph2P(CH2)nPh2P(CH2)2S (=O )Ph, n = 1 - 3 , R = Me, Et; Y- = BF4-, SbF6- ) with bidentate P,O- and P,S-ligands as well as in situ catalysts with unfunctionalize
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Sharma, Anuja, and Ryan J. Trovitch. "Phosphorous-substituted redox-active ligands in base metal hydrosilylation catalysis." Dalton Transactions 50, no. 44 (2021): 15973–77. http://dx.doi.org/10.1039/d1dt02879k.

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Gushchin, Artem L., Nikita Y. Shmelev, Svetlana F. Malysheva, Alexander V. Artem’ev, Nataliya A. Belogorlova, Pavel A. Abramov, Nikolay B. Kompan’kov, et al. "Hemilability of phosphine-thioether ligands coordinated to trinuclear Mo3S4 cluster and its effect on hydrogenation catalysis." New Journal of Chemistry 42, no. 21 (2018): 17708–17. http://dx.doi.org/10.1039/c8nj03720e.

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Phosphine-thioether ligands were coordinated to the Mo<sub>3</sub>S<sub>4</sub> cluster to afford [Mo<sub>3</sub>S<sub>4</sub>Cl<sub>3</sub>(PS)<sub>3</sub>]<sup>+</sup> complexes. Their catalytic activity in nitrobenzene reduction reflects the different hemilabile behaviours of PS1, PS2 and PS3.
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Jung, Stefan, Carsten D. Brandt, and Helmut Werner. "A cationic allenylideneruthenium(II) complex with two bulky hemilabile phosphine ligands." New Journal of Chemistry 25, no. 9 (2001): 1101–3. http://dx.doi.org/10.1039/b104787f.

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Clot, Olivier, Michael O. Wolf, Glenn P. A. Yap, and Brian O. Patrick. "Synthesis and reactivity of ruthenium(II) complexes containing hemilabile phosphine–thiophene ligands." Journal of the Chemical Society, Dalton Transactions, no. 16 (2000): 2729–37. http://dx.doi.org/10.1039/b001898h.

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Angell, Sarah E., Yan Zhang, Cerrie W. Rogers, Michael O. Wolf, and Wayne E. Jones. "Photophysical Properties of Ru(II) Bipyridyl Complexes Containing Hemilabile Phosphine−Ether Ligands." Inorganic Chemistry 44, no. 21 (October 2005): 7377–84. http://dx.doi.org/10.1021/ic050436l.

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Tole, Tegene T., Johannes H. L. Jordaan та Hermanus C. M. Vosloo. "α-Pyridinyl Alcohols, α,α’-Pyridine Diols, α-Bipyridinyl Alcohols, and α,α’-Bipyridine Diols as Structure Motifs Towards Important Organic Molecules and Transition Metal Complexes". Current Organic Synthesis 17, № 5 (27 липня 2020): 344–66. http://dx.doi.org/10.2174/1570179417666200212111049.

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Background: The preparation and use of pyridinyl alcohols as ligands showed incredible increment in the past three decades. Important property of pyridinyl alcoholato ligands is their strong basicity, which is mainly due to the lack of resonance stabilization of the corresponding anion. This strongly basic anionic nature gives them high ability to make bridges between metal centers rather than to bind to only one metal center in a terminal fashion. They are needed as ligands due to their ability to interact with transition metals both covalently (with oxygen) and hemilabile coordination (throu
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Grushin, Vladimir V. "Synthesis of Hemilabile Phosphine−Phosphine Oxide Ligands via the Highly Selective Pd-Catalyzed Mono-oxidation of Bidentate Phosphines: Scope, Limitations, and Mechanism." Organometallics 20, no. 18 (September 2001): 3950–61. http://dx.doi.org/10.1021/om010454k.

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Cadierno, Victorio, Josefina Díez, Sergio E. García-Garrido, Santiago García-Granda, and José Gimeno. "Ruthenium(ii) and ruthenium(iv) complexes containing hemilabile heterodifunctional iminophosphorane-phosphine ligands Ph2PCH2P(NR)Ph2." Journal of the Chemical Society, Dalton Transactions, no. 7 (2002): 1465. http://dx.doi.org/10.1039/b110442j.

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Caballero, Agustín, Félix A. Jalón, Blanca R. Manzano, Gustavo Espino, Mercedes Pérez-Manrique, Antonio Mucientes, Francisco J. Poblete, and Miguel Maestro. "Ruthenium Arene Derivatives with PN Hemilabile Ligands. P−C Cleavage and Phosphine to Phosphinite Transformation." Organometallics 23, no. 24 (November 2004): 5694–706. http://dx.doi.org/10.1021/om049438o.

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Dissertations / Theses on the topic "Hemilabile phosphine ligands"

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Noack, Cassandra, and n/a. "Studies in Coordination Chemistry." Griffith University. School of Science, 2003. http://www4.gu.edu.au:8080/adt-root/public/adt-QGU20031030.145610.

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The research reported in this thesis was carried out in Brisbane, Australia and Calgary, Canada. The aim of the research conducted in Brisbane was to prepare a series of copper(I) and ruthenium(II) based complexes incorporating a hemilabile phosphine ligand and to determine whether or not these compounds possessed catalytic activity. The history, uses, properties and recent work incorporating hemilabile phosphine ligands is discussed in detail as well as the application of hemilabile ligands to atom transfer radical polymerization (ATRP) and the usefulness of the 'windscreen wiper' action of
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Noack, Cassandra. "Studies in Coordination Chemistry." Thesis, Griffith University, 2003. http://hdl.handle.net/10072/366798.

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The research reported in this thesis was carried out in Brisbane, Australia and Calgary, Canada. The aim of the research conducted in Brisbane was to prepare a series of copper(I) and ruthenium(II) based complexes incorporating a hemilabile phosphine ligand and to determine whether or not these compounds possessed catalytic activity. The history, uses, properties and recent work incorporating hemilabile phosphine ligands is discussed in detail as well as the application of hemilabile ligands to atom transfer radical polymerization (ATRP) and the usefulness of the 'windscreen wiper' action of
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Thorne, Lisa Margaret. "Sensing of carbon monoxide via luminescence of ruthenium complexes containing a hemilabile phosphine pyrenyl ether ligand." Thesis, 2004. http://hdl.handle.net/2429/15717.

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Our laboratory previously reported a Ru2 + complex with a hemilabile phosphine ether ligand tcc-RuCl2(POC4Pyr-P,O)2 (14) (POC4Pyr = 4-{2- (diphenylphosphino)phenoxy}butylpyrene). This complex reacts rapidly with carbon monoxide to produce a significant luminescence response in which the monomer: excimer emission ratio changes dramatically. The reaction with CO is accompanied by a geometric isomerization from the initial trans-dicarbonyl product, ttt- RuCl2(CO)2(POC4Pyr-P)2 , to the cis-dicarbonyl product, crt-RuCl2(CO)2(POC4Pyr-P)2. However, an OFF-ON response was not achieved. Two meth
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Conference papers on the topic "Hemilabile phosphine ligands"

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Marra, Roberta K. F., Alice M. R. Bernardino, Marcos C. de Souza, Gilberto A. Romeiro, María J. Iglesias, and Fernando López-Ortiz. "Synthesis of new hemilabile ligands based on phosphinic amide and pyrazolo[1,5-c]quanazoline moieties Applications in coordination chemistry." In 15th Brazilian Meeting on Organic Synthesis. São Paulo: Editora Edgard Blücher, 2013. http://dx.doi.org/10.5151/chempro-15bmos-bmos2013_201381913053.

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