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Relevant bibliographies by topics / Heterocyclic Carbene

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Academic literature on the topic 'Heterocyclic Carbene'

Author: Grafiati

Published: 6 September 2023

Last updated: 31 July 2025

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Journal articles on the topic "Heterocyclic Carbene"

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Longevial, Jean-François, Mamadou Lo, Aurélien Lebrun, Danielle Laurencin, Sébastien Clément, and Sébastien Richeter. "Molecular complexes and main-chain organometallic polymers based on Janus bis(carbenes) fused to metalloporphyrins." Dalton Transactions 49, no. 21 (2020): 7005–14. http://dx.doi.org/10.1039/d0dt00594k.

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Janus bis(N-heterocyclic carbenes) composed of a porphyrin core with two N-heterocyclic carbene (NHC) heads fused to opposite pyrroles were used as bridging ligands for the preparation of metal complexes.

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Naeimi, Khadijeh, Mehdi Bayat, and Ehsan Alavi Pour. "Trinuclear cylinder-like potential anticancer and antibacterial Cu(i), Ag(i) and Au(i) nano-sized cationic complexes with tris-NHC ligands: cationic M₃ metal cluster displaying positive or negative cooperativity in triad [L₂(R)₆→M₃]³⁺ complexes?" RSC Advances 15, no. 9 (2025): 6742–52. https://doi.org/10.1039/d4ra08514k.

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N-Heterocyclic carbenes (NHCs) are a class of organic molecules containing a divalent carbon atom, known as a carbene, within a heterocyclic (ring) structure where nitrogen atoms (N) form part of the ring.

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Zhu, Yannan, and You Huang. "Organocatalyzed [3+3] Annulations for the Construction of Heterocycles." Synthesis 52, no. 08 (2020): 1181–202. http://dx.doi.org/10.1055/s-0039-1690810.

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Six-membered heterocyclic systems are widely distributed in many natural products and pharmaceuticals, and the construction of highly functionalized six-membered heterocyclic compounds is an important topic in modern organic synthesis. Organocatalyzed [3+3] annulations represents an important method for assembling a substantial variety of six-membered cycles that contain one or more heteroatoms. This review describes the development of organocatalyzed [3+3] annulations for the synthesis of six-membered heterocycles, including organocatalysis using secondary amines, tertiary amines, phosphines,

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Dong, Zhaowen, Cristian Pezzato, Andrzej Sienkiewicz, Rosario Scopelliti, Farzaneh Fadaei-Tirani, and Kay Severin. "SET processes in Lewis acid–base reactions: the tritylation of N-heterocyclic carbenes." Chemical Science 11, no. 29 (2020): 7615–18. http://dx.doi.org/10.1039/d0sc01278e.

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Leitão, Maria Inês P. S., Giulia Francescato, Clara S. B. Gomes, and Ana Petronilho. "Synthesis of Platinum(II) N-Heterocyclic Carbenes Based on Adenosine." Molecules 26, no. 17 (2021): 5384. http://dx.doi.org/10.3390/molecules26175384.

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Organometallic derivatization of nucleosides is a highly promising strategy for the improvement of the therapeutic profile of nucleosides. Herein, a methodology for the synthesis of metalated adenosine with a deprotected ribose moiety is described. Platinum(II) N-heterocyclic carbene complexes based on adenosine were synthesized, namely N-heterocyclic carbenes bearing a protected and unprotected ribose ring. Reaction of the 8-bromo-2′,3′,5′-tri-O-acetyladenosine with Pt(PPh3)4 by C8−Br oxidative addition yielded complex 1, with a PtII centre bonded to C-8 and an unprotonated N7. Complex 1 reac

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Fernando, Jared, Alison Levens, Daniel Moock, and David Lupton. "N-Heterocyclic Carbene Catalyzed Transformylation." Synthesis 49, no. 15 (2017): 3505–10. http://dx.doi.org/10.1055/s-0036-1588449.

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The N-heterocyclic carbene (NHC) catalyzed transformylation has been developed for the conversion of 1°, 2°, and 3° alcohols to the corresponding formates. The reaction employs low catalyst loadings and methyl formate as the formyl transfer reagent. The scope of the reaction is broad with 23 examples reported with good yields (59–96%). The reaction is insensitive to common nitrogen and oxygen protecting groups and can be achieved in the presence of a number of heterocycles.

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Fujita, Ken-ichi, Junichi Sato, and Hiroyuki Yasuda. "Tautomerization of 5-Alkylidene-2-Oxazolidinone to 2-Oxazolone by Use of an N-Heterocyclic Carbene Catalyst." Synlett 26, no. 08 (2015): 1106–10. http://dx.doi.org/10.1055/s-0034-1380274.

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By employing an N-heterocyclic carbene as a catalyst, the tautomerization of 5-alkylidene-2-oxazolidinone proceeded to afford the corresponding 2-oxazolone. Among N-heterocyclic carbenes, 1,3-di-tert-butylimidazol-2-ylidene was the most effective catalyst for the tautomerization of 5-alkylidene-2-oxazolidinone.

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Zhao, Shixian, Feifei Wu, Yuyu Ma, Wanzhi Chen, Miaochang Liu, and Huayue Wu. "Enhancement of N-heterocyclic carbenes on rhodium catalyzed olefination of triazoles." Organic & Biomolecular Chemistry 14, no. 8 (2016): 2550–55. http://dx.doi.org/10.1039/c5ob02397a.

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Hollóczki, Oldamur. "Unveiling the peculiar hydrogen bonding behavior of solvated N-heterocyclic carbenes." Physical Chemistry Chemical Physics 18, no. 1 (2016): 126–40. http://dx.doi.org/10.1039/c5cp05369b.

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After fitting a molecular mechanical force field for imidazol-2-ylidenes, MD simulations revealed carbene–carbene and three-center hydrogen bonds of carbenes. The practical importance of these structures is also highlighted.

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Wu, Wenchao, Shuangli Xu, Yan Zhang та ін. "NHC-catalyzed β-specific addition of N-based nucleophiles to allenoates". Organic Chemistry Frontiers 7, № 13 (2020): 1593–99. http://dx.doi.org/10.1039/d0qo00189a.

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N-heterocyclic carbene (NHC) catalyzed reactions of nitrogenous heterocycles or trifluoromethylated acylhydrazone with allenoates gave regiospecific β-adducts. DFT calculations rationalized the origination of regio- and E/Z selectivities.

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Dissertations / Theses on the topic "Heterocyclic Carbene"

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Ellul, Charles. "Trimetallic N-heterocyclic carbene complexes." Thesis, University of Bath, 2011. https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.538279.

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Hippolyte, Laura. "New syntheses of N-heterocyclic carbene-stabilized gold nanoparticles." Electronic Thesis or Diss., Sorbonne université, 2018. https://accesdistant.sorbonne-universite.fr/login?url=https://theses-intra.sorbonne-universite.fr/2018SORUS148.pdf.

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Récemment, les carbènes N-hétérocycliques (NHC) ont suscité un intérêt important dans le domaine de la chimie des matériaux. En effet, cette nouvelle catégorie de ligands forme des liaisons très fortes avec une diversité de métaux et leur structure, ainsi que leurs propriétés électroniques, peuvent être adaptées par de la synthèse organique. Cette forte liaison est d’un intérêt particulier dans le domaine des nanoparticules d’or (NP) et des synthèses ont déjà été proposées. En effet, les NPs présentent de nombreuses applications potentielles, par exemple dans les capteurs, en catalyse ou médec

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Casely, Ian J. "Electropositive metal N-heterocyclic carbene complexes." Thesis, University of Edinburgh, 2009. http://hdl.handle.net/1842/3873.

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The first chapter is an introduction to the f-elements, with a focus on the synthesis and chemistry of tetravalent cerium complexes. The synthesis, characterisation and reactivity of carbenes, particularly N-heterocyclic carbenes (NHCs), and anionic-functionalised NHC ligands is discussed. The synthesis and reactivity of s-block, Group three and fblock NHC complexes is reviewed. The synthesis of the alcohol-functionalised unsaturated imidazolium proligand, [H2L]I [H2L = HOCMe2CH2(1-CH{NCHCHNiPr})], is extended to saturated imidazolinium analogues, [H2LR]X, [HOCMe2CH2(1-CH{NCH2CH2NR})]X (R = iP

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Rodden, Mark. "Alkoxide functionalised N-heterocyclic carbene complexes." Thesis, University of Nottingham, 2005. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.423306.

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Williamson, Craig. "Imidazolylidenes in N-heterocyclic carbene organo-catalysis." Thesis, University of Aberdeen, 2006. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.440601.

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A library of chiral and achiral imidazolium salts was prepared, and evaluated as potential pre-catalysts of the benzoin condensation. It was found that although the carbenes derived from these compounds possess catalytic activity, this was not as pronounced as that observed for alternative heterocycle classes. Asymmetric induction, although observed from imidazolylidenes for the first time in this work, is not of an order that could be considered useful, as has been seen for other NHC catalysts. This is attributed to the use of harsh reaction conditions, required to promote catalytic activi

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Tulloch, Arran Alexander Dickon. "Novel mixed donor N-Heterocyclic carbene complexes." Thesis, University of Southampton, 2002. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.249941.

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Bemowski, Ross David. "Novel N-heterocyclic dicarbene ligands and molybdenum and dimolybdenum N-heterocyclic carbene complexes." Diss., University of Iowa, 2013. https://ir.uiowa.edu/etd/1291.

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The syntheses of a new class of polycyclic TriAmino DiCarbenes (TADCs), based on 3,9-diazajulolidine, and their precursors and adducts are described. Starting with 2,6-dimethyl-nitrobenzene, 2,6-bis ((alkylamino)methyl)anilines (alkyl = isopropyl, mesityl, and tert-butyl) were synthesized in 40% yield over five steps. These triamines were then di-cyclized stepwise to diformamidinium dications or formamidinium/2-methoxyformaminals using oxonium salts and trialkyl orthoformates. A diformamidinium dication was characterized by single-crystal X-ray diffractometry. Treatment with various bases, par

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Zhang, Pinglu. "Cyclodextrin-(N-Heterocyclic Carbene)-Metal Complexes for Cavity-Dependent Catalysis." Thesis, Paris 6, 2015. http://www.theses.fr/2015PA066380/document.

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Des complexes de Cyclodextrine (CD)-NHC-Métaux (NHC= Carbènes N-Hétérocycliques), comprenant des métaux tel que AgI, CuI et AuI ont été synthétisés. Une étude structurale a mis en évidence la position intra-cavitaire du métal, induisant des interactions C-H…M, C-H…X et π…X. L’influence du type de cavité (α-, β-, γ-CD) et du type de dérivés NHC (Imidazole, benzimidazole, triazole) a été étudiée. Les interactions diminuent avec l’augmentation de la taille de la cavité et en parallèle, celles-ci ont été amplifiées avec des dérivés NHC possédant un effet donneur plus fort. Les complexes de cuivre

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Ling, Xiang. "N-heterocyclic carbenes coated nanocrystals and supracrystals." Thesis, Paris 6, 2015. http://www.theses.fr/2015PA066334/document.

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Les nanomatériaux ont beaucoup captivé l'attention pour leur propriétés uniques, fortement associées à leurs dimensions nanoscopiques. En particulier, les nanoparticules (NP) à base de métaux nobles (Au, Ag) présentent des propriétés mécaniques, électroniques, optiques et magnétiques particulières intéressantes pour le développement d'applications dans de nombreux domaines à fort impact sociétal. En raison de leur stabilité élevée par rapport aux autres nano- particules métalliques, les nanoparticules d'or ont été abondamment explorées pour les nanotechnologies. Ces dernières décennies, les NH

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Maluenda, Borderas Irene. "(N-heterocyclic carbene) : metal catalysed carbon-carbon and carbon-heteroatom bond-forming reactions." Thesis, University of Sussex, 2018. http://sro.sussex.ac.uk/id/eprint/76274/.

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Books on the topic "Heterocyclic Carbene"

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Kühl, Olaf. Functionalised N-heterocyclic carbene complexes. Wiley, 2009.

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Kühl, Olaf. Functionalised N-heterocyclic carbene complexes. Wiley, 2009.

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Kühl, Olaf. Functionalised N-heterocyclic carbene complexes. Wiley, 2010.

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Vogel, Carola S. High- and Low-Valent tris-N-Heterocyclic Carbene Iron Complexes. Springer Berlin Heidelberg, 2012. http://dx.doi.org/10.1007/978-3-642-27254-7.

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Cazin, Catherine Suzanne Julienne. N-Heterocyclic Carbenes in Transition Metal Catalysis and Organocatalysis. Springer Science+Business Media B.V., 2011.

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6

Zou, Taotao. Anti-Cancer N-Heterocyclic Carbene Complexes of Gold(III), Gold(I) and Platinum(II). Springer Singapore, 2016. http://dx.doi.org/10.1007/978-981-10-0657-9.

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service), SpringerLink (Online, ed. High- and Low-Valent tris-N-Heterocyclic Carbene Iron Complexes: A Study of Molecular and Electronic Structure. Springer Berlin Heidelberg, 2012.

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Diez-Gonzalez, Silvia, ed. N-Heterocyclic Carbenes. Royal Society of Chemistry, 2010. http://dx.doi.org/10.1039/9781849732161.

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Diez-Gonzalez, Silvia, ed. N-Heterocyclic Carbenes. Royal Society of Chemistry, 2016. http://dx.doi.org/10.1039/9781782626817.

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Nolan, Steven P., ed. N-Heterocyclic Carbenes. Wiley-VCH Verlag GmbH & Co. KGaA, 2014. http://dx.doi.org/10.1002/9783527671229.

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Book chapters on the topic "Heterocyclic Carbene"

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Fang, Xinqiang, and Yonggui Robin Chi. "N-Heterocyclic Carbene Catalysis." In Nonnitrogenous Organocatalysis. CRC Press, 2017. http://dx.doi.org/10.1201/9781315371238-7.

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Mahatthananchai, Jessada, and Jeffrey W. Bode. "Catalytic Reactions withN-Mesityl-SubstitutedN-Heterocyclic Carbenes." In Contemporary Carbene Chemistry. John Wiley & Sons, Inc, 2013. http://dx.doi.org/10.1002/9781118730379.ch9.

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Hoyos, Mario, Daniel Guest, and Oscar Navarro. "(N-Heterocyclic Carbene)-Palladium Complexes in Catalysis." In N-Heterocyclic Carbenes. Wiley-VCH Verlag GmbH & Co. KGaA, 2014. http://dx.doi.org/10.1002/9783527671229.ch04.

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Wu, Linglin, Alvaro Salvador, and Reto Dorta. "Chiral MonodendateN-Heterocyclic Carbene Ligands in Asymmetric Catalysis." In N-Heterocyclic Carbenes. Wiley-VCH Verlag GmbH & Co. KGaA, 2014. http://dx.doi.org/10.1002/9783527671229.ch03.

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Peris, Eduardo. "Routes to N-Heterocyclic Carbene Complexes." In N-Heterocyclic Carbenes in Transition Metal Catalysis. Springer Berlin Heidelberg, 2006. http://dx.doi.org/10.1007/978-3-540-36930-1_4.

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Jahnke, Mareike C., and F. Ekkehardt Hahn. "Chemistry of N-Heterocyclic Carbene Ligands." In Topics in Organometallic Chemistry. Springer Berlin Heidelberg, 2009. http://dx.doi.org/10.1007/978-3-642-04722-0_4.

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Cavell, Kingsley J., and Adrien T. Normand. "N-Heterocyclic Carbene Complexes: Decomposition Pathways." In Catalysis by Metal Complexes. Springer Netherlands, 2010. http://dx.doi.org/10.1007/978-90-481-2866-2_13.

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Scheidt, Karl A., Eric M. Phillips, and Julien Dugal-Tessier. "N-Heterocyclic Carbene-Catalyzed Aldol Desymmetrizations." In Asymmetric Synthesis II. Wiley-VCH Verlag GmbH & Co. KGaA, 2013. http://dx.doi.org/10.1002/9783527652235.ch39.

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Rivera, Guillermina, and Robert H. Crabtree. "Chelate and Pincer Carbene Complexes." In N-Heterocyclic Carbenes in Synthesis. Wiley-VCH Verlag GmbH & Co. KGaA, 2006. http://dx.doi.org/10.1002/9783527609451.ch9.

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Mavila, Sudheendran, and N. Gabriel Lemcoff. "N-Heterocyclic Carbene-Ruthenium Complexes: A Prominent Breakthrough in Metathesis Reactions." In N-Heterocyclic Carbenes. Wiley-VCH Verlag GmbH & Co. KGaA, 2014. http://dx.doi.org/10.1002/9783527671229.ch11.

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Conference papers on the topic "Heterocyclic Carbene"

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Kim, Dowon, Sukwon Hong, Jinhwan Byeon, et al. "Dry extreme ultraviolet lithography via N-heterocyclic carbene-metal complexes and etchant-free thermal development." In International Conference on Extreme Ultraviolet Lithography 2024, edited by Joern-Holger Franke, Kurt G. Ronse, Paolo A. Gargini, Patrick P. Naulleau, and Toshiro Itani. SPIE, 2024. http://dx.doi.org/10.1117/12.3034450.

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Huang, Jinying, Weiping Wu, and Minxu Lu. "Inhibition Effect of MDHTD for Corrosion by Sulfide-Reducing Bacteria Biofilm." In CORROSION 2012. NACE International, 2012. https://doi.org/10.5006/c2012-01182.

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Abstract Potentiodynamic polarization curves, Atom Force Spectroscopy and Electronic Probe Measurement Analysis were used to study the sensitivity of biofilm on Q235 steel to a kind of novel heterocyclic bisquats named MDHTD in culture medium inoculated Sulfate-Reducing Bacteria. The experiment results show that the formation of MDHTD adsorption film could affect the status and electrochemical characteristic of metal surface and decrease the corrosion reaction facilitated by SRB greatly. Also this made it difficult for metabolized production of SRB in medium and corrosion product to deposit di

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Liu, Qiao, Yong Zhou, Qianru Li, and Wenbo Lan. "Physical calculation and molecular simulation of nitrogen heterocyclic carbene palladium." In Second International Conference on Biomedical and Intelligent Systems (IC-BIS2023), edited by Ming Chen and Gangmin Ning. SPIE, 2023. http://dx.doi.org/10.1117/12.2688197.

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Arabzadeh Nosratabad, Neda, Zhicheng Jin, Liang Du, and Hedi Mattoussi. "N-Heterocyclic carbene-stabilized gold nanoparticles and luminescent quantum dots." In Colloidal Nanoparticles for Biomedical Applications XVII, edited by Marek Osiński and Antonios G. Kanaras. SPIE, 2022. http://dx.doi.org/10.1117/12.2610485.

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Silbestri, Gustavo, Gabriela Fernández, María Vela Gurovic, Nelda Olivera, and Alicia Chopa. "Synthesis and Antimicrobial Activities of Gold(I) N-heterocyclic Carbene Complexes." In The 16th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2012. http://dx.doi.org/10.3390/ecsoc-16-01015.

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Radhi, Ali Jabbar, Ehab K. Obaid, Zaman Abdalhussein Ibadi Alaridhee, and Mohammed Z. Ghadhyeb. "New platinum (II) N-heterocyclic carbene complexes: Synthesis, identification, and antibacterial evaluation." In 4TH INTERNATIONAL CONFERENCE ON INNOVATION IN IOT, ROBOTICS AND AUTOMATION (IIRA 4.0). AIP Publishing, 2025. https://doi.org/10.1063/5.0254904.

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Mattoussi, Hedi, Neda Arabzadeh Nosratabad, Liang Du, and Zhicheng Jin. "N-Heterocyclic Carbene-stabilized QDs and Gold Nanoparticles: Effects of the Ligand Coordination." In Internet NanoGe Conference on Nanocrystals. Fundació Scito, 2021. http://dx.doi.org/10.29363/nanoge.incnc.2021.053.

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Vita, Diana E., Mercedes A. Badajoz, Marcos J. Lo Fiego, and Gustavo F. Silbestri. "Synthesis of N-Heterocyclic Carbene Gold Complexes Using 2,4,6-Trimethylphenyl Sydnone as Model Substrate †." In International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2022. http://dx.doi.org/10.3390/ecsoc-26-13674.

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Cingolani, Andrea, Rita Mazzoni, Valerio Zanotti, et al. "Bis-amino functionalized iron N-heterocyclic carbene as epoxy resins hardener and flame behaviour modifier." In THE 9TH INTERNATIONAL CONFERENCE ON STRUCTURAL ANALYSIS OF ADVANCED MATERIALS - ICSAAM 2019. AIP Publishing, 2019. http://dx.doi.org/10.1063/1.5140308.

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Fernández, Sergio, Federico Franco, Josep M. Luis, and Julio Lloret-Fillol. "Unravelling the CO2 Reduction Mechanism with a Highly Active N-Heterocyclic Carbene Manganese(I) Electrocatalyst." In nanoGe Spring Meeting 2022. Fundació Scito, 2022. http://dx.doi.org/10.29363/nanoge.nsm.2022.343.

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