Academic literature on the topic 'Heterogeneous catalysis catalytic wet air oxidation'

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Journal articles on the topic "Heterogeneous catalysis catalytic wet air oxidation"

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Li, De-bin, Duo Wang, and Zi-sheng Jiang. "Catalytic Wet Air Oxidation of Sewage Sludge: A Review." Current Organocatalysis 7, no. 3 (2020): 199–211. http://dx.doi.org/10.2174/2213337207999200819143311.

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Wet air oxidation (WAO) is an attractive technique for sewage sludge treatment. The WAO process and the factors influencing the process are examined in detail, together with the advantages and disadvantages. Catalytic wet air oxidation (CWAO) is emphasized because it can lower operational conditions, and the commonly-used and new homogeneous and heterogeneous catalysts are introduced. Homogeneous catalysts tend to be more appropriate for the CWAO treatment of sewage sludge, and Cu-based homogeneous catalysts such as CuSO4 are the most popular for industrial applications. Heterogeneous catalyst
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Ovejero, G., J. L. Sotelo, F. Martínez, and L. Gordo. "Novel heterogeneous catalysts in the wet peroxide oxidation of phenol." Water Science and Technology 44, no. 5 (2001): 153–60. http://dx.doi.org/10.2166/wst.2001.0275.

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Catalytic wet peroxide oxidation (CWPO) of diluted aqueous solutions of phenol has been studied over a series of heterogeneous catalysts at 100°C under 1MPa air pressure. Several catalysts were prepared and tested including zeolitic materials exchanged with metallic ions such as Fe and Cu and different mixed oxides. Likewise, a Fe-TS- zeolite was synthesised by isomorphous substitution of Si atoms by Fe and Ti into the MFI zeolitic framework through hydrothermal synthesis of wetness-impregnated Fe2O3-TiO2-SiO2 xerogels. This material showed a complete phenol removal and TOC reduction of up to
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Utievskyi, Yurii, Christof Neumann, Julia Sindlinger, et al. "Polyoxometalate-Modified Amphiphilic Polystyrene-block-poly(2-(dimethylamino)ethyl methacrylate) Membranes for Heterogeneous Glucose to Formic Acid Methyl Ester Oxidation." Nanomaterials 13, no. 18 (2023): 2498. http://dx.doi.org/10.3390/nano13182498.

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Herein, we present a new heterogeneous catalyst active toward glucose to formic acid methyl ester oxidation. The catalyst was fabricated via electrostatic immobilization of the inorganic polyoxometalate HPA-5 catalyst H8[PMo7V5O40] onto the pore surface of amphiphilic block copolymer membranes prepared via non-solvent-induced phase separation (NIPS). The catalyst immobilization was achieved via wet impregnation due to strong coulombic interactions between protonated tertiary amino groups of the polar poly(2-(dimethylamino)ethyl methacrylate) block and the anionic catalyst. Overall, three sets
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Yoon, C. H., S. H. Cho, S. H. Kim, and S. R. Ha. "Catalytic wet air oxidation of p-nitrophenol (PNP) aqueous solution using multi-component heterogeneous catalysts." Water Science and Technology 43, no. 2 (2001): 229–36. http://dx.doi.org/10.2166/wst.2001.0094.

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This study investigated the decomposition of high strength p-nitrophenol (PNP) of 2,000 mg/l (3,400 mg of COD/1,250 mg of TOC) by catalytic wet air oxidation. Multi-component heterogeneous catalysts were used as catalysts for this purpose. The study results using a batch reactor showed that catalyst “D” (Mn-Ce-Zr 22.4 g plus CuSO4 1.0 g; Mn-Ce-Zr-Cu [CuSO4]) was more effective (56˜74%) than catalyst “A” (Mn-Ce-Zr 22.4 g) under the given conditions (O2 partial pressure of 1.0 MPa; temperature of 170˜190°C; 30 min of reaction time). The best result was obtained when 2 g of Mn-Ce-Zr-Cu [CuSO4] wa
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Yang, Xin, Junhai Wang, Qi Zhang, et al. "Fabrication of Core-Shell Structural SiO2@H3[PM12O40] Material and Its Catalytic Activity." Journal of Nanomaterials 2014 (2014): 1–8. http://dx.doi.org/10.1155/2014/835931.

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Through a natural tree grain template and sol-gel technology, the heterogeneous catalytic materials based on polyoxometalate compounds H3[PM12O40] encapsulating SiO2: SiO2@H3[PM12O40] (SiO2@PM12, M = W, Mo) with core-shell structure had been prepared. The structure and morphology of the core-shell microspheres were characterized by the XRD, IR spectroscopy, UV-Vis absorbance, and SEM. These microsphere materials can be used as heterogeneous catalysts with high activity and stability for catalytic wet air oxidation of pollutant dyes safranine T (ST) at room condition. The results show that the
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Pham, Thien, Viet Bui, Thi Phan, and Ha Than. "CO oxidation over alumina monolith impregnated with oxides of copper and manganese." Journal of the Serbian Chemical Society 86, no. 6 (2021): 615–24. http://dx.doi.org/10.2298/jsc200509004p.

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In this work, simple methods for the preparation of highly efficient heterogeneous nanocatalysts for the low-temperature oxidation of CO are described. The main advantages of the reaction are high yields. The catalysts based on oxides of copper and manganese supported on alumina monoliths were prepared by different methods: plasma corona discharge and wet impregnation. Structure and physical properties of catalysts were characterized by FT- -IR, XRD, TEM, EDX and TG/DTA. The results showed that the use of a plasma corona discharge at atmospheric pressure for the preparation of the catalysts re
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Maicaneanu, S. Andrada, Breanna McGhee, Razvan Stefan, Lucian Barbu-Tudoran, Christopher Sedwick, and Charles H. Lake. "Investigations on Cationic Dye Degradation Using Iron-Doped Carbon Xerogel." ChemEngineering 3, no. 3 (2019): 61. http://dx.doi.org/10.3390/chemengineering3030061.

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Iron-doped carbon xerogels were prepared using sol-gel synthesis, with potassium-2,4-dihydroxybenzoate and formaldehyde as starting materials, followed by an ion exchange step. The obtained samples were characterized (XRD, FTIR, SED-EDX, TEM) and investigated as catalysts in heterogeneous Fenton and catalytic wet air oxidation (CWAO) processes. Experiments were conducted in the same conditions (0.1 g catalysts, 25 mL of 100 mg/L dye solution, 25 °C, initial solution pH, 3 h) in thermostated batch reaction tubes (shaking water bath, 50 rpm) at atmospheric pressure. A series of three cationic dy
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Arena, Francesco, Cristina Italiano, Antonino Raneri, and Concetta Saja. "Mechanistic and kinetic insights into the wet air oxidation of phenol with oxygen (CWAO) by homogeneous and heterogeneous transition-metal catalysts." Applied Catalysis B: Environmental 99, no. 1-2 (2010): 321–28. http://dx.doi.org/10.1016/j.apcatb.2010.06.039.

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Rao, Reshma R. "(Invited) Spectroelectrochemical Investigation of Oxygen Electrocatalysis on Metal Oxides." ECS Meeting Abstracts MA2022-02, no. 46 (2022): 1714. http://dx.doi.org/10.1149/ma2022-02461714mtgabs.

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Improving the kinetics of oxygen electrocatalysis is key to increasing the efficiency of hydrogen production from renewable sources, production of carbon-neutral fuels such as ethylene and rechargeable metal-air batteries1. Metal oxides exhibit state-of-the-art activity, but fundamental atomic-level insights into the reaction mechanism are often unknown. Particularly, various differences between materials, including the differences in active surface area, chemical state of the metal cations, fractional coverage of oxidized species and the range of ordered structure, renders it difficult to ide
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Duprez, D. "Recent developments in catalytic wet air oxidation." Applied Catalysis A: General 153, no. 1-2 (1997): N3—N4. http://dx.doi.org/10.1016/s0926-860x(97)90123-x.

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Dissertations / Theses on the topic "Heterogeneous catalysis catalytic wet air oxidation"

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SCELFO, SIMONE. "Metal oxides catalysts for the synthesis of value-added chemicals from 2nd generation sugars and sugar derivatives." Doctoral thesis, Politecnico di Torino, 2017. http://hdl.handle.net/11583/2675152.

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The present Ph.D. thesis provides some examples of innovative 2nd generation catalytic processes for the conversion of renewable raw materials into green value-added chemicals. In particular, D-glucose and some its derivatives, all ideally representing waste materials of dedicated biomasses, agricultural residues, or solid organic urban waste exploitation in the biorefinery plant, were converted into useful chemical building-blocks. After a brief introduction to the topic and the description of the experimental method, each chapter of the work is based on one or more scientific articles eithe
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Grosjean, Nicolas. "Oxydation par voie humide catalytique d’effluents industriels : catalyseurs métaux nobles supportés." Thesis, Lyon 1, 2010. http://www.theses.fr/2010LYO10021.

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L’industrie produit de grandes quantités d’effluents aqueux qu’il convient de traiter. Des traitements alternatifs aux procédés biologiques doivent être développés pour certains effluents toxiques et/ou non biodégradables. L’oxydation en voie humide catalytique repose sur l’action de l’oxygène sur les polluants en phase aqueuse à haute température et haute pression. Préalablement à cette étude, des catalyseurs au Ru ou Pt supportés sur ZrO2 ou TiO2très actifs et très stables pour l’OVHC de polluants modèles et de quelques effluents réels ont été développés. Ce travail a examiné ces catalyseurs
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Wu, Qiang. "Wastewater treatment by catalytic wet air oxidation in a continuous pilot-scale trickle bed reactor /." View abstract or full-text, 2004. http://library.ust.hk/cgi/db/thesis.pl?CENG%202004%20WU.

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Ayadi, Hana. "Catalyseurs performants pour le traitement de la pollution organique azotée par Oxydation en Voie Humide Catalytique." Thesis, Lyon, 2017. http://www.theses.fr/2017LYSE1273/document.

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Des catalyseurs à base d'oxyde de manganèse ont été préparés par différentes voies et évalués dans l'Oxydation en Voie Humide Catalytique de l'ammoniaque. Les catalyseurs sont actifs, sélectifs en diazote et stables dans les conditions de la réaction. Diazote et nitrite sont des produits primaires de la réaction. Une étude approfondie de l'effet des paramètres opératoires (teneur en manganèse, pression partielle en oxygène, concentration en ammoniaque, pH initial de la solution, charge de surface du catalyseur) sur les performances catalytiques a été réalisée. La sélectivité en diazote est fav
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Book chapters on the topic "Heterogeneous catalysis catalytic wet air oxidation"

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Besson, Michèle, Jean-Christophe Beziat, Bernard Blanc, Sylvain Durecu, and Pierre Gallezot. "Treatment of aqueous solutions of organic pollutants by heterogeneous catalytic wet air oxidation (CWAO)." In Studies in Surface Science and Catalysis. Elsevier, 2000. http://dx.doi.org/10.1016/s0167-2991(00)80421-8.

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Nedyalkova, Radka, Michèle Besson, and Claude Descorme. "Catalytic wet air oxidation of succinic acid over monometallic and bimetallic gold based catalysts: Influence of the preparation method." In Scientific Bases for the Preparation of Heterogeneous Catalysts - Proceedings of the 10th International Symposium, Louvain-la-Neuve, Belgium, July 11-15, 2010. Elsevier, 2010. http://dx.doi.org/10.1016/s0167-2991(10)75022-9.

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Béziat, J. C., M. Besson, P. Gallezot, S. Juif, and S. Durécu. "Catalytic wet air oxidation of wastewaters." In Studies in Surface Science and Catalysis. Elsevier, 1997. http://dx.doi.org/10.1016/s0167-2991(97)81023-3.

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Sanger, Alan R., Theo T. K. Lee, and Karl T. Chuang. "Catalytic wet air oxidation in the presence of hydrogen peroxide." In Progress in Catalysis, Proceedings of the 12th Canadian Symposium on Catalysis. Elsevier, 1992. http://dx.doi.org/10.1016/s0167-2991(08)60814-9.

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Ishii, T., J. Miyake, T. Hashimoto, K. Mitsui, and M. Kobayashi. "108 Advanced technology for catalytic wet air oxidation of wastewater." In Science and Technology in Catalysis 2002, Proceedings of the Fourth Tokyo conference on Advance Catalytic Science and Technology. Elsevier, 2003. http://dx.doi.org/10.1016/s0167-2991(03)80265-3.

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