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1

Li, De-bin, Duo Wang, and Zi-sheng Jiang. "Catalytic Wet Air Oxidation of Sewage Sludge: A Review." Current Organocatalysis 7, no. 3 (2020): 199–211. http://dx.doi.org/10.2174/2213337207999200819143311.

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Wet air oxidation (WAO) is an attractive technique for sewage sludge treatment. The WAO process and the factors influencing the process are examined in detail, together with the advantages and disadvantages. Catalytic wet air oxidation (CWAO) is emphasized because it can lower operational conditions, and the commonly-used and new homogeneous and heterogeneous catalysts are introduced. Homogeneous catalysts tend to be more appropriate for the CWAO treatment of sewage sludge, and Cu-based homogeneous catalysts such as CuSO4 are the most popular for industrial applications. Heterogeneous catalyst
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2

Ovejero, G., J. L. Sotelo, F. Martínez, and L. Gordo. "Novel heterogeneous catalysts in the wet peroxide oxidation of phenol." Water Science and Technology 44, no. 5 (2001): 153–60. http://dx.doi.org/10.2166/wst.2001.0275.

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Catalytic wet peroxide oxidation (CWPO) of diluted aqueous solutions of phenol has been studied over a series of heterogeneous catalysts at 100°C under 1MPa air pressure. Several catalysts were prepared and tested including zeolitic materials exchanged with metallic ions such as Fe and Cu and different mixed oxides. Likewise, a Fe-TS- zeolite was synthesised by isomorphous substitution of Si atoms by Fe and Ti into the MFI zeolitic framework through hydrothermal synthesis of wetness-impregnated Fe2O3-TiO2-SiO2 xerogels. This material showed a complete phenol removal and TOC reduction of up to
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3

Utievskyi, Yurii, Christof Neumann, Julia Sindlinger, et al. "Polyoxometalate-Modified Amphiphilic Polystyrene-block-poly(2-(dimethylamino)ethyl methacrylate) Membranes for Heterogeneous Glucose to Formic Acid Methyl Ester Oxidation." Nanomaterials 13, no. 18 (2023): 2498. http://dx.doi.org/10.3390/nano13182498.

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Herein, we present a new heterogeneous catalyst active toward glucose to formic acid methyl ester oxidation. The catalyst was fabricated via electrostatic immobilization of the inorganic polyoxometalate HPA-5 catalyst H8[PMo7V5O40] onto the pore surface of amphiphilic block copolymer membranes prepared via non-solvent-induced phase separation (NIPS). The catalyst immobilization was achieved via wet impregnation due to strong coulombic interactions between protonated tertiary amino groups of the polar poly(2-(dimethylamino)ethyl methacrylate) block and the anionic catalyst. Overall, three sets
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4

Yoon, C. H., S. H. Cho, S. H. Kim, and S. R. Ha. "Catalytic wet air oxidation of p-nitrophenol (PNP) aqueous solution using multi-component heterogeneous catalysts." Water Science and Technology 43, no. 2 (2001): 229–36. http://dx.doi.org/10.2166/wst.2001.0094.

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This study investigated the decomposition of high strength p-nitrophenol (PNP) of 2,000 mg/l (3,400 mg of COD/1,250 mg of TOC) by catalytic wet air oxidation. Multi-component heterogeneous catalysts were used as catalysts for this purpose. The study results using a batch reactor showed that catalyst “D” (Mn-Ce-Zr 22.4 g plus CuSO4 1.0 g; Mn-Ce-Zr-Cu [CuSO4]) was more effective (56˜74%) than catalyst “A” (Mn-Ce-Zr 22.4 g) under the given conditions (O2 partial pressure of 1.0 MPa; temperature of 170˜190°C; 30 min of reaction time). The best result was obtained when 2 g of Mn-Ce-Zr-Cu [CuSO4] wa
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5

Yang, Xin, Junhai Wang, Qi Zhang, et al. "Fabrication of Core-Shell Structural SiO2@H3[PM12O40] Material and Its Catalytic Activity." Journal of Nanomaterials 2014 (2014): 1–8. http://dx.doi.org/10.1155/2014/835931.

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Through a natural tree grain template and sol-gel technology, the heterogeneous catalytic materials based on polyoxometalate compounds H3[PM12O40] encapsulating SiO2: SiO2@H3[PM12O40] (SiO2@PM12, M = W, Mo) with core-shell structure had been prepared. The structure and morphology of the core-shell microspheres were characterized by the XRD, IR spectroscopy, UV-Vis absorbance, and SEM. These microsphere materials can be used as heterogeneous catalysts with high activity and stability for catalytic wet air oxidation of pollutant dyes safranine T (ST) at room condition. The results show that the
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6

Pham, Thien, Viet Bui, Thi Phan, and Ha Than. "CO oxidation over alumina monolith impregnated with oxides of copper and manganese." Journal of the Serbian Chemical Society 86, no. 6 (2021): 615–24. http://dx.doi.org/10.2298/jsc200509004p.

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In this work, simple methods for the preparation of highly efficient heterogeneous nanocatalysts for the low-temperature oxidation of CO are described. The main advantages of the reaction are high yields. The catalysts based on oxides of copper and manganese supported on alumina monoliths were prepared by different methods: plasma corona discharge and wet impregnation. Structure and physical properties of catalysts were characterized by FT- -IR, XRD, TEM, EDX and TG/DTA. The results showed that the use of a plasma corona discharge at atmospheric pressure for the preparation of the catalysts re
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7

Maicaneanu, S. Andrada, Breanna McGhee, Razvan Stefan, Lucian Barbu-Tudoran, Christopher Sedwick, and Charles H. Lake. "Investigations on Cationic Dye Degradation Using Iron-Doped Carbon Xerogel." ChemEngineering 3, no. 3 (2019): 61. http://dx.doi.org/10.3390/chemengineering3030061.

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Iron-doped carbon xerogels were prepared using sol-gel synthesis, with potassium-2,4-dihydroxybenzoate and formaldehyde as starting materials, followed by an ion exchange step. The obtained samples were characterized (XRD, FTIR, SED-EDX, TEM) and investigated as catalysts in heterogeneous Fenton and catalytic wet air oxidation (CWAO) processes. Experiments were conducted in the same conditions (0.1 g catalysts, 25 mL of 100 mg/L dye solution, 25 °C, initial solution pH, 3 h) in thermostated batch reaction tubes (shaking water bath, 50 rpm) at atmospheric pressure. A series of three cationic dy
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8

Arena, Francesco, Cristina Italiano, Antonino Raneri, and Concetta Saja. "Mechanistic and kinetic insights into the wet air oxidation of phenol with oxygen (CWAO) by homogeneous and heterogeneous transition-metal catalysts." Applied Catalysis B: Environmental 99, no. 1-2 (2010): 321–28. http://dx.doi.org/10.1016/j.apcatb.2010.06.039.

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9

Rao, Reshma R. "(Invited) Spectroelectrochemical Investigation of Oxygen Electrocatalysis on Metal Oxides." ECS Meeting Abstracts MA2022-02, no. 46 (2022): 1714. http://dx.doi.org/10.1149/ma2022-02461714mtgabs.

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Improving the kinetics of oxygen electrocatalysis is key to increasing the efficiency of hydrogen production from renewable sources, production of carbon-neutral fuels such as ethylene and rechargeable metal-air batteries1. Metal oxides exhibit state-of-the-art activity, but fundamental atomic-level insights into the reaction mechanism are often unknown. Particularly, various differences between materials, including the differences in active surface area, chemical state of the metal cations, fractional coverage of oxidized species and the range of ordered structure, renders it difficult to ide
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10

Duprez, D. "Recent developments in catalytic wet air oxidation." Applied Catalysis A: General 153, no. 1-2 (1997): N3—N4. http://dx.doi.org/10.1016/s0926-860x(97)90123-x.

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11

Bhargava, Suresh K., James Tardio, Harit Jani, Deepak B. Akolekar, Karl Föger, and Manh Hoang. "Catalytic Wet Air Oxidation of Industrial Aqueous Streams." Catalysis Surveys from Asia 11, no. 1-2 (2007): 70–86. http://dx.doi.org/10.1007/s10563-007-9020-6.

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12

Gomes, H. T., J. L. Figueiredo, and J. L. Faria. "Catalytic wet air oxidation of olive mill wastewater." Catalysis Today 124, no. 3-4 (2007): 254–59. http://dx.doi.org/10.1016/j.cattod.2007.03.043.

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13

Rodríguez, A., J. García, G. Ovejero, and M. Mestanza. "Wet air and catalytic wet air oxidation of several azodyes from wastewaters: the beneficial role of catalysis." Water Science and Technology 60, no. 8 (2009): 1989–99. http://dx.doi.org/10.2166/wst.2009.526.

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Degradation of several azo dyes, Acid Orange 7 (AO7), Acid Orange 74 (AO74), Direct Blue 71 (DB71), Reactive Black 5 (RB5) and Eriochrome Blue Black B (EBBB), well-known non-biodegradable mono, di and tri azo dyes has been studied using, wet-air oxidation (WAO) and catalytic wet air oxidation (CWAO). The efficiency of substrate decolorization and mineralization in each process has been comparatively discussed by evolution concentration, chemical oxygen demand, total organic carbon content and toxicity of dyes solutions. The most efficient method on decolorization and mineralization (TOC) was o
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14

Lousteau, Cédric, Michèle Besson, and Claude Descorme. "Catalytic wet air oxidation of ammonia over supported noble metals." Catalysis Today 241 (March 2015): 80–85. http://dx.doi.org/10.1016/j.cattod.2014.03.043.

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15

Posada, Diana, Paulino Betancourt, Fernando Liendo, and Joaquín L. Brito. "Catalytic Wet Air Oxidation of Aqueous Solutions of Substituted Phenols." Catalysis Letters 106, no. 1-2 (2006): 81–88. http://dx.doi.org/10.1007/s10562-005-9195-2.

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16

Lin, S. H., and S. J. Ho. "Catalytic wet-air oxidation of high strength industrial wastewater." Applied Catalysis B: Environmental 9, no. 1-4 (1996): 133–47. http://dx.doi.org/10.1016/0926-3373(96)90077-6.

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17

Pham Minh, Doan, Pierre Gallezot, Samia Azabou, Sami Sayadi, and Michèle Besson. "Catalytic wet air oxidation of olive oil mill effluents." Applied Catalysis B: Environmental 84, no. 3-4 (2008): 749–57. http://dx.doi.org/10.1016/j.apcatb.2008.06.013.

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18

Kayan, Berkant, A. Murat Gizir, and Ferruh Erdogdu. "Catalytic wet air oxidation of 2-nitrotoluidine and 2,4-dinitrotoluene." Reaction Kinetics and Catalysis Letters 81, no. 2 (2004): 241–49. http://dx.doi.org/10.1023/b:reac.0000019429.16029.ca.

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19

Rocha, Raquel P., Olívia Salomé G. P. Soares, José J. M. Órfão, Manuel Fernando R. Pereira, and José L. Figueiredo. "Heteroatom (N, S) Co-Doped CNTs in the Phenol Oxidation by Catalytic Wet Air Oxidation." Catalysts 11, no. 5 (2021): 578. http://dx.doi.org/10.3390/catal11050578.

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The N, S-co-doping of commercial carbon nanotubes (CNTs) was performed by a solvent-free mechanothermal approach using thiourea. CNTs were mixed with the N, S-dual precursor in a ball-milling apparatus, and further thermally treated under inert atmosphere between 600 and 1000 °C. The influence of the temperature applied during the thermal procedure was investigated. Textural properties of the materials were not significantly affected either by the mechanical step or by the heating phase. Concerning surface chemistry, the developed methodology allowed the incorporation of N (up to 1.43%) and S
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20

Xu, Jun Qiang, Fang Guo, Shu Shu Zou, and Xue Jun Quan. "Optimization of the Catalytic Wet Peroxide Oxidation of Phenol over the Fe/NH4Y Catalyst." Materials Science Forum 694 (July 2011): 640–44. http://dx.doi.org/10.4028/www.scientific.net/msf.694.640.

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The heterogeneous NH4Y zeolite-supported iron catalysts were prepared by incipient wetness impregnation. The catalysis oxidation degradation of phenol was carried over the heterogeneous catalyst in the peroxide catalytic oxidation process. Compared with the homogeneous Fenton process, the Fe/ NH4Y-acid catalyst can effectively degrade contaminants with high catalytic activity and easy catalyst separation from the solution. The phenol removal efficiency could reach 96% in the optimum experimental conditions. These process conditions were as follows: iron content is 5%, reaction time was 60 min,
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21

Eftaxias, A., J. Font, A. Fortuny, A. Fabregat, and F. Stüber. "Catalytic wet air oxidation of phenol over active carbon catalyst." Applied Catalysis B: Environmental 67, no. 1-2 (2006): 12–23. http://dx.doi.org/10.1016/j.apcatb.2006.04.012.

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22

Wang, Jianbing, Wanpeng Zhu, Shaoxia Yang, Wei Wang, and Yunrui Zhou. "Catalytic wet air oxidation of phenol with pelletized ruthenium catalysts." Applied Catalysis B: Environmental 78, no. 1-2 (2008): 30–37. http://dx.doi.org/10.1016/j.apcatb.2007.08.014.

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23

Xu, Jun Qiang, Fang Guo, Jun Li, Xiu Zhi Ran, and Yan Tang. "Synthesis of the Cu/Flokite Catalysts and their Performances for Catalytic Wet Peroxide Oxidation of Phenol." Advanced Materials Research 560-561 (August 2012): 869–72. http://dx.doi.org/10.4028/www.scientific.net/amr.560-561.869.

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The supported Cu/Flokite catalysts were prepared by conventional incipient wetness impregnation. The catalysis oxidation degradation of phenol was carried out in heterogeneous catalyst and H2O2 process. The results indicated that the reaction system with catalyst and hydrogen peroxide was more benefit to degradation of phenol. When the phenol initial concentration was 100 mg/L, the phenol removal over the 2.5%Cu -2.5% Fe/Flokite catalyst could reach 96%. The peroxide catalytic oxidation process over the enhanced heterogeneous catalyst would be a novel technique for the treatment of phenol wast
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24

Stüber, F., J. Font, A. Fortuny, C. Bengoa, A. Eftaxias, and A. Fabregat. "Carbon materials and catalytic wet air oxidation of organic pollutants in wastewater." Topics in Catalysis 33, no. 1-4 (2005): 3–50. http://dx.doi.org/10.1007/s11244-005-2497-1.

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25

Doluda, V. Yu, E. M. Sulman, V. G. Matveeva, et al. "Phenol Catalytic Wet Air Oxidation Over Ru Nanoparticles Formed in Hypercrosslinked Polystyrene." Topics in Catalysis 56, no. 9-10 (2013): 688–95. http://dx.doi.org/10.1007/s11244-013-0028-z.

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26

Zhao, Jun, Yuan Wei, ZongJian Liu, Lin Zhang, Qun Cui, and HaiYan Wang. "Study on heterogeneous catalytic wet air oxidation process of high concentration MDEA-containing wastewater." Chemical Engineering and Processing - Process Intensification 171 (January 2022): 108744. http://dx.doi.org/10.1016/j.cep.2021.108744.

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27

Kim, Kyoung-Hun, and Son-Ki Ihm. "Heterogeneous catalytic wet air oxidation of refractory organic pollutants in industrial wastewaters: A review." Journal of Hazardous Materials 186, no. 1 (2011): 16–34. http://dx.doi.org/10.1016/j.jhazmat.2010.11.011.

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28

Wang, Jianbing, Wanpeng Zhu, Xuwen He, and Shaoxia Yang. "Catalytic wet air oxidation of acetic acid over different ruthenium catalysts." Catalysis Communications 9, no. 13 (2008): 2163–67. http://dx.doi.org/10.1016/j.catcom.2008.04.019.

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29

Cybulski, Andrzej, and Janusz Trawczyński. "Catalytic wet air oxidation of phenol over platinum and ruthenium catalysts." Applied Catalysis B: Environmental 47, no. 1 (2004): 1–13. http://dx.doi.org/10.1016/s0926-3373(03)00327-8.

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30

Minh, Doan Pham, Pierre Gallezot, and Michèle Besson. "Degradation of olive oil mill effluents by catalytic wet air oxidation." Applied Catalysis B: Environmental 63, no. 1-2 (2006): 68–75. http://dx.doi.org/10.1016/j.apcatb.2005.09.009.

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31

Shih, Cheng-Chieh, and Jen-Ray Chang. "Pt/C stabilization for catalytic wet-air oxidation: Use of grafted TiO2." Journal of Catalysis 240, no. 2 (2006): 137–50. http://dx.doi.org/10.1016/j.jcat.2006.03.019.

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32

Béziat, Jean-Christophe, Michèle Besson, Pierre Gallezot, and Sylvain Durécu. "Catalytic Wet Air Oxidation of Carboxylic Acids on TiO2-Supported Ruthenium Catalysts." Journal of Catalysis 182, no. 1 (1999): 129–35. http://dx.doi.org/10.1006/jcat.1998.2352.

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33

Gallezot, Pierre, Stéphane Chaumet, Alain Perrard, and Pascal Isnard. "Catalytic Wet Air Oxidation of Acetic Acid on Carbon-Supported Ruthenium Catalysts." Journal of Catalysis 168, no. 1 (1997): 104–9. http://dx.doi.org/10.1006/jcat.1997.1633.

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34

T. Mohammed, Wadood, and Sama M. Abdullah. "Kinetic Study on Catalytic Wet Air Oxidation of Phenol in a Trickle Bed Reactor." Iraqi Journal of Chemical and Petroleum Engineering 9, no. 2 (2008): 17–23. http://dx.doi.org/10.31699/ijcpe.2008.2.3.

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Kinetics study on the phenol oxidation by catalytic wet air oxidation (CWAO) using CuO.NiO/Al2O3 as heterogeneous catalyst is presented. 4 g/l phenol solution of pH 7.3 was oxidized in a trickle bed reactor with gas flow rate of 80% stochiometric excess (S.E).. In order to verify the proposed kinetics, a series of CWAO experimental tests were done at two temperatures (140 and 160° C), oxygen partial pressures (9 and 12 bar), and weight hourly space velocity (WHSV) (1, 1.5, 2, 2.5, and 3 h-1). According to Power Law, the reaction orders are found to be approximately 1 and 0.5 with respect to ph
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35

Rubalcaba, Alicia, María Eugenia Suárez-Ojeda, Julián Carrera, et al. "Biodegradability enhancement of phenolic compounds by Hydrogen Peroxide Promoted Catalytic Wet Air Oxidation." Catalysis Today 124, no. 3-4 (2007): 191–97. http://dx.doi.org/10.1016/j.cattod.2007.03.037.

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36

Gomes, H. T., Ph Serp, Ph Kalck, J. L. Figueiredo, and J. L. Faria. "Carbon supported platinum catalysts for catalytic wet air oxidation of refractory carboxylic acids." Topics in Catalysis 33, no. 1-4 (2005): 59–68. http://dx.doi.org/10.1007/s11244-005-2505-5.

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37

Dobrynkin, N. M., M. V. Batygina, A. S. Noskov, et al. "Catalysts Ru–CeO2/Sibunit for catalytic wet air oxidation of aniline and phenol." Topics in Catalysis 33, no. 1-4 (2005): 69–76. http://dx.doi.org/10.1007/s11244-005-2507-3.

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38

Gallezot, Pierre, Nathalie Laurain, and Pascal Isnard. "Catalytic wet-air oxidation of carboxylic acids on carbon-supported platinum catalysts." Applied Catalysis B: Environmental 9, no. 1-4 (1996): L11—L17. http://dx.doi.org/10.1016/0926-3373(96)90070-3.

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39

Centi, Gabriele, Siglinda Perathoner, Teresa Torre, and Maria Grazia Verduna. "Catalytic wet oxidation with H2O2 of carboxylic acids on homogeneous and heterogeneous Fenton-type catalysts." Catalysis Today 55, no. 1-2 (2000): 61–69. http://dx.doi.org/10.1016/s0920-5861(99)00226-6.

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40

Zhao, Shun, Xiaohong Wang, and Mingxin Huo. "Catalytic wet air oxidation of phenol with air and micellar molybdovanadophosphoric polyoxometalates under room condition." Applied Catalysis B: Environmental 97, no. 1-2 (2010): 127–34. http://dx.doi.org/10.1016/j.apcatb.2010.03.032.

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41

Garcia, J., H. T. Gomes, P. Serp, P. Kalck, J. L. Figueiredo, and J. L. Faria. "Platinum catalysts supported on MWNT for catalytic wet air oxidation of nitrogen containing compounds." Catalysis Today 102-103 (May 2005): 101–9. http://dx.doi.org/10.1016/j.cattod.2005.02.013.

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42

Iojoiu, Eduard Emil, Emmanuel Landrivon, Henrik Raeder, Eddy G. Torp, Sylvain Miachon, and Jean-Alain Dalmon. "The “Watercatox” process: Wet air oxidation of industrial effluents in a catalytic membrane reactor." Catalysis Today 118, no. 1-2 (2006): 246–52. http://dx.doi.org/10.1016/j.cattod.2006.01.045.

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43

Besson, Michèle, and Pierre Gallezot. "Stability of ruthenium catalysts supported on TiO2 or ZrO2 in catalytic wet air oxidation." Topics in Catalysis 33, no. 1-4 (2005): 101–8. http://dx.doi.org/10.1007/s11244-005-2517-1.

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44

Bernardi, Marco, Didier Cretenot, Stéphane Deleris, Claude Descorme, Julien Chauzy, and Michèle Besson. "Performances of soluble metallic salts in the catalytic wet air oxidation of sewage sludge." Catalysis Today 157, no. 1-4 (2010): 420–24. http://dx.doi.org/10.1016/j.cattod.2010.01.030.

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45

Dhaouadi, Anissa, and Nafaâ Adhoum. "Heterogeneous catalytic wet peroxide oxidation of paraquat in the presence of modified activated carbon." Applied Catalysis B: Environmental 97, no. 1-2 (2010): 227–35. http://dx.doi.org/10.1016/j.apcatb.2010.04.006.

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46

Zhang, Yang, Dongliu Li, Yang Chen, Xiaohong Wang, and Shengtian Wang. "Catalytic wet air oxidation of dye pollutants by polyoxomolybdate nanotubes under room condition." Applied Catalysis B: Environmental 86, no. 3-4 (2009): 182–89. http://dx.doi.org/10.1016/j.apcatb.2008.08.010.

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47

Levasseur, Benoît, Benoist Renard, Jacques Barbier Jr., and Daniel Duprez. "Catalytic wet air oxidation of oleic acid on ceria-supported platinum catalyst.effect of pH." Reaction Kinetics and Catalysis Letters 87, no. 2 (2006): 269–79. http://dx.doi.org/10.1007/s11144-006-0034-2.

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48

Archila, Katherine, Ana María Campos, Lorena Lugo, et al. "Influence of the Active Phase (Fe, Ni, and Ni–Fe) of Mixed Oxides in CWAO of Crystal Violet." Catalysts 10, no. 9 (2020): 1053. http://dx.doi.org/10.3390/catal10091053.

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The catalytic oxidation of aqueous crystal violet (CV) solutions was investigated using Ni and Fe catalysts supported over Mg–Al oxides synthesized by the autocombustion method. The influence of temperature, loading, and selectivity were studied in the catalytic wet air oxidation (CWAO) of CV. The kind of metal had an important contribution in the redox process as significant differences were observed between Fe, Ni, and their mixtures. The catalysts with only Fe as active phase were more efficient for the oxidation of CV under normal conditions (T = 25 °C and atmospheric pressure) compared to
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49

Mei, Jian Guo, Shao Ming Yu, and Jun Cheng. "Heterogeneous catalytic wet peroxide oxidation of phenol over delaminated Fe–Ti-PILC employing microwave irradiation." Catalysis Communications 5, no. 8 (2004): 437–40. http://dx.doi.org/10.1016/j.catcom.2004.05.009.

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50

Juhola, Riikka, Anne Heponiemi, Sari Tuomikoski, et al. "Preparation of Granulated Biomass Carbon Catalysts—Structure Tailoring, Characterization, and Use in Catalytic Wet Air Oxidation of Bisphenol A." Catalysts 11, no. 2 (2021): 251. http://dx.doi.org/10.3390/catal11020251.

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New carbonized biomass–metakaolin (PSD/MK_Fe) granular composite catalyst materials were manufactured for the catalytic wet air oxidation (CWAO) of bisphenol A (BPA). These catalysts were characterized using different analytical and spectroscopic techniques, and results showed that the catalysts’ final properties were influenced by the addition of metakaolin (MK), polyvinyl alcohol, boric acid, and iron. Under the optimal CWAO experimental conditions (p: 20 bar, T: 160 °C, initial pH: 5–6, c[catalyst]: 1.0 g/L), nearly complete BPA conversion (>98%) and total organic carbon (TOC) conversion
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