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Journal articles on the topic 'Heterometallic compounds'

Author: Grafiati
Published: 4 June 2021
Last updated: 16 February 2022

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1

Ávila-Torres, Yenny, Lázaro Huerta, and Noráh Barba-Behrens. "XPS-Characterization of Heterometallic Coordination Compounds with Optically Active Ligands." Journal of Chemistry 2013 (2013): 1–9. http://dx.doi.org/10.1155/2013/370637.

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The heterometallic optical complexes [Cu2Co(S,S(+)cpse)3(H2O)3]·4H2O (1) and [Cu2Ni(S,S(+)cpse)3(H2O)3]·10H2O (2) were obtained from the mononuclear copper(II) compound by the addition of nickel(II) or cobalt(II) chlorides, where (H2cpse) is the acetyl amino alcohol derivative N-[2-hydroxy-1(R)-methyl-2(R)-phenylethyl]-N-methylglycine. In comparison with the homotrinuclear copper(II) compound [Cu3(S,S(+)cpse)3(H2O)3]·8H2O reported previously, the substitution of a copper(II) atom by one cobalt(II) ion gave place to a heterotrinuclear compound1, which presents ferromagnetic-antiferromagnetic be
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2

Sidorov, Alexey A., Mikhail A. Kiskin, Alexander E. Baranchikov, Vladimir K. Ivanov, and Igor L. Eremenko. "Methods for Synthesis of Molecular Materials with Unique Physical Properties." Vestnik RFFI, no. 2 (June 25, 2019): 82–100. http://dx.doi.org/10.22204/2410-4639-2019-102-02-82-100.

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The authors discovered and investigated new types of stable heterometallic carboxylate complexes in which divalent transition metal atoms of the 4th period of the Periodic Table of Chemical Elements (V, Co, Ni, Cu, Zn) combine with atoms of lithium, magnesium, calcium or rare earth elements. These polynuclear heterometallic compounds retain their structure under conditions when the homometallic compounds of these transition metals decompose to mononuclear complexes. The different metals combination in one molecule allows us to use the obtained heterometallic compounds for producing disperse an
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3

Burmakina, Galina V., Anatoly I. Rubaylo, Vladimir P. Kirin, and Vladimir A. Maksakov. "Redox Properties of Heterometallic Osmium Cluster Compounds." Journal of Siberian Federal University. Chemistry 9, no. 4 (2016): 483–95. http://dx.doi.org/10.17516/1998-2836-2016-9-4-483-495.

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4

Kenfack, Patrice, Emmanuel Wenger, Slimane Dahaoui, et al. "Dynamic porous property in a new heterometallic supramolecular compound." Acta Crystallographica Section A Foundations and Advances 70, a1 (2014): C1474. http://dx.doi.org/10.1107/s2053273314085258.

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Supramolecular compounds have attracted considerable interest to chemists, physicists and materials scientists due to their fascinating structures and potential applications as porosity [1-3] but one of the most appealing aims today, is to build multifunctional compounds. We are interested to rationalize the synthesis of porous heterometallic compounds by self- assembly via hydrogen bonds. In this communication, we present a stacked 2D Catena-{Co(amp)3Cr(ox)3.6H2O} (amp = 2-picolylamine, ox=oxalate). It is built by layers in which both (Co(amp)3+ (D) and Cr(ox)3- ( A)) ionic units are linked i
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5

Dou, Ming-Yu, and Jing Lu. "A novel octanuclear nickel(II)–molybdenum(VI) heterometallic cluster based on the salicylhydroxamate ligand." Acta Crystallographica Section C Structural Chemistry 72, no. 2 (2016): 161–65. http://dx.doi.org/10.1107/s2053229616000243.

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Salicylhydroxamic acid (H3shi) is known for its strong coordination ability and multiple coordination modes, and can easily coordinate to metal cations to form compounds with five- or six-membered rings, as well as mono-, di- and multinuclear compounds with interesting structures having potential applications in organic chemistry, coordination chemistry, and the materials and biological sciences. A novel octanuclear nickel(II)–molybdenum(VI) heterometallic cluster based on the salicylhydroxamate ligand, namely di-μ3-acetato-di-μ2-acetato-di-μ3-hydroxido-di-μ3-oxido-tetraoxidooctakis(pyridine-κ
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6

Massai, Lara, Jacob Fernández-Gallardo, Annalisa Guerri, et al. "Design, synthesis and characterisation of new chimeric ruthenium(ii)–gold(i) complexes as improved cytotoxic agents." Dalton Transactions 44, no. 24 (2015): 11067–76. http://dx.doi.org/10.1039/c5dt01614b.

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7

Fang, Ming, and Bin Zhao. "Ln-Ag heterometallic coordination polymers." Reviews in Inorganic Chemistry 35, no. 2 (2015): 81–113. http://dx.doi.org/10.1515/revic-2014-0009.

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AbstractThe last few years have seen an increasing interest in the study of lanthanide-silver (Ln-Ag) heterometallic coordination polymers due to their potential applications. It has led to intense activity of chemists to produce Ln-Ag heterometallic coordination polymers and investigate their properties. In this review, we summarize recent research development in the fascinating and challenging field of Ln-Ag heterometallic coordination polymers. This review covers 182 Ln-Ag heterometallic coordination polymers, which are categorized by the kind of ligand as N-heterocyclic carboxylate ligands
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8

Fernández-Gallardo, Jacob, Benelita T. Elie, Tanmoy Sadhukha, et al. "Heterometallic titanium–gold complexes inhibit renal cancer cells in vitro and in vivo." Chemical Science 6, no. 9 (2015): 5269–83. http://dx.doi.org/10.1039/c5sc01753j.

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9

Schmidt, Sebastian F. M., Marcel P. Merkel, George E. Kostakis, Gernot Buth, Christopher E. Anson, and Annie K. Powell. "SMM behaviour and magnetocaloric effect in heterometallic 3d–4f coordination clusters with high azide : metal ratios." Dalton Transactions 46, no. 45 (2017): 15661–65. http://dx.doi.org/10.1039/c7dt03149a.

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10

Jayasinghe, Ashini S., Maurice K. Payne, and Tori Z. Forbes. "Synthesis and characterization of heterometallic uranyl pyridinedicarboxylate compounds." Journal of Solid State Chemistry 254 (October 2017): 25–31. http://dx.doi.org/10.1016/j.jssc.2017.07.002.

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11

Banerjee, Santanu, Thomas J. Emge, and John G. Brennan. "Heterometallic Ln/Hg Compounds with Fluorinated Thiolate Ligands." Inorganic Chemistry 43, no. 20 (2004): 6307–12. http://dx.doi.org/10.1021/ic049215q.

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12

Li, Ming-xue, Yan Bai, Bing-guang Zhang, Chun-ying Duan, Jian Xu, and Qing-jin Meng. "Heterometallic Compounds Assembled from Ferrocene-Containing Bisthiosemicarbazone Clips." Inorganic Chemistry 44, no. 15 (2005): 5459–66. http://dx.doi.org/10.1021/ic0502067.

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13

Jacob, Klaus, Piero Zanello, Frank Voigt, and Marco Fontani. "On Heterometallic Ferrocenyl Compounds of Gold and Platinum." Monatshefte für Chemie / Chemical Monthly 129, no. 12 (1998): 1213–23. http://dx.doi.org/10.1007/pl00010133.

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14

Kuwamura, Naoto, Yoshinari Kurioka, Nobuto Yoshinari, and Takumi Konno. "Heterogeneous catalytic water oxidation controlled by coordination geometries of copper(ii) centers with thiolato donors." Chemical Communications 54, no. 76 (2018): 10766–69. http://dx.doi.org/10.1039/c8cc06238b.

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Heterometallic coordination compounds containing a thiolato dicopper(ii) core increase heterogeneous electrocatalytic activities for water oxidation in proportion to the numbers of vacant dicopper(ii) coordination sites.
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15

Chen, Yong, Qiao-Qiao Long, Zhao-Bo Hu, et al. "Synthesis, crystal structures and magnetic properties of a series of pentanuclear heterometallic [CuII3LnIII2] (Ln = Ho, Dy, and Gd) complexes containing mixed organic ligands." New Journal of Chemistry 43, no. 21 (2019): 8101–8. http://dx.doi.org/10.1039/c9nj00892f.

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16

Muravieva, Viktoria K., Yakov M. Gayfulin, Maxim R. Ryzhikov, et al. "Mixed-metal clusters with a {Re3Mo3Se8} core: from a polymeric solid to soluble species with multiple redox transitions." Dalton Transactions 47, no. 10 (2018): 3366–77. http://dx.doi.org/10.1039/c7dt03571c.

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17

Melník, Milan, Peter Mikuš, and Clive Holloway. "Crystalographic and structural characterization of heterometallic platinum compounds. Part III: heterotrinuclear compounds." Open Chemistry 11, no. 6 (2013): 827–900. http://dx.doi.org/10.2478/s11532-013-0226-3.

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AbstractThis review article includes over three hundred and sixty heterotrinuclear platinum complexes of the composition Pt2M (205 examples), PtM2 (132 examples) and PtMM (24 examples). The heterometals include the non-transition and transition metals. Three metal atoms form a wide variability of frameworks: M3 triangular, dicapped M3 triangular, V shaped M3, M3 linear, five-, six- and seven- metallocycles and unique structures of which triangular and linear are the most common. This has led to a rich chemistry of platinum not only from variability of metals, but also from their framework and
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18

Jonas, Klaus, Gerd Koepe, and Carl Krüger. "Heterometallic Dinuclear Complexes by Ethene Displacement with Grignard Compounds or Diorganomagnesium Compounds." Angewandte Chemie International Edition in English 25, no. 10 (1986): 923–25. http://dx.doi.org/10.1002/anie.198609231.

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19

Melnik,, Milan, Zuzana Baloghova,, Iveta Ondrejkovicova,, and Vlasta Vancova,. "Crystallographic and Structural Analysis of Iron Heterometallic Compounds. Part I. Heterobinuclear Compounds." Reviews in Inorganic Chemistry 26, no. 1-2-3 (2006): 1–365. http://dx.doi.org/10.1515/revic.2006.26.1-2-3.1.

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20

Melnik,, Milan, Iveta Ondrejkovicová,, Dusan Mikloš,, and Peter Segl'a,. "Crystallographic and Structural Analysis of Iron Heterometallic Compounds Part II. Heterotrinuclear Compounds." Reviews in Inorganic Chemistry 27, no. 2-3-4 (2007): 67–317. http://dx.doi.org/10.1515/revic.2007.27.2-3-4.67.

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21

Melnik, Milan, Iveta Ondrejkovicova, and Marian Koman. "Crystallographic and Structural Analysis of Iron Heterometallic Compounds Part IV: Heteropentameric Compounds." Reviews in Inorganic Chemistry 30, no. 1-2 (2010): 1–112. http://dx.doi.org/10.1515/revic.2010.30.1-2.1.

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22

Müller, Susanne, and Ulf Thewalt. "Polynuclear Cadmium Compounds Containing cis-[Co(en)2(OH)2]+ Ligands." Collection of Czechoslovak Chemical Communications 62, no. 2 (1997): 257–64. http://dx.doi.org/10.1135/cccc19970257.

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Polynuclear heterometallic compounds containing cobalt and cadmium were prepared by the reaction of CdCl2 with salts of the cis-[Co(en)2(H2O)2]3+ cation. X-Ray analyses of the tetranuclear Co2Cd2 complex [Cd2(mi-Cl)Cl4{(OH)2Co(en)2}2]ClO4 (1) and the polymeric compound [[Cd(mi-Cl)-(H2O)2{(OH)2Co(en)2}]Cl2]n (2) confirm that the [Co(en)2(OH)2]+ groups act as chelating ligands toward the Cd atoms. The Cd coordination octahedra are connected by a face in 1 and by corners in 2.
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23

Li, Xiao-Lei, Fan-Yong Min, Chao Wang, Shuang-Yan Lin, Zhiliang Liu, and Jinkui Tang. "[LnIII–MnII–LnIII] heterometallic compounds: rare linear SMMs with divalent manganese ions." Dalton Transactions 44, no. 7 (2015): 3430–38. http://dx.doi.org/10.1039/c4dt03713h.

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The perfectly linear metal array and the introduction of strong magnetic anisotropy Tb<sup>III</sup>and Dy<sup>III</sup>result in new trinuclear heterometallic Ln<sup>III</sup>–Mn<sup>II</sup>–Ln<sup>III</sup>SMMs with high energy barriers.
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24

Blake, Alexander J., Rocío Donamaría, Eduardo J. Fernández, et al. "Heterometallic gold(i)–thallium(i) compounds with crown thioethers." Dalton Transactions 42, no. 32 (2013): 11559. http://dx.doi.org/10.1039/c3dt51334c.

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25

Dubraja, Lidija Androš, Dubravka Matković-Čalogović, and Pavica Planinić. "Crystal disassembly and reassembly of heterometallic NiII–TaVoxalate compounds." CrystEngComm 17, no. 9 (2015): 2021–29. http://dx.doi.org/10.1039/c4ce02516d.

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26

Aguilà, David, Olivier Roubeau, and Guillem Aromí. "Designed polynuclear lanthanide complexes for quantum information processing." Dalton Transactions 50, no. 35 (2021): 12045–57. http://dx.doi.org/10.1039/d1dt01862k.

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The design of dissymmetric organic ligands has been exploited to produce heterometallic dinuclear and trinuclear lanthanide-based coordination compounds with the requirements to act as logical quantum gates for spin-based quantum computing.
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27

Chakraborty, Anindita, Albert Escuer, Joan Ribas, and Tapas Kumar Maji. "A discrete CuII6 cluster and a 3D MnII–CuII framework based on assembly of Mn2Cu4 clusters: synthesis, structure and magnetic properties." Dalton Transactions 45, no. 39 (2016): 15523–31. http://dx.doi.org/10.1039/c6dt03094g.

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Two new magnetic metal–organic coordination compounds, a 0D Cu<sub>6</sub> cluster and a 3D heterometallic framework with MnII2CuII4 secondary building units are synthesized. Detailed magnetic studies are performed with proper magneto-structural correlation.
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28

Liu, Da-Peng, Jun-Bo Peng, Xin-Ping Lin, et al. "Myo-inositol supported heterometallic Dy24M2 (M = Ni, Mn) cages." CrystEngComm 16, no. 25 (2014): 5527–30. http://dx.doi.org/10.1039/c4ce00362d.

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Two heterometallic cage-like Dy<sub>24</sub>M<sub>2</sub> (M = Ni, Mn) cluster compounds have been synthesized through self-assembly of the metal ions and the myo-inositol ligand templated by three ClO<sub>4</sub><sup>−</sup> anions.
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29

Holloway, Clive, and Milan Melnik. "Crystallographic and structural characterisation of heterometallic platinum compounds: Part I. Heterobinuclear Pt compounds." Open Chemistry 9, no. 4 (2011): 501–48. http://dx.doi.org/10.2478/s11532-011-0054-2.

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AbstractThis review covers almost 290 heterobinuclear Pt derivatives. When the heterometals (M) are non transition and the binuclear are found both with and without a metal to metal bond. Where M is a transition metal or actinide, only those with a metal-metal bond have been included here. There are thirteen non-transition metals (Sn, Hg, Ge, Sb, Tl, Zn, Pb, Cd, Na, K, Ga, Ca and In). The shortest Pt-M bond distance is 235.2(1) (Pt-Ge). There are eighteen transition metals (Fe, W, Rh, Re, Pd, Ag, Ir, Mo, Mn, Re, Co, Cu, Cr, Au, Ni, Ti, Ta and V). The shortest Pt-M bond distance is 249.5(2) pm
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30

Xia, Chengcai, Gang Xiong, Lixin You, Baoyi Ren, Shuju Wang, and Yaguang Sun. "Synthesis, Crystal Structure, and Photoluminescent Properties of a Series of LnIII–CuI Heterometallic Coordination Polymers Based on Cu4I3 Clusters and Ln–ina Rod Units." Australian Journal of Chemistry 70, no. 8 (2017): 943. http://dx.doi.org/10.1071/ch17076.

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A novel series of LnIII–CuI heterometallic coordination polymers (HCPs) {[Ln2Cu4I3(ina)7(DMA)2]n·nDMA, Ln = La (1), Ce (2), Pr (3) Nd (4), Sm (5), Eu (6), Gd (7), Tb (8), Dy (9) Ho (10), Er (11), Yb (12), Hina = isonicotinic acid, DMA = N,N-dimethylacetamide} were synthesised by a solvothermal reaction. The structures of compounds 1–12 were characterised by elemental analysis, FT-IR spectroscopy, thermogravimetric analysis, and powder X-ray diffraction. Single crystal X-ray diffraction studies revealed that 1–12 are isomorphous and are 3D heterometallic coordination polymers based on inorganic
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31

Minkin, V. I., A. A. Starikova, and A. G. Starikov. "Quantum chemical modeling of magnetically bistable metal coordination compounds. Synchronization of spin crossover, valence tautomerism and charge transfer induced spin transition mechanisms." Dalton Transactions 45, no. 30 (2016): 12103–13. http://dx.doi.org/10.1039/c6dt01687a.

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32

Ciupa, Aneta, Mirosław Mączka, Anna Gągor, Adam Pikul, and Maciej Ptak. "Synthesis and characterization of novel niccolites [(CH3)2NH2][FeIIIMII(HCOO)6] (MII = Zn, Ni, Cu)." Dalton Transactions 44, no. 29 (2015): 13234–41. http://dx.doi.org/10.1039/c5dt01608h.

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We report the synthesis, structural, magnetic, Raman and IR studies of novel niccolite-type heterometallic [(CH<sub>3</sub>)<sub>2</sub>NH<sub>2</sub>][Fe<sup>III</sup>M<sup>II</sup>(HCOO)<sub>6</sub>] compounds (M<sup>II</sup> = Ni, Zn and Cu). The Ni and Cu compounds order ferromagnetically at 42 and 28.5 K, respectively. The monoclinic Cu member exhibits different structural changes on cooling than the trigonal Zn and Ni compounds.
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33

O’Connor, Helen M., Sergio Sanz, Aaron J. Scott, et al. "[CrIII8NiII6]n+ Heterometallic Coordination Cubes." Molecules 26, no. 3 (2021): 757. http://dx.doi.org/10.3390/molecules26030757.

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Three new heterometallic [CrIII8NiII6] coordination cubes of formulae [CrIII8NiII6L24(H2O)12](NO3)12 (1), [CrIII8NiII6L24(MeCN)7(H2O)5](ClO4)12 (2), and [CrIII8NiII6L24Cl12] (3) (where HL = 1-(4-pyridyl)butane-1,3-dione), were synthesised using the paramagnetic metalloligand [CrIIIL3] and the corresponding NiII salt. The magnetic skeleton of each capsule describes a face-centred cube in which the eight CrIII and six NiII ions occupy the eight vertices and six faces of the structure, respectively. Direct current magnetic susceptibility measurements on (1) reveal weak ferromagnetic interactions
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34

Nassar, A. M., E. F. Abo Zeid, A. M. Elseman, and N. F. Alotaibi. "A novel heterometallic compound for design and study of electrical properties of silver nanoparticles-decorated lead compounds." New Journal of Chemistry 42, no. 2 (2018): 1387–95. http://dx.doi.org/10.1039/c7nj03682e.

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35

Mazzuca, Lidia, Laura Cañadillas-Delgado, J. Alberto Rodríguez-Velamazán, et al. "Magnetic Structures of Heterometallic M(II)–M(III) Formate Compounds." Inorganic Chemistry 56, no. 1 (2016): 197–207. http://dx.doi.org/10.1021/acs.inorgchem.6b01866.

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36

Popovic, Jasminka, Lidija Androš, Marijana Jurić, Krešimir Molčanov, and Pavica Planinić. "From Oxalate-based Heterometallic Compounds to nanocrystalline Ca-Cr Oxides." Acta Crystallographica Section A Foundations and Advances 70, a1 (2014): C907. http://dx.doi.org/10.1107/s2053273314090925.

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"Metal-organic coordination systems may exert a variety of specific properties including porosity, conductivity, or luminescence and have potential applications in various fields, from heterogeneous catalysis to supramolecular magnetism. Recently, these systems are exploited as molecular precursors by thermal decomposition for the preparation of mixed-metal oxide [1-3]. Since this synthetic route is relatively new and unexplored, there are few reported examples of nanomaterials obtained in this way. The heterobimetallic polymeric compounds [CaCr2(bpy)2(C2O4)4]·0.83H2O}n (1) and {[CaCr2(phen)2(
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37

Melnik, Milan, Peter Mikus, and Clive E. Holloway. "ChemInform Abstract: Crystallographic and Structural Characterization of Heterometallic Platinum Compounds. Part III: Heterotrinuclear Compounds." ChemInform 46, no. 16 (2015): no. http://dx.doi.org/10.1002/chin.201516304.

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38

Xu, Yun, Luo Feng, and Ji-Min Zheng. "Syntheses, Structures, and Magnetic Properties of a Series of Heterotri-, Tetra- and Pentanuclear LnIII–CoII Compounds." Polymers 11, no. 2 (2019): 196. http://dx.doi.org/10.3390/polym11020196.

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Three types of Ln(III)–Co(II) heterometallic compounds, LnCo2(L1)7(bipy)2 (Ln = Pr-1, Eu-2, Sm-3, Gd-4, Tb-5, Dy-6) (L1 = 4-chlorobenzoate, bipy = 2,2′-bipyridine), Ln2Co2(L2)10(bipy)2 (Ln = Sm-7, Gd-8, Tb-9, Dy-10, Ho-11, Er-12, Yb-13), (L2 = 2,4-dichlorobenzoate, bipy = 2,2′-bipyridine, phen = 1,10-phenanthroline), and Ln2Co3(L1)12(bipy)2 (Ln = Ho-14, Er-15, Yb-16), were synthesized under hydrothermal conditions and characterized by single crystal X-ray diffraction, IR spectroscopy and magnetic measurements. Structural analyses revealed that 14–16 take on a unique linear pentanuclear structu
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39

Kanižaj, Lidija, Lidija Androš Dubraja, Filip Torić, et al. "Dimensionality controlled by light exposure: 1D versus 3D oxalate-bridged [CuFe] coordination polymers based on an [Fe(C2O4)3]3− metallotecton." Inorganic Chemistry Frontiers 6, no. 11 (2019): 3327–35. http://dx.doi.org/10.1039/c9qi00926d.

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The studied heterometallic [CuFe] compounds, based on an [Fe(C<sub>2</sub>O<sub>4</sub>)<sub>3</sub>]<sup>3−</sup> building block and containing a 3D network or 1D ladder-like chains, were synthesized depending on whether the test tube with the same reaction layers was exposed to daylight or not.
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40

Holloway, Clive E., and Milan Melnik. "ChemInform Abstract: Crystallographic and Structural Characterization of Heterometallic Platinum Compounds. Part 1. Heterobinuclear Pt Compounds." ChemInform 42, no. 37 (2011): no. http://dx.doi.org/10.1002/chin.201137225.

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41

Shankar, Krapa, Alexander M. Kirillov, and Jubaraj B. Baruah. "Bottom up synthesis for homo- and heterometallic 2,3-pyridinedicarboxylate coordination compounds." Polyhedron 102 (December 2015): 521–29. http://dx.doi.org/10.1016/j.poly.2015.10.031.

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42

Barbul, Ioana, Richard A. Varga, Kieran C. Molloy, and Cristian Silvestru. "Di(imino)aryltin(iv) dichlorides as tectons for heterometallic coordination compounds." Dalton Transactions 42, no. 43 (2013): 15427. http://dx.doi.org/10.1039/c3dt52022f.

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43

Figuerola, Albert, Joan Ribas, Xavier Solans, Merce Font-Bardía, Miguel Maestro, and Carmen Diaz. "One Dimensional 3d–4f Heterometallic Compounds: Synthesis, Structure and Magnetic Properties." European Journal of Inorganic Chemistry 2006, no. 9 (2006): 1846–52. http://dx.doi.org/10.1002/ejic.200500999.

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44

Wang, Xiufeng, Hongdao Li, Juan Sun, Meng Yang, Cun Li, and Licun Li. "LnIII–CoII heterometallic chains based on pyridine substituted nitronyl nitroxides." New Journal of Chemistry 41, no. 8 (2017): 2973–79. http://dx.doi.org/10.1039/c6nj03849b.

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45

Petrus, R., A. Drąg-Jarząbek, J. Utko, T. Lis, and P. Sobota. "Transformation of molecular compounds with Ba(Sr)/Al/Si and Ca(Sr, Ba)/Ti(Zr, Hf)/Si heteroelements as new efficient route to metal silicate materials." Dalton Transactions 48, no. 13 (2019): 4283–98. http://dx.doi.org/10.1039/c8dt03796e.

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46

Konchenko, Sergey N. "Reductive Approach to the Synthesis of the Molecular Lanthanide Polypnictide Complexes." Vestnik RFFI, no. 2 (June 25, 2019): 101–12. http://dx.doi.org/10.22204/2410-4639-2019-102-02-101-112.

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In spite of the vigorous development during the last few decades, the coordination chemistry of lanthanides (Ln) is 95% still the chemistry of complexes with O- and N-donor ligands. The compounds with the Ln—E bond (E is a heavy element of the group 15th or 16th) up to now are considered as unconventional or exotic. Recently the fruitful “reductive approach” to this kind of compounds has been developed. The approach involves the performing of reactions between the strong reductants (Ln(II) complexes) and inorganic or organometallic compounds of the main group heavy elements. This paper is focu
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47

Geetharani, K., Shubhankar Kumar Bose, and Sundargopal Ghosh. "Heterometallic cubane-type clusters containing group 13 and 16 elements." Pure and Applied Chemistry 84, no. 11 (2012): 2233–41. http://dx.doi.org/10.1351/pac-con-11-10-17.

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Heterometallic cubane-type clusters were synthesized from the reaction of group 6 and 8 metallaboranes using transition-metal carbonyl compounds. Structural and spectroscopic study revealed the existence of novel “capped-cubane” geometry. In addition, the crystal structure of these clusters distinctly confirms the presence of boride unit as one of the vertices. These clusters possess 60 cluster valence electrons (cve) and six metal–metal bonds. A plausible pathway for the formation of ruthenium-capped cubane has been described.
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48

Han, Lizhi, Longyi Jin, Enbo Wang, and Zhongmin Su. "Synthesis and characterization of two isostructural 3d–4f coordination compounds based on pyridine-2,6-dicarboxylic acid and 4,4′-bipyridine." Acta Crystallographica Section C Structural Chemistry 75, no. 6 (2019): 723–27. http://dx.doi.org/10.1107/s2053229619006004.

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The design and synthesis of 3d–4f heterometallic coordination polymers have attracted much interest due to the intriguing diversity of their architectures and topologies. Pyridine-2,6-dicarboxylic acid (H2pydc) has a versatile coordination mode and has been used to construct multinuclear and heterometallic compounds. Two isostructural centrosymmetric 3d–4f coordination compounds constructed from pyridine-2,6-dicarboxylic acid and 4,4′-bipyridine (bpy), namely 4,4′-bipyridine-1,1′-diium diaquabis(μ2-pyridine-2,6-dicarboxylato)tetrakis(pyridine-2,6-dicarboxylato)bis[4-(pyridin-4-yl)pyridinium]co
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49

Melník, Milan, Peter Mikuš, and Clive Holloway. "Crystallographic and structural characterization of heterometallic platinum compounds part IV: heterotetranuclear clusters." Open Chemistry 11, no. 12 (2013): 1902–53. http://dx.doi.org/10.2478/s11532-013-0320-6.

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AbstractThis review includes over two hundred heterotetranuclear platinum clusters. The clusters are of the compositions Pt3M, Pt3M2, PtM3, Pt′2MM′, PtM2M′ and PtMM′M”. There are twenty five different M atoms (transition and non-transition) as a partner(s) of platinum. The four metal atoms are found in a tetrahedral, planar-rhombohedral, butterfly, spited-triangular, cubane, eight — and oligo-membered rings and a unique structures. There is wide variety of the ligands from uni to- undecadentate, with the most common P and C donor sites. The shortest Pt-M (transition) versus Pt-M (non-transitio
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Li, Hongdao, Juan Sun, Meng Yang, et al. "Functionalized Nitronyl Nitroxide Biradicals for the Construction of 3d–4f Heterometallic Compounds." Inorganic Chemistry 57, no. 16 (2018): 9757–65. http://dx.doi.org/10.1021/acs.inorgchem.7b03186.

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