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Journal articles on the topic 'Hexatrienes'

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1

Jing, Naiyong, and David M. Lemal. "The perfluoro-1,3,5-hexatrienes." Journal of Organic Chemistry 59, no. 7 (April 1994): 1844–48. http://dx.doi.org/10.1021/jo00086a040.

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2

JING, N., and D. M. LEMAL. "ChemInform Abstract: The Perfluoro-1,3,5-hexatrienes." ChemInform 25, no. 36 (August 19, 2010): no. http://dx.doi.org/10.1002/chin.199436093.

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3

McDiarmid, Ruth, A. Sabljic, and J. P. Doering. "Valence transitions in cis- and trans-hexatrienes." Journal of the American Chemical Society 107, no. 4 (February 1985): 826–29. http://dx.doi.org/10.1021/ja00290a016.

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4

Aumann, Rudolf. "1-Metalla-1,3,5-hexatrienes and Related Compounds." European Journal of Organic Chemistry 2000, no. 1 (January 2000): 17–31. http://dx.doi.org/10.1002/(sici)1099-0690(200001)2000:1<17::aid-ejoc17>3.0.co;2-t.

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5

Hrabal, R., Z. Chvátal, and V. Dědek. "Thermal and UV-induced isomerization of fluorinated hexatrienes." Journal of Fluorine Chemistry 63, no. 3 (August 1993): 185–91. http://dx.doi.org/10.1016/s0022-1139(00)80562-x.

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6

Chattopadhyay, Anjan, Praveen Saini, and Riddhish Pandharkar. "Exploring the isomerization paths of push–pull hexatrienes." RSC Advances 6, no. 91 (2016): 88433–42. http://dx.doi.org/10.1039/c6ra16812d.

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The first photo-excited singlet state of all-trans donor (amine), acceptor (cyano)-substituted hexatriene forms donor side-twisted minima and its passage towards the cis–trans–trans isomer is characterized by an S0/S1 conical intersection.
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7

Hinrich, P., J. A. van der Hart, and H. J. C. Jacobs. "Photochemistry of planar E-hexatrienes: an AM1 study." Journal of Photochemistry and Photobiology A: Chemistry 80, no. 1-3 (May 1994): 121–24. http://dx.doi.org/10.1016/1010-6030(93)01013-r.

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8

Koßmehl, Gerhard, and Detlev Budwill. "Flüssig-kristalline Verbindungen aus der Thiophenreihe, Teil 2. Flüssig-kristalline Azomethine, Azine und Vinylene / Liquid Crystalline Compounds in the Thiophene Series 2. Liquid Crystalline Azomethines, Azines and Vinylenes." Zeitschrift für Naturforschung B 40, no. 9 (September 1, 1985): 1199–213. http://dx.doi.org/10.1515/znb-1985-0917.

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Azomethines, azines, vinylenes and hexatrienes containing thiophene and thieno[3,2-b]- thiophene systems have been synthesized and characterisized by their IR and 1H NMR spectra. The liquid crystalline properties of these compounds have been studied thermically and optically by their textures and are compared with the analogous compounds having benzene rings.
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9

Aumann, Rudolf. "ChemInform Abstract: 1-Metalla-1,3,5-hexatrienes and Related Compounds." ChemInform 31, no. 10 (June 10, 2010): no. http://dx.doi.org/10.1002/chin.200010250.

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10

Cao, Xiao-Ping, Tze-Lock Chan, Hak-Fun Chow, and Jingren Tu. "Stereoselective synthesis of substituted 1,3,5-hexatrienes from diallylic sulfones." Journal of the Chemical Society, Chemical Communications, no. 12 (1995): 1297. http://dx.doi.org/10.1039/c39950001297.

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11

Samachetty, Hema D., and Neil R. Branda. "Integrating molecular switching and chemical reactivity using photoresponsive hexatrienes." Pure and Applied Chemistry 78, no. 12 (January 1, 2006): 2351–59. http://dx.doi.org/10.1351/pac200678122351.

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The use of photoresponsive hexatriene architectures to regulate chemical reactivity is described. The major focus of this report is how the two isomers of dithienylethene derivatives exhibit different steric and electronic properties. The ring-open form is structurally flexible, and the thiophene rings are electronically insulated from each other, while the ring-closed counterpart has a rigid structure, and there is a linear π-conjugated pathway along the molecular backbone. Representative examples that demonstrate how these photoswitches can be used to influence metal coordination, catalysis, and nucleophilicity are highlighted in this overview.
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12

Guner, Vildan Adar, K. N. Houk, and Ian W. Davies. "Computational Studies on the Electrocyclizations of 1-Amino-1,3,5-hexatrienes." Journal of Organic Chemistry 69, no. 23 (November 2004): 8024–28. http://dx.doi.org/10.1021/jo048540s.

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13

Hilt, Gerhard, Anastasia Schmidt, and Elias Maiterth. "Cobalt-Catalysed Transformations of 1,3,5-Hexatrienes on a Large Scale." Synthesis 46, no. 15 (July 9, 2014): 2040–44. http://dx.doi.org/10.1055/s-0034-1378375.

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14

HRABAL, R., Z. CHVATAL, and V. DEDEK. "ChemInform Abstract: Thermal and UV-Induced Isomerization of Fluorinated Hexatrienes." ChemInform 25, no. 38 (August 19, 2010): no. http://dx.doi.org/10.1002/chin.199438066.

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15

Kantlehner, Willi, Hansjörg Lehmann, Rüdiger Stieglitz, and Wolfgang Frey. "Orthoamide und Iminiumsalze, XCVI. Push-pull-substituierte 1,3,5-Hexatriene aus Orthoamiden von Alkincarbonsäuren und Birckenbach-analogen Acetophenonen." Zeitschrift für Naturforschung B 74, no. 11-12 (December 18, 2019): 913–24. http://dx.doi.org/10.1515/znb-2019-0077.

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AbstractFrom acetone and the orthoamide of phenylpropiolic acid (21b) N,N-dimethyl-phenylpropiolic acid amide (24) is formed. In contrast, the reaction of chloroacetone (28) with 21b results in the vinylogous guanidinium chloride 29. Unexpectedly, the Birckenbach-analogoue ethyl methyl ketone (34) reacts with the orthoamide 21b to give the push-pull-substituted butadiene 36. In contrast to this observation, the reaction of the Birckenbach-analogous acetophenones 30 with the orthoamides 21a–c delivers the push-pull-substituted 1,3,5-hexatrienes 31a–j.
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16

Buma, Wybren Jan, Bryan E. Kohler, and Kyuseok Song. "Lowest energy excited singlet states of isomers of alkyl substituted hexatrienes." Journal of Chemical Physics 94, no. 7 (April 1991): 4691–98. http://dx.doi.org/10.1063/1.460581.

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17

Dworczak, Renate, Walter M. F. Fabian, Claudia Reidlinger, Alice Rumpler, Jörg Schachner, and Klaus Zangger. "Nonlinear optical properties of diazabutadienes and -hexatrienes; experimental and computational aspects." Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 58, no. 10 (August 2002): 2135–44. http://dx.doi.org/10.1016/s1386-1425(01)00678-3.

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18

CAO, X. P., T. L. CHAN, H. F. CHOW, and J. TU. "ChemInform Abstract: Stereoselective Synthesis of Substituted 1,3,5-Hexatrienes from Diallylic Sulfones." ChemInform 26, no. 43 (August 17, 2010): no. http://dx.doi.org/10.1002/chin.199543110.

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19

Kowalski, Dorothee, Gerhard Erker, and Sirpa Kotila. "3H-Azepines by Intramolecular Condensation Reaction of 1,6-Diamino-1,3,5-hexatrienes." Liebigs Annalen 1996, no. 6 (January 25, 2006): 887–90. http://dx.doi.org/10.1002/jlac.199619960605.

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20

Yu, Tang-Qing, Yao Fu, Lei Liu, and Qing-Xiang Guo. "How to Promote Sluggish Electrocyclization of 1,3,5-Hexatrienes by Captodative Substitution." Journal of Organic Chemistry 71, no. 16 (August 2006): 6157–64. http://dx.doi.org/10.1021/jo060885i.

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21

BUHMANN, M., M. H. MOELLER, and E. U. WUERTHWEIN. "ChemInform Abstract: Synthesis and Structures of 1-Oxa-3,5-diaza-1,3,5-hexatrienes. The 1- Oxa-3,5-diaza-1,3,5-hexatriene/2H-1,3,5-Oxadiazine Tautomerism." ChemInform 25, no. 25 (August 19, 2010): no. http://dx.doi.org/10.1002/chin.199425159.

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22

Norton, Joseph E., and K. N. Houk. "H/vinyl conical intersections of hexatrienes related to the hula-twist photoisomerization." Molecular Physics 104, no. 5-7 (March 10, 2006): 993–1008. http://dx.doi.org/10.1080/00268970500417606.

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23

Dolbier, William R., Keith Palmer, Henryk Koroniak, Hua Qi Zhang, and Virgil L. Goedkin. "Fluorine substituent effects on thermal isomerizations: a new thermal reaction of 1,3,5-hexatrienes." Journal of the American Chemical Society 113, no. 3 (January 1991): 1059–60. http://dx.doi.org/10.1021/ja00003a059.

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24

Bagrov, F. V. "ChemInform Abstract: Steric Structure of 1-Hydroxy-2,3-dimethyl-1,4,5-triaza-1,3,5-hexatrienes." ChemInform 32, no. 30 (May 25, 2010): no. http://dx.doi.org/10.1002/chin.200130098.

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25

Viteva, Lilia, Tzveta Gospodova, Yuri Stefanovski, Marie-Rose Mazières, and Jean Gérard Wolf. "Nucleophilic addition of organolithium reagents to cyanine dyes. A new access to functionalized hexatrienes." Tetrahedron Letters 42, no. 45 (November 2001): 7945–48. http://dx.doi.org/10.1016/s0040-4039(01)01672-0.

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26

Sünnemann, Hans Wolf, Martin G. Banwell, and Armin de Meijere. "Synthesis and Use of New Substituted 1,3,5-Hexatrienes in Studying Thermally Induced 6π-Electrocyclizations." European Journal of Organic Chemistry 2007, no. 23 (August 2007): 3879–93. http://dx.doi.org/10.1002/ejoc.200700201.

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27

KOWALSKI, D., G. ERKER, and S. KOTILA. "ChemInform Abstract: 3H-Azepines by Intramolecular Condensation Reaction of 1,6-Diamino-1,3, 5-hexatrienes." ChemInform 27, no. 41 (August 4, 2010): no. http://dx.doi.org/10.1002/chin.199641156.

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28

Brouwer, A. M., and H. J. C. Jacobs. "Photochemistry of 2,5-dimethyl-1,3,5-hexatrienes in argon matrices. Formation of isomers and rotamers." Recueil des Travaux Chimiques des Pays-Bas 114, no. 11-12 (1995): 449–58. http://dx.doi.org/10.1002/recl.19951141105.

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29

Sonoda, Yoriko, Hisayuki Morii, Masako Sakuragi, and Yasuzo Suzuki. "Substituent Effect on the cis-trans Photoisomerization of trans,trans,trans-1,6-Diphenyl-1,3,5-hexatrienes." Chemistry Letters 27, no. 4 (April 1998): 349–50. http://dx.doi.org/10.1246/cl.1998.349.

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30

Sonoda, Yoriko, Yuji Kawanishi, Takuji Ikeda, Midori Goto, Shigenobu Hayashi, Yuji Yoshida, Nobutaka Tanigaki, and Kiyoshi Yase. "Fluorescence Spectra for the Microcrystals and Thin Films oftrans,trans,trans-1,6-Diphenyl-1,3,5-hexatrienes." Journal of Physical Chemistry B 107, no. 15 (April 2003): 3376–83. http://dx.doi.org/10.1021/jp021811n.

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31

BUMA, W. J., B. E. KOHLER, and K. SONG. "ChemInform Abstract: Lowest Energy Excited Singlet States of Isomers of Alkyl Substituted Hexatrienes (I)-(III)." ChemInform 22, no. 34 (August 22, 2010): no. http://dx.doi.org/10.1002/chin.199134040.

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32

DOLBIER, W. R. JUN, K. PALMER, H. KORONIAK, H. Q. ZHANG, and V. L. GOEDKIN. "ChemInform Abstract: Fluorine Substituent Effects on Thermal Isomerizations: A New Thermal Reaction of 1,3,5-Hexatrienes." ChemInform 22, no. 20 (August 23, 2010): no. http://dx.doi.org/10.1002/chin.199120114.

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33

Saltiel, Jack, Shujun Wang, Lucas P. Watkins, and Dong-Hoon Ko. "Direct Photoisomerization of the 1,6-Diphenyl-1,3,5-hexatrienes. Medium Effect on Triplet and Singlet Contributions." Journal of Physical Chemistry A 104, no. 48 (December 2000): 11443–50. http://dx.doi.org/10.1021/jp002359f.

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34

Viteva, Lilia, Tzveta Gospodova, Yuri Stefanovski, Marie-Rose Mazieres, and Jean Gerard Wolf. "ChemInform Abstract: Nucleophilic Addition of Organolithium Reagents to Cyanine Dyes. A New Access to Functionalized Hexatrienes." ChemInform 33, no. 8 (May 22, 2010): no. http://dx.doi.org/10.1002/chin.200208182.

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35

Brouwer, A. M., J. Cornelisse, and H. J. C. Jacobs. "Deuterium isotope effects in the photochemistry of 2,5-dimethyl- and 2,5-di-tert-butyl-1,3,5-hexatrienes." Journal of Photochemistry and Photobiology A: Chemistry 42, no. 2-3 (April 1988): 313–20. http://dx.doi.org/10.1016/1010-6030(88)80074-1.

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36

Negri, Fabrizia, Giorgio Orlandi, Albert M. Brouwer, Frans W. Langkilde, and Robert Wilbrandt. "The lowest triplet state of 1,3,5‐hexatrienes: Quantum chemical force field calculations and experimental resonance Raman spectra." Journal of Chemical Physics 90, no. 11 (June 1989): 5944–63. http://dx.doi.org/10.1063/1.456361.

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37

Aumann, Rudolf, Barbara Hildmann, and Roland Fröhlich. "Organic Syntheses via Transition Metal Complexes. 95.1Rearrangement of (Cyclobutenyl)carbene Tungsten Complexes to 1-Tungsta-1,3,5-hexatrienes." Organometallics 17, no. 6 (March 1998): 1197–201. http://dx.doi.org/10.1021/om9708586.

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38

SONODA, Y., H. MORII, M. SAKURAGI, and Y. SUZUKI. "ChemInform Abstract: Substituent Effect on the cis-trans Photoisomerization of trans,trans,trans-1,6-Diphenyl-1,3,5-hexatrienes." ChemInform 29, no. 33 (June 20, 2010): no. http://dx.doi.org/10.1002/chin.199833084.

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39

Villiers, Pierre, Nicolas Vicart, Yvan Ramondenc, and Gérard Plé. "1,6-Dibromohexa-1,3,5-triene − Stereocontrolled Synthesis of Monosubstituted and Disubstituted Hexatrienes by Palladium-Catalysed Cross-Coupling Reactions." European Journal of Organic Chemistry 2001, no. 3 (February 2001): 561–74. http://dx.doi.org/10.1002/1099-0690(200102)2001:3<561::aid-ejoc561>3.0.co;2-r.

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40

Kauffman, Joel M., and Guillermo Moyna. "Diarylamino Groups as Photostable Auxofluors in 2-Benzoxazolylfluorene, 2,5-Diphenyloxazoles, 1,3,5-Hexatrienes, 1,4-Distyrylbenzenes, and 2,7-Distyrylfluorenes." Journal of Organic Chemistry 68, no. 3 (February 2003): 839–53. http://dx.doi.org/10.1021/jo020333+.

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41

Lin, Shie Hsiung, Gene Hsiang Lee, Shie Ming Peng, and Rai Shung Liu. "Molybdenum-.pi.-allyl compounds for chemoselective synthesis of tetrahydrofurans, cis-1,3-dienes, cis-hexatrienes, and isoxazole compounds." Organometallics 12, no. 7 (July 1993): 2591–99. http://dx.doi.org/10.1021/om00031a032.

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42

Brouwer, A. M., J. Cornelisse, and H. J. C. Jacobs. "Photochemistry of 2,5-dimethyl- and 2,5-di-tert-butyl-1,3,5-hexatrienes: conformation and reactivity — a quantitative study." Journal of Photochemistry and Photobiology A: Chemistry 42, no. 1 (March 1988): 117–26. http://dx.doi.org/10.1016/1010-6030(88)80053-4.

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43

Chen, Rongliang, Leticia U. Colmenares, J. R. Thiel, and Robert S. H. Liu. "Spiral hexatrienes. The hindered cis isomer of mini-carotene-3 and hexakis-(2,2′,4,4′,6,6′-trifluoromethyl)stilbene." Tetrahedron Letters 35, no. 39 (September 1994): 7177–80. http://dx.doi.org/10.1016/0040-4039(94)85354-1.

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44

García-Rubín, Silvia, Jesús A. Varela, Luis Castedo, and Carlos Saá. "6πe−versus 8πe−Electrocyclization of 1-Aryl- and Heteroaryl-Substituted (1Z,3Z)-1,3,5-Hexatrienes: A Matter of Aromaticity†." Organic Letters 11, no. 4 (February 19, 2009): 983–86. http://dx.doi.org/10.1021/ol802925q.

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45

Lin, C. T., H. W. Guan, R. K. McCoy, and C. W. Spangler. "Dual fluorescence of p,p'-disubstituted 1,6-diphenyl-1,3,5-hexatrienes: evidence of a twisted intramolecular charge-transfer state." Journal of Physical Chemistry 93, no. 1 (January 1989): 39–43. http://dx.doi.org/10.1021/j100338a013.

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46

Dell'Erba, Carlo, Antonella Gabellini, Angelo Mugnoli, Marino Novi, Giovanni Petrillo, and Cinzia Tavani. "From 3,4-dinitrothiophene to 1,2-diaryl-4-nitrobenzenes through ( E , E , E )-1,6-diaryl-3-nitro-1,3,5-hexatrienes." Tetrahedron 57, no. 43 (October 2001): 9025–31. http://dx.doi.org/10.1016/s0040-4020(01)00898-5.

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47

Wu, He-Ping, Rudolf Aumann, Roland Fröhlich, and Birgit Wibbeling. "Stereocontrolled Synthesis of Angularly Fused Tricyclic Ring Systems by Means of 1-Metalla-1,3,5-hexatrienes (M=Cr, W)." Chemistry - A European Journal 8, no. 4 (February 15, 2002): 910–16. http://dx.doi.org/10.1002/1521-3765(20020215)8:4<910::aid-chem910>3.0.co;2-t.

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48

Shimizu, Masaki, Katsuhiro Shimono, Michael Schelper, and Tamejiro Hiyama. "Stereoselective Cross-Coupling Reaction of 2,4-Diaryl-1,1-diboryl-1,3-butadienes: Stereocontrolled Approach to 1,3,4,6-Tetraarylated 1,3,5-Hexatrienes." Synlett 2007, no. 12 (July 2007): 1969–71. http://dx.doi.org/10.1055/s-2007-982567.

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49

Brouwer, A. M., L. Bezemer, J. Cornelisse, and H. J. C. Jacobs. "Photochemistry of 2,5-dialkyl-1,3,5-hexatrienes. The influence of the ground-state conformation, controlled through steric substituent effects." Recueil des Travaux Chimiques des Pays-Bas 106, no. 12 (September 2, 2010): 613–24. http://dx.doi.org/10.1002/recl.19871061203.

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50

Williams, E. E., and J. R. Hazel. "Membrane fluidity and hemilayer temperature sensitivity in trout hepatocytes during brief in vitro cold exposure." American Journal of Physiology-Regulatory, Integrative and Comparative Physiology 266, no. 3 (March 1, 1994): R773—R780. http://dx.doi.org/10.1152/ajpregu.1994.266.3.r773.

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Fluorescent membrane probes were used to assess the fluidity of hepatocyte plasma membranes (PM) from 20 degrees C-acclimated trout after exposure to 20 and 5 degrees C. PM isolated from cells after 6 h at 5 degrees C were significantly more fluid [fluorescence depolarization of 1,6-diphenyl-1,3,5-hexatriene (DPH)] than control membranes at both temperatures. The increased fluidity was sufficient to offset 45-50% of the cold-induced membrane ordering. In contrast, the fluidity of PM in intact cells from 20 degrees C-acclimated fish remained constant when exposed to 5 degrees C for a similar period. In addition, the fluidity of the inner hemilayer [1-(4-trimethylammoniumphenyl)-6-phenyl-1,3,5-hexatriene, p-toluenesulfonate (TMA-DPH)] was significantly less sensitive to temperature change than was the fluidity of the outer hemilayer [3-(p-(6-phenyl)-1,3,5-hexatrienyl)phenylpropionic acid (PA-DPH)]. Because the isolated membrane preparation was most likely enriched with canalicular membranes (based on 5'-nucleotidase recovery), these results suggest that the canalicular domain of the plasma membrane is preferentially modified during short-term cold exposure and that the fluidity of the inner hemilayer of the plasma membrane of intact cells is relatively temperature insensitive, thus requiring fewer modifications than the outer hemilayer during temperature acclimation.
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