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Journal articles on the topic 'Homobinuclear'

Author: Grafiati

Published: 5 June 2025

Last updated: 1 August 2025

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1

Wang, Chiming, Xin Chen, Qingyun Liu, Dongdong Qi, Kang Wang, and Jianzhuang Jiang. "Combinatorial experimental and DFT theoretical investigation over the formation mechanism of a binuclear phthalocyanine dimer." RSC Advances 7, no. 84 (2017): 53043–47. http://dx.doi.org/10.1039/c7ra10678e.

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2

Vagin, Sergei I., and Bernhard Rieger. "Homo- and Hetero-bimetallic Flexibly Linked Dinuclear Salphen Complexes Homo- and Hetero-bimetallic Flexibly Linked Dinuclear Salphen Complexes." Zeitschrift für Naturforschung B 67, no. 6 (2012): 614–20. http://dx.doi.org/10.5560/znb.2012-0088.

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A modification of the previously developed synthetic approach towards dinuclear flexibly linked salphen complexes is successfully utilized for the preparation of heterodinuclear salphen dimers. A dinuclear salphen species with Pd(II) and Cr(III) centers bears a stronger structural resemblance to the related bis-Cr(III) compound than the corresponding mononuclear Cr(III) salphen complex. Therefore, it was considered as a more useful model for the comparison with the homobinuclear Cr(III) complex regarding the catalytic activity in the ring-opening polymerization of β-butyrolactone, for which a

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3

T.V., R. K. RAO, and P. YADAV R. "Homobinuclear Complexes of Magnesium and Calcium." Journal of Indian Chemical Society Vol. 70, Jun 1993 (1993): 561–62. https://doi.org/10.5281/zenodo.5917365.

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4

Brewer, Greg, and Ekk Sinn. "2,2'-Bipyrimidine-bridged homobinuclear complexes." Inorganic Chemistry 24, no. 26 (1985): 4580–84. http://dx.doi.org/10.1021/ic00220a030.

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5

Rusakova, Natalia, Olena Malinka, Oleksandr Korovin, Serhii Smola, Olga Snurnikova, and Mariia Rusakova. "HOMO- AND HETERONUCLEAR Yb(III) AND Lu(III) COMPLEXES WITH CALIX[4]ARENE MODIFIED WITH PORPHYRIN SUBSTITUENTS." Ukrainian Chemistry Journal 89, no. 9 (2023): 52–63. http://dx.doi.org/10.33609/2708-129x.89.09.2023.52-63.

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In this work we describe the approaches for the synthesis of lanthanide-containing homo- and heteronuclear complexes using 5,11,17,23-tetra-tert-butyl-25,27-dihydroxy-26,28-bis[(N-meso-(p-aminophenyl)-meso-triphenylporphyrincarbonyl)methoxy]-calix[4]arene (1). Such spatially preorganizedcalix[4]arene macrocycle facilitates lanthanide cation coordination, impacting the structure and analytical signal of porphyrin substituents. The study employs two synthesis strategies resulting in mononuclear and homobinuclear complexes, influenced by steric effects and changes in hydrogen bonding. The compl

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6

Rizzi, Alberto, Ricardo Baggio, Maria T. Garland, Octavio Peña, and Mireille Perec. "New homobinuclear carboxylate-bridged gadolinium(III) complexes." Inorganica Chimica Acta 353 (September 2003): 315–19. http://dx.doi.org/10.1016/s0020-1693(03)00255-x.

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7

Badiger, Basavantappa M., Sangarnesh A. Patil, Subhas D. Angadi, and Vasant H. Kulkarni. "Homobinuclear Complexes of Copper(II) with Copper(II) Thiocarbohydrazones." Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry 16, no. 2 (1986): 201–11. http://dx.doi.org/10.1080/00945718608057526.

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8

Huang, Chunhua, Kang Wang, Junshan Sun, and Jianzhuang Jiang. "Homobinuclear phthalocyaninato metal complexes. Synthesis, structure, spectroscopy, and electrochemistry." Dyes and Pigments 109 (October 2014): 163–68. http://dx.doi.org/10.1016/j.dyepig.2014.05.011.

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9

Sun, Junquan, Xijie Liu, Haiying Zhang, Xiaohui Xiao, Feng Lin, and Herbert Schumann. "Ethylene polymerization by phenylenedimethylene-bridged homobinuclear zirconocene/methylaluminoxane systems." Journal of Applied Polymer Science 99, no. 5 (2005): 2193–98. http://dx.doi.org/10.1002/app.22719.

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10

Katsoulos, George A., Constantinos A. Tsipis, and Fotios D. Vakoulis. "Spectral and bonding properties of bis(N,N-disubstituted-dithiocarbamato)iron(III)dihalide complexes studied by experimental and EHMO quantum-chemical methods." Canadian Journal of Chemistry 63, no. 11 (1985): 3249–55. http://dx.doi.org/10.1139/v85-537.

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A new series of homobinuclear iron(III) halobisdithiocarbamate complexes antiferromagnetically coupled through a molecular halogen bridging unit has been synthesised and studied. The complexes have been characterized chemically and by spectroscopic methods and magnetic susceptibility measurements. The volatility characteristics and thermogravimetric analysis data for the new compounds are also studied. Finally, quantum-chemical calculations have been used to provide a qualitative guide to the possible pathways for the superexchange processes observed in these molecular magnetic systems, as wel

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11

Alvarado-Monzón, José C., Jorge A. López, Gabriel A. Andreu de Riquer, Crispin Cristobal, Marcos Flores-Alamo, and Lena Ruiz-Azuara. "Iridium(I) homobinuclear complexes containing salen-type ligands as bridge." Polyhedron 161 (March 2019): 243–50. http://dx.doi.org/10.1016/j.poly.2019.01.022.

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12

Krisyuk, Vladislav V., Assia E. Turgambaeva, and Shi-Woo Rhee. "Homobinuclear copper(I) hexafluoroacetylacetonate complexes with non-cyclic diene ligands." Polyhedron 23, no. 5 (2004): 809–13. http://dx.doi.org/10.1016/j.poly.2003.12.001.

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13

Liu, Xijie, Junquan Sun, Haiying Zhang, Xiaohui Xiao, and Feng Lin. "Ethylene polymerization by novel phenylenedimethylene bridged homobinuclear titanocene/MAO systems." European Polymer Journal 41, no. 7 (2005): 1519–24. http://dx.doi.org/10.1016/j.eurpolymj.2005.01.019.

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14

Lalia-Kantouri, M., G. A. Katsoulos, and F. D. Vakoulis. "Thermal decomposition of some homobinuclear dihalide-bridged iron(III) complexes." Journal of Thermal Analysis 31, no. 2 (1986): 447–61. http://dx.doi.org/10.1007/bf01911075.

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15

M. Thakor, Priteshkumar. "NATURAL ACID-CATALYZED SYNTHESIS OF 6,6'-(((3,3'- DIMETHOXY-[1,1'-BIPHENYL]-4,4'- DIYL)BIS(AZANYLYLIDENE))BIS(METHANYLYLIDENE))BIS( 2,4-DICHLOROPHENOL), ITS CONVENTIONALLY SYNTHESIZED METAL COMPLEXES AND THEIR POTENTIAL AS BIOLOGICAL AGENTS." RASAYAN Journal of Chemistry 16, no. 01 (2023): 61–68. http://dx.doi.org/10.31788/rjc.2023.1618108.

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Organic research has recently focused on the development of a more environmentally friendly process that uses alternate reaction media in place of harmful and expensive catalysts. So here a facile protocol was developed for the green synthesis of a novel Schiff base ligand, and the synthesized ligand was characterized using physicochemical techniques. The homobinuclear complexes of synthesized ligands made of Iron (II), Cobalt (II), Manganese (II), Nickel (II), Zinc (II), and Copper (II) were characterized through the FTIR technique after synthesizing them conventionally. The in-vitro antimicr

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16

Phillips, Ian G., and Peter J. Steel. "Mono- and Bi-nuclear Complexes of the Doubly Bidentate, Bridging Ligand 4,6-Di(2-pyridyl)pyrimidine." Australian Journal of Chemistry 51, no. 5 (1998): 371. http://dx.doi.org/10.1071/c97127.

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Thirteen mononuclear, homobinuclear and heterobinuclear transition metal complexes of 4,6-di(2- pyridyl)pyrimidine have been prepared. Assignments of the 1H n.m.r. spectra of the molybdenum(0) and ruthenium(II) complexes were achieved by a combination of one- and two-dimensional n.m.r. techniques, especially 1D-TOCSY. For the ruthenium complexes, electronic absorption spectroscopy and cyclic voltammetry were used to probe the nature of the metal{ligand and, for the binuclear complexes, metal-metal interactions. The complexes have low HOMO−LUMO energy gaps. Meta-metal interactions are shown to

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17

Lin, Rongguang, and Thomas F. Guarr. "Spectroscopic and electrochemical investigation of strongly luminescent homobinuclear Re(I) complexes." Inorganica Chimica Acta 167, no. 2 (1990): 149–52. http://dx.doi.org/10.1016/s0020-1693(00)80490-9.

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18

Akrivos, Pericles D., Maria N. Christianopoulou, M. Baumgarten, and P. Kokorotsikos. "Homobinuclear metal chelates of anthraquinones having a MO4 chromophore—II. Anthrarufin." Spectrochimica Acta Part A: Molecular Spectroscopy 46, no. 3 (1990): 363–68. http://dx.doi.org/10.1016/0584-8539(90)80106-9.

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19

Bakola-Christianopoulou, M. N., P. D. Akrivos, and M. Baumgarten. "Binuclear metal chelate complexes of anthraquinones having a MO4 chromophore. Part 1. Quinizarin." Canadian Journal of Chemistry 65, no. 7 (1987): 1485–90. http://dx.doi.org/10.1139/v87-253.

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Homobinuclear metal chelate complexes having 1,4-dihydroxy-9,10-anthracenedione (quinizarin) as a bridging unit have been prepared with four bivalent first row transition elements, namely cobalt, nickel, copper, and zinc. The coordination spheres of the metal ions consist of two nearly equivalent six-membered rings with oxygen donor atoms derived from the quinizarin and the terminal ligands which are either β-diketones or salicylic aldehyde. TG, spectroscopic (ir, uv–vis, epr), and magnetic measurements have been applied to an investigation of the geometry adopted by the MO4 chromophores. The

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20

Gupta, Nidhi. "Spectroscopic methods (IR, EPR and Electronic) for characterization of Homobinuclear 3D complexes." Asian Journal of Research in Chemistry 10, no. 4 (2017): 520. http://dx.doi.org/10.5958/0974-4150.2017.00085.2.

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21

Maiboroda, Andrei, та Heinrich Lang. "Homobinuclear complexes of osmium(iv) with nitrogen-containing π-conjugated bridging units". New Journal of Chemistry 25, № 4 (2001): 642–46. http://dx.doi.org/10.1039/b007619h.

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22

Kılıç, Yalçın, and İbrahim Kani. "Selective catalytic oxidation of alkenes employing homobinuclear manganese(II) catalysts with TBHP." Polyhedron 141 (February 2018): 352–59. http://dx.doi.org/10.1016/j.poly.2017.12.019.

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23

Wojcicki, Andrew. "New chemistry based on reduction of homobinuclear bis(μ-phosphido) metal complexes". Inorganica Chimica Acta 100, № 1 (1985): 125–33. http://dx.doi.org/10.1016/s0020-1693(00)88300-0.

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24

Bu, Xian-He, Miao Du, Lei Zhang, Xu-Bo Song, Ruo-Hua Zhang, and Thomas Clifford. "Novel homobinuclear lanthanide(III) complexes with isonicotinoyl hydrazone: synthesis and coordination chemistry." Inorganica Chimica Acta 308, no. 1-2 (2000): 143–49. http://dx.doi.org/10.1016/s0020-1693(00)00215-2.

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25

Kaes, Christian, Mir Wais Hosseini, André De Cian, and Jean Fischer. "Bipyridine based exoditopic ligands: Synthesis and structural analysis of homobinuclear ruthenium complexes." Tetrahedron Letters 38, no. 22 (1997): 3901–4. http://dx.doi.org/10.1016/s0040-4039(97)00757-0.

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26

Ruo-Hua, Zhang, Wang Hong-Mei, Liao Dai-Zheng, Chen Jing-Tang, Wang Hong-Gen, and Yao Xing-Kan. "Structure and magnetic properties of homobinuclear gadolinium (III) complex of isonicotinoyl hydrazone." Chinese Journal of Chemistry 14, no. 6 (2010): 506–15. http://dx.doi.org/10.1002/cjoc.19960140605.

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27

Cucos, Andrei, Narcis Avarvari, Marius Andruh, Yves Journaux, Achim Müller, and Marc Schmidtmann. "Reinecke Anion Derivatives and Homobinuclear Complexes as Tectons in Designing Heteropolymetallic Systems." European Journal of Inorganic Chemistry 2006, no. 5 (2006): 903–7. http://dx.doi.org/10.1002/ejic.200500841.

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28

Patel, Pushpa, and P. K. Bhattacharya. "Solution and solid state studies of mixed ligand binuclear complexes containing one binucleating ligand." Canadian Journal of Chemistry 71, no. 8 (1993): 1253–58. http://dx.doi.org/10.1139/v93-161.

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Stability constants of homobinuclear binary Cu(II) complexes of the dinucleating ligands, having equivalent coordination sites, 5,5′-methylene-bis-salicylaldehyde (H2A1), 5,5′-methylene-bis-(3-bromosalicylaldehyde) (H2A2), and 5,5′-methylene-bis-(3-nitrosalicylaldehyde) (H2A3), and mixed ligand Cu(II) complexes with one of the above ligands and bipyridyl (L1) or 1,10-phenanthroline (L2) as second ligand, have been determined potentiometrically in water:dioxane medium (50:50 and 30:70,v/v using a computer programme. The values of [Formula: see text] and [Formula: see text] have been compared wi

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29

Kurbah, Sunshine Dominic, Arvind Kumar, Ibanphylla Syiemlieh, and Ram A. Lal. "Crystal structure and biomimetic activity of homobinuclear dioxidovanadium(V) complexes containing succinoyldihydrazones ligands." Polyhedron 139 (January 2018): 80–88. http://dx.doi.org/10.1016/j.poly.2017.10.013.

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30

Patel, R. N., Subodh Kumar, K. B. Pandeya, and P. V. Khadikar. "Paramagnetic resonance in imidazolate-bridged homobinuclear (copper–copper) and heterobinuclear (copper–zinc) complexes." Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 58, no. 13 (2002): 2961–69. http://dx.doi.org/10.1016/s1386-1425(02)00041-0.

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31

Chandra, Sulekh, Nidhi Gupta, and Rachna Gupta. "Novel copper(II) homobinuclear macrocyclic complexes: Cyclic voltammetry, biological properties and spectral studies." Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 63, no. 3 (2006): 587–93. http://dx.doi.org/10.1016/j.saa.2005.06.005.

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32

Costes, Jean-Pierre, Juan Modesto Clemente-Juan, Françoise Dahan, Franck Nicodème, and Marc Verelst. "Unprecedented Ferromagnetic Interaction in Homobinuclear Erbium and Gadolinium Complexes: Structural and Magnetic Studies." Angewandte Chemie 114, no. 2 (2002): 333–35. http://dx.doi.org/10.1002/1521-3757(20020118)114:2<333::aid-ange333>3.0.co;2-u.

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33

Costes, Jean-Pierre, Juan Modesto Clemente-Juan, Françoise Dahan, Franck Nicodème, and Marc Verelst. "Unprecedented Ferromagnetic Interaction in Homobinuclear Erbium and Gadolinium Complexes: Structural and Magnetic Studies." Angewandte Chemie International Edition 41, no. 2 (2002): 323–25. http://dx.doi.org/10.1002/1521-3773(20020118)41:2<323::aid-anie323>3.0.co;2-9.

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34

Naili, Noura, and Bachir Zouchoune. "Structural diversity of homobinuclear transition metal complexes of the phenazine ligand: theoretical investigation." Structural Chemistry 29, no. 3 (2017): 725–39. http://dx.doi.org/10.1007/s11224-017-1064-2.

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35

Pandya, Bhavna J., and Pabitra K. Bhattacharya. "Binary and ternary complexes of oxovanadium(IV) and homobinuclear double-bridged oxovanadium(IV) complexes." Transition Metal Chemistry 12, no. 5 (1987): 398–400. http://dx.doi.org/10.1007/bf01171645.

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36

Ho, I.-Ting, Kuan-Chang Haung, and Wen-Sheng Chung. "1,3-Alternate Calix[4]arene as a Homobinuclear Ditopic Fluorescent Chemosensor for Ag+ Ions." Chemistry - An Asian Journal 6, no. 10 (2011): 2738–46. http://dx.doi.org/10.1002/asia.201100023.

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37

Mukred, Rasel, and Samir Osman Mohammed. "Structures and properties of three new homobinuclear nanosized supramolecular copper coordination polymers derived from carboxylate type ligands and benzimidazole." French-Ukrainian Journal of Chemistry 8, no. 1 (2020): 149–66. http://dx.doi.org/10.17721/fujcv8i1p149-166.

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Three new homobinuclear nanosized supramolecular copper coordination polymers are hydrothermally synthesized by self-assembly reaction of L-tyrosine (Tyr), terephthalic acid (H2bdc), pyromellitic acid (H4btec) and benzimidazole (Hbzim) with copper chloride salt to generate with formula [[Cu2(tyr)2(bzim)2(Cl)2(H2O)2]]n 1, [[Cu2(bdc)2(bzim)2(H2O)6].3H2O]n 2 and [Cu2(H2btec)(bzim)(H2O)6].2H2O]n 3, which have been investigated by elemental analysis, molar conductivity and magnetic measurements, FT-IR and UV-Vis spectroscopy, (TGA/DTA) thermal analysis and X-ray powder diffraction(XRPD) analysis as

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38

Szesni, Normen, Matthias Drexler, Bernhard Weibert, and Helmut Fischer. "Ethynylthioamide Complexes: Synthesis, Reactivity and an Unusual Coupling Reaction with Diethylaminopropyne." Zeitschrift für Naturforschung B 62, no. 3 (2007): 346–56. http://dx.doi.org/10.1515/znb-2007-0307.

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The reaction of [(CO)5Cr(THF)] with propynethioic acid amides, R-C≡C-C(=S)NMe2 (R = H, SiMe3), yields the thioamide complexes [(CO)5Cr-S=C(NMe2)C≡C-H] (1a) and [(CO)5Cr- S=C(NMe2)C≡C-SiMe3] (1b). Treatment of solutions of 1a or 1b with methyllithium generates, via deprotonation or desilylation, the lithium salt Li[(CO)5Cr-S=C(NMe2)C≡C] (2). On filtration over silica, 2 is readily reprotonated. Complex 1a is inert towards methanol, however, adds diethylamine across the C≡C bond to give the thioacrylamide complex [(CO)5Cr-S=C(NMe2)C(H)=C(H)NMe2] (3). Thiourea displaces the thioamide ligand to gi

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39

Rettig, Steven J., Mark Sandercock, Alan Storr, and James Trotter. "Pyrazagaboles, pyrazolyl-bridged heterocycles containing boron and gallium." Canadian Journal of Chemistry 68, no. 1 (1990): 59–63. http://dx.doi.org/10.1139/v90-012.

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The synthesis and structural characterization of representative and novel pyrazagaboles, boron- and gallium-containing compounds with a central six-membered heterocyclic B—(N—N)2—Ga ring feature, are detailed. Crystals of dimethylgallium-bis(μ-pyrazolyl)dimethylboron are orthorhombic, a = 7.6135(5), b = 16.2917(5), c = 22.331(1) Å, Z = 8, space group Pbca, and those of hydroxy(methyl)galliumbis(μ-pyrazolyl)dimethylboron are orthorhombic, a = 7.6197(3), b = 16.2184(7), c = 22.190(1) Å, Z = 8, space group Pbca. Both structures were solved by conventional heavy atom methods and were refined by fu

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40

Areas, Esther S., Henrique C. S. Junior, Brunno P. Freitas, Glaucio B. Ferreira, and Guilherme P. Guedes. "Homobinuclear compounds based on a chiral oxazolidine ligand: From solid state study to aqueous solution dynamics." Inorganica Chimica Acta 529 (January 2022): 120664. http://dx.doi.org/10.1016/j.ica.2021.120664.

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41

Werner, Helmut, Petra Bachmann, and Marta Martin. "Homobinuclear Ru-Ru and heterobinuclear Ru-Rh complexes with alkynyl and vinylidene ligands as molecular units." Canadian Journal of Chemistry 79, no. 5-6 (2001): 519–24. http://dx.doi.org/10.1139/v00-170.

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The chelate complex [RuCl2{κ2(P,O)-i-Pr2PCH2CH2OMe}2] (1) reacted, in the presence of CF3SO3Ag, with 1 equiv of C6H4(CºCH)2-p (4) to afford the mononuclear vinylidene compound [RuCl(C=CHC6H4-p-CºCH){κ2(P,O)-i-Pr2PCH2CH2OMe}2](CF3SO3) (3). From 1 and 0.5 equiv of 4, the binuclear bis(vinylidene) complex [RuCl{κ2(P,O)-i-Pr2PCH2CH2OMe}2(C=CHC6H4-p-CH=C)RuCl{κ2(P,O)-i-Pr2PCH2CH2OMe}2](CF3SO3)2 (6) was obtained. The related compound [RuCl{κ2(P,O)-i-Pr2PCH2CH2OMe}2(C=CHC6H4-m-CH=C)RuCl{κ2(P,O)-i-Pr2PCH2CH2OMe}2](CF3SO3)2 (7) was prepared from 1, 0.5 equiv of C6H4(CºCH)2-m (5), and silver triflate. T

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42

Batchelor, Lucinda K., Emilia Păunescu, Mylène Soudani, Rosario Scopelliti, and Paul J. Dyson. "Influence of the Linker Length on the Cytotoxicity of Homobinuclear Ruthenium(II) and Gold(I) Complexes." Inorganic Chemistry 56, no. 16 (2017): 9617–33. http://dx.doi.org/10.1021/acs.inorgchem.7b01082.

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43

Ruiz, Eliseo, Joan Cano, Santiago Alvarez, and Pere Alemany. "Broken symmetry approach to calculation of exchange coupling constants for homobinuclear and heterobinuclear transition metal complexes." Journal of Computational Chemistry 20, no. 13 (1999): 1391–400. http://dx.doi.org/10.1002/(sici)1096-987x(199910)20:13<1391::aid-jcc6>3.0.co;2-j.

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44

Derakhshankhah, Hossein, Ali Akbar Saboury, Adeleh Divsalar, and Hasan Mansouri-Torshizi. "Synthesis, Crystal Structure, Electrochemical Studies and Artificial Tyrosinase Activity of a New Designed Homobinuclear Copper (II) Complex." Biophysical Journal 100, no. 3 (2011): 217a. http://dx.doi.org/10.1016/j.bpj.2010.12.1399.

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45

Ismail, Tarek M., Abdalla M. Khedr, Samy M. Abu-El-Wafa, and Raafat M. Issa. "Mononuclear and homobinuclear vanadium(IV), chromium(III), molybdenum(III), and uranium(VI) chelates with ortho-cresolphthalein complexone." Journal of Coordination Chemistry 57, no. 14 (2004): 1179–90. http://dx.doi.org/10.1080/00958970412331281845.

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46

Surabhi, Sinha, and Krishna V. "Multimetal multiligand complex formation equilibria of copper(II), nickel(II) and zinc(II) with iminodiacetic acid and L-pyrrolidine-2-carboxylic acid in aqueous solution." Journal of Indian Chemical Society Vol. 83, Jan 2006 (2006): 13–15. https://doi.org/10.5281/zenodo.5814603.

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Department of Chemistry, University of Allahabad, Allahabad-211 002, Uttar Pradesh. India <em>E-mail </em>: vkprochem@yahoo.com <em>Manuscript received 3 November 2004, revised 18 July 2005, accepted 12 August 2005</em> Solution equilibria of homo and heterobinuclear complexes of cu<sup>ll</sup>, Ni<sup>ll</sup> and Zn<sup>ll</sup> with iminodiacetic acid (IMDA = A<sup>2</sup>-) and L-pyrrolidine-2-carboxylic acid (proline = B<sup>-</sup>)as ligands have been investigated by pH-measurements in an aqueous medium and relevant stability constants have been evaluated using computer technique. The

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47

Jiang, Weidong, Bin Xu, Fuan Liu, Ying Wang, and Zhen Xiang. "Catalytic Reactivity of Phenoxo-Bridged Homobinuclear Copper(II) Complexes With L-Threonine Schiff Bases As a Carboxylesterase Model." Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry 45, no. 1 (2014): 34–39. http://dx.doi.org/10.1080/15533174.2013.818026.

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48

Yao, Tiantian, Suna Wang, Dacheng Li, and Jianmin Dou. "Four homobinuclear lanthanide complexes with 3-D coordination networks based on 3-methyloxysalicylaldoxime: syntheses, crystal structures, and properties." Journal of Coordination Chemistry 68, no. 8 (2015): 1332–46. http://dx.doi.org/10.1080/00958972.2015.1009451.

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Cherkasova, Anna V., Viacheslav A. Kuropatov, Galina V. Romanenko, et al. "Cobalt and nickel homobinuclear metallomacrocycles based on the redox-active bis-semiquinonato ligands as potential functional absorbing materials." Polyhedron 247 (January 2024): 116717. http://dx.doi.org/10.1016/j.poly.2023.116717.

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Magrì, Antonio, Giovanni Tabbì, Irina Naletova, Francesco Attanasio, Giuseppe Arena, and Enrico Rizzarelli. "A Deeper Insight in Metal Binding to the hCtr1 N-terminus Fragment: Affinity, Speciation and Binding Mode of Binuclear Cu2+ and Mononuclear Ag+ Complex Species." International Journal of Molecular Sciences 23, no. 6 (2022): 2929. http://dx.doi.org/10.3390/ijms23062929.

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Abstract:

Ctr1 regulates copper uptake and its intracellular distribution. The first 14 amino acid sequence of the Ctr1 ectodomain Ctr1(1-14) encompasses the characteristic Amino Terminal Cu2+ and Ni2+ binding motif (ATCUN) as well as the bis-His binding motif (His5 and His6). We report a combined thermodynamic and spectroscopic (UV-vis, CD, EPR) study dealing with the formation of Cu2+ homobinuclear complexes with Ctr1(1-14), the percentage of which is not negligible even in the presence of a small Cu2+ excess and clearly prevails at a M/L ratio of 1.9. Ascorbate fails to reduce Cu2+ when bound to the

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